Method of obtaining improved equilibrium conditions and of simultaneously ...

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METHOD OF OBTAINING IMPROVED EQUILIBRIUM CONDITIONS AND OF . SIMULTANEOUSLY PRODUCING STEAM UNDER HIGH PRESSURE IN THE PRODUCTION OF METHANOL

BACKGROUND OF THE INVENTION

1. Field of the Invention

This invention relates to a method of obtaining improved equilibrium conditions and of simultaneously producing steam under high pressure in the production of methanol by a reaction of oxides of carbon and of hydrogen-containing gases at temperatures of 200° to 300° C. under a pressure of 20 to 100 bars in the presence of a copper-containing catalyst, contained within a reactor in tubes, indirectly cooled by boiling water under pressure, wherein the resulting steam is withdrawn together with circulating water and is separated from the water, the water is recycled and the evaporated water is replaced by feed water.

2. Discussion of Prior Art

It is known to produce synthesis gas containing hydrogen and oxides of carbon by cracking hydrocarbons with steam at temperatures above 700° C. in the presence of an indirectly heated, nickel-containing catalyst. It is further known to form methanol by reacting the synthesis gas under pressures of 30 to 80 at temperatures of 230° to 280° C. in the presence of a copper-containing catalyst, contained in a reactor in tubes which are indirectly cooled with water. It is also known to utilize the cooling of the reactor tubes for production of high-pressure steam (German Pat. No. 20 13 297).

A known apparatus for producing methanol in another process comprises a tubular reactor having tubes contacted by flowing boiling water under pressure. In that apparatus, the feed water enters the lower part of the reactor and the resulting stream is fed to a superheater. Part of that steam can be withdrawn as highpressure steam and another part can be supplied to a 40 turbine, which drives a compressor. The remaining part of the steam can be recovered as turbine steam (German Pat. No. 21 23 950).

In the operation of the previously known tubular reactor, circulating water from a steam header is fed to 45 the tubular reactor. Part of the fed water is evaporated at the catalyst-filled tubes, in which the components H2O, CO and CO2 are reacted to form methanol. By thermosiphon action, the resulting steam together with circulating water is forced into the steam header, where 50 the steam is separated whereas the water, which is at its boiling point is returned to the lower part of the reactor. The steam withdrawn from the steam header must be returned to the system as feed water. Depending on the preheating of that feed water the temperature in the 55 steam header will be more or less close to the boiling point of water. If the water is circulated about ten times, feed water is fed at a temperature of 120° C. and a pressure of 40 bars is maintained in the system, the circulating water fed to to the lower part of the reactor will be 60 at a temperature of about 237° C, which is 13° C. under its boiling point. As a result, the temperature difference at the lower part of the reactor tubes containing catalyst at a temperature of about 255° C. is very low and precludes an appreciable heat exchange and a cooling of 65 the reacting mixed gases in the tubes.

Only steam at a pressure up to about 40 bars can be produced in the known tubular reactors for producing

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methanol because the copper catalyst is susceptible to elevated temperatures and a good equilibrium control is desired.

It is an object of the invention to avoid these disad5 vantages of the state of the art and to obtain a higher temperature difference in the lower part of the reactor and to effect an improved and more intense cooling of the reacting mixed gases. The equilibrium control is to be improved and steam under higher pressure is to be 10 produced at the same time. The process should involve lower energy costs.

This object is accomplished according to the invention in that a perforated thin intermediate bottom plate is provided, which is spaced 20 to 150 cm over the I5 lower tube plate, the reactor is fed with the circulating water above that intermediate bottom and with the feed water below that intermediate bottom, the gaseous reaction mixture is cooled by 20° to 50° C. in the lower part of the catalyst-filled tubes in a tube length of 20 to 20 150 cm, the feed water is heated in the reactor to temperatures of 230° to 290° C. with evaporation of part of the feed water, the resulting mixture of steam and circulating water is separated, the circulating water is recycled and the resulting high-pressure steam is with25 drawn.

In accordance with the invention the intermediate bottom is suitably spaced 50 cm over the lower tube plate.

The circulating water fed to the reactor is desirably at a temperature of 200° to 300° C, preferably at a temperature of 230° to 290° C, and the feed water is fed at a temperature of 100° to 180° C, preferably 110° to 150° C.

The advantages afforded by the invention reside particularly in that the temperature difference between the cooling fluid and the catalyst contained in the tubes can be increased in the lower part of the reactor in a simple, energy-saving process. As a result, the heat exchange is increased and the reacting gas mixture is cooled to a lower temperature so that the thermodynamic equilibrium is promoted. The temperatures used are within the limits determined by the recrystallizating characteristics of the catalyst. Methanol can be produced more economically in accordance with the invention.

BRIEF DESCRIPTION OF DRAWING

The invention is shown diagrammatically and by way of example in the drawing and will now be described more in detail;

The drawing shows the reactor 1, catalyst tubes 2, the lower tube plate 3, the intermediate bottom plate 4, a feeding of feed water at 5, a feeding of circulating water at 6, a mixture of steam and circulating water at 7, a separation of steam from the circulating water in the steam header at 8 and a withdrawal of high-pressure steam at 9.

EXAMPLE

A reactor 1 for producing methanol contains tubes 2, which contain the catalyst. An intermediate bottom plate 4 is spaced 50 cm above the lower tube plate 3 and may consist of a thin sheet steel which has apertures consisting of bores small in diameter. The feed water at a temperature of 120° C. is introduced into the reactor through a supply conduit 5 closely above the lower tube plate 3. That unmixed feed water contacts the lower part of the catalyst tubes 2 and cools the reacting mixed 4,369,255

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gases by 35° C. in a pipe length of 50 cm. As a result, the boiling water under pressure to indirectly cool the confeed water is heated to 280" C. and a small part of it is tents of said tube, steam resulting therefrom is withevaporated. drawn together with the circulating water and is sepa

Circulating water at a temperature of 280° C. is intro- rated therefrom the improvement for improving the duced through a conduit 6 into the reactor 1 closely 5 equilibrium within the reactor and simultaneously proabove the intermediate bottom plate 4. The colder feed during high pressure steam, which comprises disposing water 5 fed below the intermediate bottom plate 4 is an intermediate bottom plate 20 to 150 cm over said uniformly distributed by the latter whereas on the other iower tube plate> whereby to define a lower cooling side a backmixing with the hotter circulating water fed zone and an upper cooiing zone, said intermediate botabove the intermediate bottom plate 4 is prevented. 10 tom plate provjded with apertures to convey water

The feed water 5 is mixed with the circulating water from said lower cooling zone tQ sajd upper cooling

6 only above the intermediate bottom plate 4. As a zone> fegdi circmating water above said intermediate

result, that portion of the catalyst tubes 2 which is dis- bottom late and feed watef bdow said intermediate

posed above the mtermedmte bottom plate 4 is operated ... k whereby the gaseous reaction mixture

at a temperature of 280 . C so that a pressure of more 15 ^ {ube ^ ... fe 2Q0 tQ 5Q, Q in thfi low£r

than 60 bars is obtained in the water-circulating system . c.u t , . c., , . / ... . , . c~n.

, , . u uf • J ■ Part °ftne catalyst-filled tube in the tube length of 20 to

whereas only pressures up to 40 bars can be obtained m , ,„ ... „ , x . , A , . it °

. J r , . e 150 cm, the feed water is heated m the reactor to a

the previous processes. When the mixture of water . ' . ...0 ^ ^ . , . .

vapor and circulating water has been withdrawn at 7 ... of 230 to 290 C. with evaporation of a and has been separated into its two components at 8, 20 portion of the feed water, the resulting mixture of steam high-pressure steam under a pressure in excesss of 60 and circulating water is separated, the circulating water bars is recovered at 9 and can be used for numerous is recycled and the resulting high-pressure steam is purposes in the same plant, e.g., for expansion with withdrawn.

performance of work, for instance, in condensing steam 2- A method according to claim 1, wherein the interturbines, or for a generation of electric power by driv- 25 mediate bottom plate is spaced 50 cm over the lower ing gas compressors, or for supplying the energy re- turje plate

quired for the final distillation of the methanol, or for 3- A process according to claim 1, wherein the circuother purposes. Owing to the considerable advantages lating water is fed at a temperature of 200° to 300° C. by the process as regards energy consumption, the pro- 4- A process according to claim 1, wherein the circucess is particularly economical. 30 lating water is fed at a temperature of 230° to 290° C.

What is claimed is: 5. A process according to claim 1, wherein the feed

1. In a method of producing methanol by reaction of water is fed at a temperature of 100° to 180° C. an oxide of carbon and hydrogen at a temperature of 6. A process according to claim 1, wherein the feed 200° to 300° C. under a pressure of 20 to 100 bars by water is supplied at a temperature of 110° to 150° C. passing said oxide of carbon and hydrogen through at 35 7. A process according to claim 1, wherein said interleast one tube containing a copper-containing catalyst, mediate bottom plate has apertures therein in the form which tube is disposed on a lower tube plate and is of bores.

housed in a reactor through which passes circulating *****

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