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United States Patent [19] [ii] Patent Number: 4,732,312

Kennedy et al. [45] Date of Patent: Mar. 22, 1988

[54] METHOD FOR DIFFUSION BONDING OF ALLOYS HAVING LOW SOLUBILITY OXIDES

[75] Inventors: James R. Kennedy, Huntington;

Edmund Y. Ting, Oyster Bay, both of
N.Y.

[73] Assignee: Grumman Aerospace Corporation,
Bethpage, N.Y.

[21] Appl. No.: 928,898

[22] Filed: Not. 10,1986

[51] Int. Q.* B23K 20/22; B23K 20/24

[52] U.S. a 228/157; 228/193;

228/203; 228/205; 228/263.17; 228/172;

148/11.5 A

[58] Field of Search 228/157, 193, 118, 265,

228/172, 205, 263.17, 203; 148/11.5 A

[56] References Cited

U.S. PATENT DOCUMENTS

3,041,718 7/1962 Stuchbery 228/115

3,180,022 4/1965 Briggs et al 228/194

3,500,532 3/1970 Lozano et al 228/115

3,552,898 1/1971 Bird .

3,657,801 4/1972 Hershenson 228/194

3,680,197 8/J972 Blum et al. .

3,758,741 9/1973 Holko et al. .

3,815,219 6/1974 Wilson .

3,920,175 11/1975 Hamilton et al 228/193

3,927,817 12/1975 Hamilton-et al 228/193

3,937,387 2/1976 Fletcher et al 228/193

4.025.036 5/1977 Melnyk 228/193

4.087.037 5/1978 Schier et al 228/193

4,117,970 10/1978 Hamilton et al 228/193

4,197,978 4/1980 Kasper 228/193

4,220,276 9/1980 Weisert et al 228/118

4,331,284 5/1982 Schulz et al 228/193

4,361,262 11/1982 Israeli 228/118

4,452,389 6/1984 Amin .

4,483,478 11/1984 Schultz 228/157

4,499,156 2/1985 Smith et al 228/124

FOREIGN PATENT DOCUMENTS

66846 6/1978 Japan 228/193

585937 12/1977 U.S.S.R 228/193

287069 1/1978 U.S.S.R. .

1151404 4/1985 U.S.S.R 228/193

OTHER PUBLICATIONS

"A Review of Diffusion Welding", Gerken and Owe-
zarski, Welding Research Council, Bulletin, 10/65.
R. R. Irving, "Amorphous Metals: The New Metal-
lurgy",-Iron Age, May 11, 1983, pp. 47 to 52.
H. Jones, "The Status of Rapid Solidification of Alloys
in Research and Application", Journal of Materials
Science, 1984, pp. 1043, 1044.

T. D. Byun and P. Yavari, "The Joining of Superplastic
Aluminum for Aircraft Structural Applications", Pro-
ceedings of Int. Conf. Jul. 1985, pp. 285 to 294.
D. V. Dunford and P. G. Partridge, "Shear and Peel
Strengths of Diffusion Bonded Al-Alloys", Int. Conf.
Jul. 1985, pp. 4 to 8, plus following 16 pages.
J. Pilling and N. Ridley, "Solid State Bonding of Super-
plastic AA7475", Materials Science and Technology,
May 1987, vol. 3, pp. 353 to 358.

Primary Examiner—Nicholas P. Godici
Assistant Examiner—Samuel M. Heinrich
Attorney, Agent, or Firm—Richard G. Geib; Daniel J.
Tick; David Aker

[blocks in formation]

Diffusion bonding of surface layers of an alloy, such as an aluminum alloy, having surface oxides of low solubility in the alloy includes treating the surface layers to be bonded to remove existing surface oxide coatings, and diffusion bonding the surface layers to one another by placing the alloy to be bonded under sufficient pressure to cause disruption of the oxide coatings by localized surface deformation of the alloy, enhanced by a superplastic microstructure, without substantial deformation of the alloy, i.e., macroscopic deformation approaching zero percent, while heating the alloy in a non-oxidizing atmosphere for a time sufficient for diffusion bonding to occur. The alloy may be treated so that at least the surface layers thereof have a fine grain structure of the type associated with superplastic forming properties. Components may be formed by diffusion bonding and superplastic forming.

27 Claims, 18 Drawing Figures

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FIG. 5

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