CN103654976A - Process for fusing illumination composite epoxy resin on surface of inner dental crown body and structure thereof - Google Patents
Process for fusing illumination composite epoxy resin on surface of inner dental crown body and structure thereof Download PDFInfo
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- CN103654976A CN103654976A CN201310397568.7A CN201310397568A CN103654976A CN 103654976 A CN103654976 A CN 103654976A CN 201310397568 A CN201310397568 A CN 201310397568A CN 103654976 A CN103654976 A CN 103654976A
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- 239000002131 composite material Substances 0.000 title claims abstract description 85
- 239000003822 epoxy resin Substances 0.000 title claims abstract description 85
- 229920000647 polyepoxide Polymers 0.000 title claims abstract description 85
- 238000000034 method Methods 0.000 title claims abstract description 70
- 238000005286 illumination Methods 0.000 title claims description 84
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 120
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims abstract description 31
- 229910052573 porcelain Inorganic materials 0.000 claims abstract description 30
- 239000011248 coating agent Substances 0.000 claims abstract description 29
- 238000000576 coating method Methods 0.000 claims abstract description 29
- 239000007769 metal material Substances 0.000 claims abstract description 23
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 21
- 238000012986 modification Methods 0.000 claims description 111
- 230000004048 modification Effects 0.000 claims description 111
- 230000003287 optical effect Effects 0.000 claims description 40
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 24
- SWELZOZIOHGSPA-UHFFFAOYSA-N palladium silver Chemical compound [Pd].[Ag] SWELZOZIOHGSPA-UHFFFAOYSA-N 0.000 claims description 24
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 19
- 239000010931 gold Substances 0.000 claims description 19
- 229910052737 gold Inorganic materials 0.000 claims description 19
- 230000004927 fusion Effects 0.000 claims description 14
- 238000006116 polymerization reaction Methods 0.000 claims description 14
- 239000000843 powder Substances 0.000 claims description 13
- 210000003298 dental enamel Anatomy 0.000 claims description 12
- 235000013312 flour Nutrition 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 239000000377 silicon dioxide Substances 0.000 claims description 12
- 239000000919 ceramic Substances 0.000 claims description 11
- 208000034189 Sclerosis Diseases 0.000 claims description 10
- 229910001252 Pd alloy Inorganic materials 0.000 claims description 9
- CSCPPACGZOOCGX-UHFFFAOYSA-N acetone Substances CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 9
- 238000012216 screening Methods 0.000 claims description 9
- SHPBBNULESVQRH-UHFFFAOYSA-N [O-2].[O-2].[Ti+4].[Zr+4] Chemical compound [O-2].[O-2].[Ti+4].[Zr+4] SHPBBNULESVQRH-UHFFFAOYSA-N 0.000 claims description 7
- 229960002663 thioctic acid Drugs 0.000 claims description 7
- 238000005422 blasting Methods 0.000 claims description 6
- 238000013461 design Methods 0.000 claims description 6
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical group [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 6
- 229910001120 nichrome Inorganic materials 0.000 claims description 5
- 238000012545 processing Methods 0.000 claims description 5
- 229910052809 inorganic oxide Inorganic materials 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 238000005498 polishing Methods 0.000 claims description 3
- 238000004018 waxing Methods 0.000 claims description 3
- 238000010422 painting Methods 0.000 claims description 2
- 238000010304 firing Methods 0.000 claims 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 238000004381 surface treatment Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 134
- 238000005516 engineering process Methods 0.000 description 13
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 238000010586 diagram Methods 0.000 description 5
- 229910010293 ceramic material Inorganic materials 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 238000005728 strengthening Methods 0.000 description 3
- 230000003746 surface roughness Effects 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 230000005540 biological transmission Effects 0.000 description 2
- 238000004512 die casting Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- AGBQKNBQESQNJD-SSDOTTSWSA-N (R)-lipoic acid Chemical compound OC(=O)CCCC[C@@H]1CCSS1 AGBQKNBQESQNJD-SSDOTTSWSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- AGBQKNBQESQNJD-UHFFFAOYSA-N alpha-Lipoic acid Natural products OC(=O)CCCCC1CCSS1 AGBQKNBQESQNJD-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000805 composite resin Substances 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 239000011351 dental ceramic Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 235000019136 lipoic acid Nutrition 0.000 description 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- 229910001947 lithium oxide Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- NJPPVKZQTLUDBO-UHFFFAOYSA-N novaluron Chemical compound C1=C(Cl)C(OC(F)(F)C(OC(F)(F)F)F)=CC=C1NC(=O)NC(=O)C1=C(F)C=CC=C1F NJPPVKZQTLUDBO-UHFFFAOYSA-N 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- -1 siloxanes Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
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- Dental Preparations (AREA)
- Dental Prosthetics (AREA)
Abstract
The present invention provides a process for preparing light-irradiated composite epoxy resin by fusion-bonding on the surface of inner layer crown body and its structure, and is characterized by that it uses zirconium dioxide material or metal material for making porcelain tooth to make the surface of inner layer crown body undergo the processes of surface treatment and automatic grinding (or form stacking), and mainly coats modifying agent on the inner layer crown body to make the surface of inner layer crown body be roughened, and utilizes the scanning operation to input the pattern into computer numerical control machine to make automatic grinding into outer layer crown body, and utilizes the coating and fusion-bonding of light-irradiated composite epoxy resin to obtain firm and durable crown body structure.
Description
Technical field
The present invention relates to a kind of technique and structure thereof of dentistry prosthesis, particularly a kind ofly take zirconium dioxide material or burn the surface that metal material that attached porcelain tooth uses is internal layer corona body and utilize the technology such as physics speciality, theory of mechanics or chemical method in conjunction with technique and the structure thereof of illumination composite epoxy resin.
Background technology
Artificial tooth be include from bottom to top formed plant tooth body and corona body; And the patchery technology of current corona body roughly has several as follows:
1. utilize metal to burn the patchery technology of attached porcelain powder; 2. utilize the metal surface granule patchery technology of mechanical bond composite resin again; 3. with zirconium dioxide, burn the patchery technology of attached porcelain powder; By aluminium oxide after heating, dissolving, die casting, then the patchery technology of adhering on zirconium dioxide; By lithium oxide after heating, dissolving, die casting, then the patchery technology of adhering on zirconium dioxide.
Yet, utilize the patchery technology of above-mentioned corona body, break and only can use appropriate patchery body to repair in corona surface, and described patchery body is to have the problem on service time to exist, its main cause is, described tooth body, corona body and the patchery body of planting is to have strong structure, and unlike natural tooth, having tissue can absorption pressure, therefore, when planting the pressure producing when tooth body and natural tooth are chewed interlock and clash into, cannot be planted tooth body to absorb, planting under the long-term mutual interlock of tooth body and natural tooth, can cause patchery body damaged.
In addition, the patchery technology of aforementioned corona body stays in all the time burns attached making and stays with adhesion heap, also cannot allow zirconium dioxide material surface in conjunction with illumination composite epoxy resin, and all cannot effectively alleviate and plant between tooth body and natural tooth interlock mutually and collide the pressure producing.
Existing is to alleviate to plant the pressure that between tooth body and natural tooth, interlock collision produces mutually, is to utilize the following step:
Therefore, after completing above-mentioned steps, begin in corona surface with illumination composite epoxy resin, set up outer corona body, and irradiate with longwave optical, make outer corona body sclerosis, therefore, from the above, existing is to alleviate to plant the pressure that between tooth body and natural tooth, interlock collision produces mutually, must be in corona surface fusion modification agent repeatedly, just must be combined with corona surface in order to illumination composite epoxy resin, and further on illumination composite epoxy resin, form outer corona body, the pressure producing while making to plant tooth body and natural tooth interlock shock is utilized illumination composite epoxy resin to ease off the pressure, only, under the pressure that how can produce when effectively utilizing illumination composite epoxy resin to alleviate to plant tooth body and natural tooth interlock to clash into, simplify numerous and diverse corona surface processing operation, for the important topic of still needing at present and solving.
In addition, generally speaking, full porcelain tooth hat is expensive compared with metal porcelain tooth, therefore, if can apply the manufacturing technology of illumination composite epoxy resin on metal porcelain tooth, the prosthesis of the quality and the intensity that are similar to full ceramic material will be conducive to make at lower cost, the only metal of metal current porcelain tooth and the combination technology between pottery, still cannot allow metal material surface in conjunction with illumination composite epoxy resin, technical merit still rests on to cast so pure mechanicalness combination, its intensity is poor, causes corona body easily with increasing service time, to peel off.
Summary of the invention
Because aforesaid needs the object of the invention is to propose a kind of technique and structure thereof that fuses illumination composite epoxy resin in internal layer corona surface.
A kind of technique of processing fused illumination composite epoxy resin in internal layer corona surface of the present invention, is characterized in that, sequentially includes internal layer corona surface handling procedure and automatic grinding program; Wherein, described internal layer corona surface handling procedure comprises following steps:
And described automatic grinding program package is containing having the following steps:
Step 4, the internal layer corona body of completing steps three is scanned and sets up internal layer corona volume graphic, and design outer corona volume graphic;
Further, the present invention processes the technique of fused illumination composite epoxy resin in internal layer corona surface, it is characterized in that: the illumination composite epoxy resin described in step 5 is to be thick aspect.
In addition, a kind of technique that fuses illumination composite epoxy resin in internal layer corona surface of the present invention, is characterized in that, sequentially includes internal layer corona surface handling procedure and kenel and piles the program of building; Wherein,
Described internal layer corona surface handling procedure comprises following steps:
And described kenel heap is built program package containing having the following steps:
Step 4, in the internal layer corona surface of completing steps three with illumination composite epoxy resin, set up opaque ivory's layer, and irradiate 4～8 minutes with the longwave optical of 1400～2000 nanometers, make the sclerosis of ivory's layer;
Further, the present invention processes the technique of fused illumination composite epoxy resin in internal layer corona surface, it is characterized in that: the outer corona surface of step 6 gained more can be carried out the kenels such as polishing and waxing and be modified.
Further, the present invention processes the technique of fused illumination composite epoxy resin in internal layer corona surface, it is characterized in that: the granular size of described silica flour and titanium dioxide zirconium powder is to be 50～80 μ m, and the granular size of described ceramics is to be 30～70 μ m.
A kind of structure at the fused illumination composite epoxy resin in internal layer corona body material surface of the present invention, is characterized in that, comprising:
One internal layer corona body; One illumination composite epoxy resin layer, described illumination composite epoxy resin layer is connected with described internal layer corona body top; And an outer corona body, described outer corona body is connected with described illumination composite epoxy resin layer top.
Further, the structure of the present invention's fused illumination composite epoxy resin in internal layer corona surface, it is characterized in that, the metal material that the attached porcelain tooth of described burning is used is the palladium-silver of nichrome or cochrome or palladium-silver or silver palladium alloy or tool gold content, wherein, the gold content in the palladium-silver of described tool gold content is 2%～52% or 72%～82%.
A kind of technique that fuses illumination composite epoxy resin in internal layer corona surface of the present invention, is characterized in that, sequentially includes internal layer corona surface and processes and automatic grinding program, and wherein, the program package that process internal layer corona surface contains:
Under step 1, the state with fusion temperature 720 degree～1050 degree, the internal layer corona surface that the metal material that the attached porcelain tooth of burning is used is made fuses the first modification agent with automatic coating, forms the matsurface of predetermined thickness;
Under step 2, the state with fusion temperature 720 degree～1050 degree, the internal layer corona surface that step 1 is completed to fusion for the first time fuses the second modification agent that contains micron inorganic oxide particles with automatic coating, form the matsurface of predetermined thickness;
Described automatic grinding program package is containing having the following steps:
Step 4, the internal layer corona body of completing steps three is carried out to scanner uni set up internal layer corona volume graphic, and design outer corona volume graphic;
Further, the present invention's fused illumination composite epoxy resin in internal layer corona surface technique, it is characterized in that, the metal material that the attached porcelain tooth of described burning is used is nichrome or cochrome or palladium-silver or silver palladium alloy.
Further, the present invention's fused illumination composite epoxy resin in internal layer corona surface technique, it is characterized in that, the metal material that the attached porcelain tooth of described burning is used is the palladium-silver of tool gold content or the silver palladium alloy of tool gold content, wherein, the gold content in the silver palladium alloy of the palladium-silver of described tool gold content or described tool gold content is 2%～82%.
Further, the present invention burn in internal layer corona surface fused illumination composite epoxy resin technique, it is characterized in that, described the first modification agent is screening agent, described the second modification agent is silica flour or zirconia powder or ceramics.
Further, the present invention's fused illumination composite epoxy resin in internal layer corona surface technique, it is characterized in that, the granular size of described silica flour or zirconia powder is 20 μ m～80 μ m, the granular size of described ceramics is to be 30～70 μ m.
Technique and the structure thereof of the aforementioned the present invention of mat fused illumination composite epoxy resin in internal layer corona surface, mainly can reach effect as described below: 1. significantly shorten the time that process internal layer corona surface, and can effectively extend and plant tooth body service life.2. strengthen internal layer corona body and the fused degree that is coated with the outer corona body of illumination composite epoxy resin; Material behavior by composite epoxy resin.
Below in conjunction with the drawings and specific embodiments, describe the present invention, but not as a limitation of the invention.
Accompanying drawing explanation
Fig. 1: for zirconium dioxide material surface or burn the structural representation of the fused illumination composite epoxy resin of metal material surface that attached porcelain tooth uses;
Fig. 2: be the flow chart of the first embodiment of the technique of the fused illumination composite epoxy resin of zirconium dioxide material surface;
Fig. 3: be the flow chart of the second embodiment of the technique of the fused illumination composite epoxy resin of zirconium dioxide material surface;
Fig. 4: be the internal layer corona surface handling procedure schematic diagram of the first embodiment of the technique of the fused illumination composite epoxy resin of zirconium dioxide material surface;
Fig. 5: be the automatic grinding program schematic diagram of the first embodiment of the technique of the fused illumination composite epoxy resin of zirconium dioxide material surface;
Fig. 6: for the kenel heap of the second embodiment of the technique of the fused illumination composite epoxy resin of zirconium dioxide material surface is built program schematic diagram
Fig. 7: for burning the flow chart of the technique of the fused illumination composite epoxy resin of metal material surface that attached porcelain tooth uses;
Fig. 8: for burning the schematic diagram of internal layer corona surface handling procedure of the technique of the fused illumination composite epoxy resin of metal material surface that attached porcelain tooth uses;
Fig. 9: for burning the automatic grinding program schematic diagram of the technique of the fused illumination composite epoxy resin of metal material surface that attached porcelain tooth uses.
Wherein, Reference numeral
The specific embodiment
Refer to and further understand feature of the present invention and technology contents about detailed description of the present invention and accompanying drawing below, however appended accompanying drawing only provide with reference to and explanation use, be not used for the present invention to be limited.
A kind of corona body structure of the present invention L, as shown in Figure 1, it comprises zirconium dioxide material or burns the internal layer corona body L1 that metal material that attached porcelain tooth uses is made, one illumination composite epoxy resin layer L2 and an outer corona body L3, wherein, described illumination composite epoxy resin layer L2 is connected with described internal layer corona body L1 top, described outer corona body L3 is connected with described illumination composite epoxy resin layer L2 top, therefore, described corona body structure L be using illumination composite epoxy resin layer L2 as adhesion use interlayer, with in conjunction with described internal layer corona body L1 and described outer corona body L3.
Aforementioned corona body structure L, is made with a kind of technique at the fused illumination composite epoxy resin of zirconium dioxide material surface, and as shown in Figure 2, described technique is characterised in that and sequentially includes internal layer corona surface handling procedure 1 and automatic grinding program 2.
Through as shown in Figure 2; First embodiment of the invention sequentially includes internal layer corona surface handling procedure 1 and automatic grinding program 2.
Continue and refer to Fig. 4; Described internal layer corona surface handling procedure 1 is to comprise following steps:
The continuous Fig. 5 that refers to again; The automatic grinding program 2 of first embodiment of the invention is the abovementioned steps three that continues, consist predominantly of following steps: step 4, the internal layer corona body 40 of completing steps three is scanned to S1 and sets up figure S2 operation, to set up internal layer corona volume graphic 40A, and design outer corona volume graphic 41A.
Therefore, from the above, first embodiment of the invention is by simply coating fusion on internal layer corona body 40, the aforesaid modification agent of illumination, use the surface roughness that increases zirconium dioxide material (being internal layer corona body 40), the fused degree of the illumination composite epoxy resin on strengthening internal layer corona body 40 and outer corona body 41 inner concaves 410, effectively alleviate and plant the pressure that between tooth body and natural tooth, interlock collision produces mutually, therefore the present invention can be had, significantly shorten the time that process internal layer corona surface, and can effectively extend and plant tooth body service life.
Refer to Fig. 3, second embodiment of the invention is similar to the first embodiment haply, its Main Differences is, second embodiment of the invention is that the kenel heap that can continue after the step 3 of internal layer corona surface handling procedure 1 is built program 3, and described kenel heap build program 3 hold after explanations.
The continuous Fig. 6 that refers to; The kenel heap of the described abovementioned steps three that continues is built program 3 and is consisted predominantly of following steps: step 4, on internal layer corona body 40 surfaces of completing steps three with illumination composite epoxy resin, set up opaque ivory's layer 410 ', and irradiate 4～8 minutes with the longwave optical of 1400～2000 nanometers, make the 410 ' sclerosis of ivory's layer.
Therefore, second embodiment of the invention is as the first embodiment, by simply coating fusion on internal layer corona body 40, the aforesaid modification agent of illumination, using increase zirconium dioxide material is the surface roughness of internal layer corona body 40, the fused degree of strengthening internal layer corona body 40 and outer corona body 41 ' and illumination composite epoxy resin, can effectively alleviate equally and plant the pressure that between tooth body and natural tooth, interlock collision produces mutually, have equally and significantly shorten the time that process internal layer corona surface, and can effectively extend and plant the tooth body benefit in service life.
In addition, the kenel modifications such as polishing and waxing more can be carried out in the outer corona surface of above-mentioned steps six gained, to increase visual sense.
Be more than the fused technique of illumination composite epoxy resin of zirconium dioxide material surface and the detailed embodiment of structure thereof, below, the fused technique of illumination composite epoxy resin of metal material surface and the detailed embodiment of structure thereof that attached porcelain tooth is used burnt in the explanation that continues.
Please refer to Fig. 7 and Fig. 8, first, internal layer corona surface handling procedure 5 is mainly at internal layer corona body 70 surface coated modification agents, makes internal layer corona body 70 surface roughenings in order to fused with illumination composite epoxy resin; Wherein, internal layer corona surface handling procedure 5 is to include following steps:
Under step 1, the state with fusion temperature 720 degree～1050 degree, internal layer corona body 70 surfaces that the metal material that the attached porcelain tooth of burning is used is made fuse the first modification agent E with automatic coating, the first modification agent E of present embodiment can be dental pottery screening agent, form the matsurface of predetermined thickness, the metal material that the attached porcelain tooth of described burning is used is the palladium-silver of nichrome or cochrome or palladium-silver or silver palladium alloy or tool gold content, wherein, if the palladium-silver of gold content of take is material, its gold content is 2%～52% or 72%～82%;
Under step 2, the state with fusion temperature 720 degree～1050 degree, internal layer corona body 70 surfaces that step 1 completed to fusion for the first time fuse the second modification agent F that contains micron inorganic oxide particles with automatic coating, form the matsurface of predetermined thickness;
The aforementioned flowing mode of doing on internal layer corona body 70 surfaces of different modification agents being coated with automatic coating, obtain and realize in two ways, one, that the mechanical arm being fixedly installed coordinates rotating pedestal, internal layer corona body 50 is carried out to automatic coating, its two, be, with mechanical arm that can free operant, internal layer corona body 70 is carried out to automatic coating.
Continuing, please refer to Fig. 7 and Fig. 9, automatic grinding program 6 is that subsequent steps three is set up figure with CAD/CAM and produces by the metal porcelain tooth of illumination composite epoxy resin and outer corona body 71 combinations, automatic grinding program 6 comprises the following steps: step 4, the internal layer corona body 30a of completing steps three is scanned to S5 and set up figure S6 operation according to internal layer corona body 70a profile by CAD/CAM system, to set up internal layer corona volume graphic 70b, and design outer corona volume graphic 71a;
In sum, by being simply coated with and fusing on internal layer corona body, illumination modification agent, use the surface roughness (or the internal layer corona surface that makes to burn the metal material technique that attached porcelain tooth uses produces unlikely too thick roughness) of the internal layer corona body that increases zirconium dioxide material, the fused degree of strengthening corona body and illumination composite epoxy resin, and the time that process internal layer corona surface significantly shortens, and, the material behavior of composite epoxy resin can effectively alleviate the decompression power that between tooth body (being corona body structure L) and natural tooth, interlock collision produces mutually of planting, effectively extend and plant tooth body service life.
Certainly; the present invention also can have other various embodiments; in the situation that not deviating from spirit of the present invention and essence thereof; those of ordinary skill in the art are when making according to the present invention various corresponding changes and distortion, but these corresponding changes and distortion all should belong to the protection domain of the appended claim of the present invention.
Claims (15)
1. in internal layer corona surface, process the technique of fused illumination composite epoxy resin, it is characterized in that, sequentially include internal layer corona surface handling procedure and automatic grinding program; Wherein,
Described internal layer corona surface handling procedure comprises following steps:
Step 1, internal layer corona surface is coated with to the first modification agent, after the first modification agent has been coated with, then on the first modification agent, be coated with the second modification agent, with the temperature of 720～1050 ℃, make the first modification agent and the second modification agent be fused to internal layer corona surface again, form the matsurface of 2.5～3.5 millimeters, wherein, described the first modification agent is screening agent, and the second modification agent is silica flour or titanium dioxide zirconium powder or ceramics;
Step 2, with light, play the internal layer corona surface that modification agent is coated completing steps one, and with the longwave optical of 1400～2000 nanometers, irradiate the light of coating internal layer corona surface and play modification agent and react, wherein, to play modification agent be to be ethanol-siloxanes-acetone mixture 35～45%:5～25%:40～60% to described light;
Step 3, with photaesthesia modification agent, coat the internal layer corona surface of completing steps two, and with the longwave optical of 1600～2000 nanometers, irradiate the photaesthesia modification agent of coating internal layer corona surface and react, wherein, described photaesthesia modification agent is phosphorous acid-polymerization single polymerization monomer-thioctic acid body mixture 30～40%:15～35%:35～40%;
And described automatic grinding program package is containing having the following steps:
Step 4, the internal layer corona body of completing steps three is scanned and sets up internal layer corona volume graphic, and design outer corona volume graphic;
Step 5, by the designed outer corona volume graphic of step 4, with autogenous mill, grind out the outer corona body of corresponding internal layer corona surface, forming below is the outer corona body of inner concave, then below outer corona body, inner concave carries out blasting treatment, and is sequentially coated with lighting again and plays modification agent and illumination composite epoxy resin;
Step 6, the internal layer corona body of the outer corona body of completing steps five and completing steps three is carried out bonding, and irradiate 10 minutes twice with the longwave optical of 1400～2000 nanometers.
2. the technique of processing fused illumination composite epoxy resin in internal layer corona surface according to claim 1, is characterized in that: the illumination composite epoxy resin described in step 5 is thick aspect.
3. the technique that fuses illumination composite epoxy resin in internal layer corona surface according to claim 1, is characterized in that, sequentially includes internal layer corona surface handling procedure and kenel and piles the program of building; Wherein,
Described internal layer corona surface handling procedure comprises following steps:
Step 1, first internal layer corona surface is coated with to the first modification agent, after the first modification agent has been coated with, then on the first modification agent, be coated with the second modification agent, with the temperature of 720～1050 ℃, make the first modification agent and the second modification agent be fused to internal layer corona surface again, form the matsurface of 2.5～3.5 millimeters, wherein, described the first modification agent is screening agent, and the second modification agent is silica flour or titanium dioxide zirconium powder or ceramics;
Step 2, with light, play the internal layer corona surface that modification agent is coated completing steps one, and with the longwave optical of 1400～2000 nanometers, irradiate the light of coating internal layer corona surface and play modification agent and react, wherein, to play modification agent be ethanol-siloxanes-acetone mixture 35～45%:5～25%:40～60% to described light;
Step 3, with photaesthesia modification agent, coat the internal layer corona surface of completing steps two, and with the longwave optical of 1600～2000 nanometers, irradiate the photaesthesia modification agent of coating internal layer corona surface and react, wherein, described photaesthesia modification agent is phosphorous acid-polymerization single polymerization monomer-thioctic acid body mixture 30～40%:15～35%:35～40%;
And described kenel heap is built program package containing having the following steps:
Step 4, in the internal layer corona surface of completing steps three with illumination composite epoxy resin, set up opaque ivory's layer, and irradiate 4～8 minutes with the longwave optical of 1400～2000 nanometers, make the sclerosis of ivory's layer;
Step 5, on ivory's layer surface of completing steps four, set up translucent enamel layer, and irradiate 4～8 minutes with the longwave optical of 1400～2000 nanometers, make the sclerosis of enamel layer;
Step 6, on the enamel layer surface of completing steps five, set up clear layer, and irradiate 7～10 minutes with the longwave optical of 1400～2000 nanometers, make clear layer sclerosis, use and make ivory's layer, enamel layer and clear layer form outer corona body.
4. the technique of processing fused illumination composite epoxy resin in internal layer corona surface according to claim 3, is characterized in that: the outer corona surface of step 6 gained more carries out polishing and waxing kenel is modified.
5. according to the technique at the fused illumination composite epoxy resin of internal layer corona surface processing described in claim 1 or 3, it is characterized in that: the granular size of described silica flour and titanium dioxide zirconium powder is 50～80 μ m, the granular size of described ceramics is 30～70 μ m.
6. a structure for fused illumination composite epoxy resin in internal layer corona surface, is characterized in that, comprising: an internal layer corona body;
One illumination composite epoxy resin layer, described illumination composite epoxy resin layer is connected with described internal layer corona body top; And an outer corona body, described outer corona body is connected with described illumination composite epoxy resin layer top.
According to claim 6 in internal layer corona surface fused illumination composite epoxy resin structure, it is characterized in that, described internal layer corona body is the internal layer corona body that a zirconium dioxide material is made.
According to claim 6 in internal layer corona surface fused illumination composite epoxy resin structure, it is characterized in that, described internal layer corona body is the internal layer corona body that metal material that the attached porcelain tooth of single firing is used is made.
According to claim 8 in internal layer corona surface fused illumination composite epoxy resin structure, it is characterized in that, the metal material that the attached porcelain tooth of described burning is used is the palladium-silver of nichrome or cochrome or palladium-silver or silver palladium alloy or tool gold content, wherein, the gold content in the palladium-silver of described tool gold content is 2%～52% or 72%～82%.
10. a technique for fused illumination composite epoxy resin in internal layer corona surface, is characterized in that, sequentially include internal layer corona surface and process and automatic grinding program, wherein,
The program package that process internal layer corona surface contains:
Under step 1, the state with fusion temperature 720 degree～1050 degree, the internal layer corona surface that the metal material that the attached porcelain tooth of burning is used is made fuses the first modification agent with automatic coating, forms the matsurface of predetermined thickness;
Under step 2, the state with fusion temperature 720 degree～1050 degree, the internal layer corona surface that step 1 is completed to fusion for the first time fuses the second modification agent that contains micron inorganic oxide particles with automatic coating, form the matsurface of predetermined thickness;
Step 3, with automatic coating, photaesthesia modification agent is coated to the internal layer corona surface of completing steps two, and with the first longwave optical, irradiate the photaesthesia modification agent coat internal layer corona surface and react, the wave-length coverage of the first longwave optical is 1600～2500 nanometers;
Described automatic grinding program package is containing having the following steps:
Step 4, the internal layer corona body of completing steps three is carried out to scanner uni set up internal layer corona volume graphic, and design outer corona volume graphic;
Step 5, by the designed outer corona volume graphic of step 4, with computer numerical, control the outer corona body that board automatic grinding goes out corresponding internal layer corona surface, forming below is the outer corona body of concave surface, then the inner concave below outer corona body carries out blasting treatment, and sequentially with automatic coating painting lighting, play modification agent and the inner concave of illumination composite epoxy resin below outer corona body again, and with the first longwave optical irradiation light, play modification agent and react, the wave-length coverage of the first longwave optical is 1400～2000 nanometers;
Step 6, the internal layer corona body of the outer corona body of completing steps five and completing steps three is carried out bonding, and irradiate 10 minutes twice with the longwave optical of 1400～2000 nanometers.
11. techniques that fuse illumination composite epoxy resin in internal layer corona surface according to claim 10, is characterized in that, the metal material that the attached porcelain tooth of described burning is used is nichrome or cochrome or palladium-silver or silver palladium alloy.
The technique of the fused illumination composite epoxy resin of metal material surface that the attached porcelain tooth of 12. burning according to claim 10 is used, it is characterized in that, the metal material that the attached porcelain tooth of described burning is used is the palladium-silver of tool gold content or the silver palladium alloy of tool gold content, wherein, the gold content in the silver palladium alloy of the palladium-silver of described tool gold content or described tool gold content is 2%～82%.
13. techniques that fuse illumination composite epoxy resin in internal layer corona surface according to claim 10, is characterized in that, described the first modification agent is screening agent, and described the second modification agent is silica flour or zirconia powder or ceramics.
14. techniques that fuse illumination composite epoxy resin in internal layer corona surface according to claim 13, is characterized in that, the granular size of described silica flour or zirconia powder is 20 μ m～80 μ m, and the granular size of described ceramics is 30～70 μ m.
15. according to claim 10 in internal layer corona surface fused illumination composite epoxy resin technique, it is characterized in that, described internal layer corona body is the internal layer corona body that metal material that the attached porcelain tooth of single firing is used is made.
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| Application Number | Priority Date | Filing Date | Title |
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| DE102012108202.2A DE102012108202B4 (en) | 2012-09-04 | 2012-09-04 | A method of fusing a photocurable epoxy composite to a zirconia material surface |
| DE102012108202.2 | 2012-09-04 | ||
| TW102118685 | 2013-05-27 | ||
| TW102118685A TWI546081B (en) | 2013-05-27 | 2013-05-27 | The Process and Structure of Solvent Composite Epoxy Resin on the Surface of Metallic Materials |
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