EP0537417A1 - Lost pattern and process for making the same - Google Patents
Lost pattern and process for making the same Download PDFInfo
- Publication number
- EP0537417A1 EP0537417A1 EP92110719A EP92110719A EP0537417A1 EP 0537417 A1 EP0537417 A1 EP 0537417A1 EP 92110719 A EP92110719 A EP 92110719A EP 92110719 A EP92110719 A EP 92110719A EP 0537417 A1 EP0537417 A1 EP 0537417A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- model
- low
- shell
- melting material
- light
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22C—FOUNDRY MOULDING
- B22C7/00—Patterns; Manufacture thereof so far as not provided for in other classes
- B22C7/02—Lost patterns
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y80/00—Products made by additive manufacturing
Definitions
- the invention relates to a lost model made of a low-melting material for the investment casting of metal and a method for its production.
- the lost model consists of a low-melting material, such as wax or z. B. Sn, Bi, Sb and other metals containing MCP alloys. Such models are cast and, after solidification to form the casting mold, are backfilled in a mold box with sand or another ceramic material provided with binders. After the low-melting material has melted out of the casting mold, the casting cavity is created (Dubbel: Taschenbuch für den Maschinenbau, 14th edition, Springer-Verlag 1981, pages 946 to 949).
- the production of the lost models could be simplified if the models could be manufactured without tools according to the stereolithography principle (US Pat. No. 4,575,330).
- This method uses a laser beam that is controlled directly by a computer-aided (CAD) design drawing and a process computer.
- the UV light from the laser beam is directed at liquid monomer, which is located in a tub provided with a vertically adjustable, perforated plate.
- the monomer hardens under the influence of the UV light of the laser beam by polymerization and forms a solid polymer which is no longer soluble in the liquid phase.
- the controlled laser beam builds up a body in layers according to the drawing on the perforated plate immersed in the liquid bath of the tub at a shallow depth.
- the object of the invention is to use stereolithography to produce such a model which is dimensionally accurate and does not cause any damage to the casting mold when it melts.
- the surfaces that are crucial for the casting to be manufactured according to the model are designed to be dimensionally accurate.
- the self-supporting shell made of laser-hardened polymer is used to hold the low-melting material. This material compensates for thermal expansion of the light-curing polymer of the shell when it melts out of the casting mold by rapidly becoming liquid. This reliably prevents the mold from bursting.
- the model shown in the drawing is the model for an impeller of a turbocompressor.
- Such an impeller consists of a hub disk and a cover disk, between which convoluted blades are arranged.
- the hub disc, the cover disc and the blades limit the flow cross-section of the impeller.
- the hub disc is provided with a central hole that later receives the drive shaft of the turbo compressor.
- the reference number 1 indicates the part of the model corresponding to the hub disk of the impeller.
- the part designated by reference number 2 corresponds to the blades and the part designated by 3 corresponds to the cover plate.
- the model consists of a self-supporting, thin shell 4, 5 made of light-curing polymer.
- This shell 4, 5 is produced without tools with the aid of a laser beam controlled directly via a computer-aided design drawing by curing the liquid polymer according to the known stereolithography method discussed in the introduction to the description.
- the shell part 4 forms the outer shape of the hub disc 2 and the shell part 5 the outer shape of the cover disc 3. These surfaces delimited by the shell 4, 5 determine the shape and limit the flow cross section in the later cast impeller.
- the interior enclosed by the shell 4, 5 is filled with a low-melting material to such an extent that, after solidification, the subordinate surfaces 6, 7 of the model are limited by the surface of the low-melting material.
- These surfaces 6, 7 are the sides of the hub disk and the cover disk of the later impeller facing away from the flow cross section. Wax or an alloy of bismuth and tin is used as the low-melting material.
- the blades can also be made in the manner described above.
- the part of the model corresponding to the blade 2 consists of a shell 8 made of light-curing polymer.
- the interior 9 of the shell 8 is filled with the low-melting material.
- Very thin-walled parts such as the blades 2 according to FIG. 3 or struts, can no longer be made hollow using the method described above.
- a solid core 10 made of light-curing polymer is produced with the aid of the laser beam.
- This core 10 is surrounded by a layer 11 of low-melting material.
- the hub disc is provided with a central hole that later receives the drive shaft of the turbo compressor.
- the reference number 1 indicates the part of the model corresponding to the hub disk of the impeller.
- the part designated by reference number 2 corresponds to the blades and the part designated by 3 corresponds to the cover plate.
- the model consists of a self-supporting, thin shell 4, 5 made of light-curing polymer.
- This shell 4, 5 is produced without tools with the aid of a laser beam controlled directly via a computer-aided design drawing by curing the liquid polymer according to the known stereolithography method discussed in the introduction to the description.
- the shell part 4 forms the outer shape of the hub disc 2 and the shell part 5 the outer shape of the cover disc 3. These surfaces delimited by the shell 4, 5 determine the shape and limit the flow cross section in the later cast impeller.
- the interior enclosed by the shell 4, 5 is filled with a low-melting material to such an extent that, after solidification, the subordinate surfaces 6, 7 of the model are limited by the surface of the low-melting material.
- These surfaces 6, 7 are the sides of the hub disk and the cover disk of the later impeller facing away from the flow cross section. Wax or an alloy of bismuth and tin is used as the low-melting material.
- the blades can also be made in the manner described above.
- the part of the model corresponding to the blade 2 consists of a shell 8 made of light-curing polymer.
- the interior 9 of the shell 8 is filled with the low-melting material.
- Very thin-walled parts such as the blades 2 according to FIG. 3 or struts, can no longer be made hollow using the method described above.
- a solid core 10 made of light-curing polymer is produced with the aid of the laser beam.
- This core 10 is surrounded by a layer 11 of low-melting material. Also compensated for when melting the In the casting mold, the low-melting material through rapid liquidation expands the thermal expansion of the core 10 made of light-curing polymer.
Abstract
Die formbestimmenden Oberflächen eines verlorenen Modells für den Feinguß von Metall bestehen aus einer dünnwandigen, selbsttragenden Schale (4, 5), deren Innenraum mit einem niedrigschmelzenden Material ausgefüllt ist. Dabei sind die nicht formbestimmenden Oberflächen (6, 7) des Modells durch das niedrigschmelzende Material begrenzt. Die dünnwandige Schale (4, 5) ist aus einem lichthärtendem Polymer mit Hilfe eines über eine rechnerunterstützte Konstruktionszeichnung direkt gesteuerten Laserstrahles gefertigt. <IMAGE>The shape-determining surfaces of a lost model for the investment casting of metal consist of a thin-walled, self-supporting shell (4, 5), the interior of which is filled with a low-melting material. The non-shape-defining surfaces (6, 7) of the model are limited by the low-melting material. The thin-walled shell (4, 5) is made of a light-curing polymer using a laser beam that is directly controlled by a computer-aided design drawing. <IMAGE>
Description
Die Erfindung betrifft ein verlorenes Modell aus einem niedrigschmelzenden Material für den Feinguß von Metall und ein Verfahren zu seiner Herstellung.The invention relates to a lost model made of a low-melting material for the investment casting of metal and a method for its production.
Verlorene Modelle in verlorenen Gießformen werden verwendet, wenn das zu fertigende Formteil eine komplexe Gestalt aufweist und ein enger Toleranzbereich eingehalten werden muß. Das verlorene Modell besteht aus einem niedrigschmelzenden Material, wie Wachs oder aus z. B. Sn, Bi, Sb und andere Metalle enthaltenden MCP-Legierungen. Derartige Modelle werden gegossen und nach dem Erstarren zur Bildung der Gießform in einem Formkasten mit Sand oder einem anderen mit Bindemitteln versehenen keramischen Material hinterfüllt. Nach dem Ausschmelzen des niedrigschmelzenden Materials aus der Gießform entsteht der Gießhohlraum (Dubbel: Taschenbuch für den Maschinenbau, 14. Auflage, Springer-Verlag 1981, Seiten 946 bis 949).Lost models in lost molds are used when the molded part to be manufactured has a complex shape and a narrow tolerance range must be observed. The lost model consists of a low-melting material, such as wax or z. B. Sn, Bi, Sb and other metals containing MCP alloys. Such models are cast and, after solidification to form the casting mold, are backfilled in a mold box with sand or another ceramic material provided with binders. After the low-melting material has melted out of the casting mold, the casting cavity is created (Dubbel: Taschenbuch für den Maschinenbau, 14th edition, Springer-Verlag 1981, pages 946 to 949).
Die Herstellung der verlorenen Modelle ließe sich vereinfachen, wenn die Modelle ohne Werkzeug nach dem Prinzip der Stereolithographie gefertigt werden könnten (US-PS 45 75 330). Bei diesem Verfahren wird ein Laserstrahl verwendet, der direkt über eine rechnerunterstützte (CAD) Konstruktionszeichnung und einen Prozeßrechner gesteuert wird. Das UV-Licht des Laserstrahles wird auf flüssiges Monomer gerichtet, das sich in einer mit einer vertikal verstellbaren, perforierten Platte versehenen Wanne befindet. Das Monomer erhärtet unter dem Einfluß des UV-Lichtes des Laserstrahles durch Polymerisation und bildet ein festes, in der flüssigen Phase nicht mehr lösliches Polymer. Der gesteuerte Laserstrahl baut aufgrund dieser Reaktion auf der mit geringer Tiefe in das Flüssigkeitsbad der Wanne eintauchenden, perforierten Platte einen Körper entsprechend der Zeichnung schichtweise auf. Auf diese Weise lassen sich auch verlorene Modelle mit hoher Maßgenauigkeit herstellen. Eine solche Herstellung weist jedoch den Nachteil auf, daß die Herstellung eines vollwandigen Modelles sehr aufwendig ist, da die Herstellungszeit von dem Volumen des zu härtenden Materials abhängt. Außerdem würde das lichthärtende Polymer beim Ausschmelzen des Modells aus der Gießform sich zunächst stark ausdehnen, bevor er schmilzt. Damit besteht die Gefahr, daß die Gießform beim Ausschmelzen des Modelles gesprengt würde.The production of the lost models could be simplified if the models could be manufactured without tools according to the stereolithography principle (US Pat. No. 4,575,330). This method uses a laser beam that is controlled directly by a computer-aided (CAD) design drawing and a process computer. The UV light from the laser beam is directed at liquid monomer, which is located in a tub provided with a vertically adjustable, perforated plate. The monomer hardens under the influence of the UV light of the laser beam by polymerization and forms a solid polymer which is no longer soluble in the liquid phase. As a result of this reaction, the controlled laser beam builds up a body in layers according to the drawing on the perforated plate immersed in the liquid bath of the tub at a shallow depth. In this way, even lost models can be manufactured with high dimensional accuracy. However, such a production has the disadvantage that the production of a full-walled model is very complex, since the production time depends on the volume of the material to be hardened. In addition, the light-curing polymer would melt when the model melted out of the mold stretch hard before it melts. There is therefore a risk that the mold would be blown up when the model melted out.
Der Erfindung liegt die Aufgabe zugrunde, mit Hilfe der Stereolithographie ein solches Modell herzustellen, das maßgenau ist und beim Ausschmelzen keine Schäden in der Gießform herbeiführt.The object of the invention is to use stereolithography to produce such a model which is dimensionally accurate and does not cause any damage to the casting mold when it melts.
Diese Aufgabe wird erfindungsgemäß durch ein Modell mit den kennzeichnenden Merkmalen des Patentanspruches 1 gelöst. Eine vorteilhafte Ausgestaltung der Erfindung ist in dem Patentanspruch 2 angegeben. Ein Verfahren zur Herstellung des Modells ist Gegenstand des Patentanspruches 3.This object is achieved by a model with the characterizing features of
Bei dem erfindungsgemäß hergestellten bzw. ausgebildeten Modell sind die Flächen, auf die es bei dem nach dem Modell zu fertigenden Gußstück entscheidend ankommt, maßgenau gestaltet. Die selbsttragende Schale aus laserlichtgehärtetem Polymer dient der Aufnahme des niedrigschmelzenden Materials. Dieses Material kompensiert beim Ausschmelzen aus der Gießform durch ein schnelles Flüssigwerden eine Wärmedehnung des lichthärtenden Polymers der Schale. Ein Platzen der Gießform wird auf diese Weise sicher verhindert.In the model manufactured or designed according to the invention, the surfaces that are crucial for the casting to be manufactured according to the model are designed to be dimensionally accurate. The self-supporting shell made of laser-hardened polymer is used to hold the low-melting material. This material compensates for thermal expansion of the light-curing polymer of the shell when it melts out of the casting mold by rapidly becoming liquid. This reliably prevents the mold from bursting.
Mehrere Ausführungsbeispiele der Erfindung sind in der Zeichnung dargestellt und werden im folgenden näher erläutert. Es zeigen:
- Fig. 1
- den Längsschnitt durch ein Modell,
- Fig. 2
- die teilweise Draufsicht auf Fig. 1 und
- Fig. 3
- die teilweise Draufsicht auf Fig. 1 gemäß einer anderen Ausführungsform.
- Fig. 1
- the longitudinal section through a model,
- Fig. 2
- the partial plan view of Fig. 1 and
- Fig. 3
- the partial plan view of Fig. 1 according to another embodiment.
Das in der Zeichnung dargestellte Modell ist das Modell für ein Laufrad eines Turboverdichters. Ein solches Laufrad besteht aus einer Nabenscheibe und einer Deckscheibe, zwischen denen gewundene Schaufeln angeordnet sind. Die Nabenscheibe, die Deckscheibe und die Schaufeln begrenzen den Strömungsquerschnitt des Laufrades. Die Nabenscheibe ist mit einer zentralen Bohrung versehen, die später die Antriebswelle des Turboverdichters aufnimmt. In der Zeichnung weist die Bezugsziffer 1 auf das der Nabenscheibe des Laufrades entsprechende Teil des Modelles hin. Das mit der Bezugsziffer 2 bezeichnete Teil entspricht den Schaufeln, und das mit 3 bezeichnete Teil entspricht der Deckscheibe.The model shown in the drawing is the model for an impeller of a turbocompressor. Such an impeller consists of a hub disk and a cover disk, between which convoluted blades are arranged. The hub disc, the cover disc and the blades limit the flow cross-section of the impeller. The The hub disc is provided with a central hole that later receives the drive shaft of the turbo compressor. In the drawing, the
Das Modell besteht aus einer selbsttragenden, dünnen Schale 4, 5 aus lichthärtendem Polymer. Diese Schale 4, 5 wird ohne Werkzeug mit Hilfe eines direkt über eine rechnergestützte Konstruktionszeichnung gesteuerten Laserstrahles durch Härten des flüssigen Polymers nach dem in der Beschreibungseinleitung erörterten, bekannten Verfahren der Stereolithographie hergestellt. Dabei bildet das Schalenteil 4 die äußere Form der Nabenscheibe 2 und das Schalenteil 5 die äußere Form der Deckscheibe 3. Diese von der Schale 4, 5 begrenzten Flächen sind formbestimmend und begrenzen in dem später gegossenen Laufrad den Strömungsquerschnitt.The model consists of a self-supporting,
Der von der Schale 4, 5 umschlossene Innenraum wird mit einem niedrigschmelzenden Material soweit gefüllt, daß nach der Verfestigung die untergeordneten Flächen 6, 7 des Modells durch die Oberfläche des niedrigschmelzenden Materials begrenzt sind. Diese Flächen 6, 7 sind die dem Strömungsquerschnitt abgewandten Seiten der Nabenscheibe und der Deckscheibe des späteren Laufrades. Als niedrigschmelzendes Material wird Wachs oder eine Legierung aus Wismut und Zinn verwendet.The interior enclosed by the
Die Schaufeln können ebenfalls in der oben beschriebenen Weise hergestellt werden. Wie aus Fig. 2 zu erkennen ist, besteht das der Schaufel 2 entsprechende Teil des Modells aus einer Schale 8 aus lichthärtendem Polymer. Der Innenraum 9 der Schale 8 ist mit dem niedrigschmelzenden Material ausgefüllt.The blades can also be made in the manner described above. As can be seen from FIG. 2, the part of the model corresponding to the
Sehr dünnwandige Teile, wie die Schaufeln 2 gemäß Fig. 3 oder Verstrebungen können mit Hilfe des oben beschriebenen Verfahrens nicht mehr hohl gefertigt werden. In diesem Fall wird mit Hilfe des Laserstrahles ein massiver Kern 10 aus lichthärtendem Polymer erzeugt. Dieser Kern 10 wird mit einer Schicht 11 aus niedrigschmelzendem Material umgeben. Auch hierbei kompensiert beim Ausschmelzen des Nabenscheibe ist mit einer zentralen Bohrung versehen, die später die Antriebswelle des Turboverdichters aufnimmt. In der Zeichnung weist die Bezugsziffer 1 auf das der Nabenscheibe des Laufrades entsprechende Teil des Modelles hin. Das mit der Bezugsziffer 2 bezeichnete Teil entspricht den Schaufeln, und das mit 3 bezeichnete Teil entspricht der Deckscheibe.Very thin-walled parts, such as the
Das Modell besteht aus einer selbsttragenden, dünnen Schale 4, 5 aus lichthärtendem Polymer. Diese Schale 4, 5 wird ohne Werkzeug mit Hilfe eines direkt über eine rechnergestützte Konstruktionszeichnung gesteuerten Laserstrahles durch Härten des flüssigen Polymers nach dem in der Beschreibungseinleitung erörterten, bekannten Verfahren der Stereolithographie hergestellt. Dabei bildet das Schalenteil 4 die äußere Form der Nabenscheibe 2 und das Schalenteil 5 die äußere Form der Deckscheibe 3. Diese von der Schale 4, 5 begrenzten Flächen sind formbestimmend und begrenzen in dem später gegossenen Laufrad den Strömungsquerschnitt.The model consists of a self-supporting,
Der von der Schale 4, 5 umschlossene Innenraum wird mit einem niedrigschmelzenden Material soweit gefüllt, daß nach der Verfestigung die untergeordneten Flächen 6, 7 des Modells durch die Oberfläche des niedrigschmelzenden Materials begrenzt sind. Diese Flächen 6, 7 sind die dem Strömungsquerschnitt abgewandten Seiten der Nabenscheibe und der Deckscheibe des späteren Laufrades. Als niedrigschmelzendes Material wird Wachs oder eine Legierung aus Wismut und Zinn verwendet.The interior enclosed by the
Die Schaufeln können ebenfalls in der oben beschriebenen Weise hergestellt werden. Wie aus Fig. 2 zu erkennen ist, besteht das der Schaufel 2 entsprechende Teil des Modells aus einer Schale 8 aus lichthärtendem Polymer. Der Innenraum 9 der Schale 8 ist mit dem niedrigschmelzenden Material ausgefüllt.The blades can also be made in the manner described above. As can be seen from FIG. 2, the part of the model corresponding to the
Sehr dünnwandige Teile, wie die Schaufeln 2 gemäß Fig. 3 oder Verstrebungen können mit Hilfe des oben beschriebenen Verfahrens nicht mehr hohl gefertigt werden. In diesem Fall wird mit Hilfe des Laserstrahles ein massiver Kern 10 aus lichthärtendem Polymer erzeugt. Dieser Kern 10 wird mit einer Schicht 11 aus niedrigschmelzendem Material umgeben. Auch hierbei kompensiert beim Ausschmelzen des Modells in der Gießform das niedrigschmelzende Material durch schnelles Flüssigwerden die Wärmedehnung des aus lichthärtendem Polymer bestehendes Kernes 10.Very thin-walled parts, such as the
Claims (3)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE4133923 | 1991-10-12 | ||
DE4133923A DE4133923A1 (en) | 1991-10-12 | 1991-10-12 | LOST MODEL AND METHOD FOR THEIR PRODUCTION |
Publications (2)
Publication Number | Publication Date |
---|---|
EP0537417A1 true EP0537417A1 (en) | 1993-04-21 |
EP0537417B1 EP0537417B1 (en) | 1996-03-13 |
Family
ID=6442620
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP92110719A Expired - Lifetime EP0537417B1 (en) | 1991-10-12 | 1992-06-25 | Lost pattern and process for making the same |
Country Status (4)
Country | Link |
---|---|
US (1) | US5277241A (en) |
EP (1) | EP0537417B1 (en) |
JP (1) | JP3124387B2 (en) |
DE (2) | DE4133923A1 (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB9405440D0 (en) | 1994-03-19 | 1994-05-04 | Schwitzer Europ Ltd | Turbochargers |
DE4410046C2 (en) * | 1994-03-23 | 2000-11-30 | Eos Electro Optical Syst | Method and material for producing a three-dimensional object by sintering |
US5775412A (en) * | 1996-01-11 | 1998-07-07 | Gidding Engineering, Inc. | High pressure dense heat transfer area heat exchanger |
US5824250A (en) * | 1996-06-28 | 1998-10-20 | Alliedsignal Inc. | Gel cast molding with fugitive molds |
TW436357B (en) | 1997-12-12 | 2001-05-28 | Matsushita Electric Ind Co Ltd | Laser drilling equipment and control method |
US6663347B2 (en) * | 2001-06-06 | 2003-12-16 | Borgwarner, Inc. | Cast titanium compressor wheel |
CN102091757B (en) * | 2010-12-30 | 2013-01-02 | 沈阳黎明航空发动机(集团)有限责任公司 | Integral precision casting method for large thin-wall casing part |
US20170246677A1 (en) * | 2016-02-29 | 2017-08-31 | General Electric Company | Casting with metal components and metal skin layers |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1337560A (en) * | 1962-09-10 | 1963-09-13 | Howe Sound Co | Molding process, and device for implementing the same |
FR2479044A1 (en) * | 1980-03-26 | 1981-10-02 | Rozier Guy | Cores for high precision metal casting by lost wax process - made from stable polyurethane or epoxy! resin foam, opt. with central insert e.g. of wax |
US4844144A (en) * | 1988-08-08 | 1989-07-04 | Desoto, Inc. | Investment casting utilizing patterns produced by stereolithography |
EP0420614A2 (en) * | 1989-09-29 | 1991-04-03 | 3D Systems, Inc. | Methods of coating stereolithographic parts |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CH642877A5 (en) * | 1979-11-28 | 1984-05-15 | Zuercher Kantonalbank | Method for the production of a model of an object |
JPS6021174A (en) * | 1983-07-15 | 1985-02-02 | Toyota Motor Corp | Production of bottomed hollow body |
FR2567668B1 (en) * | 1984-07-16 | 1987-10-16 | Cilas Alcatel | DEVICE FOR PRODUCING AN INDUSTRIAL PART MODEL |
US4575330A (en) * | 1984-08-08 | 1986-03-11 | Uvp, Inc. | Apparatus for production of three-dimensional objects by stereolithography |
US4929402A (en) * | 1984-08-08 | 1990-05-29 | 3D Systems, Inc. | Method for production of three-dimensional objects by stereolithography |
JP2930354B2 (en) * | 1989-09-11 | 1999-08-03 | 三菱重工業株式会社 | Casting method using photocurable resin prototype |
JPH03182312A (en) * | 1989-12-12 | 1991-08-08 | Sekisui Chem Co Ltd | Manufacture of mold |
-
1991
- 1991-10-12 DE DE4133923A patent/DE4133923A1/en not_active Withdrawn
-
1992
- 1992-06-25 DE DE59205668T patent/DE59205668D1/en not_active Expired - Fee Related
- 1992-06-25 EP EP92110719A patent/EP0537417B1/en not_active Expired - Lifetime
- 1992-07-28 JP JP04242510A patent/JP3124387B2/en not_active Expired - Fee Related
- 1992-08-07 US US07/927,126 patent/US5277241A/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR1337560A (en) * | 1962-09-10 | 1963-09-13 | Howe Sound Co | Molding process, and device for implementing the same |
FR2479044A1 (en) * | 1980-03-26 | 1981-10-02 | Rozier Guy | Cores for high precision metal casting by lost wax process - made from stable polyurethane or epoxy! resin foam, opt. with central insert e.g. of wax |
US4844144A (en) * | 1988-08-08 | 1989-07-04 | Desoto, Inc. | Investment casting utilizing patterns produced by stereolithography |
EP0420614A2 (en) * | 1989-09-29 | 1991-04-03 | 3D Systems, Inc. | Methods of coating stereolithographic parts |
Also Published As
Publication number | Publication date |
---|---|
JP3124387B2 (en) | 2001-01-15 |
DE59205668D1 (en) | 1996-04-18 |
JPH05200483A (en) | 1993-08-10 |
DE4133923A1 (en) | 1993-04-15 |
US5277241A (en) | 1994-01-11 |
EP0537417B1 (en) | 1996-03-13 |
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