WO2014120321A3 - Self-healing nanofibers, composites and methods for manufacturing - Google Patents

Self-healing nanofibers, composites and methods for manufacturing Download PDF

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Publication number
WO2014120321A3
WO2014120321A3 PCT/US2013/070110 US2013070110W WO2014120321A3 WO 2014120321 A3 WO2014120321 A3 WO 2014120321A3 US 2013070110 W US2013070110 W US 2013070110W WO 2014120321 A3 WO2014120321 A3 WO 2014120321A3
Authority
WO
WIPO (PCT)
Prior art keywords
core
healing
shell
self
dissolved
Prior art date
Application number
PCT/US2013/070110
Other languages
French (fr)
Other versions
WO2014120321A2 (en
WO2014120321A9 (en
Inventor
Xiangfa Wu
Arifur Rahman
Zhengping ZHOU
Youhao ZHAO
Original Assignee
Ndsu Research Foundation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ndsu Research Foundation filed Critical Ndsu Research Foundation
Publication of WO2014120321A2 publication Critical patent/WO2014120321A2/en
Publication of WO2014120321A9 publication Critical patent/WO2014120321A9/en
Publication of WO2014120321A3 publication Critical patent/WO2014120321A3/en

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C73/00Repairing of articles made from plastics or substances in a plastic state, e.g. of articles shaped or produced by using techniques covered by this subclass or subclass B29D
    • B29C73/16Auto-repairing or self-sealing arrangements or agents
    • B29C73/22Auto-repairing or self-sealing arrangements or agents the article containing elements including a sealing composition, e.g. powder being liberated when the article is damaged
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/0007Electro-spinning
    • D01D5/0061Electro-spinning characterised by the electro-spinning apparatus
    • D01D5/0069Electro-spinning characterised by the electro-spinning apparatus characterised by the spinning section, e.g. capillary tube, protrusion or pin
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/24Formation of filaments, threads, or the like with a hollow structure; Spinnerette packs therefor
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01DMECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
    • D01D5/00Formation of filaments, threads, or the like
    • D01D5/28Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
    • D01D5/30Conjugate filaments; Spinnerette packs therefor
    • D01D5/34Core-skin structure; Spinnerette packs therefor

Abstract

The present invention is a new type of hybrid high-strength carbon-fiber/epoxy composites reinforced with ultrathin toughening and self-healing core-shell fibers at interfaces by means of wetted lay-up, followed by vacuum-assisted resin transfer molding (VARTM) technique. The core-shell fibers loaded with liquid healing agent (a liquid monomer at room temperature) are produced by co- electrospinning, in which a plastic polymer solution (dissolved in an organic solvent) is used as the exterior jet and the monomer solution (dissolved in the same organic solvent) is used as the interior jet. Also described is a fiber manufacturing device utilizing a novel dual-wire emulsion-electrospinning method capable of producing ultrathin continuous core-shell and hollow fibers in commercial volumes.
PCT/US2013/070110 2012-11-14 2013-11-14 Self-healing nanofibers, composites and methods for manufacturing WO2014120321A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201261726157P 2012-11-14 2012-11-14
US61/726,157 2012-11-14

Publications (3)

Publication Number Publication Date
WO2014120321A2 WO2014120321A2 (en) 2014-08-07
WO2014120321A9 WO2014120321A9 (en) 2014-09-25
WO2014120321A3 true WO2014120321A3 (en) 2014-11-06

Family

ID=51263097

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2013/070110 WO2014120321A2 (en) 2012-11-14 2013-11-14 Self-healing nanofibers, composites and methods for manufacturing

Country Status (1)

Country Link
WO (1) WO2014120321A2 (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITUB20153618A1 (en) * 2015-09-14 2017-03-14 Alenia Aermacchi Spa NEW CATALYST FOR METATHY REACTIONS IN HIGH REACTIVITY ENVIRONMENTS
JP7039588B2 (en) 2016-11-29 2022-03-22 アドバンスド マテリアルズ デザイン アンド マニュファクチャリング リミテッド Process for making hybrid (fiber-nanofiber) textiles through efficient fiber-to-nanofiber adhesion, including new effective load transfer mechanisms
EP3412801B1 (en) * 2017-06-09 2020-02-19 Technische Universität Graz Method for producing a regular arrangement of droplets of a first liquid in a continuous jet of a second liquid
CN108232027B (en) * 2017-12-27 2020-03-06 青岛海信电器股份有限公司 Graphical flexible electrode, preparation method and flexible display device
CN108342048B (en) * 2018-03-21 2020-08-04 广东电网有限责任公司电力科学研究院 Cable sheath material with self-repairing function, preparation method and cable sheath
CN108877996A (en) * 2018-07-03 2018-11-23 北京理工大学 The method for preparing the flexible electronic device of highly conductive, selfreparing and tensility

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4975317A (en) * 1987-08-03 1990-12-04 Milliken Research Corporation Electrically conductive textile materials and method for making same
US6527849B2 (en) * 1990-06-19 2003-03-04 Carolyn M. Dry Self-repairing, reinforced matrix materials
US7108914B2 (en) * 2002-07-15 2006-09-19 Motorola, Inc. Self-healing polymer compositions
WO2007005657A2 (en) * 2005-07-01 2007-01-11 Dry Carolyn M Multiple function, self-repairing composites with special adhesives
US20080261027A1 (en) * 2007-04-17 2008-10-23 The Regents Of The University Of Michigan Engineered self healing cementitious composites
US20090208684A1 (en) * 2005-06-30 2009-08-20 Michael Dunleavy Self-Reparing Structure
US20110173971A1 (en) * 2010-01-15 2011-07-21 Syracuse University Stimuli-responsive product

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4975317A (en) * 1987-08-03 1990-12-04 Milliken Research Corporation Electrically conductive textile materials and method for making same
US6527849B2 (en) * 1990-06-19 2003-03-04 Carolyn M. Dry Self-repairing, reinforced matrix materials
US7108914B2 (en) * 2002-07-15 2006-09-19 Motorola, Inc. Self-healing polymer compositions
US20090208684A1 (en) * 2005-06-30 2009-08-20 Michael Dunleavy Self-Reparing Structure
WO2007005657A2 (en) * 2005-07-01 2007-01-11 Dry Carolyn M Multiple function, self-repairing composites with special adhesives
US20080261027A1 (en) * 2007-04-17 2008-10-23 The Regents Of The University Of Michigan Engineered self healing cementitious composites
US20110173971A1 (en) * 2010-01-15 2011-07-21 Syracuse University Stimuli-responsive product

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
SHELVAY, AM .: "Reinforced Concrete: Applicability of Smart Materials.", THESIS FOR MASTER OF ENGINEERING IN CIVIL AND ENVIRONMENTAL ENGINEERING, June 2012 (2012-06-01), pages 36 *

Also Published As

Publication number Publication date
WO2014120321A2 (en) 2014-08-07
WO2014120321A9 (en) 2014-09-25

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