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3,935,364 A 1/1976 Prokesh et al. 3,970,628 A 7/1976 Connelly et al. 4,015,040 A 3/1977 Hoshida et al. 4,028,294 A 6/1977 Brown et al. 4,113,893 A 9/1978 Hahn 4,132,526 A 1/1979 Schwarz et al. 4,197,389 A * 4/1980 Becker et al. ............... .. 523/420 4,211,848 A 7/1980 Blount 4,228,761 A 10/1980 Glover et al. 4,333,867 A 6/1982 Sauntson 4,385,152 A 5/1983 Boyack et al. 4,390,688 A 6/1983 Walz et al. 4,408,018 A 10/1983 Bartman et al. 4,486,553 A * 12/1984 Wesch ........................ .. 523/179 4,522,962 A 6/1985 Abbey et al. 4,536,534 A 8/1985 Singer et al. 4,582,755 A 4/1986 Dietrich 4,598,108 A * 7/1986 Hoefs ......................... .. 523/411 4,719,149 A 1/1988 Aasen et al. 4,742,121 A 5/1988 Tornan 4,852,316 A 8/1989 Webb 4,880,660 A 11/1989 Aasen et al. 4,886,852 A 12/1989 Numa 4,904,522 A 2/1990 Markusch 4,908,229 A 3/1990 Kissel 4,916,004 A 4/1990 Ensminger et al. 5,017,632 A 5/1991 Bredow et al. 5,073,578 A 12/1991 Boodaghains et al. 5,075,370 A 12/1991 Kubitza et al. 5,100,948 A 3/1992 Aydin et al. 5,157,074 A 10/1992 Metzger et al. (Continued)
FOREIGN PATENT DOCUMENTS AU 198060655 A1 3/1981 (Continued)
Technical Data for Ancarez AR550 Waterborne Epoxy Resin, provided by Air Products (no date).*
Technical Data for Anquamine 401 Curing Agent, provided by Air Products (no date).*
Technical Data for Polycat 41 Catalyst, provided by Air Products (no date).*
ASTM D6944-03, Test Method A (2003).
Koleske et al., Two Thousand T hreeAdditives Guide, Paint and Coatings Industry, pp. 12-86, (Apr. 2003).
Witzeman, J . S. et al., Comparison of Methods for thePreparation of Acetoacetylated Coating Resins, Coatings Technology; vol. 62, No. 789, pp. 101-112 (Oct. 1990).
American Society of Testing Materials, ASTM Designation: D52389, “Standard Test Method for Specular Gloss;” 5 pages, (Reapproved 1999).
American Society ofTesting Materials, ASTM Designation: D540293, “Standard Practice for Assessing the Solvent Resistance of Organic Coatings Using Solvent Rubs;” 3 pages, (Reapproved 1999). Eastman Chemical Company, Publications N-319C, Kingport, TN., Title Page, Table of Contents, “Acetoacetoxyethyl Met11acrylate (AAEM) Acetoacetyl Chemistry,” pp. 1-11, (Dec. 1999).
Primary Examiner - Michael J Feely (74) Attorney, Agent, or Firm - IPLM Group, P.A.
A coated article and method of employing a water-based coating composition on a fiber cement composite substrate is provided. The coating composition contains: an epoxy resin, a crosslinker having epoxide-reactive functional groups, a latex polymer distinct from the epoxy resin, and water.
36 Claims, 1 Drawing Sheet
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Page2 U.S. PATENT DOCUMENTS 7,049,352 B2 5/2006 Gould et al. 5,191,012 A 3/1993 Markusch etal. Zfigéggé 5% 35882 ]§d1‘”ardSett‘;1_1' 5,212,230 A 5/1993 Tirpak etal. 7’l48’270 B2 12/2006 B0 Omone ' 5,221,710 A 6/1993 Markuschetal. ’ ’ Owe 5,236,994 A 8/1993 Markuschetal‘ 7,235,595 B2 6/2007 Hermes etal. 5,296,530 A 3/1994 Borsetalt 7,235,603 B2 6/2007 Madleetal. 5,356,716 A 10/1994 Patel E; [[5883 garggnnlila et1a1' 5,407,783 A 4/1995 Caruso ’ ’ Ver ee eta‘ 5,409,984 A 4/1995 Gerhardinger Zgggégg 5%,. Z588; gebhard et 31' 5,418,264 A 5/1995 Obloh etal. ................ .. 523/414 ’ ’ mSSeta1' """"""""" " 523/404 5,426,142 A 6/1995 Rosano etal. Z’ZZT’Zfi 5% $5882 ge'rem't’1‘°“1ureta1' , , a ere a. g4;'g§1§4§1§gA5‘ A 1%??? E“ etal . 7,758,954 B2 7/2010 Ngtiyen etal. 4 4 Chmalstleg eta1~ 2002/0009622 A1 1/2002 G d 5478 601 A 12/1995 Larson etal. 00 Son 544844849 A 1/1996 Borsetal 2002/0179240 A1 12/2002 Clemens etal. 545004457 A 3/1996 Sarkaretél 2002/0195191A1 12/2002 Weissetal. 545344310 A 7/1996 Rokowskiétal 2003/0055171 A1 3/2003 Overbeeketal. 525593192 A 9/1996 Borsetal‘ ~ 2003/0073778 A1 4/2003 zhangetal. 5,562,953 A 10/1996 Borsetalt 2003/0089061 A1 5/2003 DeFordetal. 5 567 767 A 10/1996 Smealetal 2003/0150359 A1 8/2003 Lassrnann 545714863 A U/1996 Smealetd 2003/0153673 A1 8/2003 schwalrnetal. 536723379 A 9/1997 schalletal. gggggggfigi 2} F5588; izhétnnan et 31' C ee A F5133; ]§'e°k.enhauer 2003/0224184 A1 12/2003 Hermesetal. , , che1belhoffer et al. 5708 077 A 1/1998 Nélken etal 2004/0002559 A1 1/2004 Troutman etal. 537083093 A 1/1998 Bastelbergeretal. §88j[88ggg?2 2} 3588: al Z4ZéE422Z A $332 2“ et.a1' 2004/0086676 A1 5/2004 Peng 4 4 ummlngs 6‘ a1~ ~~~~~~~~~ ~~ 428/418 2004/0161542 A1 8/2004 z‘ t 1 547774053 A 7/1998 M°B"in eta1~ 2004/0176502 A1 9/2004 Rireyilrradlrideetaal g4;?§4‘3'g§ A gfiggg émoil eta1' 2004/0198903 A1 10/2004 Madle etal. 4 4 agllosm’ eta1' 2004/0229978 A1 11/2004 Bowe 24224232 A Z1333 (S31‘“k.e“‘1~ 2005/0027079 A1 2/2005 Palmer Lauer et al. 4 4 Chelbelhoffer et a1~ 2005/0053797 A1 3/2005 R h tal 549284778 A 7/1999 Takahashi 6‘ a1' 2005/0176321 A1 8/2005 Cildtltg eteal ' 24322429‘? A @1333 g:‘;*l1)1e‘§k"i~ta1 2005/0203211 A1 9/2005 Gebhard 549734068 A 10/1999 Yamayaetal ~ 2005/0208285 A1 9/2005 Lyons etal. 549944428 A U/1999 Lutzetal‘ ~ 2006/0013950 A1 1/2006 Porteretal. 549974952 A 12/1999 Hmisetal 2006/0024480 A1 2/2006 Lyons et al. 640074619 A 12/1999 Laaset A ~ 2006/0046068 A1 3/2006 Bara_ncyketal. 6,008,289 A 12/1999 Konig etal 2006/0048708 A1 3/2006 Hamg 640304447 A 2/2000 Najietal ~ 2006/0111503 A1* 5/2006 Killileaetal. .............. .. 524/501 640454871 A 4/2000 Mamtai 2006/0135684 A1 6/2006 Killilea 640454873 A 4/2000 Adachietm 2006/0135686 A1 6/2006 Kilileaetal. 640484471 A 4/2000 Henry ~ 2006/0182946 A1 8/2006 Zarbetal. 640634864 A 5/2000 Mathuretal 2006/0288909 A1 12/2006 Najletal. 641034352 A 8/2000 Takahashi ~ 2007/0042192 A1* 2/2007 Nguyen etal. .............. .. 428/420 641144440 A 9/2000 Yamayaetal 2007/0110981 A1 5/2007 Killileaetal. 6’l36’383 A 10/2000 SchWartZeta'l 2007/0149077 A1 6/2007 Stanislawczyketal. 641464710 A 1 H2000 Symons ~ 2007/0213445 A1 9/2007 Klijnetal. 641624511 A 12/2000 Gamettetal 2007/0259166 A1 11/2007 Killileaetal. 642354228 B1 5/2001 NiChO11eta1' 2007/0259188 A1 11/2007 Wu etal. 642974320 B1 10/2001 Tang etal ' 2007/0269660 A1 11/2007 Killilea etal. 633463146 B1 2/2002 Duselis at‘ 31' 2007/0282046 A1 12/2007 Killilea etal. 6,395,827 B1 5/2002 Pemetalt 2008/0008895 A1* 1/2008 Garneretal. ............... .. 428/500 6,426,414 B1 7/2002 Laasetal‘ 2008/0139737 A1 6/2008 Alderferetal. 6,458,250 BI I0/2002 Hollidayetal‘ 2008/0141908 A1 6/2008 Peng etal. 6,475,556 B1 11/2002 Sobczak etal. ............. .. 427/137 6,485,601 B1 U/2002 Egan et al‘ FOREIGN PATENT DOCUMENTS 6,485,793 B1 11/2002 ott etal. AU 2005100347 B4 5/2005 6,492,450 B1 12/2002 Hsu DE 33 02 767 A1 8/1984 6,506,248 B1 1/2003 Duselisetal. EP 0060505 A1 9/1982 6,534,176 B2 3/2003 Terase etal. EP 0486278 A1 5/1992 6,555,625 B1 4/2003 Overbeek etal. EP 0623 659 A2 11/1994 6,590,025 B1 7/2003 Carlson etal. EP 0697 417 A1 2/1996 6,635,735 B1 10/2003 Zhang etal. EP 0705 855 A2 4/1996 6,638,567 B1 10/2003 Beisele EP 0728 779 B2 8/1996 6,641,629 B2 11/2003 Safta etal. EP 0894780 A1 2/1999 6,649,679 B1 11/2003 stockletal. EP 1454 935 A1 9/2004 6,660,386 B2 12/2003 Haque EP 1473 331 A1 11/2004 6,696,518 B1 2/2004 Dersch etal. EP 1589 083 A2 10/2005 6,740,423 B2 5/2004 Murase EP 1650 045 A2 4/2006 6,753,394 B2 6/2004 Weikard etal. EP 1798 258 A1 6/2007 6,762,230 B2 7/2004 Brandenburgeretal. GB 1407 827 9/1975 6,818,697 B2 11/2004 Zhang etal. JP 2005307161 4/2005 6,849,338 B2 2/2005 Clemens et al. su 833892 5/1981 6,893,751 B2 5/2005 Najietal. wo wo 94/07674 A1 4/1994 6,941,720 B2 9/2005 DeFord etal. wo wo 98/45222 10/1998 6,998,012 B2 2/2006 Koellikeretal. wo wo 99/67312 12/1999
WO WO 00/23495 A1 4/2000 WO WO 00/56826 9/2000 WO WO 01/68547 A1 9/2001 WO WO 02/070623 A2 9/2002 WO WO 03/000761 A1 1/2003 WO WO 03/076536 A1 9/2003 WO WO 03/101918 A2 12/2003 WO WO 2005/071179 A1 8/2005 WO WO 2006/032512 A 3/2006 WO WO 2006/065914 A1 6/2006 WO WO 2007/059516 A1 5/2007 WO WO 2007/087458 A1 8/2007 WO WO/2007/089807 A2 8/2007 WO WO 2007/089913 A1 8/2007 WO WO 2007/090132 A1 8/2007 WO WO 2008/018910 A2 2/2008
Lewis et al., “Luminescence”, Hawley’s Condensed Chemical Dictionary, 14”' Ed., John Wiley and Sons, Inc., retrieved from Knovel® online; 1 page (2002).
“Photoinitiators for UV Curing,” “Darocur 1173”, p. 2; Ciba Specialty Chemicals; 8 pages (2003).
U.S. Federal Register, vol. 60, No. 116, pp. 31633-31637, (Jun. 16, 1995).
Wicks, Zeno W. Jr., et al., “Latexes”, Organic Coatings, Science and Technology, Second Edition, (Wiley-Interscience, New York), Title Page, Copyright Page, Chapter 8, p. 143, (1999).
Dow® Z-6018 Intermediate Product Information, “Silicone Intermediates”, 3 pgs., (Aug. 28, 2006).
ISR and Written Opinion for PCTUS/2007/069387 dated Oct. 15, 2007.
Clemens, R. J . et al., A Comparison of Catalysts for Crosslinking Acetoacetylated Resins via the Michael Reaction, Journal of Coatings Technology, Mar. 1989, vol. 61, No. 770, pp. 83-91.
Clemens, R. J ., A Comparison of Catalysts for Crosslinking Acetoacetylated Resins via the Michael Reaction, Water-Borne & Higher Solids Coatings Symposium, 1988, New Orleans, LA, 55-67. Wicks, Z.W. et al., Epoxy and Phenolic Resins, Organic Coatings Science and Technology, vol. 1, Chapter XI, pp. 162-187. Tennebroek et al., New Polymer Synthesis for (self) Crosslinkable Urethanes and Urethane Acrylics, 4”’ Niirnberg Congress; International Centre for Coatings Technology, Paper 17, 2000, 19 pages. Geurts, J .M. et al., Self-crosslinkable Urethanes and Urethane/Acrylics, Verfl<roniek Nummer, Jan. 1999.
Geon® Lo-Sope Dispersion Resin, Geon® 171 Vinyl Chloride Homopolyrner Technical Data Sheet, PolyOne Corporation, May 2003, 2 pages.
Geon Copolymer Dispersion Resin Geon® 137 Vinyl Chloride Copolymer Technical Data Sheet, PolyOne Corporation, Apr. 1997, 2 pages.
Industrial Research Services, TestReportNo. 54 703-1forEpirez Safe Step 100, CSIRO, Manuf. & Infrastr. Technology, Australia, May 2004, pp. 1-6.
DSM NeoResins, Technical Data Sheet, DSM NeoResins Inc.,Bulletin XK-90, Jan. 2006, 6 pages.
Tex'Cote® Stretch Product Information, Textured Coatings of America, Inc., Panama City, Florida, Nov. 2003, 3 pages.
UCAR Emulsion Systems Applications, Architectural Coatings-Exterior-Cement Fiber Board, Dow Chemical Company product information sheet printed on Oct. 25, 2007 from the following internet archives website at: http://web.archive.org/web/20041022123748/ http ://www. dow.com/uc arlatex/app/arch/exifiberhtm.
Rector, F.D. et al., Applicatons for the Acetoacetyl Chemistry in Thermoset Coatings, Journal of Coatings Technology, vol. 61, No. 771, Apr. 1989.
“UV Cured Undercoat Vitrecure 7”, Product Data Sheet 74, Architectural & Industrial Coatings, 1 page (Dec. 21, 2004).
“UV Cured Sealer for Cement Based SubstratesVitrecure 9”, Product Data Sheet 54, Architectural & Industrial Coatings, 1 page (Jul. 24, 2004).
Fox, T. G., “Influence of diluent and of copolymer composition on the glass temperature of a polymer system”, Bull. Am. Phys. Soc. I (3), 123 (1956).
PQ® Potassium Silicates, PQ Corporation Brochure, (2004). HardiplankTM Lap Siding Installation, James Hardie Siding Products, 8 pages, (Dec. 2005), http://wwwjameshardie.com/homeowner/ technical/installation/hardieplankiinstallationphp, downloaded from the Dec. 15, 2005 Internet Archive entry at: http://web.archive. org/web/20051215084041/http://wwwjameshardie.com/ homeowner/installation/hardiplankiinstallation.php.
“Siding Painting Tips”, Paint Manufacturers’ Recommendation Sheet-No. S-100, James Hardie Siding Products, 10 pages, (May 2005), http://www.jameshardie.com/homeowner/technical/ paintingtips.php, downloaded from the Dec. 14, 2005 Internet Archive entry at: http://web.archive.org/web/20051214022056/ http://www.jameshardie.com/homeowner/technical/paintingtips. php.
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