EP0831146A1 - Detergent component or composition with protective coating - Google Patents
Detergent component or composition with protective coating Download PDFInfo
- Publication number
- EP0831146A1 EP0831146A1 EP96305381A EP96305381A EP0831146A1 EP 0831146 A1 EP0831146 A1 EP 0831146A1 EP 96305381 A EP96305381 A EP 96305381A EP 96305381 A EP96305381 A EP 96305381A EP 0831146 A1 EP0831146 A1 EP 0831146A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- detergent composition
- cellulose
- weight
- coating
- coating agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/126—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite in solid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/128—Aluminium silicates, e.g. zeolites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/221—Mono, di- or trisaccharides or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
Definitions
- the present invention relates to the field of coated particulate detergent components or compositions.
- GB-A-1 395 006 published on 21st May 1975, discloses cellulosic polymers as coating agents for detergent components. Sucrose and glucose are also disclosed therein, as plasticizers with dextrin. However cellulosic polymers and sugars are nowhere disclosed in combination as coating agents for detergent components.
- the disadvantage of coating a detergent with cellulosic polymer on its own is that the film formed is slow to dry, and can form a coating that is sticky.
- the object of the present invention relates the application of certain coatings to particulate detergent components or compositions to improve free-flow properties, improve dispensing, avoid dust formation and improve stability of storage sensitive materials.
- a further object of the present invention is to provide a fast-drying coating which forms a continuous film around the particles of the detergent component or composition.
- the object of the invention is achieved by a two-step coating process, wherein the first coating step comprises the process of mixing the detergent composition or component with a finely divided particulate material which is preferably aluminosilicate, and the second coating step comprises the process of applying a coating agent.
- Suitable coating agents comprise from 5% to 95%, preferably from 10% to 60% by weight of cellulosic polymer; from 5% to 95%, preferably from 60% to 90% by weight of sugar; and optionally, from 0% to 30% by weight of plasticizer.
- Preferred detergent components include nonionic surfactant, in particular polyhydroxy fatty acid amide; and bleach activators.
- cellulosic polymer as used herein means polymers that are built up from derivatives of cellulose.
- Cellulose is a polysaccharide made from ⁇ -D-glucose units linked together.
- one or more of the hydroxyl groups are replaced by other groups e.g. methyl, ethyl, propyl.
- Preferred cellulosic polymers include methyl cellulose, ethyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, methylhydroxymethyl cellulose, methylhydroxyethyl cellulose, methylhydroxypropyl cellulose and ethyl hydroxyethyl cellulose.
- sugar as used herein is a generic term for a class of carbohydrates which are usually crystalline and sweet by nature, and which are water soluble. Sugars are formed form glucose and fructose units which are sugars in their own right. Preferred sugars include glucose, fructose, galactose, sucrose, maltose, lactose, sorbitol, manitol, rafinose, trehalose.
- plasticizer as used herein is a material that is added to the original material for the purpose of softening the original material, and make it more flexible.
- Preferred plastisizers include polyethylene glycol having a molecular weight of between 200 and 20000, polypropylene glycol, glycerol, triacetin
- the second coating agent may be applied in any conventional coating apparatus. Suitable apparatus include pan coater; rotating drum continuous coater; spray fluidised granular, or spray fluidised continuous belt.
- Suitable apparatus include pan coater; rotating drum continuous coater; spray fluidised granular, or spray fluidised continuous belt.
- the components of the second coating agent are dissolved or dispersed in a suitable solvent or carrier medium.
- a preferred solvent is water, and an aqueous solution may be prepared which is typically 5% to 40% solids.
- the solution or dispersion may then be sprayed on to the detergent component or composition.
- the proportion of the second coating agent needed to provide a suitable coating layer depends on various parameters, such as the surface characteristics of the detergent component or composition, and will be easily determined by experiment.
- the second coating agent is from 0.1% to 30% of the finished product, more preferably, from 1% to 5%, and most preferably about 2%.
- the detergent component or composition is coated with a finely divided particulate material prior to coating with the second coating agent.
- the detergent component or composition is coated with a first coating agent comprising up to 35%, preferably from 1% to 20% by weight of finely divided particulate material prior to the application of the second coating agent.
- the first coating agent has two purposes. Firstly it allows the detergent particles to be separated (if they are sticky) so that each one can be fully coated. Secondly it gets combined into the second coating agent and adds additional structure to the coating.
- Finely divided particulate materials useful herein include aluminosilicates having the empirical formula: M z (zAlO 2 ) y ] ⁇ x H 2 O wherein z and y are integers of at least 6, the molar ratio of z to y is in the range from 1.0 to about 0.5, and x is an integer from about 15 to about 264.
- Useful aluminosilicate ion exchange materials are commercially available. These aluminosilicates can be crystalline or amorphous in structure and can be naturally-occurring aluminosilicates or synthetically derived.
- aluminosilicate ion exchange materials A method for producing aluminosilicate ion exchange materials is disclosed in US-A-3 985 669, Krummel et al, issued October 12, 1976.
- Preferred synthetic crystalline aluminosilicate ion exchange materials useful herein are available under the designations zeolite A, zeolite P(B), zeolite MAP, zeolite X and zeolite Y.
- the crystalline aluminosilicate ion exchange material has the formula : Na 12 [(AlO 2 ) 12 (SiO2) 12 ] ⁇ x H 2 O wherein x is from about 20 to about 30, especially about 27. This material is known as zeolite A.
- the "overdried" zeolites are particularly useful when a low moisture environment is required, for example to improve stability of detergent bleaches such as perborate and percarbonate.
- the aluminosilicate has a particle size of about 0.1-10 micrometers in diameter.
- Preferred ion exchange materials have a particle size diameter of from about 0.2 micrometers to about 4 micrometers.
- the term "particle size diameter” herein represents the average particle size diameter by weight of a given ion exchange material as determined by conventional analytical techniques such as, for example, microscopic determination utilizing a scanning electron microscope.
- the crystalline zeolite A materials herein are usually further characterized by their calcium ion exchange capacity, which is at least about 200 mg equivalent of CaCO 3 water hardness/g of aluminosilicate, calculated on an anhydrous basis, and which generally is in the range of from about 300 mg eq./g to about 352 mg eq./g.
- the zeolite A materials herein are still further characterized by their calcium ion exchange rate which is at least about 2 grains Ca ++ /gallon/minute/gram/gallon (0.13g Ca ++ /litre/minute/gram/litre) of aluminosilicate (anhydrous basis), and generally lies within the range of from about 2 grains/gallon/minute/gram/gallon(0.13g Ca ++ /litre/minute/gram/litre) to about 6 grains/gallon/minute/gram/gallon (0.39g Ca ++ /litre/minute/gram/litre), based on calcium ion hardness.
- Optimum aluminosilicate for builder purposes exhibit a calcium ion exchange rate of at least about 4 grains/gallon/minute/gram/gallon (0.26g Ca ++ /litre/minute/gram/litre).
- Other finely divided particulate materials include talc, silica and bentonite, as well as other clays.
- Detergent components or compositions are conventionally processed into particulate form in one of a number of ways.
- Spray-drying is one such process which has been widely practised for may decades. More recently dry neutralisation, agglomeration, extrusion, granulation in fluidised beds, flaking, encapsulation, prilling, pastillation and other processes have also been used.
- Detergent compositions and components typically comprise surfactants, builders, chelants, bleach, bleach activators, enzymes, enzyme stabilisers, soil release agents, brightener, suds suppressor, fabric softener, antiredeposition agents and mixtures of these.
- the present invention is particularly suitable for use with nonionic or cationic surfactants, or with bleach activators.
- Preferred nonionic surfactants for use in the present invention include two families of nonionics which have been found to be particularly useful. These are nonionic surfactants based on alkoxylated (especially ethoxylated) alcohols, and those nonionic surfactants based on amidation products of fatty acid esters and N-alkyl polyhydroxy amine. The amidation products of the esters and the amines are generally referred to herein as polyhydroxy fatty acid amides. Particularly useful in the present invention are mixtures comprising two or more nonionic surfactants wherein at least one nonionic surfactant is selected from each of the groups of alkoxylated alcohols and the polyhydroxy fatty acid amides.
- Suitable nonionic surfactants include compounds produced by the condensation of alkylene oxide groups (hydrophilic in nature) with an organic hydrophobic compound, which may be aliphatic or alkyl aromatic in nature.
- the length of the polyoxyalkylene group which is condensed with any particular hydrophobic group can be readily adjusted to yield a water-soluble compound having the desired degree of balance between hydrophilic and hydrophobic elements.
- nonionic surfactants such as the polyethylene oxide condensates of alkyl phenols, e.g., the condensation products of alkyl phenols having an alkyl group containing from about 6 to 16 carbon atoms, in either a straight chain or branched chain configuration, with from about 4 to 25 moles of ethylene oxide per mole of alkyl phenol.
- Preferred nonionics are the water-soluble condensation products of aliphatic alcohols containing from 8 to 22 carbon atoms, in either straight chain or branched configuration, with an average of up to 25 moles of ethylene oxide per more of alcohol.
- Particularly preferred are the condensation products of alcohols having an alkyl group containing from about 9 to 15 carbon atoms with from about 2 to 10 moles of ethylene oxide per mole of alcohol; and condensation products of propylene glycol with ethylene oxide.
- the nonionic surfactant system also includes a polyhydroxy fatty acid amide component.
- Polyhydroxy fatty acid amides may be produced by reacting a fatty acid ester and an N-alkyl polyhydroxy amine.
- the preferred amine for use in the present invention is N-(R1)-CH2(CH2OH)4-CH2-OH, where R1 is typically a alkyl, e.g. methyl group; and the preferred ester is a C12-C20 fatty acid methyl ester.
- nonionic surfactants which may be used as components of the surfactant systems herein include ethoxylated nonionic surfactants, glycerol ethers, glucosamides, glycerol amides, glycerol esters, fatty acids, fatty acid esters, fatty amides, alkyl polyglucosides, alkyl polyglycol ethers, polyethylene glycols, ethoxylated alkyl phenols and mixtures thereof.
- ethoxylated nonionic surfactants include ethoxylated nonionic surfactants, glycerol ethers, glucosamides, glycerol amides, glycerol esters, fatty acids, fatty acid esters, fatty amides, alkyl polyglucosides, alkyl polyglycol ethers, polyethylene glycols, ethoxylated alkyl phenols and mixtures thereof.
- the present invention is particularly useful with bleach activators. For hygiene reasons, the inhalation of many bleach activators should be avoided, so dusty products should be avoided.
- the present invention provides a means for minimising or eliminating dust formation by providing an effective coating.
- Particularly suitable bleach activators are caproyl oxybenzene sulfonate; N,N,N 1 N 1 tetra acetylated compounds; benzoyloxybenzene sulphonate; benzoyl caprolactam; and mixtures thereof.
- bleach activators are (6-octanamido-caproyl)oxybenzenesulfonate, (6-nonanamido-caproyl)oxy benzene sulfonate, (6-decanamido-caproyl)oxybenzenesulfonate, and mixtures thereof.
- a molten mixture consisting of the nonionic surfactants polyhydroxy fatty acid amide, ethoxylated alcohol and the hydrogenated fatty acid was prepared. Micropastilles of the molten mixture were then made by forming drops of the molten material on a cold steel belt, where they solidify. Apparatus for carrying out micropastillation is commercially available from Sandvik.
- micropastilles were then coated first with the zeolite (10% by weight), and subsequently coated with the coating agent which was an aqueous solution with a solids content of 15%, the solids content comprising hydroxy propyl methyl cellulose (35 parts), lactose (45 parts), and triacetin (20 parts).
- the first coating of zeolite was applied in a concrete mixer to ensure good distribution of the flow aid.
- the second coating agent was applied by spraying the aqueous coating in a spray fluid bed granulator. The aqueous coating was sprayed onto the particles, and warm air was used to dry off the excess water.
- NACA-OBS is nonyl amido caproyl oxy benzene sulphonate which is a bleach activator.
- AE3S is alkyl ether sulphate (with 3 EO groups per molecule).
- a detergent component comprising the bleach activator, citric acid, anionic surfactant, copolymer and water was prepared by mixing the dry materials and binders and passing the mixture through an extruder forming noodles of materials. These noodles are allowed to drop into a spheroniser (a Marumeriser® having a rotating bowl with a friction plate) which shapes beads of the desired size.
- a spheroniser a Marumeriser® having a rotating bowl with a friction plate
- the beads were then coated first with the zeolite (5% by weight), and subsequently coated with the second coating agent which was an aqueous solution with a solids content of 15%, the solids content comprising hydroxy propyl methyl cellulose (35 parts), lactose (45 parts), and triacetin (20 parts).
- the coating was applied in a fluid bed granulator.
- a molten mixture consisting of the nonionic surfactants polyhydroxy fatty acid amide, ethoxylated alcohol, hydrogenated fatty acid and glycerol tristearate was prepared. This paste was cooled and agglomerated in a CB Loedige® with the zeolite and carbonate. The finished agglomerates were dusted with additional zeolite in a KM Loedige®.
- the agglomerates were subsequently coated with the second coating agent which was an aqueous solution with a solids content of 40%, the solids content comprising hydroxy propyl methyl cellulose (10 parts), lactose (45 parts), and sucrose (45 parts).
- the second coating agent was applied by spraying the aqueous coating in a spray fluid bed granulator.
- the aqueous coating was sprayed onto the particles, and warm air was used to dry off the excess water.
Abstract
Description
JP-51 123 815, published 29th October 1976, and EP-A-0 551 700, published on 21st July 1993 both disclose combinations of cellulosic polymer and sugars as coating agents for pharmaceutical products, but there is no suggestion that these coatings are suitable for use with detergents.
Preferred cellulosic polymers include methyl cellulose, ethyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, methylhydroxymethyl cellulose, methylhydroxyethyl cellulose, methylhydroxypropyl cellulose and ethyl hydroxyethyl cellulose.
Useful aluminosilicate ion exchange materials are commercially available. These aluminosilicates can be crystalline or amorphous in structure and can be naturally-occurring aluminosilicates or synthetically derived. A method for producing aluminosilicate ion exchange materials is disclosed in US-A-3 985 669, Krummel et al, issued October 12, 1976. Preferred synthetic crystalline aluminosilicate ion exchange materials useful herein are available under the designations zeolite A, zeolite P(B), zeolite MAP, zeolite X and zeolite Y. In an especially preferred embodiment, the crystalline aluminosilicate ion exchange material has the formula :
Other finely divided particulate materials include talc, silica and bentonite, as well as other clays.
Particularly suitable bleach activators are caproyl oxybenzene sulfonate; N,N,N1N1 tetra acetylated compounds; benzoyloxybenzene sulphonate; benzoyl caprolactam; and mixtures thereof. Most suitable bleach activators are (6-octanamido-caproyl)oxybenzenesulfonate, (6-nonanamido-caproyl)oxy benzene sulfonate, (6-decanamido-caproyl)oxybenzenesulfonate, and mixtures thereof.
% by weight | |
Poly hydroxy fatty acid amide | 49 |
Nonionic surfactant (AE5) | 22 |
Hydrogenated fatty acid | 17 |
First coating agent - Zeolite A | 10 |
Second coating agent | 2 |
% by weight | |
NACA-OBS | 68 |
Citric acid | 10 |
Anionic surfactant (AE3S) | 5 |
Maleic-acrylic copolymer | 5 |
Water | 2 |
First coating agent - Zeolite A | 5 |
Second coating agent | 5 |
NACA-OBS is nonyl amido caproyl oxy benzene sulphonate
which is a bleach activator. AE3S is alkyl ether sulphate (with 3 EO groups per molecule). |
% by weight | |
Poly hydroxy fatty acid amide | 6 |
Nonionic surfactant (AE5) | 18 |
Hydrogenated fatty acid | 3 |
Glycerol Tristearate | 1 |
Zeolite A | 56 |
Carbonate | 6 |
First coating agent - Zeolite A | 5 |
Second coating agent | 5 |
Claims (9)
- A particulate detergent composition or component; the detergent composition or component being coated by a two-step coating process, wherein the first coating step comprises the process of mixing the detergent composition or component with a finely divided particulate material, and characterised in that the second coating step comprises the process of applying an coating agent, the coating agent comprising:(i) from 5% to 95% by weight of a cellulosic polymer;(ii) from 5% to 95% by weight of a sugar.
- A particulate detergent composition or component according to claim 1 wherein the coating agent applied in the second coating step comprises:(i) from 10% to 60% by weight of a cellulosic polymer;(ii) from 60% to 90% by weight of a sugar; and(iii) optionally from 0% to 30% by weight of a plasticizer.
- A particulate detergent composition or component according to claim 1 wherein the finely divided particulate material is aluminosilicate.
- A detergent composition or component according to claim 1 wherein the coating agent comprises cellulosic polymers selected from the group consisting of methyl cellulose, ethyl cellulose, hydroxymethyl cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, methylhydroxymethyl cellulose, methylhydroxyethyl cellulose, methylhydroxypropyl cellulose, ethyl hydroxyethyl cellulose or mixtures thereof.
- A detergent composition or component according to claim 1 wherein the coating agent comprises sugar selected from the group consisting of sucrose, glucose, lactose, fructose, dextrin, cellulose, sorbitol, rafinose, trehalose or mixtures thereof.
- A detergent composition or component according to claim 1 wherein the coating agent comprises at least 1% by weight of a plasticizer selected from the group consisting of polyethylene glycol, polypropylene glycol, having a molecular weight of between 200 and 20000; glucose, triacetin or mixtures thereof.
- A detergent composition or component according to any of claims 1 to 6 wherein the detergent component or composition comprises nonionic surfactant.
- A detergent composition or component according to claim 7 wherein the nonionic surfactant comprises polyhydroxy fatty acid amide.
- A detergent composition or component according to any of claims 1 to 6 wherein the detergent component or composition comprises bleach activator selected from the group consisting of caproyl oxybenzene sulfonate; N,N,N1N1 tetra acetylated compounds; (6-octanamido-caproyl)oxybenzenesulfonate, (6-nonanamidocaproyl)oxy benzene sulfonate, (6-decanamido-caproyl)oxybenzenesulfonate; benzoyl caprolactam, and mixtures thereof.
Priority Applications (11)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP96305381A EP0831146B1 (en) | 1996-07-23 | 1996-07-23 | Detergent component or composition with protective coating |
DE69626512T DE69626512T2 (en) | 1996-07-23 | 1996-07-23 | Detergent components or detergent compositions with a protective coating |
ES96305381T ES2188725T3 (en) | 1996-07-23 | 1996-07-23 | DETERGENT COMPONENT OR COMPOSITION WITH PROTECTIVE COATING. |
AT96305381T ATE233807T1 (en) | 1996-07-23 | 1996-07-23 | DETERGENT COMPONENTS OR DETERGENT COMPOSITIONS WITH A PROTECTIVE COATING |
BR9710541A BR9710541A (en) | 1996-07-23 | 1997-07-01 | Component or detergent composition with protective coating |
CA002260933A CA2260933C (en) | 1996-07-23 | 1997-07-01 | Detergent component or composition with protective coating |
JP10506943A JP2000505834A (en) | 1996-07-23 | 1997-07-01 | Detergent component or composition with protective coating |
US09/230,434 US6376454B1 (en) | 1996-07-23 | 1997-07-01 | Detergent component or composition with protective coating |
CN97198120.5A CN1230978A (en) | 1996-07-23 | 1997-07-01 | Detergent component or composition with protective coating |
PCT/US1997/011385 WO1998003620A1 (en) | 1996-07-23 | 1997-07-01 | Detergent component or composition with protective coating |
ARP970103286A AR008407A1 (en) | 1996-07-23 | 1997-07-22 | COMPONENT OR DETERGENT COMPOSITION WITH PROTECTIVE COATING |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP96305381A EP0831146B1 (en) | 1996-07-23 | 1996-07-23 | Detergent component or composition with protective coating |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0831146A1 true EP0831146A1 (en) | 1998-03-25 |
EP0831146B1 EP0831146B1 (en) | 2003-03-05 |
Family
ID=8225019
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP96305381A Expired - Lifetime EP0831146B1 (en) | 1996-07-23 | 1996-07-23 | Detergent component or composition with protective coating |
Country Status (10)
Country | Link |
---|---|
EP (1) | EP0831146B1 (en) |
JP (1) | JP2000505834A (en) |
CN (1) | CN1230978A (en) |
AR (1) | AR008407A1 (en) |
AT (1) | ATE233807T1 (en) |
BR (1) | BR9710541A (en) |
CA (1) | CA2260933C (en) |
DE (1) | DE69626512T2 (en) |
ES (1) | ES2188725T3 (en) |
WO (1) | WO1998003620A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002008137A2 (en) * | 2000-07-24 | 2002-01-31 | Henkel Kommanditgesellschaft Auf Aktien | Particulate composite material for controlled release of an agent |
WO2002044462A2 (en) * | 2000-11-29 | 2002-06-06 | Henkel Kommanditgesellschaft Auf Aktien | Particulate textiles aftertreatment agent |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19920118B4 (en) * | 1999-05-03 | 2016-08-11 | Henkel Ag & Co. Kgaa | Detergent tablets with coating and process for its preparation |
CN100348489C (en) * | 2003-04-24 | 2007-11-14 | 狮王株式会社 | Surface-treated particle of water-soluble inorganic compound, process for producing the same, and particulate detergent composition |
WO2004094313A1 (en) * | 2003-04-24 | 2004-11-04 | Lion Corporation | Surface-treated particle of water-soluble inorganic compound, process for producing the same, and particulate detergent composition |
DE102005036346A1 (en) * | 2005-07-29 | 2007-02-01 | Henkel Kgaa | Granulates/agglomerate for detergents or cleaning agents comprises dust portion content from the elutriation method, surfactant content, and nuclear particle |
EP2516613B1 (en) | 2009-12-24 | 2017-03-01 | Akzo Nobel Chemicals International B.V. | Coated particles of a glumatic acid n,n-diacetate chelating agent |
GB201019623D0 (en) * | 2010-11-19 | 2010-12-29 | Reckitt Benckiser Nv | Coated bleach materials |
KR102230496B1 (en) * | 2020-11-05 | 2021-03-23 | (주)행복바라기 | Tablet type disposable soap and manufacturing method of it |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4372876A (en) * | 1980-05-02 | 1983-02-08 | Uop Inc. | Zeolite molecular sieve adsorbent for an aqueous system |
JPS6312467A (en) * | 1986-06-27 | 1988-01-19 | ライオン株式会社 | High bulk density detergent containing water-soluble film |
JPH03111497A (en) * | 1989-09-26 | 1991-05-13 | Kao Corp | Coating of particle for compounding into detergent |
WO1993013195A1 (en) * | 1991-12-20 | 1993-07-08 | The Procter & Gamble Company | A process for preparing a perfume capsule composition |
WO1994003568A1 (en) * | 1992-08-01 | 1994-02-17 | The Procter & Gamble Company | Low gelling detergent compositions and a process for making such compositions |
EP0583512A1 (en) * | 1992-08-18 | 1994-02-23 | The Procter & Gamble Company | Detergent additives |
DE4322229A1 (en) * | 1993-07-05 | 1995-01-12 | Cognis Bio Umwelt | Enveloped enzyme preparation for detergents and cleaners |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA962158A (en) * | 1971-03-11 | 1975-02-04 | Unilever Limited | Detergent compositions |
US4009113A (en) * | 1971-04-30 | 1977-02-22 | Lever Brothers Company | Protection of materials |
JPS51123815A (en) * | 1975-04-22 | 1976-10-28 | Shin Etsu Chem Co Ltd | A process for preparing coated solid medicines |
IE51848B1 (en) * | 1980-11-06 | 1987-04-15 | Procter & Gamble | Bleach activator compositions,preparation thereof and use in granular detergent compositions |
GB8310080D0 (en) * | 1983-04-14 | 1983-05-18 | Interox Chemicals Ltd | Bleach composition |
US4657784A (en) * | 1986-03-10 | 1987-04-14 | Ecolab Inc. | Process for encapsulating particles with at least two coating layers having different melting points |
US5318714A (en) * | 1988-03-14 | 1994-06-07 | Novo Nordisk A/S | Stabilized particulate composition |
JP3192469B2 (en) * | 1991-05-17 | 2001-07-30 | 花王株式会社 | Method for producing nonionic detergent particles |
GB2256648B (en) * | 1991-05-29 | 1995-08-30 | Colorcon Ltd | Wax polish composition |
US5458801A (en) * | 1991-09-27 | 1995-10-17 | Kao Corporation | Process for producing granular bleach activator composition and granular bleach activator composition |
US5512699A (en) * | 1994-01-25 | 1996-04-30 | The Procter & Gamble Company | Poly polyhydroxy fatty acid amides |
US5648328A (en) * | 1996-02-06 | 1997-07-15 | The Procter & Gamble Company | Process for producing a particulate laundry additive composition for perfume delivery |
-
1996
- 1996-07-23 ES ES96305381T patent/ES2188725T3/en not_active Expired - Lifetime
- 1996-07-23 AT AT96305381T patent/ATE233807T1/en not_active IP Right Cessation
- 1996-07-23 EP EP96305381A patent/EP0831146B1/en not_active Expired - Lifetime
- 1996-07-23 DE DE69626512T patent/DE69626512T2/en not_active Expired - Fee Related
-
1997
- 1997-07-01 JP JP10506943A patent/JP2000505834A/en not_active Withdrawn
- 1997-07-01 BR BR9710541A patent/BR9710541A/en not_active Application Discontinuation
- 1997-07-01 WO PCT/US1997/011385 patent/WO1998003620A1/en active Application Filing
- 1997-07-01 CA CA002260933A patent/CA2260933C/en not_active Expired - Fee Related
- 1997-07-01 CN CN97198120.5A patent/CN1230978A/en active Pending
- 1997-07-22 AR ARP970103286A patent/AR008407A1/en unknown
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4372876A (en) * | 1980-05-02 | 1983-02-08 | Uop Inc. | Zeolite molecular sieve adsorbent for an aqueous system |
JPS6312467A (en) * | 1986-06-27 | 1988-01-19 | ライオン株式会社 | High bulk density detergent containing water-soluble film |
JPH03111497A (en) * | 1989-09-26 | 1991-05-13 | Kao Corp | Coating of particle for compounding into detergent |
WO1993013195A1 (en) * | 1991-12-20 | 1993-07-08 | The Procter & Gamble Company | A process for preparing a perfume capsule composition |
WO1994003568A1 (en) * | 1992-08-01 | 1994-02-17 | The Procter & Gamble Company | Low gelling detergent compositions and a process for making such compositions |
EP0583512A1 (en) * | 1992-08-18 | 1994-02-23 | The Procter & Gamble Company | Detergent additives |
DE4322229A1 (en) * | 1993-07-05 | 1995-01-12 | Cognis Bio Umwelt | Enveloped enzyme preparation for detergents and cleaners |
Non-Patent Citations (2)
Title |
---|
DATABASE WPI Section Ch Week 8808, Derwent World Patents Index; Class A97, AN 88-054705, XP002021837 * |
DATABASE WPI Section Ch Week 9125, Derwent World Patents Index; Class A97, AN 91-182438, XP002021836 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2002008137A2 (en) * | 2000-07-24 | 2002-01-31 | Henkel Kommanditgesellschaft Auf Aktien | Particulate composite material for controlled release of an agent |
WO2002008137A3 (en) * | 2000-07-24 | 2002-05-30 | Henkel Kgaa | Particulate composite material for controlled release of an agent |
WO2002044462A2 (en) * | 2000-11-29 | 2002-06-06 | Henkel Kommanditgesellschaft Auf Aktien | Particulate textiles aftertreatment agent |
WO2002044462A3 (en) * | 2000-11-29 | 2002-09-06 | Henkel Kgaa | Particulate textiles aftertreatment agent |
Also Published As
Publication number | Publication date |
---|---|
ES2188725T3 (en) | 2003-07-01 |
WO1998003620A1 (en) | 1998-01-29 |
BR9710541A (en) | 1999-08-17 |
JP2000505834A (en) | 2000-05-16 |
CA2260933A1 (en) | 1998-01-29 |
CN1230978A (en) | 1999-10-06 |
CA2260933C (en) | 2002-09-03 |
DE69626512T2 (en) | 2003-12-24 |
EP0831146B1 (en) | 2003-03-05 |
AR008407A1 (en) | 2000-01-19 |
ATE233807T1 (en) | 2003-03-15 |
DE69626512D1 (en) | 2003-04-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US5629275A (en) | Process for the production of surfactant-containing granules | |
EP0831146B1 (en) | Detergent component or composition with protective coating | |
SK32098A3 (en) | Method for preparing an amorphous alkali silicate with impregnation | |
JPH05202398A (en) | Detergent powder and its preparation | |
US6376454B1 (en) | Detergent component or composition with protective coating | |
US5663136A (en) | Process for making compact detergent compositions | |
EP0816485B1 (en) | Process for making detergent compositions | |
US4283302A (en) | Particulate bleach compositions | |
EP0622454A1 (en) | Structuring liquid nonionic surfactants prior to granulation process | |
CA2083332C (en) | Detergent compositions and process for preparing them | |
US20070225197A1 (en) | Method for Producing Granules and the Use Thereof in Washing and/or Cleaning Agents | |
US20020055451A1 (en) | Detergent tablets | |
US5610131A (en) | Structuring liquid nonionic surfactants prior to granulation process | |
WO1998050509A1 (en) | Method for producing granulates with a long shelf life containing soil release polymers and the use thereof for the production of solid detergents and cleaning agents | |
JPH08239692A (en) | Particulate foaming modifier and detergent composition usingit | |
US20010014657A1 (en) | Nonionic surfactant granules by prilling | |
US6156718A (en) | Process for making detergent compositions | |
WO1996034082A1 (en) | Process for producing granular detergent components or compositions | |
GB2053998A (en) | Particulate bleach composition | |
EP1124628B1 (en) | Polymer granules produced by fluidized bed granulation | |
EP0853117B1 (en) | Granular detergent with improved greasy soil removal performance | |
US6140301A (en) | Process for producing granular detergent components or compositions | |
DE19713328A1 (en) | Stabilisation of granular materials to prevent clumping | |
JP2002529581A (en) | Soluble surfactant granules | |
US20010009311A1 (en) | Granules by fluidized bed granulation |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PUAI | Public reference made under article 153(3) epc to a published international application that has entered the european phase |
Free format text: ORIGINAL CODE: 0009012 |
|
AK | Designated contracting states |
Kind code of ref document: A1 Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LI LU NL PT SE |
|
AX | Request for extension of the european patent |
Free format text: AL;LT;LV;SI |
|
17P | Request for examination filed |
Effective date: 19980409 |
|
AKX | Designation fees paid |
Free format text: AT BE CH DE DK ES FI FR GB GR IE IT LI LU NL PT SE |
|
RBV | Designated contracting states (corrected) |
Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LI LU NL PT SE |
|
17Q | First examination report despatched |
Effective date: 20011009 |
|
GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
GRAH | Despatch of communication of intention to grant a patent |
Free format text: ORIGINAL CODE: EPIDOS IGRA |
|
GRAA | (expected) grant |
Free format text: ORIGINAL CODE: 0009210 |
|
AK | Designated contracting states |
Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LI LU NL PT SE |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: NL Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20030305 Ref country code: LI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20030305 Ref country code: GR Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20030305 Ref country code: FI Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20030305 Ref country code: CH Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20030305 Ref country code: BE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20030305 Ref country code: AT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20030305 |
|
REG | Reference to a national code |
Ref country code: GB Ref legal event code: FG4D |
|
REG | Reference to a national code |
Ref country code: CH Ref legal event code: EP |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: FG4D |
|
REF | Corresponds to: |
Ref document number: 69626512 Country of ref document: DE Date of ref document: 20030410 Kind code of ref document: P |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: SE Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20030605 Ref country code: PT Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20030605 Ref country code: DK Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT Effective date: 20030605 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: GB Payment date: 20030612 Year of fee payment: 8 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FG2A Ref document number: 2188725 Country of ref document: ES Kind code of ref document: T3 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: FR Payment date: 20030702 Year of fee payment: 8 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: LU Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20030723 Ref country code: IE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20030723 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: ES Payment date: 20030723 Year of fee payment: 8 |
|
PGFP | Annual fee paid to national office [announced via postgrant information from national office to epo] |
Ref country code: DE Payment date: 20030731 Year of fee payment: 8 |
|
NLV1 | Nl: lapsed or annulled due to failure to fulfill the requirements of art. 29p and 29m of the patents act | ||
REG | Reference to a national code |
Ref country code: CH Ref legal event code: PL |
|
ET | Fr: translation filed | ||
PLBE | No opposition filed within time limit |
Free format text: ORIGINAL CODE: 0009261 |
|
STAA | Information on the status of an ep patent application or granted ep patent |
Free format text: STATUS: NO OPPOSITION FILED WITHIN TIME LIMIT |
|
26N | No opposition filed |
Effective date: 20031208 |
|
REG | Reference to a national code |
Ref country code: IE Ref legal event code: MM4A |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: GB Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20040723 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: ES Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20040724 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: DE Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20050201 |
|
GBPC | Gb: european patent ceased through non-payment of renewal fee |
Effective date: 20040723 |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: FR Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES Effective date: 20050331 |
|
REG | Reference to a national code |
Ref country code: FR Ref legal event code: ST |
|
PG25 | Lapsed in a contracting state [announced via postgrant information from national office to epo] |
Ref country code: IT Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES;WARNING: LAPSES OF ITALIAN PATENTS WITH EFFECTIVE DATE BEFORE 2007 MAY HAVE OCCURRED AT ANY TIME BEFORE 2007. THE CORRECT EFFECTIVE DATE MAY BE DIFFERENT FROM THE ONE RECORDED. Effective date: 20050723 |
|
REG | Reference to a national code |
Ref country code: ES Ref legal event code: FD2A Effective date: 20040724 |