US2385198A - Method for forming drawing holes in carbide die nibs - Google Patents

Method for forming drawing holes in carbide die nibs Download PDF

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US2385198A
US2385198A US429796A US42979642A US2385198A US 2385198 A US2385198 A US 2385198A US 429796 A US429796 A US 429796A US 42979642 A US42979642 A US 42979642A US 2385198 A US2385198 A US 2385198A
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nib
needle
electrolyte
passage
forming
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Edgar W Engle
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Carboloy Co Inc
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Carboloy Co Inc
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23HWORKING OF METAL BY THE ACTION OF A HIGH CONCENTRATION OF ELECTRIC CURRENT ON A WORKPIECE USING AN ELECTRODE WHICH TAKES THE PLACE OF A TOOL; SUCH WORKING COMBINED WITH OTHER FORMS OF WORKING OF METAL
    • B23H5/00Combined machining
    • B23H5/06Electrochemical machining combined with mechanical working, e.g. grinding or honing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24BMACHINES, DEVICES, OR PROCESSES FOR GRINDING OR POLISHING; DRESSING OR CONDITIONING OF ABRADING SURFACES; FEEDING OF GRINDING, POLISHING, OR LAPPING AGENTS
    • B24B19/00Single-purpose machines or devices for particular grinding operations not covered by any other main group
    • B24B19/20Single-purpose machines or devices for particular grinding operations not covered by any other main group for grinding dies
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/53After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone involving the removal of at least part of the materials of the treated article, e.g. etching, drying of hardened concrete
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/91After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics involving the removal of part of the materials of the treated articles, e.g. etching
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S451/00Abrading
    • Y10S451/908Electrical abrading

Definitions

  • the present invention relates to a method of and apparatus for forming drawing holes in reiractory material such as die nibs. More particularly the invention relates to the making of such holes by removal of material from nibs of hard, metallic, electrically conducting materials, for example, the sintered material known as cemented carbide and described and claimed in Schroter Reissue Patent No. 17,624, March 18, 1930, which by way of example consists of tungsten carbide cemented with cobalt.
  • nibs may be made in "blank” or molded form.
  • a so-called blank” nib may be a substantially solid, preferably cylindrical, block of nib material having in one end thereof either a small shallow depression or a flared conical recess extending from about two-thirds to threequarters through the nib substantially axially thereof.
  • a so-called "molded nib has a'fiared passage extending completely through the nib substantially axially thereof.
  • Such nibs are usually encased in materials of high tensile strength such as steel to reinforce them so that they will withstand the forces set up in metal drawing operations.
  • the drawing holes prior to the present invention were usually formed in nibs by abrasive action, preferably either with the use of laps having particles of abrasive material distributed in or held on the surface of a suitable binding material, or by other breaching means with the use of free particles of abrasive.
  • abrasive action preferably either with the use of laps having particles of abrasive material distributed in or held on the surface of a suitable binding material, or by other breaching means with the use of free particles of abrasive.
  • Cemented hard metal carbides are characterized by very great hardness and resistance to abrasion. Consequently, the mechanical abrasive methods heretofore employed for forming the passage in die nibs of that character have been somewhat slow and expensive.
  • a general object of the present invention is the provision of an effective and efiicient method of forming drawing holes in hard metal, electrically conductingdie nibs which method may be readily carried out in a relatively short time and without the use of excessively costly apparatus and materials.
  • a further object of my invention is the provision of readily made apparatus of simple construction which is capable of efficient and simple use in the practice of the method and which avoids rapid destructive wear of such apparatus.
  • More specific objects of the invention are the provision of an electrolytic method of efliciently and relatively rapidly removing nib material progressively to form a drawing hole in a simple and inexpensive manner characterized by the use of the nib as an anode, a broach or needle as a cathode, and an inexpensive electrolyte of a type which will not unduly attack the hole-forming means and associated structure and which will permit efficient practice of the process.
  • a further object is the provision of a combined electrolytic and mechanical method of removing nib material to permit efllcacious forming of drawing holes, the electrolytic procedure being such as to avoid interference with the mechanical procedure featured by abrasive action of particles of abrasive material, and to permit their simultaneous practice in an efllcient manner.
  • FIG. 1 is a view partly in section and partly in elevation with parts broken away of one embodiment of the apparatus of the present invention showing the relationship between an encased blank nib, a broach or needle, and an electrolyte after the apparatus has been set up for electrolytically making a drawing hole
  • Fig. 2 is a mirror view of the set-up shown in Fig. 1 with a part in section and broken away
  • Fig. 3 is a vertical sectional view of the encased nib shown in Figs. 1 and 2 showing a portion of the needle and indicating the approximate shape of the hole formed by electrolytic action
  • Fig. 1 is a view partly in section and partly in elevation with parts broken away of one embodiment of the apparatus of the present invention showing the relationship between an encased blank nib, a broach or needle, and an electrolyte after the apparatus has been set up for electrolytically making a drawing hole
  • Fig. 2 is a mirror view of the set-up shown in Fig. 1 with a part in section and broken away
  • FIG. 4 is a vertical sectional view with parts broken away of a modified form of apparatus suitable for use in carrying out the combined electrolytic and mechanical procedures of the present invention showing an encased nib after the formation of the entrance of a drawing hole;
  • Fig. 5 is an enlarged vertical sectional view of a molded nib showin a portion of a needle in position and particles of abrasive suspended in an electrolyte for the purpose of electrolytically and mechanically forming the entrance of a drawing hole;
  • Fig. 6 is a. vertical sectional view with parts broken away of another embodiment of the apparatus which may be used for performing the combined electrolytic and mechanical operations, showing the formation of the bell of the drawing hole in an encased nib with the use thereof
  • Fig. 7 is a view with parts in section and broken away taken on line1i of Fi 6;
  • Fig. 8 is an enlarged vertical sectional View of a nib having a finished drawing hole in solution removed nib material.
  • the term hard metal carbide means any of the well known carbides or combinations thereof commonly employed as metal cutting tool bits or wire drawing dies.
  • the removal of nib material by electrolytic action is accomplished by supplying a suitable electrolyte to the broach or needle and adjacent portions of the nib and passing electrical current between the nib and the needle.
  • a supply circuit is connectedv to the nib and needle with the nib serving'as an anode and the needle as a cathode so that the oxidizing ions or anions pass to the nib and the reducing ions or cations pass to the needle.
  • the needle may be of any suitable type and/or shape to meet the requirements of the particular forming operation being practiced. It may be made of any readily electrically conducting material which is not attacked by the electrolytic action, for example various nickel alloys and ferrous alloys such as steel and the like. The action on the needle is cathodic and therefore not generally corrosive to metal.
  • any suitable electrolyte may be employed I prefer an alkaline solution which will not unduly attack the parts of the apparatus and which is capable of dissolving and holding
  • the electrolyte should further be of a type that will not unduly affect the mechanical abrasive means and when mechanical abrasive action is not used it should be capable of dissolving oxide compounds of the nib material that form on the nib surfaces being processed.
  • the portions of the nib from which nib material is being removed are kept inundated by the electrolyte during the practice of the electrolytic procedure, i. e., kept submerged or flooded thereby, or the latter is kept flowing over those portions.
  • a suitable electrolyte may be a solution of sodium cyanide preferably of a concentration of-about 9 to 14 ounces of sodium cyanide per gallon of water.
  • Such an electrolyte does not unduly attack ferrous metal and effectively dissolves and holds in solution cemented hard metal carbide material and oxides thereof which may be developed. It is particularly effective in. dissolving cobalt oxide that is produced on the surface of the drawing hol'e formed in a tungsten carbidecobalt nib. Satisfactory results may be obtained by the substitution of one or more of the .compounds, sodium carbonate, sodium hydroxide. $0-
  • the broach or needle is of such form and type as to serve as a cathode and additionally as mechanical means to aid in or perform mechanical removal of nib material.
  • the broach may be a suitable tool or a lap, it preferably is an elongated member of suitable material which may have its working surfaces cylindrical in shape, or if desired shaped in complement to the shape or surfaces of a finished portion of a drawing hole.
  • a plain-surfaced broach such as a steel needle, particles of a suitable abrasive such as silicon carbide or the like are employed.
  • the abrasive particles are supplied between surfaces of the working portion of the needle and adjacent surfaces of the nib and these surfaces are moved relative to each other, such as by rotary and/or reciprocating motion of the needle, to induce abrasion of surfaces of the drawing hole of the nib.
  • the abrasive particles are carried by a flowof electrolyte continuously supplied to the needle and nib.
  • the electrolyte need not be of a type which will dissolve oxide compounde of nib material, such as cobalt oxide, developed on the surfaces of the drawing hole being formed since the abrasive action will keep the latter effectively free therefrom.
  • the electrolyte should,
  • the nib may be supported in any desirable manner in a tank or container of suitable construction and material.
  • the tank or container may be made from any natural or artificial stoneware or porcelain material resistant to the electrolyte, such as Alberene stone, or iron or steel or alloys thereof.
  • Direct current of relatively low voltage is employed, e. g. about 4 volts of less.
  • the amperage may be varied with the type of forming operation.
  • a current of about 40 amperes will give satisfactory results.
  • the current may vary from a few milliamperes to a few tenths of an ampere which, with other conditions properly adjusted. will form a passage at the rate of about an inch in ten hours.
  • the amount of electrolyte to be provided is also largely dependent upon the size of nib being processed, the forming operation being practiced, the amperage of the current and permissible opcrating temperature. To avoid rapid evaporation of the electrolyte the temperature should not exceed about 1'10 F., about 150 F. being preferred. For the 40 amperes procedure set forth above about five gallons of electrolyte are sufficient. In'opening up a very small nib with a current of a fraction of an ampere an electrolyte container of one pint or less capacity has been found to hold suflicient electrolyte.
  • a tank I preferably of cast iron having therein a body ll of suitable electrolyte, such as sodium cyanide solution.
  • a terminal l2 of a suitable extemal electrical supply circuit is shown connected to the tank I.
  • a nib support It preferably of iron or steel is positioned in the bottom of tank ll.
  • a blank nib l4 encased in a steel casing I5 is located upon the support IS.
  • the blank nib I4 is provided with a flared conical recess It.
  • the portion ll of the upper end of the nib which is normally exposed adjacent the entrance of the recess I6 is protected from electrolytic action by a. ring l8 of suitable material such as steel.
  • the depth of the body ll of electrolyte in tank I0 is suflicient to submerge the encased nib as shown.
  • An upright I! has a bracket arm (Fig. 2) mounted thereon provided with a suitable bearing 2
  • the vertical shaft 22 which may be moved vertically by means of the arm 20 is provided with an adjustable collar 23 for regulating the distance between the needle andnib.
  • the lower end of shaft 22 terminates in a chuck 24 adapted to receive the end of a broach or needle 25 suitably insulated therefrom, such as by a layer of insulation 26.
  • a second terminal 21 of the external electrical supply circuit is connected by a suitable contacting means 28 to the shank of the needle 25, supporting means for terminal 21 and contacting means 28 being suitably insulated from its support, such as by insulation 29.
  • the working portion of the needle 25 consists of a tapered point 30 which is positioned closely adjacent to the surfaces of the recess 16 in the nib l4 when the apparatus is set up for operation as shown.
  • the shank of the needle 25 is preferably provldedwith a protective or insulating coating 3
  • the electrolyte may build up an insulating oxide coating on ferrous material, it may be desirable to apply pressure to the encased nib to insure good conductivity between the tank In and the nib l4 and to av id the formation of insulating oxides between the contacting surfaces of the tank l0, support I: and the nib casing l5.
  • Passage 32 so formed will be tapered somewhat as shown in Fig. 3 with the major portion of the walls thereof disposed at an angle of about 15 to the axis of the nib.
  • a molded nib has a similarly shaped passage provided therein during the construction thereof.
  • the passage designatedas a whole by numeral 32 must be provided with a bell 33, a back relief 34, a bearing 35 and have the surface of the approach portion :1: smoothly ground or finished as indicated in
  • Fig. 4 is shown an apparatus in operation for forming or finishing the approach 38 (Fig. 8) of the drawing hole.
  • the tank H which may be of iron, or some non-conducting material such as natural or artificial stoneware or porcelain if electrical current is to be conducted to the nib H by means other than the tank as hereinafter described, is suitably supported on a platform 31 provided with suitable means, if desired, for raising and lowering the tank Ill and for imparting lateral motion thereto. It may be desirable to provide manual means such as a hand-wheel 38 for raising the tank It) to bring the surfaces of the passage 32 (Fig. 8) in the nib 14 adjacent to the working portion III of the breach 25.
  • the encased nib i4 is mounted on a support 13 which may be a cupshaped steel member. Provision may be made for conducting current to the nib I4 by means other than the tank it.
  • the support l3 may be positioned upon suitably spaced apart insulating blocks 39 in the bottom of the tank, the blocks being spaced apart to permit free circulation of the electrolyte ⁇
  • a threaded nut 38 provides a fine adjustment between the nib l4 and the working portion 30 of the needle25.
  • the tank and supporting means are mountedupon a suitable frame 40 provided with uprights 4
  • a pulley 44 driving a belt 45 for operating a pump 46 having an intake pipe 41 xtending to within a short distance of the bottom of the tank It and a dischar e pipe 48 terminating in a nozzle 49 adapted to direct a flow of electrolyte to the working portion 30 of the needle 25 and the passage through the nib l4.
  • particleS of a suitable abrasive preferably silicon carbide, are distributed in the electrolyte and circulated therewith. The circulation of the electrolyte prevents the particles of abrasive from entirely settling out and insures a constant supply thereof between the working surfaces of the needle 25 and the adjacent surfaces of the passage in the nib I4.
  • the encased nib is clamped upon its support l3 in a suitable position such as by clamps 50, 50 which may be anchored to a suitable portion of the frame or the tank.
  • Each of the clamps 50, 50 is provided with a set screw 5
  • Another layer of insulating material 54 is also preferably interposed between the bottom of the casing l5 and each clamp for completely insulating the encased nib from the apparatus.
  • nib l4 preferably through the casing l5 and the body ll of electrolyte from a contact element 55 connected to the conductor I2 and supported on tank ID by a suitable insulating member 56.
  • the contact member 55 preferably is pointed and may be a triangularly-shaped steel sheet mounted for vertical adjustment on the support 56 so that the contact area between member 55 and the electrolyte may be varied at will to act as a liquid rheostat for controlling the amount of current.
  • the shank of theneedle 25 is mounted by means of the chuck 24 on the end of the shaft 22 su tably supported in journal boxes 51 and 58 mounted onthe frame 40.
  • between a collar 59 and pulley 60.
  • a pulley 62 driven by a belt 63 from the shaft 42 rotates a lifting arm or cam 84 periodically to lift the needle 25.
  • a compression spring 65 may be used to cooperate with the force of gravity in lowering the needle 25 after it has been lifted by lift arm 6
  • the pulley 60, pinned or keyed to shaft 22, is driven by a belt 66 on shaft 42 for rotating the needle 25.
  • the shaft 22 may be provided with a rack 61 in mesh with a pinion 68 rotatable by a hand lever 69 and supported by a bracket arm 10 suitably insulated by means 1
  • the electrolyte carrying particles 11 of abrasive material such as silicon carbide, is continuously circulated by the pump to the nib, the working portion 30 of the needle 25, through the nib passage 32 and the support l3, and between the spaced apart blocks. 39. to insure continuously at proper supply of abrasive particles between the working portion 30 of the needle 25 and the surfaces of the nib passage 32.
  • Figs. 6 and 7 show an apparatus equipped with a needle adapted for the formation of the bell of a drawing hole, and the relative positions of the broach and nib during the formation thereof.
  • the tank [0 of this apparatus is not of a depth sufficient to permit submersion of the encased nib l4 when supported by the support I3.
  • the supply of electrolyte carrying abrasive particles maintained at the working portion 30 of the needle 25 by the pump 46 is adequate to keep the surfaces of the passage in the nib inundated.
  • the spaced apart blocks 39-39 are made of suitable conducting material such as iron or steel and good contact between tank I0, blocks 39-39, support l3 and casing I5 is maintained by a clamp I9 comprising an arm I9 having spaced apart members 80, adapted to engage the top of the easing IS on opposite sides of the broach 25 as shown.
  • the arm 19 is mounted on the frame or tank by a bolt 8
  • the shaft 22 is not insulated from the frame.
  • the chuck 24, however, is suitably insulated from the shaft 22 by insulating means 26 and brush 28 connected to the terminal 21 rides upon the circumferential surface of the chuck.
  • Suitable mechanism similar to that described in connection with Fig. 4 is provided for reciprocating and/or rotating the broach 25.
  • the drawing hole 83 shown in Fig. 8 may be finished by forming the back relief 34 by a similar procedure with the use of suitable apparatus such as that shown in Fig. 4 or 6.
  • needle may be employed, for example, those having a cylindrical, hexagonal or other cross-sectional area. If a cylindrical needle is employed it will tend to form a tapered hole due to the fact that the electrolytic action takes place for a longer period of time at the upper portion than at the lower portion of the surface of the hole through the die. If a needle having a uniform cross-sectional area of a shape other than cylindrical, for example hexagonal, is employed it also will tend to form a tapered hole through the die but the hole will conform to the crosssectional shape of the needle.
  • the method of forming a hole in a refractory metal body which comprises applying force to an electrically conductive needle to press it against abrasive particles between the surface of said refractory metal body and said needle, causing relative movement between a working portion of the needle and adjacent surfaces of the refractory metal body to induce abrasion of the latter and supplying an alkaline electrolyte to tl-e needle and adjacent portions of the refractory' metal body while anodically treating said body in said electrolyte.
  • the method of forming a drawing hole in a die nib which comprises electrolytically and mechanically removing material from a sintered carbide nib by simultaneously forcing an electrically conductive needle against abrasive particles between the needle and nib, moving the surfaces of a working portion of the needle relative to adjacent surfaces of the nib to induce abrasion of the latter, and maintaining a supply of an alkaline electrolyte at the adjacent portions of the needle and nib while anodically treating said nib in said electrolyte.
  • the method of forming a drawing hole in a die nib which comprises electrolytically and mechanically removing material from a cemented hard metal carbide nib by simultaneously forcing an electrically conductive'needle against abrasive particles between the needle and nib, imparting motion to the needle to induce abrasion of surfaces of the nib adjacent thereto, and maintaining a supply 01 an alkaline electrolyte at the adjacent portions of the needle and nib while anodically treating said nib in said electrolyte.
  • the method of forming a drawing hole in a refractory metal die nib having a passage therethrough comprising positioning an electrically conductive needle in the nib passage, circulating an alkaline electrolyte carrying abrasive particles between the needle and nib and through the nib passage and causing relative movement between surfaces of a working portion of the needle and adjacent-surfaces of the nib passage to induce abrasion of the latter while anodically treating said nib in said electrolyte.
  • the method of forming a drawing hole in a cemented hard metal carbide nib having a passage therethrough which comprises positioning an electrically conductive needle in the nib passage, circulating between the needle and nib and through the nib passage a substantiall saturated solution of sodium carbonate carrying abrasive particles and causing relative movement between surfaces of a working portion of the needle and adjacent surfaces of the passage to induce abrasion of the latter while anodically treating said nib in said solution.

Description

Sept. 18, 1945.
E. W. ENGLE METHOD FOR FORMING DRAWING HOLES IN CARBIDE. DIE NIBS 3 Sheets-Sheet 1 Filed Feb. 6 1942 INVENTOR Edgar W. Eng\e, BY a mw HIS ATTORNEY E. W. ENGLE Sept. 18, 1945.
METHOD FOR FORMING DRAWING HOLES IN CARBIDE DIE NIBS Filed Feb. 6, 1942 3 sheets sheet 2 INVENTOR Edgar w. Engle,
BY HIS ATTORNEY E. W. ENGLE Sept 18, 1945.
METHOD FOR FORMING DRAWING HOLES IN CARBIDE DIE NIBS Filed Feb. 6, 1942 3 Sheets-Sheet 3 E Elgar \Al. fingle HIS ATTORNEY Patented Sept. 18, 1945 METHOD FOR FORMING DRAWING HOLES IN CARBIDE DIE NIBS Edgar W. Engle, Pleasant Ridge, Mich, asslgnor to Carboloy Company, Inc., Detroit, Micln, a corporation of New York Application February 6, 1942, Serial No. 429,796
9 Claims.
The present invention relates to a method of and apparatus for forming drawing holes in reiractory material such as die nibs. More particularly the invention relates to the making of such holes by removal of material from nibs of hard, metallic, electrically conducting materials, for example, the sintered material known as cemented carbide and described and claimed in Schroter Reissue Patent No. 17,624, March 18, 1930, which by way of example consists of tungsten carbide cemented with cobalt.
In accordance with common practices of the trade die nibs may be made in "blank" or molded form. A so-called blank" nib may be a substantially solid, preferably cylindrical, block of nib material having in one end thereof either a small shallow depression or a flared conical recess extending from about two-thirds to threequarters through the nib substantially axially thereof. A so-called "molded nib has a'fiared passage extending completely through the nib substantially axially thereof. Such nibs are usually encased in materials of high tensile strength such as steel to reinforce them so that they will withstand the forces set up in metal drawing operations. The drawing holes prior to the present invention were usually formed in nibs by abrasive action, preferably either with the use of laps having particles of abrasive material distributed in or held on the surface of a suitable binding material, or by other breaching means with the use of free particles of abrasive. When referring to the drawing hole of a nib the word form is used herein in the sense of making an initial hole or passage in a blank nib, or shaping or changing the shape of a hole or passage in a molded or a previously finished nib.
' Cemented hard metal carbides are characterized by very great hardness and resistance to abrasion. Consequently, the mechanical abrasive methods heretofore employed for forming the passage in die nibs of that character have been somewhat slow and expensive.
A general object of the present invention is the provision of an effective and efiicient method of forming drawing holes in hard metal, electrically conductingdie nibs which method may be readily carried out in a relatively short time and without the use of excessively costly apparatus and materials. A further object of my invention is the provision of readily made apparatus of simple construction which is capable of efficient and simple use in the practice of the method and which avoids rapid destructive wear of such apparatus.
More specific objects of the invention are the provision of an electrolytic method of efliciently and relatively rapidly removing nib material progressively to form a drawing hole in a simple and inexpensive manner characterized by the use of the nib as an anode, a broach or needle as a cathode, and an inexpensive electrolyte of a type which will not unduly attack the hole-forming means and associated structure and which will permit efficient practice of the process.
A further object is the provision of a combined electrolytic and mechanical method of removing nib material to permit efllcacious forming of drawing holes, the electrolytic procedure being such as to avoid interference with the mechanical procedure featured by abrasive action of particles of abrasive material, and to permit their simultaneous practice in an efllcient manner.
Other objects of the invention will in part be obvious and will in part appear hereinafter.
For a fuller understanding of my invention reference should be had to the following description taken in connection with the accompanying drawings, in which Fig. 1 is a view partly in section and partly in elevation with parts broken away of one embodiment of the apparatus of the present invention showing the relationship between an encased blank nib, a broach or needle, and an electrolyte after the apparatus has been set up for electrolytically making a drawing hole; Fig. 2 is a mirror view of the set-up shown in Fig. 1 with a part in section and broken away; Fig. 3 is a vertical sectional view of the encased nib shown in Figs. 1 and 2 showing a portion of the needle and indicating the approximate shape of the hole formed by electrolytic action; Fig. 4 is a vertical sectional view with parts broken away of a modified form of apparatus suitable for use in carrying out the combined electrolytic and mechanical procedures of the present invention showing an encased nib after the formation of the entrance of a drawing hole; Fig. 5 is an enlarged vertical sectional view of a molded nib showin a portion of a needle in position and particles of abrasive suspended in an electrolyte for the purpose of electrolytically and mechanically forming the entrance of a drawing hole; Fig. 6 is a. vertical sectional view with parts broken away of another embodiment of the apparatus which may be used for performing the combined electrolytic and mechanical operations, showing the formation of the bell of the drawing hole in an encased nib with the use thereof Fig. 7 is a view with parts in section and broken away taken on line1i of Fi 6; Fig. 8 is an enlarged vertical sectional View of a nib having a finished drawing hole in solution removed nib material.
by a lower melting point metal which will give to the composition certain desired characteristics such as toughness, etc., for example metal of the iron group such as cobalt. As used herein the term hard metal carbide means any of the well known carbides or combinations thereof commonly employed as metal cutting tool bits or wire drawing dies. The removal of nib material by electrolytic action is accomplished by supplying a suitable electrolyte to the broach or needle and adjacent portions of the nib and passing electrical current between the nib and the needle. A supply circuit is connectedv to the nib and needle with the nib serving'as an anode and the needle as a cathode so that the oxidizing ions or anions pass to the nib and the reducing ions or cations pass to the needle. These two electrodes may be connected in the supply circuit in a variety of ways as will appear hereinafter. The needle may be of any suitable type and/or shape to meet the requirements of the particular forming operation being practiced. It may be made of any readily electrically conducting material which is not attacked by the electrolytic action, for example various nickel alloys and ferrous alloys such as steel and the like. The action on the needle is cathodic and therefore not generally corrosive to metal.
Although any suitable electrolyte may be employed I prefer an alkaline solution which will not unduly attack the parts of the apparatus and which is capable of dissolving and holding When mechanical removal of nib material is performed in conjunction with the electrolytic procedure the electrolyte should further be of a type that will not unduly affect the mechanical abrasive means and when mechanical abrasive action is not used it should be capable of dissolving oxide compounds of the nib material that form on the nib surfaces being processed. The portions of the nib from which nib material is being removed are kept inundated by the electrolyte during the practice of the electrolytic procedure, i. e., kept submerged or flooded thereby, or the latter is kept flowing over those portions.
When electrolytic action is used alone for removal of cemented hard metal carbide material such as tungsten carbide cemented with cobalt a suitable electrolyte may be a solution of sodium cyanide preferably of a concentration of-about 9 to 14 ounces of sodium cyanide per gallon of water. Such an electrolyte does not unduly attack ferrous metal and effectively dissolves and holds in solution cemented hard metal carbide material and oxides thereof which may be developed. It is particularly effective in. dissolving cobalt oxide that is produced on the surface of the drawing hol'e formed in a tungsten carbidecobalt nib. Satisfactory results may be obtained by the substitution of one or more of the .compounds, sodium carbonate, sodium hydroxide. $0-
dium chloride and the like for a portion of the sodium cyanide.
The invention also contemplates within its scope combined electrolytic and mechanical procedures for removal of nib material. In such a case the broach or needle is of such form and type as to serve as a cathode and additionally as mechanical means to aid in or perform mechanical removal of nib material. Although the broach may be a suitable tool or a lap, it preferably is an elongated member of suitable material which may have its working surfaces cylindrical in shape, or if desired shaped in complement to the shape or surfaces of a finished portion of a drawing hole. With a plain-surfaced broach, such as a steel needle, particles of a suitable abrasive such as silicon carbide or the like are employed. The abrasive particles are supplied between surfaces of the working portion of the needle and adjacent surfaces of the nib and these surfaces are moved relative to each other, such as by rotary and/or reciprocating motion of the needle, to induce abrasion of surfaces of the drawing hole of the nib. In the preferred procedure the abrasive particles are carried by a flowof electrolyte continuously supplied to the needle and nib. The electrolyte need not be of a type which will dissolve oxide compounde of nib material, such as cobalt oxide, developed on the surfaces of the drawing hole being formed since the abrasive action will keep the latter effectively free therefrom. The electrolyte should,
. however, be of a type which will not destructively affect the abrasive materiay. A solution of sodium carbonate or other similar alkali, as distinguished from sodium cyanide, has been found to be suitable, and a highly concentrated solution is preferred.
The nib may be supported in any desirable manner in a tank or container of suitable construction and material. For example, the tank or container may be made from any natural or artificial stoneware or porcelain material resistant to the electrolyte, such as Alberene stone, or iron or steel or alloys thereof.
Direct current of relatively low voltage is employed, e. g. about 4 volts of less. The amperage may be varied with the type of forming operation. By way of example to increase the size of the hole in a tungsten carbide-cobalt nib having a drawing hole of about iive-eighths of an inch in diameter at the bearing by combined electrolytic and mechanical removal of nib material a current of about 40 amperes will give satisfactory results. In opening up a very small blank nib with a small needle the current may vary from a few milliamperes to a few tenths of an ampere which, with other conditions properly adjusted. will form a passage at the rate of about an inch in ten hours. The maximum amperage for a given set-up is dictated by the rate of gas evolution, too rapid gas evolution causing arcing. A relatively high rate of gas evolution, however, is of material advantage since the gas evolved at the needle. tends to carry away products of electrolysis. The removal of such nib material by the method of the present invention has been found to be of the order of about one gram per ampere hour, a rate of removal much more rapid than is possible by procedures usually practiced prior to the present invention.
The amount of electrolyte to be provided is also largely dependent upon the size of nib being processed, the forming operation being practiced, the amperage of the current and permissible opcrating temperature. To avoid rapid evaporation of the electrolyte the temperature should not exceed about 1'10 F., about 150 F. being preferred. For the 40 amperes procedure set forth above about five gallons of electrolyte are sufficient. In'opening up a very small nib with a current of a fraction of an ampere an electrolyte container of one pint or less capacity has been found to hold suflicient electrolyte.
Referring to the drawings, like numerals refer to like parts throughout. In Fig. 1 is shown a tank I preferably of cast iron having therein a body ll of suitable electrolyte, such as sodium cyanide solution. A terminal l2 of a suitable extemal electrical supply circuit is shown connected to the tank I. A nib support It, preferably of iron or steel is positioned in the bottom of tank ll. A blank nib l4 encased in a steel casing I5 is located upon the support IS. The blank nib I4 is provided with a flared conical recess It. The portion ll of the upper end of the nib which is normally exposed adjacent the entrance of the recess I6 is protected from electrolytic action by a. ring l8 of suitable material such as steel. The depth of the body ll of electrolyte in tank I0 is suflicient to submerge the encased nib as shown. An upright I! has a bracket arm (Fig. 2) mounted thereon provided with a suitable bearing 2| rigidly secured to shaft 22. The vertical shaft 22 which may be moved vertically by means of the arm 20 is provided with an adjustable collar 23 for regulating the distance between the needle andnib. The lower end of shaft 22 terminates in a chuck 24 adapted to receive the end of a broach or needle 25 suitably insulated therefrom, such as by a layer of insulation 26. A second terminal 21 of the external electrical supply circuit is connected by a suitable contacting means 28 to the shank of the needle 25, supporting means for terminal 21 and contacting means 28 being suitably insulated from its support, such as by insulation 29.
The working portion of the needle 25 consists of a tapered point 30 which is positioned closely adjacent to the surfaces of the recess 16 in the nib l4 when the apparatus is set up for operation as shown. The shank of the needle 25 is preferably provldedwith a protective or insulating coating 3|, such as a section of rubber tubing, an electrolytically deposited layer of rubber, a heat vulcanized coating of rubber, or a coating of sulphur applied in a molten state for the purpose of limiting contact between the electrolyte and the needle to the portion at the tip which will be opposedto the surfaces of the drawing hole being formed in the nib. When the external supply circuit is closed current will fiow from the terminal 12 through the iron tank Hi, the steel support l3, the steel casing I5 to the nib l4, from the nib l4 through the electrolyte to the working portion 3|! of the needle 25, and from the needle to the terminal 21. As a result, nib material is progressively removed by electrolytic action forming a passage 32 in the nib l4 as shown in Fig. 3. The casing l5 and the ring ll protect .the outer surfaces of the nib from electrolytic action. Ferrous material such as iron or steel are not deleteriously affected by the electrolyte or electrolytic action. Since the electrolyte, however, may build up an insulating oxide coating on ferrous material, it may be desirable to apply pressure to the encased nib to insure good conductivity between the tank In and the nib l4 and to av id the formation of insulating oxides between the contacting surfaces of the tank l0, support I: and the nib casing l5.
Passage 32 so formed will be tapered somewhat as shown in Fig. 3 with the major portion of the walls thereof disposed at an angle of about 15 to the axis of the nib. As previously pointed out a molded nib has a similarly shaped passage provided therein during the construction thereof. To finish a molded nib or a blank nib provided with a passage in the above manner, the passage designatedas a whole by numeral 32 must be provided with a bell 33, a back relief 34, a bearing 35 and have the surface of the approach portion :1: smoothly ground or finished as indicated in In Fig. 4 is shown an apparatus in operation for forming or finishing the approach 38 (Fig. 8) of the drawing hole. The tank H), which may be of iron, or some non-conducting material such as natural or artificial stoneware or porcelain if electrical current is to be conducted to the nib H by means other than the tank as hereinafter described, is suitably supported on a platform 31 provided with suitable means, if desired, for raising and lowering the tank Ill and for imparting lateral motion thereto. It may be desirable to provide manual means such as a hand-wheel 38 for raising the tank It) to bring the surfaces of the passage 32 (Fig. 8) in the nib 14 adjacent to the working portion III of the breach 25. If relative reciprocatory movement between the nib and needle is desired it may be obtained by raising or lowering tank 50 either by such manual means or automatic mechanical means such as a driven sprocket or gear and suitable associated structure, although movement of the needle for this purpose is preferred. The encased nib i4 is mounted on a support 13 which may be a cupshaped steel member. Provision may be made for conducting current to the nib I4 by means other than the tank it. For example the support l3 may be positioned upon suitably spaced apart insulating blocks 39 in the bottom of the tank, the blocks being spaced apart to permit free circulation of the electrolyte} A threaded nut 38 provides a fine adjustment between the nib l4 and the working portion 30 of the needle25.
The tank and supporting means are mountedupon a suitable frame 40 provided with uprights 4| in which are journaled a rotatable shaft 42 driven by suitable means such as a belt 43 and an electric motor (not shown). Upon the shaft 42 is keyed a pulley 44 driving a belt 45 for operating a pump 46 having an intake pipe 41 xtending to within a short distance of the bottom of the tank It and a dischar e pipe 48 terminating in a nozzle 49 adapted to direct a flow of electrolyte to the working portion 30 of the needle 25 and the passage through the nib l4. As is indicated, particleS of a suitable abrasive, preferably silicon carbide, are distributed in the electrolyte and circulated therewith. The circulation of the electrolyte prevents the particles of abrasive from entirely settling out and insures a constant supply thereof between the working surfaces of the needle 25 and the adjacent surfaces of the passage in the nib I4.
Preferably the encased nib is clamped upon its support l3 in a suitable position such as by clamps 50, 50 which may be anchored to a suitable portion of the frame or the tank. Each of the clamps 50, 50 is provided with a set screw 5| for the purpose of clamping a top plate 52 of suitable material, such as iron or steel, against the top of the casing l5 and a nib-protecting ring l8 for maintaining the latter in position, with, if desired, a layer 53 of insulating material interposed therebetween. Another layer of insulating material 54 is also preferably interposed between the bottom of the casing l5 and each clamp for completely insulating the encased nib from the apparatus. However, if it is desired to conduct electricity to the nib through the casing I5 and the clamps 50, 50 either one or both of the layers of insulating material 53 and 54 may be omitted. Electricity is conducted to nib l4 preferably through the casing l5 and the body ll of electrolyte from a contact element 55 connected to the conductor I2 and supported on tank ID by a suitable insulating member 56. The contact member 55 preferably is pointed and may be a triangularly-shaped steel sheet mounted for vertical adjustment on the support 56 so that the contact area between member 55 and the electrolyte may be varied at will to act as a liquid rheostat for controlling the amount of current.
The shank of theneedle 25 is mounted by means of the chuck 24 on the end of the shaft 22 su tably supported in journal boxes 51 and 58 mounted onthe frame 40. Upon shaft 22 is mounted a lift arm or cam follower 6| between a collar 59 and pulley 60. A pulley 62 driven by a belt 63 from the shaft 42 rotates a lifting arm or cam 84 periodically to lift the needle 25. A compression spring 65 may be used to cooperate with the force of gravity in lowering the needle 25 after it has been lifted by lift arm 6| for reciprocating the working portion 30 of the needle relative to the surfaces of the passage in the nib l4. The pulley 60, pinned or keyed to shaft 22, is driven by a belt 66 on shaft 42 for rotating the needle 25.
The shaft 22 may be provided with a rack 61 in mesh with a pinion 68 rotatable by a hand lever 69 and supported by a bracket arm 10 suitably insulated by means 1| from a support 12 mounted on the frame 40, so that the needle may be lifted and lowered manually if desired. The
. other terminal 21 of the external electrical supply circuit is connected to the brush 28 adapted to ride on the surface of a ring 13 mounted on the shaft 22. Brush 28 is supported by means of a bracket 14 suitably mounted on the frame is such as by the journal box 58 in an insulated manner such as by means 29. Shaft 22 is insulated from the journal boxes 51 and 58, collar 59, pulley and the lift arm Bl by suitable means such as a sleeve of insulation 15.
In removing nib material from a passage 32 in a nib to form the passage I6 indicated by dotdash lines in Fig. 5, the electrolyte carrying particles 11 of abrasive material, such as silicon carbide, is continuously circulated by the pump to the nib, the working portion 30 of the needle 25, through the nib passage 32 and the support l3, and between the spaced apart blocks. 39. to insure continuously at proper supply of abrasive particles between the working portion 30 of the needle 25 and the surfaces of the nib passage 32. Current regulated by the adjustment of the l uid rhe stat including member 55 is passed through t e body ll of electrolyte and the nib casing i5 to n b H, from the nib l4 through the electrolyte to the needle 25, and through the shaft 22, ring I3 and brush 28 to the terminal 21. As a consequence nib material will be removed by combined elect olytic and mechanical action. the abrasive particles 11 keeping the surfaces of the nib passage free from metal oxides and properly finishing the surfaces of the entrance.
Figs. 6 and 7 show an apparatus equipped with a needle adapted for the formation of the bell of a drawing hole, and the relative positions of the broach and nib during the formation thereof. The tank [0 of this apparatus is not of a depth sufficient to permit submersion of the encased nib l4 when supported by the support I3. However, the supply of electrolyte carrying abrasive particles maintained at the working portion 30 of the needle 25 by the pump 46 is adequate to keep the surfaces of the passage in the nib inundated. In this modified form of the apparatus the spaced apart blocks 39-39 are made of suitable conducting material such as iron or steel and good contact between tank I0, blocks 39-39, support l3 and casing I5 is maintained by a clamp I9 comprising an arm I9 having spaced apart members 80, adapted to engage the top of the easing IS on opposite sides of the broach 25 as shown. The arm 19 is mounted on the frame or tank by a bolt 8| and a set screw 82 cooperates therewith to apply desired pressure to the assembly. In this apparatus the shaft 22 is not insulated from the frame. The chuck 24, however, is suitably insulated from the shaft 22 by insulating means 26 and brush 28 connected to the terminal 21 rides upon the circumferential surface of the chuck. Suitable mechanism similar to that described in connection with Fig. 4 is provided for reciprocating and/or rotating the broach 25. The drawing hole 83 shown in Fig. 8, may be finished by forming the back relief 34 by a similar procedure with the use of suitable apparatus such as that shown in Fig. 4 or 6.
Although I have illustrated my invention in connection with a pointed needle other forms of needle may be employed, for example, those having a cylindrical, hexagonal or other cross-sectional area. If a cylindrical needle is employed it will tend to form a tapered hole due to the fact that the electrolytic action takes place for a longer period of time at the upper portion than at the lower portion of the surface of the hole through the die. If a needle having a uniform cross-sectional area of a shape other than cylindrical, for example hexagonal, is employed it also will tend to form a tapered hole through the die but the hole will conform to the crosssectional shape of the needle.
What I claim as new and desire to secure by Letters Patent of the United States, is:
1. The method of forming a hole in a refractory metal body which comprises applying force to an electrically conductive needle to press it against abrasive particles between the surface of said refractory metal body and said needle, causing relative movement between a working portion of the needle and adjacent surfaces of the refractory metal body to induce abrasion of the latter and supplying an alkaline electrolyte to tl-e needle and adjacent portions of the refractory' metal body while anodically treating said body in said electrolyte.
2. The method of forming a drawing hole in a die nib which comprises electrolytically and mechanically removing material from a sintered carbide nib by simultaneously forcing an electrically conductive needle against abrasive particles between the needle and nib, moving the surfaces of a working portion of the needle relative to adjacent surfaces of the nib to induce abrasion of the latter, and maintaining a supply of an alkaline electrolyte at the adjacent portions of the needle and nib while anodically treating said nib in said electrolyte.
3. The method of forming a drawing hole in a die nib which comprises electrolytically and mechanically removing material from a cemented hard metal carbide nib by simultaneously forcing an electrically conductive'needle against abrasive particles between the needle and nib, imparting motion to the needle to induce abrasion of surfaces of the nib adjacent thereto, and maintaining a supply 01 an alkaline electrolyte at the adjacent portions of the needle and nib while anodically treating said nib in said electrolyte.
4. The method of forming a drawing hole in a die nib which comprises electrolytically and mechanically removing material from a cemented hard metal carbide mm by simultaneously forcing an electrically conductive needle against abrasive particles in an alkaline electrolyte between the needle and nib, and imparting motion tothe needle to induce abrasion of surfaces of the nib adjacent portions of the needle and nib and maintaining a supply of an alkaline electrolyte at the adjacent portions of the needle and nib'while anodically treating said nib in said electrolyte,
6. The method of forming a drawing hole in a die nib which comprises electrolytically and mechanically removing material from a cemented hard metal carbide nib by simultaneously forcing an electrically conductive needle against abrasive particles between the needle and nib,
imparting reciprocative and rotary motion to the needle to induce abrasion of surfaces of the nib adjacent thereto, and maintaining a supply of an alkaline electrolyte at the adjacent portions of the needle and nib while anodically treating said nib in said electrolyte.
7. The method of forming a drawing hole in a refractory metal die nib having a passage therethrough comprising positioning an electrically conductive needle in the nib passage, circulating an alkaline electrolyte carrying abrasive particles between the needle and nib and through the nib passage and causing relative movement between surfaces of a working portion of the needle and adjacent-surfaces of the nib passage to induce abrasion of the latter while anodically treating said nib in said electrolyte.
8. The method of forming a drawing hole in a cemented hard metal carbide nib having a passage therethrough comprising positioning an electrically conductive needle in the nib passage, circulating between the needle and nib and through the passage an alkaline electrolyte carrying particles of silicon carbide and causing relative movement between surfaces of a working portion of the needle and adjacent surfaces of the passage to induce abrasion of the latter while anodically treating said nib in said electrolyte.
9. The method of forming a drawing hole in a cemented hard metal carbide nib having a passage therethrough which comprises positioning an electrically conductive needle in the nib passage, circulating between the needle and nib and through the nib passage a substantiall saturated solution of sodium carbonate carrying abrasive particles and causing relative movement between surfaces of a working portion of the needle and adjacent surfaces of the passage to induce abrasion of the latter while anodically treating said nib in said solution.
EDGAR W. ENGIE.
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* Cited by examiner, † Cited by third party
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US2492214A (en) * 1945-10-25 1949-12-27 Douglass C Fonda Method of marking tungsten carbide
US2630659A (en) * 1948-05-13 1953-03-10 Saint Gobain Method of surfacing solid bodies
US2741594A (en) * 1950-04-05 1956-04-10 Charles F Bowersett Apparatus for electrolytically penetrating shell casings
US2793992A (en) * 1953-04-06 1957-05-28 Gen Motors Corp Electrical cutting and grinding
US2798846A (en) * 1953-04-28 1957-07-09 Norton Co Method and apparatus for the electrolytic erosion of work pieces
US2826540A (en) * 1952-09-18 1958-03-11 George F Keeleric Method and apparatus for electrolytic cutting, shaping, and grinding
US2885329A (en) * 1951-05-10 1959-05-05 Harvey L Slatin Method for electro-nickel plating wolfram carbide
US2905605A (en) * 1953-05-19 1959-09-22 Keeleric Dressing of abrasive tools
US2919522A (en) * 1958-05-23 1960-01-05 Hammond Machinery Builders Inc Machine tool
US2920026A (en) * 1952-05-01 1960-01-05 Norton Co Grinding machine
US2967813A (en) * 1958-08-29 1961-01-10 Allen R Lindsay Automatic marking device
US3038852A (en) * 1958-09-29 1962-06-12 Meuter Ernst Device for the galvanization of the bearing surfaces of heavy and very heavy crank shafts
US3047987A (en) * 1961-01-23 1962-08-07 Thompson Grinder Co Apparatus for submerged grinding
US3058895A (en) * 1958-11-10 1962-10-16 Anocut Eng Co Electrolytic shaping
US3061529A (en) * 1959-04-06 1962-10-30 Norton Co Electrolytic grinder and method of grinding
US3103482A (en) * 1963-09-10 figure
US3156808A (en) * 1956-11-20 1964-11-10 Rolls Royce Manufacture of turbine and compressor blades
US3202595A (en) * 1960-08-23 1965-08-24 Inoue Kiyoshi Electro-chemical machining process
US3235475A (en) * 1960-06-15 1966-02-15 Anocut Eng Co Electrolytic shaping apparatus and method
US3267013A (en) * 1962-09-18 1966-08-16 Sperry Rand Corp Electrolytic deplating process
US3293163A (en) * 1964-04-10 1966-12-20 Easco Products Inc Method of maintaining spacing in electric-discharge and electro-chemical machining
US3314311A (en) * 1964-06-22 1967-04-18 Lloyd Bastian Carbide inserted button die
US3324021A (en) * 1962-10-23 1967-06-06 Cincinnati Milling Machine Co Electrochemical machining apparatus and tool therefor
US3332869A (en) * 1964-10-05 1967-07-25 Hamilton Co Needle tapering apparatus
US3357905A (en) * 1960-03-28 1967-12-12 Cleveland Twist Drill Co Electrolyte composition and method of electrolytically removing stock from workpiece
US3371022A (en) * 1963-03-19 1968-02-27 Inoue Kiyoshi Low-electrolyte-pressure electro-chemical machining
US3421997A (en) * 1958-11-10 1969-01-14 Anocut Eng Co Electrode for electrolytic shaping
US3523834A (en) * 1967-10-13 1970-08-11 Ibm Method of deburring
US3564190A (en) * 1963-06-19 1971-02-16 Exnii Metallorenzhushichikh St Method of machining complicated surfaces
US3828628A (en) * 1970-11-24 1974-08-13 Peugeot & Renault Methods of extruding helical gear blanks
US3852176A (en) * 1971-02-23 1974-12-03 Calspan Corp Embrittlement machining method
USRE29026E (en) * 1972-12-06 1976-11-02 Cornell Aeronautical Laboratory, Inc. Embrittlement machining method
US4387287A (en) * 1978-06-29 1983-06-07 Diamond S.A. Method for a shaping of polycrystalline synthetic diamond
US4609450A (en) * 1985-03-26 1986-09-02 Agency Of Industrial Science And Technology Combined electrolytic-abrasive polishing apparatus
US5736015A (en) * 1996-09-06 1998-04-07 Pilot Industries, Inc. Electrical discharge machining apparatus

Cited By (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3103482A (en) * 1963-09-10 figure
US2492214A (en) * 1945-10-25 1949-12-27 Douglass C Fonda Method of marking tungsten carbide
US2630659A (en) * 1948-05-13 1953-03-10 Saint Gobain Method of surfacing solid bodies
US2741594A (en) * 1950-04-05 1956-04-10 Charles F Bowersett Apparatus for electrolytically penetrating shell casings
US2885329A (en) * 1951-05-10 1959-05-05 Harvey L Slatin Method for electro-nickel plating wolfram carbide
US2920026A (en) * 1952-05-01 1960-01-05 Norton Co Grinding machine
US2826540A (en) * 1952-09-18 1958-03-11 George F Keeleric Method and apparatus for electrolytic cutting, shaping, and grinding
US2793992A (en) * 1953-04-06 1957-05-28 Gen Motors Corp Electrical cutting and grinding
US2798846A (en) * 1953-04-28 1957-07-09 Norton Co Method and apparatus for the electrolytic erosion of work pieces
US2905605A (en) * 1953-05-19 1959-09-22 Keeleric Dressing of abrasive tools
US3156808A (en) * 1956-11-20 1964-11-10 Rolls Royce Manufacture of turbine and compressor blades
US2919522A (en) * 1958-05-23 1960-01-05 Hammond Machinery Builders Inc Machine tool
US2967813A (en) * 1958-08-29 1961-01-10 Allen R Lindsay Automatic marking device
US3038852A (en) * 1958-09-29 1962-06-12 Meuter Ernst Device for the galvanization of the bearing surfaces of heavy and very heavy crank shafts
US3058895A (en) * 1958-11-10 1962-10-16 Anocut Eng Co Electrolytic shaping
US3421997A (en) * 1958-11-10 1969-01-14 Anocut Eng Co Electrode for electrolytic shaping
US3061529A (en) * 1959-04-06 1962-10-30 Norton Co Electrolytic grinder and method of grinding
US3357905A (en) * 1960-03-28 1967-12-12 Cleveland Twist Drill Co Electrolyte composition and method of electrolytically removing stock from workpiece
US3235475A (en) * 1960-06-15 1966-02-15 Anocut Eng Co Electrolytic shaping apparatus and method
US3202595A (en) * 1960-08-23 1965-08-24 Inoue Kiyoshi Electro-chemical machining process
US3047987A (en) * 1961-01-23 1962-08-07 Thompson Grinder Co Apparatus for submerged grinding
US3267013A (en) * 1962-09-18 1966-08-16 Sperry Rand Corp Electrolytic deplating process
US3324021A (en) * 1962-10-23 1967-06-06 Cincinnati Milling Machine Co Electrochemical machining apparatus and tool therefor
US3371022A (en) * 1963-03-19 1968-02-27 Inoue Kiyoshi Low-electrolyte-pressure electro-chemical machining
US3564190A (en) * 1963-06-19 1971-02-16 Exnii Metallorenzhushichikh St Method of machining complicated surfaces
US3293163A (en) * 1964-04-10 1966-12-20 Easco Products Inc Method of maintaining spacing in electric-discharge and electro-chemical machining
US3314311A (en) * 1964-06-22 1967-04-18 Lloyd Bastian Carbide inserted button die
US3332869A (en) * 1964-10-05 1967-07-25 Hamilton Co Needle tapering apparatus
US3523834A (en) * 1967-10-13 1970-08-11 Ibm Method of deburring
US3828628A (en) * 1970-11-24 1974-08-13 Peugeot & Renault Methods of extruding helical gear blanks
US3852176A (en) * 1971-02-23 1974-12-03 Calspan Corp Embrittlement machining method
USRE29026E (en) * 1972-12-06 1976-11-02 Cornell Aeronautical Laboratory, Inc. Embrittlement machining method
US4387287A (en) * 1978-06-29 1983-06-07 Diamond S.A. Method for a shaping of polycrystalline synthetic diamond
US4609450A (en) * 1985-03-26 1986-09-02 Agency Of Industrial Science And Technology Combined electrolytic-abrasive polishing apparatus
US5736015A (en) * 1996-09-06 1998-04-07 Pilot Industries, Inc. Electrical discharge machining apparatus

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