WO2012094917A1 - Preparation method for degradable packaging material - Google Patents

Preparation method for degradable packaging material Download PDF

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Publication number
WO2012094917A1
WO2012094917A1 PCT/CN2011/081345 CN2011081345W WO2012094917A1 WO 2012094917 A1 WO2012094917 A1 WO 2012094917A1 CN 2011081345 W CN2011081345 W CN 2011081345W WO 2012094917 A1 WO2012094917 A1 WO 2012094917A1
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Prior art keywords
substrate
packaging material
degradable packaging
preparing
recycled plastic
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PCT/CN2011/081345
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French (fr)
Chinese (zh)
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杨辉雄
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Yang Huixiong
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Publication of WO2012094917A1 publication Critical patent/WO2012094917A1/en

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29KINDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
    • B29K2995/00Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
    • B29K2995/0037Other properties
    • B29K2995/0056Biocompatible, e.g. biopolymers or bioelastomers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

Definitions

  • the invention relates to the field of materials, in particular to a degradable material.
  • the boundary absorbs the digested biodegradable plastic material.
  • Biodegradable resinous material according to its violence
  • microbial fermentation product type starch
  • Doped type chemically synthesized type
  • polylactic acid type polylactic acid type
  • Generally used for packaging whether it is electrical appliances, home appliances, items that need to be supported by boxes, or beverage containers.
  • Plastic material Therefore, inventing a low cost and degradable packaging material has a very high price.
  • the present invention provides a natural food waste portion and recycled plastic.
  • a method of preparing a packaging material having degradability is a method of preparing a packaging material having degradability.
  • a method for preparing a degradable packaging material which is based on rice husks, corn bones and recycled plastics.
  • the shape is blister-shaped when the substrate is in a soft state.
  • the recycled plastic substrate is made of polyethylene terephthalate.
  • Step 1 ⁇ * roman i .
  • the medium particle size after grinding is 200 mesh.
  • An aperture groove is arranged in the center of the substrate, and the aperture is 1 mm.
  • the invention provides a method for preparing a degradable packaging material, which utilizes rice husk, corn bone and back
  • Plastic is used as a substrate, in which rice husks and corn bones are inedible parts of natural foods, in life.
  • the recycled plastic is poly-p-phenylene
  • Ethylene glycolate (PET), which has the characteristics of easy degradation, low melting point and good strength.
  • the degradable packaging material of the present invention made of the three substrates has low cost and sufficient profit
  • FIG. 1 Schematic diagram of the process of the present invention.
  • FIG. 1 Schematic representation of the finished product 1 produced by the process of the invention.
  • FIG. 1 Schematic representation of the finished product 2 produced by the process of the invention.
  • the invention provides a preparation method of a degradable packaging material, which adopts rice husk, corn bone and recycled plastic
  • the material is a substrate.
  • rice husks are regarded as garbage. After rice is ground into rice, rice husks are burned or buried due to rice.
  • the shell contains a large amount of antimony, by removing inorganic substances, fibers and impurities, and burning to remove carbon components.
  • Formula extracting cerium oxide from rice husk, which accounts for about one-fifth of the rice husk, while cerium oxide is produced.
  • corn bone contains starch, cellulose, etc., while starch is a decomposable substance, and its cellulose is in the knot.
  • the strength of the joint can be increased in the structure, and the recycled plastic is mainly composed of PET having a low melting point and a good strength.
  • the rice husk, corn bone and recycled plastic substrate are ground and ground to a particle size of 200 mesh.
  • Mixing is carried out, and a sterilizing agent is added to sterilize the mixed substrate.
  • the base material of the above kneaded mass is placed in a granulator to form a strip, which is then cut into pellets.
  • the granules produced in the granulation step are placed in a molding machine and heated and extruded to form a base.
  • the plate is formed with the substrate formed according to the mold, and a plurality of holes having a hole diameter of 1 mm are arranged in the center.
  • the slot is formed with the substrate formed according to the mold, and a plurality of holes having a hole diameter of 1 mm are arranged in the center.
  • the hole groove can be circular or rectangular
  • the substrate When the substrate is in a hot soft state, the substrate is molded by a mold and a vacuum suction method.
  • the shape is shaped to produce a finished product of a degradable packaging material of a predetermined shape.
  • the two are further combined into an organic (polymer) inorganic (cerium oxide) mixed material.
  • the structure of the material contains organic microstructure and inorganic microstructure, forming a highly mixed microstructure, with
  • the superiority of the organic-inorganic hybrid material such as high mechanical strength, high softness, and good heat resistance.

Abstract

Provided is a preparation method for a degradable packaging material; the method comprises using rice hulls, corn bones and recycled plastics as base materials, and then manufacturing the finished product by the steps of providing materials, grinding, mixing and sterilizing, kneading, granulating, extrusion moulding, and plastic-suction and forming, etc. The degradable packaging material prepared by this method has many advantages, such as low cost, full use of resources, and being environmentally friendly. In addition, during the preparation process, chemical changes will occur, so that a highly mixed microstructure is formed in the finished product, which gives the finished product a relatively good mechanical strength, flexibility and thermal resistance properties.

Description

一种可降解性包装材料制备方法 Method for preparing degradable packaging material 技术领域Technical field
本发明涉及的是材料领域,尤其是一种可降解性材料。 The invention relates to the field of materials, in particular to a degradable material.
背景技术Background technique
随着环境保护和节约资源的观念不断的传播,塑胶废弃物的处理问题受到很 With the continuous spread of the concept of environmental protection and resource conservation, the disposal of plastic waste is very problematic.
大关注,塑胶废弃物处理的相关领域技术也得到大力支持,尤其是可以被自Great concern, technology in the field of plastic waste disposal has also been strongly supported, especially since it can be
然界吸收消化的生物可降解塑胶材料。生物可降解性树脂状材料,根据其暴The boundary absorbs the digested biodegradable plastic material. Biodegradable resinous material, according to its violence
露于土壤或水中与微生物的作用不同而分为几种:微生物发酵产物型、淀粉It is divided into several types depending on the action of microorganisms in soil or water: microbial fermentation product type, starch
掺杂型、化学合成型及聚乳酸型等。Doped type, chemically synthesized type, and polylactic acid type.
技术问题 technical problem
一般用于包装上,无论是电器、家电商品、需装箱支撑的物件或饮料容器 Generally used for packaging, whether it is electrical appliances, home appliances, items that need to be supported by boxes, or beverage containers.
等,都需要制成一可支撑商品装箱包装的材料,此类材料有塑胶材料的、纸Etc., it is necessary to make a material that can support the packaging of goods, such materials are plastic materials, paper
质或其他材料,这些材料中,有些可以重复使用但是成本很高,如纸质的; Quality or other materials, some of which can be reused but costly, such as paper;
有些虽价格低廉,但是无法在土壤中分解,会造成环境污染,不够环保,如Some are inexpensive, but they cannot be decomposed in the soil, which can cause environmental pollution and are not environmentally friendly.
塑胶材料。因此,发明一种成本不高且具有可降解性的包装材料具有很高价Plastic material. Therefore, inventing a low cost and degradable packaging material has a very high price.
值。value.
技术解决方案Technical solution
针对以上问题,本发明提供一种运用天然食品废弃部分以及回收塑料制成In view of the above problems, the present invention provides a natural food waste portion and recycled plastic.
具有可降解性的包装材料制备方法。A method of preparing a packaging material having degradability.
为达到以上目的本发明的技术方案:The technical solution of the present invention for achieving the above object:
一种可降解性包装材料制备方法,以稻壳、玉米骨和回收塑料为基材,A method for preparing a degradable packaging material, which is based on rice husks, corn bones and recycled plastics.
包括以下步骤:Includes the following steps:
= 1 \* roman i .将所述稻壳、玉米骨和回收塑料基材研磨成颗粒状; = 1 \* roman i . Grinding the rice husk, corn bone and recycled plastic substrate into granules;
= 2 \* roman ii .将上述颗粒状稻壳、玉米骨和回收塑料分别以重量比 3:1:1  = 2 \* roman ii . The above granular husk, corn bone and recycled plastic were respectively weight ratio 3:1:1
进行混合并添加杀菌剂进行杀菌;Mixing and adding a fungicide for sterilization;
= 3 \* roman iii .在混合并杀菌后的稻壳、玉米骨和回收塑料混合基材中添 = 3 \* roman iii . Add in mixed and sterilized rice husk, corn bone and recycled plastic mixed substrate
加润滑剂,并揉捏成团状;Add lubricant and knead into a dough;
= 4 \* roman iv .将上述团状基材放入造粒机中制成条状物,再裁切成粒; = 4 \* roman iv . Putting the above-mentioned pellet substrate into a granulator to form a strip, and then cutting into pellets;
= 5 \* roman v .将步骤 i = 5 \* roman v .中所制成的颗粒放入成型机中加热 = 5 \* roman v . Will step i = 5 \* roman v . The granules made in the mold are heated in a molding machine
挤压成基板;Extruded into a substrate;
= 6 \* roman vi .在上述基板成热软状态时吸塑定形。= 6 \* roman vi . The shape is blister-shaped when the substrate is in a soft state.
还可以有以下步骤:You can also have the following steps:
= 7 \* roman vii .在产品表面印刷图样。= 7 \* roman vii . Print the pattern on the surface of the product.
所述回收塑料基材采用聚对苯二甲酸乙二醇酯。The recycled plastic substrate is made of polyethylene terephthalate.
步骤 = 1 \* roman i .中基材研磨后颗粒粒度为 200 目。Step = 1 \* roman i . The medium particle size after grinding is 200 mesh.
所述基板中央排列有孔槽,孔径为 1mm 。An aperture groove is arranged in the center of the substrate, and the aperture is 1 mm.
有益效果Beneficial effect
本发明的有益效果及优点:Advantageous effects and advantages of the present invention:
本发明提供的一种可降解性包装材料制备方法,运用稻壳、玉米骨以及回The invention provides a method for preparing a degradable packaging material, which utilizes rice husk, corn bone and back
收塑料为基材,其中稻壳、玉米骨均为天然食品中不食用的部分,在生活Plastic is used as a substrate, in which rice husks and corn bones are inedible parts of natural foods, in life.
中属于废弃物,往往会被当作垃圾处理,这类基材容易得到且成本低廉,It is waste and is often treated as garbage. Such substrates are easy to obtain and low in cost.
并且在土壤或水中容易分解,不会对环境造成污染;回收塑料为聚对苯二And it is easy to decompose in soil or water, and it will not pollute the environment; the recycled plastic is poly-p-phenylene
甲酸乙二醇酯(PET),该类塑料具有易降解、熔点低、强度较佳的特点。Ethylene glycolate (PET), which has the characteristics of easy degradation, low melting point and good strength.
由此三种基材所制成的本发明的可降解性包装材料,具有成本低、充分利The degradable packaging material of the present invention made of the three substrates has low cost and sufficient profit
用资源、对环境友好等诸多优点;另外在制备的过程中会发生化学变化,Use resources, environmental friendliness and many other advantages; in addition, chemical changes will occur during the preparation process,
在成品中形成高度混合微结构,使成品具有较佳的机械强度、柔软度及耐Forming a highly mixed microstructure in the finished product to give the finished product better mechanical strength, softness and resistance
热性质。Thermal properties.
附图说明DRAWINGS
图1.本发明方法流程示意图。Figure 1. Schematic diagram of the process of the present invention.
图2.本发明方法生产的成品1示意图。Figure 2. Schematic representation of the finished product 1 produced by the process of the invention.
图3.本发明方法生产的成品2示意图。Figure 3. Schematic representation of the finished product 2 produced by the process of the invention.
本发明的最佳实施方式BEST MODE FOR CARRYING OUT THE INVENTION
为了使本发明的目的、技术方案及优点更加清楚明白,以下结合附图及实施In order to make the objects, technical solutions and advantages of the present invention more clear, the following is described in conjunction with the accompanying drawings.
例,对本发明进行本实施例中详细说明。应当理解,此处所描述的具体实施For example, the present invention will be described in detail in this embodiment. It should be understood that the specific implementation described herein
例仅仅用以解释本发明,并不用于限定本发明。The examples are merely illustrative of the invention and are not intended to limit the invention.
本发明提供一种可降解性包装材料的制备方法,采用稻壳、玉米骨和回收塑The invention provides a preparation method of a degradable packaging material, which adopts rice husk, corn bone and recycled plastic
料为基材。The material is a substrate.
一般传统上稻壳被视为垃圾,水稻磨成米后,稻壳就被烧掉或埋掉,由于稻Traditionally, rice husks are regarded as garbage. After rice is ground into rice, rice husks are burned or buried due to rice.
壳中含有大量的矽,通过剔除无机物、纤维和杂质以及燃烧去掉碳成分等方The shell contains a large amount of antimony, by removing inorganic substances, fibers and impurities, and burning to remove carbon components.
式,从稻壳中提取出二氧化矽,含量约占稻壳的五分之一,而二氧化矽是制Formula, extracting cerium oxide from rice husk, which accounts for about one-fifth of the rice husk, while cerium oxide is produced.
造橡胶和塑胶不可或缺的添加剂,它可以增加塑胶用品的强度和透明度;另An indispensable additive for rubber and plastics, which increases the strength and transparency of plastics;
外,玉米骨中含有淀粉、纤维素等等,而淀粉为可分解物质,其纤维素在结In addition, corn bone contains starch, cellulose, etc., while starch is a decomposable substance, and its cellulose is in the knot.
构中可增加连结的强度,另外,回收塑料以熔点低,强度较佳的PET为主。The strength of the joint can be increased in the structure, and the recycled plastic is mainly composed of PET having a low melting point and a good strength.
请参考图1,生产步骤如下:Please refer to Figure 1, the production steps are as follows:
i.研磨。将稻壳、玉米骨以及回收塑料基材进行研磨,研磨至粒径200目以i. Grinding. The rice husk, corn bone and recycled plastic substrate are ground and ground to a particle size of 200 mesh.
下。under.
ii.混合杀菌。将上述颗粒状的稻壳、玉米骨及回收塑料按重量比3:1:1的比例Ii. Mixed sterilization. The above-mentioned granular rice husk, corn bone and recycled plastic are ratio of 3:1:1 by weight.
进行混合,且添加杀菌剂对混合基材杀菌。Mixing is carried out, and a sterilizing agent is added to sterilize the mixed substrate.
iii.捏合。向混合并杀菌后的稻壳、玉米骨及回收塑料中添加润滑剂,以便Iii. Kneading. Add lubricant to the mixed and sterilized rice husk, corn bone and recycled plastic so that
将其揉捏粘合成团状。It is kneaded and bonded into a dough.
iv.造粒。将上述捏合成团的基材,放入造粒机中制成条状物后裁切成粒。Iv. Granulation. The base material of the above kneaded mass is placed in a granulator to form a strip, which is then cut into pellets.
v.挤出成型。将造粒步骤中所制成的颗粒,放入成型机中加热挤压制成基v. Extrusion molding. The granules produced in the granulation step are placed in a molding machine and heated and extruded to form a base.
板,而其基板依据模具而成形,且中央排列有诸多孔径1mm的孔槽。该孔槽The plate is formed with the substrate formed according to the mold, and a plurality of holes having a hole diameter of 1 mm are arranged in the center. The slot
除可减轻重量之外,还具有增减强度的功能。所述的孔槽可以为圆形、矩形In addition to reducing weight, it also has the function of increasing or decreasing strength. The hole groove can be circular or rectangular
或者其他如图2中成品1以及图3中成品2所所示的不规则形状。Or other irregular shapes as shown in the finished product 1 in Fig. 2 and the finished product 2 in Fig. 3.
vi.吸塑定形。在基板呈热软状态时,施以模具与真空吸引方式将基板吸塑Vi. Blister shaping. When the substrate is in a hot soft state, the substrate is molded by a mold and a vacuum suction method.
定形,使其制成既定形状的可降解性包装材料成品。The shape is shaped to produce a finished product of a degradable packaging material of a predetermined shape.
除上述步骤外,还可以有vii.步骤:在上述成品表面印刷图样,增加成品的In addition to the above steps, you can also have vii. Step: printing the pattern on the surface of the above finished product to increase the finished product
美感。Aesthetic.
生产过程中发生如下化学变化:稻壳灰化成二氧化矽化合物,玉米骨与回收The following chemical changes occur during the production process: rice ash is ashed into cerium oxide compounds, corn bones and recycling
塑料则会劣化成为不同分子量有机化合物,其中含有高度未饱和基-C=C-,The plastic will deteriorate into organic compounds of different molecular weights, which contain a highly unsaturated group -C=C-,
在高温环境下,两者进一步结合成有机(高分子)无机(二氧化矽)混合材In a high temperature environment, the two are further combined into an organic (polymer) inorganic (cerium oxide) mixed material.
料,该材料结构内含有机微结构与无机微结构,形成高度混合微结构,具有Material, the structure of the material contains organic microstructure and inorganic microstructure, forming a highly mixed microstructure, with
有机无机混合材料的优越性,例如机械强度高、柔软度大及耐热性能好等。The superiority of the organic-inorganic hybrid material, such as high mechanical strength, high softness, and good heat resistance.
以上所述仅为本发明的较佳实施例而已,并不用以限制发明,凡在本发明的The above is only the preferred embodiment of the present invention and is not intended to limit the invention, and is in the present invention.
精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本发明的Any modifications, equivalent substitutions and improvements made within the spirit and principles shall be included in the present invention.
保护范围之内。Within the scope of protection.
本发明的实施方式Embodiments of the invention
工业实用性Industrial applicability
序列表自由内容Sequence table free content

Claims (5)

  1. 一种可降解性包装材料制备方法,以稻壳、玉米骨和回收塑料为A method for preparing a degradable packaging material, which comprises rice husk, corn bone and recycled plastic
    基材,其特征在于,包括以下步骤:The substrate is characterized in that it comprises the following steps:
    i.将所述稻壳、玉米骨和回收塑料基材研磨成颗粒状;i. Grinding the rice husk, corn bone and recycled plastic substrate into granules;
    ii.将上述颗粒状稻壳、玉米骨和回收塑料分别以重量比3:1:1进行Ii. The above granular rice husks, corn bones and recycled plastics were respectively carried out at a weight ratio of 3:1:1.
    混合并添加杀菌剂进行杀菌;Mixing and adding a fungicide for sterilization;
    iii.在混合并杀菌后的稻壳、玉米骨和回收塑料混合基材中添加Iii. Add in mixed and sterilized rice husk, corn bone and recycled plastic mixed substrate
    润滑剂,并揉捏成团状;Lubricant and kneaded into a dough;
    iv.将上述团状基材放入造粒机中制成条状物,再裁切成粒;Iv. Putting the above-mentioned pellet substrate into a granulator to form a strip, and then cutting into pellets;
    v.将步骤iv.中所制成的颗粒放入成型机中加热挤压成基板;v. Step iv. The granules prepared in the mold are placed in a molding machine and heated and extruded into a substrate;
    vi.在上述基板成热软状态时吸塑定形。 Vi. The shape is blister-shaped when the substrate is in a soft state.
  2. 根据权利要求1所述的可降解性包装材料制备方法,其特征在The method for preparing a degradable packaging material according to claim 1, characterized in that
    于:所述步骤vi.后还包括以下步骤:In: the step vi. It also includes the following steps:
    vii.在成品表面印刷图样。Vii. Print the pattern on the finished surface.
  3. 根据权利要求1所述的可降解性包装材料制备方法,其特征在The method for preparing a degradable packaging material according to claim 1, characterized in that
    于:所述回收塑料基材采用聚对苯二甲酸乙二醇酯。Wherein: the recycled plastic substrate is made of polyethylene terephthalate.
  4. 根据权利要求1所述的可降解性包装材料制备方法,其特征在The method for preparing a degradable packaging material according to claim 1, characterized in that
    于:步骤i.中基材研磨后颗粒粒度为200目。In: Step i. The medium particle size after grinding was 200 mesh.
  5. 根据权利要求1所述的可降解性包装材料制备方法,其特征在The method for preparing a degradable packaging material according to claim 1, characterized in that
    于:所述基板中央排列有孔槽,孔径为1mm。The hole is arranged in the center of the substrate, and the hole diameter is 1 mm.
PCT/CN2011/081345 2011-01-14 2011-10-26 Preparation method for degradable packaging material WO2012094917A1 (en)

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CN102220024B (en) * 2011-01-14 2012-07-25 杨辉雄 Method for preparing degradable packaging material

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5186990A (en) * 1991-04-05 1993-02-16 Eagle Scientific Co. Biodegradable and water soluble packaging material
CN1127276A (en) * 1995-11-08 1996-07-24 何顺伦 Biological degraded plant fibre package material and producing method
CN1244369A (en) * 1999-07-19 2000-02-16 王长玉 Once-used degradable green tableware and container and their making process
US20070179230A1 (en) * 2006-01-13 2007-08-02 Wipak Walothen Gmbh Packaging material having a nonstick composition and use thereof for packaging foods
CN102220024A (en) * 2011-01-14 2011-10-19 杨辉雄 Method for preparing degradable packaging material

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5186990A (en) * 1991-04-05 1993-02-16 Eagle Scientific Co. Biodegradable and water soluble packaging material
CN1127276A (en) * 1995-11-08 1996-07-24 何顺伦 Biological degraded plant fibre package material and producing method
CN1244369A (en) * 1999-07-19 2000-02-16 王长玉 Once-used degradable green tableware and container and their making process
US20070179230A1 (en) * 2006-01-13 2007-08-02 Wipak Walothen Gmbh Packaging material having a nonstick composition and use thereof for packaging foods
CN102220024A (en) * 2011-01-14 2011-10-19 杨辉雄 Method for preparing degradable packaging material

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