WO2012084972A1 - Deodorant and antiperspirant compositions for preventing body odor - Google Patents

Deodorant and antiperspirant compositions for preventing body odor Download PDF

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Publication number
WO2012084972A1
WO2012084972A1 PCT/EP2011/073438 EP2011073438W WO2012084972A1 WO 2012084972 A1 WO2012084972 A1 WO 2012084972A1 EP 2011073438 W EP2011073438 W EP 2011073438W WO 2012084972 A1 WO2012084972 A1 WO 2012084972A1
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chf
weight
water
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PCT/EP2011/073438
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German (de)
French (fr)
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Bernhard Banowski
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Henkel Ag & Co. Kgaa
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Priority to EP11802927.1A priority Critical patent/EP2654668A1/en
Publication of WO2012084972A1 publication Critical patent/WO2012084972A1/en

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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K3/00—Materials not provided for elsewhere
    • C09K3/30—Materials not provided for elsewhere for aerosols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/69—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing fluorine
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00—Anti-perspirants or body deodorants

Definitions

  • the present application relates to deodorant and antiperspirant compositions which are sprayed with selected fluorocarbons or fluorohydrocarbons as propellants.
  • Washing, cleansing and caring for one's own body is a fundamental human need, and modern industry is constantly trying to meet these needs of man in a variety of ways. Especially important for daily hygiene is the permanent elimination or at least reduction of body odor.
  • Body odor arises to a large extent from the bacterial decomposition of individual components of perspiration on the skin.
  • Apocrine sweat is a complex mixture that contains steroids, cholesterol and other fats as well as about 1% protein.
  • the decomposition products of apocrine perspiration which contribute significantly to the body odor, in particular to the axillary body odor, can be divided into two classes, one short-chain, in particular C 4 -C 0 -fatty acids, which may be linear, branched, saturated and unsaturated , on the other various steroid hormones and their degradation products.
  • the typical body odor especially of men, involves the metabolic products of androgens, in particular androstenol (5a-androst-16-en-3 ⁇ -ol, 5a-androst-16-en-3a-ol) and androstenone (5a -androst-16-en-3- ⁇ ).
  • Steroids themselves are not water soluble.
  • sulfate or as glucuronide In order to be carried away with the body fluids, they are usually present as sulfate or as glucuronide.
  • hydrolytic enzymes of the skin bacteria especially the coryneform bacteria.
  • all bacterial exoesterases are capable of this, especially the enzymes arylsulfatase and .beta.-glucuronidase.
  • the fatty components of the (apocrine) sweat are hydrolyzed by various lipases and esterases, predominantly short-chain, in particular C 4 -C 0 -fatty acids, which also smell strongly.
  • Suitable odor absorbers, fragrances, deodorizing ion exchangers, germ-inhibiting agents, prebiotic components and enzyme inhibitors can be used as cosmetic deodorizing agents.
  • body deodorization one can roughly differentiate between active substances which absorb unpleasant-smelling substances already formed (zinc ricinoleate, cyclodextrins, ion exchangers) or cover up (fragrances, perfumes), and impurities which prevent, or at least prevent the decomposition of perspiration and the formation of unpleasant-smelling substances slow down (germ-inhibiting active ingredients, prebiotic components and enzyme inhibitors).
  • compositions for the prevention of body odor are propellant-containing spray dispenser, which apply the composition as a mousse, that is, as a fine bubble foam.
  • a mousse that is, as a fine bubble foam.
  • both fast-breaking and stable foams can be produced.
  • the foam form helps to apply water-containing products in such a way that they do not run down immediately on the skin but remain on the application area where they can penetrate into the skin or but can be rubbed.
  • the application gives as a mousse an interesting skin feeling.
  • Typical hydrocarbon blowing agents such as propane, n-butane and isobutane
  • propane, n-butane and isobutane have a low solubility in water
  • a polar blowing agent such as dimethyl ether
  • the foams produced with these blowing agents are in their quality, especially in terms of the stability or the rate of breakage, on the fine bubbles and the sensory properties in need of further improvement.
  • compositions for the prevention of body odor are propellant-containing spray dispensers which apply the composition as a non-foaming or only slightly foaming emulsion. It is important that the blowing agent does not affect the stability of the emulsion, so that - similar to the foams - the emulsion remains on the application surface and not the aqueous and the oily phase immediately run down the skin.
  • the present application was based on the object of providing a propellant-containing foamable cosmetic composition for the prevention of body odor, which has improved properties compared with the compositions of the prior art, in particular with regard to foam stability, fine bubbles and sensory properties.
  • Another object of the present application was to provide a propellant-containing cosmetic composition for the prevention of body odor in emulsion form, which has improved properties compared to the compositions of the prior art, in particular with regard to the emulsion stability and the sensory properties.
  • a further object of the present application was to provide a propellant-containing cosmetic composition for the prevention of body odor, which has a reduced flammability compared to the compositions of the prior art.
  • the present application relates to deodorant or antiperspirant compositions containing
  • At least one blowing agent selected from at least one compound having 3 to 10 carbon atoms according to formula (I)
  • radicals R, R 2 , R 3 and R 4 independently of one another, denote a hydrogen atom, a bromine atom, a fluorine atom or a (CT - C 6 ) -alkyl group substituted by at least one fluorine atom,
  • R, R 2 , R 3 and R 4 form a five- or six-membered ring, with the proviso that: at least one of R, R 2 , R 3 or R 4 is a hydrogen atom or a fluorine atom, and
  • At least one of the radicals R, R 2 , R 3 or R 4 is a (C 1 to C 6 ) -alkyl group substituted by at least one fluorine atom or at least two of the radicals R, R 2 , R 3 and R 4 represent a or form a six-membered ring.
  • compositions are characterized by a propellant of formula (I) wherein R, R 2 , R 3 or R 4 of formula (I) are independently hydrogen, fluorine or (C 1 to C 6 ) Alkyl group, with the proviso that:
  • R, R 2 , R 3 or R 4 is a hydrogen atom or a fluorine atom
  • At least one of the radicals R, R 2 , R 3 or R 4 is a substituted with at least one fluorine atom (C ⁇ to C 6 ) alkyl group.
  • compositions according to the invention are characterized in that blowing agent of the formula (I) is selected from at least one compound of the group which is formed
  • CF 3 CH CFCF 2 CF 2 CF 2 CF 3
  • CF 3 CF CHCF 2 CF 2 CF 2 CF 3
  • C 2 F 5 CH CFCH 2 CH 2 CH 3
  • compositions according to the invention are not taken into account for the quantities which concern non-propellant ingredients. All amounts are therefore based on the total weight of the propellant-free composition, unless otherwise stated.
  • normal conditions are a temperature of 20 ° C. and a pressure of 1013.25 mbar. Melting point data likewise relate to a pressure of 1013.25 mbar.
  • the free water content of the compositions according to the invention is 5-97% by weight, preferably 10-85% by weight, more preferably 15-75% by weight, most preferably 20-65% by weight, based in each case on Total weight of the blowing agent-free composition.
  • "free water” is water which is not contained in the antiperspirant composition in the form of water of crystallization, water of hydration or similar molecularly bound water
  • free water is for example water which is added as a solvent, as a gel activator or as a solvent constituent of other active substances to the composition according to the invention.
  • the surfactant content of the compositions according to the invention is from 0.1 to 30% by weight, preferably from 0.2 to 20% by weight, more preferably from 0.5 to 10% by weight, most preferably from 1 to 8% by weight, in each case based on the total weight of the blowing agent-free composition.
  • surfactant contents 2-7% by weight or 4-6% by weight, based in each case on the total weight of the blowing agent-free composition.
  • emulsifiers are also added to the surfactants.
  • Suitable anionic surfactants in compositions according to the invention are all anionic surfactants suitable for use on the human body. These are characterized by a water-solubilizing, anionic group such as. As a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group having about 8 to 30 carbon atoms. In addition, glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups may be present in the molecule. Examples of suitable anionic Tensid- classes are, in each case in the form of the sodium, potassium and ammonium and the mono-, di- and Trialkanolammoniumsalze with 2 to 4 C-atoms in the alkanol group:
  • R 6 is preferably an aliphatic hydrocarbon radical having 8 to 30 carbon atoms
  • R 7 is hydrogen, a radical (CH 2 CH 2 0) nR 6 or X, n is from 1 to 10 and X is hydrogen, an alkali or Alkaline earth metal or NR 8 R 9 R 0 R 11 , where R 8 to R independently of one another represent a C 4 - to C 4 hydrocarbon radical, is a sulfated fatty acid alkylene glycol ester of the formula (III),
  • R 2 CO- for a linear or branched, aliphatic, saturated and / or unsaturated acyl radical having 6 to 22 carbon atoms, Alk for CH 2 CH 2 , CHCH 3 CH 2 and / or CH 2 CHCH 3 , n for numbers from 0.5 to 5 and M is a cation, as described in DE-OS 197 36 906.5,
  • R 3 CO is a linear or branched acyl radical having 6 to 22 carbon atoms
  • x, y and z are in total 0 or numbers of 1 to 30, preferably 2 to 10
  • X is an alkali or alkaline earth metal.
  • monoglyceride (ether) sulfates suitable for the purposes of the invention are the reaction products of lauric acid monoglyceride, coconut fatty acid monoglyceride, palmitic acid monoglyceride, stearic acid monoglyceride, oleic acid monoglyceride and tallow fatty acid monoglyceride and their ethylene oxide adducts with sulfur trioxide or chlorosulfonic acid in the form of their sodium salts.
  • These protein hydrolyzate-fatty acid condensation products are neutralized with a base and are then preferably present as alkali metal, ammonium, mono-, di- or trialkanolammonium salt;
  • Acylglutamates which are condensation products of glutamic acid and C 8 -C 30 fatty acids, preferably of fatty acids having 12 to 18 carbon atoms and which are present in neutralized form as K, Na or ammonium salt, and acylaspartates which are condensation products of aspartic acid and C 8 - C30 fatty acids, preferably of fatty acids having 12 to 18 carbon atoms and which are present in neutralized form as K, Na or ammonium salt;
  • Acylsarcosides having 8 to 24 carbon atoms in the acyl group.
  • Preferred anionic surfactant classes are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acid salts having 10 to 18 C atoms in the alkyl group and up to 12 glycol ether groups in the molecule, sulfosuccinic acid mono- and dialkyl esters having 8 to 18 C atoms in the alkyl group and sulfosuccinic monoalkylpolyoxyethyl esters having 8 to 18 C atoms in the alkyl group and 1 to 6 oxyethyl groups, citric acid esters with fatty alcohol ethoxylates, such as the product sold under the trade name "Plantapon LC-7"
  • Preferred surfactants of the class alkyl polyglycol ether sulfates are sodium trideceth sulfates, for example those sold under the trade name "Miracare SLB 365", “Genapol XRO" or "Rhodapex
  • Zwitterionic surfactants are those surface-active compounds which carry at least one quaternary ammonium group and at least one -COO ( - ) or -SO 3 ( - ) group in the molecule.
  • Particularly suitable zwitterionic surfactant classes are the so-called betaines such as N-alkyl-N, N-dimethylammonium glycinates, for example cocoalkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinates, for example cocoacylaminopropyl-dimethylammonium glycinate, and 2-alkylbenzenesulfonate.
  • a preferred zwitterionic surfactant is the fatty acid amide derivative known by the INCI name Cocamidopropyl Betaine.
  • Amphoteric surfactants are understood as meaning those surface-active compounds which, apart from a C 8 -C 24 -alkyl or -acyl group in the molecule, contain at least one free amino group and at least one -COOH or -SO 3 H group and are capable of forming internal salts
  • Examples of preferred ampholytic surfactant classes are N-alkylglycines, N-alkylpropyl pionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, amphoacetates, in particular cocoamphoacetates, lauroamphoacetates, olivamorphoacetates, amphopropionates, in particular cocoamphopropionates, amphodiacetates, in particular cocoamphodiacetates, lauroamphodiacetates, capryloamphodiacetates, amphodipropionates, in particular
  • Phosphatidylcholines having the general structural formula shown below are the main constituent of lecithin.
  • the substituents R and R 2 in structural formula (PL) below represent linear aliphatic alkyl radicals having from 7 to 21 carbon atoms, preferably from 1 to 19 carbon atoms, more preferably from 15 to 17 carbon atoms, having up to four Z-configured double bonds can. More preferably, R CO and R 2 CO are independently selected from palmitoyl, stearoyl, oleoyl, linoloyl and linolenoyl.
  • phosphatidylcholine also particularly preferred is phosphatidylcholine, partially hydrogenated phosphatidylcholine and fully hydrogenated phosphatidylcholine, each derived from soya lecithin.
  • Phosphatidylcholines belong to the phospholipids, but in the present context are calculated only as surfactants, not as lipids.
  • ampholytic surfactants are cocoamphoacetates, lauroamphoacetates, cocoamphodiacetates, lauroamphodiacetates and capryloamphodiacetates.
  • amphoteric and / or zwitterionic surfactants are in the compositions of the invention - based on the total weight of the propellant-free composition - in a total amount of 0.01 to 20 wt .-%, preferably in a total amount of 0.05 to 18 wt .-%, particularly preferably used in a total amount of 0.1 to 15 wt .-% and in particular in a total amount of 0.5 to 10 wt .-%.
  • Nonionic surfactants contain as hydrophilic group z.
  • a polyol group especially a polyglycerol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether groups.
  • Such classes of surfactants are, for example:
  • R 5 is hydrogen or methyl
  • R 6 is linear or branched alkyl radicals having 1 to 4 carbon atoms and w is a number from 1 to 20, amine oxides, hydroxy mixed ethers, as described, for example, in DE-OS 19738866, sorbitan fatty acid esters and adducts of ethylene oxide with sorbitan fatty acid esters such as the polysorbates, sugar fatty acid esters and addition products of ethylene oxide with sugar fatty acid esters, fatty acid alkanolamides, Addition products of ethylene oxide onto fatty acid alkanolamides and fatty amines, fatty acid N-alkylglucamides, alkylpolyglycosides corresponding to the general formula RO- (Z) x where R is alkyl,
  • the alkyl radicals R are mixtures corresponding to the starting compounds or corresponding to the particular work-up of these compounds. Particular preference is given to those alkylpolyglycosides in which R consists essentially of C 8 and C 0 -alkyl groups or substantially of C 2 and C 4 -alkyl groups or substantially of C 8 to C 6 -alkyl groups or essentially of C 2 - To C 6 alkyl groups or consists essentially of C 16 to C 8 alkyl groups.
  • sugar building block Z it is possible to use any desired mono- or oligosaccharides.
  • sugars with 5 or 6 carbon atoms and the corresponding oligosaccharides are used.
  • Such sugars are, for example, glucose, fructose, galactose, arabinose, ribose, xylose, lyxose, allose, altrose, mannose, gulose, idose, talose and sucrose.
  • Preferred sugar building blocks are glucose, fructose, galactose, arabinose and sucrose; Glucose is particularly preferred.
  • the inventively preferred Alkylpolyglycoside contain an average of 1, 1 to 5 sugar units.
  • Alkyl polyglycosides having x values of 1.1 to 2.0 are preferred. Very particular preference is given to alkyl glycosides in which x is 1: 1 to 1, 8.
  • the alkoxylated homologs of said alkylpolyglycosides can also be used according to the invention. These Homologs may contain on average up to 10 ethylene oxide and / or propylene oxide units per alkyl glycoside unit.
  • Preferred nonionic surfactants are the ethylene oxide adducts of saturated linear fatty alcohols and fatty acids having in each case 2 to 30 moles of ethylene oxide per mole of fatty alcohol or fatty acid. Compositions having excellent properties are also obtained when they contain fatty acid esters of ethoxylated glycerol as nonionic surfactants.
  • the nonionic surfactants are in the compositions of the invention - based on the total weight - in a total amount of 0.05 to 20 wt .-%, preferably in a total amount of 0.1 to 15 wt .-% and in particular in a total amount of 0, 5 to 10 wt .-% used.
  • compositions according to the invention may further comprise at least one cationic surfactant of the quaternary ammonium quaternary type, the esterquats and the amidoamines.
  • Preferred quaternary ammonium compounds are ammonium halides, especially chlorides and bromides, such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, e.g. Cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyldimethylammonium chloride, lauryldimethylammonium chloride, lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride, as well as the imidazolium compounds known under the INCI names Quaternium-27 and Quaternium-83.
  • the alkyl chains of the above-mentioned surfactants preferably have 10 to 18 carbon atoms.
  • Esterquats are known substances which contain both at least one ester function and at least one quaternary ammonium group as a structural element.
  • Preferred ester quats are quaternized ester salts of fatty acids with triethanolamine, quaternized ester salts of fatty acids with diethanolalkylamines and quaternized ester salts of fatty acids with 1,2-dihydroxypropyldialkylamines.
  • the cationic surfactants are contained in the compositions according to the invention - based on their total weight - in a total amount of 0.05 to 10 wt .-%, particularly preferably 0.5 to 3 wt .-%.
  • compositions of the invention contain at least two surfactants belonging to different classes of surfactants.
  • Preferred surfactant classes for this selection are sulfosuccinic acid monoalkylpolyoxyethyl esters having 8 to 24 C atoms, preferably 10 to 14 C atoms, more preferably 12 C atoms in the alkyl group and in each case 1 to 6 oxyethyl groups, sodium, potassium and ammonium Salts and mono-, di- and Trialkanolammonium- salts having 2 to 4 carbon atoms in the alkanol group of linear or branched fatty acids having 8 to 30 carbon atoms (soaps), fatty acid alkanolamides, Alkylpolyglycolethersulfate of the formula R-O (CH 2 -CH 2 O) x -OSO 3 H, in which R is a preferably linear alkyl group having 8 to 18 C atoms, preferably 10 to 14 and particularly preferably 12 C atoms and
  • compositions according to the invention contain at least the following surfactant class mixture: alkylpolyglycol ether sulfate / betaine, alkylpolyglycol ether sulfate / sulfosuccinic acid monoalkylpolyoxyethyl ester, alkylpolyglycol ether sulfate / alkylpolyglycoside as described above, alkylpolyglycol ether sulfate / amphoacetate, alkylpolyglycol ether sulfate / amphodiacetate, alkylpolyglycol ether sulfate / adduct of from 5 to 60 moles of ethylene oxide hydrogenated castor oil, sulfosuccinic acid mono-alkyl polyoxyethyl ester /
  • compositions according to the invention preferably contain as surfactant at least one nonionic oil-in-water emulsifier having an HLB value of more than 7.
  • HLB (100-L): 5 where L is the weight fraction of the lipophilic groups, that is the fatty alkyl or fatty acyl groups, in the ethylene oxide adducts, expressed in weight percent.
  • nonionic oil-in-water emulsifiers which are suitable according to the invention, it is particularly preferable to use a mixture of nonionic oil-in-water emulsifiers in order to optimally adjust the properties of compositions according to the invention.
  • compositions according to the invention are characterized in that the nonionic oil-in-water emulsifiers are selected from ethoxylated C 8 -C 24 -alkanols with an average of 10 to 100 moles of ethylene oxide per mole of ethoxylated C 8 -C 24 -carboxylic acids with an average of 10 - 100 moles of ethylene oxide per mole, silicone copolyols with ethylene oxide units or with ethylene oxide and propylene oxide units, alkyl mono- and oligoglycosides having 8 to 22 carbon atoms.
  • the nonionic oil-in-water emulsifiers are selected from ethoxylated C 8 -C 24 -alkanols with an average of 10 to 100 moles of ethylene oxide per mole of ethoxylated C 8 -C 24 -carboxylic acids with an average of 10 - 100 moles of ethylene oxide per mole, silicone copolyols with ethylene oxide units
  • the ethoxylated C 8 -C 24 -alkanols have the formula R 0 (CH 2 CH 2 O) n H, where R is a linear or branched alkyl and / or alkenyl radical having 8-24 carbon atoms and n, the average number of Ethylene oxide units per molecule, for numbers from 10 to 100, preferably 10 to 30, mol of ethylene oxide to 1 mol of caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, isocetyl alcohol, palmitoleyl alcohol, stearyl alcohol, isostearyl alcohol, Oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol, and technical mixtures thereof.
  • adducts of 10-100 moles of ethylene oxide with technical fatty alcohols having 12-18 carbon atoms, such as coconut, palm, palm kernel or tallow fatty alcohol are suitable.
  • the ethoxylated C 8 -C 24 carboxylic acids have the formula R (OCH 2 CH 2 ) n OH, where R is a linear or branched saturated or unsaturated acyl radical having 8-24 carbon atoms and n, the average number of ethylene oxide units per Molecule, for numbers from 10 to 100, preferably 10 to 30, mol of ethylene oxide to 1 mol of caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, cetylic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, arachidic acid, gadoleic acid, Behenic acid, erucic
  • Adducts of 10 to 100 moles of ethylene oxide with technical fatty acids containing 12 to 18 carbon atoms, such as coconut, palm, palm kernel or tallow fatty acid, are also suitable. Particularly preferred are PEG-50 monostearate, PEG-100 monostearate, PEG-50 monooleate, PEG-100 monooleate, PEG-50 monolaurate and PEG-100 monolaurate.
  • C 2 -C 8 -alkanols or the C 2 -C 8 -carboxylic acids with in each case 10 to 30 units of ethylene oxide per molecule and also mixtures of these substances, in particular ceteth-12, ceteth-20, ceteth-30, isoceteth- 20, steareth-12, steareth-20, steareth-21, steareth-30, ceteareth-12, ceteareth-20, ceteareth-30, laureth-12 and beheneth-20.
  • C 8 -C 22 -alkyl mono- and -oligoglycosides preference is given to using C 8 -C 22 -alkyl mono- and -oligoglycosides.
  • C 8 -C 22 -alkylmono- and -oligoglycosides are known, commercially available surfactants and emulsifiers. They are prepared in particular by reacting glucose or oligosaccharides with primary alcohols having 8-22 carbon atoms.
  • the glycoside radical monoglycosides in which a cyclic sugar residue is glycosidically linked to the fatty alcohol and oligomeric glycosides having a degree of oligomerization of up to about 8, preferably 1-2, are suitable.
  • the degree of oligomerization is a statistical mean, the one for such technical products is based on the usual homolog distribution. Products which are obtainable under the trademark Plantacare ®, containing a glucosidic bond C 8 -C 6 - alkyl group at an oligoglucoside whose average degree of oligomerization at 1 - 2, in particular 1, 1 - 1, 4, is located.
  • Particularly preferred C 8 -C 22 alkyl mono- and oligoglycosides are selected from octyl glucoside, decyl glucoside, lauryl glucoside, palmityl glucoside, isostearyl glucoside, stearyl glucoside, arachidyl glucoside and behenyl glucoside and mixtures thereof.
  • the glucamine-derived acylglucamides are also suitable as nonionic oil-in-water emulsifiers.
  • Ethoxylated sterols, in particular ethoxylated soy sterols are also suitable oil-in-water emulsifiers according to the invention.
  • the degree of ethoxylation must be greater than 5, preferably at least 10, in order to have an HLB value greater than 7.
  • Suitable commercial products are, for. PEG-10 Soy Sterol, PEG-16 Soy Sterol and PEG-25 Soy Sterol.
  • partial esters of polyglycerols having 2 to 10 glycerol units and having 1 to 4 saturated or unsaturated, linear or branched, optionally hydroxylated C 8 -C 30 fatty acid radicals are preferably esterified, if they have an HLB value of more than 7 ,
  • Particularly preferred Diglycerinmonocaprylat, Diglycerinmonocaprat, diglycerol are rinmonolaurat, Triglycerinmonocaprylat, Triglycerinmonocaprat, triglycerol, Tetragly- cerinmonocaprylat, rinmonocaprat Tetraglycerinmonocaprat, Tetraglycerinmonolaurat, Pentaglycerinmonocapry- lat, Pentaglycerinmonocaprat, Pentaglycerinmonolaurat, Hexaglycerinmonocaprylat, Hexaglyce-, hexa glycerol, Hexaglycerin
  • oil-in-water emulsifiers are selected from organosiloxane-oxyalkylene copolymers.
  • organosiloxane-oxyalkylene copolymers according to the invention are selected from linear polysiloxane-polyoxyalkylene block copolymers, in particular from linear polysiloxane-polyoxyethylene-polyoxypropylene block copolymers.
  • Extremely preferred according to the invention is a linear polysiloxane-polyoxyethylene-polyoxypropylene block copolymer having the INCI name PEG / PPG-22/24 dimethicones and CAS no. 64365-23-7.
  • Such a linear polysiloxane-polyoxyethylene-polyoxypropylene block copolymer is available, for example, under the trade name Mirasil DMCO (INCI: PEG / PPG-22/24 dimethicone) from Rhodia or Bluestar Silicones.
  • Mirasil DMCO INCI: PEG / PPG-22/24 dimethicone
  • Another preferred linear polysiloxane-polyoxyethylene-polyoxyethylene propylene block copolymer of this type carries the INCI name PEG / PPG-10/2 Dimethicone. It is available, for example, under the trade name Mirasil DMCP 93 (INCI: PEG / PPG-10/2 Dimethicone) from Rhodia or Bluestar Silicones.
  • organosiloxane-oxyalkylene copolymer O / W emulsifiers are selected from compounds of the general structural formulas (I), (II), (III), (IV) and (V),
  • radicals R independently of one another represent a linear or branched C 1 -C 5 -alkyl group or an optionally substituted phenyl group,
  • radicals R 2 independently of one another are the groups -C c H 2 c-O- (C 2 H 4 O-) a (C 3 H 6 O-) b R 5 or -C c H 2c -O- (C 2 H 4 0-) a R 5 , the radicals R 3 and R 4 independently of one another represent a linear or branched C 1 -C 4 -alkyl group and preferably methyl groups,
  • the radicals R 5 independently of one another represent a hydrogen atom or a linear or branched C 1 -C 4 -alkyl group and preferably a hydrogen atom or a methyl group
  • m represents a number from 0-20
  • n represents a number from 0-500
  • o a number from 0 - 20
  • p represents a number from 1 to 50
  • a represents a number from 0 to 50
  • b represents a number from 0 to 50
  • c a number from 1 to 4, particularly preferred 3
  • x represents a number from 1 to 100.
  • organosiloxane-oxyalkylene copolymer is available, for example, under the trade name Dow Corning 1 90 (INCI: PEG / PPG-1 8/1 8 Dimethicone).
  • organosiloxane-oxyalkylene Copolymer is available, for example, under the trade name Dow Corning 1 93 (INCI: PEG-1 2 Dimethicone).
  • organosiloxane-oxyalkylene copolymer is available, for example, under the trade name Silwet L-77.
  • organosiloxane-oxyalkylene Copolymer is available, for example, under the trade name Dow Corning Q2-5220 (INCI: PEG / PPG-1 7/1 8 Dimethicone).
  • organosiloxane-oxyalkylene copolymer is, for example available under the trade name Abil B 881 84 (INCI: PEG / PPG-20/6 Dimethicone).
  • compositions according to the invention are characterized in that at least one organosiloxane-oxyalkylene copolymer of the general structural formula (II) is present.
  • R methyl
  • R 2 -C c H 2 c-O- (C 2 H 4 O-) a (C 3 H 6 O-) b
  • Such an organosiloxane-oxyalkylene copolymer is available, for example, under the trade name Abil B 8851 (INCI: PEG / PPG-14/4 Dimethicone).
  • compositions according to the invention are characterized in that at least one oil-in-water emulsifier, preferably at least one nonionic oil-in-water emulsifier, in a total amount of 0.5-10 wt.%, Preferably 1-9 wt %, more preferably 1.5-8.5% by weight, most preferably 2-8% by weight, and also 2.5, 3, 3.5, 4.0, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, and 8 wt .-%, based on the propellant-free composition is included.
  • compositions according to the invention comprise at least one water-in-oil emulsifier having an HLB value greater than 1.0, and less than or equal to 7.0, preferably at least one nonionic water-in-oil emulsifier having an HLB value greater than 1, 0 and ⁇ 7.0.
  • compositions according to the invention comprise mixtures, in particular technical mixtures, of at least two water-in-oil emulsifiers.
  • Preferred water-in-oil emulsifiers with an HLB value greater than 1.0, and ⁇ 7.0 are selected from the mono- and diesters of ethylene glycol and the mono-, di-, tri- and tetra-esters of pentaerythritol with linear saturated fatty acids with 12-30, in particular 14-22, carbon atoms which may be hydroxylated, as well as mixtures thereof.
  • the mono- and diesters are preferred.
  • C 2 -C 30 fatty acid radicals preferred according to the invention are selected from lauric acid, myristic acid, palmitic acid, stearic acid, arachic acid and behenic acid radicals; particularly preferred is the stearic acid residue.
  • Particularly preferred nonionic water-in-oil emulsifiers according to the invention having an HLB value greater than 1.0, and ⁇ 7.0 are selected from pentaerythrityl monostearate, pentaerythrityl distearate, pentaerythrityl tristearate, pentaerythrityl tetrastearate, ethylene glycol monostearate, ethylene glycol distearate, and mixtures thereof.
  • particularly preferred water-in-oil emulsifiers having an HLB value greater than 1, 0 and ⁇ 7.0 are, for example, as commercial products Cutina ® PES (INCI: Pentaerythrityl distearate), Cutina ® AGS (INCI: Glycol distearate) or Cutina ® EGMS (INCI: Glycol stearate) available.
  • Cutina ® PES INCI: Pentaerythrityl distearate
  • Cutina ® AGS INCI: Glycol distearate
  • Cutina ® EGMS INCI: Glycol stearate
  • These commercial products are already mixtures of mono- and diesters (in the pentaerythrityl esters are also tri- and tetraesters contain). Under a technical mixture, for example, a commercial product such as Cutina ® understood PES.
  • water-in-oil emulsifiers are: linear saturated alkanols having 12-30 carbon atoms, in particular having 16-22 carbon atoms, in particular cetyl alcohol, stearyl alcohol, arachidyl alcohol, behenyl alcohol and lanolin alcohol or mixtures of these alcohols, as obtainable in the industrial hydrogenation of vegetable and animal fatty acids,
  • Such esters or partial esters are, for.
  • Sterols ie steroids which carry a hydroxyl group at the C3 atom of the steroid skeleton and both from animal tissue (zoosterols, eg cholesterol, lanosterol) as well as from plants (phytosterols, eg ergosterol, stigmasterol, sitosterol) and from fungi and yeasts (mycosterols) which may be low ethoxylated (1-5 EO);
  • Alkanols and carboxylic acids each having 8-24 C atoms, in particular having 16-22 C atoms, in the alkyl group and 1-4 ethylene oxide units per molecule which have an HLB value of greater than 1.0, and less than or equal to 7.0 exhibit,
  • Partial esters of polyglycerols with n 2 to 10 glycerol units and with 1 to 5 saturated or unsaturated, linear or branched, optionally hydroxylated C 8 - C 30 fatty acid residues esterified, if they have an HLB value of less than or equal to 7,
  • Particularly advantageously usable water-in-oil emulsifiers are stearyl alcohol, cetyl alcohol, glyceryl monostearate, glyceryl Glycerylmonocaprinat, glyceryl, glyceryl monolaurate, glyceryl monomyristate rylmonooleat, glyceryl, Glycerylmonohydroxystearat, glycerol, lenglycolmonostearat Glycerylmonolanolat, Glyceryldimyristat, Glyceryldipalmitat, glyceryl, propylene, propylene glycol , Sorbitan monocaprylate, sorbitan monolaurate, sorbitan monomyristate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquistearate, sorbitan tandearate, sorbitan dioleate, sorbitan sesquioleate, suc
  • W / O emulsifiers are silicone-free polymeric water-in-oil emulsifiers, in particular PEG-30 dipolyhydroxystearate, available for. B. under the trade name Arlacel P 135 from Uniqema.
  • PEG / PPG-18/18 dimethicones z. B. in a 1: 9 mixture with Cyclomethicone under the name Dow Corning 3225 C or Dow Corning 5225 C is commercially available
  • PEG / PPG-18/18 Dimethicone the z. B. in a 1: 3 mixture with non-volatile dimethicone as Dow Corning ES 5227 DM Formulation Aid is commercially available
  • PEG / PPG-4/12 Dimethicone, the z. B. under the name Abil B 8852 is available
  • silicone-based W / O emulsifiers which are preferred according to the invention are poly (C 2 -C 3 ) -alkylene glycol-modified silicones which are hydrophobically modified with C 4 -C 8 -alkyl groups, particularly preferably cetyl PEG / PPG-10/1 Dimethicone (formerly: Cetyl Dimethicone Copolyol, eg available as Abil EM 90 or in a mixture of polyglyceryl-4-isostearate, Cetyl PEG / PPG-10/1 dimethicone and hexyl laurate under the trade name Abil WE 09), furthermore alkyl methicone Copolyols and Alkyl Dimethicone Ethoxy Glucosides.
  • poly (C 2 -C 3 ) -alkylene glycol-modified silicones which are hydrophobically modified with C 4 -C 8 -alkyl groups, particularly preferably cetyl PEG / PPG-10/1
  • compositions contain at least one water-in-oil emulsifier in a total amount of 0.01 to 7 wt .-%, preferably 0.1 to 3 wt .-%, particularly preferably 0.5 to 1 wt .-% .
  • the deodorant or antiperspirant compositions according to the invention also contain 0.1-50% by weight of at least one deodorant or antiperspirant active ingredient.
  • aluminum chlorhydroxides aluminum chlorohydrates
  • aluminum-zirconium compounds are suitable; However, zirconium compounds are not permitted by law in aerosol preparations.
  • Preferred antiperspirant active ingredients are water-soluble.
  • water solubility is understood to mean a solubility of at least 5% by weight at 20 ° C., that is to say amounts of at least 5 g of the antiperspirant active substance are soluble in 95 g of water at 20 ° C.
  • antiperspirant actives are selected from aluminum chlorohydrate, aluminum chlorohydrate, in particular having the general formula [Al 2 (OH) 5 CI ⁇ 1 -6 H 2 0] n, [AI preferably 2 (OH) 5 CI 2-3 ⁇ H 2 0 ] n , which may be in non-activated or in activated (depolymerized) form, and aluminum chlorohydrate having the general formula [Al 2 (OH) 4 Cl 2 ⁇ 1 -6 H 2 O] n , preferably [Al 2 (OH) 4 CI 2 ⁇ 2-3 H 2 O] n , which may be in unactivated or in activated (depolymerized) form.
  • the preparation of preferred antiperspirant agents is disclosed, for example, in US 3887692, US 3904741, US 4359456, GB 2048229 and GB 1347950.
  • aluminum sesquichlorohydrate aluminum dichlorohydrate, aluminum chlorohydrex-propylene glycol (PG) or aluminum chlorohydrex-polyethylene glycol (PEG), aluminum glycol complexes, eg. Aluminum-propylene glycol complexes, aluminum sesquichlorohydrex-PG or aluminum sesquichlorohydrex-PEG, aluminum-PG-dichlorhydrex or aluminum-PEG-dichlorhydrex, aluminum hydroxide, further selected from sodium aluminum chlorohydroxy lactate, aluminum chlorohydrate allantoinate and sodium aluminum chlorhydroxylactate.
  • antiperspirant active substances are selected from what are known as “activated” aluminum chlorhydroxides, which are also referred to as “antiperspirant active ingredients” having increased activity (English: enhanced activity). Such agents are known in the art and are also commercially available. Their preparation is disclosed, for example, in GB 2048229, US 4775528 and US 6010688.
  • Activated aluminum chlorhydroxides are typically produced by heat treating a relatively dilute solution of the salt (e.g., about 10% by weight of salt) to increase its HPLC peak 4-to-peak 3 area ratio. The activated salt can then be dried to a powder, in particular spray-dried. In addition to the spray drying z. B. also suitable for drum drying.
  • Activated aluminum chlorhydroxides typically have a HPLC peak 4-to-peak 3 area ratio of at least 0.4, preferably at least 0.7, more preferably at least 0.9, with at least 70% of the aluminum attributable to these peaks.
  • Activated aluminum chlorhydroxides do not necessarily have to be used as a spray-dried powder.
  • antiperspirant active ingredients non-aqueous solutions or solubilisates of an activated antiperspirant aluminum salt, for example according to US 6010688, which comprises adding an effective amount of a polyhydric alcohol having 3 to 6 carbon atoms and 3 to 6 hydroxyl groups, preferably propylene glycol, sorbitol and pentaerythritol the loss of activation against the rapid degradation of the HPLC peak 4: peak 3 area ratio of the salt are stabilized.
  • weight percent (USP) compositions 12-45% by weight, based on the propellant-free composition, of an activated aluminum salt, 55-82% by weight of at least one anhydrous polyhydric alcohol of 3 to 6 carbon atoms, and 3 to 6 hydroxyl groups, preferably propylene glycol, butylene glycol, diethylene glycol, dipropylene glycol, glycerol, sorbitol and pentaerythritol, more preferably propylene glycol.
  • USP weight percent
  • complexes of activated antiperspirant aluminum salts with a polyhydric alcohol containing from 20 to 50% by weight, more preferably from 20 to 42% by weight, of activated antiperspirant aluminum salt and from 2 to 16% by weight of molecularly bound water; Rest to 100 wt .-% of at least one polyhydric alcohol having 3 to 6 carbon atoms and 3 to 6 hydroxyl groups.
  • a polyhydric alcohol containing from 20 to 50% by weight, more preferably from 20 to 42% by weight, of activated antiperspirant aluminum salt and from 2 to 16% by weight of molecularly bound water; Rest to 100 wt .-% of at least one polyhydric alcohol having 3 to 6 carbon atoms and 3 to 6 hydroxyl groups.
  • Propylene glycol, propylene glycol / sorbitol mixtures and propylene glycol / pentaerythritol mixtures are preferred such alcohols.
  • Further preferred antiperspirant actives are basic calcium aluminum salts, as disclosed, for example, in US 2571030. These salts are prepared by reacting calcium carbonate with aluminum chlorhydroxide or aluminum chloride and aluminum powder or by adding calcium chloride dihydrate to aluminum chlorhydroxide.
  • antiperspirant active compounds are activated aluminum salts, as disclosed, for example, in US Pat. No. 6,245,325 or US Pat. No. 6,042,816, containing 5-78% by weight (USP) of an activated antiperspirant aluminum salt, an amino acid or hydroxyalkanoic acid in such an amount as to afford Amino acid or hydroxyalkanoic acid) to AI weight ratio of 2: 1-1: 20 and preferably 1: 1 to 1:10, and a water-soluble calcium salt in such an amount to give a Ca: Al weight ratio of 1: 1-1: 28 and preferably 1: 2 - 1: 25 provide.
  • USP 5-78% by weight
  • an activated antiperspirant aluminum salt an amino acid or hydroxyalkanoic acid in such an amount as to afford Amino acid or hydroxyalkanoic acid
  • AI weight ratio 2: 1-1: 20 and preferably 1: 1 to 1:10
  • a water-soluble calcium salt in such an amount to give a Ca: Al weight ratio of 1: 1-1:
  • Particularly preferred solid activated antiperspirant salt compositions for example according to US Pat. No. 6,245,325 or US Pat. No. 6,042,816, contain 48-78% by weight (USP), preferably 66-75% by weight of an activated aluminum salt and 1-16% by weight, preferably 4%. 13 wt .-% molecularly bound water (water of hydration), further sufficient water-soluble calcium salt that the Ca: Al weight ratio of 1: 1 - 1: 28, preferably 1: 2 - 1: 25, and so much amino acid that the amino acid to Al - weight ratio 2: 1 - 1: 20, preferably 1: 1 - 1: 10, is.
  • solid antiperspirant activated salt compositions for example according to US 6245325 or US 6042816, contain 48-78% by weight (USP), preferably 66-75% by weight of an activated aluminum salt and 1-16% by weight, preferably 4 - 13 wt .-% molecularly bound water (water of hydration), further so much water-soluble calcium salt that the Ca: Al weight ratio of 1: 1 - 1: 28, preferably 1: 2 - 1: 25, and so much glycine, that the glycine to Al - weight ratio 2: 1 - 1: 20, preferably 1: 1 - 1: 10, is.
  • USP 48-78% by weight
  • an activated aluminum salt and 1-16% by weight preferably 4 - 13 wt .-% molecularly bound water (water of hydration)
  • water of hydration water of hydration
  • solid antiperspirant activated salt compositions for example according to US 6245325 or US 6042816, contain 48-78% by weight (USP), preferably 66-75% by weight of an activated aluminum salt and 1-16% by weight, preferably 4 - 13 wt .-% molecularly bound water, further so much water-soluble calcium salt that the Ca: AI weight ratio 1: 1 - 1: 28, preferably 1: 2 - 1: 25, and is so much hydroxyalkanoic that the hydroxyalkanoic acid to AI - Weight ratio 2: 1 - 1: 20, preferably 1: 1 - 1: 10, is.
  • Preferred water-soluble calcium salts for the stabilization of antiperspirant salts are selected from calcium chloride, calcium bromide, calcium nitrate, calcium citrate, calcium formate, calcium acetate, calcium gluconate, calcium ascorbate, calcium lactate, calcium glycinate, calcium carbonate, calcium sulfate, calcium hydroxide, and mixtures thereof.
  • Preferred amino acids for the stabilization of the antiperspirant salts are selected from glycine, alanine, leucine, isoleucine, ⁇ -alanine, valine, cysteine, serine, tryptophan, phenylalanine, methionine, ⁇ -amino-n-butanoic acid and ⁇ -amino-n-butanoic acid and the salts thereof, each in the d-form, the I-form and the dl-form; Glycine is particularly preferred.
  • Preferred hydroxyalkanoic acids for the stabilization of the antiperspirant salts are selected from glycolic acid and lactic acid.
  • activated aluminum salts such as disclosed in US 6902723, containing 5-78% by weight (USP) of an activated antiperspirant aluminum salt, an amino acid or hydroxyalkanoic acid in such amount as to add (amino acid or hydroxyalkanoic acid) Al - weight ratio of 2: 1 - 1: 20 and preferably 1: 1 to 1:10, and a water-soluble strontium salt in such an amount to have a Sr: Al weight ratio of 1: 1 - 1:28 and preferably 1: 2 - 1: 25.
  • USP activated aluminum salts
  • an amino acid or hydroxyalkanoic acid in such amount as to add (amino acid or hydroxyalkanoic acid) Al - weight ratio of 2: 1 - 1: 20 and preferably 1: 1 to 1:10
  • a water-soluble strontium salt in such an amount to have a Sr: Al weight ratio of 1: 1 - 1:28 and preferably 1: 2 - 1: 25.
  • Particularly preferred solid antiperspirant activated salt compositions contain 48-78% by weight (USP), preferably 66-75% by weight of an activated aluminum salt and 1-16% by weight, preferably 4-13% by weight. -% molecularly bound water, further enough so much water-soluble strontium salt that the Sr: Al weight ratio is 1: 1 - 1: 28, preferably 1: 2 - 1: 25, and so much amino acid that the amino acid to AI - weight ratio 2: 1 - 1: 20, preferably 1: 1 - 1: 10, is.
  • USP 48-78% by weight
  • -% molecularly bound water, further enough so much water-soluble strontium salt that the Sr: Al weight ratio is 1: 1 - 1: 28, preferably 1: 2 - 1: 25, and so much amino acid that the amino acid to AI - weight ratio 2: 1 - 1: 20, preferably 1: 1 - 1: 10, is.
  • solid antiperspirant activated salt compositions for example according to US 6902723, contain 48-78% by weight (USP), preferably 66-75% by weight of an activated aluminum salt and 1-16% by weight, preferably 4-13% by weight .-% molecularly bound water, further so much water-soluble strontium salt that the Sr: Al weight ratio of 1: 1 - 1: 28, preferably 1: 2 - 1: 25, and is so much glycine that the glycine to Al - weight ratio 2: 1-1: 20, preferably 1: 1-1: 10.
  • solid antiperspirant activated salt compositions for example according to US 6902723, contain 48-78% by weight (USP), preferably 66-75% by weight of an activated aluminum salt and 1-16% by weight, preferably 4-13% by weight .-% molecularly bound water, further so much water-soluble strontium salt that the Sr: Al weight ratio is 1: 1 - 1: 28, preferably 1: 2 - 1: 25, and as much hydroxyalkanoic that the hydroxyalkanoic acid to AI - Weight ratio 2: 1 - 1: 20, preferably 1: 1 - 1: 10, is.
  • activated aluminum salts are those of the general formula Al 2 (OH) 6 . a Xa, wherein X is Cl, Br, I or N0 3 and "a" is a value of 0.3 to 5, preferably from 0.8 to 2.5 and particularly preferably 1 to 2, so that the molar ratio of Al X is 0.9: 1 to 2.1: 1, as disclosed, for example, in US 6074632.
  • These salts generally associate some hydration water, typically 1 to 6 moles of water per mole of salt.
  • Particularly preferred is aluminum chlorohydrate (ie, X is Cl in the aforementioned formula) and especially 5/6 basic aluminum chlorohydrate wherein "a” is 1 such that the molar ratio of aluminum to chlorine is 1.9: 1 to 2.1: 1 ,
  • Preferred aluminum salts have a molar metal-to-chloride ratio of 0.9-1.3, preferably 0.9-1.1, more preferably 0.9-1.0.
  • water of hydration is associatively bound to these salts, typically 1-6 moles of water per mole of salt, corresponding to 1-16% by weight, preferably 4-13% by weight of water of hydration.
  • the particularly effective antiperspirant salt comprises a so-called "activated" salt, in particular one with a high HPLC peak 5-aluminum content, in particular with a peak 5 surface of at least 33%, particularly preferred at least 45%, based on the total area under peaks 2-5, measured by HPLC of a 10% by weight aqueous solution of the active material under conditions in which the aluminum species are resolved into at least 4 consecutive peaks (with peaks 2 - 5). 5).
  • the antiperspirant active substances can be used as non-aqueous solutions or as glycolic solubilisates.
  • the antiperspirant active ingredients can be present both in solubilized and in dissolved form.
  • USP water-free active substance
  • the composition contains a adstringie- rendes aluminum salt, especially aluminum chlorohydrate, for example, in powder form as Micro Dry ® Ultrafine or Microdry from Reheis, Microdry sold 323 from Summit as Chlorhydrol ® as well as in activated form as Reach ® 501 from Reheis. Under the name Reach® 301 an aluminum sesquichlorohydrate from Reheis is offered, which is likewise particularly preferred. Also particularly preferred are activated aluminum chlorohydrates which are available under the names Reach® 101 and Reach® 103 from Reheis / Summit.
  • antiperspirant active ingredients are selected from diols of the structure (DIOL)
  • radical R 1 is selected from a phenyl radical, CH 3 - and H-
  • radicals R 2 , R 3 and R 4 are independently selected from the groups OH, -CH 2 OH, CH 3 -, C 2 H 5 -, H, with the proviso that two OH groups are present in the molecule and that the carbon number of all radicals R2, R3 and R4 is at most 6.
  • Preferred antiperspirant diols are selected from 1,2-propylene glycol, 1,3-propylene glycol, 1,3-butylene glycol, 2,4-pentylene glycol and 2,5-hexanediol, with 1,3-propylene glycol being particularly preferred.
  • compositions according to the invention contain at least one diol of the structure (DIOL) described above in a total amount of 8-48% by weight, preferably 12-25% by weight, particularly preferably 14-20% by weight, based in each case on the Total weight of the blowing agent-free composition
  • DIOL structure
  • Deodorant compositions according to the invention comprise at least one deodorant active substance in a total amount of 0.1-50% by weight, based on the total weight of the blowing agent-free composition.
  • Deodorant agents which are preferred according to the invention are germ-inhibiting agents, odor absorbers, deodorizing ion exchangers, prebiotically active components and also enzyme inhibitors or, particularly preferred, combinations of the mentioned active substances.
  • Silicates serve as odor absorbers, which can also advantageously simultaneously support the rheological properties of the composition according to the invention.
  • the silicates particularly preferred according to the invention are, in particular, phyllosilicates and, among these, in particular montmorillonite, kaolinite, mit, beidellite, nontronite, saponite, hectorite, bentonite, smectite and talcum.
  • odor absorbers are, for example, zeolites, Zinkricinoleat, cyclodextrins, certain metal oxides, such as. As alumina, and chlorophyll. Further inventively preferred odor absorbers are selected from perlite (volcanic glass) and expanded perlite. Odor absorbers are preferably used in a total amount of 0.1-10% by weight, more preferably 0.5-7% by weight and most preferably 1-5% by weight, based in each case on the total weight of the blowing agent-free composition.
  • germ-inhibiting or antimicrobial active substances are understood to mean those active substances which reduce the number of skin germs participating in the formation of the odor or inhibit their growth.
  • These organisms include, among others, various species from the group of staphylococci, the group of Corynebacteria, anaerococci and micrococci.
  • Preferred germinal or antimicrobial active substances according to the invention are in particular organohalogen compounds and halides, quaternary ammonium compounds, a series of plant extracts and zinc compounds. These include triclosan, chlorhexidine and chlorhexidine gluconate, 3,4,4'-trichlorocarbanilide, bromochlorophene, dichlorophen, chlorothymol, chloroxylenol, hexachlorophene, dichloro-m-xylenol, dequalinium chloride, domiphenbromide, ammonium phenolsulfonate, benzalkonium halides, benzalkonium cetyl phosphate, benzalkonium saccharinates, benzethonium chloride, Cetylpyridinium chloride, laurylpyridinium chloride, laurylisoquinolinium bromide, methylbenzethonium chloride.
  • phenol phenoxyethanol, di-sodium dihydroxyethylsulfosuccinyl undecylenate, sodium bicarbonate, zinc lactate, sodium phenol sulfonate and zinc phenolsulfonate, ketoglutaric acid, terpene alcohols such as.
  • chlorophyllin copper complexes alpha monoalkyl glycerol ether with a branched or linear saturated or unsaturated, optionally hydroxylated C 6 - C 22 alkyl, particularly preferably alpha- (2-ethylhexyl) glycerol, commercially available as Sensiva ® SC 50 (ex Schülke & Mayr), carboxylic acid esters of mono-, di- and triglycerol (eg glycerol monolaurate, diglycerol mono- caprinate), lantibiotics and plant extracts (eg green tea and components of lime blossom oil).
  • Sensiva ® SC 50 ex Schülke & Mayr
  • carboxylic acid esters of mono-, di- and triglycerol eg glycerol monolaurate, diglycerol mono- caprinate
  • lantibiotics and plant extracts eg green tea and components of lime blossom oil.
  • deodorant active substances are selected from so-called prebiotically active components, which according to the invention are to be understood as meaning those components which inhibit only or at least predominantly the odor-causing germs of the skin microflora, but not the desired ones, that is, the non-odor-forming germs forming a include healthy skin microflora.
  • active ingredients which in DE 10333245 and DE 10 2004 01 1 968 as prebiotically effective, are included; these include conifer extracts, in particular from the group of Pinaceae, and plant extracts from the group of Sapindaceae, Araliaceae, Lamiaceae and Saxifragaceae, in particular extracts from Picea spp., Paullinia sp., Panax sp., Lamium album or Ribes nigrum and mixtures of these substances.
  • conifer extracts in particular from the group of Pinaceae
  • plant extracts from the group of Sapindaceae, Araliaceae, Lamiaceae and Saxifragaceae, in particular extracts from Picea spp., Paullinia sp., Panax sp., Lamium album or Ribes nigrum and mixtures of these substances.
  • deodorant active ingredients are selected from the germ-inhibiting active perfume oils and Deosafe ® -Par colmölen that, Haarmann and Reimer, by the company Symrise previously available.
  • deodorant active ingredients are selected from silver salts, in particular silver citrate, dihydrogen silver citrate, silver lactate and silver sulfate, soluble complex salts of silver, supported silver halides, in particular titanium dioxide-supported silver chloride, colloidal silver and silver zeolites.
  • Preferred deodorant or antiperspirant compositions according to the invention are characterized in that silver ions (Ag + ) in a total amount of 1-100 ppm, preferably 2-50 ppm, more preferably 5-20 ppm, most preferably 7-10 ppm, in each case by weight the propellant-free composition according to the invention are included.
  • the enzyme inhibitors include substances which inhibit the enzymes responsible for the sweat decomposition, in particular arylsulfatase, beta-glucuronidase, aminoacylase, esterases, lipases and / or lipoxigenase, e.g. B. trialkylcitric acid, in particular triethyl citrate, or zinc glycinate.
  • Preferred deodorant or antiperspirant compositions according to the invention comprise at least one deodorant active ingredient selected from arylsulfatase inhibitors, beta-glucuronidase inhibitors, aminoacylase inhibitors, esterase inhibitors, lipase inhibitors and lipoxygenase inhibitors, alpha-monoalkylglycerol ethers having a branched or linear, saturated or unsaturated, optionally hydroxylated C 6 - C 22 alkyl radical, in particular alpha- (2-ethylhexyl) glycerol ether, phenoxyethanol, germ-inhibiting active perfume oils, Deosafe ® -Par colmölen (Deosafe ® is a registered trademark of the company Symrise, formerly Haarmann & Reimer), prebiotic components, silver salts, trialkyl citric acid esters, in particular triethyl citrate, active ingredients which reduce or inhibit the growth of the number of skin germs from the group of staphylococci, cor
  • deodorant active ingredients are selected from at least one double salt of the alum type having the general formula M I M I "(S0 4) 2 x H 2 ⁇ Q included, where M 1 is a monovalent cation selected from potassium, sodium, rubidium, cesium and ammonium ions, M 1 "is a trivalent cation selected from aluminum, gallium, indium, scandium, titanium and vanadium ions, and x represent a rational number ranging from 0 to 12, including 0.
  • KAI (S0 4 ) 2 KAI (S0 4 ) 2 , KAI (S0 4 ) 2 ⁇ 1 H 2 0, KAI (S0 4 ) 2 ⁇ 2 H 2 0, KAI (S0 4 ) 2 ⁇ 3 H 2 0, KAI (S0 4 ) 2 ⁇ 4 H 2 0, KAI (S0 4 ) 2 ⁇ 5 H 2 0, KAI (S0 4 ) 2 ⁇ 6 H 2 0, KAI (S0 4 ) 2 ⁇ 7 H 2 0, KAI (S0 4 ) 2 ⁇ 8 H z O, KAI (S0 4 ) 2 ⁇ 9 H 2 0, KAI (S0 4 ) 2 ⁇ 10 H 2 0, KAI (S0 4 ) 2 ⁇ 1 1 H z O and KAI (S0 4 ) 2 ⁇ 12H 2 0.
  • the at least one double salt of the alum type having the general formula M'M '' (S0 4) 2 ⁇ x H 2 0 is preferably in a total amount of 0, 1 in the present compositions - 10 wt .-%, particularly preferably 0 , 5 - 7 wt .-% and most preferably 1 - 3 wt .-%, each based on the total weight of the propellant-free composition containing.
  • Active ingredients are selected from at least one aromatic compound
  • R - R 6 independently a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, which may be linear or branched and which may be substituted by OH groups or alkoxy groups having 1 to 5 carbon atoms, or an alkenyl group having 2 to 10 Carbon atoms which may be linear or branched and which may be substituted by OH groups or alkoxy groups having 1 to 5 carbon atoms,
  • R 7 - R independently a hydrogen atom, a halogen atom, in particular a chlorine atom, or an alkyl group having 1 to 1 0 carbon atoms, which may be linear or branched and which may be substituted by OH groups or alkoxy groups having 1 to 5 Carbon atoms, in particular with a methoxy group,
  • n, o, p can independently be integers from 0 to 10, at least one of the values n, o, p being 0.
  • compositions according to the invention are characterized in that the deodorising aromatic alcohol of structure (AA-1) is selected from phenoxyethanol, phenoxyisopropanol (3-phenoxy-propan-2-ol), anisalcohol, 2-methyl-5-phenyl-pentane 1 -ol, 1,1-dimethyl-3-phenyl-propan-1-ol, benzyl alcohol, 2-phenylethane-1-ol, 3-phenylpropan-1-ol, 4-phenyl-1-butanol, 5- Phenylpentan-1-ol, 2-benzylheptan-1-ol, 2,2-dimethyl-3-phenylpropan-1-ol, 2,2-dimethyl-3- (3'-methylphenyl) -propan-1-ol, 2 Ethyl 3-phenylpropan-1-ol, 2-ethyl-3- (3'-methylphenyl) -propan-1-ol, 3- (3'-chlorophenyl) -2
  • Examples of the C r to C 5 -alkyl radicals mentioned as substituents in the compounds used according to the invention are the groups methyl, ethyl, propyl, isopropyl, n-butyl, tert-butyl, n-pentyl, amyl, isoamyl.
  • Ethyl, methyl, propyl, isopropyl, n-butyl, tert-butyl, n-pentyl, amyl, iso-amyl are preferred alkyl radicals, particular preference is given to methyl and n-pentyl.
  • Preferred C to C 4 -alkoxy radicals according to the invention are, for example, a methoxy or an ethoxy group.
  • a C to C 5 -hydroxyalkyl group a Hydroxymethyl, a 2-hydroxyethyl, a 3-hydroxypropyl or a 4-hydroxybutyl group.
  • a 2-hydroxyethyl group is particularly preferred.
  • a particularly preferred C 2 to C 4 polyhydroxyalkyl group is the 1, 2-dihydroxyethyl group.
  • halogen atoms are F, Cl or Br atoms, Cl atoms are very particularly preferred.
  • compositions according to the invention are characterized in that the deodorant aromatic alcohol of structure (AA-1) is selected from anisalcohol, 2-methyl-5-phenyl-pentane-1-ol, 1, 1-dimethyl-3-phenyl propan-1-ol, 3-phenylpropan-1-ol, 4-phenylbutan-1-ol, 5-phenylpentan-1-ol, 2-benzylheptan-1-ol, 2,2-dimethyl-3-phenylpropan-1 - ol and 2-n-pentyl-3-phenylpropan-1-ol. Extraordinary preference is given to 2-benzylheptan-1-ol.
  • the at least one deodorant aromatic alcohol of the structure (AA-1) as described above is preferably in a total amount of 0.01-5 wt%, more preferably 0.1
  • deodorant agents are selected from 1, 2-alkanediols having 7 to 16 carbon atoms in the molecule, in particular 1, 2-octanediol, 1, 2-decanediol and 1, 2-dodecanediol.
  • Further preferred deodorant or antiperspirant compositions according to the invention are characterized in that the at least one deodorant active ingredient is present in a total amount of 0.1-20% by weight, preferably 0.2-10% by weight, particularly preferably 0 3
  • compositions according to the invention contain both at least one deodorant and at least one antiperspirant active.
  • the aerosol sprays according to the invention can be in the form of a water-in-oil emulsion, water-in-silicone oil emulsions, oil-in-water emulsion, silicone oil-in-water emulsion, water-in-oil microemulsion, oil-in-water Microemulsion, silicone oil-in-water microemulsion, polyol-in-oil emulsion, oil-in-polyol emulsion, polyol-oil multiple emulsion, each having only a low water content (e.g.
  • Alcoholic solution in particular ethanolic solution, hydroalcoholic solution, solution, in particular as a solution in propylene glycol, glycerol, dipropylene glycol and (under normal conditions) liquid polyethylene glycols, hydroglycolic solution, Polyol solution, water-polyol solution and as an aqueous gel.
  • All said compositions may be thickened, for example, based on fatty acid soaps, dibenzylidenesorbitol, N-acylamino acid amides, 12-hydroxystearic acid, carbomer and carbopol type polyacrylates, polyacrylamides and polysaccharides, which may be chemically and / or physically modified.
  • the compositions of the invention may be transparent, translucent or opaque.
  • the blowing agent d) according to the invention is of particular advantage because it significantly reduces the flammability of the entire composition.
  • the low flammability of the blowing agent d) according to the invention also has an effect on compositions according to the invention which contain no ethanol, and also represents a surprising advantage for them.
  • compositions according to the invention may contain a total of 0.05 to 5 wt .-%, preferably 0.1 to 2 wt .-%, particularly preferably 0.5 to 1 wt .-%, each based on the total weight of the blowing agent-free composition, at least one wax component with a melting point> 50 ° C included.
  • Preference according to the invention for example, natural vegetable waxes, z. Candelilla wax, carnauba wax, Japan wax, sugarcane wax, ouricoury wax, cork wax, sunflower wax, fruit waxes such as orange waxes, lemon waxes, grapefruit wax, and animal waxes, e.g. Beeswax, shellac wax and spermaceti.
  • waxes For the purposes of the invention, it may be particularly preferred to use hydrogenated or hardened waxes.
  • a wax component and chemically modified waxes especially the hard waxes, such as.
  • montan ester waxes hydrogenated jojoba waxes and Sasol waxes used.
  • Synthetic waxes which are also preferable in the invention include, for example, polyalkylene waxes and polyethylene glycol waxes, C 2 ° C 40 dialkyl esters of dimer acids, C 30 -5o-alkyl and alkylaryl esters of Alkylbienenwachs and dimer fatty acids.
  • a particularly preferred wax component is selected from at least one ester of a saturated, monohydric C 6 -C 60 -alcohol and a saturated C 8 -C 36 -monocarboxylic acid.
  • lactides the cyclic double esters of alpha-hydroxy carboxylic acids of the corresponding chain length, also belong thereto.
  • the preferred esters are composed of saturated branched or unbranched monocarboxylic acids and saturated branched or unbranched monohydric alcohols.
  • esters of aromatic carboxylic acids or hydroxycarboxylic acids (eg 12-hydroxystearic acid) and saturated branched or unbranched alcohols can be used according to the invention, provided that the wax component has a melting point> 50 ° C.
  • the wax components from the group of esters of saturated branched or unbranched alkanecarboxylic acids having a chain length of 12 to 24 carbon atoms and the saturated branched or unbranched alcohols having a chain length of 16 to 50 carbon atoms and having a melting point> 50 ° C have.
  • a wax component C 6 . 36 alkyl stearates and C 8 _ 38 -Alkylhydroxystearoyl- stearates C 20 -4o-Alkylerucate and Cetearylbehenat be advantageous.
  • the wax or the wax components have a melting point> 50 ° C, preferably> 60 ° C, on.
  • the wax component comprises a C 2 -C 40 -alkyl stearate, cetyl behenate, stearyl behenate, cetearyl behenate or mixtures thereof.
  • Further preferred wax components with a melting point> 50 ° C are the triglycerides of saturated and optionally hydroxylated C 2 - 3 o fatty acids such as hydrogenated triglyceride fats (hydrogenated palm oil, hydrogenated coconut oil, hydrogenated castor oil), glyceryl tribehenate (tribehenin) or glyceryl tri-12-hydroxystearat further synthetic Vollester of fatty acids and glycols or polyols containing 2 - 6 carbon atoms as long as they have a melting point above 50 ° C, for example, preferably C 18 - C 36 acid triglyceride (Syncrowax HGL-C ®).
  • hydrogenated castor oil is particularly preferred as the wax component.
  • Further preferred wax components having a melting point> 50 ° C are the saturated linear C 4 - C 36 carboxylic acids, in particular myristic acid, palmitic acid, stearic acid and behenic acid and mixtures of these compounds, eg. B. Syncrowax ® AW 1 C (C 8 - C 36 -Fett- acids) or Cutina ® FS 45 (palmitic and stearic acid).
  • Oil-in-water emulsifiers oil-in-water emulsifiers
  • compositions according to the invention which are formulated as an emulsion, in particular as an oil-in-water emulsion or a polyol-in-water emulsion, preferably comprise at least one nonionic oil-in-water emulsifier having an HLB value of more than 7
  • emulsifiers which are generally known to the person skilled in the art and are listed, for example, in Kirk-Othmer, "Encyclopedia of Chemical Technology", 3rd edition, 1979, Volume 8, pages 913-916.
  • nonionic oil-in-water emulsifiers which are suitable according to the invention, it is particularly preferable to use a mixture of nonionic oil-in-water emulsifiers in order to optimally adjust the stability of O / W emulsion compositions according to the invention.
  • the individual emulsifier components provide a proportion of the total HLB value or mean HLB value of the oil-in-water emulsifier mixture according to their weight fraction of the total weight of the nonionic and optionally present ionic oil-in-water emulsifiers.
  • the mean HLB value of the oil-in-water emulsifier mixture is 10-19, preferably 12-18 and particularly preferably 14-17.
  • the antiperspirant compositions of the present invention may also contain only a single nonionic oil-in-water emulsifier having an HLB in the range of 10-19.
  • Preferred antiperspirant compositions according to the invention are characterized in that the nonionic oil-in-water emulsifiers are selected from ethoxylated C 8 -C 24 -alkanols having on average 10 to 100 moles of ethylene oxide per mole of ethoxylated C 8 -C 24 -carboxylic acids with an average of 10 to 100 moles of ethylene oxide per mole, silicone copolyols having ethylene oxide units or with ethylene oxide and propylene oxide units, alkyl mono- and oligoglycosides having 8 to 22 carbon atoms in the alkyl radical and their ethoxylated analogs, ethoxylated sterols, partial esters of polyglycerols with 2 to 10 glycerol units and esterified with 1 to 4 saturated or unsaturated, linear or branched, optionally hydroxylated C 8 - C 30 fatty acid residues, if they have an HLB value of more than 7, and mixtures of
  • the ethoxylated C 8 -C 24 -alkanols have the formula R 0 (CH 2 CH 2 O) n ll, where R is a linear or branched alkyl and / or alkenyl radical having 8-24 carbon atoms and n, the average number of Ethylene oxide units per molecule, for numbers from 10 to 100, preferably 10 to 30, mol of ethylene oxide to 1 mol of caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, isocetyl alcohol, palmitoleyl alcohol, stearyl alcohol, isostearyl alcohol, Oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol, and technical mixtures thereof.
  • adducts of 10-100 moles of ethylene oxide with technical fatty alcohols having 12-18 carbon atoms, such as coconut, palm, palm kernel or tallow fatty alcohol are suitable.
  • the ethoxylated C 8 -C 24 carboxylic acids have the formula R (OCH 2 CH 2 ) n OH, where R is a linear or branched saturated or unsaturated acyl radical having 8-24 carbon atoms and n, the average number of ethylene oxide units per Molecule, for numbers from 10 to 100, preferably 10 to 30, mol of ethylene oxide to 1 mol of caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, cetylic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, arachidic acid, gadoleic acid, Behenic acid, erucic
  • Adducts of 10 to 100 moles of ethylene oxide with technical fatty acids containing 12 to 18 carbon atoms, such as coconut, palm, palm kernel or tallow fatty acid, are also suitable. Particularly preferred are PEG-50 monostearate, PEG-100 monostearate, PEG-50 monooleate, PEG-100 monooleate, PEG-50 monolaurate and PEG-100 monolaurate.
  • C 2 -C 8 -alkanols or the C 2 -C 8 -carboxylic acids with in each case 10 to 30 units of ethylene oxide per molecule and also mixtures of these substances, in particular ceteth-12, ceteth-20, ceteth-30, isoceteth- 20, steareth-12, steareth-20, steareth-21, steareth-30, ceteareth-12, ceteareth-20, ceteareth-30, laureth-12 and beheneth-20.
  • C 8 -C 22 -alkyl mono- and -oligoglycosides preference is given to using C 8 -C 22 -alkyl mono- and -oligoglycosides.
  • C 8 -C 22 -alkylmono- and -oligoglycosides are known, commercially available surfactants and emulsifiers. They are prepared in particular by reacting glucose or oligosaccharides with primary alcohols having 8-22 carbon atoms.
  • the glycoside radical monoglycosides in which a cyclic sugar residue is glycosidically linked to the fatty alcohol and oligomeric glycosides having a degree of oligomerization of up to about 8, preferably 1-2, are suitable.
  • the degree of oligomerization is a statistical mean, which is based on a homolog distribution typical for such technical products. Products which are obtainable under the trademark Plantacare ®, containing a glucosidic bond C 8 -C 6 - alkyl group at an oligoglucoside whose average degree of oligomerization at 1 - 2, in particular 1, 1 - 1, 4, is located.
  • Particularly preferred C 8 -C 22 alkyl mono- and oligoglycosides are selected from octyl glucoside, decyl glucoside, lauryl glucoside, palmityl glucoside, isostearyl glucoside, stearyl glucoside, arachidyl glucoside and behenyl glucoside and mixtures thereof.
  • the glucamine-derived acylglucamides are also suitable as nonionic oil-in-water emulsifiers.
  • Ethoxylated sterols, in particular ethoxylated soy sterols are also suitable oil-in-water emulsifiers according to the invention.
  • the degree of ethoxylation must be greater than 5, preferably at least 10, in order to have an HLB value greater than 7.
  • Suitable commercial products are, for. PEG-10 Soy Sterol, PEG-16 Soy Sterol and PEG-25 Soy Sterol.
  • partial esters of polyglycerols having 2 to 10 glycerol units and having 1 to 4 saturated or unsaturated, linear or branched, optionally hydroxylated C 8 -C 30 fatty acid radicals are preferably esterified, if they have an HLB value of more than 7 ,
  • Particularly preferred Diglycerinmonocaprylat, Diglycerinmonocaprat, diglycerol are rinmonolaurat, Triglycerinmonocaprylat, Triglycerinmonocaprat, triglycerol, Tetragly- cerinmonocaprylat, rinmonocaprat Tetraglycerinmonocaprat, Tetraglycerinmonolaurat, Pentaglycerinmonocapry- lat, Pentaglycerinmonocaprat, Pentaglycerinmonolaurat, Hexaglycerinmonocaprylat, Hexaglyce-, hexa glycerol, Hexaglycerin
  • antiperspirant compositions comprise from 5 to 97% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of from 0.1 to 50% by weight, and at least one nonionic oil.
  • in-water emulsifier in a total amount of 0.1-10% by weight, especially preferably 0.5 to 4 wt .-% and most preferably 1 to 3 wt .-%, each based on the propellant-free composition.
  • compositions which are preferred according to the invention and which are formulated as an emulsion, in particular as a water-in-oil emulsion, comprise at least one water-in-oil emulsifier having an HLB value of greater than 1.0, and less than or equal to 7.0, preferably at least one nonionic Water-in-oil emulsifier with an HLB value greater than 1, 0 and ⁇ 7.0.
  • compositions according to the invention comprise mixtures, in particular technical mixtures, of at least two water-in-oil emulsifiers.
  • Preferred water-in-oil emulsifiers with an HLB value greater than 1.0, and ⁇ 7.0 are selected from the mono- and diesters of ethylene glycol and the mono-, di-, tri- and tetra-esters of pentaerythritol with linear saturated fatty acids with 12-30, in particular 14-22, carbon atoms which may be hydroxylated, as well as mixtures thereof.
  • the mono- and diesters are preferred.
  • C 2 -C 30 fatty acid radicals preferred according to the invention are selected from lauric acid, myristic acid, palmitic acid, stearic acid, arachic acid and behenic acid radicals; particularly preferred is the stearic acid residue.
  • Particularly preferred nonionic water-in-oil emulsifiers according to the invention having an HLB value greater than 1.0, and ⁇ 7.0 are selected from pentaerythrityl monostearate, pentaerythrityl distearate, pentaerythrityl tristearate, pentaerythrityl tetrastearate, ethylene glycol monostearate, ethylene glycol distearate, and mixtures thereof.
  • particularly preferred water-in-oil emulsifiers having an HLB value greater than 1, 0 and ⁇ 7.0 are, for example, as commercial products Cutina ® PES (INCI: Pentaerythrityl distearate), Cutina ® AGS (INCI: Glycol distearate) or Cutina ® EGMS (INCI: Glycol stearate) available.
  • Cutina ® PES INCI: Pentaerythrityl distearate
  • Cutina ® AGS INCI: Glycol distearate
  • Cutina ® EGMS INCI: Glycol stearate
  • These commercial products are already mixtures of mono- and diesters (in the pentaerythrityl esters are also tri- and tetraesters contain). Under a technical mixture, for example, a commercial product such as Cutina ® understood PES.
  • Sterols ie steroids which carry a hydroxyl group at the C3 atom of the steroid skeleton and both from animal tissue (zoosterols, eg cholesterol, lanosterol) as well as from plants (phytosterols, eg ergosterol, stigmasterol, sitosterol) and from fungi and yeasts (mycosterols) which may be low ethoxylated (1-5 EO);
  • Alkanols and carboxylic acids each having 8-24 C atoms, in particular having 16-22 C atoms, in the alkyl group and 1-4 ethylene oxide units per molecule which have an HLB value of greater than 1.0, and less than or equal to 7.0 exhibit,
  • Partial esters of polyglycerols with n 2 to 10 glycerol units and with 1 to 5 saturated or unsaturated, linear or branched, optionally hydroxylated C 8 - C 30 fatty acid residues esterified, if they have an HLB value of less than or equal to 7,
  • Particularly advantageously usable water-in-oil emulsifiers are stearyl alcohol, cetyl alcohol, glyceryl monostearate, glyceryl Glycerylmonocaprinat, glyceryl, glyceryl monolaurate, glyceryl monomyristate rylmonooleat, glyceryl, Glycerylmonohydroxystearat, glycerol, lenglycolmonostearat Glycerylmonolanolat, Glyceryldimyristat, Glyceryldipalmitat, glyceryl, propylene, propylene glycol , Sorbitan monocaprylate, sorbitan monolaurate, sorbitan monomyristate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquistearate, sorbitan tandearate, sorbitan dioleate, sorbitan sesquioleate, suc
  • W / O emulsifiers are silicone-free polymeric water-in-oil emulsifiers, in particular PEG-30 dipolyhydroxystearate, available for. B. under the trade name Arlacel P 135 from Uniqema.
  • this emulsifier can be formulated low viscosity, sprayable water-in-oil emulsions.
  • total amounts of at least one silicone-free water-in-oil emulsifier of from 2 to 3 to 3.5% by weight, based on the total weight of the blowing agent-free composition may be extraordinarily preferred according to the invention.
  • deodorant or antiperspirant compositions contain from 5 to 97% by weight of free water, from 0.1 to 30% by weight of at least one surfactant, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1-50 wt .-%, each based on the propellant-free composition, and further at least one polysaccharide.
  • compositions according to the invention are packaged as an oil-in-water emulsion which is not a microemulsion and comprise 0.5-6.5% by weight of oil or fat phase comprising at least one liquid which is liquid at 20 ° C.
  • An oil component selected from linear and branched saturated mono- or polyhydric C 3 -C 30 -alkanols etherified with at least one propylene oxide unit per molecule, propylene glycol monoesters of branched saturated C 6 -C 30 -alkanecarboxylic acids and branched saturated C 0 -C 30 -Alkano- len, further at least 60 - 97 wt .-% free water, and at least one antiperspirant Wrkstoff.
  • Polysaccharides (glycans, polyglycans) is the collective term for macromolecular carbohydrates whose molecules consist of a large number (at least> 10, but usually significantly more) of glycosidically linked monosaccharide molecules (glycoses).
  • the preferred polysaccharides according to the invention include, in particular, the biopolymers starch, cellulose and dextran, which can be regarded as the polycondensation product of D-glucose (polyglucosans, glucans), inulin as polycondensate of D-fructose (polyfructosan, fructan), chitin and alginic acid ,
  • suitable polysaccharides are both non-modified polysaccharides, such as xanthan or starch, and chemically modified polysaccharide derivatives, such as Aluminium Congressoctenylsuccinat, hydroxypropylmethylcellulose or dehydrated xanthan (INCI: dehydroxanthan gum), as well as physically modified polysaccharides, for example by thermal Treatment pregelatinized starch, understood.
  • Preferred polysaccharides according to the invention are selected from starches, in particular from corn, potatoes and wheat, their constituents such as amylose and amylopectin, starch hydrolysates and starch degradation products, such as maltodextrin, the physically or chemically modified starch derivatives, in particular the anionic starch derivatives Aluminium Staroctenylsuccinat, Natrium Positionoctenylsuccinat, Calcium Whyoctenylsuccinat, Ditialphosphaten , Hydroxyethyl starch phosphates, hydroxypropyl starch phosphates, sodium carboxymethyl starches and sodium starch glycolate, cellulose, the chemically modified cellulose derivatives methylcellulose, hydroxypropylcellulose, hydroxyethylcellulose, hydroxypropylmethylcellulose, hydroxypropylethylcellulose, hydroxyethylmethylcellulose and carboxymethylcellulose.
  • Polysaccharides that form gums or gums such as guar gum, xanthan gum, dehydroxanthan gum, alginates, especially sodium alginate, gum arabic, karaya gum, carrageenans, locust bean gum, linseed gums, and agar-agar, may also be included. but are less preferred. In a particularly preferred embodiment, the compositions according to the invention are free of polysaccharide gums.
  • compositions according to the invention are free of guar gum, xanthan gum, dehydroxanthan gum, alginates, in particular sodium alginate, gum arabic, karaya gum, carrageenans, locust bean gum, linseed gums and agar agar.
  • compositions according to the invention are characterized in that the at least one polysaccharide is selected from anionic and nonionic polysaccharides and mixtures thereof.
  • compositions according to the invention are characterized in that the at least one polysaccharide is selected from anionic and nonionic polysaccharides which do not form polysaccharide gums.
  • antiperspirant compositions according to the invention are characterized in that the anionic polysaccharide is selected from aluminum starch octenyl succinate, sodium starch octenyl succinate, calcium starch octenyl succinate, distarch phosphates, hydroxyethyl starch phosphates, hydroxypropyl starch phosphates, sodium carboxymethyl starches, sodium starch glycolate and Mixtures thereof.
  • An anionic polysaccharide extraordinarily preferred according to the invention is aluminum starch octenylsuccinate.
  • compositions according to the invention are characterized in that the nonionic polysaccharide is selected from starches, starch hydrolysates, cellulose, methyl cellulose, hydroxypropyl cellulose, hydroxyethyl cellulose, hydroxypropylmethyl cellulose, hydroxypropyl cellulose propylethylcellulose, hydroxyethylmethylcellulose and mixtures thereof.
  • compositions according to the invention are characterized in that the at least one polysaccharide is present in a total amount of 0.01-1.0% by weight, preferably 0.05 - 0.5 and particularly preferably 0.09 - 0.2 wt .-%, each based on the total weight of the blowing agent-free emulsion is included.
  • Antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that the at least one linear or branched saturated mono- or polyhydric C 3 -C 30 -alkanol which has been etherified with at least one propylene oxide unit per molecule , is selected from adducts of at least 6 propylene oxide units per molecule of monovalent or polyvalent C 3 .
  • 30 -alkanols in particular butanol, butanediol, myristyl alcohol and stearyl alcohol.
  • Particularly preferred such compounds are selected from PPG-13 butyl ether, PPG-14 butyl ether, PPG-9 butyl ether, PPG-10-butanediol and PPG-15 stearyl ether and mixtures thereof.
  • compositions according to the invention in the form of oil-in-water emulsions are characterized in that the at least one propylene glycol monoester of branched saturated C 6 -C 30 -alkanecarboxylic acids is selected from propylene glycol monoisostearate, propylene glycol monoisopalmitate, propylene glycol monoisobehenate, propylene glycol glycol monoisoarachinate, propylene glycol monoisomyristate, propylene glycol monoisocaprate, propylene glycol monoisocaprate and propylene glycol monoisocaprylate, and mixtures thereof.
  • the at least one propylene glycol monoester of branched saturated C 6 -C 30 -alkanecarboxylic acids is selected from propylene glycol monoisostearate, propylene glycol monoisopalmitate, propylene glycol monoisobehenate, propylene glycol glycol monoisoarachinate, propylene glycol monois
  • compositions according to the invention in the form of oil-in-water emulsions are characterized in that the at least one branched saturated C 10 -C 30 -alkanol is selected from isostearyl alcohol, isocetyl alcohol, isomyristyl alcohol, isotridecyl alcohol, isoarachidyl alcohol, isobehenyl alcohol, isocapryl alcohol, Isocaprinyl alcohol, isocaprylyl alcohol, and mixtures thereof.
  • compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range from 3 to 6 is present.
  • the at least one nonionic emulsifier having an HLB value in the range 3-6 selected from linear saturated and unsaturated C 2 - C 30 alkanols containing 1-4 ethylene oxide units per molecule which are highly preferred are steareth, ceteth, myristeth, laureth, trideceth, araffleth and beheneth each having 1-4 ethylene oxide units per molecule, especially steareth-2, steareth-3, steareth-4, ceteth-2, ceteth 3, ceteth-4, myristeth-2, myristeth-3, myristeth-4, laureth-2, laureth-3, laureth-4, trideceth-2, trideceth-3 and trideceth-4 and mixtures thereof.
  • compositions in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range of 3-6 in a total amount of 1, 8 to 3 wt .-%, based on the total weight of the composition of the invention is included.
  • compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range from 3 to 6, selected from steareth-2, steareth-3, steareth -4, ceteth-2, ceteth-3, ceteth-4, myristeth-2, myristeth-3, myristeth-4, laureth-2, laureth-3, laureth-4, trideceth-2, trideceth-3 and trideceth-4 and mixtures thereof, in a total amount of 1, 8 - 3 wt .-%, based on the total weight of the propellant-free composition according to the invention is contained.
  • compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range from 12 to 18 is contained.
  • Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that the at least one nonionic emulsifier having an HLB value in the range of 12-18 is selected from linear saturated and unsaturated C 2 -C 24 - Alkanols etherified with 7 to 40 ethylene oxide units per molecule.
  • the aforementioned emulsifiers are particularly preferably selected from steareth, ceteth, myristeth, laureth, trideceth, araffleth and beheneth, each having 7 to 40 ethylene oxide units per molecule, in particular steareth-10, steareth-20, steareth-21, steareth-30, steareth -40, ceteth-10, ceteth-20, ceteth-21, ceteth-30, ceteth-40, laureth-10, laureth-20, laureth-30, trideceth-10, trideceth-20 and trideceth-30 and mixtures thereof.
  • compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range of 12-18, which is preferably selected from steareth-10, steareth-20, steareth- 21, steareth-30, steareth-40, ceteth-10, ceteth-20, ceteth-21, ceteth-30, ceteth-40, laureth-10, laureth-20, laureth-30, trideceth-10, trideceth-20 and Trideceth-30 and mixtures thereof, in a total amount of 1 - 2 wt .-%, based on the total weight of the composition according to the invention.
  • compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range from 3 to 6 and at least one nonionic emulsifier having an HLB value in the range from 12 to 18 are included.
  • compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range from 3 to 6 in a total amount of 1.8 to 3% by weight and at least one nonionic emulsifier having an HLB value in the range of 12-18 in a total amount of 1 - 2 wt .-%, wherein the amounts are in each case based on the total weight of the composition according to the invention.
  • compositions according to the invention in the form of oil-in-water emulsions are characterized in that they have a nonionic emulsifier with an HLB value in the range of 3 to 6 steareth-2 and simultaneously as a nonionic emulsifier with an HLB value in the range of 12 - 18 steareth-21 is included.
  • deodorant or antiperspirant compositions in the form of oil-in-water emulsions are characterized in that steareth-2, steareth-21 and PPG-15 stearyl ether are included.
  • deodorant or antiperspirant compositions in the form of oil-in-water emulsions are characterized in that at least one polysaccharide selected from aluminum starch octenyl succinate and distarch phosphates is contained.
  • Further inventively preferred deodorant or antiperspirant compositions in the form of oil-in-water emulsions are characterized in that steareth-2, steareth-21, PPG-15-stearyl ether and Aluminium Congressoctenylsuccinat are included.
  • deodorant or antiperspirant compositions in the form of oil-in-water emulsions are characterized in that the weight ratio of nonionic emulsifiers having an HLB value in the range of 3-6 and nonionic emulsifiers having an HLB value in the range from 12 to 18 from 0.9 to 3, preferably 1, 3 to 1, 9.
  • deodorant or antiperspirant compositions in the form of oil-in-water emulsions are characterized in that a total of at most 3% by weight, preferably at most 1% by weight and particularly preferably 0% by weight, in each case based on the total weight of the propellant-free composition according to the invention, of monohydric - C 3 -alkanols, such as ethanol or isopropanol.
  • compositions according to the invention which are formulated as a water-in-oil emulsion, comprise at least one silicone-based water-in-oil emulsifier.
  • Preferred deodorant or antiperspirant compositions according to the invention contain from 5 to 97% by weight of free water, at least one antiperspirant active substance and / or at least one deodo-antiperspirant.
  • PEG / PPG-18/18 dimethicones z. B. in a 1: 9 mixture with Cyclomethicone under the name Dow Corning 3225 C or Dow Corning 5225 C is commercially available
  • PEG / PPG-18/18 Dimethicone the z. B. in a 1: 3 mixture with non-volatile dimethicone as Dow Corning ES 5227 DM formulation Aid commercially available
  • PEG / PPG-4/12 Dimethicone, the z. B. under the name Abil B 8852 is available
  • bis-PEG / PPG-14/14 Dimethicone the z. B.
  • silicone-based W / O emulsifiers which are preferred according to the invention are poly (C 2 -C 3 ) -alkylene glycol-modified silicones which are hydrophobically modified with C 4 -C 8 -alkyl groups, particularly preferably cetyl PEG / PPG-10/1 Dimethicone (formerly: Cetyl Dimethicone Copolyol, eg available as Abil EM 90 or in a mixture of polyglyceryl-4-isostearate, Cetyl PEG / PPG-10/1 dimethicone and hexyl laurate under the trade name Abil WE 09), furthermore alkyl methicone Copolyols and Alkyl Dimethicone Ethoxy Glucosides.
  • poly (C 2 -C 3 ) -alkylene glycol-modified silicones which are hydrophobically modified with C 4 -C 8 -alkyl groups, particularly preferably cetyl PEG / PPG-10/1
  • Particularly preferred deodorant or antiperspirant compositions according to the invention comprise from 5 to 97% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of from 0.1 to 50% by weight and the silicone rubber.
  • HLB values can also be calculated according to Griffin, as described, for example, in the R ⁇ MPP Chemie Lexikon, in particular in the online version of November 2003, and the manuals cited there under the heading "HLB system" by Fiedler, Kirk-Othmer and If there is different information on the HLB value of a substance in the literature, the HLB value for the teaching according to the invention which comes closest to the value calculated according to Griffin should be used can not determine a unique HLB value, the HLB value, which indicates the manufacturer of the emulsifier to use for the teaching of the invention.If this is not possible, the HLB value is determined experimentally for those from H.
  • compositions according to the invention are characterized in that the total content of nonionic and ionic emulsifiers and / or surfactants with an HLB value above 8 not more than 20 wt .-%, preferably at most 15 wt .-%, particularly preferably at most 10 wt .-% , particularly preferably at most 7 wt .-%, more preferably at most 4 wt .-% and most preferably at most 3 wt .-%, each based on the total composition of the invention is.
  • compositions of the present invention which are in the form of an emulsion, preferably further contain at least one oil which is liquid at 20 ° C. and which is not a fragrance component and does not represent an essential oil.
  • Phospholipids and lecithins are according to the invention to the surfactants, not to oils or waxes.
  • Cosmetic oils preferred according to the invention are selected from silicone oils, to which z.
  • dialkyl and alkylaryl such as cyclopentasiloxane, cyclohexasiloxane, dimethylpolysiloxane and methylphenylpolysiloxane, but also hexamethyldisiloxane, octamethyltrisiloxane and decamethyltetrasiloxane include.
  • Particularly preferred are volatile silicone oils, which may be cyclic, such as. For example, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and dodecamethylcyclohexasiloxane and mixtures thereof, as described, for. B.
  • volatile linear silicone oils in particular hexamethyldisiloxane (L 2 ), octamethyltrisiloxane (L 3 ), decamethyltetrasiloxane (L 4 ), dodecamethylpentasiloxane (L 5 ), as well as any two, three and four mixtures of L 2 , L 3 , L 4 and / or L 5 , as z.
  • Dow Corning® 200 (0.65 cSt) and Dow Corning® 200 (1.5 cSt) from Dow Corning contained, wherein the values of the kinematic viscosity relate to a temperature of 25 ° C.
  • compositions of the invention are free of cyclomethicones.
  • volatile non-silicone oil In addition to or instead of the at least one volatile silicone oil, it is also possible for at least one volatile non-silicone oil to be present.
  • volatile non-silicone oils are selected from C 8 -C 6 -isoalkanes, in particular from isodecane, isododecane, isotetradecane and isohexadecane and mixtures thereof.
  • compositions according to the invention may further comprise at least one non-volatile cosmetic oil selected from non-volatile silicone oils and non-volatile non-silicone oils.
  • Preferred nonvolatile silicone oils are selected from higher molecular weight linear dimethyl polysiloxanes, commercially available for.
  • Nonvolatile silicone oils which are likewise preferred in accordance with the invention are selected from silicones selected from integers of 1 to 20, preferably 1 to 3.
  • a preferred silicone oil of formula (Sil-1) is available under the INCI name Phenyl Trimethicone.
  • Natural and synthetic hydrocarbons such as paraffin oils, C 8 -C 30 - isoalkanes, particularly isoeicosane, polyisobutenes or polydecenes, the ®, for example, under the designation Emery ® 3004, 3006, 3010 or under the name Ethylflo ® from Albemarle or Nexbase 2004G from Nestle are available, as well as 1, 3-di- (2-ethylhexyl) -cyclohexane (obtainable, for. example, under the trade name Cetiol ® S from BASF) also belong to the invention preferred non-volatile non-silicone oils.
  • paraffin oils C 8 -C 30 - isoalkanes, particularly isoeicosane, polyisobutenes or polydecenes
  • the ® for example, under the designation Emery ® 3004, 3006, 3010 or under the name Ethylflo ® from Albemarle or Nexbase 2004G from Nestle are
  • non-volatile non-silicone oils which are preferred according to the invention are selected from the benzoic acid esters of linear or branched C 8 . 22 -alkanols. Particularly preferred are benzoic C12-C15 alkyl esters, z. B. available as a commercial product Finsolv ® TN, benzoic isostearylester, z. B. available as a commercial product Finsolv ® SB, ethylhexyl benzoate, z. B. available as a commercial product Finsolv ® EB, and Benzoekladyldocecylester, z. B. available as a commercial product Finsolv ® BOD.
  • benzoic C12-C15 alkyl esters z. B. available as a commercial product Finsolv ® TN
  • benzoic isostearylester z. B. available as a commercial product Finsolv ® SB
  • ethylhexyl benzoate z. B. available
  • Such benzoic acid ester oils have a pleasant feel on the skin.
  • Further non-volatile non-silicone oils which are preferred according to the invention are selected from branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms. These alcohols are also often referred to as Guerbet alcohols, as they are obtainable by the Guerbet reaction.
  • Preferred alcohol oils are 2-hexyldecanol, 2-octyldodecanol and 2-ethylhexyl alcohol.
  • Non-volatile non-silicone oils are selected from mixtures of Guerbet alcohols and Guerbet alcohol esters, e.g. 2-hexyldecanol and 2-hexyldecyl laurate.
  • non-volatile non-silicone oils which are preferred according to the invention are selected from the triglycerides of linear or branched, saturated or unsaturated, optionally hydroxylated C 8 . 30- fatty acids. Particularly suitable may be the use of natural oils, for example soybean oil, cottonseed oil, sunflower oil, palm oil, palm kernel oil, linseed oil, almond oil, castor oil, corn oil, rapeseed oil, olive oil, sesame oil, thistle oil, wheat germ oil, peach kernel oil and the liquid portions of coconut oil and the like. But are also synthetic triglyceride oils, in particular Capric / Caprylic triglycerides, with unbranched fatty acid residues and z. B. glyceryl triisostearin with branched fatty acid residues.
  • non-volatile non-silicone oils which are particularly preferred according to the invention are selected from the dicarboxylic acid esters of linear or branched C 2 -C 0 -alkanols, in particular diisopropyl adipate, di-n-butyl adipate, di (2-ethylhexyl) adipate, dioctyl adipate, diethyl / di-n- butyl / dioctyl sebacate, diisopropyl sebacate, dioctyl malate, dioctyl maleate, dicaprylyl maleate, diisooctyl succinate, di-2-ethylhexyl succinate and di (2-hexyldecyl) succinate.
  • dicarboxylic acid esters of linear or branched C 2 -C 0 -alkanols in particular diisopropyl adipate, di-n-but
  • non-volatile non-silicone oils which are particularly preferred according to the invention are selected from the esters of linear or branched saturated or unsaturated fatty alcohols having 2 to 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms which may be hydroxylated.
  • these include 2-hexyldecyl stearate (z. B. Eutanol ® G 16 S), hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, and 2-ethylhexyl stearate, in particular 2-ethylhexyl palmitate.
  • non-volatile non-silicone oils are selected from the addition products of 1 to 5 propylene oxide units of mono- or polyhydric C 8 _ 22 alkanols such as octanol, decanol, decanediol, lauryl alcohol, myristyl alcohol and stearyl alcohol, eg. B. PPG-2 myristyl ether and PPG-3 myristyl ether (z. B. Wtconol ® APM).
  • mono- or polyhydric C 8 _ 22 alkanols such as octanol, decanol, decanediol, lauryl alcohol, myristyl alcohol and stearyl alcohol, eg. B. PPG-2 myristyl ether and PPG-3 myristyl ether (z. B. Wtconol ® APM).
  • non-volatile non-silicone oils which are particularly preferred according to the invention are selected from the adducts of at least 6 ethylene oxide and / or propylene oxide units with monovalent or polyvalent C 3 . 22 -alkanols such as glycerol, butanol, butanediol, myristyl alcohol and stearyl alcohol, which may be esterified if desired, for.
  • PPG-14 butyl ether z. B. Ucon ® fluid AP
  • PPG-9-butyl ether z. B. Breox B25 ®
  • PPG-10 butanediol z. B. Macol ® 57
  • PPG 15- stearyl ether z. B. Arlamol ® e
  • Glycereth-7-diisononanoate As PPG-14 butyl ether (z. B. Ucon ® fluid AP), PPG-9-butyl ether (z. B. Bre
  • non-volatile non-silicone oils which are particularly preferred according to the invention are selected from the C 2 -C 22 fatty alcohol esters of monohydric or polyhydric C 2 -C 7 hydroxycarboxylic acids, in particular the esters of glycolic acid, lactic acid, malic acid, tartaric acid, citric acid and salicylic acid.
  • esters based on linear C 2/5 alkanols and in the 2-position branched C 2/3 of alkanols are preferably selected from C 2 .C 5 alkyl lactate, di-C12-13-Alkylmalat and tri-C12-13 Alkyl citrate, e.g. B. available under the trademark Cosmacol ® from Nordmann, Rassmann GmbH & Co, Hamburg.
  • Another such preferred oil component is triethyl citrate.
  • non-volatile non-silicone oils are selected from the symmetrical, asymmetrical or cyclic esters of carbonic acid with fatty alcohols, eg. B. dicaprylyl or the esters according to the teaching of DE 19756454 A1.
  • compositions according to the invention are characterized in that the conditional liquid conditioner is selected from volatile silicone oils, nonvolatile silicone oils, volatile hydrocarbon oils, branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms, triglycerides of linear or branched, saturated or unsaturated, optionally hydroxylated C 8 .
  • compositions according to the invention contain at least one oil in a total amount of from 0.1 to 35% by weight, preferably from 0.5 to 25% by weight, more preferably from 1 to 15% by weight and most preferably from 2 to 8% by weight. %, in each case based on the total weight of the propellant-free composition according to the invention.
  • wax components can be used even under normal conditions.
  • Particularly preferred wax components are selected from coconut fatty acid glycerol mono-, di- and triesters, Butyrospermum Parkii (shea butter) and esters of saturated, monohydric C 8 -C 8 alcohols with saturated C 2 -C 8 monocarboxylic acids and mixtures of these substances is.
  • Further preferred esters of saturated monohydric C 2 -C 8 alcohols with saturated C 2 -C 8 monocarboxylic acids are stearyl laurate, cetearyl stearate, cetyl palmitate and myristyl myristate.
  • Conditioning agents which are preferred according to the invention are also vegetable waxes, eg. Candelilla wax, carnauba wax, Japan wax, sugarcane wax, ouricoury wax, cork wax, sunflower wax, fruit waxes such as orange waxes, lemon waxes, grapefruit wax, and animal waxes, e.g. As beeswax, shellac wax and spermaceti, hydrogenated or hardened waxes, chemically modified waxes, especially the hard waxes, such as.
  • vegetable waxes eg. Candelilla wax, carnauba wax, Japan wax, sugarcane wax, ouricoury wax, cork wax, sunflower wax, fruit waxes such as orange waxes, lemon waxes, grapefruit wax, and animal waxes, e.g. As beeswax, shellac wax and spermaceti, hydrogenated or hardened waxes, chemically modified waxes, especially the hard waxes, such as.
  • a particularly preferred wax component is selected from at least one ester of a saturated, monohydric C 6 -C 60 -alcohol and a saturated C 8 -C 36 -monocarboxylic acid.
  • lactides the cyclic double esters of alpha-hydroxycarboxylic acids of the corresponding chain length.
  • wax components are the triglycerides of saturated and optionally hydroxylated C 2 .
  • 30 fatty acids such as hardened triglyceride fats (hydrogenated palm oil, hydrogenated coconut oil, hydrogenated castor oil), glyceryl tribehenate (tribehenin) or glyceryl trihydrate 12-hydroxystearate, furthermore synthetic full esters of fatty acids and glycols or polyols having 2 to 6 carbon atoms.
  • hydrogenated castor oil is particularly preferred as the wax component.
  • Further preferred wax components are the saturated linear C 4 -C 36 -fatty alcohols, in particular myristyl alcohol, palmityl alcohol, cetyl alcohol, stearyl alcohol, arachidyl alcohol and behenyl alcohol, and also mixtures of these compounds.
  • compositions according to the invention comprise at least one wax component in a total amount of from 0.1 to 5% by weight, preferably 0.2 to 4% by weight, more preferably 0.5 to 3% by weight and most preferably 1 to 2% by weight .-%, in each case based on the total weight of the blowing agent-free composition according to the invention.
  • Particularly preferred deodorant or antiperspirant compositions according to the invention are characterized in that the oil (s) liquid at 20 ° C. in a total amount of 0.1-80% by weight, preferably 2-20% by weight, particularly preferably 3-15% by weight, in each case based on the total weight of the blowing agent-free composition, is / are contained.
  • a proportion of the oil components of at least 80 wt .-%, a refractive index n D of 1, 39 - 1, 51 on.
  • Water-in-oil emulsion sprays contain no zirconium-containing salts due to regulatory requirements.
  • the zirconium-free antiperspirant active compounds described above are also suitable for water-in-oil emulsion sprays according to the invention.
  • Preferred compositions according to the invention, which are formulated as a water-in-oil emulsion spray, comprise at least one zirconium-free aluminum salt as antiperspirant active in a total amount of 5-40% by weight, preferably 10-35% by weight and more preferably 15-28% by weight and exceptionally neat preferably 23-27% by weight, in each case based on the total weight of the water-free active substance (USP) in the blowing agent-free composition.
  • USP water-free active substance
  • compositions according to the invention which are formulated as a water-in-oil emulsion spray, comprise free water in a total amount of 10 to 85% by weight, preferably 15 to 75% by weight, particularly preferably 20 to 65% by weight, extraordinarily preferably 25-55% by weight, furthermore very preferably 30-40% by weight, in each case based on the total weight of the blowing agent-free composition.
  • the outer phase of preferred water-in-oil emulsions according to the invention comprises at least one cosmetic oil.
  • Oils which are preferred as constituents of preferred water-in-oil emulsions according to the invention have already been mentioned above.
  • Water-in-oil emulsions preferred according to the invention comprise 10 to 85% by weight of free water, at least one antiperspirant active substance and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, 0.1 to 30% %
  • surfactant including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and 1-40% by weight of at least one cosmetic oil selected from branched saturated or unsaturated fatty alcohols with 6 to 30 carbon atoms, dicarboxylic acid esters of linear or branched C 2 -C 0 -alkanols, addition products of 1 to 5 propylene oxide units to mono- or polyhydric C 8
  • water-in-oil emulsions which contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight are preferred %, 0.1-30% by weight of surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and 1-40% by weight of at least one cosmetic Oil selected from two and three mixtures of C 8 -C 6 isoalkanes, linear dimethylpolysiloxanes having kinematic viscosities in the range of 5 to 100 cSt (25 ° C) and esters of linear or branched saturated or unsaturated fatty alcohols having 2 to 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms which may be hydroxylated , contain.
  • surfactant including at least one water-in-oil emulsifier
  • water-in-oil emulsions which contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, 0.1-30% by weight of surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and 1-40% by weight of at least one cosmetic oil, selected from two and three mixtures of C 8 -C 6 -alkanes, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5 - 100 cSt (25 ° C) and esters of linear or branched saturated or unsaturated fatty alcohols having 2 - 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms, which may be hydroxylated, and are free of cyclomethicones.
  • water-in-oil emulsions containing 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, 0.1-30% by weight of surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, at least one water-in-oil emulsifier, in particular a silicone-based Water-in-oil emulsifier, and 1 - 40 wt .-% of at least one cosmetic oil selected from two and three mixtures of C 8 -C 6 -lsoalkanen, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5 - 100 cSt (25 ° C) and esters selected from hexyldecyl stearate, hexyldecyl laurate, isodecy
  • water-in-oil emulsions containing 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, 0.1-30% by weight of surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, at least one water-in-oil emulsifier, in particular a silicone-based Water-in-oil emulsifier, and 1 - 40 wt .-% of at least one cosmetic oil selected from two and three mixtures of C 8 -C 6 -lsoalkanen, linear dimethylpolysiloxanes having kinematic viscosities in the range of 5 - 100 cSt (25 ° C) and esters selected from hexyldecyl stearate, hexyldecyl laurate, isodecy
  • water-in-oil emulsions which contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight , 1 - 30 wt .-% surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and 1-40 wt .-% of at least one cosmetic oil selected from two and tri-mixtures of C 8 -C 6 isoalkanes, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5-100 cSt (25 ° C.) and esters of linear or branched saturated or unsaturated fatty alcohols having 2-30 carbon atoms with linear or branched saturated or unsaturated fatty acids having from 2 to 30 carbon atoms, which may be hydroxylated, are free of cyclomethicones and are packaged
  • water-in-oil emulsions containing 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight , 1 - 30 wt .-% surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and 1-40 wt .-% of at least one cosmetic oil selected from two and tri-mixtures of C 8 -C 6 isoalkanes, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5-100 cSt (25 ° C.) and esters selected from hexyldecylstearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palm
  • water-in-oil emulsions containing 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight , 1 - 30 wt .-% surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and 1-40 wt .-% of at least one cosmetic oil selected from two and tri-mixtures of C 8 -C 6 -alkanes, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5-100 cSt (25 ° C.) and esters selected from hexyldecylstearate, hexyldecyl laurate, isodecylneopentanoate, isononylisononanoate, 2-ethylhexyl palmitate
  • the at least one cosmetic oil is present in the inventive compositions which are present as emulsion (O / W or W / O) in a total amount of 1-40% by weight, preferably 2-30% by weight, particularly preferably 5%. 25 wt .-% and most preferably 10 to 20 wt .-%, each based on the total weight of the propellant-free deodorant or antiperspirant composition.
  • Further water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-free water-in-oil emulsifier as described above in a total amount of 0.1-15% by weight, preferably 0.5-8.0% by weight, and particularly preferably 1-4% by weight , and 1 - 40 wt .-% of at least one cosmetic oil selected from branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms, dicarboxylic acid esters of linear or branched C 2 -C 0 alkanols, addition products of 1 to 5 propylene oxide units to a - or polyvalent C 8 .
  • Further water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-based water-in-oil emulsifier as described above in a total amount of 0.1-5% by weight, more preferably 0.5-3.5% by weight, most preferably 1.0-0.3% by weight.
  • At least one cosmetic oil selected from branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms, dicarboxylic acid esters of linear or branched C 2 -C 0 alkanols, addition products of 1 to 5 propylene oxide units mono- or polyvalent C 8 . 22 -alkanols, addition products of at least 6 ethylene oxide and / or propylene oxide units to monovalent or polyvalent C 3 .
  • Further water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-based water-in-oil emulsifier selected from PEG / PPG-18/18 dimethicones, in a total amount of 0.1-5% by weight, more preferably 0.5-3.5% by weight, exceptionally preferred 1, 0 to 3 wt .-%, and 1-40 wt .-% of at least one cosmetic oil selected from branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms, dicarboxylic acid esters of linear or branched C 2 -C 0 alkanols, addition products from 1 to 5 propylene oxide units to mono- or polyhydric C 8 .
  • 22 -alkanols addition products of at least 6 ethylene oxide and / or propylene oxide units to monovalent or polyvalent C 3 .
  • 22 -alkanols esters of linear or branched saturated or unsaturated fatty alcohols having 2 to 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms which may be hydroxylated, dicaprylyl carbonate, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, hexamethyldisiloxane (L 2 ), octamethyltrisiloxane (L 3 ), decamethyltetrasiloxane (L 4 ), dodecamethylpentasiloxane (L 5 ), as well as any two, three and four mixtures of L 2 , L 3 , L 4 and / or L 5 , linear dimethylpolys
  • water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-free water-in-oil emulsifier as described above in a total amount of 0.1-15% by weight, preferably 0.5-8.0% by weight, and particularly preferably 1-4% by weight and from 1 to 40% by weight of at least one cosmetic oil selected from mixtures of two and three of C 8 -C 6 -alkanes, linear dimethylpolysiloxanes having kinematic viscosities in the range from 5 to 100 cSt (25 ° C.) and esters selected from hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyliso nonanoate, 2-ethylhexyl palmitate
  • these water-in-oil emulsions are free of cyclomethicones.
  • Further water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-based water-in-oil emulsifier as described above in a total amount of 0.1-5% by weight, more preferably 0.5-3.5% by weight, most preferably 1.0-0.3% by weight.
  • At least one cosmetic oil selected from two and three mixtures of C 8 -C 6 - isoalkanes, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5 - 100 cSt (25 ° C) and Esters selected from hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononan
  • Further water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-based water-in-oil emulsifier selected from PEG / PPG-18/18 dimethicones, in a total amount of 0.1-5% by weight, more preferably 0.5-3.5% by weight, exceptionally preferably 1, 0-3 wt .-%, and 1 - 40 wt .-% of at least one cosmetic oil selected from two- and three-mixtures of C 8 -C 6 -lsoalkanen, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5 100 cSt (25 ° C.) and esters
  • these water-in-oil emulsions are free of cyclomethicones.
  • the water-in-oil emulsions preferred according to the invention contain from 10 to 85% by weight of free water, at least one antiperspirant active and / or at least one deodorant active substance in a total amount of from 0.1 to 50 % By weight, at least one silicone-free water-in-oil emulsifier as described above in a total amount of 0.1-15 wt .-%, preferably 0.5 to 8.0 wt .-%, and particularly preferably 1 to 4% by weight, 1 to 40% by weight of at least one cosmetic oil, and at least one nonionic polyalkylene glycol ether having an HLB value of> 7, which is preferably selected from isoceteth-20, the quantities given in each case referring to Total weight of the propellant-free deodorant or antiperspirant composition are related.
  • the nonionic polyalkylene glycol ether having an HLB value> 7 is preferably in a total amount of 0.1-3 wt.%, Preferably 0.5-1.5 wt.%, In each case based on the total weight of the blowing agent-free deodorant or antiperspirant Composition, included.
  • these water-in-oil emulsions are free of cyclomethicones.
  • the water-in-oil emulsions preferred according to the invention contain from 10 to 85% by weight of free water, at least one antiperspirant active and / or at least one deodorant active substance in a total amount of from 0.1 to 50 % By weight, at least one silicone-based water-in-oil emulsifier as described above, in a total amount of 0.1-5% by weight, more preferably 0.5-3.5% by weight, extremely preferably 1, 0-3 wt .-%, 1 - 40 wt .-% of at least one cosmetic oil, and at least one nonionic polyalkylene glycol ether having an HLB value> 7, which is preferably selected from isoceteth-20, wherein the amounts are in each case on the total weight of the antifriction antiperspirant composition are related.
  • the water-in-oil emulsions preferred according to the invention contain from 10 to 85% by weight of free water, at least one antiperspirant active and / or at least one deodorant active substance in a total amount of from 0.1 to 50 %
  • at least one water-in-oil emulsifier based on silicone selected from PEG / PPG-18/18 dimethicones, in a total amount of 0.1-5 wt.%, Particularly preferably 0.5-3, 5% by weight, exceptionally preferably 1, 0-3% by weight, 1-40% by weight of at least one cosmetic oil, and at least one nonionic polyalkylene glycol ether having an HLB value> 7, which is preferably selected from Isoceteth- 20, wherein the amounts are each based on the total weight of the blowing agent-free deodorant or antiperspirant composition.
  • the nonionic polyalkylene glycol ether having an HLB value> 7 is preferably in a total amount of 0.1-3 wt.%, Preferably 0.5-1.5 wt.%, In each case based on the total weight of the blowing agent-free deodorant or antiperspirant Composition, included.
  • Further water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-based water-in-oil emulsifier as described above in a total amount of 0.1-5% by weight, more preferably 0.5-3.5% by weight, most preferably 1.0-0.3% by weight.
  • At least one cosmetic oil selected from mixtures of two and three of C 8 -C 6 -alkanes, linear dimethylpolysiloxanes with kinematic viscosities in the range from 5 to 100 cSt (25 ° C.) and esters selected from hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononanoate, isotridec
  • water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-based water-in-oil emulsifier selected from PEG / PPG-18/18 dimethicones, in a total amount of 0.1-5% by weight, more preferably 0.5-3.5% by weight, exceptionally preferably 1, 0-3 wt .-%, 1-40 wt .-% of at least one cosmetic oil selected from two- and three-mixtures of C 8 -C 6 -lsoalkanen, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5 - 100 cSt (25 ° C) and esters selected from hexyldecyl stearate, hexyldecyl laurate, isodecyl neopent
  • the nonionic polyalkylene glycol ether having an HLB value> 7 is preferably in a total amount of 0.1-3 wt.%, Preferably 0.5-1.5 wt.%, In each case based on the total weight of the blowing agent-free deodorant or antiperspirant Composition, included.
  • compositions of the invention preferably contain at least one propellant selected from
  • CHF 2 CF CFCF 2 CF 3
  • CF 3 CF CFCF 2 CHF 2
  • CF 3 CF CFCHFCF 3
  • CHF CFCF (CF 3 ) 2
  • CHF CF (CF 2 ) 2 CHF 2
  • CH 2 C (CF 3 ) C 2 F 5
  • CF 2 CHCH (CF 3 ) 2
  • CHF CHCF (CF 3 ) 2
  • CH 2 CFCH (CF3) 2
  • CHF CHCH (CF3) 2
  • CH 2 FCH C (CF 3) 2
  • CH 3 CF C (CF3) 2
  • CH 2 CHCF 2 CHFCF 3
  • CH 2 C (CF 3 ) CH 2 CF 3
  • (CF 3 ) 2 C CHC 2 F 5
  • CH 2 CHC (CF 3 ) 3
  • the amount of blowing agent is not taken into account in the weight data for the other components of the compositions according to the invention.
  • the propellant-free composition according to the invention is mixed with the entire propellant (propellant according to formula (I), in particular fluorocarbon or a fluorohydrocarbon d) i) or d) ii) and optionally further propellants) in a composition / propellant weight ratio from 2/98 to 98/2 , preferably 5/95 to 95/5, more preferably 10/90 to 90/10, more preferably 15/85 to 85/15, still more preferably 20/80 to 80/20, further preferably 30/70 to 70/30, and also 40/60 to 60/40 and 50/50, filled in a suitable aerosol spray can.
  • propellant propellant according to formula (I), in particular fluorocarbon or a fluorohydrocarbon d) i) or d) ii) and optionally further propellants
  • the £ -CF 3 CH CHF (£ -1, 3,3,3-tetrafluoropropene-1) is contained as the sole propellant.
  • the fluorocarbon (s) or the fluorocarbon (s) d) i) or d) ii) in combination with at least one further blowing agent selected from propane, propene, n-butane, isobutane, isobutene, n-pentane, pentene, iso-pentane, iso-pentene, methane, ethane, dimethyl ether, nitrogen, carbon dioxide, air, oxygen, nitrous oxide, 1, 1, 1, 3-tetrafluoroethane, heptafluoro-n-propane, perfluoroethane, monochlorodifluoromethane, 1, 1 - difluoroethane, and mixtures of these blowing agents to use.
  • compositions of the invention are packaged with the propellant in a suitable pressure vessel.
  • Containers made of metal (aluminum, tinplate, tin), protected or non-splitterndem plastic or glass, which is coated with plastic on the outside, in question, in their selection pressure and fracture resistance, corrosion resistance, easy fillability as well as aesthetic Aspects, handiness, printability etc. play a role.
  • Special internal protective lacquers ensure the corrosion resistance with respect to the suspension according to the invention.
  • An inner protective lacquer which is preferred according to the invention is an epoxy phenolic lacquer.
  • compositions of the invention may also be packaged in a multi-chamber dispenser.
  • the multi-chamber dispenser can also be used so that one chamber is filled with the composition according to the invention, while another chamber contains the compressed propellant.
  • Such a multi-chamber dispenser is for example a so-called bag-in-can packaging.
  • This material is particularly suitable for masking residues of antiperspirant aluminum salts. It is there for these effects immaterial whether cyclohexane-1, 4-dimethanol as a pure c / 's-isomer, as a pure trans-isomer or as a mixture of isomers of cis- and iran-isomer is used.
  • Commercially available 1,4-dimethylolcyclohexane is present as a cis / trans isomeric mixture. This isomer mixture has the CAS No. 105-08-8.
  • a preferred isomer mixture according to the invention contains 29-33% by weight of cis-isomer (CAS No. 3236-47-3) and 71-67% by weight of trans-isomer (CAS No. 3236-48-4) and has a refractive index n D 20 of 1.487.
  • n D 20 refractive index
  • deodorant or antiperspirant compositions according to their propellant-free total weight, 1-12 wt .-%, preferably 2-10 wt .-%, particularly preferably 3-7 wt .-% 1, 4-dimethylolcyclo hexane.
  • a further preferred embodiment of the invention is characterized in that 0.01 to 5 wt .-%, preferably 0.05 to 2 wt .-%, particularly preferably 0.1 to 1 wt .-%, each based on the total inventive Composition, a mineral mixture obtained from a natural mineral water, a thermal water or a natural healing water is included.
  • a mineral mixture obtained from a natural mineral water, a thermal water or a natural healing water is included.
  • such mineral mixtures can further improve the antiperspirant performance of the compositions according to the invention.
  • such mineral mixtures may have a favorable effect on the skin compatibility of the compositions according to the invention.
  • Natural mineral water is based on the definition of the German Mineral and Table Water Ordinance (MinTafWV, ⁇ 2) .
  • the mineral mixture is considered to be the solid residue of the named waters.
  • Occupationally preferred mineral mixtures originate from the thermal water of La Toja (Spain), Bad Blumau, Bad Radkersburg, Aachen, Wiesbaden (all Germany), Carlsbad (Czech Republic), La Bourboule, Enghien-les-bains, Allevard-les-bains, Digne, Nyrac-Ies- bains, Lons le Saunier, Eaux Bonnes, Rochefort, les Fumades, Saint Christau, Uriage-les-bains, La Roche-Posay (all France) or the natural mineral or medicinal waters of Evian, Volvic, Vichy, Avene, Vittel (all France), Gerolstein or fraingen (Germany) preferred compositions contain at least one water-soluble polyhydric C 2 -C 9 -alkanol with 2-6 hydroxyl groups and
  • Water solubility according to the invention is understood to mean a solubility of at least 5% by weight at 20 ° C., that is to say amounts of at least 5 g of the polyol in 95 g of water are soluble at 20 ° C.
  • Preferred compositions according to the invention contain at least one water-soluble polyhydric C 2 -C 9 -alkanol having 2 to 6 hydroxyl groups and / or at least one water-soluble polyethylene glycol having 3 to 20 ethylene oxide units and mixtures thereof.
  • These components are preferably selected from 1,2-propylene glycol, 1,3-propylene glycol, 2-methyl-1,3-propanediol, glycerol, 1,2-butylene glycol, 1,3-butylene glycol and 1,4-butylene glycol.
  • pentyleneglycols such as 1, 2-pentanediol and 1, 5-pentanediol
  • hexanediols such as 1, 2-hexanediol and 1, 6-hexanediol
  • hexanetriols such as 1, 2,6-hexanetriol
  • 1, 2-octanediol 1, 8- Octanediol
  • dipropylene glycol tripropylene glycol, diglycerol, triglycerol, erythritol, sorbitol and mixtures of the aforementioned substances.
  • Suitable water-soluble polyethylene glycols are selected from PEG-3, PEG-4, PEG-6, PEG-7, PEG-8, PEG-9, PEG-10, PEG-12, PEG-14, PEG-16, PEG-18 and PEG-20 and mixtures thereof, with PEG-3 to PEG-8 being preferred.
  • compositions according to the invention comprise the at least one water-soluble polyhydric C 2 -C 9 -alkanol having 2 to 6 hydroxyl groups and / or at least one water-soluble polyethylene glycol having 3 to 20 ethylene oxide units in a total amount of 0.5 to 30% by weight, preferably 3 to 20 wt .-%, particularly preferably 5 to 10 wt .-%, each based on the total weight of the blowing agent-free composition.
  • the above-described water-in-oil emulsions preferably contain at least one water-soluble polyhydric C 2 -C 9 -alkanol having 2 to 6 hydroxyl groups and / or at least one water-soluble polyethylene glycol having 3 to 20 ethylene oxide units in total in amounts of 3 to 30 Wt .-%, preferably 8 - 25 wt .-%, particularly preferably 10 - 18 wt .-%, each based on the blowing agent-free composition.
  • compositions comprising
  • At least one surfactant in a total amount of 0.2-20% by weight, more preferably 0.5-10% by weight, most preferably 1-8% by weight,
  • At least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1-50% by weight
  • compositions contain at least one hydrogel former.
  • hydrogel formers are selected from cellulose ethers, especially hydroxyalkylcelluloses, in particular hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, carboxymethylcellulose, cetylhydroxyethylcellulose, hydroxybutylmethylcellulose, methylhydroxyethylcellulose, furthermore xanthan gum, sclerotium gum, succinoglucans, polygalactomannans, in particular guar gum and locust bean gum (Locust bean gum), in particular guar gum and locust bean gum itself and the nonionic hydroxyalkyl guar derivatives and locust bean gum derivatives such as hydroxypropyl guar, carboxymethylhydroxy propylguar, hydroxypropylmethylguar, hydroxyethylguar and carboxymethylguar, furthermore pectins, agar, carrageenan, tragacanth
  • compositions preferred according to the invention comprise at least one hydrogel former in a total amount of 0.1-3.0% by weight, preferably 0.3-2.0% by weight, more preferably 0.5-1.5% by weight and extraordinarily preferably 0.7-1.0% by weight, in each case based on the total weight of the total composition according to the invention.
  • compositions according to the invention are in the form of hydrogels and contain at least one hydrogel former in a total amount of 0.1-3.0% by weight, preferably 0.3-2.0% by weight, particularly preferably 0, 5-1.5% by weight and most preferably 0.7-1.0% by weight, based in each case on the total weight of the total composition according to the invention.
  • Compositions which are particularly preferred according to the invention furthermore preferably contain at least one skin-cooling active substance.
  • Skin-cooling active ingredients suitable according to the invention are, for example, menthol, isopulegol and menthol derivatives, eg.
  • Preferred skin-cooling active substances are menthol, isopulegol, menthyl lactate, menthoxypropanediol and menthylpyrrolidonecarboxylic acid, and also mixtures of these substances, in particular mixtures of menthol and menthyl lactate, menthol, menthol glycolate and menthyl lactate, menthol and menthoxypropanediol or menthol and isopulegol.
  • At least one skin-cooling active substance to be present in a total amount of 0.01-1% by weight, more preferably 0.02-0.5% by weight and most preferably 0.05-0.2-0.3% by weight %, in each case based on the total weight of the propellant-free composition is included.
  • compositions of the invention may contain other additives such as pH regulators, buffering agents, electrolytes, preservatives, chelating agents, antioxidants, thickeners, pigments, dyes, anti-wrinkle agents, active ingredients which increase skin moisture, e.g. As urea, alkyl-substituted ureas, betaine, or carnitine, plant extracts, alpha-hydroxycarboxylic acids.
  • Preferred deodorant or antiperspirant compositions according to the invention comprise at least one perfume.
  • the fragrances are as disclosed in the priority document to this application, DE102010055816.8, on page 66, line 1 to page 67, third last line.
  • Dodorant- or antiperspirant compositions are characterized in that at least one fragrance component in a total amount of 0.00001 to 10 wt .-%, preferably 0.5 to 7 wt .-%, particularly preferably 1 - 5 wt. %, in each case based on the propellant-free composition is included.
  • compositions according to the invention comprise at least one hair growth inhibiting substance.
  • Preferred compositions according to the invention comprise at least one hair growth inhibiting substance in a total amount of 0.0001-5 wt.%, Preferably 0.001-2 wt.%, Particularly preferably 0.01-1 wt.%, And most preferably 0, 1 to 0.5% by weight, based in each case on the weight of the active substance of the hair growth inhibiting active substance (s) and the total weight of the propellant-free composition according to the invention.
  • Contained active substances in particular deodorant active substances, fragrances and / or skin-cooling active substances, may preferably also be present in encapsulated form.
  • Contained active substances in particular deodorant active substances, fragrances and / or skin-cooling active substances, may preferably also be present in supported form, for example on zeolite, titanium dioxide, silica and other adsorbents.
  • Contained active substances in particular deodorant active substances, fragrances and / or skin-cooling active substances, may preferably also be complexed in form, for example cyclodextrin, to be present.
  • Example 1 Antiperspirant Emulsions According to the Invention (Oil-in-Water Emulsions) (Quantities in% by Weight)
  • Sprayable, translucent antiperspirant microemulsions (in% by weight)
  • Example Composition 4.1 contains an antiperspirant emulsion according to the invention with 9.9
  • Example Composition 4.2 contains an antiperspirant emulsion according to the invention with 17.49% by weight aluminum chlorohydrate, based on the weight of the propellant-free emulsion. At a spray rate of 0.2 g / s, 0.035 g of the antiperspirant active ingredient aluminum chlorohydrate is sprayed onto the skin surface every second.
  • Water-in-oil emulsion for administration as a spray (with propellant) (in% by weight)
  • Deodorant foams (amounts in% by weight based on the content of active substance)
  • the example compositions according to the invention are applied to the skin, in particular the underarm skin.
  • a further subject of the present application is a method for non-therapeutic sweat reduction, which is characterized in that a composition according to the invention or a preferred composition according to the invention is applied to the skin, in particular the underarm skin.
  • compositions according to the invention applies mutatis mutandis.

Abstract

The invention relates to deodorant and antiperspirant compositions which are sprayed with selected fluorocarbons or hydrofluorocarbons as propellants.

Description

„Deodorant- und Antitranspirant-Zusammensetzungen Zusammensetzung zur Verhinderung von Körpergeruch" "Deodorant and antiperspirant compositions composition for the prevention of body odor"
Gegenstand der vorliegenden Anmeldung sind Deodorant- und Antitranspirant-Zusammensetzun- gen, die mit ausgewählten Fluorkohlenstoffen oder Fluorkohlenwasserstoffen als Treibmittel versprüht werden. The present application relates to deodorant and antiperspirant compositions which are sprayed with selected fluorocarbons or fluorohydrocarbons as propellants.
Das Waschen, Reinigen und Pflegen des eigenen Körpers stellt ein menschliches Grundbedürfnis dar, und die moderne Industrie versucht fortlaufend, diesen Bedürfnissen des Menschen in vielfältiger Weise gerecht zu werden. Besonders wichtig für die tägliche Hygiene ist die anhaltende Beseitigung oder zumindest Reduzierung des Körpergeruchs. Körpergeruch entsteht zu einem großen Teil aus der bakteriellen Zersetzung einzelner Bestandteile des Schweißes auf der Haut. Apokriner Schweiß stellt eine komplexe Mischung dar, die unter anderem Steroide, Cholesterin und andere Fette sowie ca. 1 0 % Eiweiße enthält. Die Zersetzungsprodukte des apokrinen Schweißes, die wesentlich zum Körpergeruch, insbesondere zum axillaren Körpergeruch, beitragen, lassen sich in zwei Klassen einteilen, zum einen kurzkettige, insbesondere C4-C 0-Fettsäu- ren, die linear, verzweigt, gesättigt und ungesättigt sein können, zum anderen verschiedene Steroidhormone und deren Abbauprodukte. Beispielsweise sind an dem typischen Körpergeruch, besonders an dem der Männer, die Stoffwechselprodukte der Androgene beteiligt, insbesondere Androstenol (5a-androst-16-en-3ß-ol, 5a-androst-16-en-3a-ol) und Androstenon (5a-androst-16- en-3-οη). Steroide selbst sind nicht wasserlöslich. Um mit den Körperflüssigkeiten abtransportiert werden zu können, liegen sie normalerweise als Sulfat oder als Glucuronid vor. Auf der Haut erfolgt die Spaltung dieser Steroidester in die flüchtigen freien Steroide durch hydrolytische Enzyme der Hautbakterien, insbesondere der coryneformen Bakterien. Prinzipiell sind dazu alle bakteriellen Exoesterasen in der Lage, besonders die Enzyme Arylsulfatase und ß-Glucuronidase. Die Fettbestandteile des (apokrinen) Schweißes werden über diverse Lipasen und Esterasen hydroly- siert, wobei überwiegend kurzkettige, insbesondere C4-C 0-Fettsäuren, entstehen, die ebenfalls stark riechen. Washing, cleansing and caring for one's own body is a fundamental human need, and modern industry is constantly trying to meet these needs of man in a variety of ways. Especially important for daily hygiene is the permanent elimination or at least reduction of body odor. Body odor arises to a large extent from the bacterial decomposition of individual components of perspiration on the skin. Apocrine sweat is a complex mixture that contains steroids, cholesterol and other fats as well as about 1% protein. The decomposition products of apocrine perspiration, which contribute significantly to the body odor, in particular to the axillary body odor, can be divided into two classes, one short-chain, in particular C 4 -C 0 -fatty acids, which may be linear, branched, saturated and unsaturated , on the other various steroid hormones and their degradation products. For example, the typical body odor, especially of men, involves the metabolic products of androgens, in particular androstenol (5a-androst-16-en-3β-ol, 5a-androst-16-en-3a-ol) and androstenone (5a -androst-16-en-3-οη). Steroids themselves are not water soluble. In order to be carried away with the body fluids, they are usually present as sulfate or as glucuronide. On the skin, the cleavage of these steroid esters in the volatile free steroids by hydrolytic enzymes of the skin bacteria, especially the coryneform bacteria. In principle, all bacterial exoesterases are capable of this, especially the enzymes arylsulfatase and .beta.-glucuronidase. The fatty components of the (apocrine) sweat are hydrolyzed by various lipases and esterases, predominantly short-chain, in particular C 4 -C 0 -fatty acids, which also smell strongly.
Genau so vielfältig, wie die Bestandteile des Schweißes und die Ursachen für die Körpergeruchsentwicklung sind, sind auch die deodorierenden Wirkstoffe der handelsüblichen Deodorantien. Als kosmetische deodorierende Wirkstoffe einsetzbar sind Geruchsabsorber, Duftstoffe, desodorierend wirkende Ionenaustauscher, keimhemmende Mittel, präbiotisch wirksame Komponenten sowie Enzyminhibitoren. Bei der Körperdeodorierung kann man grob unterscheiden zwischen Wirkstoffen, die bereits entstandene unangenehm riechende Substanzen absorbieren (Zinkricinoleat, Cyclodextrine, Ionenaustauscher) oder überdecken (Duftstoffe, Parfüms), und Wrkstoffen, die die Zersetzung des Schweißes und die Entstehung der unangenehm riechende Substanzen verhindern oder zumindest verlangsamen (keimhemmende Wirkstoffe, präbiotisch wirksame Komponenten sowie Enzyminhibitoren). Just as diverse as the components of sweat and the causes of the development of body odor are the deodorants of commercial deodorants. Suitable odor absorbers, fragrances, deodorizing ion exchangers, germ-inhibiting agents, prebiotic components and enzyme inhibitors can be used as cosmetic deodorizing agents. In body deodorization, one can roughly differentiate between active substances which absorb unpleasant-smelling substances already formed (zinc ricinoleate, cyclodextrins, ion exchangers) or cover up (fragrances, perfumes), and impurities which prevent, or at least prevent the decomposition of perspiration and the formation of unpleasant-smelling substances slow down (germ-inhibiting active ingredients, prebiotic components and enzyme inhibitors).
Im Stand der Technik sind zahlreiche spezielle deodorierende Körperpflegemittel bekannt, die für die Anwendung in Körperregionen mit einer hohen Dichte von Schweißdrüsen, insbesondere in der Unterarmregion und an den Füßen, entwickelt wurden. Diese sind in den unterschiedlichsten Darreichungsformen konfektioniert, beispielsweise als Puder, in Stiftform, als Aerosolspray, Pumpspray, flüssige und gelförmige Roll on-Applikation, Creme, Gel und als getränktes flexibles Substrat (Deotücher).  Numerous specific deodorant personal care products are known in the art which have been developed for use in body regions having a high density of sweat glands, particularly in the forearm region and on the feet. These are packaged in a wide variety of dosage forms, for example as powder, in stick form, as aerosol spray, pump spray, liquid and gel roll on application, cream, gel and as a soaked flexible substrate (towels).
Eine interessante Variante zur Dosierung von Zusammensetzungen zur Verhinderung von Körpergeruch stellen treibmittelhaltige Sprühspender dar, die die Zusammensetzung als Mousse, das heißt, als feinblasigen Schaum, ausbringen. Je nach Anwendungsgebiet lassen sich sowohl schnell brechende als auch stabile Schäume herstellen. Bei Pflegeprodukten, die zur Deodorie- rung der Haut, insbesondere der Achselhöhlen, aufgetragen werden, hilft die Schaumform, wasserhaltige Produkte so zu applizieren, dass sie nicht sofort an der Haut herunterlaufen, sondern auf der Applikationsfläche verbleiben und dort in die Haut einziehen können oder aber eingerieben werden können. Außerdem verleiht die Applikation als Mousse ein interessantes Hautgefühl.  An interesting variant for the dosing of compositions for the prevention of body odor is propellant-containing spray dispenser, which apply the composition as a mousse, that is, as a fine bubble foam. Depending on the field of application, both fast-breaking and stable foams can be produced. In the case of care products that are applied to deodorizing the skin, in particular the armpits, the foam form helps to apply water-containing products in such a way that they do not run down immediately on the skin but remain on the application area where they can penetrate into the skin or but can be rubbed. In addition, the application gives as a mousse an interesting skin feeling.
Für die Qualität eines Schaums, der aus einer wasser- und tensidhaltigen Zusammensetzung mit einem Treibmittel erzeugt wird, spielt die Löslichkeit des Treibmittels im Wasser eine wichtige Rolle. Übliche Kohlenwasserstoff-Treibmittel, wie Propan, n-Butan und Isobutan, weisen eine geringe Löslichkeit im Wasser auf, während ein polares Treibmittel wie Dimethylether eine sehr hohe Löslichkeit im Wasser aufweist. Die mit diesen Treibmitteln erzeugten Schäume sind in ihrer Qualität, insbesondere in Bezug auf die Stabilität bzw. die Geschwindigkeit des Brechens, auf die Feinblasigkeit und die sensorischen Eigenschaften weiter verbesserungsbedürftig.  For the quality of a foam, which is produced from a water and surfactant-containing composition with a blowing agent, the solubility of the blowing agent in the water plays an important role. Typical hydrocarbon blowing agents, such as propane, n-butane and isobutane, have a low solubility in water, while a polar blowing agent, such as dimethyl ether, has a very high solubility in water. The foams produced with these blowing agents are in their quality, especially in terms of the stability or the rate of breakage, on the fine bubbles and the sensory properties in need of further improvement.
Eine weitere interessante Variante zur Dosierung von Zusammensetzungen zur Verhinderung von Körpergeruch stellen treibmittelhaltige Sprühspender dar, die die Zusammensetzung als nichtschäumende oder nur gering schäumende Emulsion ausbringen. Hierbei ist es bedeutsam, dass das Treibmittel nicht die Stabilität der Emulsion beeinträchtigt, damit - ähnlich wie bei den Schäumen - die Emulsion auf der Applikationsfläche verbleibt und nicht die wässrige und die ölige Phase sofort an der Haut herunterlaufen. Another interesting variant for the dosing of compositions for the prevention of body odor are propellant-containing spray dispensers which apply the composition as a non-foaming or only slightly foaming emulsion. It is important that the blowing agent does not affect the stability of the emulsion, so that - similar to the foams - the emulsion remains on the application surface and not the aqueous and the oily phase immediately run down the skin.
Aufgabe Der vorliegenden Anmeldung lag die Aufgabe zu Grunde, eine treibmittelhaltige verschäumbare kosmetische Zusammensetzung zur Verhinderung von Körpergeruch bereitzustellen, die gegenüber den Zusammensetzungen des Standes der Technik verbesserte Eigenschaften, insbesondere in Bezug auf die Schaumstabilität, die Feinblasigkeit und die sensorischen Eigenschaften, aufweist. task The present application was based on the object of providing a propellant-containing foamable cosmetic composition for the prevention of body odor, which has improved properties compared with the compositions of the prior art, in particular with regard to foam stability, fine bubbles and sensory properties.
Eine weitere Aufgabe der vorliegenden Anmeldung war es, eine treibmittelhaltige kosmetische Zusammensetzung zur Verhinderung von Körpergeruch in Emulsionsform bereitzustellen, die gegenüber den Zusammensetzungen des Standes der Technik verbesserte Eigenschaften, insbesondere in Bezug auf die Emulsionsstabilität und die sensorischen Eigenschaften, aufweist. Eine weitere Aufgabe der vorliegenden Anmeldung war es, eine treibmittelhaltige kosmetische Zusammensetzung zur Verhinderung von Körpergeruch bereitzustellen, die gegenüber den Zusammensetzungen des Standes der Technik eine verringerte Entflammbarkeit aufweist.  Another object of the present application was to provide a propellant-containing cosmetic composition for the prevention of body odor in emulsion form, which has improved properties compared to the compositions of the prior art, in particular with regard to the emulsion stability and the sensory properties. A further object of the present application was to provide a propellant-containing cosmetic composition for the prevention of body odor, which has a reduced flammability compared to the compositions of the prior art.
Überraschend wurde gefunden, dass sich mit einem Treibmittel, das aus ungesättigten Fluorkohlenstoffen und ungesättigten Fluorkohlenwasserstoffen sowie Mischungen hiervon ausgewählt ist, Deodorant- und Antitranspirant-Zusammensetzungen des Standes der Technik insbesondere in Bezug auf Schaum- oder Emulsionsstabilität, Feinblasigkeit (bei Schäumen) und sensorische Eigenschaften optimieren lassen. Surprisingly, it has been found that with a propellant selected from unsaturated fluorocarbons and unsaturated fluorohydrocarbons, as well as mixtures thereof, prior art deodorant and antiperspirant compositions, especially with respect to foam or emulsion stability, fine bubbles (in foams) and sensory properties optimize.
Gegenstand der vorliegenden Anmeldung sind Deodorant- oder Antitranspirant-Zusammenset- zungen, enthaltend  The present application relates to deodorant or antiperspirant compositions containing
a) 5 - 97 Gew.-% freies Wasser,  a) 5 to 97% by weight of free water,
b) 0,1 - 30 Gew.-% mindestens eines Tensids,  b) 0.1-30% by weight of at least one surfactant,
c) 0,1 - 50 Gew.-% mindestens eines Deodorant- oder Antitranspirant-Wirkstoffs, wobei sich die Mengenangaben auf das Gesamtgewicht der treibmittelfreien Deodorant- oder Antitranspirant-Zusammensetzung beziehen,  c) 0.1-50% by weight of at least one deodorant or antiperspirant active, the quantities being based on the total weight of the propellant-free deodorant or antiperspirant composition,
d) mindestens ein Treibmittel, ausgewählt aus mindestens einer Verbindung mit 3 bis 10 Kohlenstoffatomen gemäß Formel (I)  d) at least one blowing agent selected from at least one compound having 3 to 10 carbon atoms according to formula (I)
Figure imgf000004_0001
Figure imgf000004_0001
worin die Reste R , R2, R3 und R4 unabhängig voneinander ein Wasserstoffatom, ein Bromatom, ein Fluoratom oder eine mit mindestens einem Fluoratom substituierte (CT - C6)-Alkylgruppe bedeuten, in which the radicals R, R 2 , R 3 and R 4, independently of one another, denote a hydrogen atom, a bromine atom, a fluorine atom or a (CT - C 6 ) -alkyl group substituted by at least one fluorine atom,
oder zwei der Reste R , R2, R3 und R4 einen fünf- oder sechsgliedrigen Ring bilden, mit der Maßgabe, dass: - mindestens einer der Reste R , R2, R3 oder R4 für ein Wasserstoffatom oder ein Fluoratom steht, und or two of the radicals R, R 2 , R 3 and R 4 form a five- or six-membered ring, with the proviso that: at least one of R, R 2 , R 3 or R 4 is a hydrogen atom or a fluorine atom, and
- mindestens einer der Reste R , R2, R3 oder R4 für eine mit mindestens einem Fluoratom substituierte (C^ bis C6)-Alkylgruppe steht oder mindestens zwei der Reste R , R2, R3 und R4 einen fünf- oder sechsgliedrigen Ring bilden . at least one of the radicals R, R 2 , R 3 or R 4 is a (C 1 to C 6 ) -alkyl group substituted by at least one fluorine atom or at least two of the radicals R, R 2 , R 3 and R 4 represent a or form a six-membered ring.
Bevorzugte Zusammensetzungen sind durch ein Treibmittel der Formel (I) gekennzeichnet, wobei R , R2, R3 oder R4 gemäß Formel (I) unabhängig voneinander ein Wasserstoffatom, ein Fluoratom oder eine mit mindestens einem Fluoratom substituierte (C^ bis C6)-Alkylgruppe bedeuten, mit der Maßgabe, dass: Preferred compositions are characterized by a propellant of formula (I) wherein R, R 2 , R 3 or R 4 of formula (I) are independently hydrogen, fluorine or (C 1 to C 6 ) Alkyl group, with the proviso that:
- mindestens einer der Reste R , R2, R3 oder R4 für ein Wasserstoffatom oder ein Fluoratom steht, und at least one of R, R 2 , R 3 or R 4 is a hydrogen atom or a fluorine atom, and
- mindestens einer der Reste R , R2, R3 oder R4 für eine mit mindestens einem Fluoratom substituierte (C^ bis C6)-Alkylgruppe steht. - At least one of the radicals R, R 2 , R 3 or R 4 is a substituted with at least one fluorine atom (C ^ to C 6 ) alkyl group.
Weitere bevorzugte erfindungsgemäße Zusammensetzungen sind dadurch gekennzeichnet, dass Treibmittel der Formel (I) aus mindestens einer Verbindung der Gruppe gewählt wird , die gebildet wird aus  Further preferred compositions according to the invention are characterized in that blowing agent of the formula (I) is selected from at least one compound of the group which is formed
einem Fluorkohlenstoff oder einem Fluorkohlenwasserstoff aus der Gruppe, bestehend aus einem Fluorkohlenwasserstoff mit der Formel £-R CH=CHR2 oder Z-R CH=CHR2, worin R und R2 unabhängig voneinander eine perfluorierte Cr bis C6-Alkylgruppe darstellen, sowie aus Mischungen der vorgenannten Substanzen, oder a fluorocarbon or a fluorohydrocarbon selected from the group consisting of a fluorohydrocarbon having the formula ε-R CH = CHR 2 or ZR CH = CHR 2 , wherein R and R 2 independently represent a perfluorinated C r to C 6 alkyl group, and from Mixtures of the aforementioned substances, or
einem Fluorkohlenstoff oder einem Fluorkohlenwasserstoff aus der Gruppe, bestehend aus CF3CF=CHF, CF3CH=CF2, CHF2CF=CF2, CHF2CH=CHF, CF3CF=CH2, CF3CH=CHF, CH2FCF=CF2, CHF2CH=CF2, CHF2CF=CHF, CHF2CF=CH2, CF3CH=CH2, CH3CF=CF2, CH2FCH=CF2, CH2FCF=CHF, CHF2CH=CHF, CF3CF=CFCF3, CF3CF2CF=CF2, CF3CF=CHCF3, CF3CF2CF=CH2, CF3CH=CHF3, CF3CF2CH=CH2, CF2=CHCF2CF3, CF2=CHCF2CF3, CF2=CFCHFCF3, CF2=CFCF2CHF2, CHF2CH=CHCF3, (CF3)2C=CHCF3, CF3CF=CHCF2CF3, CF3CH=CFCF2CF3, (CF3)2CFCH=CH2, CF3CF2CF2CH=CH2, CF3(CF2)3CF=CF2, CF3CF2CF=CFCF2CF3, (CF3)2C=C(CF3)2, (CF3)2CFCF=CHCF3, CF2=CFCF2CH2F, CF2=CFCHFCHF2, CH2=C(CF3)2, CH2CF2CF=CF2, CH2FCF=CFCHF2, CH2FCF2CF=CF2, CF2=C(CF3)(CH3), CH2=C(CHF2)(CF3), CH2=CHCF2CHF2,a fluorocarbon or a fluorohydrocarbon selected from CF 3 CF = CHF, CF 3 CH = CF 2 , CHF 2 CF = CF 2 , CHF 2 CH = CHF, CF 3 CF = CH 2 , CF 3 CH = CHF, CH 2 FCF = CF 2 , CHF 2 CH = CF 2 , CHF 2 CF = CHF, CHF 2 CF = CH 2 , CF 3 CH = CH 2 , CH 3 CF = CF 2 , CH 2 FCH = CF 2 , CH 2 FCF = CHF, CHF 2 CH = CHF, CF 3 CF = CFCF 3 , CF 3 CF 2 CF = CF 2 , CF 3 CF = CHCF 3 , CF 3 CF 2 CF = CH 2 , CF 3 CH = CHF 3 , CF 3 CF 2 CH = CH 2 , CF 2 = CHCF 2 CF 3 , CF 2 = CHCF 2 CF 3 , CF 2 = CFCHFCF 3 , CF 2 = CFCF 2 CHF 2 , CHF 2 CH = CHCF 3 , (CF 3 ) 2 C = CHCF 3 , CF 3 CF = CHCF 2 CF 3 , CF 3 CH = CFCF 2 CF 3 , (CF 3 ) 2 CFCH = CH 2 , CF 3 CF 2 CF 2 CH = CH 2 , CF 3 (CF 2 ) 3 CF = CF 2 , CF 3 CF 2 CF = CFCF 2 CF 3 , (CF 3 ) 2 C = C (CF 3 ) 2 , (CF 3 ) 2 CFCF = CHCF 3 , CF 2 = CFCF 2 CH 2 F, CF 2 = CFCHFCHF 2 , CH 2 = C (CF 3 ) 2 , CH 2 CF 2 CF = CF 2 , CH 2 FCF = CFCHF 2 , CH 2 FCF 2 CF = CF 2 , CF 2 = C (CF 3 ) ( CH 3 ), CH 2 = C (CHF 2 ) (CF 3 ), CH 2 = CHCF 2 CHF 2 ,
CF2=C(CHF2)(CH3), CHF=C(CF3)(CH3), CH2=C(CHF2)2, CF3CF=CFCH3, CH3CF=CHCF3, CF2=CF(CF2)2CF3, CHF=CF(CF2)2CF3, CF2=CH(CF2)2CF3, CF2=CF(CF2)2CHF2, CHF2CF=CFCF2CF3, CF3CF=CFCF2CHF2, CF3CF=CFCHFCF3, CHF=CFCF(CF3)2, CF2=CFCH(CF3)2, CF3CH=C(CF3)2, CF2=CHCF(CF3)2, CH2=CF(CF2)2CF3,CF 2 = C (CHF 2 ) (CH 3 ), CHF = C (CF 3 ) (CH 3 ), CH 2 = C (CHF 2 ) 2 , CF 3 CF = CFCH 3 , CH 3 CF = CHCF 3 , CF 2 = CF (CF 2 ) 2 CF 3 , CHF = CF (CF 2 ) 2 CF 3 , CF 2 = CH (CF 2 ) 2 CF 3 , CF 2 = CF (CF 2 ) 2 CHF 2 , CHF 2 CF = CFCF 2 CF 3 , CF 3 CF = CFCF 2 CHF 2 , CF 3 CF = CFCHFCF 3 , CHF = CFCF (CF 3 ) 2 , CF 2 = CFCH (CF 3 ) 2 , CF 3 CH = C (CF 3 ) 2 , CF 2 = CHCF (CF 3 ) 2 , CH 2 = CF (CF 2 ) 2 CF 3 ,
CHF=CF(CF2)2CHF2, CH2=C(CF3)C2F5, CF2=CHCH(CF3)2, CHF=CHCF(CF3)2, CF2=C(CF3)CH2CF3, CH2=CF(CF2)2CHF2, CF2=CHCF2CH2CF3, CF3CF=C(CF3)CH3, CH2=CFCH(CF3)2, CHF=CHCH(CF3)2, CH2FCH=C(CF3)2, CH3CF=C(CF3)2,CHF = CF (CF 2 ) 2 CHF 2 , CH 2 = C (CF 3 ) C 2 F 5 , CF 2 = CHCH (CF 3 ) 2 , CHF = CHCF (CF 3 ) 2 , CF 2 = C (CF 3 ) CH 2 CF 3 , CH 2 = CF (CF 2 ) 2 CHF 2 , CF 2 = CHCF 2 CH 2 CF 3 , CF 3 CF = C (CF 3 ) CH 3 , CH 2 = CFCH (CF 3 ) 2 , CHF = CHCH (CF 3 ) 2 , CH 2 FCH = C (CF 3 ) 2 , CH 3 CF = C (CF 3 ) 2 ,
CH2=CHCF2CHFCF3, CH2=C(CF3)CH2CF3, (CF3)2C=CHC2F5, CH2=CHC(CF3)3, (CF3)2C=C(CH3)CF3, CH2=CFCF2CH(CF3)2, CF3CF=C(CH3)C2F5, CF3CH=CHCH(CF3)2, CH2=CH(CF2)3CHF2, (CF3)2C=CHCF2CH3, CH2=C(CF3)CH2C2F5, CH2=CHCH2CF2CF2CF3, C2F5CF=CFC2H5, CH2=CHCH2CF(CF3)2, CF3CF=CHCH(CF3)(CH3), (CF3)2C=CFC2H5, cyclo- CF2CF2CF2CH=CH-, cyclo-CF2CF2CH=CH-, CF3CF2CF2C(CH3)=CH2, CF3CF2CF2CH=CHCH3, cyclo-CF2CF2CF=CF-, cyclo-CF2CF=CFCF2CF2-, cyclo-CF2CF=CFCF2CF2CF2-,CH 2 = CHCF 2 CHFCF 3 , CH 2 = C (CF 3 ) CH 2 CF 3 , (CF 3 ) 2 C = CHC 2 F 5 , CH 2 = CHC (CF 3 ) 3 , (CF 3 ) 2 C = C (CH 3 ) CF 3 , CH 2 = CFCF 2 CH (CF 3 ) 2 , CF 3 CF = C (CH 3 ) C 2 F 5 , CF 3 CH = CHCH (CF 3 ) 2 , CH 2 = CH ( CF 2 ) 3 CHF 2 , (CF 3 ) 2 C = CHCF 2 CH 3 , CH 2 = C (CF 3 ) CH 2 C 2 F 5 , CH 2 = CHCH 2 CF 2 CF 2 CF 3 , C 2 F 5 CF = CFC 2 H 5 , CH 2 = CHCH 2 CF (CF 3 ) 2 , CF 3 CF = CHCH (CF 3 ) (CH 3 ), (CF 3 ) 2 C = CFC 2 H 5 , cycloCF 2 CF 2 CF 2 CH = CH-, cyclo-CF 2 CF 2 CH = CH-, CF 3 CF 2 CF 2 C (CH 3 ) = CH 2 , CF 3 CF 2 CF 2 CH = CHCH 3 , cyclo-CF 2 CF 2 CF = CF-, cyclo-CF 2 CF = CFCF 2 CF 2 -, cyclo-CF 2 CF = CFCF 2 CF 2 CF 2 -,
CF3CF2CF2CF2CH=CH2, CF3CH=CHC2F5, C2F5CH=CHC2F5, CF3CH=CHCF2CF2CF3, CF3CF=CFC2F5, CF3CF=CFCF2CF2CF2CF3, C2F5CF=CFCF2CF2CF3,CF 3 CF 2 CF 2 CF 2 CH = CH 2 , CF 3 CH = CHC 2 F 5 , C 2 F 5 CH = CHC 2 F 5 , CF 3 CH = CHCF 2 CF 2 CF 3 , CF 3 CF = CFC 2 F 5 , CF 3 CF = CFCF 2 CF 2 CF 2 CF 3 , C 2 F 5 CF = CFCF 2 CF 2 CF 3 ,
CF3CH=CFCF2CF2CF2CF3, CF3CF=CHCF2CF2CF2CF3, C2F5CH=CFCH2CH2CH3,CF 3 CH = CFCF 2 CF 2 CF 2 CF 3 , CF 3 CF = CHCF 2 CF 2 CF 2 CF 3 , C 2 F 5 CH = CFCH 2 CH 2 CH 3 ,
C2F5CF=CHCF2CF2CF3, CF3CF2CF2CF=CHCH3, C2F5CF=CHCH3, (CF3)2C=CHCH3, CF3C(CH3)=CHCF3, CHF=CFC2F5, CHF2CF=CFCF3, (CF3)2C=CHF, CH2FCF=CFCF3, CHF=CHC2F5, CHF2CH=CFCF3, CHF=CFCHFCF3, CF3CH=CFCHF2, CHF=CFCF2CHF2, CHF2CF=CFCHF2, CH2CF=CFCF3, CH2FCH=CFCF3, CH2=CFCHFCF3, CH2=CFCF2CHF2, CF3CH=CFCH2F, CHF=CFCH2CF3, CHF=CHCHFCF3, CHF=CHCF2CHF2, CHF2CF=CHCHF2, CHF=CFCHFCHF2, CF3CF=CHCH3, CF2=CHCF2Br, CHF=CBrCHF2, CHBr=CHCF3, CF3CBr=CFCF3, CH2=CBrC2F5, CHBr=CHC2F5, CH2=CH(CF2)2Br, CH2=CHCBrFCF3, CH3CBr=CHCF3, CF3CBr=CHCH3, (CF3)2C=CHBr, CF3CF=CBrC2F5, £-CHF2CBr=CFC2F5, Z-CHF2CBr=CFC2F5, CF2=CBrCHFC2F5, (CF3)2CFCBr=CH2, CHBr=CF(CF2)2CHF2, CH2=CBrCF2CF2CF3, CF2=C(CH2Br)CF3, CH2=C(CBrF2)CF3, (CF3)2CHCH=CHBr, (CF3)2C=CHCH2Br, CH2=CHCF(CF3)CBrF2, CF2=CHCF2CH2CBrF2, CFBr=CHCF3, CFBr=CFCF3 und CH2=CBrCF2CF2CF2CF3, jeweils in der £-Form oder der Z-Form, sowie aus Mischungen der vorgenannten Substanzen. C 2 F 5 CF = CHCF 2 CF 2 CF 3 , CF 3 CF 2 CF 2 CF = CHCH 3 , C 2 F 5 CF = CHCH 3 , (CF 3 ) 2 C = CHCH 3 , CF 3 C (CH 3 ) = CHCF 3 , CHF = CFC 2 F 5 , CHF 2 CF = CFCF 3 , (CF 3 ) 2 C = CHF, CH 2 FCF = CFCF 3 , CHF = CHC 2 F 5 , CHF 2 CH = CFCF 3 , CHF = CFCHFCF 3 , CF 3 CH = CFCHF 2 , CHF = CFCF 2 CHF 2 , CHF 2 CF = CFCHF 2 , CH 2 CF = CFCF 3 , CH 2 FCH = CFCF 3 , CH 2 = CFCHFCF 3 , CH 2 = CFCF 2 CHF 2 , CF 3 CH = CFCH 2 F, CHF = CFCH 2 CF 3 , CHF = CHCHFCF 3 , CHF = CHCF 2 CHF 2 , CHF 2 CF = CHCHF 2 , CHF = CFCHFCHF 2 , CF 3 CF = CHCH 3 , CF 2 = CHCF 2 Br, CHF = CBrCHF 2 , CHBr = CHCF 3 , CF 3 CBr = CFCF 3 , CH 2 = CBrC 2 F 5 , CHBr = CHC 2 F 5 , CH 2 = CH (CF 2 ) 2 Br, CH 2 = CHCBrFCF 3 , CH 3 CBr = CHCF 3 , CF 3 CBr = CHCH 3 , (CF 3 ) 2 C = CHBr, CF 3 CF = CBrC 2 F 5 , £ -CHF 2 CBr = CFC 2 F 5 , Z-CHF 2 CBr = CFC 2 F 5 , CF 2 = CBrCHFC 2 F 5 , (CF 3 ) 2 CFCBr = CH 2 , CHBr = CF (CF 2 ) 2 CHF 2 , CH 2 = CBrCF 2 CF 2 CF 3 , CF 2 = C (CH 2 Br) CF 3 , CH 2 = C (CBrF 2 ) CF 3 , (CF 3 ) 2 CHCH = CHBr, (CF 3 ) 2 C = CHCH 2 Br, CH 2 = CHCF (CF 3 ) CBrF 2 , CF 2 = CHCF 2 CH 2 CBrF 2 , CF Br = CHCF 3 , CFBr = CFCF 3 and CH 2 = CBrCF 2 CF 2 CF 2 CF 3 , in each case in the ε-form or the Z-form, and also from mixtures of the abovementioned substances.
Das in den erfindungsgemäßen Zusammensetzungen enthaltene Treibmittel wird für die Mengenangaben, die Inhaltsstoffe betreffen, die kein Treibmittel sind, nicht berücksichtigt. Alle Mengenangaben beziehen sich daher auf das Gesamtgewicht der treibmittelfreien Zusammensetzung, sofern nichts anderes erwähnt ist. The propellant contained in the compositions according to the invention is not taken into account for the quantities which concern non-propellant ingredients. All amounts are therefore based on the total weight of the propellant-free composition, unless otherwise stated.
„Normalbedingungen" sind im Sinne der vorliegenden Anmeldung eine Temperatur von 20 °C und ein Druck von 1013,25 mbar. Schmelzpunktangaben beziehen sich ebenfalls auf einen Druck von 1013,25 mbar.  For the purposes of the present application, "normal conditions" are a temperature of 20 ° C. and a pressure of 1013.25 mbar. Melting point data likewise relate to a pressure of 1013.25 mbar.
Wassergehalt water content
Der Gehalt der erfindungsgemäßen Zusammensetzungen an freiem Wasser beträgt 5 - 97 Gew.- %, bevorzugt 10 - 85 Gew.-%, besonders bevorzugt 15 - 75 Gew.-%, außerordentlich bevorzugt 20 - 65 Gew.-%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien Zusammensetzung. „Freies Wasser" im Sinne der vorliegenden Anmeldung ist Wasser, das nicht in Form von Kristallwasser, Hydratationswasser oder ähnlich molekular gebundenem Wasser in der Antitranspirant- Zusammensetzung enthalten ist. Der Gehalt an Kristallwasser, Hydratationswasser oder ähnlich molekular gebundenem Wasser, der in den eingesetzten Bestandteilen, insbesondere in den schweißhemmenden Wrkstoffen, enthalten ist, stellt im Sinne der vorliegenden Anmeldung kein freies Wasser dar. Freies Wasser ist beispielsweise solches Wasser, das als Lösemittel, als Gelaktivator oder als Lösemittelbestandteil anderer Wrkstoffe zur erfindungsgemäßen Zusammensetzung zugegeben wird. The free water content of the compositions according to the invention is 5-97% by weight, preferably 10-85% by weight, more preferably 15-75% by weight, most preferably 20-65% by weight, based in each case on Total weight of the blowing agent-free composition. For the purposes of the present application, "free water" is water which is not contained in the antiperspirant composition in the form of water of crystallization, water of hydration or similar molecularly bound water The content of water of crystallization, water of hydration or similar molecularly bound water, that in the constituents used For the purposes of the present application, free water is for example water which is added as a solvent, as a gel activator or as a solvent constituent of other active substances to the composition according to the invention.
Tenside surfactants
Der Tensidgehalt der erfindungsgemäßen Zusammensetzungen beträgt 0,1 - 30 Gew.-%, bevorzugt 0,2 - 20 Gew.-%, besonders bevorzugt 0,5 - 10 Gew.-%, außerordentlich bevorzugt 1 - 8 Gew.-%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien Zusammensetzung. Je nach Darreichungsform der erfindungsgemäßen Zusammensetzung können auch Tensidgehalte von 2 - 7 Gew.-% oder 4 - 6 Gew.-%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien Zusammensetzung, bevorzugt sein.  The surfactant content of the compositions according to the invention is from 0.1 to 30% by weight, preferably from 0.2 to 20% by weight, more preferably from 0.5 to 10% by weight, most preferably from 1 to 8% by weight, in each case based on the total weight of the blowing agent-free composition. Depending on the dosage form of the composition according to the invention, it is also possible to use surfactant contents of 2-7% by weight or 4-6% by weight, based in each case on the total weight of the blowing agent-free composition.
Erfindungsgemäß werden auch Emulgatoren den Tensiden zugerechnet.  According to the invention, emulsifiers are also added to the surfactants.
Als anionische Tenside eignen sich in erfindungsgemäßen Zusammensetzungen alle für die Verwendung am menschlichen Körper geeigneten anionischen oberflächenaktiven Stoffe. Diese sind gekennzeichnet durch eine wasserlöslich machende, anionische Gruppe wie z. B. eine Carboxy- lat-, Sulfat-, Sulfonat- oder Phosphat-Gruppe und eine lipophile Alkylgruppe mit etwa 8 bis 30 C- Atomen. Zusätzlich können im Molekül Glycol- oder Polyglycolether-Gruppen, Ester-, Ether- und Amidgruppen sowie Hydroxylgruppen enthalten sein. Beispiele für geeignete anionische Tensid- klassen sind, jeweils in Form der Natrium-, Kalium- und Ammonium- sowie der Mono-, Di- und Trialkanolammoniumsalze mit 2 bis 4 C-Atomen in der Alkanolgruppe:  Suitable anionic surfactants in compositions according to the invention are all anionic surfactants suitable for use on the human body. These are characterized by a water-solubilizing, anionic group such as. As a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group having about 8 to 30 carbon atoms. In addition, glycol or polyglycol ether groups, ester, ether and amide groups and hydroxyl groups may be present in the molecule. Examples of suitable anionic Tensid- classes are, in each case in the form of the sodium, potassium and ammonium and the mono-, di- and Trialkanolammoniumsalze with 2 to 4 C-atoms in the alkanol group:
lineare und verzweigte Fettsäuren mit 8 bis 30 C-Atomen (Seifen), Ethercarbonsäuren der Formel R-0-(CH2-CH20)x-CH2-COOH, in der R eine lineare Alkylgruppe mit 8 bis 18 C-Atomen und x = 0 oder 1 bis 16 ist, Acylsarcoside mit 8 bis 24 C-Atomen in der Acylgruppe, Acyltauride mit 8 bis 24 C-Atomen in der Acylgruppe, Acylisethionate mit 8 bis 24 C-Atomen in der Acylgruppe, Sulfobernsteinsäuremono- und -dialkylester mit 8 bis 24 C-Atomen in der Alkylgruppe und Sulfobernsteinsäuremono-alkylpolyoxyethylester mit 8 bis 24 C-Atomen, bevorzugt 10 - 14 C- Atomen, besonders bevorzugt 12 C-Atomen in der Alkylgruppe und jeweils 1 bis 6 Oxyethylgruppen, lineare Alkansulfonate mit 8 bis 24 C-Atomen, lineare alpha-Olefinsulfonate mit 8 bis 24 C-Atomen, alpha-Sulfofettsäuremethylester von Fettsäuren mit 8 bis 30 C-Atomen, Alkylsulfate und Alkylpolyglycolethersulfate der Formel R-0(CH2-CH20)x-OS03H, in der R eine bevorzugt lineare Alkylgruppe mit 8 bis 18 C-Atomen, bevorzugt 10 - 14 und besonders bevorzugt 12 C-Atomen und x = 0 oder 1 bis 12, besonders bevorzugt 2 - 4, ist, Gemische oberflächenaktiver Hydroxysulfonate, sulfatierte Hydroxyalkylpolyethylen- und/oder Hydroxyalkylenpropylenglycolether, Sulfonate ungesättigter Fettsäuren mit 8 bis 24 C-Atomen und 1 bis 6 Doppelbindungen, Ester der Weinsäure und Zitronensäure mit Alkoholen, die Anlagerungsprodukte von etwa 2-15 Molekülen Ethylenoxid und/oder Propylenoxid an Fettalkohole mit 8 bis 22 C-Atomen darstellen, linear and branched fatty acids having 8 to 30 C atoms (soaps), ether carboxylic acids of the formula R-O- (CH 2 -CH 2 O) x-CH 2 -COOH, in which R is a linear alkyl group having 8 to 18 C atoms and x = 0 or 1 to 16, acylsarcosides having 8 to 24 carbon atoms in the acyl group, acyl taurides having 8 to 24 carbon atoms in the acyl group, acyl isethionates having 8 to 24 carbon atoms in the acyl group, sulfosuccinic acid mono- and dialkyl ester with 8 to 24 C atoms in the alkyl group and sulfosuccinic monoalkylpolyoxyethylester having 8 to 24 carbon atoms, preferably 10-14 C atoms, more preferably 12 carbon atoms in the alkyl group and each 1-6 oxyethyl groups, linear alkanesulfonates having 8 to 24 C. Atoms, linear α-olefinsulfonates having 8 to 24 carbon atoms, alpha-sulfofatty acid methyl esters of fatty acids having 8 to 30 carbon atoms, alkyl sulfates and alkyl polyglycol ether sulfates of the formula R-O (CH 2 -CH 2 O) x -OSO 3 H, in the R is a preferably linear alkyl group having 8 to 18 carbon atoms, preferably 10 - 14 and especially more preferably 12 carbon atoms and x = 0 or 1 to 12, particularly preferably 2 to 4, is mixtures surface-active hydroxysulfonates, sulfated hydroxyalkylpolyethylene and / or hydroxyalkylene-propylene glycol ethers, sulfonates of unsaturated fatty acids having 8 to 24 carbon atoms and 1 to 6 double bonds, esters of tartaric acid and citric acid with alcohols, the adducts of about 2-15 molecules of ethylene oxide and / or propylene oxide with fatty alcohols with 8 to 22 carbon atoms,
Alkyl- und/oder Alkenyletherphosphate der Formel (II),  Alkyl and / or alkenyl ether phosphates of the formula (II),
0  0
R6(OCH2CH2)n-0-P-OR7 (II) R6 (OCH 2 CH 2) n -0-P-OR7 (II)
6x  6x
in der R6 bevorzugt für einen aliphatischen Kohlenwasserstoffrest mit 8 bis 30 Kohlenstoffatomen, R7 für Wasserstoff, einen Rest (CH2CH20)nR6 oder X, n für Zahlen von 1 bis 10 und X für Wasserstoff, ein Alkali- oder Erdalkalimetall oder NR8R9R 0R11 , mit R8 bis R unabhängig voneinander stehend für einen bis C4 - Kohlenwasserstoffrest, steht, sulfatierte Fettsäurealkylenglycolester der Formel (III), in the R 6 is preferably an aliphatic hydrocarbon radical having 8 to 30 carbon atoms, R 7 is hydrogen, a radical (CH 2 CH 2 0) nR 6 or X, n is from 1 to 10 and X is hydrogen, an alkali or Alkaline earth metal or NR 8 R 9 R 0 R 11 , where R 8 to R independently of one another represent a C 4 - to C 4 hydrocarbon radical, is a sulfated fatty acid alkylene glycol ester of the formula (III),
R 2CO(AlkO)nS03M (III) R 2 CO (AlkO) n S0 3 M (III)
in der R 2CO- für einen linearen oder verzweigten, aliphatischen, gesättigten und/oder ungesättigten Acylrest mit 6 bis 22 C-Atomen, Alk für CH2CH2, CHCH3CH2 und/oder CH2CHCH3, n für Zahlen von 0,5 bis 5 und M für ein Kation steht, wie sie in der DE-OS 197 36 906.5 beschrieben sind, in the R 2 CO- for a linear or branched, aliphatic, saturated and / or unsaturated acyl radical having 6 to 22 carbon atoms, Alk for CH 2 CH 2 , CHCH 3 CH 2 and / or CH 2 CHCH 3 , n for numbers from 0.5 to 5 and M is a cation, as described in DE-OS 197 36 906.5,
Monoglyceridsulfate und Monoglyceridethersulfate der Formel (IV), CH20(CH2CH20)x— COR13 Monoglyceride sulfates and monoglyceride ether sulfates of the formula (IV), CH 2 O (CH 2 CH 2 O) x - COR 13
CHO(CH2CH20)yH (IV) CHO (CH 2 CH 2 O) y H (IV)
CH20(CH2CH20)z— S03X CH 2 O (CH 2 CH 2 O) z - S0 3 X
in der R 3CO für einen linearen oder verzweigten Acylrest mit 6 bis 22 Kohlenstoffatomen, x, y und z in Summe für 0 oder für Zahlen von 1 bis 30, vorzugsweise 2 bis 10, und X für ein Alkali- oder Erdalkalimetall steht. Typische Beispiele für im Sinne der Erfindung geeignete Monoglycerid(ether)sulfate sind die Umsetzungsprodukte von Laurinsäuremonoglycerid, Kokosfettsäuremonoglycerid, Palmitinsäuremonoglycerid, Stearinsäuremonoglycerid, Ölsäu- remonoglycerid und Talgfettsäuremonoglycerid sowie deren Ethylenoxidaddukte mit Schwefeltrioxid oder Chlorsulfonsäure in Form ihrer Natriumsalze. Vorzugsweise werden Monoglyceridsulfate der Formel (IV) eingesetzt, in der R 3CO für einen linearen Acylrest mit 8 bis 18 Kohlenstoffatomen steht, Amidethercarbonsäuren, Eiweißhydrolysat-Fettsäure-Kondensationsprodukte; diese werden durch Kondensation von C8 - C30 Fettsäuren, bevorzugt von Fettsäuren mit 12 - 18 C-Atomen mit Aminosäuren, Mono-, Di- und wasserlöslichen Oligopeptiden und Gemischen solcher Produkte hergestellt, wie sie bei der Hydrolyse von Proteinen anfallen. Diese Eiweißhydrolysat-Fett- säure-Kondensationsprodukte werden mit einer Base neutralisiert und liegen dann bevorzugt als Alkali-, Ammonium-, Mono-, Di- oder Trialkanolammoniumsalz vor; Acylglutamate, welche Kondensationsprodukte aus der Glutaminsäure und C8 - C30 Fettsäuren, bevorzugt von Fettsäuren mit 12 bis 18 C-Atomen darstellen und welche in neutralisierter Form als K-, Na- oder Ammoniumsalz vorliegen, und Acylaspartate, welche Kondensationsprodukte aus der Asparaginsäure und C8 - C30 Fettsäuren, bevorzugt von Fettsäuren mit 12 bis 18 C-Atomen darstellen und welche in neutralisierter Form als K-, Na- oder Ammoniumsalz vorliegen; Acylsarcoside mit 8 bis 24 C- Atomen in der Acylgruppe. in which R 3 CO is a linear or branched acyl radical having 6 to 22 carbon atoms, x, y and z are in total 0 or numbers of 1 to 30, preferably 2 to 10, and X is an alkali or alkaline earth metal. Typical examples of monoglyceride (ether) sulfates suitable for the purposes of the invention are the reaction products of lauric acid monoglyceride, coconut fatty acid monoglyceride, palmitic acid monoglyceride, stearic acid monoglyceride, oleic acid monoglyceride and tallow fatty acid monoglyceride and their ethylene oxide adducts with sulfur trioxide or chlorosulfonic acid in the form of their sodium salts. It is preferred to use monoglyceride sulfates of the formula (IV) in which R 3 CO is a linear acyl radical having 8 to 18 carbon atoms, Amide-ether carboxylic acids, protein hydrolyzate-fatty acid condensation products; These are prepared by condensation of C8 - C30 fatty acids, preferably fatty acids having 12 - 18 C atoms with amino acids, mono-, di- and water-soluble oligopeptides and mixtures of such products as obtained in the hydrolysis of proteins. These protein hydrolyzate-fatty acid condensation products are neutralized with a base and are then preferably present as alkali metal, ammonium, mono-, di- or trialkanolammonium salt; Acylglutamates, which are condensation products of glutamic acid and C 8 -C 30 fatty acids, preferably of fatty acids having 12 to 18 carbon atoms and which are present in neutralized form as K, Na or ammonium salt, and acylaspartates which are condensation products of aspartic acid and C 8 - C30 fatty acids, preferably of fatty acids having 12 to 18 carbon atoms and which are present in neutralized form as K, Na or ammonium salt; Acylsarcosides having 8 to 24 carbon atoms in the acyl group.
Bevorzugte anionische Tensidklassen sind Alkylsulfate, Alkylpolyglycolethersulfate und Ether- carbonsäuresalze mit 10 bis 18 C-Atomen in der Alkylgruppe und bis zu 12 Glycolethergruppen im Molekül, Sulfobernsteinsäuremono- und -dialkylester mit 8 bis 18 C-Atomen in der Alkylgruppe und Sulfobernsteinsäuremonoalkylpolyoxyethylester mit 8 bis 18 C-Atomen in der Alkylgruppe und 1 bis 6 Oxyethylgruppen, Zitronensäureester mit Fettalkoholethoxylaten, wie beispielsweise das unter dem Handelsnamen „Plantapon LC-7" vertriebene Produkt. Bevorzugte Tenside der Klasse Alkylpolyglycolethersulfate sind Natriumtridecethsulfate, beispielsweise die unter den Handelsnamen „Miracare SLB 365", „Genapol XRO" oder „Rhodapex EST-30" vertriebenen Natriumtridecethsulfat-Tensidmischungen, sowie Natriummyrethsulfate. Besonders bevorzugte Alkylpolyglycolethersulfate sind die Alkali- oder Ammoniumsalze des Laurylethersulfates mit einem Ethoxylierungsgrad von 2 bis 4 EO.  Preferred anionic surfactant classes are alkyl sulfates, alkyl polyglycol ether sulfates and ether carboxylic acid salts having 10 to 18 C atoms in the alkyl group and up to 12 glycol ether groups in the molecule, sulfosuccinic acid mono- and dialkyl esters having 8 to 18 C atoms in the alkyl group and sulfosuccinic monoalkylpolyoxyethyl esters having 8 to 18 C atoms in the alkyl group and 1 to 6 oxyethyl groups, citric acid esters with fatty alcohol ethoxylates, such as the product sold under the trade name "Plantapon LC-7" Preferred surfactants of the class alkyl polyglycol ether sulfates are sodium trideceth sulfates, for example those sold under the trade name "Miracare SLB 365", "Genapol XRO" or "Rhodapex EST-30" sold sodium trideceth sulfate surfactant mixtures, as well as sodium myrethsulfates. Particularly preferred alkyl polyglycol ether sulfates are the alkali metal or ammonium salts of lauryl ether sulfate having a degree of ethoxylation of 2 to 4 EO.
Als zwitterionische Tenside werden solche oberflächenaktiven Verbindungen bezeichnet, die mindestens eine quartäre Ammoniumgruppe und mindestens eine -COO(_) - oder -S03 (_) -Gruppe im Molekül tragen. Besonders geeignete zwitterionische Tensidklassen sind die so genannten Betaine wie die N-Alkyl-N,N-dimethylammoniumglycinate, beispielsweise das Kokosalkyldimethyl- ammoniumglycinat, N-Acyl-aminopropyl-N,N-dimethylammoniumglycinate, beispielsweise das Kokosacylaminopropyl-dimethylammoniumglycinat, und 2-Alkyl-3-carboxymethyl-3-hydroxyethyl- imidazoline mit jeweils 8 bis 18 C-Atomen in der Alkyl- oder Acylgruppe sowie das Kokosacyl- aminoethylhydroxyethylcarboxymethylglycinat. Ein bevorzugtes zwitterionisches Tensid ist das unter der INCI-Bezeichnung Cocamidopropyl Betaine bekannte Fettsäureamid-Derivat. Zwitterionic surfactants are those surface-active compounds which carry at least one quaternary ammonium group and at least one -COO ( - ) or -SO 3 ( - ) group in the molecule. Particularly suitable zwitterionic surfactant classes are the so-called betaines such as N-alkyl-N, N-dimethylammonium glycinates, for example cocoalkyldimethylammonium glycinate, N-acylaminopropyl-N, N-dimethylammonium glycinates, for example cocoacylaminopropyl-dimethylammonium glycinate, and 2-alkylbenzenesulfonate. 3-carboxymethyl-3-hydroxyethyl imidazolines having in each case 8 to 18 C atoms in the alkyl or acyl group and the cocoacylaminoethylhydroxyethylcarboxymethylglycinate. A preferred zwitterionic surfactant is the fatty acid amide derivative known by the INCI name Cocamidopropyl Betaine.
Unter amphoteren Tensiden werden solche oberflächenaktiven Verbindungen verstanden, die außer einer C8 - C24 - Alkyl- oder -Acylgruppe im Molekül mindestens eine freie Aminogruppe und mindestens eine -COOH- oder -S03H-Gruppe enthalten und zur Ausbildung innerer Salze befähigt sind. Beispiele für bevorzugte ampholytische Tensidklassen sind N-Alkylglycine, N-Alkylpro- pionsäuren, N-Alkylaminobuttersäuren, N-Alkyliminodipropionsäuren, N-Hydroxyethyl-N-alkylami- dopropylglycine, Amphoacetate, insbesondere Cocoamphoacetate, Lauroamphoacetate, Oliv- amphoacetate, Amphopropionate, insbesondere Cocoamphopropionate, Amphodiacetate, insbesondere Cocoamphodiacetate, Lauroamphodiacetate, Capryloamphodiacetate, Amphodipropio- nate, insbesondere Cocoamphodipropionate, N-Acyltaurine, N-Acylsarcosine, 2-Alkylaminopro- pionsäuren und Alkylaminoessigsäuren mit jeweils etwa 8 bis 24 C-Atomen in der Alkylgruppe. Weitere erfindungsgemäß bevorzugte amphotere Tenside sind Phosphatidylcholine. Phosphati- dylcholine mit der unten dargestellten allgemeinen Strukturformel sind Hauptbestandteil des Lecithins. Die Substituenten R und R2 in der untenstehenden Strukturformel (PL) stellen lineare aliphatische Alkylreste mit 7 bis 21 Kohlenstoffatomen, bevorzugt mit 1 1 bis 19 Kohlenstoffatomen, besonders bevorzugt mit 15 bis 17 Kohlenstoffatomen, dar, die bis zu vier Z-konfigurierte Doppelbindungen aufweisen können. Besonders bevorzugt sind R CO und R2CO unabhängig voneinander ausgewählt aus Palmitoyl, Stearoyl, Oleoyl, Linoloyl und Linolenoyl. Besonders bevorzugt ist weiterhin Phosphatidylcholin, teilhydriertes Phosphatidylcholin und vollständig hydriertes Phos- phatidylcholin, das jeweils aus Sojalecithin stammt. Phosphatidylcholine gehören zu den Phos- pholipiden, werden aber im vorliegenden Zusammenhang nur zu den Tensiden gerechnet, nicht zu den Lipiden. Amphoteric surfactants are understood as meaning those surface-active compounds which, apart from a C 8 -C 24 -alkyl or -acyl group in the molecule, contain at least one free amino group and at least one -COOH or -SO 3 H group and are capable of forming internal salts , Examples of preferred ampholytic surfactant classes are N-alkylglycines, N-alkylpropyl pionic acids, N-alkylaminobutyric acids, N-alkyliminodipropionic acids, N-hydroxyethyl-N-alkylamidopropylglycines, amphoacetates, in particular cocoamphoacetates, lauroamphoacetates, olivamorphoacetates, amphopropionates, in particular cocoamphopropionates, amphodiacetates, in particular cocoamphodiacetates, lauroamphodiacetates, capryloamphodiacetates, amphodipropionates, in particular Cocoamphodipropionates, N-acyltaurines, N-acylsarcosines, 2-Alkylaminopro- pionsäuren and Alkylaminoessigsäuren each having about 8 to 24 carbon atoms in the alkyl group. Further inventively preferred amphoteric surfactants are phosphatidylcholines. Phosphatidylcholines having the general structural formula shown below are the main constituent of lecithin. The substituents R and R 2 in structural formula (PL) below represent linear aliphatic alkyl radicals having from 7 to 21 carbon atoms, preferably from 1 to 19 carbon atoms, more preferably from 15 to 17 carbon atoms, having up to four Z-configured double bonds can. More preferably, R CO and R 2 CO are independently selected from palmitoyl, stearoyl, oleoyl, linoloyl and linolenoyl. Also particularly preferred is phosphatidylcholine, partially hydrogenated phosphatidylcholine and fully hydrogenated phosphatidylcholine, each derived from soya lecithin. Phosphatidylcholines belong to the phospholipids, but in the present context are calculated only as surfactants, not as lipids.
O O
O H2C-0-C-R1 OH 2 C-0-CR 1
I I I  I II
R2— C-O-C-H O CH3 R 2 - COCHO CH 3
I I I I ,  I I I,
H2C-0-P-0-CH2— CH2— N-CH3 H 2 C-O-P-O-CH 2 -CH 2 -N-CH 3
CT CH3 (PL) CT CH 3 (PL)
Besonders bevorzugte ampholytische Tenside sind Cocoamphoacetate, Lauroamphoacetate, Cocoamphodiacetate, Lauroamphodiacetate und Capryloamphodiacetate.  Particularly preferred ampholytic surfactants are cocoamphoacetates, lauroamphoacetates, cocoamphodiacetates, lauroamphodiacetates and capryloamphodiacetates.
Die amphoteren und/oder zwitterionischen Tenside werden in den erfindungsgemäßen Zusammensetzungen - bezogen auf das Gesamtgewicht der treibmittelfreien Zusammensetzung - in einer Gesamtmenge von 0,01 bis 20 Gew.-%, bevorzugt in einer Gesamtmenge von 0,05 bis 18 Gew.-%, besonders bevorzugt in einer Gesamtmenge von 0,1 bis 15 Gew.-% und insbesondere in einer Gesamtmenge von 0,5 bis 10 Gew.-% eingesetzt. The amphoteric and / or zwitterionic surfactants are in the compositions of the invention - based on the total weight of the propellant-free composition - in a total amount of 0.01 to 20 wt .-%, preferably in a total amount of 0.05 to 18 wt .-%, particularly preferably used in a total amount of 0.1 to 15 wt .-% and in particular in a total amount of 0.5 to 10 wt .-%.
Nichtionische Tenside enthalten als hydrophile Gruppe z. B. eine Polyolgruppe, insbesondere eine Polyglyceringruppe, eine Polyalkylenglycolethergruppe oder eine Kombination aus Polyol- und Polyglycolethergruppe. Solche Tensidklassen sind beispielsweise :  Nonionic surfactants contain as hydrophilic group z. A polyol group, especially a polyglycerol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether groups. Such classes of surfactants are, for example:
Anlagerungsprodukte von 2 bis 50 Mol Ethylenoxid und/oder 0 bis 5 Mol Propylenoxid an lineare und verzweigte Fettalkohole mit 8 bis 30 C-Atomen, an Fettsäuren mit 8 bis 30 C-Atomen und an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe, mit einem Methyl- oder C2-C6-Alkylrest endgruppenverschlossene Anlagerungsprodukte von 2 bis 50 Mol Ethylenoxid und/oder 0 bis 5 Mol Propylenoxid an lineare und verzweigte Fettalkohole mit 8 bis 30 C-Atomen, an Fettsäuren mit 8 bis 30 C-Atomen und an Alkylphenole mit 8 bis 15 C-Atomen in der Alkylgruppe, wie beispielsweise die unter den Verkaufsbezeichnungen Dehydol® LS, Dehydol® LT (BASF) erhältlichen Typen, C 2-C30-Fettsäuremono- und -diester von Anlagerungsprodukten von 1 bis 30 Mol Ethylenoxid an Glycerin, Anlagerungsprodukte von 5 bis 60 Mol Ethylenoxid an Rizinusöl und gehärtetes Rizinusöl, beispielsweise Rizinusöl-hydriert+40 EO, Polyolfettsäureester, wie beispielsweise das Handelsprodukt Hydagen® HSP (BASF) oder Sovermol - Typen (BASF), alkoxylierte Triglyceride, alkoxylierte Fettsäurealkylester der Formel (V) Addition products of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear and branched fatty alcohols having 8 to 30 carbon atoms, to fatty acids having 8 to 30 carbon atoms and to alkylphenols having 8 to 15 carbon atoms in the alkyl group , with a methyl or C 2 -C 6 alkyl radical end-capped addition products of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide to linear and branched fatty alcohols having 8 to 30 carbon atoms, to fatty acids with 8 to 30 carbon atoms and onto alkylphenols having 8 to 15 carbon atoms in the alkyl group, such as those available under the trade names Dehydol ® LS, LT Dehydol ® types (BASF) available, C 2 -C 30 fatty acid and - diesters of addition products of 1 to 30 mol ethylene oxide onto glycerol, addition products of 5 to 60 mol ethylene oxide onto castor oil and hydrogenated castor oil, for example castor oil hydrogenated + 40 EO, polyol, such as the commercial product Hydagen ® HSP (BASF) or Sovermol - types ( BASF), alkoxylated triglycerides, alkoxylated fatty acid alkyl esters of the formula (V)
R14CO— (OCH^CHR syDRie (V) in der R 4CO für einen linearen oder verzweigten, gesättigten und/oder ungesättigten Acylrest mit 6 bis 22 Kohlenstoffatomen, R 5 für Wasserstoff oder Methyl, R 6 für lineare oder verzweigte Alkylreste mit 1 bis 4 Kohlenstoffatomen und w für Zahlen von 1 bis 20 steht, Aminoxide, Hydroxymischether, wie sie beispielsweise in der DE-OS 19738866 beschrieben sind, Sorbitanfettsäureester und Anlagerungsprodukte von Ethylenoxid an Sorbitanfettsäureester wie beispielsweise die Polysorbate, Zuckerfettsäureester und Anlagerungsprodukte von Ethylenoxid an Zuckerfettsäureester, Fettsäurealkanolamide, Anlagerungsprodukte von Ethylenoxid an Fett- säurealkanolamide und Fettamine, Fettsäure-N-alkylglucamide, Alkylpolyglycoside entsprechend der allgemeinen Formel RO-(Z)x wobei R für Alkyl, Z für Zucker sowie x für die Anzahl der Zuckereinheiten steht. Die erfindungsgemäß verwendbaren Alkylpolyglycoside können lediglich einen bestimmten Alkylrest R enthalten. Üblicherweise werden diese Verbindungen aber ausgehend von natürlichen Fetten und Ölen oder Mineralölen hergestellt. In diesem Fall liegen als Alkylreste R Mischungen entsprechend den Ausgangsverbindungen bzw. entsprechend der jeweiligen Aufarbeitung dieser Verbindungen vor. Besonders bevorzugt sind solche Alkylpolyglycoside, bei denen R im wesentlichen aus C8- und C 0-Alkylgruppen oder im wesentlichen aus C 2- und C 4- Alkylgruppen oder im wesentlichen aus C8- bis C 6-Alkylgruppen oder im wesentlichen aus C 2- bis C 6-Alkylgruppen oder im wesentlichen aus C16 bis C 8-Alkylgruppen besteht. R 14 CO- (OCH) CHR syDRie (V) in the R 4 CO for a linear or branched, saturated and / or unsaturated acyl radical having 6 to 22 carbon atoms, R 5 is hydrogen or methyl, R 6 is linear or branched alkyl radicals having 1 to 4 carbon atoms and w is a number from 1 to 20, amine oxides, hydroxy mixed ethers, as described, for example, in DE-OS 19738866, sorbitan fatty acid esters and adducts of ethylene oxide with sorbitan fatty acid esters such as the polysorbates, sugar fatty acid esters and addition products of ethylene oxide with sugar fatty acid esters, fatty acid alkanolamides, Addition products of ethylene oxide onto fatty acid alkanolamides and fatty amines, fatty acid N-alkylglucamides, alkylpolyglycosides corresponding to the general formula RO- (Z) x where R is alkyl, Z is sugar and x is the number of sugar units The alkylpolyglycosides which can be used according to the invention can only a particular alkyl radical R entha Usually, however, these compounds are prepared starting from natural fats and oils or mineral oils. In this case, the alkyl radicals R are mixtures corresponding to the starting compounds or corresponding to the particular work-up of these compounds. Particular preference is given to those alkylpolyglycosides in which R consists essentially of C 8 and C 0 -alkyl groups or substantially of C 2 and C 4 -alkyl groups or substantially of C 8 to C 6 -alkyl groups or essentially of C 2 - To C 6 alkyl groups or consists essentially of C 16 to C 8 alkyl groups.
Als Zuckerbaustein Z können beliebige Mono- oder Oligosaccharide eingesetzt werden. Üblicherweise werden Zucker mit 5 bzw. 6 Kohlenstoffatomen sowie die entsprechenden Oligosaccharide eingesetzt. Solche Zucker sind beispielsweise Glucose, Fructose, Galactose, Arabinose, Ribose, Xylose, Lyxose, Allose, Altrose, Mannose, Gulose, Idose, Talose und Sucrose. Bevorzugte Zuckerbausteine sind Glucose, Fructose, Galactose, Arabinose und Sucrose; Glucose ist besonders bevorzugt. Die erfindungsgemäß bevorzugten Alkylpolyglycoside enthalten im Schnitt 1 ,1 bis 5 Zuckereinheiten. Alkylpolyglycoside mit x-Werten von 1 ,1 bis 2,0 sind bevorzugt. Ganz besonders bevorzugt sind Alkylglycoside, bei denen x 1 ,1 bis 1 ,8 beträgt. Auch die alkoxylierten Homologen der genannten Alkylpolyglycoside können erfindungsgemäß eingesetzt werden. Diese Homologen können durchschnittlich bis zu 10 Ethylenoxid- und/oder Propylenoxideinheiten pro Alkylglycosideinheit enthalten. As sugar building block Z it is possible to use any desired mono- or oligosaccharides. Usually, sugars with 5 or 6 carbon atoms and the corresponding oligosaccharides are used. Such sugars are, for example, glucose, fructose, galactose, arabinose, ribose, xylose, lyxose, allose, altrose, mannose, gulose, idose, talose and sucrose. Preferred sugar building blocks are glucose, fructose, galactose, arabinose and sucrose; Glucose is particularly preferred. The inventively preferred Alkylpolyglycoside contain an average of 1, 1 to 5 sugar units. Alkyl polyglycosides having x values of 1.1 to 2.0 are preferred. Very particular preference is given to alkyl glycosides in which x is 1: 1 to 1, 8. The alkoxylated homologs of said alkylpolyglycosides can also be used according to the invention. These Homologs may contain on average up to 10 ethylene oxide and / or propylene oxide units per alkyl glycoside unit.
Als bevorzugte nichtionische Tenside haben sich die Ethylenoxid-Anlagerungsprodukte an gesättigte lineare Fettalkohole und Fettsäuren mit jeweils 2 bis 30 Mol Ethylenoxid pro Mol Fettalkohol bzw. Fettsäure erwiesen. Zusammensetzungen mit hervorragenden Eigenschaften werden ebenfalls erhalten, wenn sie als nichtionische Tenside Fettsäureester von ethoxyliertem Glycerin enthalten.  Preferred nonionic surfactants are the ethylene oxide adducts of saturated linear fatty alcohols and fatty acids having in each case 2 to 30 moles of ethylene oxide per mole of fatty alcohol or fatty acid. Compositions having excellent properties are also obtained when they contain fatty acid esters of ethoxylated glycerol as nonionic surfactants.
Die nichtionischen Tenside werden in den erfindungsgemäßen Zusammensetzungen - bezogen auf deren Gesamtgewicht - in einer Gesamtmenge von 0,05 bis 20 Gew.-%, bevorzugt in einer Gesamtmenge von 0,1 bis 15 Gew.-% und insbesondere in einer Gesamtmenge von 0,5 bis 10 Gew.-% eingesetzt.  The nonionic surfactants are in the compositions of the invention - based on the total weight - in a total amount of 0.05 to 20 wt .-%, preferably in a total amount of 0.1 to 15 wt .-% and in particular in a total amount of 0, 5 to 10 wt .-% used.
Gemäß einer weiteren Ausführungsform der Erfindung können die erfindungsgemäßen Zusammensetzungen weiterhin mindestens ein kationisches Tensid vom Typ der quartären (quaternä- ren) Ammoniumverbindungen, der Esterquats und der Amidoamine enthalten.  According to a further embodiment of the invention, the compositions according to the invention may further comprise at least one cationic surfactant of the quaternary ammonium quaternary type, the esterquats and the amidoamines.
Bevorzugte quaternäre Ammoniumverbindungen sind Ammoniumhalogenide, insbesondere Chloride und Bromide, wie Alkyltrimethylammoniumchloride, Dialkyldimethylammoniumchloride und Trialkylmethylammoniumchloride, z. B. Cetyltrimethylammoniumchlorid, Stearyltrimethylammo- niumchlorid, Distearyldimethylammoniumchlorid, Lauryldimethylammoniumchlorid, Lauryldi- methylbenzylammoniumchlorid und Tricetylmethylammoniumchlorid, sowie die unter den INCI- Bezeichnungen Quaternium-27 und Quaternium-83 bekannten Imidazolium-Verbindungen. Die Alkylketten der oben genannten Tenside weisen bevorzugt 10 bis 18 Kohlenstoffatome auf. Preferred quaternary ammonium compounds are ammonium halides, especially chlorides and bromides, such as alkyltrimethylammonium chlorides, dialkyldimethylammonium chlorides and trialkylmethylammonium chlorides, e.g. Cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, distearyldimethylammonium chloride, lauryldimethylammonium chloride, lauryldimethylbenzylammonium chloride and tricetylmethylammonium chloride, as well as the imidazolium compounds known under the INCI names Quaternium-27 and Quaternium-83. The alkyl chains of the above-mentioned surfactants preferably have 10 to 18 carbon atoms.
Bei Esterquats handelt es sich um bekannte Stoffe, die sowohl mindestens eine Esterfunktion als auch mindestens eine quartäre Ammoniumgruppe als Strukturelement enthalten. Bevorzugte Esterquats sind quaternierte Estersalze von Fettsäuren mit Triethanolamin, quaternierte Estersalze von Fettsäuren mit Diethanolalkylaminen und quaternierten Estersalzen von Fettsäuren mit 1 ,2-Dihydroxypropyldialkylaminen. Esterquats are known substances which contain both at least one ester function and at least one quaternary ammonium group as a structural element. Preferred ester quats are quaternized ester salts of fatty acids with triethanolamine, quaternized ester salts of fatty acids with diethanolalkylamines and quaternized ester salts of fatty acids with 1,2-dihydroxypropyldialkylamines.
Die kationischen Tenside sind in den erfindungsgemäßen Zusammensetzungen - bezogen auf deren Gesamtgewicht - in einer Gesamtmenge von 0,05 bis 10 Gew.-%, besonders bevorzugt 0,5 bis 3 Gew.-% enthalten.  The cationic surfactants are contained in the compositions according to the invention - based on their total weight - in a total amount of 0.05 to 10 wt .-%, particularly preferably 0.5 to 3 wt .-%.
Besonders bevorzugte erfindungsgemäße Zusammensetzungen enthalten mindestens zwei Tenside, die verschiedenen Tensidklassen angehören. Für diese Auswahl bevorzugte Tensidklassen sind Sulfobernsteinsäuremono-alkylpolyoxyethylester mit 8 bis 24 C-Atomen, bevorzugt 10 bis 14 C-Atomen, besonders bevorzugt 12 C-Atomen in der Alkylgruppe und jeweils 1 bis 6 Oxyethyl- gruppen, Natrium-, Kalium- und Ammonium-Salze sowie Mono-, Di- und Trialkanolammonium- salze mit 2 bis 4 C-Atomen in der Alkanolgruppe von linearen oder verzweigten Fettsäuren mit 8 bis 30 C-Atomen (Seifen), Fettsäurealkanolamide, Alkylpolyglycolethersulfate der Formel R-0(CH2-CH20)x-OS03H, in der R eine bevorzugt lineare Alkylgruppe mit 8 bis 18 C-Atomen, bevorzugt 10 - 14 und besonders bevorzugt 12 C-Atomen und x = 1 - 12, besonders bevorzugt 2 - 4, ist, Ethercarbonsäuren der Formel R-0-(CH2-CH20)x-CH2-COOH, in der R eine lineare Alkylgruppe mit 8 bis 30 C-Atomen und x = 0 oder 1 bis 16 ist, N-Acylsarcosinate, Betaine, Am- phoacetate, Amphodiacetate, Anlagerungsprodukte von 2 bis 50 Mol Ethylenoxid und/oder 0 bis 5 Mol Propylenoxid an lineare und verzweigte Fettalkohole mit 8 bis 30 C-Atomen, Anlagerungsprodukte von 5 bis 60 Mol Ethylenoxid an gehärtetes Rizinusöl, Anlagerungsprodukte von Ethylenoxid an Sorbitanfettsäureester, Alkylpolyglycoside, bei denen R im wesentlichen aus C8- und C 0-Alkylgruppen oder im wesentlichen aus C 2- und C 4-Alkylgruppen oder im wesentlichen aus C8- bis C 6-Alkylgruppen oder im wesentlichen aus C 2- bis C 6-Alkylgruppen besteht; Ester- quats. Particularly preferred compositions of the invention contain at least two surfactants belonging to different classes of surfactants. Preferred surfactant classes for this selection are sulfosuccinic acid monoalkylpolyoxyethyl esters having 8 to 24 C atoms, preferably 10 to 14 C atoms, more preferably 12 C atoms in the alkyl group and in each case 1 to 6 oxyethyl groups, sodium, potassium and ammonium Salts and mono-, di- and Trialkanolammonium- salts having 2 to 4 carbon atoms in the alkanol group of linear or branched fatty acids having 8 to 30 carbon atoms (soaps), fatty acid alkanolamides, Alkylpolyglycolethersulfate of the formula R-O (CH 2 -CH 2 O) x -OSO 3 H, in which R is a preferably linear alkyl group having 8 to 18 C atoms, preferably 10 to 14 and particularly preferably 12 C atoms and x = 1 to 12, more preferably 2-4, is ether carboxylic acids of the formula R-O- (CH 2 -CH 2 O) x -CH 2 -COOH, wherein R is a linear alkyl group of 8 to 30 carbon atoms and x is 0 or 1 to 16, N Acylsarcosinates, betaines, amphoacetates, amphodiacetates, addition products of 2 to 50 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide onto linear and branched fatty alcohols containing 8 to 30 carbon atoms, addition products of 5 to 60 moles of ethylene oxide onto hardened castor oil, Addition products of ethylene oxide with sorbitan fatty acid esters, alkylpolyglycosides in which R consists essentially of C 8 and C 0 alkyl groups or substantially of C 2 and C 4 alkyl groups or substantially of C 8 to C 6 alkyl groups or substantially C 2 to C 6 alkyl groups; Ester quats.
Mischungen dieser Tensidklassen ergeben mit dem erfindungsgemäßen Treibmittel besonders stabile und feinblasige Schäume mit hervorragenden sensorischen Eigenschaften. Diesbezüglich besonders bevorzugte erfindungsgemäße Zusammensetzungen enthalten mindestens folgende Tensidklassenmischung: Alkylpolyglycolethersulfat/Betain, Alkylpolyglycolethersulfat/Sulfobern- steinsäuremono-alkylpolyoxyethylester, Alkylpolyglycolethersulfat/Alkylpolyglycosid, wie vorstehend bezeichnet, Alkylpolyglycolethersulfat/Amphoacetat, Alkylpolyglycolethersulfat/ Amphodi- acetat, Alkylpolyglycolethersulfat/Anlagerungsprodukt von 5 bis 60 Mol Ethylenoxid an gehärtetes Rizinusöl, Sulfobernsteinsäuremono-alkylpolyoxyethylester/Betain, Sulfobernsteinsäuremono- alkylpolyoxyethylester/Alkylpolyglycosid, wie vorstehend bezeichnet, Seifen/Fettsäurealkanol- amide.  Mixtures of these classes of surfactants with the blowing agent according to the invention give particularly stable and fine-bubble foams with excellent sensory properties. In this regard, particularly preferred compositions according to the invention contain at least the following surfactant class mixture: alkylpolyglycol ether sulfate / betaine, alkylpolyglycol ether sulfate / sulfosuccinic acid monoalkylpolyoxyethyl ester, alkylpolyglycol ether sulfate / alkylpolyglycoside as described above, alkylpolyglycol ether sulfate / amphoacetate, alkylpolyglycol ether sulfate / amphodiacetate, alkylpolyglycol ether sulfate / adduct of from 5 to 60 moles of ethylene oxide hydrogenated castor oil, sulfosuccinic acid mono-alkyl polyoxyethyl ester / betaine, sulfosuccinic acid mono- alkyl polyoxyethyl ester / alkyl polyglycoside, as described above, soaps / fatty acid alkanol amides.
Weitere erfindungsgemäße Zusammensetzungen enthalten als Tensid bevorzugt mindestens einen nichtionischen ÖI-in-Wasser-Emulgator mit einem HLB-Wert von mehr als 7. Hierbei handelt es sich um dem Fachmann allgemein bekannte Emulgatoren, wie sie beispielsweise in Kirk-Othmer, "Encyclopedia of Chemical Technology", 3. Aufl., 1979, Band 8, Seite 913-916, aufgelistet sind. Für ethoxylierte Produkte wird der HLB-Wert nach der Formel HLB = (100 - L) : 5 berechnet, wobei L der Gewichtsanteil der lipophilen Gruppen, das heißt der Fettalkyl- oder Fettacylgruppen, in den Ethylenoxidaddukten, ausgedrückt in Gewichtsprozent, ist.  Further compositions according to the invention preferably contain as surfactant at least one nonionic oil-in-water emulsifier having an HLB value of more than 7. These are emulsifiers generally known to the person skilled in the art, as described, for example, in Kirk-Othmer, "Encyclopedia of Chemical Technology ", 3rd ed., 1979, Vol. 8, pages 913-916. For ethoxylated products, the HLB value is calculated according to the formula HLB = (100-L): 5, where L is the weight fraction of the lipophilic groups, that is the fatty alkyl or fatty acyl groups, in the ethylene oxide adducts, expressed in weight percent.
Bei der Auswahl erfindungsgemäß geeigneter nichtionischer ÖI-in-Wasser-Emulgatoren ist es besonders bevorzugt, ein Gemisch von nichtionischen ÖI-in-Wasser-Emulgatoren einzusetzen, um die Eigenschaften erfindungsgemäßer Zusammensetzungen optimal einstellen zu können. Bevorzugte erfindungsgemäße Zusammensetzungen sind dadurch gekennzeichnet, dass die nichtionischen ÖI-in-Wasser-Emulgatoren ausgewählt sind aus ethoxylierten C8-C24-Alkanolen mit durchschnittlich 10 - 100 Mol Ethylenoxid pro Mol, ethoxylierten C8-C24-Carbonsäuren mit durchschnittlich 10 - 100 Mol Ethylenoxid pro Mol, Silicon-Copolyolen mit Ethylenoxid-Einheiten oder mit Ethylenoxid- und Propylenoxid-Einheiten, Alkylmono- und -oligoglycosiden mit 8 bis 22 Koh- lenstoffatomen im Alkylrest und deren ethoxylierten Analoga, ethoxylierten Sterinen, Partialestern von Polyglycerinen mit 2 bis 10 Glycerineinheiten und mit 1 bis 4 gesättigten oder ungesättigten, linearen oder verzweigten, gegebenenfalls hydroxylierten C8 - C30-Fettsäureresten verestert, sofern sie einen HLB-Wert von mehr als 7 aufweisen, sowie Mischungen der vorgenannten Substanzen. In selecting nonionic oil-in-water emulsifiers which are suitable according to the invention, it is particularly preferable to use a mixture of nonionic oil-in-water emulsifiers in order to optimally adjust the properties of compositions according to the invention. Preferred compositions according to the invention are characterized in that the nonionic oil-in-water emulsifiers are selected from ethoxylated C 8 -C 24 -alkanols with an average of 10 to 100 moles of ethylene oxide per mole of ethoxylated C 8 -C 24 -carboxylic acids with an average of 10 - 100 moles of ethylene oxide per mole, silicone copolyols with ethylene oxide units or with ethylene oxide and propylene oxide units, alkyl mono- and oligoglycosides having 8 to 22 carbon atoms. esterified in the alkyl radical and their ethoxylated analogs, ethoxylated sterols, partial esters of polyglycerols having 2 to 10 glycerol units and with 1 to 4 saturated or unsaturated, linear or branched, optionally hydroxylated C 8 - C 30 fatty acid residues, provided that they have an HLB value of have more than 7, and mixtures of the aforementioned substances.
Die ethoxylierten C8-C24-Alkanole haben die Formel R 0(CH2CH20)nH, wobei R steht für einen linearen oder verzweigten Alkyl- und/oder Alkenylrest mit 8 - 24 Kohlenstoffatomen und n, die mittlere Anzahl der Ethylenoxid-Einheiten pro Molekül, für Zahlen von 10 - 100, vorzugsweise 10 - 30 Mol Ethylenoxid an 1 Mol Caprylalkohol, 2-Ethylhexylalkohol, Caprinalkohol, Laurylalko- hol, Isotridecylalkohol, Myristylalkohol, Cetylalkohol, Isocetylalkohol, Palmitoleylalkohol, Stearyl- alkohol, Isostearylalkohol, Oleylalkohol, Elaidylalkohol, Petroselinylalkohol, Arachylalkohol, Gado- leylalkohol, Behenylalkohol, Erucylalkohol und Brassidylalkohol sowie deren technische Mischungen. Auch Addukte von 10 - 100 Mol Ethylenoxid an technische Fettalkohole mit 12 - 18 Kohlenstoffatomen, wie beispielsweise Kokos-, Palm-, Palmkern- oder Talgfettalkohol, sind geeignet. Die ethoxylierten C8-C24-Carbonsäuren haben die Formel R (OCH2CH2)nOH, wobei R steht für einen linearen oder verzweigten gesättigten oder ungesättigten Acylrest mit 8 -24 Kohlenstoffatomen und n, die mittlere Anzahl der Ethylenoxid-Einheiten pro Molekül, für Zahlen von 10 - 100, vorzugsweise 10 - 30 Mol Ethylenoxid an 1 Mol Caprylsäure, 2-Ethylhexansäure, Caprinsäure, Laurinsäure, Isotridecansäure, Myristinsäure, Cetylsäure, Palmitoleinsäure, Stearinsäure, Isostearinsäure, Ölsäure, Elaidinsäure, Petroselinsäure, Arachinsäure, Gadoleinsäure, Behensäure, Erucasäure und Brassidinsäure sowie deren technische Mischungen. Auch Addukte von 10 - 100 Mol Ethylenoxid an technische Fettsäuren mit 12 - 18 Kohlenstoffatomen, wie Kokos-, Palm-, Palmkern- oder Talgfettsäure, sind geeignet. Besonders bevorzugt sind PEG-50-monostearat, PEG-100-monostearat, PEG-50-monooleat, PEG-100-monooleat, PEG-50-monolaurat und PEG- 100-monolaurat. The ethoxylated C 8 -C 24 -alkanols have the formula R 0 (CH 2 CH 2 O) n H, where R is a linear or branched alkyl and / or alkenyl radical having 8-24 carbon atoms and n, the average number of Ethylene oxide units per molecule, for numbers from 10 to 100, preferably 10 to 30, mol of ethylene oxide to 1 mol of caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, isocetyl alcohol, palmitoleyl alcohol, stearyl alcohol, isostearyl alcohol, Oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol, and technical mixtures thereof. Also, adducts of 10-100 moles of ethylene oxide with technical fatty alcohols having 12-18 carbon atoms, such as coconut, palm, palm kernel or tallow fatty alcohol, are suitable. The ethoxylated C 8 -C 24 carboxylic acids have the formula R (OCH 2 CH 2 ) n OH, where R is a linear or branched saturated or unsaturated acyl radical having 8-24 carbon atoms and n, the average number of ethylene oxide units per Molecule, for numbers from 10 to 100, preferably 10 to 30, mol of ethylene oxide to 1 mol of caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, cetylic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, arachidic acid, gadoleic acid, Behenic acid, erucic acid and brassidic acid as well as their technical mixtures. Adducts of 10 to 100 moles of ethylene oxide with technical fatty acids containing 12 to 18 carbon atoms, such as coconut, palm, palm kernel or tallow fatty acid, are also suitable. Particularly preferred are PEG-50 monostearate, PEG-100 monostearate, PEG-50 monooleate, PEG-100 monooleate, PEG-50 monolaurate and PEG-100 monolaurate.
Besonders bevorzugt eingesetzt werden die C 2-C 8-Alkanole oder die C 2-C 8-Carbonsäuren mit jeweils 10 - 30 Einheiten Ethylenoxid pro Molekül sowie Mischungen dieser Substanzen, insbesondere Ceteth-12, Ceteth-20, Ceteth-30, lsoceteth-20, Steareth-12, Steareth-20, Steareth- 21 , Steareth-30, Ceteareth-12, Ceteareth-20, Ceteareth-30, Laureth-12 und Beheneth-20. Particular preference is given to using the C 2 -C 8 -alkanols or the C 2 -C 8 -carboxylic acids with in each case 10 to 30 units of ethylene oxide per molecule and also mixtures of these substances, in particular ceteth-12, ceteth-20, ceteth-30, isoceteth- 20, steareth-12, steareth-20, steareth-21, steareth-30, ceteareth-12, ceteareth-20, ceteareth-30, laureth-12 and beheneth-20.
Weiterhin werden vorzugsweise C8 - C22-Alkylmono- und -oligoglycoside eingesetzt. C8 -C22- Alkylmono- und -oligoglycoside stellen bekannte, handelsübliche Tenside und Emulgatoren dar. Ihre Herstellung erfolgt insbesondere durch Umsetzung von Glucose oder Oligosacchariden mit primären Alkoholen mit 8 - 22 Kohlenstoffatomen. Bezüglich des Glycosidrestes gilt, dass sowohl Monoglycoside, bei denen ein cyclischer Zuckerrest glycosidisch an den Fettalkohol gebunden ist, als auch oligomere Glycoside mit einem Oligomerisationsgrad bis etwa 8, vorzugsweise 1 - 2, geeignet sind. Der Oligomerisierungsgrad ist dabei ein statistischer Mittelwert, dem eine für solche technischen Produkte übliche Homologenverteilung zugrunde liegt. Produkte, die unter dem Warenzeichen Plantacare® erhältlich sind, enthalten eine glucosidisch gebundene C8-C 6- Alkylgruppe an einem Oligoglucosidrest, dessen mittlerer Oligomerisationsgrad bei 1 - 2, insbesondere bei 1 ,1 - 1 ,4, liegt. Besonders bevorzugte C8 - C22-Alkylmono- und -oligoglycoside sind ausgewählt aus Octylglucosid, Decylglucosid, Laurylglucosid, Palmitylglucosid, Isostearylglucosid, Stearylglucosid, Arachidylglucosid und Behenylglucosid sowie Mischungen hiervon. Auch die vom Glucamin abgeleiteten Acylglucamide sind als nicht-ionische ÖI-in-Wasser-Emulgatoren geeignet. Auch ethoxylierte Sterine, insbesondere ethoxylierte Sojasterine, stellen erfindungsgemäß geeignete ÖI-in-Wasser-Emulgatoren dar. Der Ethoxylierungsgrad muss größer als 5, bevorzugt mindestens 10 sein, um einen HLB-Wert größer 7 aufzuweisen. Geeignete Handelsprodukte sind z. B. PEG-10 Soy Sterol, PEG-16 Soy Sterol und PEG-25 Soy Sterol. Furthermore, preference is given to using C 8 -C 22 -alkyl mono- and -oligoglycosides. C 8 -C 22 -alkylmono- and -oligoglycosides are known, commercially available surfactants and emulsifiers. They are prepared in particular by reacting glucose or oligosaccharides with primary alcohols having 8-22 carbon atoms. With regard to the glycoside radical, monoglycosides in which a cyclic sugar residue is glycosidically linked to the fatty alcohol and oligomeric glycosides having a degree of oligomerization of up to about 8, preferably 1-2, are suitable. The degree of oligomerization is a statistical mean, the one for such technical products is based on the usual homolog distribution. Products which are obtainable under the trademark Plantacare ®, containing a glucosidic bond C 8 -C 6 - alkyl group at an oligoglucoside whose average degree of oligomerization at 1 - 2, in particular 1, 1 - 1, 4, is located. Particularly preferred C 8 -C 22 alkyl mono- and oligoglycosides are selected from octyl glucoside, decyl glucoside, lauryl glucoside, palmityl glucoside, isostearyl glucoside, stearyl glucoside, arachidyl glucoside and behenyl glucoside and mixtures thereof. The glucamine-derived acylglucamides are also suitable as nonionic oil-in-water emulsifiers. Ethoxylated sterols, in particular ethoxylated soy sterols, are also suitable oil-in-water emulsifiers according to the invention. The degree of ethoxylation must be greater than 5, preferably at least 10, in order to have an HLB value greater than 7. Suitable commercial products are, for. PEG-10 Soy Sterol, PEG-16 Soy Sterol and PEG-25 Soy Sterol.
Weiterhin werden vorzugsweise Partialester von Polyglycerinen mit 2 bis 10 Glycerineinheiten und mit 1 bis 4 gesättigten oder ungesättigten, linearen oder verzweigten, gegebenenfalls hydro- xylierten C8 - C30-Fettsäureresten verestert, eingesetzt, sofern sie einen HLB-Wert von mehr als 7 aufweisen. Besonders bevorzugt sind Diglycerinmonocaprylat, Diglycerinmonocaprat, Diglyce- rinmonolaurat, Triglycerinmonocaprylat, Triglycerinmonocaprat, Triglycerinmonolaurat, Tetragly- cerinmonocaprylat, Tetraglycerinmonocaprat, Tetraglycerinmonolaurat, Pentaglycerinmonocapry- lat, Pentaglycerinmonocaprat, Pentaglycerinmonolaurat, Hexaglycerinmonocaprylat, Hexaglyce- rinmonocaprat, Hexa glycerinmonolaurat, Hexaglycerinmonomyristat, Hexaglycerinmonostearat, Decaglycerinmonocaprylat, Decaglycerinmonocaprat, Decaglycerinmonolaurat, Decaglycerin- monomyristat, Decaglycerinmonoisostearat, Decaglycerinmonostearat, Decaglycerinmonooleat, Decaglycerinmonohydroxystearat, Decaglycerindicaprylat, Decaglycerindicaprat, Decaglycerindi- laurat, Decaglycerindimyristat, Decaglycerindiisostearat, Decaglycerindistearat, Decaglycerindi- oleat, Decaglycerindihydroxystearat, Decaglycerintricaprylat, Decaglycerintricaprat, Decaglycerin- trilaurat, Decaglycerintrimyristat, Decaglycerintriisostearat, Decaglycerintristearat, Decaglycerintri- oleat und Decaglycerintrihydroxystearat. Furthermore, partial esters of polyglycerols having 2 to 10 glycerol units and having 1 to 4 saturated or unsaturated, linear or branched, optionally hydroxylated C 8 -C 30 fatty acid radicals are preferably esterified, if they have an HLB value of more than 7 , Particularly preferred Diglycerinmonocaprylat, Diglycerinmonocaprat, diglycerol are rinmonolaurat, Triglycerinmonocaprylat, Triglycerinmonocaprat, triglycerol, Tetragly- cerinmonocaprylat, rinmonocaprat Tetraglycerinmonocaprat, Tetraglycerinmonolaurat, Pentaglycerinmonocapry- lat, Pentaglycerinmonocaprat, Pentaglycerinmonolaurat, Hexaglycerinmonocaprylat, Hexaglyce-, hexa glycerol, Hexaglycerinmonomyristat, Hexaglycerinmonostearat, Decaglycerinmonocaprylat, Decaglycerinmonocaprat, decaglyceryl monolaurate, monomyristate Decaglycerin-, laurate Decaglycerinmonoisostearat, decaglycerol monostearate, Decaglycerinmonooleat, Decaglycerinmonohydroxystearat, Decaglycerindicaprylat, Decaglycerindicaprat, Decaglycerindi-, Decaglycerindimyristat, Decaglycerindiisostearat, Decaglycerindistearat, Decaglycerindi- oleate, trilaurate Decaglycerindihydroxystearat, Decaglycerintricaprylat, Decaglycerintricaprat, Decaglycerin-, Decaglycerintrimyristat, Decaglycerintriisostearat, Decaglycerintrist earat, decaglycerol tri oleate and decaglycerol trihydroxystearate.
Weitere erfindungsgemäß bevorzugte ÖI-in-Wasser-Emulgatoren sind ausgewählt aus Organo- siloxan-Oxyalkylen-Copolymeren.  Further inventively preferred oil-in-water emulsifiers are selected from organosiloxane-oxyalkylene copolymers.
Erfindungsgemäß besonders bevorzugte Organosiloxan-Oxyalkylen-Copolymere sind ausgewählt aus linearen Polysiloxan-Polyoxyalkylen-Blockcopolymeren, insbesondere aus linearen Polysil- oxan-Polyoxyethylen-Polyoxypropylen-Blockcopolymeren. Erfindungsgemäß außerordentlich bevorzugt ist ein lineares Polysiloxan-Polyoxyethylen-Polyoxypropylen-Blockcopolymer mit der INCI-Bezeichnung PEG/PPG-22/24 Dimethicone und der CAS-Nr. 64365-23-7. Ein derartiges lineares Polysiloxan-Polyoxyethylen-Polyoxypropylen-Blockcopolymer ist beispielsweise unter dem Handelsnamen Mirasil DMCO (INCI: PEG/PPG-22/24 Dimethicone) von Rhodia bzw. Blue- star Silicones erhältlich. Ein weiteres bevorzugtes lineares Polysiloxan-Polyoxyethylen-Polyoxy- propylen-Blockcopolymer dieses Typs trägt die INCI-Bezeichnung PEG/PPG-10/2 Dimethicone. Es ist beispielsweise unter der Handelsbezeichnung Mirasil DMCP 93 (INCI: PEG/PPG-10/2 Dimethicone) von Rhodia bzw. Bluestar Silicones erhältlich. Particularly preferred organosiloxane-oxyalkylene copolymers according to the invention are selected from linear polysiloxane-polyoxyalkylene block copolymers, in particular from linear polysiloxane-polyoxyethylene-polyoxypropylene block copolymers. Extremely preferred according to the invention is a linear polysiloxane-polyoxyethylene-polyoxypropylene block copolymer having the INCI name PEG / PPG-22/24 dimethicones and CAS no. 64365-23-7. Such a linear polysiloxane-polyoxyethylene-polyoxypropylene block copolymer is available, for example, under the trade name Mirasil DMCO (INCI: PEG / PPG-22/24 dimethicone) from Rhodia or Bluestar Silicones. Another preferred linear polysiloxane-polyoxyethylene-polyoxyethylene propylene block copolymer of this type carries the INCI name PEG / PPG-10/2 Dimethicone. It is available, for example, under the trade name Mirasil DMCP 93 (INCI: PEG / PPG-10/2 Dimethicone) from Rhodia or Bluestar Silicones.
Weitere bevorzugte Organosiloxan-Oxyalkylen-Copolymer-O/W-Emulgatoren sind ausgewählt aus Verbindungen der allgemeinen Strukturformeln (I), (II), (III), (IV) und (V),
Figure imgf000016_0001
Further preferred organosiloxane-oxyalkylene copolymer O / W emulsifiers are selected from compounds of the general structural formulas (I), (II), (III), (IV) and (V),
Figure imgf000016_0001
Si— O— ]n— Si- (l)Si- O-] n - Si- (l)
Figure imgf000016_0002
Figure imgf000016_0002
(II)(II)
Figure imgf000016_0003
Figure imgf000016_0003
(IN)(IN)
Figure imgf000016_0004
Figure imgf000016_0004
CH3 CH 3
I I
O Si-]x-(OC2H4)a(OC3H6)bOR4]3 (IV) O Si-] x - (OC 2 H 4 ) a (OC 3 H 6 ) b OR 4 ] 3 (IV)
I I
CH3
Figure imgf000016_0005
CH 3
Figure imgf000016_0005
R! Si— O— ]n— Si— (V)R ! Si- O-] n - Si- (V)
Figure imgf000016_0006
wobei
Figure imgf000016_0006
in which
die Reste R unabhängig voneinander eine lineare oder verzweigte C^Cso-Alkylgruppe oder eine ggf. substituierte Phenylgruppe darstellen, the radicals R independently of one another represent a linear or branched C 1 -C 5 -alkyl group or an optionally substituted phenyl group,
die Reste R2 unabhängig voneinander die Gruppen -CcH2c-0-(C2H40-)a(C3H60-)bR5 oder -CcH2c- 0-(C2H40-)aR5 darstellen, die Reste R3 und R4 unabhängig voneinander eine lineare oder verzweigte C^C^-Alkylgruppe und bevorzugt Methylgruppen darstellen, the radicals R 2 independently of one another are the groups -C c H 2 c-O- (C 2 H 4 O-) a (C 3 H 6 O-) b R 5 or -C c H 2c -O- (C 2 H 4 0-) a R 5 , the radicals R 3 and R 4 independently of one another represent a linear or branched C 1 -C 4 -alkyl group and preferably methyl groups,
die Reste R5 unabhängig voneinander ein Wasserstoffatom oder eine lineare oder verzweigte C^C^-Alkylgruppe und bevorzugt ein Wasserstoffatom oder eine Methylgruppe darstellen, m eine Zahl von 0 - 20 darstellt, n eine Zahl von 0 - 500 darstellt, o eine Zahl von 0 - 20 darstellt, p eine Zahl von 1 - 50 darstellt, a eine Zahl von 0 - 50 darstellt, b eine Zahl von 0 - 50 darstellt, a + b mindestens 1 sind, c eine Zahl von 1 - 4 , besonders bevorzugt 3 , darstellt, x eine Zahl von 1 - 1 00 darstellt. the radicals R 5 independently of one another represent a hydrogen atom or a linear or branched C 1 -C 4 -alkyl group and preferably a hydrogen atom or a methyl group, m represents a number from 0-20, n represents a number from 0-500, o a number from 0 - 20, p represents a number from 1 to 50, a represents a number from 0 to 50, b represents a number from 0 to 50, a + b at least 1, c a number from 1 to 4, particularly preferred 3 , x represents a number from 1 to 100.
Erfindungsgemäß bevorzugte Zusammensetzungen sind dadurch gekennzeichnet, dass mindestens ein Organosiloxan-Oxyalkylen-Copolymer der allgemeinen Strukturformel (II) enthalten ist mit R = Methyl, R2 = -CcH2c-0-(C2H40-)a(C3H60-)bR5 mit a = 1 8 , b = 1 8, c = 3, R5 = Methyl, n = 1 0 - 500 und p = 1 0 - 50. Ein derartiges Organosiloxan-Oxyalkylen-Copolymer ist beispielsweise unter der Handelsbezeichnung Dow Corning 1 90 (INCI: PEG/PPG-1 8/1 8 Dimethicone) erhältlich. Weitere bevorzugte erfindungsgemäße Zusammensetzungen sind dadurch gekennzeichnet, dass mindestens ein Organosiloxan-Oxyalkylen-Copolymer der allgemeinen Strukturformel (II) enthalten ist mit R = Methyl, R2 = -CcH2c-0-(C2H40-)a(C3H60-)bR5 mit a = 1 2, b = 0, c = 3, R5 = Methyl, n = 1 0 - 500 und p = 1 0 - 50. Ein derartiges Organosiloxan-Oxyalkylen-Copolymer ist beispielsweise unter der Handelsbezeichnung Dow Corning 1 93 (INCI: PEG-1 2 Dimethicone) erhältlich. Weitere bevorzugte erfindungsgemäße Zusammensetzungen sind dadurch gekennzeichnet, dass mindestens ein Organosiloxan-Oxyalkylen-Copolymer der allgemeinen Strukturformel (II) enthalten ist mit R = Methyl, R2 = -CcH2c-0-(C2H40-)a(C3H60-)bR5 mit a = 7, b = 0, c = 2, R5 = Methyl, n = 0 und p = 1 . Ein derartiges Organosiloxan-Oxyalkylen-Copolymer ist beispielsweise unter der Handelsbezeichnung Silwet L-77 erhältlich. Preferred compositions according to the invention are characterized in that at least one organosiloxane-oxyalkylene copolymer of the general structural formula (II) is present where R = methyl, R 2 = -C c H 2c- O- (C 2 H 4 O-) a (C 3 H 6 O-) b R 5 with a = 1 8, b = 1 8, c = 3, R 5 = methyl, n = 1 0-500 and p = 1 0-50. Such an organosiloxane-oxyalkylene copolymer is available, for example, under the trade name Dow Corning 1 90 (INCI: PEG / PPG-1 8/1 8 Dimethicone). Further preferred compositions according to the invention are characterized in that at least one organosiloxane-oxyalkylene copolymer of the general structural formula (II) is present where R = methyl, R 2 = -C c H 2 c-O- (C 2 H 4 O-) a (C 3 H 6 O-) b R 5 with a = 1 2, b = 0, c = 3, R 5 = methyl, n = 1 0 - 500 and p = 1 0 - 50. Such an organosiloxane-oxyalkylene Copolymer is available, for example, under the trade name Dow Corning 1 93 (INCI: PEG-1 2 Dimethicone). Further preferred compositions according to the invention are characterized in that at least one organosiloxane-oxyalkylene copolymer of the general structural formula (II) is present where R = methyl, R 2 = -C c H 2 c-O- (C 2 H 4 O-) a (C 3 H 6 O-) b R 5 with a = 7, b = 0, c = 2, R 5 = methyl, n = 0 and p = 1. Such an organosiloxane-oxyalkylene copolymer is available, for example, under the trade name Silwet L-77.
Weitere bevorzugte erfindungsgemäße Zusammensetzungen sind dadurch gekennzeichnet, dass mindestens ein Organosiloxan-Oxyalkylen-Copolymer der allgemeinen Strukturformel (II) enthalten ist mit R = Methyl, R2 = -CcH2c-0-(C2H40-)a(C3H60-)bR5 mit a = 1 7, b = 1 8, c = 3, R5 = Methyl, n = 1 0 - 500 und p = 1 0 - 50. Ein derartiges Organosiloxan-Oxyalkylen-Copolymer ist beispielsweise unter der Handelsbezeichnung Dow Corning Q2-5220 (INCI: PEG/PPG-1 7/1 8 Dimethicone) erhältlich. Further preferred compositions according to the invention are characterized in that at least one organosiloxane-oxyalkylene copolymer of the general structural formula (II) is present where R = methyl, R 2 = -C c H 2c- O- (C 2 H 4 O-) a ( C 3 H 6 O-) b R 5 with a = 1 7, b = 1 8, c = 3, R 5 = methyl, n = 1 0 - 500 and p = 1 0 - 50. Such an organosiloxane-oxyalkylene Copolymer is available, for example, under the trade name Dow Corning Q2-5220 (INCI: PEG / PPG-1 7/1 8 Dimethicone).
Weitere bevorzugte erfindungsgemäße Zusammensetzungen sind dadurch gekennzeichnet, dass mindestens ein Organosiloxan-Oxyalkylen-Copolymer der allgemeinen Strukturformel (II) enthalten ist mit R = Methyl, R2 = -CcH2c-0-(C2H40-)a(C3H60-)bR5 mit a = 20, b = 6, c = 3, R5 = Methyl, n = 1 0 - 500 und p = 5 - 50. Ein derartiges Organosiloxan-Oxyalkylen-Copolymer ist beispielsweise unter der Handelsbezeichnung Abil B 881 84 (INCI: PEG/PPG-20/6 Dimethicone) erhältlich. Weitere bevorzugte erfindungsgemäße Zusammensetzungen sind dadurch gekennzeichnet, dass mindestens ein Organosiloxan-Oxyalkylen-Copolymer der allgemeinen Strukturformel (II) enthal- ten ist mit R = Methyl, R2 = -CcH2c-0-(C2H40-)a(C3H60-)bR5 mit a = 14, b = 4, c = 3, R5 = Methyl, n = 10 - 500 und p = 5 - 50. Ein derartiges Organosiloxan-Oxyalkylen-Copolymer ist beispielsweise unter der Handelsbezeichnung Abil B 8851 (INCI: PEG/PPG-14/4 Dimethicone) erhältlich. Besonders bevorzugte erfindungsgemäße Zusammensetzungen sind dadurch gekennzeichnet, dass mindestens ein ÖI-in-Wasser-Emulgator, bevorzugt mindestens ein nichtionischer Öl-in- Wasser-Emulgator, in einer Gesamtmenge von 0,5 - 10 Gew.-%, bevorzugt 1 - 9 Gew.-%, besonders bevorzugt 1 ,5 - 8,5 Gew.-%, außerordentlich bevorzugt 2 - 8 Gew.-%, weiterhin auch 2,5, 3, 3,5, 4,0, 4,5, 5, 5,5, 6, 6,5, 7, 7,5, und 8 Gew.-%, bezogen auf die treibmittelfreie Zusammensetzung, enthalten ist. Further preferred compositions according to the invention are characterized in that at least one organosiloxane-oxyalkylene copolymer of the general structural formula (II) is present where R = methyl, R 2 = -C c H 2c- O- (C 2 H 4 O-) a ( C 3 H 6 O-) b R 5 with a = 20, b = 6, c = 3, R 5 = methyl, n = 1 0-500 and p = 5-50. Such an organosiloxane-oxyalkylene copolymer is, for example available under the trade name Abil B 881 84 (INCI: PEG / PPG-20/6 Dimethicone). Further preferred compositions according to the invention are characterized in that at least one organosiloxane-oxyalkylene copolymer of the general structural formula (II) is present. with R = methyl, R 2 = -C c H 2 c-O- (C 2 H 4 O-) a (C 3 H 6 O-) b R 5 with a = 14, b = 4, c = 3, R 5 = methyl, n = 10 - 500 and p = 5 - 50. Such an organosiloxane-oxyalkylene copolymer is available, for example, under the trade name Abil B 8851 (INCI: PEG / PPG-14/4 Dimethicone). Particularly preferred compositions according to the invention are characterized in that at least one oil-in-water emulsifier, preferably at least one nonionic oil-in-water emulsifier, in a total amount of 0.5-10 wt.%, Preferably 1-9 wt %, more preferably 1.5-8.5% by weight, most preferably 2-8% by weight, and also 2.5, 3, 3.5, 4.0, 4.5, 5, 5.5, 6, 6.5, 7, 7.5, and 8 wt .-%, based on the propellant-free composition is included.
Weitere erfindungsgemäß bevorzugte Zusammensetzungen enthalten mindestens einen Wasser- in-ÖI-Emulgator mit einem HLB-Wert größer 1 ,0 und kleiner/gleich 7,0, bevorzugt mindestens einen nichtionischen Wasser-in-ÖI-Emulgator mit einem HLB-Wert größer 1 ,0 und < 7,0.  Further preferred compositions according to the invention comprise at least one water-in-oil emulsifier having an HLB value greater than 1.0, and less than or equal to 7.0, preferably at least one nonionic water-in-oil emulsifier having an HLB value greater than 1, 0 and <7.0.
Erfindungsgemäß kann es bevorzugt sein, nur einen einzigen Wasser-in-ÖI-Emulgator einzusetzen. In einer anderen bevorzugten Ausführungsform enthalten die erfindungsgemäßen Zusammensetzungen Mischungen, insbesondere technische Mischungen, von mindestens zwei Wasser- in-ÖI-Emulgatoren. According to the invention, it may be preferable to use only a single water-in-oil emulsifier. In another preferred embodiment, the compositions according to the invention comprise mixtures, in particular technical mixtures, of at least two water-in-oil emulsifiers.
Einige dieser geeigneten Emulgatoren sind beispielsweise in Kirk-Othmer, "Encyclopedia of Chemical Technology", 3. Aufl., 1979, Band 8, Seite 913, aufgelistet. Für ethoxylierte Addukte lässt sich der HLB-Wert, wie bereits erwähnt, auch berechnen.  Some of these suitable emulsifiers are listed, for example, in Kirk-Othmer, "Encyclopedia of Chemical Technology", 3rd Ed., 1979, Vol. 8, page 913. For ethoxylated adducts, the HLB value, as already mentioned, can also be calculated.
Bevorzugte Wasser-in-ÖI-Emulgatoren mit einem HLB-Wert größer 1 ,0 und < 7,0 sind ausgewählt aus den Mono- und Diestern von Ethylenglycol und den Mono-, Di-, Tri- und Tetraestern von Pentaerythrit mit linearen gesättigten Fettsäuren mit 12 - 30, insbesondere 14 - 22 Kohlenstoffatomen, die hydroxyliert sein können, sowie Mischungen hiervon. Erfindungsgemäß bevorzugt sind die Mono- und Diester. Erfindungsgemäß bevorzugte C 2-C30-Fettsäurereste sind ausgewählt aus Laurinsäure-, Myristinsäure-, Palmitinsäure-, Stearinsäure-, Arachinsäure- und Behensäure-Resten; besonders bevorzugt ist der Stearinsäurerest. Erfindungsgemäß besonders bevorzugte nichtionische Wasser-in-ÖI-Emulgatoren mit einem HLB-Wert größer 1 ,0 und < 7,0 sind ausgewählt aus Pentaerythritylmonostearat, Pentaerythrityldistearat, Pentaerythrityltristearat, Pentaerythrityltetrastearat, Ethylenglycolmonostearat, Ethylenglycoldistearat sowie Mischungen hiervon. Erfindungsgemäß besonders bevorzugte Wasser-in-ÖI-Emulgatoren mit einem HLB-Wert größer 1 ,0 und < 7,0 sind zum Beispiel als Handelsprodukte Cutina® PES (INCI: Pentaerythrityl distearate), Cutina® AGS (INCI: Glycol distearate) oder Cutina® EGMS (INCI: Glycol stearate) erhältlich. Diese Handelsprodukte stellen bereits Mischungen aus Mono- und Diestern (bei den Pentaerythritylestern sind auch Tri- und Tetraester enthalten) dar. Unter einer technischen Mischung wird beispielsweise ein Handelsprodukt wie Cutina® PES verstanden. Preferred water-in-oil emulsifiers with an HLB value greater than 1.0, and <7.0 are selected from the mono- and diesters of ethylene glycol and the mono-, di-, tri- and tetra-esters of pentaerythritol with linear saturated fatty acids with 12-30, in particular 14-22, carbon atoms which may be hydroxylated, as well as mixtures thereof. According to the invention, the mono- and diesters are preferred. C 2 -C 30 fatty acid radicals preferred according to the invention are selected from lauric acid, myristic acid, palmitic acid, stearic acid, arachic acid and behenic acid radicals; particularly preferred is the stearic acid residue. Particularly preferred nonionic water-in-oil emulsifiers according to the invention having an HLB value greater than 1.0, and <7.0 are selected from pentaerythrityl monostearate, pentaerythrityl distearate, pentaerythrityl tristearate, pentaerythrityl tetrastearate, ethylene glycol monostearate, ethylene glycol distearate, and mixtures thereof. According to the invention, particularly preferred water-in-oil emulsifiers having an HLB value greater than 1, 0 and <7.0 are, for example, as commercial products Cutina ® PES (INCI: Pentaerythrityl distearate), Cutina ® AGS (INCI: Glycol distearate) or Cutina ® EGMS (INCI: Glycol stearate) available. These commercial products are already mixtures of mono- and diesters (in the pentaerythrityl esters are also tri- and tetraesters contain). Under a technical mixture, for example, a commercial product such as Cutina ® understood PES.
Weitere bevorzugte Wasser-in-ÖI-Emulgatoren sind: lineare gesättigte Alkanole mit 12 - 30 Kohlenstoffatomen, insbesondere mit 16 - 22 Kohlenstoffatomen, insbesondere Cetylalkohol, Stearylalkohol, Arachidylalkohol, Behenylalkohol und Lanolinalkohol oder Gemische dieser Alkohole, wie sie bei der technischen Hydrierung von pflanzlichen und tierischen Fettsäuren erhältlich sind, Other preferred water-in-oil emulsifiers are: linear saturated alkanols having 12-30 carbon atoms, in particular having 16-22 carbon atoms, in particular cetyl alcohol, stearyl alcohol, arachidyl alcohol, behenyl alcohol and lanolin alcohol or mixtures of these alcohols, as obtainable in the industrial hydrogenation of vegetable and animal fatty acids,
Ester und insbesondere Partialester aus einem Polyol mit 3 - 6 C-Atomen und linearen gesättigten und ungesättigten Fettsäuren mit 12 - 30, insbesondere 14 - 22 C-Atomen, die hydroxyliert sein können. Solche Ester oder Partialester sind z. B. die Mono- und Diester von Glycerin oder die Monoester von Propylenglycol mit linearen gesättigten und ungesättigten C12 - C30-Carbonsäuren, die hydroxyliert sein können, insbesondere diejenigen mit Palmitin- und Stearinsäure, die Sorbitanmono-, -di- oder -triester von linearen gesättigten und ungesättigten C 2 - C30-Carbonsäuren, die hydroxyliert sein können, insbesondere diejenigen von Myristinsäure, Palmitinsäure, Stearinsäure oder von Mischungen dieser Fettsäuren und die Methylglucosemono- und -diester von linearen gesättigten und ungesättigten C 2 - C30- Carbonsäuren, die hydroxyliert sein können; Esters and in particular partial esters of a polyol having 3 to 6 C atoms and linear saturated and unsaturated fatty acids having 12 to 30, in particular 14 to 22, C atoms which may be hydroxylated. Such esters or partial esters are, for. The monoesters and diesters of glycerine or the monoesters of propylene glycol with linear saturated and unsaturated C 12 -C 30 carboxylic acids which may be hydroxylated, especially those with palmitic and stearic acid, the sorbitan mono-, di- or triesters of linear saturated and unsaturated C 2 - C 30 carboxylic acids, which may be hydroxylated, especially those of myristic acid, palmitic acid, stearic acid or of mixtures of these fatty acids and the monoesters and diesters of Methylglucosemono- linear saturated and unsaturated C 2 - C 30 - carboxylic acids, which may be hydroxylated;
Sterine, also Steroide, die am C3-Atom des Steroid-Gerüstes eine Hydroxylgruppe tragen und sowohl aus tierischem Gewebe (Zoosterine, z. B. Cholesterin, Lanosterin) wie auch aus Pflanzen (Phytosterine, z. B. Ergosterin, Stigmasterin, Sitosterin) und aus Pilzen und Hefen (Mykosterine) isoliert werden und die niedrig ethoxyliert (1 - 5 EO) sein können;  Sterols, ie steroids which carry a hydroxyl group at the C3 atom of the steroid skeleton and both from animal tissue (zoosterols, eg cholesterol, lanosterol) as well as from plants (phytosterols, eg ergosterol, stigmasterol, sitosterol) and from fungi and yeasts (mycosterols) which may be low ethoxylated (1-5 EO);
Alkanole und Carbonsäuren mit jeweils 8 - 24 C-Atomen, insbesondere mit 16 - 22 C- Atomen, in der Alkylgruppe und 1 - 4 Ethylenoxid-Einheiten pro Molekül, die einen HLB-Wert größer 1 ,0 und kleiner/gleich 7,0 aufweisen,  Alkanols and carboxylic acids each having 8-24 C atoms, in particular having 16-22 C atoms, in the alkyl group and 1-4 ethylene oxide units per molecule which have an HLB value of greater than 1.0, and less than or equal to 7.0 exhibit,
Glycerinmonoether gesättigter und/oder ungesättigter, verzweigter und/oder unverzweigter Alkohole einer Kettenlänge von 8 - 30, insbesondere 12 - 18 Kohlenstoffatomen.  Glycerol monoethers of saturated and / or unsaturated, branched and / or unbranched alcohols of a chain length of 8-30, in particular 12-18 carbon atoms.
Partialester von Polyglycerinen mit n = 2 bis 10 Glycerineinheiten und mit 1 bis 5 gesättigten oder ungesättigten, linearen oder verzweigten, gegebenenfalls hydroxylierten C8 - C30-Fett- säureresten verestert, sofern sie einen HLB-Wert von kleiner/gleich 7 aufweisen, Partial esters of polyglycerols with n = 2 to 10 glycerol units and with 1 to 5 saturated or unsaturated, linear or branched, optionally hydroxylated C 8 - C 30 fatty acid residues esterified, if they have an HLB value of less than or equal to 7,
sowie Mischungen der vorgenannten Substanzen.  and mixtures of the aforementioned substances.
Besonders vorteilhaft einsetzbare Wasser-in-ÖI-Emulgatoren sind Stearylalkohol, Cetylalkohol, Glycerylmonostearat, Glyceryldistearat, Glycerylmonocaprinat, Glycerylmonocaprylat, Glyceryl- monolaurat, Glycerylmonomyristat, Glycerylmonopalmitat, Glycerylmonohydroxystearat, Glyce- rylmonooleat, Glycerylmonolanolat, Glyceryldimyristat, Glyceryldipalmitat, Glyceryldioleat, Propy- lenglycolmonostearat, Propylenglycolmonolaurat, Sorbitanmonocaprylat, Sorbitanmonolaurat, Sorbitanmonomyristat, Sorbitanmonopalmitat, Sorbitanmonostearat, Sorbitansesquistearat, Sorbi- tandistearat, Sorbitandioleat, Sorbitansesquioleat, Saccharosedistearat, Arachidylalkohol, Behenylalkohol, Polyethylenglycol(2)stearylether (Steareth-2), Steareth-5, Oleth-2, Diglycerinmono- stearat, Diglycerinmonoisostearat, Diglycerinmonooleat, Diglycerindihydroxystearat, Diglycerindi- stearat, Diglycerindioleat, Triglycerindistearat, Tetraglycerinmonostearat, Tetraglycerindistearat, Tetraglycerintristearat, Decaglycerinpentastearat, Decaglycerinpentahydroxystearat, Decaglyce- rinpentaisostearat, Decaglycerinpentaoleat, Soy Sterol, PEG-1 Soy Sterol, PEG-5 Soy Sterol, PEG-2-monolaurat und PEG-2-monostearat. Particularly advantageously usable water-in-oil emulsifiers are stearyl alcohol, cetyl alcohol, glyceryl monostearate, glyceryl Glycerylmonocaprinat, glyceryl, glyceryl monolaurate, glyceryl monomyristate rylmonooleat, glyceryl, Glycerylmonohydroxystearat, glycerol, lenglycolmonostearat Glycerylmonolanolat, Glyceryldimyristat, Glyceryldipalmitat, glyceryl, propylene, propylene glycol , Sorbitan monocaprylate, sorbitan monolaurate, sorbitan monomyristate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquistearate, sorbitan tandearate, sorbitan dioleate, sorbitan sesquioleate, sucrose distearate, arachidyl alcohol, behenyl alcohol, polyethylene glycol (2) stearyl ether (steareth-2), steareth-5, oleth-2, diglycerol monostearate, Diglycerol monoisostearate, diglycerol monooleate, diglycerol dihydroxystearate, diglycerin stearate, diglycerol dioleate, triglycerol distearate, tetraglycerol monostearate, tetraglycerol distearate, tetraglycerol tristearate, decaglycerol penta stearate, decaglycerin pentahydroxystearate, decaglycerin pentaaisstearate, decaglycerin pentaoleate, soy sterol, PEG-1 soy sterol, PEG-5 soy sterol, PEG-2 monolaurate and PEG-2 monostearate.
Weitere erfindungsgemäß bevorzugte W/O-Emulgatoren sind Silicon-freie polymere Wasser-in- Öl-Emulgatoren, insbesondere PEG-30 Dipolyhydroxystearat, erhältlich z. B. unter dem Handelsnamen Arlacel P 135 von Uniqema.  Further inventively preferred W / O emulsifiers are silicone-free polymeric water-in-oil emulsifiers, in particular PEG-30 dipolyhydroxystearate, available for. B. under the trade name Arlacel P 135 from Uniqema.
Eine erfindungsgemäß besonders bevorzugte Gruppe von Wasser-in-ÖI-Emulgatoren auf Siliconbasis sind die Poly-(C2-C3)alkylenglycol-modifizierten Silicone, deren frühere INCI-Bezeichnung Dimethicone Copolyol lautete, mit den aktuellen INCI-Bezeichnungen PEG-x Dimethicone (mit x = 2 - 20, bevorzugt 3 - 17, besonders bevorzugt 1 1 - 12), Bis-PEG-y Dimethicone (mit y = 3 - 25, bevorzugt 4 - 20), PEG/PPG a/b Dimethicone (wobei a und b unabhängig voneinander für Zahlen von 2 - 30, bevorzugt 3 - 30 und besonders bevorzugt 12 - 20, insbesondere 14 - 18, stehen), Bis-PEG/PPG-c/d Dimethicone (wobei c und d unabhängig voneinander für Zahlen von 10 - 25, bevorzugt 14 - 20 und besonders bevorzugt 14 - 16, stehen) und Bis-PEG/PPG-e/f PEG/PPG g/h Dimethicone (wobei e, f, g und h unabhängig voneinander für Zahlen von 10 - 20, bevorzugt 14 - 18 und besonders bevorzugt 16, stehen). Besonders bevorzugt sind PEG/PPG-18/18 Dimethicone, das z. B. in einer 1 :9-Mischung mit Cyclomethicone unter der Bezeichnung Dow Corning 3225 C bzw. Dow Corning 5225 C im Handel erhältlich ist, PEG/PPG-18/18 Dimethicone, das z. B. in einer 1 :3-Mischung mit nicht-flüchtigem Dimethicone als Dow Corning ES 5227 DM Formulation Aid im Handel erhältlich ist, PEG/PPG-4/12 Dimethicone, das z. B. unter der Bezeichnung Abil B 8852 erhältlich ist, sowie Bis-PEG/PPG-14/14 Dimethicone, das z. B. in einer Mischung mit Cyclomethicone als Abil EM 97 (Evonik) im Handel erhältlich ist, Bis-PEG/PPG- 20/20 Dimethicone, das z. B. unter der Bezeichnung Abil B 8832 erhältlich ist, PEG/PPG-5/3 Trisiloxane (z. B. Silsoft 305), sowie PEG/PPG-20/23 Dimethicone (z. B. Silsoft 430 und Silsoft 440). A particularly preferred group of silicone-based water-in-oil emulsifiers according to the invention are the poly (C 2 -C 3 ) alkylene glycol-modified silicones whose earlier INCI name was dimethicone copolyol, with the current INCI names PEG-x dimethicone (with x = 2-20, preferably 3-17, more preferably 1-1-12), bis-PEG-y dimethicone (with y = 3-25, preferably 4-20), PEG / PPG a / b dimethicone (where a and b independently of one another represent numbers from 2 to 30, preferably 3 to 30 and more preferably 12 to 20, in particular 14 to 18), bis-PEG / PPG-c / d dimethicones (where c and d independently of one another represent numbers 10-25, preferably 14-20 and more preferably 14-16) and bis-PEG / PPG-e / f PEG / PPG g / h dimethicone (where e, f, g and h independently represent numbers of 10 20, preferably 14-18 and more preferably 16). Particularly preferred are PEG / PPG-18/18 dimethicones, z. B. in a 1: 9 mixture with Cyclomethicone under the name Dow Corning 3225 C or Dow Corning 5225 C is commercially available, PEG / PPG-18/18 Dimethicone, the z. B. in a 1: 3 mixture with non-volatile dimethicone as Dow Corning ES 5227 DM Formulation Aid is commercially available, PEG / PPG-4/12 Dimethicone, the z. B. under the name Abil B 8852 is available, and bis-PEG / PPG-14/14 Dimethicone, the z. B. in a mixture with Cyclomethicone as Abil EM 97 (Evonik) is commercially available Bis-PEG / PPG 20/20 Dimethicone, the z. B. under the name Abil B 8832, PEG / PPG-5/3 trisiloxanes (eg Silsoft 305), and PEG / PPG-20/23 Dimethicone (eg Silsoft 430 and Silsoft 440).
Weitere erfindungsgemäß bevorzugte W/O-Emulgatoren auf Siliconbasis sind Poly-(C2-C3)alky- lenglycol-modifizierte Silicone, die mit C4-C 8-Alkylgruppen hydrophob modifiziert sind, besonders bevorzugt Cetyl PEG/PPG-10/1 Dimethicone (früher: Cetyl Dimethicone Copolyol, z. B. erhältlich als Abil EM 90 oder in einer Mischung aus Polyglyceryl-4-isostearat, Cetyl PEG/PPG-10/1 Dimethicone und Hexyllaurat unter der Handelsbezeichnung Abil WE 09), weiterhin Alkyl Methicone Copolyole und Alkyl Dimethicone Ethoxy Glucoside. Other silicone-based W / O emulsifiers which are preferred according to the invention are poly (C 2 -C 3 ) -alkylene glycol-modified silicones which are hydrophobically modified with C 4 -C 8 -alkyl groups, particularly preferably cetyl PEG / PPG-10/1 Dimethicone (formerly: Cetyl Dimethicone Copolyol, eg available as Abil EM 90 or in a mixture of polyglyceryl-4-isostearate, Cetyl PEG / PPG-10/1 dimethicone and hexyl laurate under the trade name Abil WE 09), furthermore alkyl methicone Copolyols and Alkyl Dimethicone Ethoxy Glucosides.
Weitere erfindungsgemäß bevorzugte Zusammensetzungen enthalten mindestens einen Wasser- in-ÖI-Emulgator in einer Gesamtmenge von 0,01 - 7 Gew.-%, bevorzugt 0,1 - 3 Gew.-%, besonders bevorzugt 0,5 - 1 Gew.-%. Die erfindungsgemäßen Deodorant- oder Antitranspirant-Zusammensetzungen enthalten weiterhin 0,1 - 50 Gew.-% mindestens eines Deodorant- oder Antitranspirant-Wirkstoffs. Further inventively preferred compositions contain at least one water-in-oil emulsifier in a total amount of 0.01 to 7 wt .-%, preferably 0.1 to 3 wt .-%, particularly preferably 0.5 to 1 wt .-% , The deodorant or antiperspirant compositions according to the invention also contain 0.1-50% by weight of at least one deodorant or antiperspirant active ingredient.
Der Antitranspirant-Wirkstoff ist bevorzugt ausgewählt aus Aluminiumchlorhydroxiden (= Aluminiumchlorhydraten) und deren Derivaten und Komplexverbindungen, die im folgenden erläutert sind. Prinzipiell sind auch Aluminium-Zirconium-Verbindungen geeignet; allerdings sind Zirco- nium-Verbindungen in Aerosolzubereitungen gesetzlich nicht zugelassen. The antiperspirant active is preferably selected from aluminum chlorhydroxides (= aluminum chlorohydrates) and their derivatives and complex compounds, which are explained below. In principle, aluminum-zirconium compounds are suitable; However, zirconium compounds are not permitted by law in aerosol preparations.
Bevorzugte Antitranspirant-Wirkstoffe sind wasserlöslich. Erfindungsgemäß wird unter Wasserlöslichkeit eine Löslichkeit von wenigstens 5 Gew.-% bei 20 °C verstanden, das heißt, dass Mengen von wenigstens 5 g des Antitranspirant-Wrkstoffs in 95 g Wasser bei 20 °C löslich sind. Besonders bevorzugte Antitranspirant-Wirkstoffe sind ausgewählt aus Aluminiumchlorhydrat, insbesondere Aluminiumchlorhydrat mit der allgemeinen Formel [AI2(OH)5CI ■ 1 -6 H20]n, bevorzugt [AI2(OH)5CI ■ 2-3 H20]n, das in nicht-aktivierter oder in aktivierter (depolymerisierter) Form vorliegen kann, sowie Aluminiumchlorhydrat mit der allgemeinen Formel [AI2(OH)4CI2 ■ 1 -6 H20]n, bevorzugt [AI2(OH)4CI2 ■ 2-3 H20]n, das in nicht-aktivierter oder in aktivierter (depolymerisierter) Form vorliegen kann. Die Herstellung bevorzugter Antitranspirant-Wirkstoffe ist beispielsweise in US 3887692, US 3904741 , US 4359456, GB 2048229 und GB 1347950 offenbart. Preferred antiperspirant active ingredients are water-soluble. According to the invention, water solubility is understood to mean a solubility of at least 5% by weight at 20 ° C., that is to say amounts of at least 5 g of the antiperspirant active substance are soluble in 95 g of water at 20 ° C. Particularly preferred antiperspirant actives are selected from aluminum chlorohydrate, aluminum chlorohydrate, in particular having the general formula [Al 2 (OH) 5 CI ■ 1 -6 H 2 0] n, [AI preferably 2 (OH) 5 CI 2-3 ■ H 2 0 ] n , which may be in non-activated or in activated (depolymerized) form, and aluminum chlorohydrate having the general formula [Al 2 (OH) 4 Cl 2 ■ 1 -6 H 2 O] n , preferably [Al 2 (OH) 4 CI 2 ■ 2-3 H 2 O] n , which may be in unactivated or in activated (depolymerized) form. The preparation of preferred antiperspirant agents is disclosed, for example, in US 3887692, US 3904741, US 4359456, GB 2048229 and GB 1347950.
Weiterhin bevorzugt sind Aluminiumsesquichlorhydrat, Aluminiumdichlorhydrat, Aluminiumchlor- hydrex-Propylenglykol (PG) oder Aluminiumchlorhydrex-Polyethylenglykol (PEG), Aluminium- Glycol-Komplexe, z. B. Aluminium-Propylenglycol-Komplexe, Aluminiumsesquichlorhydrex-PG oder Aluminiumsesquichlorhydrex-PEG, Aluminium-PG-dichlorhydrex oder Aluminium-PEG- dichlorhydrex, Aluminiumhydroxid, weiterhin ausgewählt aus Natriumaluminiumchlorhydroxy- lactat, Aluminiumchlorhydroxyallantoinat und Natrium-Aluminium-Chlorhydroxylactat. Also preferred are aluminum sesquichlorohydrate, aluminum dichlorohydrate, aluminum chlorohydrex-propylene glycol (PG) or aluminum chlorohydrex-polyethylene glycol (PEG), aluminum glycol complexes, eg. Aluminum-propylene glycol complexes, aluminum sesquichlorohydrex-PG or aluminum sesquichlorohydrex-PEG, aluminum-PG-dichlorhydrex or aluminum-PEG-dichlorhydrex, aluminum hydroxide, further selected from sodium aluminum chlorohydroxy lactate, aluminum chlorohydrate allantoinate and sodium aluminum chlorhydroxylactate.
Erfindungsgemäß besonders bevorzugte Antitranspirant-Wrkstoffe sind ausgewählt aus so genannten „aktivierten" Aluminiumchlorhydroxiden, die auch als Antitranspirant-Wirkstoffe „mit erhöhter Wrksamkeit (englisch: enhanced activity)" bezeichnet werden. Derartige Wirkstoffe sind im Stand der Technik bekannt und auch kommerziell erhältlich. Ihre Herstellung ist beispielsweise in GB 2048229, US 4775528 und US 6010688 offenbart. Aktivierte Aluminiumchlorhydroxide werden in der Regel durch Wärmebehandlung einer relativ verdünnten Lösung des Salzes erzeugt (z.B. etwa 10 Gew.-% Salz), um dessen HPLC-Peak 4-zu-Peak 3-Flächenverhältnis zu vergrößern. Das aktivierte Salz kann anschließend zu einem Pulver getrocknet, insbesondere sprühgetrocknet werden. Neben der Sprühtrocknung ist z. B. auch die Walzentrocknung geeignet. Aktivierte Aluminiumchlorhydroxide haben typischerweise ein HPLC-Peak 4-zu-Peak 3-Flächen- verhältnis von mindestens 0,4, bevorzugt mindestens 0,7, besonders bevorzugt mindestens 0,9, wobei mindestens 70% des Aluminiums diesen Peaks zuzuordnen sind. Particularly preferred antiperspirant active substances according to the invention are selected from what are known as "activated" aluminum chlorhydroxides, which are also referred to as "antiperspirant active ingredients" having increased activity (English: enhanced activity). Such agents are known in the art and are also commercially available. Their preparation is disclosed, for example, in GB 2048229, US 4775528 and US 6010688. Activated aluminum chlorhydroxides are typically produced by heat treating a relatively dilute solution of the salt (e.g., about 10% by weight of salt) to increase its HPLC peak 4-to-peak 3 area ratio. The activated salt can then be dried to a powder, in particular spray-dried. In addition to the spray drying z. B. also suitable for drum drying. Activated aluminum chlorhydroxides typically have a HPLC peak 4-to-peak 3 area ratio of at least 0.4, preferably at least 0.7, more preferably at least 0.9, with at least 70% of the aluminum attributable to these peaks.
Aktivierte Aluminiumchlorhydroxide müssen nicht notwendigerweise als sprühgetrocknetes Pulver eingesetzt werden. Erfindungsgemäß ebenfalls bevorzugte schweißhemmende Wirkstoffe sind nicht-wässrige Lösungen oder Solubilisate eines aktivierten schweißhemmenden Aluminiumsalzes, beispielsweise gemäß US 6010688, die durch den Zusatz einer wirksamen Menge eines mehrwertigen Alkohols, der 3 bis 6 Kohlenstoffatome und 3 bis 6 Hydroxyl-Gruppen, bevorzugt Propylenglycol, Sorbit und Pentaerythrit, aufweist, gegen den Verlust der Aktivierung gegen den raschen Abbau des HPLC-Peak 4:Peak 3-Flächenverhältnisses des Salzes stabilisiert sind. Beispielsweise bevorzugt sind Zusammensetzungen, die in Gewichtsprozent (USP) enthalten: 12 - 45 Gew.-%, bezogen auf die treibmittelfreie Zusammensetzung, eines aktivierten Aluminiumsalzes, 55 - 82 Gew.-% mindestens eines wasserfreien mehrwertigen Alkohols mit 3 bis 6 Kohlenstoffatomen und 3 bis 6 Hydroxyl-Gruppen, bevorzugt Propylenglycol, Butylenglycol, Diethylen- glycol, Dipropylenglycol, Glycerin, Sorbit und Pentaerythrit, besonders bevorzugt Propylenglycol. Besonders bevorzugt sind auch Komplexe aktivierter schweißhemmender Aluminiumsalze mit einem mehrwertigen Alkohol, die 20 - 50 Gew.-%, besonders bevorzugt 20 - 42 Gew.-%, aktiviertes schweißhemmendes Aluminiumsalzes und 2 - 16 Gew.-% molekular gebundenes Wasser enthalten, wobei der Rest zu 100 Gew.-% mindestens ein mehrwertiger Alkohol mit 3 bis 6 Kohlenstoffatome und 3 bis 6 Hydroxyl-Gruppen ist. Propylenglycol, Propylenglycol/Sorbit- Mischungen und Propylenglycol/Pentaerythrit-Mischungen sind bevorzugte derartige Alkohole. Derartige erfindungsgemäß bevorzugte Komplexe eines aktivierten schweißhemmenden Aluminiumsalzes mit einem mehrwertigen Alkohol sind z. B. offenbart in US 5643558 und US 6245325. Weitere bevorzugte schweißhemmende Wrkstoffe sind basische Calcium-Aluminiumsalze, wie sie beispielsweise in US 2571030 offenbart sind. Diese Salze werden durch Umsetzen von Calciumcarbonat mit Aluminiumchlorhydroxid oder Aluminiumchlorid und Aluminiumpulver oder durch Zusetzen von Calciumchlorid-Dihydrat zu Aluminiumchlorhydroxid hergestellt. Activated aluminum chlorhydroxides do not necessarily have to be used as a spray-dried powder. According to the invention are also preferred antiperspirant active ingredients non-aqueous solutions or solubilisates of an activated antiperspirant aluminum salt, for example according to US 6010688, which comprises adding an effective amount of a polyhydric alcohol having 3 to 6 carbon atoms and 3 to 6 hydroxyl groups, preferably propylene glycol, sorbitol and pentaerythritol the loss of activation against the rapid degradation of the HPLC peak 4: peak 3 area ratio of the salt are stabilized. For example, preferred are weight percent (USP) compositions: 12-45% by weight, based on the propellant-free composition, of an activated aluminum salt, 55-82% by weight of at least one anhydrous polyhydric alcohol of 3 to 6 carbon atoms, and 3 to 6 hydroxyl groups, preferably propylene glycol, butylene glycol, diethylene glycol, dipropylene glycol, glycerol, sorbitol and pentaerythritol, more preferably propylene glycol. Also particularly preferred are complexes of activated antiperspirant aluminum salts with a polyhydric alcohol containing from 20 to 50% by weight, more preferably from 20 to 42% by weight, of activated antiperspirant aluminum salt and from 2 to 16% by weight of molecularly bound water; Rest to 100 wt .-% of at least one polyhydric alcohol having 3 to 6 carbon atoms and 3 to 6 hydroxyl groups. Propylene glycol, propylene glycol / sorbitol mixtures and propylene glycol / pentaerythritol mixtures are preferred such alcohols. Such inventively preferred complexes of an activated antiperspirant aluminum salt with a polyhydric alcohol are, for. Disclosed in US 5643558 and US 6245325. Further preferred antiperspirant actives are basic calcium aluminum salts, as disclosed, for example, in US 2571030. These salts are prepared by reacting calcium carbonate with aluminum chlorhydroxide or aluminum chloride and aluminum powder or by adding calcium chloride dihydrate to aluminum chlorhydroxide.
Weitere bevorzugte schweißhemmende Wirkstoffe sind aktivierte Aluminiumsalze, wie sie beispielsweise in US 6245325 oder US 6042816 offenbart sind, enthaltend 5 - 78 Gew.-% (USP) eines aktivierten schweißhemmenden Aluminiumsalzes, eine Aminosäure oder Hydroxyalkan- säure in einer solchen Menge, um ein (Aminosäure oder Hydroxyalkansäure) zu AI - Gewichtsverhältnis von 2:1 - 1 :20 und bevorzugt 1 :1 bis 1 :10 bereitzustellen, sowie ein wasserlösliches Calciumsalz in einer solchen Menge, um ein Ca:AI-Gewichtsverhältnis von 1 :1 - 1 :28 und bevorzugt 1 :2 - 1 :25 bereitzustellen. Further preferred antiperspirant active compounds are activated aluminum salts, as disclosed, for example, in US Pat. No. 6,245,325 or US Pat. No. 6,042,816, containing 5-78% by weight (USP) of an activated antiperspirant aluminum salt, an amino acid or hydroxyalkanoic acid in such an amount as to afford Amino acid or hydroxyalkanoic acid) to AI weight ratio of 2: 1-1: 20 and preferably 1: 1 to 1:10, and a water-soluble calcium salt in such an amount to give a Ca: Al weight ratio of 1: 1-1: 28 and preferably 1: 2 - 1: 25 provide.
Besonders bevorzugte feste aktivierte schweißhemmende Salzzusammensetzungen, beispielsweise gemäß US 6245325 oder US 6042816, enthalten 48 - 78 Gew.-% (USP), bevorzugt 66 - 75 Gew.-% eines aktivierten Aluminiumsalzes und 1 - 16 Gew.-%, bevorzugt 4 - 13 Gew.-% molekular gebundenes Wasser (Hydratationswasser), weiterhin soviel wasserlösliches Calciumsalz, dass das Ca:AI-Gewichtsverhältnis 1 :1 - 1 :28, bevorzugt 1 :2 - 1 :25, beträgt und soviel Aminosäure, dass das Aminosäure zu AI - Gewichtsverhältnis 2:1 - 1 :20, bevorzugt 1 :1 - 1 :10, beträgt. Weitere besonders bevorzugte feste schweißhemmende aktivierte Salzzusammensetzungen, beispielsweise gemäß US 6245325 oder US 6042816, enthalten 48 - 78 Gew.-% (USP), bevorzugt 66 - 75 Gew.-% eines aktivierten Aluminiumsalzes und 1 - 16 Gew.-%, bevorzugt 4 - 13 Gew.-% molekular gebundenes Wasser (Hydratationswasser), weiterhin soviel wasserlösliches Calcium- salz, dass das Ca:AI-Gewichtsverhältnis 1 :1 - 1 :28, bevorzugt 1 :2 - 1 :25, beträgt und soviel Glycin, dass das Glycin zu AI - Gewichtsverhältnis 2:1 - 1 :20, bevorzugt 1 :1 - 1 :10, beträgt. Particularly preferred solid activated antiperspirant salt compositions, for example according to US Pat. No. 6,245,325 or US Pat. No. 6,042,816, contain 48-78% by weight (USP), preferably 66-75% by weight of an activated aluminum salt and 1-16% by weight, preferably 4%. 13 wt .-% molecularly bound water (water of hydration), further sufficient water-soluble calcium salt that the Ca: Al weight ratio of 1: 1 - 1: 28, preferably 1: 2 - 1: 25, and so much amino acid that the amino acid to Al - weight ratio 2: 1 - 1: 20, preferably 1: 1 - 1: 10, is. Further particularly preferred solid antiperspirant activated salt compositions, for example according to US 6245325 or US 6042816, contain 48-78% by weight (USP), preferably 66-75% by weight of an activated aluminum salt and 1-16% by weight, preferably 4 - 13 wt .-% molecularly bound water (water of hydration), further so much water-soluble calcium salt that the Ca: Al weight ratio of 1: 1 - 1: 28, preferably 1: 2 - 1: 25, and so much glycine, that the glycine to Al - weight ratio 2: 1 - 1: 20, preferably 1: 1 - 1: 10, is.
Weitere besonders bevorzugte feste schweißhemmende aktivierte Salzzusammensetzungen, beispielsweise gemäß US 6245325 oder US 6042816, enthalten 48 - 78 Gew.-% (USP), bevorzugt 66 - 75 Gew.-% eines aktivierten Aluminiumsalzes und 1 - 16 Gew.-%, bevorzugt 4 - 13 Gew.-% molekular gebundenes Wasser, weiterhin soviel wasserlösliches Calciumsalz, dass das Ca:AI- Gewichtsverhältnis 1 :1 - 1 :28, bevorzugt 1 :2 - 1 :25, beträgt und soviel Hydroxyalkansäure, dass das Hydroxyalkansäure zu AI - Gewichtsverhältnis 2:1 - 1 :20, bevorzugt 1 :1 - 1 :10, beträgt. Further particularly preferred solid antiperspirant activated salt compositions, for example according to US 6245325 or US 6042816, contain 48-78% by weight (USP), preferably 66-75% by weight of an activated aluminum salt and 1-16% by weight, preferably 4 - 13 wt .-% molecularly bound water, further so much water-soluble calcium salt that the Ca: AI weight ratio 1: 1 - 1: 28, preferably 1: 2 - 1: 25, and is so much hydroxyalkanoic that the hydroxyalkanoic acid to AI - Weight ratio 2: 1 - 1: 20, preferably 1: 1 - 1: 10, is.
Für die Stabilisierung der schweißhemmenden Salze bevorzugte wasserlösliche Calciumsalze sind ausgewählt aus Calciumchlorid, Calciumbromid, Calciumnitrat, Calciumcitrat, Calciumformiat, Calciumacetat, Calciumgluconat, Calciumascorbat, Calciumlactat, Calciumglycinat, Calciumcarbonat, Calciumsulfat, Calciumhydroxid, sowie Mischungen davon. Preferred water-soluble calcium salts for the stabilization of antiperspirant salts are selected from calcium chloride, calcium bromide, calcium nitrate, calcium citrate, calcium formate, calcium acetate, calcium gluconate, calcium ascorbate, calcium lactate, calcium glycinate, calcium carbonate, calcium sulfate, calcium hydroxide, and mixtures thereof.
Für die Stabilisierung der schweißhemmenden Salze bevorzugte Aminosäuren sind ausgewählt aus Glycin, Alanin, Leucin, Isoleucin, ß-Alanin, Valin, Cystein, Serin, Tryptophan, Phenylalanin, Methionin, ß-Amino-n-butansäure und γ-Amino-n-butansäure und den Salzen davon, jeweils in der d-Form, der I-Form und der dl-Form; Glycin ist besonders bevorzugt.  Preferred amino acids for the stabilization of the antiperspirant salts are selected from glycine, alanine, leucine, isoleucine, β-alanine, valine, cysteine, serine, tryptophan, phenylalanine, methionine, β-amino-n-butanoic acid and γ-amino-n-butanoic acid and the salts thereof, each in the d-form, the I-form and the dl-form; Glycine is particularly preferred.
Für die Stabilisierung der schweißhemmenden Salze bevorzugte Hydroxyalkansäuren sind ausgewählt aus Glycolsäure und Milchsäure.  Preferred hydroxyalkanoic acids for the stabilization of the antiperspirant salts are selected from glycolic acid and lactic acid.
Weitere bevorzugte schweißhemmende Wirkstoffe sind aktivierte Aluminiumsalze, wie sie beispielsweise in US 6902723 offenbart sind, enthaltend 5 - 78 Gew.-% (USP) eines aktivierten schweißhemmenden Aluminiumsalzes, eine Aminosäure oder Hydroxyalkansäure in einer solchen Menge, um ein (Aminosäure oder Hydroxyalkansäure) zu AI - Gewichtsverhältnis von 2:1 - 1 :20 und bevorzugt 1 :1 bis 1 :10 bereitzustellen, sowie ein wasserlösliches Strontiumsalz in einer solchen Menge, um ein Sr: AI-Gewichtsverhältnis von 1 :1 - 1 :28 und bevorzugt 1 :2 - 1 :25 bereitzustellen.  Other preferred antiperspirant actives are activated aluminum salts, such as disclosed in US 6902723, containing 5-78% by weight (USP) of an activated antiperspirant aluminum salt, an amino acid or hydroxyalkanoic acid in such amount as to add (amino acid or hydroxyalkanoic acid) Al - weight ratio of 2: 1 - 1: 20 and preferably 1: 1 to 1:10, and a water-soluble strontium salt in such an amount to have a Sr: Al weight ratio of 1: 1 - 1:28 and preferably 1: 2 - 1: 25.
Besonders bevorzugte feste schweißhemmende aktivierte Salzzusammensetzungen, beispielsweise gemäß US 6902723, enthalten 48 - 78 Gew.-% (USP), bevorzugt 66 - 75 Gew.-% eines aktivierten Aluminiumsalzes und 1 - 16 Gew.-%, bevorzugt 4 - 13 Gew.-% molekular gebundenes Wasser, weiterhin soviel wasserlösliches Strontiumsalz, dass das Sr:AI-Gewichtsverhältnis 1 :1 - 1 :28, bevorzugt 1 :2 - 1 :25, beträgt und soviel Aminosäure, dass das Aminosäure zu AI - Gewichtsverhältnis 2:1 - 1 :20, bevorzugt 1 :1 - 1 :10, beträgt. Weitere besonders bevorzugte feste schweißhemmende aktivierte Salzzusammensetzungen, beispielsweise gemäß US 6902723, enthalten 48 - 78 Gew.-% (USP), bevorzugt 66 - 75 Gew.-% eines aktivierten Aluminiumsalzes und 1 - 16 Gew.-%, bevorzugt 4 - 13 Gew.-% molekular gebundenes Wasser, weiterhin soviel wasserlösliches Strontiumsalz, dass das Sr:AI-Gewichts- verhältnis 1 :1 - 1 :28, bevorzugt 1 :2 - 1 :25, beträgt und soviel Glycin, dass das Glycin zu AI - Gewichtsverhältnis 2:1 - 1 :20, bevorzugt 1 :1 - 1 :10, beträgt. Particularly preferred solid antiperspirant activated salt compositions, for example according to US 6902723, contain 48-78% by weight (USP), preferably 66-75% by weight of an activated aluminum salt and 1-16% by weight, preferably 4-13% by weight. -% molecularly bound water, further enough so much water-soluble strontium salt that the Sr: Al weight ratio is 1: 1 - 1: 28, preferably 1: 2 - 1: 25, and so much amino acid that the amino acid to AI - weight ratio 2: 1 - 1: 20, preferably 1: 1 - 1: 10, is. Further particularly preferred solid antiperspirant activated salt compositions, for example according to US 6902723, contain 48-78% by weight (USP), preferably 66-75% by weight of an activated aluminum salt and 1-16% by weight, preferably 4-13% by weight .-% molecularly bound water, further so much water-soluble strontium salt that the Sr: Al weight ratio of 1: 1 - 1: 28, preferably 1: 2 - 1: 25, and is so much glycine that the glycine to Al - weight ratio 2: 1-1: 20, preferably 1: 1-1: 10.
Weitere besonders bevorzugte feste schweißhemmende aktivierte Salzzusammensetzungen, beispielsweise gemäß US 6902723, enthalten 48 - 78 Gew.-% (USP), bevorzugt 66 - 75 Gew.-% eines aktivierten Aluminiumsalzes und 1 - 16 Gew.-%, bevorzugt 4 - 13 Gew.-% molekular gebundenes Wasser, weiterhin soviel wasserlösliches Strontiumsalz, dass das Sr:AI-Gewichtsver- hältnis 1 :1 - 1 :28, bevorzugt 1 :2 - 1 :25, beträgt und soviel Hydroxyalkansäure, dass das Hydroxy- alkansäure zu AI - Gewichtsverhältnis 2:1 - 1 :20, bevorzugt 1 :1 - 1 :10, beträgt.  Further particularly preferred solid antiperspirant activated salt compositions, for example according to US 6902723, contain 48-78% by weight (USP), preferably 66-75% by weight of an activated aluminum salt and 1-16% by weight, preferably 4-13% by weight .-% molecularly bound water, further so much water-soluble strontium salt that the Sr: Al weight ratio is 1: 1 - 1: 28, preferably 1: 2 - 1: 25, and as much hydroxyalkanoic that the hydroxyalkanoic acid to AI - Weight ratio 2: 1 - 1: 20, preferably 1: 1 - 1: 10, is.
Weitere bevorzugte aktivierte Aluminiumsalze sind solche der allgemeinen Formel AI2(OH)6.aXa, worin X Cl, Br, I oder N03 ist und "a" ein Wert von 0,3 bis 5, bevorzugt von 0,8 bis 2,5 und besonders bevorzugt 1 bis 2 ist, so dass das Molverhältnis von AI:X 0,9:1 bis 2,1 :1 beträgt, wie sie beispielsweise in US 6074632 offenbart sind. Bei diesen Salzen ist im Allgemeinen etwas Hydratationswasser assoziativ gebunden, typischerweise 1 bis 6 Mol Wasser pro Mol Salz. Besonders bevorzugt ist Aluminiumchlorhydrat (d.h. X ist Cl in der vorgenannten Formel) und speziell 5/6- basisches Aluminiumchlorhydrat, worin "a" 1 beträgt, so dass das Molverhältnis von Aluminium zu Chlor 1 ,9:1 bis 2,1 :1 beträgt. Further preferred activated aluminum salts are those of the general formula Al 2 (OH) 6 . a Xa, wherein X is Cl, Br, I or N0 3 and "a" is a value of 0.3 to 5, preferably from 0.8 to 2.5 and particularly preferably 1 to 2, so that the molar ratio of Al X is 0.9: 1 to 2.1: 1, as disclosed, for example, in US 6074632. These salts generally associate some hydration water, typically 1 to 6 moles of water per mole of salt. Particularly preferred is aluminum chlorohydrate (ie, X is Cl in the aforementioned formula) and especially 5/6 basic aluminum chlorohydrate wherein "a" is 1 such that the molar ratio of aluminum to chlorine is 1.9: 1 to 2.1: 1 ,
Bevorzugte Aluminiumsalze weisen ein molares Metall-zu-Chlorid-Verhältnis von 0,9 - 1 ,3, bevorzugt 0,9 - 1 ,1 , besonders bevorzugt 0,9 - 1 ,0, auf.  Preferred aluminum salts have a molar metal-to-chloride ratio of 0.9-1.3, preferably 0.9-1.1, more preferably 0.9-1.0.
Bei diesen Salzen ist im Allgemeinen etwas Hydratationswasser assoziativ gebunden, typischerweise 1 - 6 Mol Wasser pro Mol Salz, entsprechend 1 - 16 Gew.-%, bevorzugt 4 - 13 Gew.-% Hydratationswasser.  In general, some of the water of hydration is associatively bound to these salts, typically 1-6 moles of water per mole of salt, corresponding to 1-16% by weight, preferably 4-13% by weight of water of hydration.
In einer besonders bevorzugten erfindungsgemäßen Ausführungsform ist als besonders wirksames Antitranspirant-Salz ein so genanntes„aktiviertes" Salz enthalten, insbesondere eines mit einem hohen HPLC-Peak 5-Aluminium-Gehalt, insbesondere mit einer Peak 5-Fläche von mindestens 33 %, besonders bevorzugt mindestens 45 %, bezogen auf die gesamte Fläche unter den Peaks 2 - 5, gemessen mit HPLC einer 10 Gew.-%igen wässrigen Lösung des Wrkstoffs unter Bedingungen, bei denen die Aluminiumspecies in mindestens 4 aufeinander folgende Peaks aufgelöst werden (mit Peaks 2 - 5 bezeichnet).  In a particularly preferred embodiment according to the invention, the particularly effective antiperspirant salt comprises a so-called "activated" salt, in particular one with a high HPLC peak 5-aluminum content, in particular with a peak 5 surface of at least 33%, particularly preferred at least 45%, based on the total area under peaks 2-5, measured by HPLC of a 10% by weight aqueous solution of the active material under conditions in which the aluminum species are resolved into at least 4 consecutive peaks (with peaks 2 - 5). 5).
Die Antitranspirant-Wrkstoffe können als nicht-wässrige Lösungen oder als glycolische Solubili- sate eingesetzt werden.  The antiperspirant active substances can be used as non-aqueous solutions or as glycolic solubilisates.
Die schweißhemmenden Wirkstoffe können sowohl in solubilisierter als auch in gelöster Form vorliegen. Besonders bevorzugte erfindungsgemäße Zusammensetzungen sind dadurch gekennzeichnet, dass der mindestens eine Antitranspirant-Wirkstoff, der ausgewählt ist aus Aluminiumchlor- hydroxiden (= Aluminiumchlorhydraten) und deren Derivaten und Komplexverbindungen, in einer Gesamtmenge von 5 - 40 Gew.-%, bevorzugt 10 - 38 Gew.-% und besonders bevorzugt 13 - 35 Gew.-%, enthalten ist, bezogen auf das Gesamtgewicht der kristallwasserfreien Aktivsubstanz (USP) in der treibmittelfreien Zusammensetzung. The antiperspirant active ingredients can be present both in solubilized and in dissolved form. Particularly preferred compositions according to the invention are characterized in that the at least one antiperspirant active ingredient which is selected from aluminum chlorohydroxides (= aluminum chlorohydrates) and their derivatives and complex compounds, in a total amount of 5-40 wt .-%, preferably 10-38 wt .-% and particularly preferably 13 - 35 wt .-%, based on the total weight of the water-free active substance (USP) in the blowing agent-free composition.
In einer besonders bevorzugten Ausführungsform enthält die Zusammensetzung ein adstringie- rendes Aluminiumsalz, insbesondere Aluminiumchlorohydrat, das beispielsweise pulverförmig als Micro Dry® Ultrafine oder Microdry von Reheis, Microdry 323 von Summit als Chlorhydrol® sowie in aktivierter Form als Reach® 501 von Reheis vertrieben wird. Unter der Bezeichnung Reach® 301 wird ein Aluminiumsesquichlorohydrat von Reheis angeboten, das ebenfalls besonders bevorzugt ist. Besonders bevorzugt sind auch aktivierte Aluminiumchlorohydrate, die unter den Bezeichnungen Reach® 101 und Reach® 103 von Reheis/Summit erhältlich sind. In a particularly preferred embodiment, the composition contains a adstringie- rendes aluminum salt, especially aluminum chlorohydrate, for example, in powder form as Micro Dry ® Ultrafine or Microdry from Reheis, Microdry sold 323 from Summit as Chlorhydrol ® as well as in activated form as Reach ® 501 from Reheis. Under the name Reach® 301 an aluminum sesquichlorohydrate from Reheis is offered, which is likewise particularly preferred. Also particularly preferred are activated aluminum chlorohydrates which are available under the names Reach® 101 and Reach® 103 from Reheis / Summit.
Weitere erfindungsgemäß bevorzugte schweißhemmende Wirkstoffe sind ausgewählt aus Diolen der Struktur (DIOL)
Figure imgf000025_0001
Further inventively preferred antiperspirant active ingredients are selected from diols of the structure (DIOL)
Figure imgf000025_0001
R2  R2
(DIOL)  (DIOL)
wobei der Rest R1 ausgewählt ist aus einem Phenylrest, CH3- und H-, und die Reste R2, R3 und R4 unabhängig voneinander ausgewählt sind aus den Gruppen OH-, -CH2OH, CH3-, C2H5-, H-, mit der Maßgabe, dass zwei OH-Gruppen im Molekül vorhanden sind und dass die Kohlenstoffanzahl aller Reste R2, R3 und R4 maximal 6 ist. Bevorzugte schweißhemmende Diole sind ausgewählt aus 1 ,2-Propylenglycol, 1 ,3-Propylenglycol, 1 ,3- Butylenglycol, 2,4-Pentylenglycol und 2,5 Hexandiol, wobei 1 ,3-Propylenglycol besonders bevorzugt ist. Besonders bevorzugte erfindungsgemäße Zusammensetzungen enthalten mindestens ein vorstehend beschriebenes Diol der Struktur (DIOL) in einer Gesamtmenge von 8 - 48 Gew.-%, bevorzugt 12 - 25 Gew.-%, besonders bevorzugt 14 bis 20 Gew.-%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien Zusammensetzung wherein the radical R 1 is selected from a phenyl radical, CH 3 - and H-, and the radicals R 2 , R 3 and R 4 are independently selected from the groups OH, -CH 2 OH, CH 3 -, C 2 H 5 -, H, with the proviso that two OH groups are present in the molecule and that the carbon number of all radicals R2, R3 and R4 is at most 6. Preferred antiperspirant diols are selected from 1,2-propylene glycol, 1,3-propylene glycol, 1,3-butylene glycol, 2,4-pentylene glycol and 2,5-hexanediol, with 1,3-propylene glycol being particularly preferred. Particularly preferred compositions according to the invention contain at least one diol of the structure (DIOL) described above in a total amount of 8-48% by weight, preferably 12-25% by weight, particularly preferably 14-20% by weight, based in each case on the Total weight of the blowing agent-free composition
Erfindungsgemäße Deodorant-Zusammensetzungen enthalten mindestens einen Deodorant- Wrkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, bezogen auf das Gesamtgewicht der treibmittelfreien Zusammensetzung.  Deodorant compositions according to the invention comprise at least one deodorant active substance in a total amount of 0.1-50% by weight, based on the total weight of the blowing agent-free composition.
Erfindungsgemäß bevorzugte Deodorant-Wirkstoffe sind keimhemmende Mittel, Geruchsabsorber, desodorierend wirkende Ionenaustauscher, präbiotisch wirksame Komponenten sowie Enzyminhibitoren oder, besonders bevorzugt, Kombinationen der genannten Wrkstoffe. Silicate dienen als Geruchsabsorber, die auch gleichzeitig die rheologischen Eigenschaften der erfindungsgemäßen Zusammensetzung vorteilhaft unterstützen können. Zu den erfindungsgemäß besonders bevorzugten Silicaten zählen vor allem Schichtsilicate und unter diesen insbesondere Montmorillonit, Kaolinit, Mit, Beidellit, Nontronit, Saponit, Hectorit, Bentonit, Smectit und Talkum. Weitere bevorzugte Geruchsabsorber sind beispielsweise Zeolithe, Zinkricinoleat, Cyclodextrine, bestimmte Metalloxide, wie z. B. Aluminiumoxid, sowie Chlorophyll. Weitere erfindungsgemäß bevorzugte Geruchsabsorber sind ausgewählt aus Perlit (vulkanisches Glas) und Blähperlit. Geruchsabsorber werden bevorzugt in einer Gesamtmenge von 0,1 - 10 Gew.-%, besonders bevorzugt 0,5 - 7 Gew.-% und außerordentlich bevorzugt 1 - 5 Gew.-%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien Zusammensetzung, eingesetzt. Deodorant agents which are preferred according to the invention are germ-inhibiting agents, odor absorbers, deodorizing ion exchangers, prebiotically active components and also enzyme inhibitors or, particularly preferred, combinations of the mentioned active substances. Silicates serve as odor absorbers, which can also advantageously simultaneously support the rheological properties of the composition according to the invention. Among the silicates particularly preferred according to the invention are, in particular, phyllosilicates and, among these, in particular montmorillonite, kaolinite, mit, beidellite, nontronite, saponite, hectorite, bentonite, smectite and talcum. Other preferred odor absorbers are, for example, zeolites, Zinkricinoleat, cyclodextrins, certain metal oxides, such as. As alumina, and chlorophyll. Further inventively preferred odor absorbers are selected from perlite (volcanic glass) and expanded perlite. Odor absorbers are preferably used in a total amount of 0.1-10% by weight, more preferably 0.5-7% by weight and most preferably 1-5% by weight, based in each case on the total weight of the blowing agent-free composition.
Unter keimhemmenden oder antimikrobiellen Wrkstoffen werden erfindungsgemäß solche Wrkstoffe verstanden, die die Zahl der an der Geruchsbildung beteiligten Hautkeime reduzieren bzw. deren Wachstum hemmen. Zu diesen Keimen zählen unter anderem verschiedene Spezies aus der Gruppe der Staphylokokken, der Gruppe der Corynebakterien, Anaerokokken und Mikrokokken.  According to the invention, germ-inhibiting or antimicrobial active substances are understood to mean those active substances which reduce the number of skin germs participating in the formation of the odor or inhibit their growth. These organisms include, among others, various species from the group of staphylococci, the group of Corynebacteria, anaerococci and micrococci.
Als keimhemmende oder antimikrobielle Wrkstoffe erfindungsgemäß bevorzugt sind insbesondere Organohalogenverbindungen sowie -halogenide, quartäre Ammoniumverbindungen, eine Reihe von Pflanzenextrakten und Zinkverbindungen. Hierzu zählen u. a. Triclosan, Chlorhexidin und Chlorhexidingluconat, 3,4,4'-Trichlorcarbanilid, Bromchlorophen, Dichlorophen, Chlorothymol, Chloroxylenol, Hexachlorophen, Dichloro-m-xylenol, Dequaliniumchlorid, Domiphenbromid, Ammoniumphenolsulfonat, Benzalkoniumhalogenide, Benzalkoniumcetylphosphat, Benzalko- niumsaccharinate, Benzethoniumchlorid, Cetylpyridiniumchlorid, Laurylpyridiniumchlorid, Lauryl- isoquinoliniumbromid, Methylbenzethoniumchlorid. Weiterhin sind Phenol, Phenoxyethanol, Di- natriumdihydroxyethylsulfosuccinylundecylenat, Natriumbicarbonat, Zinklactat, Natriumphenol- sulfonat und Zinkphenolsulfonat, Ketoglutarsäure, Terpenalkohole wie z. B. Farnesol, Chlorophyllin-Kupfer-Komplexe, alpha-Monoalkylglycerinether mit einem verzweigten oder linearen gesättigten oder ungesättigten, gegebenenfalls hydroxylierten C6 - C22-Alkylrest, besonders bevorzugt alpha-(2-Ethylhexyl)glycerinether, im Handel erhältlich als Sensiva® SC 50 (ex Schülke & Mayr), Carbonsäureester des Mono-, Di- und Triglycerins (z. B. Glycerinmonolaurat, Diglycerinmono- caprinat), Lantibiotika sowie Pflanzenextrakte (z. B. grüner Tee und Bestandteile des Lindenblütenöls) einsetzbar. Preferred germinal or antimicrobial active substances according to the invention are in particular organohalogen compounds and halides, quaternary ammonium compounds, a series of plant extracts and zinc compounds. These include triclosan, chlorhexidine and chlorhexidine gluconate, 3,4,4'-trichlorocarbanilide, bromochlorophene, dichlorophen, chlorothymol, chloroxylenol, hexachlorophene, dichloro-m-xylenol, dequalinium chloride, domiphenbromide, ammonium phenolsulfonate, benzalkonium halides, benzalkonium cetyl phosphate, benzalkonium saccharinates, benzethonium chloride, Cetylpyridinium chloride, laurylpyridinium chloride, laurylisoquinolinium bromide, methylbenzethonium chloride. Furthermore, phenol, phenoxyethanol, di-sodium dihydroxyethylsulfosuccinyl undecylenate, sodium bicarbonate, zinc lactate, sodium phenol sulfonate and zinc phenolsulfonate, ketoglutaric acid, terpene alcohols such as. As farnesol, chlorophyllin copper complexes, alpha monoalkyl glycerol ether with a branched or linear saturated or unsaturated, optionally hydroxylated C 6 - C 22 alkyl, particularly preferably alpha- (2-ethylhexyl) glycerol, commercially available as Sensiva ® SC 50 (ex Schülke & Mayr), carboxylic acid esters of mono-, di- and triglycerol (eg glycerol monolaurate, diglycerol mono- caprinate), lantibiotics and plant extracts (eg green tea and components of lime blossom oil).
Weitere bevorzugte Deodorant-Wrkstoffe sind ausgewählt aus sogenannten präbiotisch wirksamen Komponenten, worunter erfindungsgemäß solche Komponenten zu verstehen sind, die nur oder zumindest überwiegend die geruchsbildenden Keime der Hautmikroflora hemmen, nicht aber die erwünschten, das heißt, die nicht-geruchsbildenden Keime, die zu einer gesunden Hautmikroflora gehören. Explizit sind hier die Wrkstoffe, die in DE 10333245 und DE 10 2004 01 1 968 als präbiotisch wirksam offenbart sind, mit einbezogen; dazu gehören Nadelbaumextrakte, insbesondere aus der Gruppe der Pinaceae, und Pflanzenextrakte aus der Gruppe der Sapindaceae, Araliaceae, Lamiaceae und Saxifragaceae, insbesondere Extrakte aus Picea spp., Paullinia sp., Panax sp., Lamium album oder Ribes nigrum sowie Mischungen dieser Substanzen. Further preferred deodorant active substances are selected from so-called prebiotically active components, which according to the invention are to be understood as meaning those components which inhibit only or at least predominantly the odor-causing germs of the skin microflora, but not the desired ones, that is, the non-odor-forming germs forming a include healthy skin microflora. Explicit here are the active ingredients, which in DE 10333245 and DE 10 2004 01 1 968 as prebiotically effective, are included; these include conifer extracts, in particular from the group of Pinaceae, and plant extracts from the group of Sapindaceae, Araliaceae, Lamiaceae and Saxifragaceae, in particular extracts from Picea spp., Paullinia sp., Panax sp., Lamium album or Ribes nigrum and mixtures of these substances.
Weitere bevorzugte Deodorant-Wirkstoffe sind ausgewählt aus den keimhemmend wirkenden Parfümölen und den Deosafe®-Parfümölen, die von der Firma Symrise, vormals Haarmann und Reimer, erhältlich sind. Further preferred deodorant active ingredients are selected from the germ-inhibiting active perfume oils and Deosafe ® -Parfümölen that, Haarmann and Reimer, by the company Symrise previously available.
Weitere bevorzugte Deodorant-Wirkstoffe sind ausgewählt aus Silbersalzen, insbesondere Silber- citrat, Dihydrogensilbercitrat, Silberlactat und Silbersulfat, löslichen Komplexsalzen des Silbers, auf einen Trägerstoff aufgebrachten Silberhalogeniden, insbesondere Titandioxid-geträgertem Silberchlorid, kolloidalem Silber und Silberzeolithen. Bevorzugte erfindungsgemäße Deodorantoder Antitranspirant-Zusammensetzungen sind dadurch gekennzeichnet, dass Silberionen (Ag+) in einer Gesamtmenge von 1 - 100 ppm, bevorzugt 2 - 50 ppm, besonders bevorzugt 5 - 20 ppm, außerordentlich bevorzugt 7 - 10 ppm, jeweils bezogen auf das Gewicht der treibmittelfreien erfindungsgemäßen Zusammensetzung, enthalten sind. Further preferred deodorant active ingredients are selected from silver salts, in particular silver citrate, dihydrogen silver citrate, silver lactate and silver sulfate, soluble complex salts of silver, supported silver halides, in particular titanium dioxide-supported silver chloride, colloidal silver and silver zeolites. Preferred deodorant or antiperspirant compositions according to the invention are characterized in that silver ions (Ag + ) in a total amount of 1-100 ppm, preferably 2-50 ppm, more preferably 5-20 ppm, most preferably 7-10 ppm, in each case by weight the propellant-free composition according to the invention are included.
Zu den Enzyminhibitoren gehören Stoffe, die die für die Schweißzersetzung verantwortlichen Enzyme, insbesondere die Arylsulfatase, beta-Glucuronidase, Aminoacylase, Esterasen, Lipasen und/oder Lipoxigenase, hemmen, z. B. Trialkylcitronensäureester, insbesondere Triethylcitrat, oder Zinkglycinat.  The enzyme inhibitors include substances which inhibit the enzymes responsible for the sweat decomposition, in particular arylsulfatase, beta-glucuronidase, aminoacylase, esterases, lipases and / or lipoxigenase, e.g. B. trialkylcitric acid, in particular triethyl citrate, or zinc glycinate.
Bevorzugte erfindungsgemäße Deodorant- oder Antitranspirant-Zusammensetzungen enthalten mindestens einen Deodorant-Wrkstoff, der ausgewählt ist aus Arylsulfatase-Inhibitoren, beta- Glucuronidase-Inhibitoren, Aminoacylase-Inhibitoren, Esterase-Inhibitoren, Lipase-Inhibitoren und Lipoxigenase-Inhibitoren, alpha-Monoalkylglycerinethern mit einem verzweigten oder linearen gesättigten oder ungesättigten, gegebenenfalls hydroxylierten C6 - C22-Alkylrest, insbesondere alpha-(2-Ethylhexyl)glycerinether, Phenoxyethanol, keimhemmend wirkenden Parfümölen, Deosafe®-Parfümölen (Deosafe® ist ein eingetragenes Warenzeichen der Firma Symrise, vormals Haarmann & Reimer), präbiotisch wirksamen Komponenten, Silbersalzen, Trialkylcitronensäure- estern, insbesondere Triethylcitrat, Wirkstoffen, die die Zahl der an der Geruchsbildung beteiligten Hautkeime aus der Gruppe der Staphylokokken, Corynebakterien, Anaerokokken und Mikro- kokken reduzieren bzw. deren Wachstum hemmen, Zinkverbindungen, insbesondere Zinkphenol- sulfonat und Zinkricinoleat, Tropolon, Organohalogenverbindungen, insbesondere Triclosan, Chlorhexidin, Chlorhexidingluconat und Benzalkoniumhalogeniden, quartären Ammoniumverbindungen, insbesondere Cetylpyridiniumchlorid, Geruchsabsorbern, insbesondere Silikaten und Zeolithen, Natriumbicarbonat, Lantibiotika, sowie Mischungen der vorgenannten Substanzen. Weitere bevorzugte Deodorant-Wirkstoffe sind ausgewählt aus mindestens einem Doppelsalz vom Alaun-Typ mit der allgemeinen Formel MIMI"(S04)2■ x H2Q enthalten, wobei M1 ein einwertiges Kation, ausgewählt aus Kalium-, Natrium-, Rubidium-, Cäsium- und Ammonium- Ionen, M1" ein dreiwertiges Kation, ausgewählt aus Aluminium-, Gallium-, Indium-, Scandium- Titan- und Vanadium-Ionen, und x eine rationale Zahl im Bereich von 0 bis 12, einschließlich 0 darstellen. Preferred deodorant or antiperspirant compositions according to the invention comprise at least one deodorant active ingredient selected from arylsulfatase inhibitors, beta-glucuronidase inhibitors, aminoacylase inhibitors, esterase inhibitors, lipase inhibitors and lipoxygenase inhibitors, alpha-monoalkylglycerol ethers having a branched or linear, saturated or unsaturated, optionally hydroxylated C 6 - C 22 alkyl radical, in particular alpha- (2-ethylhexyl) glycerol ether, phenoxyethanol, germ-inhibiting active perfume oils, Deosafe ® -Parfümölen (Deosafe ® is a registered trademark of the company Symrise, formerly Haarmann & Reimer), prebiotic components, silver salts, trialkyl citric acid esters, in particular triethyl citrate, active ingredients which reduce or inhibit the growth of the number of skin germs from the group of staphylococci, corynebacteria, anaerococci and micrococci which participate in the formation of odor conditions, in particular zinc phenol sulphonate and zinc ricinoleate, tropolone, organohalogen compounds, in particular triclosan, chlorhexidine, chlorhexidine gluconate and benzalkonium halides, quaternary ammonium compounds, in particular cetylpyridinium chloride, odor absorbers, in particular silicates and zeolites, sodium bicarbonate, lantibiotics, and mixtures of the abovementioned substances. Further preferred deodorant active ingredients are selected from at least one double salt of the alum type having the general formula M I M I "(S0 4) 2 x H 2 ■ Q included, where M 1 is a monovalent cation selected from potassium, sodium, rubidium, cesium and ammonium ions, M 1 "is a trivalent cation selected from aluminum, gallium, indium, scandium, titanium and vanadium ions, and x represent a rational number ranging from 0 to 12, including 0.
Besonders bevorzugt sind die Doppelsalze mit M1" = Aluminiumion, insbesondere KAI(S04)2 KAI(S04)2 ■ 1 H20, KAI(S04)2 ■ 2 H20, KAI(S04)2 ■ 3 H20, KAI(S04)2 ■ 4 H20, KAI(S04)2 ■ 5 HzO KAI(S04)2 ■ 6 H20, KAI(S04)2 ■ 7 H20, KAI(S04)2 ■ 8 H20, KAI(S04)2 ■ 9 H20, KAI(S04)2 ■ 10 HzO KAI(S04)2 ■ 11 H20 und KAI(S04)2 ■ 12 H20, NH4AI(S04)2, NH4AI(S04)2-1 HzOParticularly preferred are the double salts with M 1 "= aluminum ion, in particular KAI (S0 4 ) 2 KAI (S0 4 ) 2 ■ 1 H 2 0, KAI (S0 4 ) 2 ■ 2 H 2 0, KAI (S0 4 ) 2 ■ 3 H 2 0, KAI (S0 4 ) 2 ■ 4 H 2 0, KAI (S0 4 ) 2 ■ 5 H z O KAI (S0 4 ) 2 ■ 6 H 2 0, KAI (S0 4 ) 2 ■ 7 H 2 0, KAI (S0 4 ) 2 ■ 8 H 2 0, KAI (S0 4 ) 2 ■ 9 H 2 0, KAI (S0 4 ) 2 ■ 10 H z O KAI (S0 4 ) 2 ■ 11 H 2 0 and KAI (S0 4 ) 2 ■ 12 H 2 O, NH 4 Al (S0 4 ) 2 , NH 4 Al (S0 4 ) 2 -1 H z O
NH4AI(S04)2-2 H20, NH4AI(S04)2-3 H20, NH4AI(S04)2-4 H2Q, NH4AI(S04)2-5 H20 NH4AI(S04)2-6 H20, NH4AI(S04)2-7 H20, NH4AI(S04)2 ■ 8 H20, NH4AI(S04)2 ■ 9 H20 NH4AI(S04)2 ■ 10 H20, NH4AI(S04)2 ■ 1 1 H20 und NH4AI(S04)2 12 H20, RbAI(S04)2 RbAI(S04)2 ■ 1 H20, RbAI(S04)2 ■ 2 H20, RbAI(S04)2 ■ 3 H20, RbAI(S04)2 ■ 4 H20 RbAI(S04)2 5 H20, RRbbAAII((SSQ044))22 ■■ 66 HH2200,, RRbbAAII((SSQ044))22 ■■ 77 HH2200,, RbAI(S04)2 ■ 8 HzO RbAI(S04)2 9 H20, RbAI(S04)2 ■ 10 H20, RbAI(S04)2 ■ 11 HzO und RbAI(S04)2 ■ 12 HzO NaAI(S04)2, NaAI(S04)2 ■ 1 H20, NaAI(S04)2 ■ 2 H20, NaAI(S04)2 ■ 3 H20, NaAI(S04)2 ■ 4 HzO NaAI(S04)2 5 H20, NaAI(S04)2 ■ 6 H20, NaAI(S04)2 ■ 7 H20, NaAI(S04)2 ■ 8 HzO NaAI(SQ4)2 9 H20, NaAI(S04)2 ■ 10 H20, NaAI(S04)2 ■ 11 HzO und NaAI(S04)2 ■ 12 HzO KSc(S04)2, KSc(S04)2 ■ 1 H20, KSc(S04)2 ■ 2 H20, KSc(S04)2 ■ 3 H20, KSc(S04)2 ■ 4 HzO KSc(S04)2 ■ 5 H20, KSc(S04)2 ■ 6 H20, KSc(S04)2 ■ 7 H20, KSc(S04)2 ■ 8 HzONH 4 Al (SO 4 ) 2 -2 H 2 O, NH 4 Al (SO 4 ) 2 -3 H 2 O, NH 4 Al (SO 4 ) 2 -4 H 2 Q, NH 4 Al (SO 4 ) 2 -5 H 2 O NH 4 Al (SO 4 ) 2 -6 H 2 O, NH 4 Al (SO 4 ) 2 -7 H 2 O, NH 4 Al (SO 4 ) 2 ■ 8 H 2 O, NH 4 Al (S0 4 ) 2 ■ 9 H 2 0 NH 4 Al (SO 4 ) 2 ■ 10 H 2 0, NH 4 Al (SO 4 ) 2 ■ 1 1 H 2 0 and NH 4 Al (SO 4 ) 2 12 H 2 0, RbAI (S0 4 ) 2 RbAI (S0 4 ) 2 ■ 1 H 2 0, RbAI (S0 4 ) 2 ■ 2 H 2 0, RbAI (S0 4 ) 2 ■ 3 H 2 0, RbAI (S0 4 ) 2 ■ 4 H 2 0 RbAI (S0 4 ) 2 5 H 2 0, RRbbAAII ((SSQ0 44 )) 22 ■■ 66 HH 22 00 ,, RRbbAAII ((SSQ0 44 )) 22 ■■ 77 HH 22 00 ,, RbAI ( S0 4 ) 2 ■ 8 H z O RbAI (S0 4 ) 2 9 H 2 0, RbAI (S0 4 ) 2 ■ 10 H 2 0, RbAI (S0 4 ) 2 ■ 11 H z O and RbAI (S0 4 ) 2 ■ 12 H z O NaAl (SO 4 ) 2 , NaAl (SO 4 ) 2 ■ 1 H 2 O, NaAl (SO 4 ) 2 ■ 2 H 2 O, NaAl (SO 4 ) 2 ■ 3 H 2 O, NaAl ( S0 4 ) 2 ■ 4 H z O NaAl (S0 4 ) 2 5 H 2 0, NaAl (S0 4 ) 2 ■ 6 H 2 0, NaAl (S0 4 ) 2 ■ 7 H 2 0, NaAl (S0 4 ) 2 ■ 8 H z O NaAl (SQ 4 ) 2 9 H 2 0, NaAl (S0 4 ) 2 ■ 10 H 2 0, NaAl (S0 4 ) 2 ■ 11 H z O and NaAl (S0 4 ) 2 ■ 12 H z O KSc (S0 4 ) 2 , KSc (S0 4 ) 2 ■ 1 H 2 0, KSc (S0 4 ) 2 ■ 2 H 2 0, KSc (S0 4 ) 2 ■ 3 H 2 0, KSc (S0 4 ) 2 ■ 4 H z O KSc (S0 4 ) 2 ■ 5 H 2 0, KSc (S0 4 ) 2 ■ 6 H 2 0, KSc (S0 4 ) 2 ■ 7 H 2 0, KSc (S0 4 ) 2 ■ 8 H z O
KSc(S04)2 ■ 9 H20, KSc(S04)2 ■ 10 H20, KSc(S04)2 ■ 1 1 HzO und KSc(S04)2 ■ 12 HzO NH4Sc(S04)2, NH4Sc(S04)2 ■ 1 H20, NH4Sc(S04)2 ■ 2 H20, NH4Sc(S04)2 ■ 3 HzO NH4Sc(S04)2 ■ 4 H20, NH4Sc(S04)2 ■ 5 H20, NH4Sc(S04)2 ■ 6 H20, NH4Sc(S04)2 ■ 7 HzO NH4Sc(S04)2 ■ 8 H20, NH4Sc(S04)2 ■ 9 H20, NH4Sc(S04)2 ■ 10 H20, NH4Sc(S04)2 ■ 11 HzO und NH4Sc(S04)2 ■ 12 H20, RbSc(S04)2, RbSc(S04)2 ■ 1 H20, RbSc(S04)2 ■ 2 HzOKSc (S0 4 ) 2 ■ 9 H 2 0, KSc (S0 4 ) 2 ■ 10 H 2 0, KSc (S0 4 ) 2 ■ 1 1 H z O and KSc (S0 4 ) 2 ■ 12 H z O NH 4 Sc (S0 4) 2, NH 4 Sc (S0 4) 2 ■ 1 H 2 0, NH 4 Sc (S0 4) 2 ■ 2H 2 0, NH 4 Sc (S0 4) 2 ■ 3 H z O NH 4 Sc (S0 4 ) 2 ■ 4 H 2 O, NH 4 Sc (SO 4 ) 2 ■ 5 H 2 O, NH 4 Sc (SO 4 ) 2 ■ 6 H 2 O, NH 4 Sc (SO 4 ) 2 ■ 7 H z O NH 4 Sc (SO 4 ) 2 ■ 8 H 2 O, NH 4 Sc (SO 4 ) 2 ■ 9 H 2 O, NH 4 Sc (SO 4 ) 2 ■ 10 H 2 0, NH 4 Sc (S0 4 ) 2 ■ 11 H z O and NH 4 Sc (S0 4 ) 2 ■ 12 H 2 0, RbSc (S0 4 ) 2 , RbSc (S0 4 ) 2 ■ 1 H 2 0, RbSc (S0 4 ) 2 ■ 2 H z o
RbSc(S04)2 ■ 3 H20, RbSc(S04)2 ■ 4 H20, RbSc(S04)2 ■ 5 H20, RbSc(S04)2 ■ 6 HzORbSc (S0 4 ) 2 ■ 3 H 2 0, RbSc (S0 4 ) 2 ■ 4 H 2 0, RbSc (S0 4 ) 2 ■ 5 H 2 0, RbSc (S0 4 ) 2 ■ 6 H z O
RbSc(S04)2 7 H20, RbSc(S04)2 ■ 8 H20, RbSc(S04)2 ■ 9 H20, RbSc(S04)2 ■ 10 H20 RbSc(S04)2 11 H20 und RbSc(S04)2 12 H20, NaSc(S04)2 NaSc(S04)2 ■ 1 H20 NaSc(S04)2 2 H20, NaSc(S04)2 ■ 3 H20, NaSc(SQ4)2 ■ 4 H20, NaSc(S04)2 ■ 5 H20 NaSc(S04)2 6 H20, NaSc(S04)2 ■ 7 H20, NaSc(S04)2 ■ 8 H20, NaSc(S04)2 ■ 9 H20 NaSc(S04)2 10 H20, NaSc(S04)2 ■ 1 1 H20 und NaSc(S04)2 12 H20, KGa(S04)2 KGa(S04)2 ■ 1 H20 KGa(S04)2 ■ 2 H20, KGa(S04)2 ■ 3 H20, KGa(S04)2 ■ 4 H20 KGa(S04)2 ■ 5 H20 KGa(SQ4)2 ■ 6 H20, KGa(S04)2 ■ 7 H20, KGa(S04)2 ■ 8 H20 KGa(S04)2 ■ 9 H20, KGa(S04)2 ■ 10 H20, KGa(S04)2 ■ 1 1 H20 und KGa(S04)2 ■ 12 H20 NH4Ga(SQ4)2, NH4Ga(SQ4)2 ■ 1 H2Q, NH4Ga(SQ4)2 ■ 2 H2Q, NH4Ga(S04)2 ■ 3 HzORbSc (S0 4 ) 2 7 H 2 0, RbSc (S0 4 ) 2 ■ 8 H 2 0, RbSc (S0 4 ) 2 ■ 9 H 2 0, RbSc (S0 4 ) 2 ■ 10 H 2 0 RbSc (S0 4 ) 2 11 H 2 0 and RbSc (S0 4 ) 2 12 H 2 0, NaSc (S0 4 ) 2 NaSc (S0 4 ) 2 ■ 1 H 2 0 NaSc (S0 4 ) 2 2 H 2 0, NaSc (S0 4 ) 2 ■ 3 H 2 0, NaSc (SQ 4 ) 2 ■ 4 H 2 0, NaSc (S0 4 ) 2 ■ 5 H 2 0 NaSc (S0 4 ) 2 6 H 2 0, NaSc (S0 4 ) 2 ■ 7 H 2 0, nasc (S0 4) 2 ■ 8 H 2 0, nasc (S0 4) 2 ■ 9 H 2 0 nasc (S0 4) 2 10H 2 0, nasc (S0 4) 2 ■ 1 1 H 2 0 and NaSc (S0 4 ) 2 12 H 2 O, KGa (S0 4 ) 2 KGa (S0 4 ) 2 ■ 1 H 2 0 KGa (S0 4 ) 2 ■ 2 H 2 0, KGa (S0 4 ) 2 ■ 3 H 2 0, KGa (S0 4 ) 2 ■ 4 H 2 0 KGa (S0 4 ) 2 ■ 5 H 2 0 KGa (SQ 4 ) 2 ■ 6 H 2 0, KGa (S0 4 ) 2 ■ 7 H 2 0, KGa (S0 4 ) 2 ■ 8 H 2 0 KGa (S0 4 ) 2 ■ 9 H 2 0, KGa (S0 4 ) 2 ■ 10 H 2 0, KGa (S0 4 ) 2 ■ 1 1 H 2 0 and KGa (S0 4 ) 2 ■ 12 H 2 0 NH 4 Ga (SQ 4 ) 2 , NH 4 Ga (SQ 4 ) 2 ■ 1 H 2 Q, NH 4 Ga (SQ 4 ) 2 ■ 2 H 2 Q, NH 4 Ga (S0 4 ) 2 ■ 3 H z O
NH4Ga(SQ4)2 ■ 4 H2Q, NH4Ga(SQ4)2 ■ 5 H2Q, NH4Ga(SQ4)2 ■ 6 H2Q, NH4Ga(SQ4)2 ■ 7 H2QNH 4 Ga (SQ 4 ) 2 ■ 4 H 2 Q, NH 4 Ga (SQ 4 ) 2 ■ 5 H 2 Q, NH 4 Ga (SQ 4 ) 2 ■ 6 H 2 Q, NH 4 Ga (SQ 4 ) 2 ■ 7 H 2 Q
NH4Ga(SQ4)2 ■ 8 H2Q, NH4Ga(SQ4)2 ■ 9 H2Q, NH4Ga(SQ4)2 ■ 10 H2Q, NH4Ga(SQ4)2 ■ 11 H2Q und NH4Ga(S04)2 ■ 12 H20, RbGa(S04)2, RbGa(S04)2 ■ 1 H20, RbGa(S04)2 ■ 2 H20, RbGa(S04)2 ■ 3 H20, RbGa(S04)2 ■ 4 H20, RbGa(S04)2 ■ 5 H20, RbGa(S04)2 ■ 6 H20, RbGa(S04)2 7 H20, RbGa(S04)2 ■ 8 H20, RbGa(S04)2 ■ 9 H20, RbGa(S04)2 ■ 10 H20, RbGa(S04)2 11 H20 und RbGa(S04)2 · 12 H20, NaGa(S04)2, NaGa(S04)2 ■ 1 H20, NaGa(S04)2 2 H20, NaGa(S04)2 ■ 3 H20, NaGa(S04)2 ■ 4 H20, NaGa(S04)2 ■ 5 H20, NaGa(S04)2 6 H20, NaGa(S04)2 ■ 7 HzO, NaGa(S04)2 ■ 8 HzO, NaGa(S04)2 ■ 9 H20, NaGa(S04)2 10 H20, NaGa(S04)2 ■ 11 H20 und NaGa(S04)2 12 H20, KTi(SQ4)2, KTi(S04)2 ■ 1 H20, KTi(S04)2 ■ 2 H20, KTi(S04)2 ■ 3 H20, KTi(S04)2 ■ 4 H20, KTi(S04)2 ■ 5 H20, KTi(S04)2 ■ 6 H20, KTi(S04)2 ■ 7 H20, KTi(S04)2 ■ 8 H20, KTi(S04)2 ■ 9 H20, KTi(S04)2 ■ 10 H20, KTi(S04)2 ■ 1 1 H20 und KTi(S04)2 ■ 12 H20, NH4Ti(S04)2, NH4Ti(S04)2 ■ 1 H20, NH4Ti(S04)2-2 H20, NH4Ti(S04)2 ■ 3 H20, NH4Ti(S04)2 ■ 4 H20, NH4Ti(S04)2 ■ 5 H20, NH4Ti(SQ4)2 ■ 6 H20, NH4Ti(SQ4)2 ■ 7 H20, NNHH44TTii((SSQ044))22 ■■ 88 HH2200,, NH4Ti(SQ4)2 ■ 9 H20,NH 4 Ga (SQ 4 ) 2 ■ 8 H 2 Q, NH 4 Ga (SQ 4 ) 2 ■ 9 H 2 Q, NH 4 Ga (SQ 4 ) 2 ■ 10 H 2 Q, NH 4 Ga (SQ 4 ) 2 ■ 11 H 2 Q and NH 4 Ga (S0 4 ) 2 ■ 12 H 2 O, RbGa (S0 4 ) 2 , RbGa (S0 4 ) 2 ■ 1 H 2 0, RbGa (S0 4 ) 2 ■ 2 H 2 0, RbGa (S0 4 ) 2 ■ 3 H 2 0, RbGa (S0 4 ) 2 ■ 4 H 2 0, RbGa (S0 4 ) 2 ■ 5 H 2 0, RbGa (S0 4 ) 2 ■ 6 H 2 0, RbGa (S0 4 ) 2 7 H 2 0, RbGa (S0 4 ) 2 ■ 8 H 2 0, RbGa (S0 4 ) 2 ■ 9 H 2 0, RbGa (S0 4 ) 2 ■ 10 H 2 0, RbGa (S0 4 ) 2 11 H 2 0 and RBGA (S0 4) 2 · 12 H 2 0, NaGa (S0 4) 2, NaGa (S0 4) 2 ■ 1 H 2 0, NaGa (S0 4) 2 2 H 2 0, NaGa (S0 4) 2 ■ 3 H 2 O, NaGa (SO 4 ) 2 ■ 4 H 2 O, NaGa (SO 4 ) 2 ■ 5 H 2 O, NaGa (SO 4 ) 2 6 H 2 O, NaGa (SO 4 ) 2 ■ 7 H z O, NaGa (S0 4) 2 ■ 8 H z O, NaGa (S0 4) 2 ■ 9 H 2 0, NaGa (S0 4) 2 10H 2 0, NaGa (S0 4) 2 ■ 11 H 2 0 and NaGa (S0 4 ) 2 12 H 2 0, KTi (SQ 4 ) 2 , KTi (S0 4 ) 2 ■ 1 H 2 0, KTi (S0 4 ) 2 ■ 2 H 2 0, KTi (S0 4 ) 2 ■ 3 H 2 0, KTi (S0 4 ) 2 ■ 4 H 2 0, KTi (S0 4 ) 2 ■ 5 H 2 0, KTi (S0 4 ) 2 ■ 6 H 2 0, KTi (S0 4 ) 2 ■ 7 H 2 0 , KTi (S0 4 ) 2 ■ 8 H 2 0, KTi (S0 4 ) 2 ■ 9 H 2 0, KTi (S0 4 ) 2 ■ 10 H 2 0, KTi (S0 4 ) 2 ■ 1 1 H 2 0 and KTi (S0 4 ) 2 ■ 12 H 2 O, NH 4 Ti (SO 4 ) 2 , NH 4 Ti (SO 4 ) 2 ■ 1 H 2 O, NH 4 Ti (SO 4 ) 2 -2 H 2 O, NH 4 Ti (S0 4) 2 ■ 3 H 2 0, NH 4 Ti (S0 4) 2 ■ 4 H 2 0, NH 4 Ti (S0 4) 2 ■ 5 H 2 0, NH 4 Ti (SQ 4) 2 ■ 6 H 2 0, NH 4 Ti (SQ 4 ) 2 ■ 7 H 2 0, NNHH 44 TTii ((SSQ0 44 )) 22 ■■ 88 HH 22 00 ,, NH 4 Ti (SQ 4 ) 2 ■ 9 H 2 0
NH4Ti(S04)2 ■ 10 H20, NH4Ti(S04)2 ■ 1 1 H20 und NH4Ti(S04)2 12 H20, RbTi(S04)2, RbTi(S04)2 ■ 1 H20, RbTi(S04)2 ■ 2 H20, RbTi(S04)2 ■ 3 H20, RbTi(S04)2 ■ 4 H20, RbTi(S04)2 5 H20, RRbbTTii((SSQ044))22 ■■ 66 HH2200,, RRbbTTii((SSQ044))22 ■■ 77 HH2200,, RbTi(S04)2 ■ 8 H20, RbTi(S04)2 9 H20, RbTi(S04)2 ■ 10 H20, RbTi(S04)2 ■ 1 1 H20 und RbTi(S04)2 ■ 12 H20, NaTi(S04)2, NaTi(S04)2 ■ 1 H20, NaTi(S04)2 ■ 2 H20, NaTi(S04)2 ■ 3 H20, NaTi(S04)2 ■ 4 H20, NaTi(S04)2 5 H20, NaTi(S04)2 ■ 6 H20, NaTi(S04)2 ■ 7 H20, NaTi(S04)2 ■ 8 H20, NaTi(SQ4)2 9 H20, NaTi(S04)2 ■ 10 H20, NaTi(S04)2 ■ 1 1 H20 und NaTi(S04)2 ■ 12 H20. NH 4 Ti (S0 4) 2 ■ 10 H 2 0, NH 4 Ti (S0 4) 2 ■ 1 1 H 2 0 and NH 4 Ti (S0 4) 2 12H 2 0, RBTI (S0 4) 2, RBTI (S0 4 ) 2 ■ 1 H 2 0, RbTi (S0 4 ) 2 ■ 2 H 2 0, RbTi (S0 4 ) 2 ■ 3 H 2 0, RbTi (S0 4 ) 2 ■ 4 H 2 0, RbTi (S0 4 ) 2 5 H 2 0, RRbbTTii ((SSQ0 44 )) 22 ■■ 66 HH 22 00 ,, RRbbTTii ((SSQ0 44 )) 22 ■■ 77 HH 22 00 ,, RbTi (S0 4 ) 2 ■ 8 H 2 0, RbTi (S0 4 ) 2 9 H 2 0, RbTi (S0 4 ) 2 ■ 10 H 2 0, RbTi (S0 4 ) 2 ■ 1 1 H 2 0 and RbTi (S0 4 ) 2 ■ 12 H 2 0, NaTi (S0 4 ) 2 , NaTi (S0 4 ) 2 ■ 1 H 2 0, NaTi (S0 4 ) 2 ■ 2 H 2 0, NaTi (S0 4 ) 2 ■ 3 H 2 0, NaTi (S0 4 ) 2 ■ 4 H 2 O, NaTi (SO 4 ) 2 5 H 2 O, NaTi (SO 4 ) 2 ■ 6 H 2 O, NaTi (SO 4 ) 2 ■ 7 H 2 O, NaTi (SO 4 ) 2 ■ 8 H 2 0, NaTi (SQ 4 ) 2 9 H 2 O, NaTi (S0 4 ) 2 ■ 10 H 2 0, NaTi (S0 4 ) 2 ■ 1 1 H 2 0 and NaTi (S0 4 ) 2 ■ 12 H 2 0.
Besonders bevorzugt sind KAI(S04)2, KAI(S04)2 ■ 1 H20, KAI(S04)2 ■ 2 H20, KAI(S04)2 ■ 3 H20, KAI(S04)2 ■ 4 H20, KAI(S04)2 ■ 5 H20, KAI(S04)2 ■ 6 H20, KAI(S04)2 ■ 7 H20, KAI(S04)2 ■ 8 HzO, KAI(S04)2 ■ 9 H20, KAI(S04)2 ■ 10 H20, KAI(S04)2 ■ 1 1 HzO und KAI(S04)2 ■ 12 H20. Particularly preferred are KAI (S0 4 ) 2 , KAI (S0 4 ) 2 ■ 1 H 2 0, KAI (S0 4 ) 2 ■ 2 H 2 0, KAI (S0 4 ) 2 ■ 3 H 2 0, KAI (S0 4 ) 2 ■ 4 H 2 0, KAI (S0 4 ) 2 ■ 5 H 2 0, KAI (S0 4 ) 2 ■ 6 H 2 0, KAI (S0 4 ) 2 ■ 7 H 2 0, KAI (S0 4 ) 2 ■ 8 H z O, KAI (S0 4 ) 2 ■ 9 H 2 0, KAI (S0 4 ) 2 ■ 10 H 2 0, KAI (S0 4 ) 2 ■ 1 1 H z O and KAI (S0 4 ) 2 ■ 12H 2 0.
Das mindestens eine Doppelsalz vom Alaun-Typ mit der allgemeinen Formel M'M"'(S04)2 ■ x H20 ist in den erfindungsgemäßen Zusammensetzungen bevorzugt in einer Gesamtmenge von 0, 1 - 10 Gew.-%, besonders bevorzugt 0,5 - 7 Gew.-% und außerordentlich bevorzugt 1 - 3 Gew.-%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien Zusammensetzung, enthalten. The at least one double salt of the alum type having the general formula M'M '' (S0 4) 2 ■ x H 2 0 is preferably in a total amount of 0, 1 in the present compositions - 10 wt .-%, particularly preferably 0 , 5 - 7 wt .-% and most preferably 1 - 3 wt .-%, each based on the total weight of the propellant-free composition containing.
Weitere bevorzugte Deodorant- Further preferred deodorant
5 3 1 5 3 1
Wirkstoffe sind ausgewählt aus mindestens einem aromatischen Active ingredients are selected from at least one aromatic
OH Alkohol der Struktur (AA-1),
Figure imgf000029_0001
OH alcohol of structure (AA-1),
Figure imgf000029_0001
(AA-1) wobei die Struktur (AA-1 ) folgendermaßen gekennzeichnet ist: (AA-1) wherein the structure (AA-1) is characterized as follows:
R - R6 = unabhängig voneinander ein Wasserstoffatom, eine Alkylgruppe mit 1 bis 10 Kohlenstoffatomen, die linear oder verzweigt sein kann und die substituiert sein kann mit OH-Gruppen oder Alkoxy-Gruppen mit 1 bis 5 Kohlenstoffatomen, oder eine Alkenylgruppe mit 2 bis 10 Kohlenstoffatomen, die linear oder verzweigt sein kann und die substituiert sein kann mit OH-Gruppen oder Alkoxy-Gruppen mit 1 bis 5 Kohlenstoffatomen, R - R 6 = independently a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, which may be linear or branched and which may be substituted by OH groups or alkoxy groups having 1 to 5 carbon atoms, or an alkenyl group having 2 to 10 Carbon atoms which may be linear or branched and which may be substituted by OH groups or alkoxy groups having 1 to 5 carbon atoms,
R7 - R = unabhängig voneinander ein Wasserstoffatom, ein Halogenatom, insbesondere ein Chloratom, oder eine Alkylgruppe mit 1 bis 1 0 Kohlenstoffatomen , die linear oder verzweigt sein kann und die substituiert sein kann mit OH-Gruppen oder Alkoxy-Gruppen mit 1 bis 5 Kohlenstoffatomen, insbesondere mit einer Methoxygruppe, R 7 - R = independently a hydrogen atom, a halogen atom, in particular a chlorine atom, or an alkyl group having 1 to 1 0 carbon atoms, which may be linear or branched and which may be substituted by OH groups or alkoxy groups having 1 to 5 Carbon atoms, in particular with a methoxy group,
m = 0 oder 1 ist, m = 0 or 1,
n, o, p = unabhängig voneinander ganze Zahlen von 0 bis 1 0 sein können, wobei mindestens einer der Werte n, o, p 0 ist. n, o, p = can independently be integers from 0 to 10, at least one of the values n, o, p being 0.
Erfindungsgemäß bevorzugte Zusammensetzungen sind dadurch gekennzeichnet, dass der deodorierend wirkende aromatische Alkohol der Struktur (AA-1 ) ausgewählt ist aus Phenoxyethanol, Phenoxyisopropanol (3-Phenoxy-propan-2-ol), Anisalkohol, 2-Methyl-5-phenyl-pentan-1 -ol, 1 , 1 - Dimethyl-3-phenyl-propan-1 -ol, Benzylalkohol, 2-Phenylethan-1 -ol, 3-Phenylpropan-1 -ol, 4-Phe- nylbutan-1 -ol, 5-Phenylpentan-1 -ol, 2-Benzylheptan-1 -ol, 2,2-Dimethyl-3-phenylpropan-1 -ol, 2,2-Dimethyl-3-(3'-methylphenyl)-propan-1 -ol, 2-Ethyl-3-phenylpropan-1 -ol, 2-Ethyl-3-(3'-methyl- phenyl)-propan-1 -ol, 3-(3'-Chlorphenyl)-2-ethylpropan-1 -ol, 3-(2'-Chlorphenyl)-2-ethylpropan-1 -ol, 3-(4'-Chlorphenyl)-2-ethylpropan-1 -ol, 3-(3',4'-Dichlorphenyl)-2-ethylpropan-1 -ol, 2-Ethyl-3-(2'- methylphenyl)-propan-1 -ol, 2-Ethyl-3-(4'-methylphenyl)-propan-1 -ol, 3-(3',4'-Dimethylphenyl)-2- ethylpropan-1 -ol, 2-Ethyl-3-(4'-methoxyphenyl)-propan-1 -ol, 3-(3',4'-Dimethoxyphenyl)-2-ethyl- propan-1 -ol, 2-Allyl-3-phenylpropan-1 -ol und 2-n-Pentyl-3-phenylpropan-1 -ol sowie Mischungen hiervon. Besonders bevorzugte Alkohole der Struktur AA-1 sind solche, bei denen m = 0 ist. Weitere besonders bevorzugte Alkohole der Struktur AA-1 sind solche, bei denen mindestens einer der Reste R , R2, R3, R4, R5 oder R6 Φ H ist. Preferred compositions according to the invention are characterized in that the deodorising aromatic alcohol of structure (AA-1) is selected from phenoxyethanol, phenoxyisopropanol (3-phenoxy-propan-2-ol), anisalcohol, 2-methyl-5-phenyl-pentane 1 -ol, 1,1-dimethyl-3-phenyl-propan-1-ol, benzyl alcohol, 2-phenylethane-1-ol, 3-phenylpropan-1-ol, 4-phenyl-1-butanol, 5- Phenylpentan-1-ol, 2-benzylheptan-1-ol, 2,2-dimethyl-3-phenylpropan-1-ol, 2,2-dimethyl-3- (3'-methylphenyl) -propan-1-ol, 2 Ethyl 3-phenylpropan-1-ol, 2-ethyl-3- (3'-methylphenyl) -propan-1-ol, 3- (3'-chlorophenyl) -2-ethyl-propan-1-ol, 3 - (2'-chlorophenyl) -2-ethyl-propan-1-ol, 3- (4'-chlorophenyl) -2-ethyl-propan-1-ol, 3- (3 ', 4'-dichlorophenyl) -2-ethyl-propane-1 -ol, 2-ethyl-3- (2'-methylphenyl) -propan-1-ol, 2-ethyl-3- (4'-methylphenyl) -propan-1-ol, 3- (3 ', 4'- Dimethylphenyl) -2-ethyl-propan-1-ol, 2-ethyl-3- (4'-methoxyphenyl) -propan-1-ol, 3- (3 ', 4'-dimethoxyphenyl) -2-ethyl-propan-1 - ol, 2-allyl-3-phenylp ropan-1-ol and 2-n-pentyl-3-phenylpropan-1-ol and mixtures thereof. Particularly preferred alcohols of structure AA-1 are those in which m = 0. Further particularly preferred alcohols of the structure AA-1 are those in which at least one of the radicals R, R 2 , R 3 , R 4 , R 5 or R 6 Φ H.
Weitere besonders bevorzugte Alkohole der Struktur AA-1 sind solche, bei denen m = 0 und mindestens einer der Reste R , R2, R3, R4, R5 oder R6 1 H ist. Further particularly preferred alcohols of the structure AA-1 are those in which m = 0 and at least one of the radicals R, R 2 , R 3 , R 4 , R 5 or R 6 is 1 H.
Beispiele für die als Substituenten in den erfindungsgemäß verwendeten Verbindungen genannten Cr bis C5-Alkylreste sind die Gruppen Methyl, Ethyl, Propyl, Isopropyl, n-Butyl, tert.-Butyl, n-Pentyl, Amyl, Isoamyl. Ethyl, Methyl, Propyl, Isopropyl, n-Butyl, tert.-Butyl, n-Pentyl, Amyl, Iso- amyl sind bevorzugte Alkylreste, besonders bevorzugt sind Methyl und n-Pentyl. Erfindungsgemäß bevorzugte C bis C4-Alkoxyreste sind beispielsweise eine Methoxy- oder eine Ethoxy- gruppe. Weiterhin können als bevorzugte Beispiele für eine C bis C5-Hydroxyalkylgruppe eine Hydroxymethyl-, eine 2-Hydroxyethyl-, eine 3-Hydroxypropyl- oder eine 4-Hydroxybutylgruppe genannt werden. Eine 2-Hydroxyethylgruppe ist besonders bevorzugt. Eine besonders bevorzugte C2- bis C4-Polyhydroxyalkylgruppe ist die 1 ,2-Dihydroxyethylgruppe. Examples of the C r to C 5 -alkyl radicals mentioned as substituents in the compounds used according to the invention are the groups methyl, ethyl, propyl, isopropyl, n-butyl, tert-butyl, n-pentyl, amyl, isoamyl. Ethyl, methyl, propyl, isopropyl, n-butyl, tert-butyl, n-pentyl, amyl, iso-amyl are preferred alkyl radicals, particular preference is given to methyl and n-pentyl. Preferred C to C 4 -alkoxy radicals according to the invention are, for example, a methoxy or an ethoxy group. Furthermore, as preferred examples of a C to C 5 -hydroxyalkyl group, a Hydroxymethyl, a 2-hydroxyethyl, a 3-hydroxypropyl or a 4-hydroxybutyl group. A 2-hydroxyethyl group is particularly preferred. A particularly preferred C 2 to C 4 polyhydroxyalkyl group is the 1, 2-dihydroxyethyl group.
Erfindungsgemäß bevorzugte Beispiele für Halogenatome sind F-, Cl- oder Br-Atome, Cl-Atome sind ganz besonders bevorzugt. According to preferred examples of halogen atoms are F, Cl or Br atoms, Cl atoms are very particularly preferred.
Erfindungsgemäß besonders bevorzugte Zusammensetzungen sind dadurch gekennzeichnet, dass der deodorierend wirkende aromatische Alkohol der Struktur (AA-1) ausgewählt ist aus Anisalkohol, 2-Methyl-5-phenyl-pentan-1 -ol, 1 ,1 -Dimethyl-3-phenyl-propan-1 -ol, 3-Phenylpropan-1 -ol, 4-Phenylbutan-1 -ol, 5-Phenylpentan-1 -ol, 2-Benzylheptan-1 -ol, 2,2-Dimethyl-3-phenylpropan-1 -ol und 2-n-Pentyl-3-phenylpropan-1 -ol. Außerordentlich bevorzugt ist 2-Benzylheptan-1 -ol. Der mindestens eine deodorierend wirkende aromatische Alkohol der Struktur (AA-1), wie vorstehend beschrieben, ist bevorzugt in einer Gesamtmenge von 0,01 - 5 Gew.-%, besonders bevorzugt 0,1 Particularly preferred compositions according to the invention are characterized in that the deodorant aromatic alcohol of structure (AA-1) is selected from anisalcohol, 2-methyl-5-phenyl-pentane-1-ol, 1, 1-dimethyl-3-phenyl propan-1-ol, 3-phenylpropan-1-ol, 4-phenylbutan-1-ol, 5-phenylpentan-1-ol, 2-benzylheptan-1-ol, 2,2-dimethyl-3-phenylpropan-1 - ol and 2-n-pentyl-3-phenylpropan-1-ol. Extraordinary preference is given to 2-benzylheptan-1-ol. The at least one deodorant aromatic alcohol of the structure (AA-1) as described above is preferably in a total amount of 0.01-5 wt%, more preferably 0.1
- 2 Gew.-%, außerordentlich bevorzugt 0,2 - 1 Gew.-%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien erfindungsgemäßen Zusammensetzung, enthalten. - 2 wt .-%, most preferably 0.2 to 1 wt .-%, each based on the total weight of the blowing agent-free composition of the invention.
Weitere erfindungsgemäß bevorzugte Deodorant-Wirkstoffe sind ausgewählt aus 1 ,2-Alkandiolen mit 7 bis 16 Kohlenstoffatomen im Molekül, insbesondere 1 ,2-Octandiol, 1 ,2-Decandiol und 1 ,2- Dodecandiol. Weitere bevorzugte erfindungsgemäße Deodorant- oder Antitranspirant-Zusam- mensetzungen sind dadurch gekennzeichnet, dass der mindestens eine Deodorant-Wrkstoff in einer Gesamtmenge von 0,1 - 20 Gew.-%, bevorzugt 0,2 - 10 Gew.-%, besonders bevorzugt 0,3 Further inventively preferred deodorant agents are selected from 1, 2-alkanediols having 7 to 16 carbon atoms in the molecule, in particular 1, 2-octanediol, 1, 2-decanediol and 1, 2-dodecanediol. Further preferred deodorant or antiperspirant compositions according to the invention are characterized in that the at least one deodorant active ingredient is present in a total amount of 0.1-20% by weight, preferably 0.2-10% by weight, particularly preferably 0 3
- 5 Gew.-% und außerordentlich bevorzugt 1 - 3 Gew.-%, jeweils bezogen auf das Gesamtgewicht der Deodorant-Wrkstoffe in der treibmittelfreien Zusammensetzung, enthalten ist. - 5 wt .-% and most preferably 1 - 3 wt .-%, each based on the total weight of the deodorant impurities in the propellant-free composition is included.
Die erfindungsgemäßen Zusammensetzungen enthalten in einer bevorzugten Ausführungsform sowohl mindestens einen Deodorant- als auch mindestens einen Antitranspirant-Wrkstoff.  In a preferred embodiment, the compositions according to the invention contain both at least one deodorant and at least one antiperspirant active.
Die erfindungsgemäßen Aerosolsprays können als Wasser-in-ÖI-Emulsion, Wasser-in-Siliconöl- Emulsionen, ÖI-in-Wasser-Emulsion, Siliconöl-in-Wasser-Emulsion, Wasser-in-ÖI-Mikroemulsion, ÖI-in-Wasser-Mikroemulsion, Siliconöl-in-Wasser-Mikroemulsion, Polyol-in-ÖI-Emulsion, Öl-in- Polyol-Emulsion, Polyol-Öl-Mehrfach-Emulsion, wobei die Polyolphase jeweils nur einen geringen Wassergehalt (z. B. 5 - 10 Gew.-% freies Wasser, bezogen auf die gesamte treibmittelfreie Zusammensetzung) aufweisen kann, alkoholische Lösung, insbesondere ethanolische Lösung, hydroalkoholische Lösung, Lösung, insbesondere als Lösung in Propylenglycol, Glycerin, Dipropylenglycol und (unter Normalbedingungen) flüssigen Polyethylenglycolen, hydroglycolische Lösung, Polyol-Lösung, Wasser-Polyol-Lösung und als wässriges Gel vorliegen. Alle genannten Zusammensetzungen können verdickt sein, beispielsweise auf der Basis von Fettsäureseifen, Dibenzylidensorbitol, N-Acylaminosäureamiden, 12-Hydroxystearinsäure, Polyacrylaten vom Carbomer- und Carbopol-Typ, Polyacrylamiden und Polysacchariden, die chemisch und/oder physikalisch modifiziert sein können. Die erfindungsgemäßen Zusammensetzungen können transparent, translucent oder opak sein. Für erfindungsgemäß bevorzugte Zusammensetzungen, die Ethanol enthalten, insbesondere mit einem Ethanolgehalt von 5 - 75 Gew.-%, besonders bevorzugt 10 - 60 Gew.-%, jeweils bezogen auf das Gewicht der treibmittelfreien Zusammensetzung, ist das erfindungsgemäße Treibmittel d) von besonderem Vorteil, da es die Entflammbarkeit der gesamten Zusammensetzung deutlich reduziert. Selbstverständlich wirkt sich die geringe Entflammbarkeit der erfindungsgemäßen Treibmittel d) auch auf erfindungsgemäße Zusammensetzungen aus, die kein Ethanol enthalten, und stellt auch für diese einen überraschenden Vorteil dar. The aerosol sprays according to the invention can be in the form of a water-in-oil emulsion, water-in-silicone oil emulsions, oil-in-water emulsion, silicone oil-in-water emulsion, water-in-oil microemulsion, oil-in-water Microemulsion, silicone oil-in-water microemulsion, polyol-in-oil emulsion, oil-in-polyol emulsion, polyol-oil multiple emulsion, each having only a low water content (e.g. Alcoholic solution, in particular ethanolic solution, hydroalcoholic solution, solution, in particular as a solution in propylene glycol, glycerol, dipropylene glycol and (under normal conditions) liquid polyethylene glycols, hydroglycolic solution, Polyol solution, water-polyol solution and as an aqueous gel. All said compositions may be thickened, for example, based on fatty acid soaps, dibenzylidenesorbitol, N-acylamino acid amides, 12-hydroxystearic acid, carbomer and carbopol type polyacrylates, polyacrylamides and polysaccharides, which may be chemically and / or physically modified. The compositions of the invention may be transparent, translucent or opaque. For inventively preferred compositions containing ethanol, in particular with an ethanol content of 5 to 75 wt .-%, particularly preferably 10 to 60 wt .-%, each based on the weight of the propellant-free composition, the blowing agent d) according to the invention is of particular advantage because it significantly reduces the flammability of the entire composition. Of course, the low flammability of the blowing agent d) according to the invention also has an effect on compositions according to the invention which contain no ethanol, and also represents a surprising advantage for them.
Die erfindungsgemäßen Zusammensetzungen können insgesamt 0,05 bis 5 Gew.-%, bevorzugt 0,1 - 2 Gew.-%, besonders bevorzugt 0,5 - 1 Gew.-%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien Zusammensetzung, mindestens einer Wachskomponente mit einem Schmelzpunkt > 50°C enthalten. Erfindungsgemäß bevorzugt sind beispielsweise natürliche pflanzliche Wachse, z. B. Candelillawachs, Carnaubawachs, Japanwachs, Zuckerrohrwachs, Ouricourywachs, Korkwachs, Sonnenblumenwachs, Fruchtwachse wie Orangenwachse, Zitronenwachse, Grapefruitwachs, und tierische Wachse, z. B. Bienenwachs, Schellackwachs und Walrat. Im Sinne der Erfindung kann es besonders bevorzugt sein, hydrierte oder gehärtete Wachse einzusetzen. Als Wachskomponente sind auch chemisch modifizierte Wachse, insbesondere die Hartwachse, wie z. B. Montanesterwachse, hydrierte Jojobawachse und Sasolwachse, einsetzbar. Zu den synthetischen Wachsen, die ebenfalls erfindungsgemäß bevorzugt sind, zählen beispielsweise Polyalkylenwachse und Polyethylenglycolwachse, C2o-C40-Dialkylester von Dimersäuren, C30-5o-Alkylbienenwachs sowie Alkyl- und Alkylarylester von Dimerfettsäuren. The compositions according to the invention may contain a total of 0.05 to 5 wt .-%, preferably 0.1 to 2 wt .-%, particularly preferably 0.5 to 1 wt .-%, each based on the total weight of the blowing agent-free composition, at least one wax component with a melting point> 50 ° C included. Preference according to the invention, for example, natural vegetable waxes, z. Candelilla wax, carnauba wax, Japan wax, sugarcane wax, ouricoury wax, cork wax, sunflower wax, fruit waxes such as orange waxes, lemon waxes, grapefruit wax, and animal waxes, e.g. Beeswax, shellac wax and spermaceti. For the purposes of the invention, it may be particularly preferred to use hydrogenated or hardened waxes. As a wax component and chemically modified waxes, especially the hard waxes, such as. As montan ester waxes, hydrogenated jojoba waxes and Sasol waxes used. Synthetic waxes, which are also preferable in the invention include, for example, polyalkylene waxes and polyethylene glycol waxes, C 2 ° C 40 dialkyl esters of dimer acids, C 30 -5o-alkyl and alkylaryl esters of Alkylbienenwachs and dimer fatty acids.
Eine besonders bevorzugte Wachskomponente ist ausgewählt aus mindestens einem Ester aus einem gesättigten, einwertigen C 6-C60-Alkohol und einer gesättigten C8-C36-Monocarbonsäure. Erfindungsgemäß zählen hierzu auch Lactide, die cyclischen Doppelester von alpha-Hydroxy- carbonsäuren der entsprechenden Kettenlänge. Die bevorzugten Ester setzen sich aus gesättigten verzweigten oder unverzweigten Monocarbonsäuren und gesättigten verzweigten oder unverzweigten einwertigen Alkoholen zusammen. Auch Ester aus aromatischen Carbonsäuren bzw. Hydroxycarbonsäuren (z. B. 12-Hydroxystearinsäure) und gesättigten verzweigten oder unverzweigten Alkoholen sind erfindungsgemäß einsetzbar, sofern die Wachskomponente einen Schmelzpunkt > 50°C hat. Besonders bevorzugt ist, die Wachskomponenten zu wählen aus der Gruppe der Ester aus gesättigten verzweigten oder unverzweigten Alkancarbonsäuren einer Kettenlänge von 12 bis 24 C-Atomen und den gesättigten verzweigten oder unverzweigten Alkoholen einer Kettenlänge von 16 bis 50 C-Atomen, die einen Schmelzpunkt > 50°C haben. Insbesondere können als Wachskomponente C 6.36-Alkylstearate und C 8_38-Alkylhydroxystearoyl- stearate, C20-4o-Alkylerucate sowie Cetearylbehenat vorteilhaft sein. Das Wachs oder die Wachskomponenten weisen einen Schmelzpunkt > 50°C, bevorzugt > 60°C, auf. Eine besonders bevor- zugte erfindungsgemäße Ausführung enthält als Wachskomponente ein C2o-C40-Alkylstearat, Cetylbehenat, Stearylbehenat, Cetearylbehenat oder Mischungen hiervon. Weitere bevorzugte Wachskomponenten mit einem Schmelzpunkt > 50°C sind die Triglyceride gesättigter und gegebenenfalls hydroxylierter C 2-3o-Fettsäuren, wie gehärtete Triglycerid fette (hydriertes Palmöl, hydriertes Kokosöl, hydriertes Rizinusöl), Glyceryltribehenat (Tribehenin) oder Glyceryltri-12- hydroxystearat, weiterhin synthetische Vollester aus Fettsäuren und Glycolen oder Polyolen mit 2 - 6 Kohlenstoffatomen, solange sie einen Schmelzpunkt oberhalb von 50 °C aufweisen, beispielsweise bevorzugt C18 - C36 Acid Triglyceride (Syncrowax® HGL-C). Erfindungsgemäß ist als Wachskomponente hydriertes Rizinusöl besonders bevorzugt. A particularly preferred wax component is selected from at least one ester of a saturated, monohydric C 6 -C 60 -alcohol and a saturated C 8 -C 36 -monocarboxylic acid. According to the invention, lactides, the cyclic double esters of alpha-hydroxy carboxylic acids of the corresponding chain length, also belong thereto. The preferred esters are composed of saturated branched or unbranched monocarboxylic acids and saturated branched or unbranched monohydric alcohols. Also esters of aromatic carboxylic acids or hydroxycarboxylic acids (eg 12-hydroxystearic acid) and saturated branched or unbranched alcohols can be used according to the invention, provided that the wax component has a melting point> 50 ° C. It is particularly preferred to choose the wax components from the group of esters of saturated branched or unbranched alkanecarboxylic acids having a chain length of 12 to 24 carbon atoms and the saturated branched or unbranched alcohols having a chain length of 16 to 50 carbon atoms and having a melting point> 50 ° C have. In particular, as a wax component C 6 . 36 alkyl stearates and C 8 _ 38 -Alkylhydroxystearoyl- stearates, C 20 -4o-Alkylerucate and Cetearylbehenat be advantageous. The wax or the wax components have a melting point> 50 ° C, preferably> 60 ° C, on. A particularly In accordance with the invention, the wax component comprises a C 2 -C 40 -alkyl stearate, cetyl behenate, stearyl behenate, cetearyl behenate or mixtures thereof. Further preferred wax components with a melting point> 50 ° C are the triglycerides of saturated and optionally hydroxylated C 2 - 3 o fatty acids such as hydrogenated triglyceride fats (hydrogenated palm oil, hydrogenated coconut oil, hydrogenated castor oil), glyceryl tribehenate (tribehenin) or glyceryl tri-12-hydroxystearat further synthetic Vollester of fatty acids and glycols or polyols containing 2 - 6 carbon atoms as long as they have a melting point above 50 ° C, for example, preferably C 18 - C 36 acid triglyceride (Syncrowax HGL-C ®). According to the invention, hydrogenated castor oil is particularly preferred as the wax component.
Weitere bevorzugte Wachskomponenten mit einem Schmelzpunkt > 50°C sind die gesättigten linearen C 4 - C36-Carbonsäuren, insbesondere Myristinsäure, Palmitinsäure, Stearinsäure und Behensäure sowie Mischungen dieser Verbindungen, z. B. Syncrowax® AW 1 C (C 8 - C36-Fett- säuren) oder Cutina® FS 45 (Palmitin- und Stearinsäure). Further preferred wax components having a melting point> 50 ° C are the saturated linear C 4 - C 36 carboxylic acids, in particular myristic acid, palmitic acid, stearic acid and behenic acid and mixtures of these compounds, eg. B. Syncrowax ® AW 1 C (C 8 - C 36 -Fett- acids) or Cutina ® FS 45 (palmitic and stearic acid).
ÖI-in-Wasser-Emulgatoren Oil-in-water emulsifiers
Die erfindungsgemäßen Zusammensetzungen, die als Emulsion, insbesondere als Öl-in-Wasser- Emulsion oder Polyol-in-Wasser-Emulsion, formuliert sind, enthalten bevorzugt mindestens einen nichtionischen ÖI-in-Wasser-Emulgator mit einem HLB-Wert von mehr als 7. Hierbei handelt es sich um dem Fachmann allgemein bekannte Emulgatoren, wie sie beispielsweise in Kirk-Othmer, "Encyclopedia of Chemical Technology", 3. Aufl., 1979, Band 8, Seite 913-916, aufgelistet sind. Für ethoxylierte Produkte wird der HLB-Wert nach der Formel HLB = (100 - L) : 5 berechnet, wobei L der Gewichtsanteil der lipophilen Gruppen, das heißt der Fettalkyl- oder Fettacylgruppen, in den Ethylenoxidaddukten, ausgedrückt in Gewichtsprozent, ist.  The compositions according to the invention which are formulated as an emulsion, in particular as an oil-in-water emulsion or a polyol-in-water emulsion, preferably comprise at least one nonionic oil-in-water emulsifier having an HLB value of more than 7 These are emulsifiers which are generally known to the person skilled in the art and are listed, for example, in Kirk-Othmer, "Encyclopedia of Chemical Technology", 3rd edition, 1979, Volume 8, pages 913-916. For ethoxylated products, the HLB value is calculated according to the formula HLB = (100-L): 5, where L is the weight fraction of the lipophilic groups, that is the fatty alkyl or fatty acyl groups, in the ethylene oxide adducts, expressed in weight percent.
Bei der Auswahl erfindungsgemäß geeigneter nichtionischer ÖI-in-Wasser-Emulgatoren ist es besonders bevorzugt, ein Gemisch von nichtionischen ÖI-in-Wasser-Emulgatoren einzusetzen, um die Stabilität erfindungsgemäßer O/W-Emulsionszusammensetzungen optimal einstellen zu können. Die einzelnen Emulgatorkomponenten liefern dabei einen Anteil zum Gesamt-HLB-Wert oder mittleren HLB-Wert des ÖI-in-Wasser-Emulgatorgemisches gemäß ihrem Gewichtsanteil am Gesamtgewicht der nichtionischen und gegebenenfalls vorhandenen ionischen ÖI-in-Wasser- Emulgatoren. Erfindungsgemäß beträgt der mittlere HLB-Wert des ÖI-in-Wasser-Emulgator- gemisches 10 - 19, bevorzugt 12 - 18 und besonders bevorzugt 14 - 17. Um derartige mittlere HLB-Werte zu erzielen, werden bevorzugt ÖI-in-Wasser-Emulgatoren aus den HLB-Wertberei- chen 10 - 14, 14 - 16 und gegebenenfalls 16 - 19 miteinander kombiniert. Die erfindungsgemäßen Antitranspirant-Zusammensetzungen können in einer anderen bevorzugten Ausführungsform auch nur einen einzigen nichtionischen ÖI-in-Wasser-Emulgator mit einem HLB-Wert im Bereich von 10 - 19 enthalten. Bevorzugte erfindungsgemäße Antitranspirant-Zusammensetzungen sind dadurch gekennzeichnet, dass die nichtionischen ÖI-in-Wasser-Emulgatoren ausgewählt sind aus ethoxylierten C8-C24- Alkanolen mit durchschnittlich 10 - 100 Mol Ethylenoxid pro Mol, ethoxylierten C8-C24-Carbon- säuren mit durchschnittlich 10 - 100 Mol Ethylenoxid pro Mol, Silicon-Copolyolen mit Ethylenoxid- Einheiten oder mit Ethylenoxid- und Propylenoxid-Einheiten, Alkylmono- und -oligoglycosiden mit 8 bis 22 Kohlenstoffatomen im Alkylrest und deren ethoxylierten Analoga, ethoxylierten Sterinen, Partialestern von Polyglycerinen mit 2 bis 10 Glycerineinheiten und mit 1 bis 4 gesättigten oder ungesättigten, linearen oder verzweigten, gegebenenfalls hydroxylierten C8 - C30-Fettsäureresten verestert, sofern sie einen HLB-Wert von mehr als 7 aufweisen, sowie Mischungen der vorgenannten Substanzen. In selecting nonionic oil-in-water emulsifiers which are suitable according to the invention, it is particularly preferable to use a mixture of nonionic oil-in-water emulsifiers in order to optimally adjust the stability of O / W emulsion compositions according to the invention. The individual emulsifier components provide a proportion of the total HLB value or mean HLB value of the oil-in-water emulsifier mixture according to their weight fraction of the total weight of the nonionic and optionally present ionic oil-in-water emulsifiers. According to the invention, the mean HLB value of the oil-in-water emulsifier mixture is 10-19, preferably 12-18 and particularly preferably 14-17. In order to achieve such average HLB values, preference is given to oil-in-water emulsifiers from the HLB value ranges 10 - 14, 14 - 16 and optionally 16 - 19 combined. In another preferred embodiment, the antiperspirant compositions of the present invention may also contain only a single nonionic oil-in-water emulsifier having an HLB in the range of 10-19. Preferred antiperspirant compositions according to the invention are characterized in that the nonionic oil-in-water emulsifiers are selected from ethoxylated C 8 -C 24 -alkanols having on average 10 to 100 moles of ethylene oxide per mole of ethoxylated C 8 -C 24 -carboxylic acids with an average of 10 to 100 moles of ethylene oxide per mole, silicone copolyols having ethylene oxide units or with ethylene oxide and propylene oxide units, alkyl mono- and oligoglycosides having 8 to 22 carbon atoms in the alkyl radical and their ethoxylated analogs, ethoxylated sterols, partial esters of polyglycerols with 2 to 10 glycerol units and esterified with 1 to 4 saturated or unsaturated, linear or branched, optionally hydroxylated C 8 - C 30 fatty acid residues, if they have an HLB value of more than 7, and mixtures of the aforementioned substances.
Die ethoxylierten C8-C24-Alkanole haben die Formel R 0(CH2CH20)nl-l, wobei R steht für einen linearen oder verzweigten Alkyl- und/oder Alkenylrest mit 8 - 24 Kohlenstoffatomen und n, die mittlere Anzahl der Ethylenoxid-Einheiten pro Molekül, für Zahlen von 10 - 100, vorzugsweise 10 - 30 Mol Ethylenoxid an 1 Mol Caprylalkohol, 2-Ethylhexylalkohol, Caprinalkohol, Laurylalko- hol, Isotridecylalkohol, Myristylalkohol, Cetylalkohol, Isocetylalkohol, Palmitoleylalkohol, Stearyl- alkohol, Isostearylalkohol, Oleylalkohol, Elaidylalkohol, Petroselinylalkohol, Arachylalkohol, Gado- leylalkohol, Behenylalkohol, Erucylalkohol und Brassidylalkohol sowie deren technische Mischungen. Auch Addukte von 10 - 100 Mol Ethylenoxid an technische Fettalkohole mit 12 - 18 Kohlenstoffatomen, wie beispielsweise Kokos-, Palm-, Palmkern- oder Talgfettalkohol, sind geeignet. Die ethoxylierten C8-C24-Carbonsäuren haben die Formel R (OCH2CH2)nOH, wobei R steht für einen linearen oder verzweigten gesättigten oder ungesättigten Acylrest mit 8 -24 Kohlenstoffatomen und n, die mittlere Anzahl der Ethylenoxid-Einheiten pro Molekül, für Zahlen von 10 - 100, vorzugsweise 10 - 30 Mol Ethylenoxid an 1 Mol Caprylsäure, 2-Ethylhexansäure, Caprinsäure, Laurinsäure, Isotridecansäure, Myristinsäure, Cetylsäure, Palmitoleinsäure, Stearinsäure, Isostearinsäure, Ölsäure, Elaidinsäure, Petroselinsäure, Arachinsäure, Gadoleinsäure, Behensäure, Erucasäure und Brassidinsäure sowie deren technische Mischungen. Auch Addukte von 10 - 100 Mol Ethylenoxid an technische Fettsäuren mit 12 - 18 Kohlenstoffatomen, wie Kokos-, Palm-, Palmkern- oder Talgfettsäure, sind geeignet. Besonders bevorzugt sind PEG-50-monostearat, PEG-100-monostearat, PEG-50-monooleat, PEG-100-monooleat, PEG-50-monolaurat und PEG- 100-monolaurat. The ethoxylated C 8 -C 24 -alkanols have the formula R 0 (CH 2 CH 2 O) n ll, where R is a linear or branched alkyl and / or alkenyl radical having 8-24 carbon atoms and n, the average number of Ethylene oxide units per molecule, for numbers from 10 to 100, preferably 10 to 30, mol of ethylene oxide to 1 mol of caprylic alcohol, 2-ethylhexyl alcohol, capric alcohol, lauryl alcohol, isotridecyl alcohol, myristyl alcohol, cetyl alcohol, isocetyl alcohol, palmitoleyl alcohol, stearyl alcohol, isostearyl alcohol, Oleyl alcohol, elaidyl alcohol, petroselinyl alcohol, arachyl alcohol, gadoleyl alcohol, behenyl alcohol, erucyl alcohol and brassidyl alcohol, and technical mixtures thereof. Also, adducts of 10-100 moles of ethylene oxide with technical fatty alcohols having 12-18 carbon atoms, such as coconut, palm, palm kernel or tallow fatty alcohol, are suitable. The ethoxylated C 8 -C 24 carboxylic acids have the formula R (OCH 2 CH 2 ) n OH, where R is a linear or branched saturated or unsaturated acyl radical having 8-24 carbon atoms and n, the average number of ethylene oxide units per Molecule, for numbers from 10 to 100, preferably 10 to 30, mol of ethylene oxide to 1 mol of caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, cetylic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic acid, petroselinic acid, arachidic acid, gadoleic acid, Behenic acid, erucic acid and brassidic acid as well as their technical mixtures. Adducts of 10 to 100 moles of ethylene oxide with technical fatty acids containing 12 to 18 carbon atoms, such as coconut, palm, palm kernel or tallow fatty acid, are also suitable. Particularly preferred are PEG-50 monostearate, PEG-100 monostearate, PEG-50 monooleate, PEG-100 monooleate, PEG-50 monolaurate and PEG-100 monolaurate.
Besonders bevorzugt eingesetzt werden die C 2-C 8-Alkanole oder die C 2-C 8-Carbonsäuren mit jeweils 10 - 30 Einheiten Ethylenoxid pro Molekül sowie Mischungen dieser Substanzen, insbesondere Ceteth-12, Ceteth-20, Ceteth-30, lsoceteth-20, Steareth-12, Steareth-20, Steareth- 21 , Steareth-30, Ceteareth-12, Ceteareth-20, Ceteareth-30, Laureth-12 und Beheneth-20. Particular preference is given to using the C 2 -C 8 -alkanols or the C 2 -C 8 -carboxylic acids with in each case 10 to 30 units of ethylene oxide per molecule and also mixtures of these substances, in particular ceteth-12, ceteth-20, ceteth-30, isoceteth- 20, steareth-12, steareth-20, steareth-21, steareth-30, ceteareth-12, ceteareth-20, ceteareth-30, laureth-12 and beheneth-20.
Weiterhin werden vorzugsweise C8 - C22-Alkylmono- und -oligoglycoside eingesetzt. C8 -C22- Alkylmono- und -oligoglycoside stellen bekannte, handelsübliche Tenside und Emulgatoren dar. Ihre Herstellung erfolgt insbesondere durch Umsetzung von Glucose oder Oligosacchariden mit primären Alkoholen mit 8 - 22 Kohlenstoffatomen. Bezüglich des Glycosidrestes gilt, dass sowohl Monoglycoside, bei denen ein cyclischer Zuckerrest glycosidisch an den Fettalkohol gebunden ist, als auch oligomere Glycoside mit einem Oligomerisationsgrad bis etwa 8, vorzugsweise 1 - 2, geeignet sind. Der Oligomerisierungsgrad ist dabei ein statistischer Mittelwert, dem eine für solche technischen Produkte übliche Homologenverteilung zugrunde liegt. Produkte, die unter dem Warenzeichen Plantacare® erhältlich sind, enthalten eine glucosidisch gebundene C8-C 6- Alkylgruppe an einem Oligoglucosidrest, dessen mittlerer Oligomerisationsgrad bei 1 - 2, insbesondere bei 1 ,1 - 1 ,4, liegt. Besonders bevorzugte C8 - C22-Alkylmono- und -oligoglycoside sind ausgewählt aus Octylglucosid, Decylglucosid, Laurylglucosid, Palmitylglucosid, Isostearylglucosid, Stearylglucosid, Arachidylglucosid und Behenylglucosid sowie Mischungen hiervon. Auch die vom Glucamin abgeleiteten Acylglucamide sind als nicht-ionische ÖI-in-Wasser-Emulgatoren geeignet. Auch ethoxylierte Sterine, insbesondere ethoxylierte Sojasterine, stellen erfindungsgemäß geeignete ÖI-in-Wasser-Emulgatoren dar. Der Ethoxylierungsgrad muss größer als 5, bevorzugt mindestens 10 sein, um einen HLB-Wert größer 7 aufzuweisen. Geeignete Handelsprodukte sind z. B. PEG-10 Soy Sterol, PEG-16 Soy Sterol und PEG-25 Soy Sterol. Furthermore, preference is given to using C 8 -C 22 -alkyl mono- and -oligoglycosides. C 8 -C 22 -alkylmono- and -oligoglycosides are known, commercially available surfactants and emulsifiers. They are prepared in particular by reacting glucose or oligosaccharides with primary alcohols having 8-22 carbon atoms. With regard to the glycoside radical, monoglycosides in which a cyclic sugar residue is glycosidically linked to the fatty alcohol and oligomeric glycosides having a degree of oligomerization of up to about 8, preferably 1-2, are suitable. The degree of oligomerization is a statistical mean, which is based on a homolog distribution typical for such technical products. Products which are obtainable under the trademark Plantacare ®, containing a glucosidic bond C 8 -C 6 - alkyl group at an oligoglucoside whose average degree of oligomerization at 1 - 2, in particular 1, 1 - 1, 4, is located. Particularly preferred C 8 -C 22 alkyl mono- and oligoglycosides are selected from octyl glucoside, decyl glucoside, lauryl glucoside, palmityl glucoside, isostearyl glucoside, stearyl glucoside, arachidyl glucoside and behenyl glucoside and mixtures thereof. The glucamine-derived acylglucamides are also suitable as nonionic oil-in-water emulsifiers. Ethoxylated sterols, in particular ethoxylated soy sterols, are also suitable oil-in-water emulsifiers according to the invention. The degree of ethoxylation must be greater than 5, preferably at least 10, in order to have an HLB value greater than 7. Suitable commercial products are, for. PEG-10 Soy Sterol, PEG-16 Soy Sterol and PEG-25 Soy Sterol.
Weiterhin werden vorzugsweise Partialester von Polyglycerinen mit 2 bis 10 Glycerineinheiten und mit 1 bis 4 gesättigten oder ungesättigten, linearen oder verzweigten, gegebenenfalls hydro- xylierten C8 - C30-Fettsäureresten verestert, eingesetzt, sofern sie einen HLB-Wert von mehr als 7 aufweisen. Besonders bevorzugt sind Diglycerinmonocaprylat, Diglycerinmonocaprat, Diglyce- rinmonolaurat, Triglycerinmonocaprylat, Triglycerinmonocaprat, Triglycerinmonolaurat, Tetragly- cerinmonocaprylat, Tetraglycerinmonocaprat, Tetraglycerinmonolaurat, Pentaglycerinmonocapry- lat, Pentaglycerinmonocaprat, Pentaglycerinmonolaurat, Hexaglycerinmonocaprylat, Hexaglyce- rinmonocaprat, Hexa glycerinmonolaurat, Hexaglycerinmonomyristat, Hexaglycerinmonostearat, Decaglycerinmonocaprylat, Decaglycerinmonocaprat, Decaglycerinmonolaurat, Decaglycerin- monomyristat, Decaglycerinmonoisostearat, Decaglycerinmonostearat, Decaglycerinmonooleat, Decaglycerinmonohydroxystearat, Decaglycerindicaprylat, Decaglycerindicaprat, Decaglycerindi- laurat, Decaglycerindimyristat, Decaglycerindiisostearat, Decaglycerindistearat, Decaglycerindi- oleat, Decaglycerindihydroxystearat, Decaglycerintricaprylat, Decaglycerintricaprat, Decaglycerin- trilaurat, Decaglycerintrimyristat, Decaglycerintriisostearat, Decaglycerintristearat, Decaglycerintri- oleat und Decaglycerintrihydroxystearat. Furthermore, partial esters of polyglycerols having 2 to 10 glycerol units and having 1 to 4 saturated or unsaturated, linear or branched, optionally hydroxylated C 8 -C 30 fatty acid radicals are preferably esterified, if they have an HLB value of more than 7 , Particularly preferred Diglycerinmonocaprylat, Diglycerinmonocaprat, diglycerol are rinmonolaurat, Triglycerinmonocaprylat, Triglycerinmonocaprat, triglycerol, Tetragly- cerinmonocaprylat, rinmonocaprat Tetraglycerinmonocaprat, Tetraglycerinmonolaurat, Pentaglycerinmonocapry- lat, Pentaglycerinmonocaprat, Pentaglycerinmonolaurat, Hexaglycerinmonocaprylat, Hexaglyce-, hexa glycerol, Hexaglycerinmonomyristat, Hexaglycerinmonostearat, Decaglycerinmonocaprylat, Decaglycerinmonocaprat, decaglyceryl monolaurate, monomyristate Decaglycerin-, laurate Decaglycerinmonoisostearat, decaglycerol monostearate, Decaglycerinmonooleat, Decaglycerinmonohydroxystearat, Decaglycerindicaprylat, Decaglycerindicaprat, Decaglycerindi-, Decaglycerindimyristat, Decaglycerindiisostearat, Decaglycerindistearat, Decaglycerindi- oleate, trilaurate Decaglycerindihydroxystearat, Decaglycerintricaprylat, Decaglycerintricaprat, Decaglycerin-, Decaglycerintrimyristat, Decaglycerintriisostearat, Decaglycerintrist earat, decaglycerol tri oleate and decaglycerol trihydroxystearate.
Besonders bevorzugte erfindungsgemäße Antitranspirant-Zusammensetzungen enthalten 5 - 97 Gew.-% freies Wasser, mindestens einen Antitranspirant-Wirkstoff und/oder mindestens einen Deodorant-Wrkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, sowie mindestens einen nichtionischen ÖI-in-Wasser-Emulgator in einer Gesamtmenge von 0,1 - 10 Gew.-%, besonders bevorzugt 0,5 - 4 Gew.-% und außerordentlich bevorzugt 1 - 3 Gew.-%, jeweils bezogen auf die treibmittelfreie Zusammensetzung. Particularly preferred antiperspirant compositions according to the invention comprise from 5 to 97% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of from 0.1 to 50% by weight, and at least one nonionic oil. in-water emulsifier in a total amount of 0.1-10% by weight, especially preferably 0.5 to 4 wt .-% and most preferably 1 to 3 wt .-%, each based on the propellant-free composition.
Wasser-in-ÖI-Emulgatoren  Water-in-oil emulsifiers
Erfindungsgemäß bevorzugte Zusammensetzungen, die als Emulsion, insbesondere als Wasserin-Öl-Emulsion, formuliert sind, enthalten mindestens einen Wasser-in-ÖI-Emulgator mit einem HLB-Wert größer 1 ,0 und kleiner/gleich 7,0, bevorzugt mindestens einen nichtionischen Wasser- in-ÖI-Emulgator mit einem HLB-Wert größer 1 ,0 und < 7,0.  Compositions which are preferred according to the invention and which are formulated as an emulsion, in particular as a water-in-oil emulsion, comprise at least one water-in-oil emulsifier having an HLB value of greater than 1.0, and less than or equal to 7.0, preferably at least one nonionic Water-in-oil emulsifier with an HLB value greater than 1, 0 and <7.0.
Erfindungsgemäß kann es bevorzugt sein, nur einen einzigen Wasser-in-ÖI-Emulgator einzusetzen. In einer anderen bevorzugten Ausführungsform enthalten die erfindungsgemäßen Zusammensetzungen Mischungen, insbesondere technische Mischungen, von mindestens zwei Wasser-in-ÖI-Emulgatoren.  According to the invention, it may be preferable to use only a single water-in-oil emulsifier. In another preferred embodiment, the compositions according to the invention comprise mixtures, in particular technical mixtures, of at least two water-in-oil emulsifiers.
Einige dieser geeigneten Emulgatoren sind beispielsweise in Kirk-Othmer, "Encyclopedia of Chemical Technology", 3. Aufl., 1979, Band 8, Seite 913, aufgelistet. Für ethoxylierte Addukte lässt sich der HLB-Wert, wie bereits erwähnt, auch berechnen.  Some of these suitable emulsifiers are listed, for example, in Kirk-Othmer, "Encyclopedia of Chemical Technology", 3rd Ed., 1979, Vol. 8, page 913. For ethoxylated adducts, the HLB value, as already mentioned, can also be calculated.
Bevorzugte Wasser-in-ÖI-Emulgatoren mit einem HLB-Wert größer 1 ,0 und < 7,0 sind ausgewählt aus den Mono- und Diestern von Ethylenglycol und den Mono-, Di-, Tri- und Tetraestern von Pentaerythrit mit linearen gesättigten Fettsäuren mit 12 - 30, insbesondere 14 - 22 Kohlenstoffatomen, die hydroxyliert sein können, sowie Mischungen hiervon. Erfindungsgemäß bevorzugt sind die Mono- und Diester. Erfindungsgemäß bevorzugte C 2-C30-Fettsäurereste sind ausgewählt aus Laurinsäure-, Myristinsäure-, Palmitinsäure-, Stearinsäure-, Arachinsäure- und Behensäure-Resten; besonders bevorzugt ist der Stearinsäurerest. Erfindungsgemäß besonders bevorzugte nichtionische Wasser-in-ÖI-Emulgatoren mit einem HLB-Wert größer 1 ,0 und < 7,0 sind ausgewählt aus Pentaerythritylmonostearat, Pentaerythrityldistearat, Pentaerythrityltristearat, Pentaerythrityltetrastearat, Ethylenglycolmonostearat, Ethylenglycoldistearat sowie Mischungen hiervon. Erfindungsgemäß besonders bevorzugte Wasser-in-ÖI-Emulgatoren mit einem HLB-Wert größer 1 ,0 und < 7,0 sind zum Beispiel als Handelsprodukte Cutina® PES (INCI: Pentaerythrityl distearate), Cutina® AGS (INCI: Glycol distearate) oder Cutina® EGMS (INCI: Glycol stearate) erhältlich. Diese Handelsprodukte stellen bereits Mischungen aus Mono- und Diestern (bei den Pentaerythritylestern sind auch Tri- und Tetraester enthalten) dar. Unter einer technischen Mischung wird beispielsweise ein Handelsprodukt wie Cutina® PES verstanden. Preferred water-in-oil emulsifiers with an HLB value greater than 1.0, and <7.0 are selected from the mono- and diesters of ethylene glycol and the mono-, di-, tri- and tetra-esters of pentaerythritol with linear saturated fatty acids with 12-30, in particular 14-22, carbon atoms which may be hydroxylated, as well as mixtures thereof. According to the invention, the mono- and diesters are preferred. C 2 -C 30 fatty acid radicals preferred according to the invention are selected from lauric acid, myristic acid, palmitic acid, stearic acid, arachic acid and behenic acid radicals; particularly preferred is the stearic acid residue. Particularly preferred nonionic water-in-oil emulsifiers according to the invention having an HLB value greater than 1.0, and <7.0 are selected from pentaerythrityl monostearate, pentaerythrityl distearate, pentaerythrityl tristearate, pentaerythrityl tetrastearate, ethylene glycol monostearate, ethylene glycol distearate, and mixtures thereof. According to the invention, particularly preferred water-in-oil emulsifiers having an HLB value greater than 1, 0 and <7.0 are, for example, as commercial products Cutina ® PES (INCI: Pentaerythrityl distearate), Cutina ® AGS (INCI: Glycol distearate) or Cutina ® EGMS (INCI: Glycol stearate) available. These commercial products are already mixtures of mono- and diesters (in the pentaerythrityl esters are also tri- and tetraesters contain). Under a technical mixture, for example, a commercial product such as Cutina ® understood PES.
Weitere bevorzugte Wasser-in-ÖI-Emulgatoren sind: Other preferred water-in-oil emulsifiers are:
lineare gesättigte Alkanole mit 12 - 30 Kohlenstoffatomen, insbesondere mit 16 - 22 Kohlenstoffatomen, insbesondere Cetylalkohol, Stearylalkohol, Arachidylalkohol, Behenylalkohol und Lanolinalkohol oder Gemische dieser Alkohole, wie sie bei der technischen Hydrierung von pflanzlichen und tierischen Fettsäuren erhältlich sind, Ester und insbesondere Partialester aus einem Polyol mit 3 - 6 C-Atomen und linearen gesättigten und ungesättigten Fettsäuren mit 12 - 30, insbesondere 14 - 22 C-Atomen, die hydroxyliert sein können. Solche Ester oder Partialester sind z. B. die Mono- und Diester von Glycerin oder die Monoester von Propylenglycol mit linearen gesättigten und ungesättigten C12 - C30-Carbonsäuren, die hydroxyliert sein können, insbesondere diejenigen mit Palmitin- und Stearinsäure, die Sorbitanmono-, -di- oder -triester von linearen gesättigten und ungesättigten C 2 - C30-Carbonsäuren, die hydroxyliert sein können, insbesondere diejenigen von Myristinsäure, Palmitinsäure, Stearinsäure oder von Mischungen dieser Fettsäuren und die Methylglucosemono- und -diester von linearen gesättigten und ungesättigten C 2 - C30- Carbonsäuren, die hydroxyliert sein können; linear saturated alkanols having 12-30 carbon atoms, in particular having 16-22 carbon atoms, in particular cetyl alcohol, stearyl alcohol, arachidyl alcohol, behenyl alcohol and lanolin alcohol or mixtures of these alcohols, as obtainable in the industrial hydrogenation of vegetable and animal fatty acids, Esters and in particular partial esters of a polyol having 3 to 6 C atoms and linear saturated and unsaturated fatty acids having 12 to 30, in particular 14 to 22, C atoms which may be hydroxylated. Such esters or partial esters are, for. The monoesters and diesters of glycerine or the monoesters of propylene glycol with linear saturated and unsaturated C 12 -C 30 carboxylic acids which may be hydroxylated, especially those with palmitic and stearic acid, the sorbitan mono-, di- or triesters of linear saturated and unsaturated C 2 - C 30 carboxylic acids, which may be hydroxylated, especially those of myristic acid, palmitic acid, stearic acid or of mixtures of these fatty acids and the monoesters and diesters of Methylglucosemono- linear saturated and unsaturated C 2 - C 30 - carboxylic acids, which may be hydroxylated;
Sterine, also Steroide, die am C3-Atom des Steroid-Gerüstes eine Hydroxylgruppe tragen und sowohl aus tierischem Gewebe (Zoosterine, z. B. Cholesterin, Lanosterin) wie auch aus Pflanzen (Phytosterine, z. B. Ergosterin, Stigmasterin, Sitosterin) und aus Pilzen und Hefen (Mykosterine) isoliert werden und die niedrig ethoxyliert (1 - 5 EO) sein können;  Sterols, ie steroids which carry a hydroxyl group at the C3 atom of the steroid skeleton and both from animal tissue (zoosterols, eg cholesterol, lanosterol) as well as from plants (phytosterols, eg ergosterol, stigmasterol, sitosterol) and from fungi and yeasts (mycosterols) which may be low ethoxylated (1-5 EO);
Alkanole und Carbonsäuren mit jeweils 8 - 24 C-Atomen, insbesondere mit 16 - 22 C- Atomen, in der Alkylgruppe und 1 - 4 Ethylenoxid-Einheiten pro Molekül, die einen HLB-Wert größer 1 ,0 und kleiner/gleich 7,0 aufweisen,  Alkanols and carboxylic acids each having 8-24 C atoms, in particular having 16-22 C atoms, in the alkyl group and 1-4 ethylene oxide units per molecule which have an HLB value of greater than 1.0, and less than or equal to 7.0 exhibit,
Glycerinmonoether gesättigter und/oder ungesättigter, verzweigter und/oder unverzweigter Alkohole einer Kettenlänge von 8 - 30, insbesondere 12 - 18 Kohlenstoffatomen.  Glycerol monoethers of saturated and / or unsaturated, branched and / or unbranched alcohols of a chain length of 8-30, in particular 12-18 carbon atoms.
Partialester von Polyglycerinen mit n = 2 bis 10 Glycerineinheiten und mit 1 bis 5 gesättigten oder ungesättigten, linearen oder verzweigten, gegebenenfalls hydroxylierten C8 - C30-Fett- säureresten verestert, sofern sie einen HLB-Wert von kleiner/gleich 7 aufweisen, Partial esters of polyglycerols with n = 2 to 10 glycerol units and with 1 to 5 saturated or unsaturated, linear or branched, optionally hydroxylated C 8 - C 30 fatty acid residues esterified, if they have an HLB value of less than or equal to 7,
sowie Mischungen der vorgenannten Substanzen.  and mixtures of the aforementioned substances.
Besonders vorteilhaft einsetzbare Wasser-in-ÖI-Emulgatoren sind Stearylalkohol, Cetylalkohol, Glycerylmonostearat, Glyceryldistearat, Glycerylmonocaprinat, Glycerylmonocaprylat, Glyceryl- monolaurat, Glycerylmonomyristat, Glycerylmonopalmitat, Glycerylmonohydroxystearat, Glyce- rylmonooleat, Glycerylmonolanolat, Glyceryldimyristat, Glyceryldipalmitat, Glyceryldioleat, Propy- lenglycolmonostearat, Propylenglycolmonolaurat, Sorbitanmonocaprylat, Sorbitanmonolaurat, Sorbitanmonomyristat, Sorbitanmonopalmitat, Sorbitanmonostearat, Sorbitansesquistearat, Sorbi- tandistearat, Sorbitandioleat, Sorbitansesquioleat, Saccharosedistearat, Arachidylalkohol, Behe- nylalkohol, Polyethylenglycol(2)stearylether (Steareth-2), Steareth-5, Oleth-2, Diglycerinmono- stearat, Diglycerinmonoisostearat, Diglycerinmonooleat, Diglycerindihydroxystearat, Diglycerindi- stearat, Diglycerindioleat, Triglycerindistearat, Tetraglycerinmonostearat, Tetraglycerindistearat, Tetraglycerintristearat, Decaglycerinpentastearat, Decaglycerinpentahydroxystearat, Decaglyce- rinpentaisostearat, Decaglycerinpentaoleat, Soy Sterol, PEG-1 Soy Sterol, PEG-5 Soy Sterol, PEG-2-monolaurat und PEG-2-monostearat. Particularly advantageously usable water-in-oil emulsifiers are stearyl alcohol, cetyl alcohol, glyceryl monostearate, glyceryl Glycerylmonocaprinat, glyceryl, glyceryl monolaurate, glyceryl monomyristate rylmonooleat, glyceryl, Glycerylmonohydroxystearat, glycerol, lenglycolmonostearat Glycerylmonolanolat, Glyceryldimyristat, Glyceryldipalmitat, glyceryl, propylene, propylene glycol , Sorbitan monocaprylate, sorbitan monolaurate, sorbitan monomyristate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquistearate, sorbitan tandearate, sorbitan dioleate, sorbitan sesquioleate, sucrose distearate, arachidyl alcohol, behenyl alcohol, polyethylene glycol (2) stearyl ether (steareth-2), steareth-5, oleth-2, diglycerol mono- stearate, diglycerol monoisostearate, diglycerol monooleate, diglycerol dihydroxystearate, diglycerol stearate, diglycerol dioleate, triglycerol distearate, tetraglycerol monostearate, tetraglycerol distearate, tetraglycerol tristearate, decaglycerin pentaste arat, decaglycerin pentahydroxystearate, Decaglyce rinpentaisostearat, decaglycerol pentaoleate, soy sterol, PEG-1 soy sterol, PEG-5 soy sterol, PEG-2 monolaurate and PEG-2 monostearate.
Weitere erfindungsgemäß bevorzugte W/O-Emulgatoren sind Silicon-freie polymere Wasser-in- Öl-Emulgatoren, insbesondere PEG-30 Dipolyhydroxystearat, erhältlich z. B. unter dem Handelsnamen Arlacel P 135 von Uniqema. Insbesondere mit Hilfe dieses Emulgators lassen sich niedrigviskose, sprühbare Wasser-in-ÖI-Emulsionen formulieren.  Further inventively preferred W / O emulsifiers are silicone-free polymeric water-in-oil emulsifiers, in particular PEG-30 dipolyhydroxystearate, available for. B. under the trade name Arlacel P 135 from Uniqema. In particular, with the help of this emulsifier can be formulated low viscosity, sprayable water-in-oil emulsions.
Besonders bevorzugte erfindungsgemäße Deodorant- oder Antitranspirant-Zusammensetzungen enthalten 5 - 97 Gew.-% freies Wasser, mindestens einen Antitranspirant-Wirkstoff und/oder mindestens einen Deodorant-Wrkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, und mindestens einen Silicon-freien Wasser-in-ÖI-Emulgator (= Tensid) in einer Gesamtmenge von 0,1 - 15 Gew.-%, bevorzugt 0,5 - 8,0 Gew.-%, und besonders bevorzugt 1 - 4 Gew.-%, jeweils bezogen auf die treibmittelfreie Zusammensetzung. Weiterhin können Gesamtmengen an mindestens einem Silicon-freien Wasser-in-ÖI-Emulgator von 2 - 3 - 3,5 Gew.-%, bezogen auf das Gesamtgewicht der treibmittelfreien Zusammensetzung, erfindungsgemäß außerordentlich bevorzugt sein.  Particularly preferred deodorant or antiperspirant compositions according to the invention contain from 5 to 97% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of from 0.1 to 50% by weight, and at least one Silicone-free water-in-oil emulsifier (= surfactant) in a total amount of 0.1-15 wt .-%, preferably 0.5 to 8.0 wt .-%, and particularly preferably 1 - 4 wt. %, in each case based on the propellant-free composition. Furthermore, total amounts of at least one silicone-free water-in-oil emulsifier of from 2 to 3 to 3.5% by weight, based on the total weight of the blowing agent-free composition, may be extraordinarily preferred according to the invention.
Weitere bevorzugte erfindungsgemäße Deodorant- oder Antitranspirant-Zusammensetzungen enthalten 5 - 97 Gew.-% freies Wasser, 0,1 - 30 Gew.-% mindestens eines Tensids, mindestens einen Antitranspirant-Wirkstoff und/oder mindestens einen Deodorant-Wrkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, jeweils bezogen auf die treibmittelfreie Zusammensetzung, und weiterhin mindestens ein Polysaccharid.  Further preferred deodorant or antiperspirant compositions according to the invention contain from 5 to 97% by weight of free water, from 0.1 to 30% by weight of at least one surfactant, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1-50 wt .-%, each based on the propellant-free composition, and further at least one polysaccharide.
Weitere bevorzugte erfindungsgemäße Antitranspirant-Zusammensetzungen sind als Öl-in-Was- ser-Emulsion, die keine Mikroemulsion darstellt, konfektioniert und enthalten 0,5 - 6,5 Gew.-% Öl- oder Fettphase, umfassend mindestens eine bei 20 °C flüssige Olkomponente, ausgewählt aus linearen und verzweigten gesättigten ein- oder mehrwertigen C3 - C30-Alkanolen, die mit mindestens einer Propylenoxid-Einheit pro Molekül verethert sind, Propylenglycolmonoestern von verzweigten gesättigten C6 - C30-Alkancarbonsäuren und verzweigten gesättigten C 0 - C30-Alkano- len, weiterhin mindestens 60 - 97 Gew.-% freies Wasser, sowie mindestens einen Antitranspi- rant-Wrkstoff. Further preferred antiperspirant compositions according to the invention are packaged as an oil-in-water emulsion which is not a microemulsion and comprise 0.5-6.5% by weight of oil or fat phase comprising at least one liquid which is liquid at 20 ° C. An oil component selected from linear and branched saturated mono- or polyhydric C 3 -C 30 -alkanols etherified with at least one propylene oxide unit per molecule, propylene glycol monoesters of branched saturated C 6 -C 30 -alkanecarboxylic acids and branched saturated C 0 -C 30 -Alkano- len, further at least 60 - 97 wt .-% free water, and at least one antiperspirant Wrkstoff.
Polysaccharide (Glycane, Polyglycane) ist die Sammelbezeichnung für makromolekulare Kohlenhydrate, deren Moleküle aus einer großen Zahl (mindestens >10, gewöhnlich jedoch erheblich mehr) glycosidisch miteinander verknüpfter Monosaccharid-Moleküle (Glycosen) bestehen.  Polysaccharides (glycans, polyglycans) is the collective term for macromolecular carbohydrates whose molecules consist of a large number (at least> 10, but usually significantly more) of glycosidically linked monosaccharide molecules (glycoses).
Zu den erfindungsgemäß bevorzugten Polysacchariden gehören vor allem die Biopolymere Stärke, Cellulose und Dextran, die als Polykondensationsprodukt der D-Glucose aufgefasst werden können (Polyglucosane, Glucane), Inulin als Polykondensat der D-Fructose (Polyfructo- san, Fructan), Chitin und Alginsäure. Unter erfindungsgemäß geeigneten Polysacchariden werden sowohl nicht-modifizierte Polysaccharide, wie beispielsweise Xanthan oder Stärke, als auch chemisch modifizierte Polysaccharid- Derivate, wie beispielsweise Aluminiumstärkeoctenylsuccinat, Hydroxypropylmethylcellulose oder dehydratisiertes Xanthan (INCI: Dehydroxanthan Gum), als auch physikalisch modifizierte Polysaccharide, beispielsweise eine durch thermische Behandlung vorverkleisterte Stärke, verstanden. The preferred polysaccharides according to the invention include, in particular, the biopolymers starch, cellulose and dextran, which can be regarded as the polycondensation product of D-glucose (polyglucosans, glucans), inulin as polycondensate of D-fructose (polyfructosan, fructan), chitin and alginic acid , In accordance with the invention suitable polysaccharides are both non-modified polysaccharides, such as xanthan or starch, and chemically modified polysaccharide derivatives, such as Aluminiumstärkeoctenylsuccinat, hydroxypropylmethylcellulose or dehydrated xanthan (INCI: dehydroxanthan gum), as well as physically modified polysaccharides, for example by thermal Treatment pregelatinized starch, understood.
Erfindungsgemäß bevorzugte Polysaccharide sind ausgewählt aus Stärken, insbesondere aus Mais, Kartoffeln und Weizen, deren Bestandteilen wie Amylose und Amylopektin, Stärkehydroly- saten und Stärkeabbauprodukten, wie Maltodextrin, den physikalisch oder chemisch modifizierten Stärkederivaten, insbesondere den anionischen Stärkederivaten Aluminiumstärkeoctenylsuccinat, Natriumstärkeoctenylsuccinat, Calciumstärkeoctenylsuccinat, Distärkephosphaten, Hydroxyethyl- stärkephosphaten, Hydroxypropylstärkephosphaten, Natriumcarboxymethylstärken und Natrium- stärkeglycolat, Cellulose, den chemisch modifizierten Cellulosederivaten Methylcellulose, Hydro- xypropylcellulose, Hydroxyethylcellulose, Hydroxypropylmethylcellulose, Hydroxypropylethylcellu- lose, Hydroxyethylmethylcellulose und Carboxymethylcellulose. Polysaccharide, die Gums oder Gummen bilden, wie beispielsweise Guar-Gum, Xanthan-Gum, Dehydroxanthan Gum, Alginate, insbesondere Natriumalginat, Gummi arabicum, Karaya-Gummi, Carrageenane, Johannisbrotkernmehl, Leinsamen-Gums und Agar-Agar, können ebenfalls enthalten sein, sind aber weniger bevorzugt. In einer besonders bevorzugten Ausführungsform sind die erfindungsgemäßen Zusammensetzungen frei von Polysaccharid-Gums. In einer weiteren besonders bevorzugten Ausführungsform sind die erfindungsgemäßen Zusammensetzungen frei von Guar-Gum, Xanthan-Gum, Dehydroxanthan Gum, Alginate, insbesondere Natriumalginat, Gummi arabicum, Karaya-Gummi, Carrageenane, Johannisbrotkernmehl, Leinsamen-Gums und Agar-Agar.  Preferred polysaccharides according to the invention are selected from starches, in particular from corn, potatoes and wheat, their constituents such as amylose and amylopectin, starch hydrolysates and starch degradation products, such as maltodextrin, the physically or chemically modified starch derivatives, in particular the anionic starch derivatives Aluminiumstärkeoctenylsuccinat, Natriumstärkeoctenylsuccinat, Calciumstärkeoctenylsuccinat, Distärkephosphaten , Hydroxyethyl starch phosphates, hydroxypropyl starch phosphates, sodium carboxymethyl starches and sodium starch glycolate, cellulose, the chemically modified cellulose derivatives methylcellulose, hydroxypropylcellulose, hydroxyethylcellulose, hydroxypropylmethylcellulose, hydroxypropylethylcellulose, hydroxyethylmethylcellulose and carboxymethylcellulose. Polysaccharides that form gums or gums, such as guar gum, xanthan gum, dehydroxanthan gum, alginates, especially sodium alginate, gum arabic, karaya gum, carrageenans, locust bean gum, linseed gums, and agar-agar, may also be included. but are less preferred. In a particularly preferred embodiment, the compositions according to the invention are free of polysaccharide gums. In a further particularly preferred embodiment, the compositions according to the invention are free of guar gum, xanthan gum, dehydroxanthan gum, alginates, in particular sodium alginate, gum arabic, karaya gum, carrageenans, locust bean gum, linseed gums and agar agar.
Besonders bevorzugte erfindungsgemäße Antitranspirant-Zusammensetzungen, insbesondere solche in Form von ÖI-in-Wasser-Emulsionen, sind dadurch gekennzeichnet, dass das mindestens eine Polysaccharid ausgewählt ist aus anionischen und nichtionischen Polysacchariden sowie Mischungen hiervon. Particularly preferred antiperspirant compositions according to the invention, in particular those in the form of oil-in-water emulsions, are characterized in that the at least one polysaccharide is selected from anionic and nonionic polysaccharides and mixtures thereof.
Weitere besonders bevorzugte erfindungsgemäße Antitranspirant-Zusammensetzungen, insbesondere solche in Form von ÖI-in-Wasser-Emulsionen, sind dadurch gekennzeichnet, dass das mindestens eine Polysaccharid ausgewählt ist aus anionischen und nichtionischen Polysacchariden, die keine Polysaccharid-Gums bilden.  Further particularly preferred antiperspirant compositions according to the invention, in particular those in the form of oil-in-water emulsions, are characterized in that the at least one polysaccharide is selected from anionic and nonionic polysaccharides which do not form polysaccharide gums.
Weitere besonders bevorzugte erfindungsgemäße Antitranspirant-Zusammensetzungen, insbesondere solche in Form von ÖI-in-Wasser-Emulsionen, sind dadurch gekennzeichnet, dass das anionische Polysaccharid ausgewählt ist aus Aluminiumstärkeoctenylsuccinat, Natriumstärkeoctenylsuccinat, Calciumstärkeoctenylsuccinat, Distärkephosphaten, Hydroxyethylstärkephosphaten, Hydroxypropylstärkephosphaten, Natriumcarboxymethylstärken, Natriumstärkeglycolat sowie Mischungen hiervon. Ein erfindungsgemäß außerordentlich bevorzugtes anionisches Polysaccharid ist Aluminiumstärkeoctenylsuccinat. Further particularly preferred antiperspirant compositions according to the invention, in particular those in the form of oil-in-water emulsions, are characterized in that the anionic polysaccharide is selected from aluminum starch octenyl succinate, sodium starch octenyl succinate, calcium starch octenyl succinate, distarch phosphates, hydroxyethyl starch phosphates, hydroxypropyl starch phosphates, sodium carboxymethyl starches, sodium starch glycolate and Mixtures thereof. An anionic polysaccharide extraordinarily preferred according to the invention is aluminum starch octenylsuccinate.
Weitere besonders bevorzugte erfindungsgemäße Antitranspirant-Zusammensetzungen, insbesondere solche in Form von ÖI-in-Wasser-Emulsionen, sind dadurch gekennzeichnet, dass das nichtionische Polysaccharid ausgewählt ist aus Stärken, Stärkehydrolysaten, Cellulose, Methyl- cellulose, Hydroxypropylcellulose, Hydroxyethylcellulose, Hydroxypropylmethylcellulose, Hydroxy- propylethylcellulose, Hydroxyethylmethylcellulose sowie Mischungen hiervon.  Further particularly preferred antiperspirant compositions according to the invention, in particular those in the form of oil-in-water emulsions, are characterized in that the nonionic polysaccharide is selected from starches, starch hydrolysates, cellulose, methyl cellulose, hydroxypropyl cellulose, hydroxyethyl cellulose, hydroxypropylmethyl cellulose, hydroxypropyl cellulose propylethylcellulose, hydroxyethylmethylcellulose and mixtures thereof.
Weitere besonders bevorzugte erfindungsgemäße Antitranspirant-Zusammensetzungen, insbesondere solche in Form von ÖI-in-Wasser-Emulsionen, sind dadurch gekennzeichnet, dass das mindestens eine Polysaccharid in einer Gesamtmenge von 0,01 - 1 ,0 Gew.-%, bevorzugt 0,05 - 0,5 und besonders bevorzugt 0,09 - 0,2 Gew.-%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien Emulsion, enthalten ist. Further particularly preferred antiperspirant compositions according to the invention, in particular those in the form of oil-in-water emulsions, are characterized in that the at least one polysaccharide is present in a total amount of 0.01-1.0% by weight, preferably 0.05 - 0.5 and particularly preferably 0.09 - 0.2 wt .-%, each based on the total weight of the blowing agent-free emulsion is included.
Erfindungsgemäß bevorzugte Antitranspirant-Zusammensetzungen in Form von ÖI-in-Wasser- Emulsionen sind dadurch gekennzeichnet, dass das mindestens eine lineare oder verzweigte gesättigte ein- oder mehrwertige C3 - C30-Alkanol, das mit mindestens einer Propylenoxid-Einheit pro Molekül verethert ist, ausgewählt ist aus Anlagerungsprodukten von mindestens 6 Propylen- oxid-Einheiten pro Molekül an ein- oder mehrwertige C3.30-Alkanole, insbesondere an Butanol, Butandiol, Myristylalkohol und Stearylalkohol. Besonders bevorzugte derartige Verbindungen sind ausgewählt aus PPG-13-Butylether, PPG-14-Butylether, PPG-9-Butylether, PPG-10-Butandiol und PPG-15-Stearylether sowie Mischungen hiervon. Antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that the at least one linear or branched saturated mono- or polyhydric C 3 -C 30 -alkanol which has been etherified with at least one propylene oxide unit per molecule , is selected from adducts of at least 6 propylene oxide units per molecule of monovalent or polyvalent C 3 . 30 -alkanols, in particular butanol, butanediol, myristyl alcohol and stearyl alcohol. Particularly preferred such compounds are selected from PPG-13 butyl ether, PPG-14 butyl ether, PPG-9 butyl ether, PPG-10-butanediol and PPG-15 stearyl ether and mixtures thereof.
Weitere erfindungsgemäß bevorzugte Antitranspirant-Zusammensetzungen in Form von ÖI-in- Wasser-Emulsionen sind dadurch gekennzeichnet, dass der mindestens eine Propylenglycol- monoester von verzweigten gesättigten C6 - C30-Alkancarbonsäuren ausgewählt ist aus Propylen- glycolmonoisostearat, Propylenglycolmonoisopalmitat, Propylenglycolmonoisobehenat, Propylen- glycolmonoisoarachinat, Propylenglycolmonoisomyristat, Propylenglycolmonoisocaprat, Propylen- glycolmonoisocaprinat und Propylenglycolmonoisocaprylat sowie Mischungen hiervon. Weitere erfindungsgemäß bevorzugte Antitranspirant-Zusammensetzungen in Form von ÖI-in-Wasser- Emulsionen sind dadurch gekennzeichnet, dass das mindestens eine verzweigte gesättigte C10 - C30-Alkanol ausgewählt ist aus Isostearylalkohol, Isocetylalkohol, Isomyristylalkohol, Isotridecylalkohol, Isoarachidylalkohol, Isobehenylalkohol, Isocaprylalkohol, Isocaprinylalkohol, Isocaprylylalkohol, sowie Mischungen hiervon. Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that the at least one propylene glycol monoester of branched saturated C 6 -C 30 -alkanecarboxylic acids is selected from propylene glycol monoisostearate, propylene glycol monoisopalmitate, propylene glycol monoisobehenate, propylene glycol glycol monoisoarachinate, propylene glycol monoisomyristate, propylene glycol monoisocaprate, propylene glycol monoisocaprate and propylene glycol monoisocaprylate, and mixtures thereof. Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that the at least one branched saturated C 10 -C 30 -alkanol is selected from isostearyl alcohol, isocetyl alcohol, isomyristyl alcohol, isotridecyl alcohol, isoarachidyl alcohol, isobehenyl alcohol, isocapryl alcohol, Isocaprinyl alcohol, isocaprylyl alcohol, and mixtures thereof.
Weitere erfindungsgemäß bevorzugte Antitranspirant-Zusammensetzungen in Form von ÖI-in- Wasser-Emulsionen sind dadurch gekennzeichnet, dass mindestens ein nichtionischer Emulgator mit einem HLB-Wert im Bereich von 3 - 6 enthalten ist. Besonders bevorzugt ist der mindestens eine nichtionische Emulgator mit einem HLB-Wert im Bereich von 3 - 6 ausgewählt aus linearen gesättigten und ungesättigten C 2 - C30-Alkanolen, die mit 1 - 4 Ethylenoxid-Einheiten pro Molekül verethert sind, welche außerordentlich bevorzugt sind aus Steareth, Ceteth, Myristeth, Laureth, Trideceth, Arachideth und Beheneth mit jeweils 1 - 4 Ethylenoxid-Einheiten pro Molekül, insbesondere Steareth-2, Steareth-3, Steareth-4, Ceteth-2, Ceteth-3, Ceteth-4, Myristeth-2, Myristeth- 3, Myristeth-4, Laureth-2, Laureth-3, Laureth-4, Trideceth-2, Trideceth-3 und Trideceth-4 sowie Mischungen hiervon. Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range from 3 to 6 is present. Particularly preferred is the at least one nonionic emulsifier having an HLB value in the range 3-6 selected from linear saturated and unsaturated C 2 - C 30 alkanols containing 1-4 ethylene oxide units per molecule which are highly preferred are steareth, ceteth, myristeth, laureth, trideceth, arachideth and beheneth each having 1-4 ethylene oxide units per molecule, especially steareth-2, steareth-3, steareth-4, ceteth-2, ceteth 3, ceteth-4, myristeth-2, myristeth-3, myristeth-4, laureth-2, laureth-3, laureth-4, trideceth-2, trideceth-3 and trideceth-4 and mixtures thereof.
Weitere erfindungsgemäß bevorzugte Antitranspirant-Zusammensetzungen in Form von Öl-inWasser-Emulsionen sind dadurch gekennzeichnet, dass mindestens ein nichtionischer Emulgator mit einem HLB-Wert im Bereich von 3 - 6 in einer Gesamtmenge von 1 ,8 - 3 Gew.-%, bezogen auf das Gesamtgewicht der erfindungsgemäßen Zusammensetzung, enthalten ist. Weitere erfindungsgemäß bevorzugte Antitranspirant-Zusammensetzungen in Form von ÖI-in-Wasser-Emul- sionen sind dadurch gekennzeichnet, dass mindestens ein nichtionischer Emulgator mit einem HLB-Wert im Bereich von 3 - 6, ausgewählt aus Steareth-2, Steareth-3, Steareth-4, Ceteth-2, Ceteth-3, Ceteth-4, Myristeth-2, Myristeth-3, Myristeth-4, Laureth-2, Laureth-3, Laureth-4, Trideceth-2, Trideceth-3 und Trideceth-4 sowie Mischungen hiervon, in einer Gesamtmenge von 1 ,8 - 3 Gew.-%, bezogen auf das Gesamtgewicht der treibmitelfreien erfindungsgemäßen Zusammensetzung, enthalten ist.  Further inventively preferred antiperspirant compositions in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range of 3-6 in a total amount of 1, 8 to 3 wt .-%, based on the total weight of the composition of the invention is included. Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range from 3 to 6, selected from steareth-2, steareth-3, steareth -4, ceteth-2, ceteth-3, ceteth-4, myristeth-2, myristeth-3, myristeth-4, laureth-2, laureth-3, laureth-4, trideceth-2, trideceth-3 and trideceth-4 and mixtures thereof, in a total amount of 1, 8 - 3 wt .-%, based on the total weight of the propellant-free composition according to the invention is contained.
Weitere erfindungsgemäß bevorzugte Antitranspirant-Zusammensetzungen in Form von Öl-inWasser-Emulsionen sind dadurch gekennzeichnet, dass mindestens ein nichtionischer Emulgator mit einem HLB-Wert im Bereich von 12 - 18 enthalten ist. Weitere erfindungsgemäß bevorzugte Antitranspirant-Zusammensetzungen in Form von ÖI-in-Wasser-Emulsionen sind dadurch gekennzeichnet, dass der mindestens eine nichtionische Emulgator mit einem HLB-Wert im Bereich von 12 - 18 ausgewählt ist aus linearen gesättigten und ungesättigten C 2 - C24-Alkanolen, die mit 7 - 40 Ethylenoxid-Einheiten pro Molekül verethert sind. Besonders bevorzugt sind die vorgenannten Emulgatoren ausgewählt aus Steareth, Ceteth, Myristeth, Laureth, Trideceth, Arachideth und Beheneth mit jeweils 7 - 40 Ethylenoxid-Einheiten pro Molekül, insbesondere Steareth-10, Steareth-20, Steareth-21 , Steareth-30, Steareth-40, Ceteth-10, Ceteth-20, Ceteth-21 , Ceteth-30, Ceteth-40, Laureth-10, Laureth-20, Laureth-30, Trideceth-10, Trideceth-20 und Trideceth-30 sowie Mischungen hiervon. Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range from 12 to 18 is contained. Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that the at least one nonionic emulsifier having an HLB value in the range of 12-18 is selected from linear saturated and unsaturated C 2 -C 24 - Alkanols etherified with 7 to 40 ethylene oxide units per molecule. The aforementioned emulsifiers are particularly preferably selected from steareth, ceteth, myristeth, laureth, trideceth, arachideth and beheneth, each having 7 to 40 ethylene oxide units per molecule, in particular steareth-10, steareth-20, steareth-21, steareth-30, steareth -40, ceteth-10, ceteth-20, ceteth-21, ceteth-30, ceteth-40, laureth-10, laureth-20, laureth-30, trideceth-10, trideceth-20 and trideceth-30 and mixtures thereof.
Weitere erfindungsgemäß bevorzugte Antitranspirant-Zusammensetzungen in Form von Öl-inWasser-Emulsionen sind dadurch gekennzeichnet, dass mindestens ein nichtionischer Emulgator mit einem HLB-Wert im Bereich von 12 - 18, der bevorzugt ausgewählt ist aus Steareth-10, Steareth-20, Steareth-21 , Steareth-30, Steareth-40, Ceteth-10, Ceteth-20, Ceteth-21 , Ceteth-30, Ceteth-40, Laureth-10, Laureth-20, Laureth-30, Trideceth-10, Trideceth-20 und Trideceth-30 sowie Mischungen hiervon, in einer Gesamtmenge von 1 - 2 Gew.-% enthalten ist, bezogen auf das Gesamtgewicht der erfindungsgemäßen Zusammensetzung. Weitere erfindungsgemäß bevorzugte Antitranspirant-Zusammensetzungen in Form von Öl-inWasser-Emulsionen sind dadurch gekennzeichnet, dass mindestens ein nichtionischer Emulgator mit einem HLB-Wert im Bereich von 3 - 6 und mindestens ein nichtionischer Emulgator mit einem HLB-Wert im Bereich von 12 - 18 enthalten sind. Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range of 12-18, which is preferably selected from steareth-10, steareth-20, steareth- 21, steareth-30, steareth-40, ceteth-10, ceteth-20, ceteth-21, ceteth-30, ceteth-40, laureth-10, laureth-20, laureth-30, trideceth-10, trideceth-20 and Trideceth-30 and mixtures thereof, in a total amount of 1 - 2 wt .-%, based on the total weight of the composition according to the invention. Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range from 3 to 6 and at least one nonionic emulsifier having an HLB value in the range from 12 to 18 are included.
Weitere erfindungsgemäß bevorzugte Antitranspirant-Zusammensetzungen in Form von Öl-inWasser-Emulsionen sind dadurch gekennzeichnet, dass mindestens ein nichtionischer Emulgator mit einem HLB-Wert im Bereich von 3 - 6 in einer Gesamtmenge von 1 ,8 - 3 Gew.-% und mindestens ein nichtionischer Emulgator mit einem HLB-Wert im Bereich von 12 - 18 in einer Gesamtmenge von 1 - 2 Gew.-%, enthalten sind, wobei die Mengenangaben jeweils auf das Gesamtgewicht der erfindungsgemäßen Zusammensetzung bezogen sind.  Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that at least one nonionic emulsifier having an HLB value in the range from 3 to 6 in a total amount of 1.8 to 3% by weight and at least one nonionic emulsifier having an HLB value in the range of 12-18 in a total amount of 1 - 2 wt .-%, wherein the amounts are in each case based on the total weight of the composition according to the invention.
Weitere erfindungsgemäß bevorzugte Antitranspirant-Zusammensetzungen in Form von Öl-inWasser-Emulsionen sind dadurch gekennzeichnet, dass als nichtionischer Emulgator mit einem HLB-Wert im Bereich von 3 - 6 Steareth-2 und gleichzeitig als nichtionischer Emulgator mit einem HLB-Wert im Bereich von 12 - 18 Steareth-21 enthalten ist. Further preferred antiperspirant compositions according to the invention in the form of oil-in-water emulsions are characterized in that they have a nonionic emulsifier with an HLB value in the range of 3 to 6 steareth-2 and simultaneously as a nonionic emulsifier with an HLB value in the range of 12 - 18 steareth-21 is included.
Weitere erfindungsgemäß bevorzugte Deodorant- oder Antitranspirant-Zusammensetzungen in Form von ÖI-in-Wasser-Emulsionen sind dadurch gekennzeichnet, dass Steareth-2, Steareth-21 und PPG-15-Stearylether enthalten sind.  Further inventively preferred deodorant or antiperspirant compositions in the form of oil-in-water emulsions are characterized in that steareth-2, steareth-21 and PPG-15 stearyl ether are included.
Weitere erfindungsgemäß bevorzugte Deodorant- oder Antitranspirant-Zusammensetzungen in Form von ÖI-in-Wasser-Emulsionen sind dadurch gekennzeichnet, dass mindestens ein Polysaccharid, ausgewählt aus Aluminiumstärkeoctenylsuccinat und Distärkephosphaten, enthalten ist. Weitere erfindungsgemäß bevorzugte Deodorant- oder Antitranspirant-Zusammensetzungen in Form von ÖI-in-Wasser-Emulsionen sind dadurch gekennzeichnet, dass Steareth-2, Steareth- 21 , PPG-15-Stearylether und Aluminiumstärkeoctenylsuccinat enthalten sind.  Further inventively preferred deodorant or antiperspirant compositions in the form of oil-in-water emulsions are characterized in that at least one polysaccharide selected from aluminum starch octenyl succinate and distarch phosphates is contained. Further inventively preferred deodorant or antiperspirant compositions in the form of oil-in-water emulsions are characterized in that steareth-2, steareth-21, PPG-15-stearyl ether and Aluminiumstärkeoctenylsuccinat are included.
Weitere erfindungsgemäß bevorzugte Deodorant- oder Antitranspirant-Zusammensetzungen in Form von ÖI-in-Wasser-Emulsionen sind dadurch gekennzeichnet, dass das Gewichtsverhältnis von nichtionischen Emulgatoren mit einem HLB-Wert im Bereich von 3 - 6 und nichtionischen Emulgatoren mit einem HLB-Wert im Bereich von 12 - 18 von 0,9 bis 3, bevorzugt 1 ,3 - 1 ,9 beträgt. Weitere erfindungsgemäß bevorzugte Deodorant- oder Antitranspirant-Zusammensetzun- gen in Form von ÖI-in-Wasser-Emulsionen sind dadurch gekennzeichnet, dass insgesamt maximal 3 Gew.-%, bevorzugt maximal 1 Gew.-% und besonders bevorzugt 0 Gew.-%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien erfindungsgemäßen Zusammensetzung, an einwertigen - C3-Alkanolen, wie Ethanol oder Isopropanol, enthalten ist. Further inventively preferred deodorant or antiperspirant compositions in the form of oil-in-water emulsions are characterized in that the weight ratio of nonionic emulsifiers having an HLB value in the range of 3-6 and nonionic emulsifiers having an HLB value in the range from 12 to 18 from 0.9 to 3, preferably 1, 3 to 1, 9. Further inventively preferred deodorant or antiperspirant compositions in the form of oil-in-water emulsions are characterized in that a total of at most 3% by weight, preferably at most 1% by weight and particularly preferably 0% by weight, in each case based on the total weight of the propellant-free composition according to the invention, of monohydric - C 3 -alkanols, such as ethanol or isopropanol.
Weitere erfindungsgemäß bevorzugte Zusammensetzungen, die als Wasser-in-ÖI-Emulsion konfektioniert sind, enthalten mindestens einen Wasser-in-ÖI-Emulgator auf Siliconbasis. Bevorzugte erfindungsgemäße Deodorant- oder Antitranspirant-Zusammensetzungen enthalten 5 - 97 Gew.- % freies Wasser, mindestens einen Antitranspirant-Wrkstoff und/oder mindestens einen Deodo- rant-Wirkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-% und mindestens einen Wasser-in-ÖI- Emulgator auf Siliconbasis (= Tensid) in einer Gesamtmenge von 0,1 - 5 Gew.-%, besonders bevorzugt 0,5 - 3,5 Gew.-%, außerordentlich bevorzugt 1 ,0 - 3 Gew.-%, weiterhin außerordentlich bevorzugt 1 ,5 - 2,5 Gew.-%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien Emulsion. Further preferred compositions according to the invention, which are formulated as a water-in-oil emulsion, comprise at least one silicone-based water-in-oil emulsifier. Preferred deodorant or antiperspirant compositions according to the invention contain from 5 to 97% by weight of free water, at least one antiperspirant active substance and / or at least one deodo-antiperspirant. rant active ingredient in a total amount of 0.1-50% by weight and at least one water-in-oil emulsifier based on silicone (= surfactant) in a total amount of 0.1-5% by weight, particularly preferably 0, 5 to 3.5 wt .-%, exceptionally preferably 1, 0 to 3 wt .-%, furthermore very preferably 1, 5 to 2.5 wt .-%, each based on the total weight of the blowing agent-free emulsion.
Eine erfindungsgemäß besonders bevorzugte Gruppe von Wasser-in-ÖI-Emulgatoren auf Siliconbasis sind die Poly-(C2-C3)alkylenglycol-modifizierten Silicone, deren frühere INCI-Bezeichnung Dimethicone Copolyol lautete, mit den aktuellen INCI-Bezeichnungen PEG-x Dimethicone (mit x = 2 - 20, bevorzugt 3 - 17, besonders bevorzugt 1 1 - 12), Bis-PEG-y Dimethicone (mit y = 3 - 25, bevorzugt 4 - 20), PEG/PPG a/b Dimethicone (wobei a und b unabhängig voneinander für Zahlen von 2 - 30, bevorzugt 3 - 30 und besonders bevorzugt 12 - 20, insbesondere 14 - 18, stehen), Bis-PEG/PPG-c/d Dimethicone (wobei c und d unabhängig voneinander für Zahlen von 10 - 25, bevorzugt 14 - 20 und besonders bevorzugt 14 - 16, stehen) und Bis-PEG/PPG-e/f PEG/PPG g/h Dimethicone (wobei e, f, g und h unabhängig voneinander für Zahlen von 10 - 20, bevorzugt 14 - 18 und besonders bevorzugt 16, stehen). Besonders bevorzugt sind PEG/PPG-18/18 Dimethicone, das z. B. in einer 1 :9-Mischung mit Cyclomethicone unter der Bezeichnung Dow Corning 3225 C bzw. Dow Corning 5225 C im Handel erhältlich ist, PEG/PPG-18/18 Dimethicone, das z. B. in einer 1 :3-Mischung mit nicht-flüchtigem Dimethicone als Dow Corning ES 5227 DM Formula- tion Aid im Handel erhältlich ist, PEG/PPG-4/12 Dimethicone, das z. B. unter der Bezeichnung Abil B 8852 erhältlich ist, sowie Bis-PEG/PPG-14/14 Dimethicone, das z. B. in einer Mischung mit Cyclomethicone als Abil EM 97 (Evonik) im Handel erhältlich ist, Bis-PEG/PPG-20/20 Dimethicone, das z. B. unter der Bezeichnung Abil B 8832 erhältlich ist, PEG/PPG-5/3 Trisiloxane (z. B. Silsoft 305), sowie PEG/PPG-20/23 Dimethicone (z. B. Silsoft 430 und Silsoft 440). A particularly preferred group of silicone-based water-in-oil emulsifiers according to the invention are the poly (C 2 -C 3 ) alkylene glycol-modified silicones whose earlier INCI name was dimethicone copolyol, with the current INCI names PEG-x dimethicone (with x = 2-20, preferably 3-17, more preferably 1-1-12), bis-PEG-y dimethicone (with y = 3-25, preferably 4-20), PEG / PPG a / b dimethicone (where a and b independently of one another represent numbers from 2 to 30, preferably 3 to 30 and more preferably 12 to 20, in particular 14 to 18), bis-PEG / PPG-c / d dimethicones (where c and d independently of one another represent numbers 10-25, preferably 14-20 and more preferably 14-16) and bis-PEG / PPG-e / f PEG / PPG g / h dimethicone (where e, f, g and h independently represent numbers of 10 20, preferably 14-18 and more preferably 16). Particularly preferred are PEG / PPG-18/18 dimethicones, z. B. in a 1: 9 mixture with Cyclomethicone under the name Dow Corning 3225 C or Dow Corning 5225 C is commercially available, PEG / PPG-18/18 Dimethicone, the z. B. in a 1: 3 mixture with non-volatile dimethicone as Dow Corning ES 5227 DM formulation Aid commercially available, PEG / PPG-4/12 Dimethicone, the z. B. under the name Abil B 8852 is available, and bis-PEG / PPG-14/14 Dimethicone, the z. B. in a mixture with Cyclomethicone as Abil EM 97 (Evonik) is commercially available Bis-PEG / PPG-20/20 Dimethicone, the z. B. under the name Abil B 8832, PEG / PPG-5/3 trisiloxanes (eg Silsoft 305), and PEG / PPG-20/23 Dimethicone (eg Silsoft 430 and Silsoft 440).
Weitere erfindungsgemäß bevorzugte W/O-Emulgatoren auf Siliconbasis sind Poly-(C2-C3)alky- lenglycol-modifizierte Silicone, die mit C4-C 8-Alkylgruppen hydrophob modifiziert sind, besonders bevorzugt Cetyl PEG/PPG-10/1 Dimethicone (früher: Cetyl Dimethicone Copolyol, z. B. erhältlich als Abil EM 90 oder in einer Mischung aus Polyglyceryl-4-isostearat, Cetyl PEG/PPG-10/1 Dimethicone und Hexyllaurat unter der Handelsbezeichnung Abil WE 09), weiterhin Alkyl Methicone Copolyole und Alkyl Dimethicone Ethoxy Glucoside. Other silicone-based W / O emulsifiers which are preferred according to the invention are poly (C 2 -C 3 ) -alkylene glycol-modified silicones which are hydrophobically modified with C 4 -C 8 -alkyl groups, particularly preferably cetyl PEG / PPG-10/1 Dimethicone (formerly: Cetyl Dimethicone Copolyol, eg available as Abil EM 90 or in a mixture of polyglyceryl-4-isostearate, Cetyl PEG / PPG-10/1 dimethicone and hexyl laurate under the trade name Abil WE 09), furthermore alkyl methicone Copolyols and Alkyl Dimethicone Ethoxy Glucosides.
Besonders bevorzugte erfindungsgemäße Deodorant- oder Antitranspirant-Zusammensetzungen enthalten 5 - 97 Gew.-% freies Wasser, mindestens einen Antitranspirant-Wrkstoff und/oder mindestens einen Deodorant-Wrkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-% und den Silicon-basierten Wasser-in-ÖI-Emulgator PEG/PPG-18/18 Dimethicone in einer Gesamtmenge von 0,5 - 5 Gew.-%, besonders bevorzugt 1 ,0 - 3,5 Gew.-%, außerordentlich bevorzugt 1 ,5 - 3 Gew.-%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien Zusammensetzung. In der nachfolgenden Tabelle sind verschiedene ÖI-in-Wasser-Emulgatoren und Wasser-in-ÖI- Emulgatoren und ihre HLB-Werte zusammengestellt. Die HLB-Werte können aber auch nach Griffin berechnet werden, wie es beispielsweise im RÖMPP Chemie Lexikon, insbesondere in der Online-Version von November 2003, und den dort unter dem Stichwort„HLB-System" zitierten Handbüchern von Fiedler, Kirk-Othmer und Janistyn dargestellt beziehungsweise tabelliert ist. Sofern es in der Literatur unterschiedliche Angaben zum HLB-Wert einer Substanz gibt, sollte derjenige HLB-Wert für die erfindungsgemäße Lehre genutzt werden, der dem nach Griffin berechneten Wert am nächsten kommt. Falls sich auf diese Art und Weise kein eindeutiger HLB- Wert ermitteln lässt, ist der HLB-Wert, den der Hersteller des Emulgators angibt, für die erfindungsgemäße Lehre zu nutzen. Falls auch dies nicht möglich ist, ist der HLB-Wert experimentell zu ermitteln. Für die aus H. Janistyn, Handbuch der Kosmetika und Riechstoffe, Hüthig-Verlag Heidelberg, 3. Auflage, 1978, Band 1 , Seite 470 und Band 3, Seiten 68 - 78, zitierten HLB-Werte wird verwiesen auf das Prioritätsdokument zu dieser Anmeldung, DE102010055816.8, Seite 41 , Zeile 4 bis Seite 46, Zeile 12. Particularly preferred deodorant or antiperspirant compositions according to the invention comprise from 5 to 97% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of from 0.1 to 50% by weight and the silicone rubber. based water-in-oil emulsifier PEG / PPG-18/18 Dimethicone in a total amount of 0.5-5 wt .-%, particularly preferably 1, 0 - 3.5 wt .-%, most preferably 1, 5 - 3 wt .-%, each based on the total weight of the blowing agent-free composition. The following table summarizes various oil-in-water emulsifiers and water-in-oil emulsifiers and their HLB values. However, the HLB values can also be calculated according to Griffin, as described, for example, in the RÖMPP Chemie Lexikon, in particular in the online version of November 2003, and the manuals cited there under the heading "HLB system" by Fiedler, Kirk-Othmer and If there is different information on the HLB value of a substance in the literature, the HLB value for the teaching according to the invention which comes closest to the value calculated according to Griffin should be used can not determine a unique HLB value, the HLB value, which indicates the manufacturer of the emulsifier to use for the teaching of the invention.If this is not possible, the HLB value is determined experimentally for those from H. Janistyn , Handbook of cosmetics and fragrances, Hüthig-Verlag Heidelberg, 3rd edition, 1978, Volume 1, page 470 and Volume 3, pages 68-78, quoted HLB values is referenced the priority document of this application, DE102010055816.8, page 41, line 4 to page 46, line 12.
Weitere bevorzugte erfindungsgemäße Zusammensetzungen sind dadurch gekennzeichnet, dass der Gesamtgehalt an nichtionischen und ionischen Emulgatoren und/oder Tensiden mit einem HLB-Wert über 8 maximal 20 Gew.-%, bevorzugt maximal 15 Gew.-%, besonders bevorzugt maximal 10 Gew.-%, besonders bevorzugt maximal 7 Gew.-%, weiterhin besonders bevorzugt maximal 4 Gew.-% und außerordentlich bevorzugt maximal 3 Gew.-%, jeweils bezogen auf die gesamte erfindungsgemäße Zusammensetzung, beträgt.  Further preferred compositions according to the invention are characterized in that the total content of nonionic and ionic emulsifiers and / or surfactants with an HLB value above 8 not more than 20 wt .-%, preferably at most 15 wt .-%, particularly preferably at most 10 wt .-% , particularly preferably at most 7 wt .-%, more preferably at most 4 wt .-% and most preferably at most 3 wt .-%, each based on the total composition of the invention is.
Bevorzugte erfindungsgemäße Zusammensetzungen, die als Emulsion vorliegen, enthalten bevorzugt weiterhin mindestens ein bei 20 ° C flüssiges Öl, das keine Riechstoffkomponente und kein etherisches Öl darstellt. Phospholipide und Lecithine zählen erfindungsgemäß zu den Tensiden, nicht zu Ölen oder Wachsen.  Preferred compositions of the present invention, which are in the form of an emulsion, preferably further contain at least one oil which is liquid at 20 ° C. and which is not a fragrance component and does not represent an essential oil. Phospholipids and lecithins are according to the invention to the surfactants, not to oils or waxes.
Erfindungsgemäß bevorzugte kosmetische Öle sind ausgewählt aus Siliconölen, zu denen z. B. Dialkyl- und Alkylarylsiloxane, wie beispielsweise Cyclopentasiloxan, Cyclohexasiloxan, Dimethyl- polysiloxan und Methylphenylpolysiloxan, aber auch Hexamethyldisiloxan, Octamethyltrisiloxan und Decamethyltetrasiloxan zählen. Besonders bevorzugt sind flüchtige Siliconöle, die cyclisch sein können, wie z. B. Octamethylcyclotetrasiloxan, Decamethylcyclopentasiloxan und Dodeca- methylcyclohexasiloxan sowie Mischungen hiervon, wie sie z. B. in den Handelsprodukten DC 244, 245, 344 und 345 von Dow Corning enthalten sind. Ebenfalls besonders bevorzugt sind flüchtige lineare Siliconöle, insbesondere Hexamethyldisiloxan (L2), Octamethyltrisiloxan (L3), Decamethyltetrasiloxan (L4), Dodecamethylpentasiloxan (L5), sowie beliebige Zweier-, Dreier und Vierermischungen aus L2, L3, L4 und/oder L5, wie sie z. B. in den Handelsprodukten Dow Corning 2-1 184 Fluid, Dow Corning® 200 (0,65 cSt) und Dow Corning® 200 (1 ,5 cSt) von Dow Corning enthalten sind, wobei sich die Werte der kinematischen Viskosität auf eine Temperatur von 25°C beziehen. Cosmetic oils preferred according to the invention are selected from silicone oils, to which z. As dialkyl and alkylaryl, such as cyclopentasiloxane, cyclohexasiloxane, dimethylpolysiloxane and methylphenylpolysiloxane, but also hexamethyldisiloxane, octamethyltrisiloxane and decamethyltetrasiloxane include. Particularly preferred are volatile silicone oils, which may be cyclic, such as. For example, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane and dodecamethylcyclohexasiloxane and mixtures thereof, as described, for. B. in the commercial products DC 244, 245, 344 and 345 of Dow Corning. Also particularly preferred are volatile linear silicone oils, in particular hexamethyldisiloxane (L 2 ), octamethyltrisiloxane (L 3 ), decamethyltetrasiloxane (L 4 ), dodecamethylpentasiloxane (L 5 ), as well as any two, three and four mixtures of L 2 , L 3 , L 4 and / or L 5 , as z. Dow Corning® 200 (0.65 cSt) and Dow Corning® 200 (1.5 cSt) from Dow Corning contained, wherein the values of the kinematic viscosity relate to a temperature of 25 ° C.
In einer anderen bevorzugten Ausführungsform sind die erfindungsgemäßen Zusammensetzungen frei von Cyclomethicone.  In another preferred embodiment, the compositions of the invention are free of cyclomethicones.
Neben oder anstelle des mindestens einen flüchtigen Siliconöls kann auch mindestens ein flüchtiges Nichtsiliconöl enthalten sein. Bevorzugte flüchtige Nichtsiliconöle sind ausgewählt aus C8-C 6- Isoalkanen, insbesondere aus Isodecan, Isododecan, Isotetradecan und Isohexadecan sowie Mischungen hiervon. In addition to or instead of the at least one volatile silicone oil, it is also possible for at least one volatile non-silicone oil to be present. Preferred volatile non-silicone oils are selected from C 8 -C 6 -isoalkanes, in particular from isodecane, isododecane, isotetradecane and isohexadecane and mixtures thereof.
Neben den vorgenannten, üblicherweise als „flüchtigen" Siliconölen bezeichneten Substanzen sowie neben den vorgenannten flüchtigen Nichtsiliconölen können erfindungsgemäß besonders bevorzugte Zusammensetzungen weiterhin mindestens ein nichtflüchtiges kosmetisches Öl, ausgewählt aus nichtflüchtigen Siliconölen und nichtflüchtigen Nichtsiliconölen, enthalten.  In addition to the abovementioned substances, which are commonly referred to as "volatile" silicone oils, as well as the abovementioned volatile non-silicone oils, particularly preferred compositions according to the invention may further comprise at least one non-volatile cosmetic oil selected from non-volatile silicone oils and non-volatile non-silicone oils.
Bevorzugte nichtflüchtige Siliconöle sind ausgewählt aus höhermolekularen linearen Dimethyl- polysiloxanen, im Handel erhältlich z. B. unter der Bezeichnung Dow Corning® 190, Dow Corning® 200 Fluid mit kinematischen Viskositäten (25°C) im Bereich von 5 - 100 cSt, bevorzugt 5 - 50 cSt oder auch 5 - 10 cSt, und Baysilon® 350 M (mit einer kinematischen Viskosität (25°C) von etwa 350 cSt. Preferred nonvolatile silicone oils are selected from higher molecular weight linear dimethyl polysiloxanes, commercially available for. Example under the name Dow Corning ® 190, Dow Corning ® 200 fluid having kinematic viscosities (25 ° C) in the range from 5 to 100 cSt, preferably of 5 - 50 cSt or 5 - 10 cSt, and Baysilon ® 350 M (with a kinematic viscosity (25 ° C) of about 350 cSt.
Erfindungsgemäß ebenfalls bevorzugte nichtflüchtige Siliconöle sind ausgewählt aus Siliconen sgewählt ist aus ganzen Zahlen von 1 - 20, bevorzugt 1 - 3.  Nonvolatile silicone oils which are likewise preferred in accordance with the invention are selected from silicones selected from integers of 1 to 20, preferably 1 to 3.
SifCHa);SifCHa);
Figure imgf000045_0001
Figure imgf000045_0001
(Sil-1)  (Sil-1)
Ein bevorzugtes Siliconöl der Formel (Sil-1) ist erhältlich unter der INCI-Bezeichnung Phenyl Trimethicone.  A preferred silicone oil of formula (Sil-1) is available under the INCI name Phenyl Trimethicone.
Natürliche und synthetische Kohlenwasserstoffe, wie beispielsweise Paraffinöle, C 8-C30- Isoalkane, insbesondere Isoeicosan, Polyisobutene oder Polydecene, die beispielsweise unter der Bezeichnung Emery® 3004, 3006, 3010 oder unter der Bezeichnung Ethylflo® von Albemarle oder Nexbase® 2004G von Nestle erhältlich sind, sowie 1 ,3-Di-(2-ethylhexyl)-cyclohexan (erhältlich z. B. unter dem Handelsnamen Cetiol®S von BASF) gehören ebenfalls zu den erfindungsgemäß bevorzugten nichtflüchtigen Nichtsiliconölen. Weitere erfindungsgemäß bevorzugte nichtflüchtige Nichtsiliconöle sind ausgewählt aus den Benzoesäureestern von linearen oder verzweigten C8.22-Alkanolen. Besonders bevorzugt sind Benzoesäure-C12-C15-alkylester, z. B. erhältlich als Handelsprodukt Finsolv® TN, Benzoesäure- isostearylester, z. B. erhältlich als Handelsprodukt Finsolv® SB, Ethylhexylbenzoat, z. B. erhältlich als Handelsprodukt Finsolv® EB, und Benzoesäureoctyldocecylester, z. B. erhältlich als Handelsprodukt Finsolv® BOD. Derartige Benzoesäureesteröle weisen ein angenehmes Hautgefühl auf. Weitere erfindungsgemäß bevorzugte nichtflüchtige Nichtsiliconöle sind ausgewählt aus verzweigten gesättigten oder ungesättigten Fettalkoholen mit 6 - 30 Kohlenstoffatomen. Diese Alkohole werden häufig auch als Guerbet-Alkohole bezeichnet, da sie nach der Guerbet-Reaktion erhältlich sind. Bevorzugte Alkoholöle sind 2-Hexyldecanol, 2-Octyldodecanol und 2-Ethyl- hexylalkohol. Natural and synthetic hydrocarbons such as paraffin oils, C 8 -C 30 - isoalkanes, particularly isoeicosane, polyisobutenes or polydecenes, the ®, for example, under the designation Emery ® 3004, 3006, 3010 or under the name Ethylflo ® from Albemarle or Nexbase 2004G from Nestle are available, as well as 1, 3-di- (2-ethylhexyl) -cyclohexane (obtainable, for. example, under the trade name Cetiol ® S from BASF) also belong to the invention preferred non-volatile non-silicone oils. Further non-volatile non-silicone oils which are preferred according to the invention are selected from the benzoic acid esters of linear or branched C 8 . 22 -alkanols. Particularly preferred are benzoic C12-C15 alkyl esters, z. B. available as a commercial product Finsolv ® TN, benzoic isostearylester, z. B. available as a commercial product Finsolv ® SB, ethylhexyl benzoate, z. B. available as a commercial product Finsolv ® EB, and Benzoesäureoctyldocecylester, z. B. available as a commercial product Finsolv ® BOD. Such benzoic acid ester oils have a pleasant feel on the skin. Further non-volatile non-silicone oils which are preferred according to the invention are selected from branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms. These alcohols are also often referred to as Guerbet alcohols, as they are obtainable by the Guerbet reaction. Preferred alcohol oils are 2-hexyldecanol, 2-octyldodecanol and 2-ethylhexyl alcohol.
Weitere bevorzugte nichtflüchtige Nichtsiliconöle sind ausgewählt aus Mischungen aus Guerbet- alkoholen und Guerbetalkoholestern, z.B. 2-Hexyldecanol und 2-Hexyldecyllaurat.  Other preferred non-volatile non-silicone oils are selected from mixtures of Guerbet alcohols and Guerbet alcohol esters, e.g. 2-hexyldecanol and 2-hexyldecyl laurate.
Weitere erfindungsgemäß bevorzugte nichtflüchtige Nichtsiliconöle sind ausgewählt aus den Triglyceriden von linearen oder verzweigten, gesättigten oder ungesättigten, gegebenenfalls hydro- xylierten C8.30-Fettsäuren. Besonders geeignet kann die Verwendung natürlicher Öle, z.B. Sojaöl, Baumwollsaatöl, Sonnenblumenöl, Palmöl, Palmkernöl, Leinöl, Mandelöl, Rizinusöl, Maisöl, Rapsöl, Olivenöl, Sesamöl, Distelöl, Weizenkeimöl, Pfirsichkernöl und die flüssigen Anteile des Kokosöls und dergleichen sein. Geeignet sind aber auch synthetische Triglyceridöle, insbesondere Capric/Caprylic Triglycerides, mit unverzweigten Fettsäureresten sowie z. B. Glyceryltriisostearin mit verzweigten Fettsäureresten. Further non-volatile non-silicone oils which are preferred according to the invention are selected from the triglycerides of linear or branched, saturated or unsaturated, optionally hydroxylated C 8 . 30- fatty acids. Particularly suitable may be the use of natural oils, for example soybean oil, cottonseed oil, sunflower oil, palm oil, palm kernel oil, linseed oil, almond oil, castor oil, corn oil, rapeseed oil, olive oil, sesame oil, thistle oil, wheat germ oil, peach kernel oil and the liquid portions of coconut oil and the like. But are also synthetic triglyceride oils, in particular Capric / Caprylic triglycerides, with unbranched fatty acid residues and z. B. glyceryl triisostearin with branched fatty acid residues.
Weitere erfindungsgemäß besonders bevorzugte nichtflüchtige Nichtsiliconöle sind ausgewählt aus den Dicarbonsäureestern von linearen oder verzweigten C2-C 0-Alkanolen, insbesondere Diisopropyladipat, Di-n-butyladipat, Di-(2-ethylhexyl)adipat, Dioctyladipat, Diethyl-/Di-n-butyl/ Dioctylsebacat, Diisopropylsebacat, Dioctylmalat, Dioctylmaleat, Dicaprylylmaleat, Diisooctyl- succinat, Di-2-ethylhexylsuccinat und Di-(2-hexyldecyl)-succinat. Further non-volatile non-silicone oils which are particularly preferred according to the invention are selected from the dicarboxylic acid esters of linear or branched C 2 -C 0 -alkanols, in particular diisopropyl adipate, di-n-butyl adipate, di (2-ethylhexyl) adipate, dioctyl adipate, diethyl / di-n- butyl / dioctyl sebacate, diisopropyl sebacate, dioctyl malate, dioctyl maleate, dicaprylyl maleate, diisooctyl succinate, di-2-ethylhexyl succinate and di (2-hexyldecyl) succinate.
Weitere erfindungsgemäß besonders bevorzugte nichtflüchtige Nichtsiliconöle sind ausgewählt aus den Estern der linearen oder verzweigten gesättigten oder ungesättigten Fettalkohole mit 2 - 30 Kohlenstoffatomen mit linearen oder verzweigten gesättigten oder ungesättigten Fettsäuren mit 2 - 30 Kohlenstoffatomen, die hydroxyliert sein können. Dazu zählen 2-Hexyldecylstearat (z. B. Eutanol® G 16 S), Hexyldecyllaurat, Isodecylneopentanoat, Isononylisononanoat, 2-Ethylhexyl- palmitat und 2-Ethylhexylstearat, insbesondere 2-Ethylhexylpalmitat. Ebenfalls bevorzugt sind Isopropylmyristat, Isopropylpalmitat, Isopropylstearat, Isopropylisostearat, Isopropyloleat, Isooctyl- stearat, Isononylstearat, Isocetylstearat, Isononylisononanoat, Isotridecylisononanoat, Cetearyl- isononanoat, 2-Ethylhexyllaurat, 2-Ethylhexylisostearat, 2-Ethylhexylcocoat, 2-Octyldodecylpalmi- tat, Butyloctansäure-2-butyloctanoat, Diisotridecylacetat, n-Butylstearat, n-Hexyllaurat, n-Decyloleat, Oleyloleat, Oleylerucat, Erucyloleat, Erucylerucat, Ethylenglycoldioleat und Ethylen- glycoldipalmitat. Further non-volatile non-silicone oils which are particularly preferred according to the invention are selected from the esters of linear or branched saturated or unsaturated fatty alcohols having 2 to 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms which may be hydroxylated. These include 2-hexyldecyl stearate (z. B. Eutanol ® G 16 S), hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, and 2-ethylhexyl stearate, in particular 2-ethylhexyl palmitate. Also preferred are isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyldodecyl palmitate, butyloctanoic acid-2 butyloctanoate, diisotridecyl acetate, n-butyl stearate, n-hexyl laurate, n-decyl oleate, oleyl oleate, oleyl erucate, erucyl oleate, erucyl erucate, ethylene glycol dioleate and ethylene glycol dipalmitate.
Weitere erfindungsgemäß besonders bevorzugte nichtflüchtige Nichtsiliconöle sind ausgewählt aus den Anlagerungsprodukten von 1 bis 5 Propylenoxid-Einheiten an ein- oder mehrwertige C8_22-Alkanole wie Octanol, Decanol, Decandiol, Laurylalkohol, Myristylalkohol und Stearylalkohol, z. B. PPG-2-Myristylether und PPG-3-Myristylether (z. B. Wtconol® APM). Further inventively particularly preferred non-volatile non-silicone oils are selected from the addition products of 1 to 5 propylene oxide units of mono- or polyhydric C 8 _ 22 alkanols such as octanol, decanol, decanediol, lauryl alcohol, myristyl alcohol and stearyl alcohol, eg. B. PPG-2 myristyl ether and PPG-3 myristyl ether (z. B. Wtconol ® APM).
Weitere erfindungsgemäß besonders bevorzugte nichtflüchtige Nichtsiliconöle sind ausgewählt aus den Anlagerungsprodukten von mindestens 6 Ethylenoxid- und/oder Propylenoxid-Einheiten an ein- oder mehrwertige C3.22-Alkanole wie Glycerin, Butanol, Butandiol, Myristylalkohol und Stearylalkohol, die gewünschtenfalls verestert sein können, z. B. PPG-14-Butylether (z. B. Ucon Fluid® AP), PPG-9-Butylether (z. B. Breox® B25), PPG-10-Butandiol (z. B. Macol® 57), PPG-15- Stearylether (z. B. Arlamol® E) und Glycereth-7-diisononanoat. Further non-volatile non-silicone oils which are particularly preferred according to the invention are selected from the adducts of at least 6 ethylene oxide and / or propylene oxide units with monovalent or polyvalent C 3 . 22 -alkanols such as glycerol, butanol, butanediol, myristyl alcohol and stearyl alcohol, which may be esterified if desired, for. As PPG-14 butyl ether (z. B. Ucon ® fluid AP), PPG-9-butyl ether (z. B. Breox B25 ®), PPG-10 butanediol (z. B. Macol ® 57), PPG 15- stearyl ether (z. B. Arlamol ® e), and Glycereth-7-diisononanoate.
Weitere erfindungsgemäß besonders bevorzugte nichtflüchtige Nichtsiliconöle sind ausgewählt aus den C2-C22-Fettalkoholestern einwertiger oder mehrwertiger C2-C7-Hydroxycarbonsäuren, insbesondere die Ester der Glycolsäure, Milchsäure, Äpfelsäure, Weinsäure, Citronensäure und Salicylsäure. Solche Ester auf Basis von linearen C 2/ 5-Alkanolen und von in 2-Position verzweigten C 2/ 3-Alkanolen sind bevorzugt ausgewählt aus C 2.C 5-Alkyllactat, Di-C12-13-Alkylmalat und Tri-C12-13 Alkylcitrat, z. B. erhältlich unter dem Warenzeichen Cosmacol® von der Firma Nordmann, Rassmann GmbH & Co, Hamburg. Eine weitere derart bevorzugte Ölkomponente ist Triethylcitrat. Further non-volatile non-silicone oils which are particularly preferred according to the invention are selected from the C 2 -C 22 fatty alcohol esters of monohydric or polyhydric C 2 -C 7 hydroxycarboxylic acids, in particular the esters of glycolic acid, lactic acid, malic acid, tartaric acid, citric acid and salicylic acid. Such esters based on linear C 2/5 alkanols and in the 2-position branched C 2/3 of alkanols are preferably selected from C 2 .C 5 alkyl lactate, di-C12-13-Alkylmalat and tri-C12-13 Alkyl citrate, e.g. B. available under the trademark Cosmacol ® from Nordmann, Rassmann GmbH & Co, Hamburg. Another such preferred oil component is triethyl citrate.
Weitere erfindungsgemäß besonders bevorzugte nichtflüchtige Nichtsiliconöle sind ausgewählt aus den symmetrischen, unsymmetrischen oder cyclischen Estern der Kohlensäure mit Fettalkoholen, z. B. Dicaprylylcarbonat oder die Ester gemäß der Lehre der DE 19756454 A1 .  Further inventively particularly preferred non-volatile non-silicone oils are selected from the symmetrical, asymmetrical or cyclic esters of carbonic acid with fatty alcohols, eg. B. dicaprylyl or the esters according to the teaching of DE 19756454 A1.
Weitere Öle, die erfindungsgemäß bevorzugt sein können, sind ausgewählt aus den Estern von Dimeren ungesättigter C 2-C22-Fettsäuren (Dimerfettsäuren) mit einwertigen linearen, verzweigten oder cyclischen C2-C 8-Alkanolen oder mit mehrwertigen linearen oder verzweigten C2-C6-Alka- nolen. Further oils which may be preferred according to the invention are selected from the esters of dimers of unsaturated C 2 -C 22 -fatty acids (dimer fatty acids) with monovalent linear, branched or cyclic C 2 -C 8 -alkanols or with polyvalent linear or branched C 2 - C 6 -alkanols.
Es kann erfindungsgemäß bevorzugt sein, Mischungen der vorgenannten Öle einzusetzen.  It may be preferred according to the invention to use mixtures of the aforementioned oils.
Bevorzugte erfindungsgemäße Zusammensetzungen sind dadurch gekennzeichnet, dass das unter Normalbedingungen flüssige Konditioniermittel ausgewählt ist flüchtigen Siliconölen, nichtflüchtigen Siliconölen, flüchtigen Kohlenwasserstoffölen, verzweigten gesättigten oder ungesättigten Fettalkoholen mit 6 - 30 Kohlenstoffatomen, Triglyceriden von linearen oder verzweigten, gesättigten oder ungesättigten, gegebenenfalls hydroxylierten C8.30-Fettsäuren, Dicarbonsäure- estern von linearen oder verzweigten C2-C 0-Alkanolen, Estern von verzweigten gesättigten oder ungesättigten Fettalkoholen mit 2 - 30 Kohlenstoffatomen mit linearen oder verzweigten gesättigten oder ungesättigten Fettsäuren mit 2 - 30 Kohlenstoffatomen, die hydroxyliert sein können, Anlagerungsprodukten von 1 bis 5 Propylenoxid-Einheiten an ein- oder mehrwertige C8_22-Alka- nole, Anlagerungsprodukten von mindestens 6 Ethylenoxid und/oder Propylenoxid-Einheiten an ein- oder mehrwertige C3.22-Alkanole, C8-C22-Fettalkoholestern einwertiger oder mehrwertiger C2-C7-Hydroxycarbonsäuren, symmetrischen, unsymmetrischen oder cyclischen Estern der Kohlensäure mit Fettalkoholen, den Estern von Dimeren ungesättigter C 2-C22-Fettsäuren (Dimer- fettsäuren) mit einwertigen linearen, verzweigten oder cyclischen C2-C 8-Alkanolen oder mit mehrwertigen linearen oder verzweigten C2-C6-Alkanolen, sowie Mischungen der vorgenannten Substanzen. Es kann erfindungsgemäß außerordentlich bevorzugt sein, Mischungen der vorgenannten Öle einzusetzen, um eine optimale Feinabstimmung der Produkteigenschaften, insbesondere des Hautgefühls, der Wirkstofffreisetzung oder, gegebenenfalls, der Schaumeigenschaften, zu erzielen. Preferred compositions according to the invention are characterized in that the conditional liquid conditioner is selected from volatile silicone oils, nonvolatile silicone oils, volatile hydrocarbon oils, branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms, triglycerides of linear or branched, saturated or unsaturated, optionally hydroxylated C 8 . 30 -fatty acids, dicarboxylic acid esters of linear or branched C 2 -C 0 -alkanols, esters of branched saturated or unsaturated fatty alcohols having 2 to 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms, which may be hydroxylated, Addition products of 1 to 5 propylene oxide units of mono- or polyhydric C 8 _ 22 -alkanols, addition products of at least 6 ethylene oxide and / or propylene oxide units to mono- or polyvalent C 3 . 2 2-alkanols, C 8 -C 22 fatty alcohol esters of monohydric or polyhydric C 2 -C 7 hydroxycarboxylic acids, symmetrical, asymmetrical or cyclic esters of carbonic acid with fatty alcohols, the esters of dimers of unsaturated C 2 -C 22 fatty acids (dimer fatty acids ) with monovalent linear, branched or cyclic C 2 -C 8 -alkanols or with polyvalent linear or branched C 2 -C 6 -alkanols, and mixtures of the abovementioned substances. It may be extraordinarily preferred according to the invention to use mixtures of the abovementioned oils in order to achieve optimum fine-tuning of the product properties, in particular skin feel, release of the active ingredient or, if appropriate, foaming properties.
Bevorzugte erfindungsgemäße Zusammensetzungen enthalten mindestens ein Öl in einer Gesamtmenge von 0,1 bis 35 Gew.-%, bevorzugt 0,5 - 25 Gew.-%, besonders bevorzugt 1 - 15 Gew.-% und außerordentlich bevorzugt 2 - 8 Gew.-%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien erfindungsgemäßen Zusammensetzung.  Preferred compositions according to the invention contain at least one oil in a total amount of from 0.1 to 35% by weight, preferably from 0.5 to 25% by weight, more preferably from 1 to 15% by weight and most preferably from 2 to 8% by weight. %, in each case based on the total weight of the propellant-free composition according to the invention.
Neben den Ölen, das heißt, den Substanzen, die unter Normalbedingungen flüssig vorliegen, können auch bei Normalbedingungen fest vorliegende Wachskomponenten verwendet werden. Besonders bevorzugte Wachskomponenten sind ausgewählt aus Kokosfettsäureglycerinmono-, - di- und -triestern, Butyrospermum Parkii (Shea Butter) und Estern von gesättigten, einwertigen C8-C 8-Alkoholen mit gesättigten C 2-C 8-Monocarbonsäuren sowie Mischungen dieser Substanzen, enthalten ist. Weitere bevorzugte Ester von gesättigten, einwertigen C 2-C 8- Alkoholen mit gesättigten C 2-C 8-Monocarbonsäuren sind Stearyllaurat, Cetearylstearat, Cetylpalmitat und Myristylmyristat. Erfindungsgemäß bevorzugte Konditioniermittel sind weiterhin pflanzliche Wachse, z. B. Candelillawachs, Carnaubawachs, Japanwachs, Zuckerrohrwachs, Ouricourywachs, Korkwachs, Sonnenblumenwachs, Fruchtwachse wie Orangenwachse, Zitronenwachse, Grapefruitwachs, und tierische Wachse, z. B. Bienenwachs, Schellackwachs und Walrat, hydrierte oder gehärtete Wachse, chemisch modifizierte Wachse, insbesondere die Hartwachse, wie z. B. Montanesterwachse, hydrierte Jojobawachse und Sasolwachse, Polyalky- lenwachse und Polyethylenglycolwachse, C2o-C4o-Dialkylester von Dimersäuren, C30-50- Alkyl- bienenwachs sowie Alkyl- und Alkylarylester von Dimerfettsäuren. Eine besonders bevorzugte Wachskomponente ist ausgewählt aus mindestens einem Ester aus einem gesättigten, einwertigen C 6-C60-Alkohol und einer gesättigten C8-C36-Monocarbonsäure. Erfindungsgemäß zählen hierzu auch Lactide, die cyclischen Doppelester von alpha-Hydroxycarbonsäuren der entsprechenden Kettenlänge. Weitere bevorzugte Wachskomponenten sind die Triglyceride gesättigter und gegebenenfalls hydroxylierter C 2.30-Fettsäuren, wie gehärtete Triglyceridfette (hydriertes Palmöl, hydriertes Kokosöl, hydriertes Rizinusöl), Glyceryltribehenat (Tribehenin) oder Glyceryltri- 12-hydroxystearat, weiterhin synthetische Vollester aus Fettsäuren und Glycolen oder Polyolen mit 2 - 6 Kohlenstoffatomen. Erfindungsgemäß ist als Wachskomponente hydriertes Rizinusöl besonders bevorzugt. Weitere bevorzugte Wachskomponenten sind die gesättigten linearen C 4 - C36-Fettalkohole, insbesondere Myristylalkohol, Palmitylalkohol, Cetylalkohol, Stearylalkohol, Arachidylalkohol und Behenylalkohol, sowie Mischungen dieser Verbindungen. In addition to the oils, that is, the substances which are liquid under normal conditions, solid wax components can be used even under normal conditions. Particularly preferred wax components are selected from coconut fatty acid glycerol mono-, di- and triesters, Butyrospermum Parkii (shea butter) and esters of saturated, monohydric C 8 -C 8 alcohols with saturated C 2 -C 8 monocarboxylic acids and mixtures of these substances is. Further preferred esters of saturated monohydric C 2 -C 8 alcohols with saturated C 2 -C 8 monocarboxylic acids are stearyl laurate, cetearyl stearate, cetyl palmitate and myristyl myristate. Conditioning agents which are preferred according to the invention are also vegetable waxes, eg. Candelilla wax, carnauba wax, Japan wax, sugarcane wax, ouricoury wax, cork wax, sunflower wax, fruit waxes such as orange waxes, lemon waxes, grapefruit wax, and animal waxes, e.g. As beeswax, shellac wax and spermaceti, hydrogenated or hardened waxes, chemically modified waxes, especially the hard waxes, such as. Montan ester waxes, hydrogenated jojoba waxes and sasol waxes, polyalkylene waxes and polyethylene glycol waxes, C 2 o-C 40 dialkyl esters of dimer acids, C 30-50 alkyl beeswax and alkyl and alkylaryl esters of dimer fatty acids. A particularly preferred wax component is selected from at least one ester of a saturated, monohydric C 6 -C 60 -alcohol and a saturated C 8 -C 36 -monocarboxylic acid. For this purpose also include lactides, the cyclic double esters of alpha-hydroxycarboxylic acids of the corresponding chain length. Further preferred wax components are the triglycerides of saturated and optionally hydroxylated C 2 . 30 fatty acids, such as hardened triglyceride fats (hydrogenated palm oil, hydrogenated coconut oil, hydrogenated castor oil), glyceryl tribehenate (tribehenin) or glyceryl trihydrate 12-hydroxystearate, furthermore synthetic full esters of fatty acids and glycols or polyols having 2 to 6 carbon atoms. According to the invention, hydrogenated castor oil is particularly preferred as the wax component. Further preferred wax components are the saturated linear C 4 -C 36 -fatty alcohols, in particular myristyl alcohol, palmityl alcohol, cetyl alcohol, stearyl alcohol, arachidyl alcohol and behenyl alcohol, and also mixtures of these compounds.
Bevorzugte erfindungsgemäße Zusammensetzungen enthalten mindestens eine Wachskomponente in einer Gesamtmenge von 0,1 bis 5 Gew.-%, bevorzugt 0,2 - 4 Gew.-%, besonders bevorzugt 0,5 - 3 Gew.-% und außerordentlich bevorzugt 1 - 2 Gew.-%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien erfindungsgemäßen Zusammensetzung. Preferred compositions according to the invention comprise at least one wax component in a total amount of from 0.1 to 5% by weight, preferably 0.2 to 4% by weight, more preferably 0.5 to 3% by weight and most preferably 1 to 2% by weight .-%, in each case based on the total weight of the blowing agent-free composition according to the invention.
Besonders bevorzugte erfindungsgemäße Deodorant- oder Antitranspirant-Zusammensetzungen sind dadurch gekennzeichnet, dass das/die bei 20 °C flüssige/n Öl/e in einer Gesamtmenge von 0,1 - 80 Gew.-%, bevorzugt 2 - 20 Gew.-%, besonders bevorzugt 3 - 15 Gew.-%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien Zusammensetzung, enthalten ist/sind. In einer weiteren bevorzugten Ausführungsform der Erfindung weist ein Anteil der Ölkomponenten von mindestens 80 Gew.-% einen Brechungsindex nD von 1 ,39 - 1 ,51 auf. Besonders bevorzugt ist es, wenn 5 - 40 - 50 Gew.-%, außerordentlich bevorzugt 10 - 12 - 25 - 30 Gew.-% der Ölkomponenten einen Brechungsindex nD von 1 ,43 - 1 ,58, bevorzugt 1 ,44 - 1 ,51 , besonders bevorzugt 1 ,45 - 1 ,47 - 1 ,49, bei 20 °C (gemessen bei λ = 589 nm) aufweisen. Particularly preferred deodorant or antiperspirant compositions according to the invention are characterized in that the oil (s) liquid at 20 ° C. in a total amount of 0.1-80% by weight, preferably 2-20% by weight, particularly preferably 3-15% by weight, in each case based on the total weight of the blowing agent-free composition, is / are contained. In a further preferred embodiment of the invention, a proportion of the oil components of at least 80 wt .-%, a refractive index n D of 1, 39 - 1, 51 on. It is particularly preferred if 5 - 40 - 50 wt .-%, most preferably 10 - 12 - 25 - 30 wt .-% of the oil components have a refractive index n D of 1, 43 - 1, 58, preferably 1, 44 - 1 , 51, more preferably 1, 45 - 1, 47 - 1, 49, at 20 ° C (measured at λ = 589 nm) have.
Weitere besonders bevorzugte erfindungsgemäße Deodorant- oder Antitranspirant-Zusammen- setzungen liegen als Wasser-in-ÖI-Emulsion vor und enthalten 5 - 97 Gew.-% freies Wasser, 0,1 - 30 Gew.-% Tensid, darunter mindestens ein Wasser-in-ÖI-Emulgator, insbesondere ein Siliconbasierter Wasser-in-ÖI-Emulgator, mindestens einen Antitranspirant-Wirkstoff und/oder mindestens einen Deodorant-Wrkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, und 1 - 40 Gew.-% mindestens eines kosmetischen Öls, wobei die Mengenangaben jeweils auf das Gesamtgewicht der treibmittelfreien Antitranspirant-Zusammensetzung bezogen sind, und sind mit £-CF3CH=CHF als Treibmittel in einer Aerosol-Abgabevorrichtung verpackt. Further particularly preferred deodorant or antiperspirant compositions according to the invention are in the form of a water-in-oil emulsion and contain from 5 to 97% by weight of free water, from 0.1 to 30% by weight of surfactant, including at least one water in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1-50 wt.%, and 1-40 wt. % of at least one cosmetic oil, the amounts of each being based on the total weight of the antiperspirant propellant-free composition, and are packaged with £ -CF 3 CH = CHF as propellant in an aerosol dispenser.
Überraschend wurde festgestellt, dass erfindungsgemäße Wasser-in-ÖI-Emulsionen eine besonders hohe Temperaturstabilität aufweisen. Weiterhin wurde festgestellt, dass derartige erfindungsgemäß bevorzugte Wasser-in-ÖI-Emulsionen, die mit £-CF3CH=CHF als Treibmittel in einer Aerosol-Abgabevorrichtung verpackt sind, eine besonders geringe Korrosivität aufweisen. Surprisingly, it has been found that water-in-oil emulsions according to the invention have a particularly high temperature stability. Furthermore, it has been found that such water-in-oil emulsions preferred according to the invention, which are packaged with ε-CF 3 CH = CHF as propellant in an aerosol dispenser, have a particularly low corrosivity.
Wasser-in-ÖI-Emulsionssprays enthalten aufgrund gesetzlicher Vorschriften keine Zirconium-hal- tigen Salze. Die vorstehend beschriebenen Zirconium-freien Antitranspirant-Wirkstoffe sind auch für erfindungsgemäße Wasser-in-ÖI-Emulsionssprays geeignet. Bevorzugte erfindungsgemäße Zusammensetzungen, die als Wasser-in-ÖI-Emulsionsspray konfektioniert sind, enthalten mindestens ein Zirconium-freies Aluminiumsalz als Antitranspirant-Wrkstoff in einer Gesamtmenge von 5 - 40 Gew.-%, bevorzugt 10 - 35 Gew.-% und besonders bevorzugt 15 - 28 Gew.-% und außer- ordentlich bevorzugt 23 - 27 Gew.-%, jeweils bezogen auf das Gesamtgewicht der kristallwasserfreien Aktivsubstanz (USP) in der treibmittelfreien Zusammensetzung. Water-in-oil emulsion sprays contain no zirconium-containing salts due to regulatory requirements. The zirconium-free antiperspirant active compounds described above are also suitable for water-in-oil emulsion sprays according to the invention. Preferred compositions according to the invention, which are formulated as a water-in-oil emulsion spray, comprise at least one zirconium-free aluminum salt as antiperspirant active in a total amount of 5-40% by weight, preferably 10-35% by weight and more preferably 15-28% by weight and exceptionally neat preferably 23-27% by weight, in each case based on the total weight of the water-free active substance (USP) in the blowing agent-free composition.
Bevorzugte erfindungsgemäße Zusammensetzungen, die als Wasser-in-ÖI-Emulsionsspray konfektioniert sind, enthalten freies Wasser in einer Gesamtmenge von 10 - 85 Gew.-%, bevorzugt 15 - 75 Gew.-%, besonders bevorzugt 20 - 65 Gew.-%, außerordentlich bevorzugt 25 - 55 Gew.- %, weiterhin außerordentlich bevorzugt 30 - 40 Gew.-%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien Zusammensetzung.  Preferred compositions according to the invention, which are formulated as a water-in-oil emulsion spray, comprise free water in a total amount of 10 to 85% by weight, preferably 15 to 75% by weight, particularly preferably 20 to 65% by weight, extraordinarily preferably 25-55% by weight, furthermore very preferably 30-40% by weight, in each case based on the total weight of the blowing agent-free composition.
Die äußere Phase erfindungsgemäß bevorzugter Wasser-in-ÖI-Emulsionen umfasst mindestens ein kosmetisches Öl. Öle, die als Bestandteil erfindungsgemäß bevorzugter Wasser-in-ÖI-Emulsionen bevorzugt sind, sind bereits vorstehend aufgeführt. Erfindungsgemäß bevorzugte Wasserin-Öl-Emulsionen enthalten 10 - 85 Gew.-% freies Wasser, mindestens einen Antitranspirant- Wrkstoff und/oder mindestens einen Deodorant-Wrkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, 0,1 - 30 Gew.-% Tensid, darunter mindestens einen Wasser-in-ÖI-Emulgator, insbesondere einen Silicon-basierten Wasser-in-ÖI-Emulgator, und 1 - 40 Gew.-% mindestens eines kosmetischen Öls, ausgewählt aus verzweigten gesättigten oder ungesättigten Fettalkoholen mit 6 - 30 Kohlenstoffatomen, Dicarbonsäureestern von linearen oder verzweigten C2-C 0-Alkanolen, Anlagerungsprodukten von 1 bis 5 Propylenoxid-Einheiten an ein- oder mehrwertige C8_22-Alka- nole, Anlagerungsprodukten von mindestens 6 Ethylenoxid und/oder Propylenoxid-Einheiten an ein- oder mehrwertige C3.22-Alkanole, Estern der linearen oder verzweigten gesättigten oder ungesättigten Fettalkohole mit 2 - 30 Kohlenstoffatomen mit linearen oder verzweigten gesättigten oder ungesättigten Fettsäuren mit 2 - 30 Kohlenstoffatomen, die hydroxyliert sein können, Dicaprylylcarbonat, Octamethylcyclotetrasiloxan, Decamethylcyclopentasiloxan, Dodecamethyl- cyclohexasiloxan, Hexamethyldisiloxan (L2), Octamethyltrisiloxan (L3), Decamethyltetrasiloxan (L4), Dodecamethylpentasiloxan (L5), sowie beliebigen Zweier-, Dreier und Vierermischungen aus L2, l_3, l_4 und/oder L5, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5 - 100 cSt, wobei sich die Werte der kinematischen Viskosität auf eine Temperatur von 25°C beziehen, C8-C 6-lsoalkanen, C 0-C 3-Isoalkanen, Isohexadecan, Isoeicosan, Polyisobutenen, hydrierten Polyisobutenen und Polydecenen, sowie Mischungen der vorgenannten Öle, wobei die Mengenangaben jeweils auf das Gesamtgewicht der treibmittelfreien Zusammensetzung bezogen sind. The outer phase of preferred water-in-oil emulsions according to the invention comprises at least one cosmetic oil. Oils which are preferred as constituents of preferred water-in-oil emulsions according to the invention have already been mentioned above. Water-in-oil emulsions preferred according to the invention comprise 10 to 85% by weight of free water, at least one antiperspirant active substance and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, 0.1 to 30% % By weight of surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and 1-40% by weight of at least one cosmetic oil selected from branched saturated or unsaturated fatty alcohols with 6 to 30 carbon atoms, dicarboxylic acid esters of linear or branched C 2 -C 0 -alkanols, addition products of 1 to 5 propylene oxide units to mono- or polyhydric C 8 -C 22 -alkanols, adducts of at least 6 ethylene oxide and / or propylene oxide Units of monovalent or polyvalent C 3 . 2 2-alkanols, esters of linear or branched saturated or unsaturated fatty alcohols having 2 to 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms which may be hydroxylated, dicaprylyl carbonate, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, hexamethyldisiloxane ( L 2 ), octamethyltrisiloxane (L 3 ), decamethyltetrasiloxane (L 4 ), dodecamethylpentasiloxane (L 5 ), as well as any two, three and four mixtures of L 2 , l_3, l_4 and / or L 5 , linear dimethylpolysiloxanes with kinematic viscosities in the range from 5 to 100 cSt, wherein the values of the kinematic viscosity relate to a temperature of 25 ° C, C 8 -C 6 -alkoalkanes, C 0 -C 3 isoalkanes, isohexadecane, isoeicosane, polyisobutenes, hydrogenated polyisobutenes and polydecenes, and Mixtures of the aforesaid oils, the quantities given being based on the total weight of the medium lfreien composition are related.
Aufgrund der besonders günstigen Rückstandseigenschaften sind erfindungsgemäß Wasser-in- ÖI-Emulsionen bevorzugt, die 10 - 85 Gew.-% freies Wasser, mindestens einen Antitranspirant- Wrkstoff und/oder mindestens einen Deodorant-Wrkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, 0,1 - 30 Gew.-% Tensid, darunter mindestens einen Wasser-in-ÖI-Emulgator, insbesondere einen Silicon-basierten Wasser-in-ÖI-Emulgator, und 1 - 40 Gew.-% mindestens eines kosmetischen Öls, ausgewählt aus Zweier- und Dreier-Mischungen von C8-C 6-lsoalkanen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5 - 100 cSt (25°C) und Estern der linearen oder verzweigten gesättigten oder ungesättigten Fettalkohole mit 2 - 30 Kohlenstoffatomen mit linearen oder verzweigten gesättigten oder ungesättigten Fettsäuren mit 2 - 30 Kohlenstoffatomen, die hydroxyliert sein können, enthalten. Due to the particularly favorable residue properties, water-in-oil emulsions which contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight are preferred %, 0.1-30% by weight of surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and 1-40% by weight of at least one cosmetic Oil selected from two and three mixtures of C 8 -C 6 isoalkanes, linear dimethylpolysiloxanes having kinematic viscosities in the range of 5 to 100 cSt (25 ° C) and esters of linear or branched saturated or unsaturated fatty alcohols having 2 to 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms which may be hydroxylated , contain.
Erfindungsgemäß besonders bevorzugt sind Wasser-in-ÖI-Emulsionen, die 10 - 85 Gew.-% freies Wasser, mindestens einen Antitranspirant-Wirkstoff und/oder mindestens einen Deodorant- Wrkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, 0,1 - 30 Gew.-% Tensid, darunter mindestens einen Wasser-in-ÖI-Emulgator, insbesondere einen Silicon-basierten Wasser-in-ÖI-Emul- gator, und 1 - 40 Gew.-% mindestens eines kosmetischen Öls, ausgewählt aus Zweier- und Dreier-Mischungen von C8-C 6-lsoalkanen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5 - 100 cSt (25°C) und Estern der linearen oder verzweigten gesättigten oder ungesättigten Fettalkohole mit 2 - 30 Kohlenstoffatomen mit linearen oder verzweigten gesättigten oder ungesättigten Fettsäuren mit 2 - 30 Kohlenstoffatomen, die hydroxyliert sein können, enthalten und frei sind von Cyclomethiconen. Particularly preferred according to the invention are water-in-oil emulsions which contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, 0.1-30% by weight of surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and 1-40% by weight of at least one cosmetic oil, selected from two and three mixtures of C 8 -C 6 -alkanes, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5 - 100 cSt (25 ° C) and esters of linear or branched saturated or unsaturated fatty alcohols having 2 - 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms, which may be hydroxylated, and are free of cyclomethicones.
Besonders bevorzugt sind weiterhin Wasser-in-ÖI-Emulsionen, die 10 - 85 Gew.-% freies Wasser, mindestens einen Antitranspirant-Wrkstoff und/oder mindestens einen Deodorant-Wirkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, 0,1 - 30 Gew.-% Tensid, darunter mindestens einen Wasser-in-ÖI-Emulgator, insbesondere einen Silicon-basierten Wasser-in-ÖI-Emulgator, mindestens einen Wasser-in-ÖI-Emulgator, insbesondere einen Silicon-basierten Wasser-in-ÖI-Emulgator, und 1 - 40 Gew.-% mindestens eines kosmetischen Öls, ausgewählt aus Zweier- und Dreier- Mischungen von C8-C 6-lsoalkanen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5 - 100 cSt (25°C) und Estern, ausgewählt aus Hexyldecylstearat, Hexyldecyl- laurat, Isodecylneopentanoat, Isononylisononanoat, 2-Ethylhexylpalmitat, 2-Ethylhexylstearat, Iso- propylmyristat, Isopropylpalmitat, Isopropylstearat, Isopropylisostearat, Isopropyloleat, Isooctylste- arat, Isononylstearat, Isocetylstearat, Isononylisononanoat, Isotridecylisononanoat, Cetearyliso- nonanoat, 2-Ethylhexyllaurat, 2-Ethylhexylisostearat, 2-Ethylhexylcocoat, 2-Octyldodecylpalmitat, Butyloctansäure-2-butyloctanoat, Diisotridecylacetat, n-Butylstearat und n-Hexyllaurat, enthalten. Besonders bevorzugt sind weiterhin Wasser-in-ÖI-Emulsionen, die 10 - 85 Gew.-% freies Wasser, mindestens einen Antitranspirant-Wrkstoff und/oder mindestens einen Deodorant-Wirkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, 0,1 - 30 Gew.-% Tensid, darunter mindestens einen Wasser-in-ÖI-Emulgator, insbesondere einen Silicon-basierten Wasser-in-ÖI-Emulgator, mindestens einen Wasser-in-ÖI-Emulgator, insbesondere einen Silicon-basierten Wasser-in-ÖI- Emulgator, und 1 - 40 Gew.-% mindestens eines kosmetischen Öls, ausgewählt aus Zweier- und Dreier-Mischungen von C8-C 6-lsoalkanen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5 - 100 cSt (25°C) und Estern, ausgewählt aus Hexyldecylstearat, Hexyldecyllaurat, Isodecylneopentanoat, Isononylisononanoat, 2-Ethylhexylpalmitat, 2-Ethylhexyl- stearat, Isopropylmyristat, Isopropylpalmitat, Isopropylstearat, Isopropylisostearat, Isopropyloleat, Isooctylstearat, Isononylstearat, Isocetylstearat, Isononylisononanoat, Isotridecylisononanoat, Cetearylisononanoat, 2-Ethylhexyllaurat, 2-Ethylhexylisostearat, 2-Ethylhexylcocoat, 2-Octyldode- cylpalmitat, Butyloctansäure-2-butyloctanoat, Diisotridecylacetat, n-Butylstearat und n-Hexyl- laurat, enthalten und frei sind von Cyclomethiconen. Also particularly preferred are water-in-oil emulsions containing 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, 0.1-30% by weight of surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, at least one water-in-oil emulsifier, in particular a silicone-based Water-in-oil emulsifier, and 1 - 40 wt .-% of at least one cosmetic oil selected from two and three mixtures of C 8 -C 6 -lsoalkanen, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5 - 100 cSt (25 ° C) and esters selected from hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyl dodecyl palmitate, butyloctanoic acid 2-butyloctanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate. Also particularly preferred are water-in-oil emulsions containing 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, 0.1-30% by weight of surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, at least one water-in-oil emulsifier, in particular a silicone-based Water-in-oil emulsifier, and 1 - 40 wt .-% of at least one cosmetic oil selected from two and three mixtures of C 8 -C 6 -lsoalkanen, linear dimethylpolysiloxanes having kinematic viscosities in the range of 5 - 100 cSt (25 ° C) and esters selected from hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, cylpalmitat isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, Isononylstearat, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl, 2-ethylhexyl cocoate, 2-Octyldode-, butyloctanoic acid-2-butyl octanoate, Diisotridecylacetat, n-butyl stearate and n-hexyl laurate, and are free of cyclomethicones.
Weiterhin sind Wasser-in-ÖI-Emulsionen bevorzugt, die 10 - 85 Gew.-% freies Wasser, mindestens einen Antitranspirant-Wrkstoff und/oder mindestens einen Deodorant-Wirkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, 0,1 - 30 Gew.-% Tensid, darunter mindestens einen Wasser- in-ÖI-Emulgator, insbesondere einen Silicon-basierten Wasser-in-ÖI-Emulgator, und 1 - 40 Gew.- % mindestens eines kosmetischen Öls, ausgewählt aus Zweier- und Dreier-Mischungen von C8- C 6-lsoalkanen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5 - 100 cSt (25°C) und Estern der linearen oder verzweigten gesättigten oder ungesättigten Fettalkohole mit 2 - 30 Kohlenstoffatomen mit linearen oder verzweigten gesättigten oder ungesättigten Fettsäuren mit 2 - 30 Kohlenstoffatomen, die hydroxyliert sein können, enthalten und mit £-CF3CH=CHF als Treibmittel in einer Aerosol-Abgabevorrichtung verpackt sind, wobei die Mengenangaben jeweils auf das Gesamtgewicht der treibmittelfreien Antitranspirant-Zusammenset- zung bezogen sind. Furthermore, water-in-oil emulsions are preferred which contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight , 1 - 30 wt .-% of surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and 1-40% by weight of at least one cosmetic oil selected from two and tri-mixtures of C 8 -C 6 -alkoalkanes, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5-100 cSt (25 ° C.) and esters of linear or branched saturated or unsaturated fatty alcohols having 2-30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms, which may be hydroxylated, and are packaged with ε-CF 3 CH = CHF as a propellant in an aerosol dispenser, the amounts given being based on the total weight of the propellant pure antiperspirant composition are related.
Weiterhin sind Wasser-in-ÖI-Emulsionen bevorzugt, die 10 - 85 Gew.-% freies Wasser, mindestens einen Antitranspirant-Wirkstoff und/oder mindestens einen Deodorant-Wrkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, 0,1 - 30 Gew.-% Tensid, darunter mindestens einen Wasser-in-ÖI-Emulgator, insbesondere einen Silicon-basierten Wasser-in-ÖI-Emulgator, und 1 - 40 Gew.-% mindestens eines kosmetischen Öls, ausgewählt aus Zweier- und Dreier-Mischungen von C8-C 6-lsoalkanen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5 - 100 cSt (25°C) und Estern der linearen oder verzweigten gesättigten oder ungesättigten Fettalkohole mit 2 - 30 Kohlenstoffatomen mit linearen oder verzweigten gesättigten oder ungesättigten Fettsäuren mit 2 - 30 Kohlenstoffatomen, die hydroxyliert sein können, enthalten frei sind von Cyclomethiconen und mit £-CF3CH=CHF als Treibmittel in einer Aerosol-Abgabevorrichtung verpackt sind, wobei die Mengenangaben jeweils auf das Gesamtgewicht der treibmittelfreien Antitranspirant-Zusammensetzung bezogen sind. Furthermore, water-in-oil emulsions are preferred which contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight , 1 - 30 wt .-% surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and 1-40 wt .-% of at least one cosmetic oil selected from two and tri-mixtures of C 8 -C 6 isoalkanes, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5-100 cSt (25 ° C.) and esters of linear or branched saturated or unsaturated fatty alcohols having 2-30 carbon atoms with linear or branched saturated or unsaturated fatty acids having from 2 to 30 carbon atoms, which may be hydroxylated, are free of cyclomethicones and are packaged with ε-CF 3 CH = CHF as a propellant in an aerosol dispenser, the quantities given to each of the Ges amtgewicht the propellant-free antiperspirant composition are related.
Besonders bevorzugt sind Wasser-in-ÖI-Emulsionen, die 10 - 85 Gew.-% freies Wasser, mindestens einen Antitranspirant-Wrkstoff und/oder mindestens einen Deodorant-Wrkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, 0,1 - 30 Gew.-% Tensid, darunter mindestens einen Wasser-in-ÖI-Emulgator, insbesondere einen Silicon-basierten Wasser-in-ÖI-Emulgator, und 1 - 40 Gew.-% mindestens eines kosmetischen Öls, ausgewählt aus Zweier- und Dreier-Mischungen von C8-C 6-lsoalkanen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5 - 100 cSt (25°C) und Estern, ausgewählt aus Hexyldecylstearat, Hexyldecyllaurat, Isodecyl- neopentanoat, Isononylisononanoat, 2-Ethylhexylpalmitat, 2-Ethylhexylstearat, Isopropylmyristat, Isopropylpalmitat, Isopropylstearat, Isopropylisostearat, Isopropyloleat, Isooctylstearat, Isononyl- stearat, Isocetylstearat, Isononylisononanoat, Isotridecylisononanoat, Cetearylisononanoat, 2-Ethylhexyllaurat, 2-Ethylhexylisostearat, 2-Ethylhexylcocoat, 2-Octyldodecylpalmitat, Butyl- octansäure-2-butyloctanoat, Diisotridecylacetat, n-Butylstearat und n-Hexyllaurat, enthalten und mit £-CF3CH=CHF als Treibmittel in einer Aerosol-Abgabevorrichtung verpackt sind, wobei die Mengenangaben jeweils auf das Gesamtgewicht der treibmittelfreien Antitranspirant-Zusammen- setzung bezogen sind. Particular preference is given to water-in-oil emulsions containing 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight , 1 - 30 wt .-% surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and 1-40 wt .-% of at least one cosmetic oil selected from two and tri-mixtures of C 8 -C 6 isoalkanes, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5-100 cSt (25 ° C.) and esters selected from hexyldecylstearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2- Octyldodecyl palmitate, butyl octanoic acid 2-butyloctanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, and are packaged with £ -CF 3 CH = CHF as propellant in an aerosol dispenser, the amounts given are based on the total weight of the propellant-free antiperspirant Compound are related.
Besonders bevorzugt sind Wasser-in-ÖI-Emulsionen, die 10 - 85 Gew.-% freies Wasser, mindestens einen Antitranspirant-Wrkstoff und/oder mindestens einen Deodorant-Wrkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, 0,1 - 30 Gew.-% Tensid, darunter mindestens einen Wasser-in-ÖI-Emulgator, insbesondere einen Silicon-basierten Wasser-in-ÖI-Emulgator, und 1 - 40 Gew.-% mindestens eines kosmetischen Öls, ausgewählt aus Zweier- und Dreier-Mischungen von C8-C 6-lsoalkanen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5 - 100 cSt (25°C) und Estern, ausgewählt aus Hexyldecylstearat, Hexyldecyllaurat, Isodecyl- neopentanoat, Isononylisononanoat, 2-Ethylhexylpalmitat, 2-Ethylhexylstearat, Isopropylmyristat, Isopropylpalmitat, Isopropylstearat, Isopropylisostearat, Isopropyloleat, Isooctylstearat, Isononyl- stearat, Isocetylstearat, Isononylisononanoat, Isotridecylisononanoat, Cetearylisononanoat, 2-Ethylhexyllaurat, 2-Ethylhexylisostearat, 2-Ethylhexylcocoat, 2-Octyldodecylpalmitat, Butyl- octansäure-2-butyloctanoat, Diisotridecylacetat, n-Butylstearat und n-Hexyllaurat, enthalten, frei sind von Cyclomethiconen und mit £-CF3CH=CHF als Treibmittel in einer Aerosol-Abgabevorrichtung verpackt sind, wobei die Mengenangaben jeweils auf das Gesamtgewicht der treibmittelfreien Antitranspirant-Zusammensetzung bezogen sind. Particular preference is given to water-in-oil emulsions containing 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight , 1 - 30 wt .-% surfactant, including at least one water-in-oil emulsifier, in particular a silicone-based water-in-oil emulsifier, and 1-40 wt .-% of at least one cosmetic oil selected from two and tri-mixtures of C 8 -C 6 -alkanes, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5-100 cSt (25 ° C.) and esters selected from hexyldecylstearate, hexyldecyl laurate, isodecylneopentanoate, isononylisononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl coco 2-octyl dodecyl palmitate, butyl octanoic acid 2-butyl octanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, are free of cyclomethicones and are packaged with ε-CF 3 CH = CHF as the propellant in an aerosol dispenser the quantities are each based on the total weight of the propellant-free antiperspirant composition.
Das mindestens eine kosmetische Öl ist in den erfindungsgemäßen Zusammensetzungen, die als Emulsion (O/W oder W/O) vorliegen, in einer Gesamtmenge von 1 - 40 Gew.-%, bevorzugt 2 - 30 Gew.-%, besonders bevorzugt 5 - 25 Gew.-% und außerordentlich bevorzugt 10 - 20 Gew.-%, enthalten, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien Deodorant- oder Anti- transpirant-Zusammensetzung.  The at least one cosmetic oil is present in the inventive compositions which are present as emulsion (O / W or W / O) in a total amount of 1-40% by weight, preferably 2-30% by weight, particularly preferably 5%. 25 wt .-% and most preferably 10 to 20 wt .-%, each based on the total weight of the propellant-free deodorant or antiperspirant composition.
Weitere erfindungsgemäß bevorzugte Wasser-in-ÖI-Emulsionen enthalten 10 - 85 Gew.-% freies Wasser, mindestens einen Antitranspirant-Wrkstoff und/oder mindestens einen Deodorant-Wirkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, mindestens einen Silicon-freien Wasser-in-ÖI- Emulgator wie vorstehend beschrieben in einer Gesamtmenge von 0,1 - 15 Gew.-%, bevorzugt 0,5 - 8,0 Gew.-%, und besonders bevorzugt 1 - 4 Gew.-%, und 1 - 40 Gew.-% mindestens eines kosmetischen Öls, ausgewählt aus verzweigten gesättigten oder ungesättigten Fettalkoholen mit 6 - 30 Kohlenstoffatomen, Dicarbonsäureestern von linearen oder verzweigten C2-C 0-Alkanolen, Anlagerungsprodukten von 1 bis 5 Propylenoxid-Einheiten an ein- oder mehrwertige C8.22-Alka- nole, Anlagerungsprodukten von mindestens 6 Ethylenoxid und/oder Propylenoxid-Einheiten an ein- oder mehrwertige C3.22-Alkanole, Estern der linearen oder verzweigten gesättigten oder ungesättigten Fettalkohole mit 2 - 30 Kohlenstoffatomen mit linearen oder verzweigten gesättigten oder ungesättigten Fettsäuren mit 2 - 30 Kohlenstoffatomen, die hydroxyliert sein können, Dicaprylylcarbonat, Octamethylcyclotetrasiloxan, Decamethylcyclopentasiloxan, Dodecamethyl- cyclohexasiloxan, Hexamethyldisiloxan (L2), Octamethyltrisiloxan (L3), Decamethyltetrasiloxan (L4), Dodecamethylpentasiloxan (L5), sowie beliebigen Zweier-, Dreier und Vierermischungen aus L2, L3, l_4 und/oder L5, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5 - 100 cSt, wobei sich die Werte der kinematischen Viskosität auf eine Temperatur von 25°C beziehen, C8-C 6-lsoalkanen, C 0-C 3-Isoalkanen, Isohexadecan, Isoeicosan, Polyisobutenen, hydrierten Polyisobutenen und Polydecenen, sowie Mischungen der vorgenannten Öle, wobei die Mengenangaben jeweils auf das Gesamtgewicht der treibmittelfreien Deodorant- oder Antitranspirant-Zusammensetzung bezogen sind. In einer weiteren bevorzugten Ausführungsform sind diese Wasser-in-ÖI-Emulsionen frei von Cyclomethiconen. In einer weiteren bevorzugten Ausführungsform sind diese Wasser-in-ÖI-Emulsionen mit £-CF3CH=CHF als Treibmittel in einer Ae roso I- Abg a be vo rri ch tu n g ve rpa ckt . Further water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-free water-in-oil emulsifier as described above in a total amount of 0.1-15% by weight, preferably 0.5-8.0% by weight, and particularly preferably 1-4% by weight , and 1 - 40 wt .-% of at least one cosmetic oil selected from branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms, dicarboxylic acid esters of linear or branched C 2 -C 0 alkanols, addition products of 1 to 5 propylene oxide units to a - or polyvalent C 8 . 22 -alka nole, addition products of at least 6 ethylene oxide and / or propylene oxide units to monovalent or polyvalent C 3 . 22 -alkanols, esters of linear or branched saturated or unsaturated fatty alcohols having 2 to 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms which may be hydroxylated, dicaprylyl carbonate, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, hexamethyldisiloxane (L 2 ), octamethyltrisiloxane (L 3 ), decamethyltetrasiloxane (L 4 ), dodecamethylpentasiloxane (L 5 ), as well as any two, three and four mixtures of L 2 , L 3 , l_4 and / or L 5 , linear dimethylpolysiloxanes with kinematic viscosities in the range from 5 to 100 cSt, wherein the values of the kinematic viscosity relate to a temperature of 25 ° C, C 8 -C 6 -alkoalkanes, C 0 -C 3 isoalkanes, isohexadecane, isoeicosane, polyisobutenes, hydrogenated polyisobutenes and polydecenes, and Mixtures of the aforesaid oils, the quantities given in each case based on the total weight of treibmitt free from deodorant or antiperspirant composition. In a further preferred embodiment, these water-in-oil emulsions are free of cyclomethicones. In a further preferred embodiment, these water-in-oil emulsions with ε-CF 3 CH = CHF as propellants in an aerosol discharge are preconfigured.
Weitere erfindungsgemäß bevorzugte Wasser-in-ÖI-Emulsionen enthalten 10 - 85 Gew.-% freies Wasser, mindestens einen Antitranspirant-Wrkstoff und/oder mindestens einen Deodorant-Wirkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, mindestens einen Wasser-in-ÖI-Emulgator auf Siliconbasis wie vorstehend beschrieben in einer Gesamtmenge von 0,1 - 5 Gew.-%, besonders bevorzugt 0,5 - 3,5 Gew.-%, außerordentlich bevorzugt 1 ,0 - 3 Gew.-%, und 1 - 40 Gew.-% mindestens eines kosmetischen Öls, ausgewählt aus verzweigten gesättigten oder ungesättigten Fettalkoholen mit 6 - 30 Kohlenstoffatomen, Dicarbonsäureestern von linearen oder verzweigten C2-C 0-Alkanolen, Anlagerungsprodukten von 1 bis 5 Propylenoxid-Einheiten an ein- oder mehrwertige C8.22-Alkanole, Anlagerungsprodukten von mindestens 6 Ethylenoxid und/oder Propylenoxid-Einheiten an ein- oder mehrwertige C3.22-Alkanole, Estern der linearen oder verzweigten gesättigten oder ungesättigten Fettalkohole mit 2 - 30 Kohlenstoffatomen mit linearen oder verzweigten gesättigten oder ungesättigten Fettsäuren mit 2 - 30 Kohlenstoffatomen, die hydroxyliert sein können, Dicaprylylcarbonat, Octamethylcyclotetrasiloxan, Decamethylcyclopentasiloxan, Dodecamethylcyclohexasiloxan, Hexamethyldisiloxan (L2), Octamethyltrisiloxan (L3), Decamethyltetrasiloxan (L4), Dodecamethylpentasiloxan (L5), sowie beliebigen Zweier-, Dreier und Vierermischungen aus L2, L3, l_4 und/oder L5, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5 - 100 cSt, wobei sich die Werte der kinematischen Viskosität auf eine Temperatur von 25°C beziehen, C8-C 6-lsoalkanen, C 0-C 3-Isoalkanen, Isohexadecan, Isoeicosan, Polyisobutenen, hydrierten Polyisobutenen und Polydecenen, sowie Mischungen der vorgenannten Öle, wobei die Mengenangaben jeweils auf das Gesamtgewicht der treibmittelfreien Deodorant- oder Antitranspirant-Zusammensetzung bezogen sind. In einer weiteren bevorzugten Ausführungsform sind diese Wasser-in-ÖI-Emulsionen frei von Cyclomethiconen. In einer weiteren bevorzugten Ausführungsform sind diese Wasser-in-ÖI-Emulsionen mit £-CF3CH=CHF als Treibmittel in einer Aerosol-Abgabevorrichtung verpackt. Further water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-based water-in-oil emulsifier as described above in a total amount of 0.1-5% by weight, more preferably 0.5-3.5% by weight, most preferably 1.0-0.3% by weight. %, and 1 - 40 wt .-% of at least one cosmetic oil selected from branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms, dicarboxylic acid esters of linear or branched C 2 -C 0 alkanols, addition products of 1 to 5 propylene oxide units mono- or polyvalent C 8 . 22 -alkanols, addition products of at least 6 ethylene oxide and / or propylene oxide units to monovalent or polyvalent C 3 . 22 -alkanols, esters of linear or branched saturated or unsaturated fatty alcohols having 2 to 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms which may be hydroxylated, dicaprylyl carbonate, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, hexamethyldisiloxane (L 2 ) , Octamethyltrisiloxan (L 3 ), Decamethyltetrasiloxan (L 4 ), Dodecamethylpentasiloxan (L 5 ), as well as any two, three and four mixtures of L 2 , L 3 , l_4 and / or L 5 , linear dimethylpolysiloxanes with kinematic viscosities in the range of 5 - 100 cSt, wherein the values of the kinematic viscosity relate to a temperature of 25 ° C, C 8 -C 6 -lsoalkanen, C 0 -C 3 isoalkanes, Isohexadecan, Isoeicosan, polyisobutenes, hydrogenated polyisobutenes and polydecenes, and mixtures of the aforementioned oils, the quantities given in each case on the total weight of the propellant free Deodorant or antiperspirant composition. In a further preferred embodiment, these water-in-oil emulsions are free of cyclomethicones. In a further preferred embodiment, these water-in-oil emulsions are packed with £ -CF 3 CH = CHF as a propellant in an aerosol dispenser.
Weitere erfindungsgemäß bevorzugte Wasser-in-ÖI-Emulsionen enthalten 10 - 85 Gew.-% freies Wasser, mindestens einen Antitranspirant-Wrkstoff und/oder mindestens einen Deodorant-Wirkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, mindestens einen Wasser-in-ÖI-Emulgator auf Siliconbasis, ausgewählt PEG/PPG-18/18 Dimethicone, in einer Gesamtmenge von 0,1 - 5 Gew.- %, besonders bevorzugt 0,5 - 3,5 Gew.-%, außerordentlich bevorzugt 1 ,0 - 3 Gew.-%, und 1 - 40 Gew.-% mindestens eines kosmetischen Öls, ausgewählt aus verzweigten gesättigten oder ungesättigten Fettalkoholen mit 6 - 30 Kohlenstoffatomen, Dicarbonsäureestern von linearen oder verzweigten C2-C 0-Alkanolen, Anlagerungsprodukten von 1 bis 5 Propylenoxid-Einheiten an ein- oder mehrwertige C8.22-Alkanole, Anlagerungsprodukten von mindestens 6 Ethylenoxid und/oder Propylenoxid-Einheiten an ein- oder mehrwertige C3.22-Alkanole, Estern der linearen oder verzweigten gesättigten oder ungesättigten Fettalkohole mit 2 - 30 Kohlenstoffatomen mit linearen oder verzweigten gesättigten oder ungesättigten Fettsäuren mit 2 - 30 Kohlenstoffatomen, die hydroxyliert sein können, Dicaprylylcarbonat, Octamethylcyclotetrasiloxan, Decamethylcyclo- pentasiloxan, Dodecamethylcyclohexasiloxan, Hexamethyldisiloxan (L2), Octamethyltrisiloxan (L3), Decamethyltetrasiloxan (L4), Dodecamethylpentasiloxan (L5), sowie beliebigen Zweier-, Dreier und Vierermischungen aus L2, L3, L4 und/oder L5, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5 - 100 cSt, wobei sich die Werte der kinematischen Viskosität auf eine Temperatur von 25°C beziehen, C8-C 6-lsoalkanen, C 0-C 3-Isoalkanen, Iso- hexadecan, Isoeicosan, Polyisobutenen, hydrierten Polyisobutenen und Polydecenen, sowie Mischungen der vorgenannten Öle, wobei die Mengenangaben jeweils auf das Gesamtgewicht der treibmittelfreien Deodorant- oder Antitranspirant-Zusammensetzung bezogen sind. In einer weiteren bevorzugten Ausführungsform sind diese Wasser-in-ÖI-Emulsionen frei von Cyclomethiconen. In einer weiteren bevorzugten Ausführungsform sind diese Wasser-in-ÖI- Emulsionen mit £-CF3CH=CHF als Treibmittel in einer Aerosol-Abgabevorrichtung verpackt. Weitere erfindungsgemäß bevorzugte Wasser-in-ÖI-Emulsionen enthalten 10 - 85 Gew.-% freies Wasser, mindestens einen Antitranspirant-Wrkstoff und/oder mindestens einen Deodorant-Wirkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, mindestens einen Silicon-freien Wasser-in-ÖI- Emulgator wie vorstehend beschrieben in einer Gesamtmenge von 0,1 - 15 Gew.-%, bevorzugt 0,5 - 8,0 Gew.-%, und besonders bevorzugt 1 - 4 Gew.-%, und 1 - 40 Gew.-% mindestens eines kosmetischen Öls, ausgewählt aus Zweier- und Dreier-Mischungen von C8-C 6-lsoalkanen, line- ren Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5 - 100 cSt (25°C) und Estern, ausgewählt aus Hexyldecylstearat, Hexyldecyllaurat, Isodecylneopentanoat, Isononyliso- nonanoat, 2-Ethylhexylpalmitat, 2-Ethylhexylstearat, Isopropylmyristat, Isopropylpalmitat, Isopro- pylstearat, Isopropylisostearat, Isopropyloleat, Isooctylstearat, Isononylstearat, Isocetylstearat, Isononylisononanoat, Isotridecylisononanoat, Cetearylisononanoat, 2-Ethylhexyllaurat, 2-Ethyl- hexylisostearat, 2-Ethylhexylcocoat, 2-Octyldodecylpalmitat, Butyloctansäure-2-butyloctanoat, Diisotridecylacetat, n-Butylstearat und n-Hexyllaurat, wobei die Mengenangaben jeweils auf das Gesamtgewicht der treibmittelfreien Deodorant- oder Antitranspirant-Zusammensetzung bezogen sind. In einer weiteren bevorzugten Ausführungsform sind diese Wasser-in-ÖI-Emulsionen frei von Cyclomethiconen. In einer weiteren bevorzugten Ausführungsform sind diese Wasser-in-ÖI- Emulsionen mit £-CF3CH=CHF als Treibmittel in einer Aerosol-Abgabevorrichtung verpackt. Weitere erfindungsgemäß bevorzugte Wasser-in-ÖI-Emulsionen enthalten 10 - 85 Gew.-% freies Wasser, mindestens einen Antitranspirant-Wrkstoff und/oder mindestens einen Deodorant-Wirkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, mindestens einen Wasser-in-ÖI-Emulgator auf Siliconbasis wie vorstehend beschrieben in einer Gesamtmenge von 0,1 - 5 Gew.-%, besonders bevorzugt 0,5 - 3,5 Gew.-%, außerordentlich bevorzugt 1 ,0 - 3 Gew.-%, und 1 - 40 Gew.-% mindestens eines kosmetischen Öls, ausgewählt aus Zweier- und Dreier-Mischungen von C8-C 6- Isoalkanen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5 - 100 cSt (25°C) und Estern, ausgewählt aus Hexyldecylstearat, Hexyldecyllaurat, Isodecylneopen- tanoat, Isononylisononanoat, 2-Ethylhexylpalmitat, 2-Ethylhexylstearat, Isopropylmyristat, Isopropylpalmitat, Isopropylstearat, Isopropylisostearat, Isopropyloleat, Isooctylstearat, Isononylstearat, Isocetylstearat, Isononylisononanoat, Isotridecylisononanoat, Cetearylisononanoat, 2-Ethylhexyllaurat, 2-Ethylhexylisostearat, 2-Ethylhexylcocoat, 2-Octyldodecylpalmitat, Butyloctansäure-2- butyloctanoat, Diisotridecylacetat, n-Butylstearat und n-Hexyllaurat, wobei die Mengenangaben jeweils auf das Gesamtgewicht der treibmittelfreien Antitranspirant-Zusammensetzung bezogen sind. In einer weiteren bevorzugten Ausführungsform sind diese Wasser-in-ÖI-Emulsionen frei von Cyclomethiconen. In einer weiteren bevorzugten Ausführungsform sind diese Wasser-in-ÖI- Emulsionen mit £-CF3CH=CHF als Treibmittel in einer Aerosol-Abgabevorrichtung verpackt. Weitere erfindungsgemäß bevorzugte Wasser-in-ÖI-Emulsionen enthalten 10 - 85 Gew.-% freies Wasser, mindestens einen Antitranspirant-Wrkstoff und/oder mindestens einen Deodorant-Wirkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, mindestens einen Wasser-in-ÖI-Emulgator auf Siliconbasis, ausgewählt aus PEG/PPG-18/18 Dimethicone, in einer Gesamtmenge von 0,1 - 5 Gew.-%, besonders bevorzugt 0,5 - 3,5 Gew.-%, außerordentlich bevorzugt 1 ,0 - 3 Gew.-%, und 1 - 40 Gew.-% mindestens eines kosmetischen Öls, ausgewählt aus Zweier- und Dreier-Mischungen von C8-C 6-lsoalkanen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5 - 100 cSt (25°C) und Estern, ausgewählt aus Hexyldecylstearat, Hexyldecyllaurat, Isodecylneopentanoat, Isononylisononanoat, 2-Ethylhexylpalmitat, 2-Ethylhexylstearat, Isopropylmyristat, Isopropylpalmitat, Isopropylstearat, Isopropylisostearat, Isopropyloleat, Isooctylstearat, Isononylstearat, Isocetylstearat, Isononylisononanoat, Isotridecylisononanoat, Cetearylisonona- noat, 2-Ethylhexyllaurat, 2-Ethylhexylisostearat, 2-Ethylhexylcocoat, 2-Octyldodecylpalmitat, Butyloctansäure-2-butyloctanoat, Diisotridecylacetat, n-Butylstearat und n-Hexyllaurat, wobei die Mengenangaben jeweils auf das Gesamtgewicht der treibmittelfreien Deodorant- oder Antitranspi- rant-Zusammensetzung bezogen sind. In einer weiteren bevorzugten Ausführungsform sind diese Wasser-in-ÖI-Emulsionen frei von Cyclomethiconen. In einer weiteren bevorzugten Ausführungsform sind diese Wasser-in-ÖI-Emulsionen mit £-CF3CH=CHF als Treibmittel in einer Aerosol- Abgabevorrichtung verpackt. Further water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-based water-in-oil emulsifier selected from PEG / PPG-18/18 dimethicones, in a total amount of 0.1-5% by weight, more preferably 0.5-3.5% by weight, exceptionally preferred 1, 0 to 3 wt .-%, and 1-40 wt .-% of at least one cosmetic oil selected from branched saturated or unsaturated fatty alcohols having 6 to 30 carbon atoms, dicarboxylic acid esters of linear or branched C 2 -C 0 alkanols, addition products from 1 to 5 propylene oxide units to mono- or polyhydric C 8 . 22 -alkanols, addition products of at least 6 ethylene oxide and / or propylene oxide units to monovalent or polyvalent C 3 . 22 -alkanols, esters of linear or branched saturated or unsaturated fatty alcohols having 2 to 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms which may be hydroxylated, dicaprylyl carbonate, octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, dodecamethylcyclohexasiloxane, hexamethyldisiloxane (L 2 ), octamethyltrisiloxane (L 3 ), decamethyltetrasiloxane (L 4 ), dodecamethylpentasiloxane (L 5 ), as well as any two, three and four mixtures of L 2 , L 3 , L 4 and / or L 5 , linear dimethylpolysiloxanes with kinematic viscosities Range of 5-100 cSt, with kinematic viscosity values relating to a temperature of 25 ° C, C 8 -C 6 isoalkanes, C 0 -C 3 isoalkanes, isohexadecane, isoeicosane, polyisobutenes, hydrogenated polyisobutenes, and Polydecenes, and mixtures of the aforementioned oils, wherein the amounts given in each case on the total weight of treibmi non-deodorant or antiperspirant composition. In a further preferred embodiment, these water-in-oil emulsions are free of cyclomethicones. In another preferred embodiment, these water-in-oil emulsions are packaged with £ -CF 3 CH = CHF as propellant in an aerosol dispenser. Further water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-free water-in-oil emulsifier as described above in a total amount of 0.1-15% by weight, preferably 0.5-8.0% by weight, and particularly preferably 1-4% by weight and from 1 to 40% by weight of at least one cosmetic oil selected from mixtures of two and three of C 8 -C 6 -alkanes, linear dimethylpolysiloxanes having kinematic viscosities in the range from 5 to 100 cSt (25 ° C.) and esters selected from hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyliso nonanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2- Octyldodecyl palmitate, butyloctanoic acid 2-butyloctanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, the amounts given being based on the total weight of the propellant-free deodorant or antiperspirant composition. In a further preferred embodiment, these water-in-oil emulsions are free of cyclomethicones. In another preferred embodiment, these water-in-oil emulsions are packaged with £ -CF 3 CH = CHF as propellant in an aerosol dispenser. Further water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-based water-in-oil emulsifier as described above in a total amount of 0.1-5% by weight, more preferably 0.5-3.5% by weight, most preferably 1.0-0.3% by weight. %, and 1 - 40 wt .-% of at least one cosmetic oil selected from two and three mixtures of C 8 -C 6 - isoalkanes, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5 - 100 cSt (25 ° C) and Esters selected from hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononanoate, isotridecyl isoneone anoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyl dodecyl palmitate, butyloctanoic acid 2-butyloctanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, the amounts given being based on the total weight of the antiperspirant composition , In a further preferred embodiment, these water-in-oil emulsions are free of cyclomethicones. In another preferred embodiment, these water-in-oil emulsions are packaged with £ -CF 3 CH = CHF as propellant in an aerosol dispenser. Further water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-based water-in-oil emulsifier selected from PEG / PPG-18/18 dimethicones, in a total amount of 0.1-5% by weight, more preferably 0.5-3.5% by weight, exceptionally preferably 1, 0-3 wt .-%, and 1 - 40 wt .-% of at least one cosmetic oil selected from two- and three-mixtures of C 8 -C 6 -lsoalkanen, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5 100 cSt (25 ° C.) and esters selected from hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, Isononyl stearate, isocetyl stearate, isononyl isononanoate, isotridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyl dodecyl palmitate, butyloctanoic acid 2-butyloctanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, the quantities given in each case to the Total weight of the propellant-free deodorant or antiperspirant composition are related. In a further preferred embodiment, these water-in-oil emulsions are free of cyclomethicones. In another preferred embodiment, these water-in-oil emulsions are packaged with £ -CF 3 CH = CHF as the propellant in an aerosol dispenser.
In einer weiteren bevorzugten Ausführungsform enthalten die erfindungsgemäß bevorzugten Wasser-in-ÖI-Emulsionen 10 - 85 Gew.-% freies Wasser, mindestens einen Antitranspirant-Wrk- stoff und/oder mindestens einen Deodorant-Wrkstoff in einer Gesamtmenge von 0,1 - 50 Gew.- %, mindestens einen Silicon-freien Wasser-in-ÖI-Emulgator wie vorstehend beschrieben in einer Gesamtmenge von 0,1 - 15 Gew.-%, bevorzugt 0,5 - 8,0 Gew.-%, und besonders bevorzugt 1 - 4 Gew.-%, 1 - 40 Gew.-% mindestens eines kosmetischen Öls, und mindestens einen nichtionischen Polyalkylenglycolether mit einem HLB-Wert > 7, der bevorzugt ausgewählt ist aus Iso- ceteth-20, wobei die Mengenangaben jeweils auf das Gesamtgewicht der treibmittelfreien Deodorant- oder Antitranspirant-Zusammensetzung bezogen sind. Der nichtionische Polyalkylenglycolether mit einem HLB-Wert > 7 ist bevorzugt in einer Gesamtmenge von 0,1 - 3 Gew.-%, bevorzugt 0,5 - 1 ,5 Gew.-%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien Deodorant- oder Antitranspirant-Zusammensetzung, enthalten. In einer weiteren bevorzugten Ausführungsform sind diese Wasser-in-ÖI-Emulsionen frei von Cyclomethiconen. In einer weiteren bevorzugten Ausführungsform sind diese Wasser-in-ÖI-Emulsionen mit £-CF3CH=CHF als Treibmittel in einer Aerosol-Abgabevorrichtung verpackt. In a further preferred embodiment, the water-in-oil emulsions preferred according to the invention contain from 10 to 85% by weight of free water, at least one antiperspirant active and / or at least one deodorant active substance in a total amount of from 0.1 to 50 % By weight, at least one silicone-free water-in-oil emulsifier as described above in a total amount of 0.1-15 wt .-%, preferably 0.5 to 8.0 wt .-%, and particularly preferably 1 to 4% by weight, 1 to 40% by weight of at least one cosmetic oil, and at least one nonionic polyalkylene glycol ether having an HLB value of> 7, which is preferably selected from isoceteth-20, the quantities given in each case referring to Total weight of the propellant-free deodorant or antiperspirant composition are related. The nonionic polyalkylene glycol ether having an HLB value> 7 is preferably in a total amount of 0.1-3 wt.%, Preferably 0.5-1.5 wt.%, In each case based on the total weight of the blowing agent-free deodorant or antiperspirant Composition, included. In a further preferred embodiment, these water-in-oil emulsions are free of cyclomethicones. In a further preferred embodiment, these water-in-oil emulsions are packed with £ -CF 3 CH = CHF as a propellant in an aerosol dispenser.
In einer weiteren bevorzugten Ausführungsform enthalten die erfindungsgemäß bevorzugten Wasser-in-ÖI-Emulsionen 10 - 85 Gew.-% freies Wasser, mindestens einen Antitranspirant-Wrk- stoff und/oder mindestens einen Deodorant-Wrkstoff in einer Gesamtmenge von 0,1 - 50 Gew.- %, mindestens einen Wasser-in-ÖI-Emulgator auf Siliconbasis, wie vorstehend beschrieben, in einer Gesamtmenge von 0,1 - 5 Gew.-%, besonders bevorzugt 0,5 - 3,5 Gew.-%, außerordentlich bevorzugt 1 ,0 - 3 Gew.-%, 1 - 40 Gew.-% mindestens eines kosmetischen Öls, und mindestens einen nichtionischen Polyalkylenglycolether mit einem HLB-Wert > 7, der bevorzugt ausgewählt ist aus lsoceteth-20, wobei die Mengenangaben jeweils auf das Gesamtgewicht der treibmittelfreien Antitranspirant-Zusammensetzung bezogen sind. Der nichtionische Polyalkylenglycolether mit einem HLB-Wert > 7 ist bevorzugt in einer Gesamtmenge von 0,1 - 3 Gew.-%, bevorzugt 0,5 - 1 ,5 Gew.-%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien Deodorantoder Antitranspirant-Zusammensetzung, enthalten. In einer weiteren bevorzugten Ausführungs- form sind diese Wasser-in-ÖI-Emulsionen mit £-CF3CH=CHF als Treibmittel in einer Aerosol- Abgabevorrichtung verpackt. In a further preferred embodiment, the water-in-oil emulsions preferred according to the invention contain from 10 to 85% by weight of free water, at least one antiperspirant active and / or at least one deodorant active substance in a total amount of from 0.1 to 50 % By weight, at least one silicone-based water-in-oil emulsifier as described above, in a total amount of 0.1-5% by weight, more preferably 0.5-3.5% by weight, extremely preferably 1, 0-3 wt .-%, 1 - 40 wt .-% of at least one cosmetic oil, and at least one nonionic polyalkylene glycol ether having an HLB value> 7, which is preferably selected from isoceteth-20, wherein the amounts are in each case on the total weight of the antifriction antiperspirant composition are related. The nonionic polyalkylene glycol ether having an HLB value> 7 is preferably in a total amount of 0.1-3 wt.%, Preferably 0.5-1.5 wt.%, In each case based on the total weight of the blowing agent-free deodorant or antiperspirant composition , contain. In a further preferred embodiment form, these water-in-oil emulsions are packaged with £ -CF 3 CH = CHF as propellant in an aerosol dispenser.
In einer weiteren bevorzugten Ausführungsform enthalten die erfindungsgemäß bevorzugten Wasser-in-ÖI-Emulsionen 10 - 85 Gew.-% freies Wasser, mindestens einen Antitranspirant-Wrk- stoff und/oder mindestens einen Deodorant-Wrkstoff in einer Gesamtmenge von 0,1 - 50 Gew.- %, mindestens einen Wasser-in-ÖI-Emulgator auf Siliconbasis, ausgewählt aus PEG/PPG-18/18 Dimethicone, in einer Gesamtmenge von 0,1 - 5 Gew.-%, besonders bevorzugt 0,5 - 3,5 Gew.- %, außerordentlich bevorzugt 1 ,0 - 3 Gew.-%, 1 - 40 Gew.-% mindestens eines kosmetischen Öls, und mindestens einen nichtionischen Polyalkylenglycolether mit einem HLB-Wert > 7, der bevorzugt ausgewählt ist aus lsoceteth-20, wobei die Mengenangaben jeweils auf das Gesamtgewicht der treibmittelfreien Deodorant- oder Antitranspirant-Zusammensetzung bezogen sind. Der nichtionische Polyalkylenglycolether mit einem HLB-Wert > 7 ist bevorzugt in einer Gesamtmenge von 0,1 - 3 Gew.-%, bevorzugt 0,5 - 1 ,5 Gew.-%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien Deodorant- oder Antitranspirant-Zusammensetzung, enthalten. In einer weiteren bevorzugten Ausführungsform sind diese Wasser-in-ÖI-Emulsionen mit £-CF3CH=CHF als Treibmittel in einer Aerosol-Abgabevorrichtung verpackt. In a further preferred embodiment, the water-in-oil emulsions preferred according to the invention contain from 10 to 85% by weight of free water, at least one antiperspirant active and / or at least one deodorant active substance in a total amount of from 0.1 to 50 % By weight, at least one water-in-oil emulsifier based on silicone, selected from PEG / PPG-18/18 dimethicones, in a total amount of 0.1-5 wt.%, Particularly preferably 0.5-3, 5% by weight, exceptionally preferably 1, 0-3% by weight, 1-40% by weight of at least one cosmetic oil, and at least one nonionic polyalkylene glycol ether having an HLB value> 7, which is preferably selected from Isoceteth- 20, wherein the amounts are each based on the total weight of the blowing agent-free deodorant or antiperspirant composition. The nonionic polyalkylene glycol ether having an HLB value> 7 is preferably in a total amount of 0.1-3 wt.%, Preferably 0.5-1.5 wt.%, In each case based on the total weight of the blowing agent-free deodorant or antiperspirant Composition, included. In a further preferred embodiment, these water-in-oil emulsions are packed with £ -CF 3 CH = CHF as a propellant in an aerosol dispenser.
Weitere erfindungsgemäß bevorzugte Wasser-in-ÖI-Emulsionen enthalten 10 - 85 Gew.-% freies Wasser, mindestens einen Antitranspirant-Wrkstoff und/oder mindestens einen Deodorant-Wirkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, mindestens einen Wasser-in-ÖI-Emulgator auf Siliconbasis wie vorstehend beschrieben in einer Gesamtmenge von 0,1 - 5 Gew.-%, besonders bevorzugt 0,5 - 3,5 Gew.-%, außerordentlich bevorzugt 1 ,0 - 3 Gew.-%, 1 - 40 Gew.-% mindestens eines kosmetischen Öls, ausgewählt aus Zweier- und Dreier-Mischungen von C8-C 6-lso- alkanen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5 - 100 cSt (25°C) und Estern, ausgewählt aus Hexyldecylstearat, Hexyldecyllaurat, Isodecylneopenta- noat, Isononylisononanoat, 2-Ethylhexylpalmitat, 2-Ethylhexylstearat, Isopropylmyristat, Isopropyl- palmitat, Isopropylstearat, Isopropylisostearat, Isopropyloleat, Isooctylstearat, Isononylstearat, Isocetylstearat, Isononylisononanoat, Isotridecylisononanoat, Cetearylisononanoat, 2-Ethylhexyl- laurat, 2-Ethylhexylisostearat, 2-Ethylhexylcocoat, 2-Octyldodecylpalmitat, Butyloctansäure-2- butyloctanoat, Diisotridecylacetat, n-Butylstearat und n-Hexyllaurat, und mindestens einen nichtionischen Polyalkylenglycolether mit einem HLB-Wert > 7, der bevorzugt ausgewählt ist aus lsoceteth-20, wobei die Mengenangaben jeweils auf das Gesamtgewicht der treibmittelfreien Deodorant- oder Antitranspirant-Zusammensetzung bezogen sind. Der nichtionische Polyalkylenglycolether mit einem HLB-Wert > 7 ist bevorzugt in einer Gesamtmenge von 0,1 - 3 Gew.-%, bevorzugt 0,5 - 1 ,5 Gew.-%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien Deodorantoder Antitranspirant-Zusammensetzung, enthalten. In einer weiteren bevorzugten Ausführungs- form sind diese Wasser-in-ÖI-Emulsionen mit £-CF3CH=CHF als Treibmittel in einer Aerosol- Abgabevorrichtung verpackt. Further water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-based water-in-oil emulsifier as described above in a total amount of 0.1-5% by weight, more preferably 0.5-3.5% by weight, most preferably 1.0-0.3% by weight. %, 1 to 40% by weight of at least one cosmetic oil selected from mixtures of two and three of C 8 -C 6 -alkanes, linear dimethylpolysiloxanes with kinematic viscosities in the range from 5 to 100 cSt (25 ° C.) and esters selected from hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononanoate, isotridecyl isononone noate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyldodecyl palmitate, butyloctanoic acid-2-butyloctanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, and at least one nonionic polyalkylene glycol ether having an HLB value> 7 , which is preferably selected from isoceteth-20, wherein the amounts are in each case based on the total weight of the blowing agent-free deodorant or antiperspirant composition. The nonionic polyalkylene glycol ether having an HLB value> 7 is preferably in a total amount of 0.1-3 wt.%, Preferably 0.5-1.5 wt.%, In each case based on the total weight of the blowing agent-free deodorant or antiperspirant composition , contain. In a further preferred embodiment form, these water-in-oil emulsions are packaged with £ -CF 3 CH = CHF as propellant in an aerosol dispenser.
Weitere erfindungsgemäß bevorzugte Wasser-in-ÖI-Emulsionen enthalten 10 - 85 Gew.-% freies Wasser, mindestens einen Antitranspirant-Wrkstoff und/oder mindestens einen Deodorant-Wirkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, mindestens einen Wasser-in-ÖI-Emulgator auf Siliconbasis, ausgewählt aus PEG/PPG-18/18 Dimethicone, in einer Gesamtmenge von 0,1 - 5 Gew.-%, besonders bevorzugt 0,5 - 3,5 Gew.-%, außerordentlich bevorzugt 1 ,0 - 3 Gew.-%, 1 - 40 Gew.-% mindestens eines kosmetischen Öls, ausgewählt aus Zweier- und Dreier-Mischungen von C8-C 6-lsoalkanen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5 - 100 cSt (25°C) und Estern, ausgewählt aus Hexyldecylstearat, Hexyldecyllaurat, Isodecyl- neopentanoat, Isononylisononanoat, 2-Ethylhexylpalmitat, 2-Ethylhexylstearat, Isopropylmyristat, Isopropylpalmitat, Isopropylstearat, Isopropylisostearat, Isopropyloleat, Isooctylstearat, Isononyl- stearat, Isocetylstearat, Isononylisononanoat, Isotridecylisononanoat, Cetearylisononanoat, 2-Ethylhexyllaurat, 2-Ethylhexylisostearat, 2-Ethylhexylcocoat, 2-Octyldodecylpalmitat, Butyl- octansäure-2-butyloctanoat, Diisotridecylacetat, n-Butylstearat und n-Hexyllaurat, und mindestens einen nichtionischen Polyalkylenglycolether mit einem HLB-Wert > 7, der bevorzugt ausgewählt ist aus lsoceteth-20, wobei die Mengenangaben jeweils auf das Gesamtgewicht der treibmittelfreien Deodorant- oder Antitranspirant-Zusammensetzung bezogen sind. Der nichtionische Polyalkylenglycolether mit einem HLB-Wert > 7 ist bevorzugt in einer Gesamtmenge von 0,1 - 3 Gew.-%, bevorzugt 0,5 - 1 ,5 Gew.-%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien Deodorant- oder Antitranspirant-Zusammensetzung, enthalten. In einer weiteren bevorzugten Ausführungsform sind diese Wasser-in-ÖI-Emulsionen mit £-CF3CH=CHF als Treibmittel in einer Aerosol-Abgabevorrichtung verpackt. Further water-in-oil emulsions preferred according to the invention contain 10 to 85% by weight of free water, at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1 to 50% by weight, at least one Silicone-based water-in-oil emulsifier selected from PEG / PPG-18/18 dimethicones, in a total amount of 0.1-5% by weight, more preferably 0.5-3.5% by weight, exceptionally preferably 1, 0-3 wt .-%, 1-40 wt .-% of at least one cosmetic oil selected from two- and three-mixtures of C 8 -C 6 -lsoalkanen, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5 - 100 cSt (25 ° C) and esters selected from hexyldecyl stearate, hexyldecyl laurate, isodecyl neopentanoate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-ethylhexyl stearate, isopropyl myristate, isopropyl palmitate, isopropyl stearate, isopropyl isostearate, isopropyl oleate, isooctyl stearate, isononyl stearate, isocetyl stearate, isononyl isononanoate, iso tridecyl isononanoate, cetearyl isononanoate, 2-ethylhexyl laurate, 2-ethylhexyl isostearate, 2-ethylhexyl cocoate, 2-octyldodecyl palmitate, butyl octanoic acid 2-butyl octanoate, diisotridecyl acetate, n-butyl stearate and n-hexyl laurate, and at least one nonionic polyalkylene glycol ether having an HLB value> 7 , which is preferably selected from isoceteth-20, wherein the amounts are in each case based on the total weight of the blowing agent-free deodorant or antiperspirant composition. The nonionic polyalkylene glycol ether having an HLB value> 7 is preferably in a total amount of 0.1-3 wt.%, Preferably 0.5-1.5 wt.%, In each case based on the total weight of the blowing agent-free deodorant or antiperspirant Composition, included. In a further preferred embodiment, these water-in-oil emulsions are packed with £ -CF 3 CH = CHF as a propellant in an aerosol dispenser.
Überraschend wurde festgestellt, dass derartige Emulsionen eine besonders hohe Temperaturstabilität und eine besonders geringe Korrosivität aufweisen.  Surprisingly, it has been found that such emulsions have a particularly high temperature stability and a particularly low corrosivity.
Die erfindungsgemäßen Zusammensetzungen enthalten bevorzugt mindestens ein Treibmittel, ausgewählt aus  The compositions of the invention preferably contain at least one propellant selected from
i. einem Fluorkohlenstoff oder einem Fluorkohlenwasserstoff aus der Gruppe, bestehend aus einem Fluorkohlenwasserstoff mit der Formel £-R CH=CHR2 oder Z-R CH=CHR2, worin R und R2 unabhängig voneinander eine perfluorierte C bis C6-Alkylgruppe darstellen, sowie aus Mischungen der vorgenannten Substanzen, oder i. a fluorocarbon or a hydrofluorocarbon selected from the group consisting of a fluorohydrocarbon having the formula ε-R CH = CHR 2 or ZR CH = CHR 2 , wherein R and R 2 independently represent a perfluorinated C to C 6 alkyl group, and mixtures the aforementioned substances, or
ii. einem Fluorkohlenstoff oder einem Fluorkohlenwasserstoff aus der Gruppe, bestehend aus CF3CF=CHF, CF3CH=CF2, CHF2CF=CF2, CHF2CH=CHF, CF3CF=CH2, CF3CH=CHF, CH2FCF=CF2, CHF2CH=CF2, CHF2CF=CHF, CHF2CF=CH2, CF3CH=CH2, CH3CF=CF2, CH2FCH=CF2, CH2FCF=CHF, CHF2CH=CHF, CF3CF=CFCF3, CF3CF2CF=CF2, CF3CF=CHCF3, CF3CF2CF=CH2, CF3CH=CHF3, CF3CF2CH=CH2, CF2=CHCF2CF3, CF2=CHCF2CF3, CF2=CFCHFCF3, CF2=CFCF2CHF2, CHF2CH=CHCF3, (CF3)2C=CHCF3 CF3CF=CHCF2CF3, CF3CH=CFCF2CF3, (CF3)2CFCH=CH2, CF3CF2CF2CH=CH2 CF3(CF2)3CF=CF2, CF3CF2CF=CFCF2CF3, (CF3)2C=C(CF3)2, (CF3)2CFCF=CHCF3 CF2=CFCF2CH2F, CF2=CFCHFCHF2, CH2=C(CF3)2, CH2CF2CF=CF2, CH2FCF=CFCHF2 CH2FCF2CF=CF2, CF2=C(CF3)(CH3), CH2=C(CHF2)(CF3), CH2=CHCF2CHF2 CF2=C(CHF2)(CH3), CHF=C(CF3)(CH3), CH2=C(CHF2)2, CF3CF=CFCH3, CH3CF=CHCF3 CF2=CF(CF2)2CF3, CHF=CF(CF2)2CF3, CF2=CH(CF2)2CF3, CF2=CF(CF2)2CHF2 ii. a fluorocarbon or a fluorohydrocarbon selected from CF 3 CF = CHF, CF 3 CH = CF 2 , CHF 2 CF = CF 2 , CHF 2 CH = CHF, CF 3 CF = CH 2 , CF 3 CH = CHF, CH 2 FCF = CF 2 , CHF 2 CH = CF 2 , CHF 2 CF = CHF, CHF 2 CF = CH 2 , CF 3 CH = CH 2 , CH 3 CF = CF 2 , CH 2 FCH = CF 2 , CH 2 FCF = CHF, CHF 2 CH = CHF, CF 3 CF = CFCF 3 , CF 3 CF 2 CF = CF 2 , CF 3 CF = CHCF 3 , CF 3 CF 2 CF = CH 2 , CF 3 CH = CHF 3 , CF 3 CF 2 CH = CH 2 , CF 2 = CHCF 2 CF 3 , CF 2 = CHCF 2 CF 3 , CF 2 = CFCHFCF 3 , CF 2 = CFCF 2 CHF 2 , CHF 2 CH = CHCF 3 , (CF 3 ) 2 C = CHCF 3 CF 3 CF = CHCF 2 CF 3 , CF 3 CH = CFCF 2 CF 3 , (CF 3 ) 2 CFCH = CH 2 , CF 3 CF 2 CF 2 CH = CH 2 CF 3 (CF 2 ) 3 CF = CF 2 , CF 3 CF 2 CF = CFCF 2 CF 3 , CF 3 ) 2 C = C (CF 3 ) 2 , (CF 3 ) 2 CFCF = CHCF 3 CF 2 = CFCF 2 CH 2 F, CF 2 = CFCHFCHF 2 , CH 2 = C (CF 3 ) 2 , CH 2 CF 2 CF = CF 2 , CH 2 FCF = CFCHF 2 CH 2 FCF 2 CF = CF 2 , CF 2 = C (CF 3 ) (CH 3 ), CH 2 = C (CHF 2 ) (CF 3 ), CH 2 = CHCF 2 CHF 2 CF 2 = C (CHF 2 ) (CH 3 ), CHF = C (CF 3 ) (CH 3 ), CH 2 = C (CHF 2 ) 2 , CF 3 CF = CFCH 3 , CH 3 CF = CHCF 3 CF 2 = CF (CF 2 ) 2 CF 3 , CHF = CF (CF 2 ) 2 CF 3 , CF 2 = CH (CF 2 ) 2 CF 3 , CF 2 = CF (CF 2 ) 2 CHF 2
CHF2CF=CFCF2CF3, CF3CF=CFCF2CHF2, CF3CF=CFCHFCF3, CHF=CFCF(CF3)2 CHF 2 CF = CFCF 2 CF 3 , CF 3 CF = CFCF 2 CHF 2 , CF 3 CF = CFCHFCF 3 , CHF = CFCF (CF 3 ) 2
CF2=CFCH(CF3)2, CF3CH=C(CF3)2, CF2=CHCF(CF3)2, CH2=CF(CF2)2CF3 CF 2 = CFCH (CF 3 ) 2 , CF 3 CH = C (CF 3 ) 2 , CF 2 = CHCF (CF 3 ) 2 , CH 2 = CF (CF 2 ) 2 CF 3
CHF=CF(CF2)2CHF2, CH2=C(CF3)C2F5, CF2=CHCH(CF3)2, CHF=CHCF(CF3)2 CHF = CF (CF 2 ) 2 CHF 2 , CH 2 = C (CF 3 ) C 2 F 5 , CF 2 = CHCH (CF 3 ) 2 , CHF = CHCF (CF 3 ) 2
CF2=C(CF3)CH2CF3, CH2=CF(CF2)2CHF2, CF2 =CHCF2CH2CF3, CF3CF=C(CF3)CH3 CF 2 = C (CF 3 ) CH 2 CF 3 , CH 2 = CF (CF 2 ) 2 CHF 2 , CF 2 = CHCF 2 CH 2 CF 3 , CF 3 CF = C (CF 3 ) CH 3
CH2=CFCH(CF3)2, CHF=CHCH(CF3)2, CH2FCH=C(CF3)2, CH3CF=C(CF3)2 CH 2 = CFCH (CF3) 2, CHF = CHCH (CF3) 2, CH 2 FCH = C (CF 3) 2, CH 3 CF = C (CF3) 2
CH2=CHCF2CHFCF3, CH2=C(CF3)CH2CF3, (CF3)2C=CHC2F5, CH2=CHC(CF3)3 CH 2 = CHCF 2 CHFCF 3 , CH 2 = C (CF 3 ) CH 2 CF 3 , (CF 3 ) 2 C = CHC 2 F 5 , CH 2 = CHC (CF 3 ) 3
(CF3)2C=C(CH3)CF3, CH2=CFCF2CH(CF3)2, CF3CF=C(CH3)C2F5, CF3CH=CHCH(CF3)2 (CF 3 ) 2 C = C (CH 3 ) CF 3 , CH 2 = CFCF 2 CH (CF 3 ) 2 , CF 3 CF = C (CH 3 ) C 2 F 5 , CF 3 CH = CHCH (CF 3 ) 2
CH2=CH(CF2)3CHF2, (CF3)2C=CHCF2CH3, CH2=C(CF3)CH2C2F5, CH2=CHCH2CF2CF2CF3 C2F5CF=CFC2H5, CH2=CHCH2CF(CF3)2, CF3CF=CHCH(CF3)(CH3), (CF3)2C=CFC2H5, cyclo- CF2CF2CF2CH=CH-, cyclo-CF2CF2CH=CH-, CF3CF2CF2C(CH3)=CH2 CH 2 = CH (CF 2 ) 3 CHF 2 , (CF 3 ) 2 C = CHCF 2 CH 3 , CH 2 = C (CF 3 ) CH 2 C 2 F 5 , CH 2 = CHCH 2 CF 2 CF 2 CF 3 C 2 F 5 CF = CFC 2 H 5 , CH 2 = CHCH 2 CF (CF 3 ) 2 , CF 3 CF = CHCH (CF 3 ) (CH 3 ), (CF 3 ) 2 C = CFC 2 H 5 , cyclo -CF 2 CF 2 CF 2 CH = CH-, cyclo-CF 2 CF 2 CH = CH-, CF 3 CF 2 CF 2 C (CH 3 ) = CH 2
CF3CF2CF2CH=CHCH3, cyclo-CF2CF2CF=CF-, cyclo-CF2CF=CFCF2CF2-, cyclo- CF2CF=CFCF2CF2CF2-, CF3CF2CF2CF2CH=CH2, CF3CH=CHC2F5, C2F5CH=CHC2F5 CF3CH=CHCF2CF2CF3, CF3CF=CFC2F5, CF3CF=CFCF2CF2CF2CF3, C2F5CF=CFCF2CF2CF3 CF3CH=CFCF2CF2CF2CF3, CF3CF=CHCF2CF2CF2CF3, C2F5CH=CFCF2CF2CF3 CF 3 CF 2 CF 2 CH = CHCH 3 , cyclo-CF 2 CF 2 CF = CF-, cyclo-CF 2 CF = CFCF 2 CF 2 -, cyclo-CF 2 CF = CFCF 2 CF 2 CF 2 -, CF 3 CF 2 CF 2 CF 2 CH = CH 2 , CF 3 CH = CHC 2 F 5 , C 2 F 5 CH = CHC 2 F 5 CF 3 CH = CHCF 2 CF 2 CF 3 , CF 3 CF = CFC 2 F 5 CF 3 CF = CFCF 2 CF 2 CF 2 CF 3 , C 2 F 5 CF = CFCF 2 CF 2 CF 3 CF 3 CH = CFCF 2 CF 2 CF 2 CF 3 , CF 3 CF = CHCF 2 CF 2 CF 2 CF 3 , C 2 F 5 CH = CFCF 2 CF 2 CF 3
C2F5CF=CHCF2CF2CF3, CF3CF2CF2CF=CHCH3, C2F5CF=CHCH3, (CF3)2C=CHCH3 CF3C(CH3)=CHCF3, CHF=CFC2F5, CHF2CF=CFCF3, (CF3)2C=CHF, CH2FCF=CFCF3 CHF=CHC2F5, CHF2CH=CFCF3, CHF=CFCHFCF3, CF3CH=CFCHF2, CHF=CFCF2CHF2 CHF2CF=CFCHF2, CH2CF=CFCF3, CH2FCH=CFCF3, CH2=CFCHFCF3, CH2=CFCF2CHF2 CF3CH=CFCH2F, CHF=CFCH2CF3, CHF=CHCHFCF3, CHF=CHCF2CHF2 C 2 F 5 CF = CHCF 2 CF 2 CF 3 , CF 3 CF 2 CF 2 CF = CHCH 3 , C 2 F 5 CF = CHCH 3 , (CF 3 ) 2 C = CHCH 3 CF 3 C (CH 3 ) = CHCF 3 , CHF = CFC 2 F 5 , CHF 2 CF = CFCF 3 , (CF 3 ) 2 C = CHF, CH 2 FCF = CFCF 3 CHF = CHC 2 F 5 , CHF 2 CH = CFCF 3 , CHF = CFCHFCF 3 , CF 3 CH = CFCHF 2 , CHF = CFCF 2 CHF 2 CHF 2 CF = CFCHF 2 , CH 2 CF = CFCF 3 , CH 2 FCH = CFCF 3 , CH 2 = CFCHFCF 3 , CH 2 = CFCF 2 CHF 2 CF 3 CH = CFCH 2 F, CHF = CFCH 2 CF 3 , CHF = CHCHFCF 3 , CHF = CHCF 2 CHF 2
CHF2CF=CHCHF2, CHF=CFCHFCHF2, CF3CF=CHCH3, CF2=CHCF2Br, CHF=CBrCHF2 CHBr=CHCF3, CF3CBr=CFCF3, CH2=CBrC2F5, CHBr=CHC2F5, CH2=CH(CF2)2Br; CH2=CHCBrFCF3, CH3CBr=CHCF3, CF3CBr=CHCH3, (CF3)2C=CHBr, CF3CF=CBrC2F5, E- CHF2CBr=CFC2F5, Z-CHF2CBr=CFC2F5, CF2=CBrCHFC2F5, (CF3)2CFCBr=CH2 CHBr=CF(CF2)2CHF2, CH2=CBrCF2CF2CF3, CF2=C(CH2Br)CF3, CH2=C(CBrF2)CF3 (CF3)2CHCH=CHBr, (CF3)2C=CHCH2Br, CH2=CHCF(CF3)CBrF2, CF2=CHCF2CH2CBrF2 CFBr=CHCF3, CFBr=CFCF3 und CH2=CBrCF2CF2CF2CF3, jeweils in der E-Form oder der Z- Form, sowie aus Mischungen der vorgenannten Substanzen. CHF 2 CF = CHCHF 2 , CHF = CFCHFCHF 2 , CF 3 CF = CHCH 3 , CF 2 = CHCF 2 Br, CHF = CBrCHF 2 CHBr = CHCF 3 , CF 3 CBr = CFCF 3 , CH 2 = CBrC 2 F 5 , CHBr = CHC 2 F 5 , CH 2 = CH (CF 2 ) 2 Br ; CH 2 = CHCBrFCF 3 , CH 3 CBr = CHCF 3 , CF 3 CBr = CHCH 3 , (CF 3 ) 2 C = CHBr, CF 3 CF = CBrC 2 F 5 , E-CHF 2 CBr = CFC 2 F 5 , Z -CHF 2 CBr = CFC 2 F 5 , CF 2 = CBrCHFC 2 F 5 , (CF 3 ) 2 CFCBr = CH 2 CHBr = CF (CF 2 ) 2 CHF 2 , CH 2 = CBrCF 2 CF 2 CF 3 , CF 2 = C (CH 2 Br) CF 3 , CH 2 = C (CBrF 2 ) CF 3 (CF 3 ) 2 CHCH = CHBr, (CF 3 ) 2 C = CHCH 2 Br, CH 2 = CHCF (CF 3 ) CBrF 2 , CF 2 = CHCF 2 CH 2 CBrF 2 CFBr = CHCF 3 , CFBr = CFCF 3 and CH 2 = CBrCF 2 CF 2 CF 2 CF 3 , each in the E-form or the Z-form, as well as mixtures of the aforementioned substances ,
bevorzugtes Treibmittel d) stellt das E-CF3CH=CHF (E-1 ,3,3,3-Tetrafluorpropen-1) dar. Die Menge an Treibmittel wird bei den Gewichtsangaben für die übrigen Komponenten der erfindungsgemäßen Zusammensetzungen nicht berücksichtigt. preferred blowing agent d) represents the E-CF 3 CH = CHF (E-1, 3,3,3-tetrafluoropropene-1). The amount of blowing agent is not taken into account in the weight data for the other components of the compositions according to the invention.
Die treibmittelfreie erfindungsgemäße Zusammensetzung wird mit dem gesamten Treibmittel (Treibmittel gemäß Formel (I), insbesondere Fluorkohlenstoff oder einem Fluorkohlenwasserstoff d)i) oder d)ii) und gegebenenfalls weitere Treibmittel) in einem Gewichtsverhältnis Zusammensetzung/Treibmittel von 2/98 bis 98/2, bevorzugt 5/95 bis 95/5, weiter bevorzugt 10/90 bis 90/10, besonders bevorzugt 15/85 bis 85/15, außerordentlich bevorzugt 20/80 bis 80/20, weiterhin bevorzugt 30/70 bis 70/30 sowie auch 40/60 bis 60/40 und 50/50, in einer geeigneten Aerosol- Spraydose abgefüllt.  The propellant-free composition according to the invention is mixed with the entire propellant (propellant according to formula (I), in particular fluorocarbon or a fluorohydrocarbon d) i) or d) ii) and optionally further propellants) in a composition / propellant weight ratio from 2/98 to 98/2 , preferably 5/95 to 95/5, more preferably 10/90 to 90/10, more preferably 15/85 to 85/15, still more preferably 20/80 to 80/20, further preferably 30/70 to 70/30, and also 40/60 to 60/40 and 50/50, filled in a suitable aerosol spray can.
Besonders bevorzugt ist das £-CF3CH=CHF (£-1 ,3,3,3-Tetrafluorpropen-1) als einziges Treibmittel enthalten. Es ist aber auch möglich, den oder die Fluorkohlenstoffe oder den oder die Fluorkohlenwasserstoff d)i) oder d)ii) in Kombination mit mindestens einem weiteren Treibmittel, ausgewählt aus Propan, Propen, n-Butan, iso-Butan, iso-Buten, n-Pentan, Penten, iso-Pentan, iso-Penten, Methan, Ethan, Dimethylether, Stickstoff, Kohendioxid, Luft, Sauerstoff, Lachgas, 1 ,1 ,1 ,3-Tetrafluorethan, Heptafluoro-n-propan, Perfluorethan, Monochlordifluormethan, 1 ,1 - Difluorethan, sowie Mischungen dieser Treibmittel, einzusetzen. Most preferably, the £ -CF 3 CH = CHF (£ -1, 3,3,3-tetrafluoropropene-1) is contained as the sole propellant. However, it is also possible to use the fluorocarbon (s) or the fluorocarbon (s) d) i) or d) ii) in combination with at least one further blowing agent selected from propane, propene, n-butane, isobutane, isobutene, n-pentane, pentene, iso-pentane, iso-pentene, methane, ethane, dimethyl ether, nitrogen, carbon dioxide, air, oxygen, nitrous oxide, 1, 1, 1, 3-tetrafluoroethane, heptafluoro-n-propane, perfluoroethane, monochlorodifluoromethane, 1, 1 - difluoroethane, and mixtures of these blowing agents to use.
Die erfindungsgemäßen Zusammensetzungen sind mit dem Treibmittel in einem geeigneten Druckbehälter verpackt. Als Druckbehälter kommen Gefäße aus Metall (Aluminium, Weißblech, Zinn), geschütztem bzw. nicht-splitterndem Kunststoff oder aus Glas, das außen mit Kunststoff beschichtet ist, in Frage, bei deren Auswahl Druck- und Bruchfestigkeit, Korrosionsbeständigkeit, leichte Füllbarkeit wie auch ästhetische Gesichtspunkte, Handlichkeit, Bedruckbarkeit etc. eine Rolle spielen. Spezielle Innenschutzlacke gewährleisten die Korrosionsbeständigkeit gegenüber der erfindungsgemäßen Suspension. Ein erfindungsgemäß bevorzugter Innenschutzlack ist ein Epoxy-Phenollack. Besonders bevorzugt weisen die verwendeten Ventile einen innenlackierten Ventilteller auf, wobei Lackierung und Ventilmaterial miteinander kompatibel sind. Werden Aluminiumventile eingesetzt, so können deren Ventilteller innen z. B. mit Micoflex-Lack beschichtet sein. Werden erfindungsgemäß Weißblechventile eingesetzt, so können deren Ventilteller innen z. B. mit PET (Polyethylenterephthalat) beschichtet sein.  The compositions of the invention are packaged with the propellant in a suitable pressure vessel. Containers made of metal (aluminum, tinplate, tin), protected or non-splitterndem plastic or glass, which is coated with plastic on the outside, in question, in their selection pressure and fracture resistance, corrosion resistance, easy fillability as well as aesthetic Aspects, handiness, printability etc. play a role. Special internal protective lacquers ensure the corrosion resistance with respect to the suspension according to the invention. An inner protective lacquer which is preferred according to the invention is an epoxy phenolic lacquer. Particularly preferably, the valves used on an internally painted valve disc, wherein the coating and valve material are compatible with each other. If aluminum valves are used, their valve plates can be internally z. B. be coated with Micoflex paint. If tinplate valves are used according to the invention, their valve disks can be internally z. B. be coated with PET (polyethylene terephthalate).
Die erfindungsgemäßen Zusammensetzungen können auch in einem Mehrkammerspender verpackt sein. Der Mehrkammerspender kann auch so eingesetzt werden, dass eine Kammer mit der erfindungsgemäßen Zusammensetzung befüllt ist, während eine andere Kammer das komprimierte Treibmittel enthält. Ein derartiger Mehrkammerspender ist beispielsweise eine so genannte Bag-in-Can-Verpackung. The compositions of the invention may also be packaged in a multi-chamber dispenser. The multi-chamber dispenser can also be used so that one chamber is filled with the composition according to the invention, while another chamber contains the compressed propellant. Such a multi-chamber dispenser is for example a so-called bag-in-can packaging.
Bevorzugte erfindungsgemäße Zusammensetzungen können optional 1 ,4-Dimethylolcyclohexan (= Cyclohexan-1 ,4-dimethanol) enthalten. Dieser Wrkstoff ist insbesondere geeignet, um Rückstände von schweißhemmenden Aluminiumsalzen zu maskieren. Für diese Effekte ist es dabei unerheblich, ob Cyclohexan-1 ,4-dimethanol als reines c/'s-lsomer, als reines trans-lsomer oder als Isomeren-Gemisch aus eis- und irans-lsomeren eingesetzt wird. Im Handel erhältliches 1 ,4-Dime- thylolcyclohexan liegt als cis/trans-lsomerengemisch vor. Dieses Isomerengemisch hat die CAS- Nr. 105-08-8. Ein erfindungsgemäß bevorzugtes Isomerengemisch enthält 29 - 33 Gew.-% cis- Isomer (CAS-Nr. 3236-47-3) und 71 - 67 Gew.-% trans-lsomer (CAS-Nr. 3236-48-4) und weist einen Brechungsindex nD 20 von 1 ,487 auf. Erfindungsgemäß bevorzugte Deodorant- oder Anti- transpirant-Zusammensetzungen enthalten, bezogen auf ihr treibmittelfreies Gesamtgewicht, 1 - 12 Gew.-%, bevorzugt 2 - 10 Gew.-%, besonders bevorzugt 3 - 7 Gew.-% 1 ,4-Dimethylolcyclo- hexan. Preferred compositions of the invention may optionally contain 1, 4-dimethylolcyclohexane (= cyclohexane-1, 4-dimethanol). This material is particularly suitable for masking residues of antiperspirant aluminum salts. It is there for these effects immaterial whether cyclohexane-1, 4-dimethanol as a pure c / 's-isomer, as a pure trans-isomer or as a mixture of isomers of cis- and iran-isomer is used. Commercially available 1,4-dimethylolcyclohexane is present as a cis / trans isomeric mixture. This isomer mixture has the CAS No. 105-08-8. A preferred isomer mixture according to the invention contains 29-33% by weight of cis-isomer (CAS No. 3236-47-3) and 71-67% by weight of trans-isomer (CAS No. 3236-48-4) and has a refractive index n D 20 of 1.487. According to preferred deodorant or antiperspirant compositions according to their propellant-free total weight, 1-12 wt .-%, preferably 2-10 wt .-%, particularly preferably 3-7 wt .-% 1, 4-dimethylolcyclo hexane.
Eine weitere bevorzugte Ausführungsform der Erfindung ist dadurch gekennzeichnet, dass 0,01 - 5 Gew.-%, bevorzugt 0,05 - 2 Gew.-%, besonders bevorzugt 0,1 - 1 Gew.-%, jeweils bezogen auf die gesamte erfindungsgemäße Zusammensetzung, einer aus einem natürlichen Mineralwasser, einem Thermalwasser oder einem natürlichen Heilwasser erhaltenen Mineralstoffmischung enthalten ist. Überraschend wurde festgestellt, dass derartige Mineralstoffmischungen die schweißhemmende Leistung der erfindungsgemäßen Zusammensetzungen weiter verbessern können. Außerdem können sich derartige Mineralstoffmischungen günstig auf die Hautverträglichkeit der erfindungsgemäßen Zusammensetzungen auswirken. Die Bezeichnung„natürliches Mineralwasser" richtet sich nach der Definition der deutschen Mineral- und Tafelwasserverordnung (MinTafWV, § 2). Als Mineralstoffmischung gilt der feste Rückstand der genannten Wässer. Erfindungsgemäß besonders bevorzugte Mineralstoffmischungen stammen aus dem Thermalwasser von La Toja (Spanien), Bad Blumau, Bad Radkersburg, Aachen, Wiesbaden (alle Deutschland), Karlsbad (Tschechien), La Bourboule, Enghien-les-bains, Allevard-les-bains, Digne, Nyrac-Ies- bains, Lons le Saunier, Eaux Bonnes, Rochefort, les Fumades, Saint Christau, Uriage-les-bains, la Roche-Posay (alle Frankreich) oder den natürlichen Mineralwässern oder Heilwässern von Evian, Volvic, Vichy, Avene, Vittel (alle Frankreich), Gerolstein oder Fachingen (Deutschland). Weitere erfindungsgemäß bevorzugte Zusammensetzungen enthalten mindestens ein wasserlösliches mehrwertiges C2 - C9-Alkanol mit 2 - 6 Hydroxylgruppen und/oder mindestens ein wasserlösliches Polyethylenglycol mit 3 - 20 Ethylenoxid-Einheiten sowie Mischungen hiervon, um die Stabilität der Zusammensetzungen weiter zu verbessern. A further preferred embodiment of the invention is characterized in that 0.01 to 5 wt .-%, preferably 0.05 to 2 wt .-%, particularly preferably 0.1 to 1 wt .-%, each based on the total inventive Composition, a mineral mixture obtained from a natural mineral water, a thermal water or a natural healing water is included. Surprisingly, it has been found that such mineral mixtures can further improve the antiperspirant performance of the compositions according to the invention. In addition, such mineral mixtures may have a favorable effect on the skin compatibility of the compositions according to the invention. The term "natural mineral water" is based on the definition of the German Mineral and Table Water Ordinance (MinTafWV, § 2) .The mineral mixture is considered to be the solid residue of the named waters.Occupationally preferred mineral mixtures originate from the thermal water of La Toja (Spain), Bad Blumau, Bad Radkersburg, Aachen, Wiesbaden (all Germany), Carlsbad (Czech Republic), La Bourboule, Enghien-les-bains, Allevard-les-bains, Digne, Nyrac-Ies- bains, Lons le Saunier, Eaux Bonnes, Rochefort, les Fumades, Saint Christau, Uriage-les-bains, La Roche-Posay (all France) or the natural mineral or medicinal waters of Evian, Volvic, Vichy, Avene, Vittel (all France), Gerolstein or Fachingen (Germany) preferred compositions contain at least one water-soluble polyhydric C 2 -C 9 -alkanol with 2-6 hydroxyl groups and / or at least one water-soluble polyethylene glycol with 3 20 ethylene oxide units and mixtures thereof to further improve the stability of the compositions.
Erfindungsgemäß wird unter Wasserlöslichkeit eine Löslichkeit von wenigstens 5 Gew.-% bei 20 °C verstanden, das heißt, dass Mengen von wenigstens 5 g des Polyols in 95 g Wasser bei 20 °C löslich sind. Bevorzugte erfindungsgemäße Zusammensetzungen enthalten mindestens ein wasserlösliches mehrwertiges C2 - C9-Alkanol mit 2 - 6 Hydroxylgruppen und/oder mindestens ein wasserlösliches Polyethylenglycol mit 3 - 20 Ethylenoxid-Einheiten sowie Mischungen hiervon. Bevorzugt sind diese Komponenten ausgewählt aus 1 ,2-Propylenglycol, 1 ,3-Propylen- glycol, 2-Methyl-1 ,3-propandiol, Glycerin, 1 ,2-Butylenglycol, 1 ,3-Butylenglycol und 1 ,4-Butylengly- col, Pentylenglycolen wie 1 ,2-Pentandiol und 1 ,5-Pentandiol, Hexandiolen wie 1 ,2-Hexandiol und 1 ,6-Hexandiol, Hexantriolen wie 1 ,2,6-Hexantriol, 1 ,2-Octandiol, 1 ,8-Octandiol, Dipropylenglycol, Tripropylenglycol, Diglycerin, Triglycerin, Erythrit, Sorbit sowie Mischungen der vorgenannten Substanzen. Geeignete wasserlösliche Polyethylenglycole sind ausgewählt aus PEG-3, PEG-4, PEG-6, PEG-7, PEG-8, PEG-9, PEG-10, PEG-12, PEG-14, PEG-16, PEG-18 und PEG-20 sowie Mischungen hiervon, wobei PEG-3 bis PEG-8 bevorzugt sind. Water solubility according to the invention is understood to mean a solubility of at least 5% by weight at 20 ° C., that is to say amounts of at least 5 g of the polyol in 95 g of water are soluble at 20 ° C. Preferred compositions according to the invention contain at least one water-soluble polyhydric C 2 -C 9 -alkanol having 2 to 6 hydroxyl groups and / or at least one water-soluble polyethylene glycol having 3 to 20 ethylene oxide units and mixtures thereof. These components are preferably selected from 1,2-propylene glycol, 1,3-propylene glycol, 2-methyl-1,3-propanediol, glycerol, 1,2-butylene glycol, 1,3-butylene glycol and 1,4-butylene glycol. col, pentyleneglycols such as 1, 2-pentanediol and 1, 5-pentanediol, hexanediols such as 1, 2-hexanediol and 1, 6-hexanediol, hexanetriols such as 1, 2,6-hexanetriol, 1, 2-octanediol, 1, 8- Octanediol, dipropylene glycol, tripropylene glycol, diglycerol, triglycerol, erythritol, sorbitol and mixtures of the aforementioned substances. Suitable water-soluble polyethylene glycols are selected from PEG-3, PEG-4, PEG-6, PEG-7, PEG-8, PEG-9, PEG-10, PEG-12, PEG-14, PEG-16, PEG-18 and PEG-20 and mixtures thereof, with PEG-3 to PEG-8 being preferred.
Besonders bevorzugte erfindungsgemäße Zusammensetzungen enthalten das mindestens eine wasserlösliche mehrwertige C2 - C9-Alkanol mit 2 - 6 Hydroxylgruppen und/oder mindestens eine wasserlösliche Polyethylenglycol mit 3 - 20 Ethylenoxid-Einheiten in einer Gesamtmenge von 0,5 - 30 Gew.-%, bevorzugt 3 - 20 Gew.-%, besonders bevorzugt 5 - 10 Gew.-%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien Zusammensetzung. Particularly preferred compositions according to the invention comprise the at least one water-soluble polyhydric C 2 -C 9 -alkanol having 2 to 6 hydroxyl groups and / or at least one water-soluble polyethylene glycol having 3 to 20 ethylene oxide units in a total amount of 0.5 to 30% by weight, preferably 3 to 20 wt .-%, particularly preferably 5 to 10 wt .-%, each based on the total weight of the blowing agent-free composition.
Insbesondere die vorstehend beschriebenen Wasser-in-ÖI-Emulsionen enthalten bevorzugt mindestens ein wasserlösliches mehrwertiges C2 - C9-Alkanol mit 2 - 6 Hydroxylgruppen und/oder mindestens ein wasserlösliches Polyethylenglycol mit 3 - 20 Ethylenoxid-Einheiten insgesamt in Mengen von 3 - 30 Gew.-%, bevorzugt 8 - 25 Gew.-%, besonders bevorzugt 10 - 18 Gew.-%, jeweils bezogen auf die treibmittelfreie Zusammensetzung. Besonders bevorzugt sind diese Wasser-in-ÖI-Emulsionen mit £-CF3CH=CHF (£-1 ,3,3,3-Tetrafluorpropen-1) als Treibmittel in einer Aerosol-Abgabevorrichtung verpackt. In particular, the above-described water-in-oil emulsions preferably contain at least one water-soluble polyhydric C 2 -C 9 -alkanol having 2 to 6 hydroxyl groups and / or at least one water-soluble polyethylene glycol having 3 to 20 ethylene oxide units in total in amounts of 3 to 30 Wt .-%, preferably 8 - 25 wt .-%, particularly preferably 10 - 18 wt .-%, each based on the blowing agent-free composition. Most preferably, these water-in-oil emulsions are packaged with ε-CF 3 CH = CHF (ε -1, 3,3,3-tetrafluoropropene-1) as a propellant in an aerosol dispenser.
Weiterhin erfindungsgemäß besonders bevorzugt sind Zusammensetzungen, enthaltend  Further particularly preferred according to the invention are compositions comprising
10 - 85 Gew.-%, bevorzugt 15 - 75 Gew.-%, besonders bevorzugt 20 - 65 Gew.-%, freies Wasser,  From 10 to 85% by weight, preferably from 15 to 75% by weight, particularly preferably from 20 to 65% by weight, of free water,
mindestens ein Tensid in einer Gesamtmenge von 0,2 - 20 Gew.-%, besonders bevorzugt 0,5 - 10 Gew.-%, außerordentlich bevorzugt 1 - 8 Gew.-%,  at least one surfactant in a total amount of 0.2-20% by weight, more preferably 0.5-10% by weight, most preferably 1-8% by weight,
mindestens einen Antitranspirant-Wirkstoff und/oder mindestens einen Deodorant-Wrkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%,  at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1-50% by weight,
wobei sich die Mengenangaben auf das Gesamtgewicht der treibmittelfreien Zusammensetzung beziehen, sowie £-CF3CH=CHF (£-1 ,3,3,3-Tetrafluorpropen-1) als Treibmittel. wherein the amounts are based on the total weight of the propellant-free composition, and £ -CF 3 CH = CHF (£ -1, 3,3,3-tetrafluoropropene-1) as a propellant.
Weitere erfindungsgemäß bevorzugte Zusammensetzungen enthalten mindestens einen Hydro- gelbildner. Derartige Zusammensetzungen weisen eine verbesserte Temperaturstabilität auf. Bevorzugte Hydrogelbildner sind ausgewählt aus Celluloseethern, vor allem Hydroxyalkylcellulo- sen, insbesondere Hydroxypropylcellulose, Hydroxypropylmethylcellulose, Hydroxyethylcellulose, Carboxymethylcellulose, Cetylhydroxyethylcellulose, Hydroxybutylmethylcellulose, Methyl- hydroxyethylcellulose, weiterhin Xanthan-Gum, Sclerotium Gum, Succinoglucanen, Polygalacto- mannanen, insbesondere Guar-Gums und Johannisbrotkernmehl (Locust Bean Gum), insbesondere Guar-Gum und Locust Bean Gum selbst und den nichtionischen Hydroxyalkylguar- derivaten und Johannisbrotkernmehl-Derivaten, wie Hydroxypropylguar, Carboxymethylhydroxy- propylguar, Hydroxypropylmethylguar, Hydroxyethylguar und Carboxymethylguar, weiterhin Pectinen, Agar, Carragheen (Carrageenan), Traganth, Gummi arabicum, Karayagummi, Taragummi, Gellan, Gelatine, Casein, Pektin, Propylenglycolalginat, Alginsäuren und deren Salzen, insbesondere Natriumalginat, Kaliumalginat und Calciumalginat, weiterhin Polyvinylpyrrolidonen, Polyvinylalkoholen, Polyacrylamiden, weiterhin physikalisch (z. B. durch Vorverkleisterung) und/oder chemisch modifizierten Stärken, insbesondere hydroxypropylierten Stärkephosphaten und Octenylstärkesuccinaten und deren Aluminium-, Calcium- oder Natriumsalzen, weiterhin wasserlöslichen Acrylsäure-Acrylat-Copolymeren, Acrylsäure-Acrylamid-Copolymeren, Acryl- säure-Vinylpyrrolidon-Copolymeren, Acrylsäure-Vinylformamid-Copolymeren und Polyacrylaten. Erfindungsgemäß bevorzugte Zusammensetzungen enthalten mindestens einen Hydrogelbildner in einer Gesamtmenge von 0,1 - 3,0 Gew.-%, bevorzugt 0,3 - 2, 0 Gew.-%, besonders bevorzugt 0,5 - 1 ,5 Gew.-% und außerordentlich bevorzugt 0,7 - 1 ,0 Gew.-%, jeweils bezogen auf das Gesamtgewicht der gesamten erfindungsgemäßen Zusammensetzung. Further inventively preferred compositions contain at least one hydrogel former. Such compositions have improved temperature stability. Preferred hydrogel formers are selected from cellulose ethers, especially hydroxyalkylcelluloses, in particular hydroxypropylcellulose, hydroxypropylmethylcellulose, hydroxyethylcellulose, carboxymethylcellulose, cetylhydroxyethylcellulose, hydroxybutylmethylcellulose, methylhydroxyethylcellulose, furthermore xanthan gum, sclerotium gum, succinoglucans, polygalactomannans, in particular guar gum and locust bean gum (Locust bean gum), in particular guar gum and locust bean gum itself and the nonionic hydroxyalkyl guar derivatives and locust bean gum derivatives such as hydroxypropyl guar, carboxymethylhydroxy propylguar, hydroxypropylmethylguar, hydroxyethylguar and carboxymethylguar, furthermore pectins, agar, carrageenan, tragacanth, gum arabic, karaya gum, tara gum, gellan, gelatin, casein, pectin, propylene glycol alginate, alginic acids and their salts, especially sodium alginate, potassium alginate and calcium alginate Polyvinylpyrrolidones, polyvinyl alcohols, polyacrylamides, furthermore physically (eg by pre-gelatinization) and / or chemically modified starches, in particular hydroxypropylated starch phosphates and octenyl starch succinates and their aluminum, calcium or sodium salts, furthermore water-soluble acrylic acid-acrylate copolymers, acrylic acid-acrylamide Copolymers, acrylic acid-vinylpyrrolidone copolymers, acrylic acid-vinylformamide copolymers and polyacrylates. Compositions preferred according to the invention comprise at least one hydrogel former in a total amount of 0.1-3.0% by weight, preferably 0.3-2.0% by weight, more preferably 0.5-1.5% by weight and extraordinarily preferably 0.7-1.0% by weight, in each case based on the total weight of the total composition according to the invention.
In einer weiteren bevorzugten Ausführungsform sind die erfindungsgemäßen Zusammensetzungen als Hydrogel ausgebildet und enthalten mindestens einen Hydrogelbildner in einer Gesamtmenge von 0,1 - 3,0 Gew.-%, bevorzugt 0,3 - 2, 0 Gew.-%, besonders bevorzugt 0,5 - 1 ,5 Gew.- % und außerordentlich bevorzugt 0,7 - 1 ,0 Gew.-%, jeweils bezogen auf das Gesamtgewicht der gesamten erfindungsgemäßen Zusammensetzung.  In a further preferred embodiment, the compositions according to the invention are in the form of hydrogels and contain at least one hydrogel former in a total amount of 0.1-3.0% by weight, preferably 0.3-2.0% by weight, particularly preferably 0, 5-1.5% by weight and most preferably 0.7-1.0% by weight, based in each case on the total weight of the total composition according to the invention.
Erfindungsgemäß besonders bevorzugte Zusammensetzungen enthalten weiterhin bevorzugt mindestens einen hautkühlenden Wirkstoff enthalten. Erfindungsgemäß geeignete hautkühlende Wirkstoffe sind beispielsweise Menthol, Isopulegol sowie Mentholderivate, z. B. Menthyllactat, Menthylglycolat, Menthylpyrrolidoncarbonsäure, Menthylmethylether, Menthoxypropandiol, Men- thonglycerinacetal (9-Methyl-6-(1 -methylethyl)-1 ,4-dioxaspiro (4.5)decan-2-methanol), Monomen- thylsuccinat und 2-Hydroxymethyl-3,5,5-trimethylcyclohexanol. Als hautkühlende Wrkstoffe bevorzugt sind Menthol, Isopulegol, Menthyllactat, Menthoxypropandiol und Menthylpyrrolidoncarbonsäure sowie Mischungen dieser Substanzen, insbesondere Mischungen von Menthol und Menthyllactat, Menthol, Mentholglycolat und Menthyllactat, Menthol und Menthoxypropandiol oder Menthol und Isopulegol. Erfindungsgemäß besonders bevorzugt ist, dass mindestens ein hautkühlender Wrkstoff in einer Gesamtmenge von 0,01 - 1 Gew.%, besonders bevorzugt 0,02 - 0,5 Gew.% und außerordentlich bevorzugt 0,05 - 0,2 - 0,3 Gew.%, jeweils bezogen auf das Gesamtgewicht der treibmittelfreien Zusammensetzung, enthalten ist.  Compositions which are particularly preferred according to the invention furthermore preferably contain at least one skin-cooling active substance. Skin-cooling active ingredients suitable according to the invention are, for example, menthol, isopulegol and menthol derivatives, eg. For example, menthyl lactate, menthyl glycolate, menthyl pyrrolidone carboxylic acid, menthyl methyl ether, menthoxypropanediol, methionyl glycerol acetal (9-methyl-6- (1-methylethyl) -1,4-dioxaspiro (4.5) decane-2-methanol), monomethyl succinate and 2-hydroxymethyl -3,5,5-trimethylcyclohexanol. Preferred skin-cooling active substances are menthol, isopulegol, menthyl lactate, menthoxypropanediol and menthylpyrrolidonecarboxylic acid, and also mixtures of these substances, in particular mixtures of menthol and menthyl lactate, menthol, menthol glycolate and menthyl lactate, menthol and menthoxypropanediol or menthol and isopulegol. It is particularly preferred according to the invention for at least one skin-cooling active substance to be present in a total amount of 0.01-1% by weight, more preferably 0.02-0.5% by weight and most preferably 0.05-0.2-0.3% by weight %, in each case based on the total weight of the propellant-free composition is included.
Die erfindungsgemäßen Zusammensetzungen können weitere Zusatzstoffe enthalten, wie beispielsweise pH-Wertregulatoren, Puffersubstanzen, Elektrolyte, Konservierungsmittel, Komplexbildner, Antioxidantien, Verdickungsmittel, Pigmente, Farbstoffe, Antifaltenwirkstoffe, Wrkstoffe, die die Hautfeuchtigkeit steigern, z. B. Harnstoff, alkylsubstituierte Harnstoffe, Betain, oder Carni- tin, Pflanzenextrakte, alpha-Hydroxycarbonsäuren. Bevorzugte erfindungsgemäße Deodorant- oder Antitranspirant-Zusammensetzungen enthalten mindestens einen Riechstoff. Die Riechstoffe sind wie im Prioritätsdokument zu dieser Anmeldung, DE102010055816.8, auf Seite 66, Zeile 1 bis Seite 67, drittletzte Zeile, offenbart. Besonders bevorzugte erfindungsgemäße Dodorant- oder Antitranspirant-Zusammensetzungen sind dadurch gekennzeichnet, dass mindestens eine Riechstoffkomponente in einer Gesamtmenge von 0,00001 bis 10 Gew.-%, bevorzugt 0,5 - 7 Gew.-%, besonders bevorzugt 1 - 5 Gew.- %, jeweils bezogen auf die treibmittelfreie Zusammensetzung, enthalten ist. The compositions of the invention may contain other additives such as pH regulators, buffering agents, electrolytes, preservatives, chelating agents, antioxidants, thickeners, pigments, dyes, anti-wrinkle agents, active ingredients which increase skin moisture, e.g. As urea, alkyl-substituted ureas, betaine, or carnitine, plant extracts, alpha-hydroxycarboxylic acids. Preferred deodorant or antiperspirant compositions according to the invention comprise at least one perfume. The fragrances are as disclosed in the priority document to this application, DE102010055816.8, on page 66, line 1 to page 67, third last line. Particularly preferred according to the invention Dodorant- or antiperspirant compositions are characterized in that at least one fragrance component in a total amount of 0.00001 to 10 wt .-%, preferably 0.5 to 7 wt .-%, particularly preferably 1 - 5 wt. %, in each case based on the propellant-free composition is included.
In einer weiteren bevorzugten Ausführungsform enthalten die erfindungsgemäßen Zusammensetzungen mindestens eine den Haarwuchs inhibierende Substanz. Bevorzugte erfindungsgemäße Zusammensetzungen enthalten mindestens eine den Haarwuchs inhibierende Substanz in einer Gesamtmenge von 0,0001 - 5 Gew.-%, bevorzugt 0,001 - 2 Gew.-%, besonders bevorzugt 0,01 - 1 Gew.-%, und außerordentlich bevorzugt 0,1 - 0,5 Gew.-%, jeweils bezogen auf das Gewicht an Aktivsubstanz des/der Haarwuchs inhibierenden Wirkstoffs/e und das Gesamtgewicht der treibmittelfreien erfindungsgemäßen Zusammensetzung. In a further preferred embodiment, the compositions according to the invention comprise at least one hair growth inhibiting substance. Preferred compositions according to the invention comprise at least one hair growth inhibiting substance in a total amount of 0.0001-5 wt.%, Preferably 0.001-2 wt.%, Particularly preferably 0.01-1 wt.%, And most preferably 0, 1 to 0.5% by weight, based in each case on the weight of the active substance of the hair growth inhibiting active substance (s) and the total weight of the propellant-free composition according to the invention.
Enthaltene Wirkstoffe, insbesondere Deodorant-Wrkstoffe, Riechstoffe und/oder hautkühlende Wrkstoffe, können bevorzugt auch in verkapselter Form enthalten sein.  Contained active substances, in particular deodorant active substances, fragrances and / or skin-cooling active substances, may preferably also be present in encapsulated form.
Enthaltene Wirkstoffe, insbesondere Deodorant-Wrkstoffe, Riechstoffe und/oder hautkühlende Wrkstoffe, können bevorzugt auch in geträgerter Form, beispielsweise auf Zeolith, Titandioxid, Silica und anderen Adsorbentien, enthalten sein.  Contained active substances, in particular deodorant active substances, fragrances and / or skin-cooling active substances, may preferably also be present in supported form, for example on zeolite, titanium dioxide, silica and other adsorbents.
Enthaltene Wirkstoffe, insbesondere Deodorant-Wrkstoffe, Riechstoffe und/oder hautkühlende Wrkstoffe, können bevorzugt auch in komplexierter Form, beispielsweise Cyclodextrin- komplexiert, enthalten sein.  Contained active substances, in particular deodorant active substances, fragrances and / or skin-cooling active substances, may preferably also be complexed in form, for example cyclodextrin, to be present.
Die nachfolgenden Formulierungsbeispiele sollen den Gegenstand der Erfindung erläutern, ohne ihn hierauf zu beschränken.  The following formulation examples are intended to illustrate the subject matter of the invention without limiting it thereto.
Beispiel 1 : Erfindungsgemäße Antitranspirant-Emulsionen (ÖI-in-Wasser-Emulsionen) (Mengenangaben in Gew.-%)  Example 1 Antiperspirant Emulsions According to the Invention (Oil-in-Water Emulsions) (Quantities in% by Weight)
Figure imgf000065_0001
20 Gewichtsteile der vorstehenden schweißhemmenden Emulsionen 1 .1
Figure imgf000065_0001
20 parts by weight of the above antiperspirant emulsions 1 .1
mit 80 Gewichtsteilen £-CF3CH=CHF in einer Spraydose abgefüllt. filled with 80 parts by weight of £ -CF 3 CH = CHF in a spray can.
Sprühfähige, translucente Antitranspirant-Mikroemulsionen (Angaben in Gew.-%) Sprayable, translucent antiperspirant microemulsions (in% by weight)
Figure imgf000066_0001
Figure imgf000066_0001
15 Gewichtsteile der vorstehenden schweißhemmenden Emulsionen 2.1  15 parts by weight of the above antiperspirant emulsions 2.1
mit 85 Gewichtsteilen £-CF3CH=CHF in einer Spraydose abgefüllt. filled with 85 parts by weight of £ -CF 3 CH = CHF in a spray can.
Wasser-in-ÖI-Emulsionssprays Water-in-oil emulsion spray
Beispiel 3.1 Beispiel 3.1 Beispiel 3.2 Beispiel 3.2 Example 3.1 Example 3.1 Example 3.2 Example 3.2
[Gew.-%, [Gew.-%, [Gew.-%, bezo[Gew.-%, bezobezogen auf bezogen auf gen auf Gesamtgen auf W/O- GesamtzubeW/O-Emulsion] zubereitung incl. Emulsion] reitung incl. Treibgas] [% By weight, [% by weight, [% by weight, bezo [% by weight, based on gen up to total amount on W / O GesamtzubeW / O emulsion] preparation including emulsion preparation incl Propellant]
Treibgas]  LPG]
Dow Corning 345 2,0 12,5 1 ,0 4,9  Dow Corning 345 2.0 12.5 1, 0 4.9
Fluid fluid
1 ,4-Dimethylol- 0,5 3,1 2,0 9,8  1,4-dimethylol-0.5, 3.1, 2.0, 9.8
cyclohexan cyclohexane
Dow Corning 5225 3,0 16,9 (Ol) 2,5 1 1 ,0 (Ol) C 1 ,9 (Emulgator) 1 ,2 (Emulgator) 2-Ethylhexyl- 0,5 3,1 0,5 2,4 Dow Corning 5225 3.0 16.9 (Ol) 2.5 1 1, 0 (Ol) C 1, 9 (Emulsifier) 1, 2 (Emulsifier) 2-ethylhexyl-0.5 3.1 0.5 2.4
palmitat  palmitate
Phenoxyethanol 0,08 0,5 0,1 0,5  Phenoxyethanol 0.08 0.5 0.1 0.5
Wasser, 4,92 30,7 7,15 34,9  Water, 4.92 30.7 7.15 34.9
vollentsalzt  desalinated
Microdry 5,0 31 ,3 7,25 35,3  Microdry 5.0 31, 3 7.25 35.3
£-CF3CH=CHF 84,0 - 79,5 - £ -CF 3 CH = CHF 84.0 - 79.5 -
W/O-Emulsions-Kompaktspray W / O emulsion Compact Spray
Figure imgf000067_0001
Figure imgf000067_0001
Beispielzusammensetzung 4.1 enthält eine erfindungsgemäße Antitranspirant-Emulsion mit 9,9 Example Composition 4.1 contains an antiperspirant emulsion according to the invention with 9.9
Gew.-% Aluminiumchlorohydrat, bezogen auf das Gewicht der treibgasfreien Emulsion. Mit einer Sprührate von 0,35 g/s versprüht man in der Sekunde 0,035 g des schweißhemmenden Wrkstoffs Aluminiumchlorohydrat auf die Hautoberfläche. % By weight of aluminum chlorohydrate, based on the weight of the propellant-free emulsion. With a spray rate of 0.35 g / s, 0.035 g of the antiperspirant active substance aluminum chlorohydrate are sprayed onto the skin surface every second.
Beispielzusammensetzung 4.2 enthält eine erfindungsgemäße Antitranspirant-Emulsion mit 17,49 Gew.-% Aluminiumchlorohydrat, bezogen auf das Gewicht der treibgasfreien Emulsion. Mit einer Sprührate von 0,2 g/s versprüht man in der Sekunde 0,035 g des schweißhemmenden Wirkstoffs Aluminiumchlorohydrat auf die Hautoberfläche. Example Composition 4.2 contains an antiperspirant emulsion according to the invention with 17.49% by weight aluminum chlorohydrate, based on the weight of the propellant-free emulsion. At a spray rate of 0.2 g / s, 0.035 g of the antiperspirant active ingredient aluminum chlorohydrate is sprayed onto the skin surface every second.
Wasser-in-ÖI-Emulsion zur Darreichung als Spray (mitTreibgas) (Angaben in Gew.-%) Water-in-oil emulsion for administration as a spray (with propellant) (in% by weight)
Beispiel 5.1  Example 5.1
Aluminiumchlorhydrat 33  Aluminum chlorohydrate 33
C 0-C 3-Isoalkan 8,9 C 0 -C 3 isoalkane 8.9
PEG/PPG-18/18 Dimethicone 1 ,4  PEG / PPG-18/18 Dimethicone 1, 4
lsoceteth-20 0,5  Isoceteth-20 0.5
Dimethicone(5 cSt) 4,2 Isopropylmyristat 9,0 Dimethicone (5 cSt) 4.2 Isopropyl myristate 9.0
1 ,2-Propandiol 5,0  1, 2-propanediol 5.0
1 ,4-Dimethylolcyclohexan 4,0  1,4-dimethylolcyclohexane 4.0
Phenoxyethanol 0,50  Phenoxyethanol 0.50
Parfüm 2,5  Perfume 2.5
Wasser ad 100  Water ad 100
15 Gewichtsteile der schweißhemmenden Wasser-in-ÖI-Emulsion 5.1 werden zusammen mit 85 Gewichtsteilen £-CF3CH=CHF in einer Spraydose abgefüllt. 15 parts by weight of the water-in-oil antiperspirant emulsion 5.1 are filled in a spray can together with 85 parts by weight of -C-CF 3 CH = CHF.
Schweißhemmender "Crackling foam" Sweat-resistant "Crackling foam"
Figure imgf000068_0001
Figure imgf000068_0001
40 Gewichtsteile der vorstehenden schweißhemmenden "Crackling foam"-Zusammensetzung werden zusammen mit 60 Gewichtsteilen £-CF3CH=CHF in einer Spraydose abgefüllt. Bei Entnahme des Produktes entsteht ein Schaum, der mit einem deutlich hörbaren krachenden, knackenden Geräusch beim Verreiben bzw. beim Schließen der Achseln bricht. 40 parts by weight of the above "cracking foam" antiperspirant composition are filled in a spray can together with 60 parts by weight of -C-CF 3 CH = CHF. When the product is removed, a foam is formed which breaks with a clearly audible crackling, crackling noise when rubbing or when closing the armpits.
Deodorant-Schäume Deodorant foams
Wirkstoff- AerosolAerosol¬ Active agent aerosol aerosol
Rohstoff INCI lösung schaum schaum Raw material INCI solution foam foam
PEG-40 HYDROGENATED  PEG-40 HYDROGENATED
CASTOR OIL, TRIDECETH- CASTOR OIL, TRIDECETH
Lösungsvermittler 9, PROPYLENE GLYCOL, Solubilizer 9, PROPYLENE GLYCOL,
No.660352 (Symrise) AQUA 1 ,25 1 1  No.660352 (Symrise) AQUA 1, 25 1 1
Parfüm PERFUM 1 0,8 0,8 Perfume PERFUM 1 0,8 0,8
Propandiol-1 ,2 PROPYLENE GLYCOL 7,5 6 6 Propanediol-1, 2 PROPYLENE GLYCOL 7,5 6 6
Ethanol 96% vergällt ALCOHOL DENAT. 7,5 6 6  Ethanol 96% denatured ALCOHOL DENAT. 7.5 6 6
Cocamidopropyl PG- Dimonium Chloride  Cocamidopropyl PG-Dimonium Chloride
Phospholipid Arlasilk PTC Phosphate 0,5 0,4 0,4 Phospholipid Arlasilk PTC Phosphate 0.5 0.4 0.4
Citronensäure Monohydrat CITRIC ACID 2 1 ,6 1 ,6Citric acid monohydrate CITRIC ACID 2 1, 6 1, 6
Natronlauge 50% Sodium Hydroxide, Aqua Sodium hydroxide 50% Sodium Hydroxide, Aqua
Standard (Water) 0,9 0,72 0,72Standard (Water) 0.9 0.72 0.72
Vitamin E Acetat TOCOPHERYL ACETATE 0,05 0,04 0,04Vitamin E acetate TOCOPHERYL ACETATE 0.05 0.04 0.04
Wasser vollentsalzt AQUA (WATER) 79,3 63,44 63,44Water demineralized AQUA (WATER) 79.3 63.44 63.44
£-CF3CH=CHF 2,1 bar 5 20 Dimethylether DIMETHYLETHER 15 0 £ -CF 3 CH = CHF 2.1 bar 5 20 Dimethyl ether DIMETHYL ETHER 15 0
Summe 100,00 100,00 100,00  Total 100.00 100.00 100.00
Deodorant-Schäume (Mengenangaben in Gew.-% bezogen auf den Gehalt an Aktivsubstanz) Deodorant foams (amounts in% by weight based on the content of active substance)
Figure imgf000069_0001
Figure imgf000069_0001
Die fertigen Zusammensetzungen Nr. 1 - 5 wurden mit £-CF3CH=CHF im Gewichtsverhältnis £-CF3CH=CHF : Zusammensetzung von 4 : 96 in eine Aerosoldose aus innenbeschichtetem Aluminium oder innenbeschichtetem Weißblech abgefüllt. Die erfindungsgemäßen Beispielzusammensetzungen werden auf die Haut, insbesondere die Achselhaut, aufgetragen. The finished compositions Nos. 1-5 were filled with £ -CF 3 CH = CHF in the weight ratio £ -CF 3 CH = CHF: composition of 4:96 in an aerosol can made of internally coated aluminum or internally coated tinplate. The example compositions according to the invention are applied to the skin, in particular the underarm skin.
Damit ist ein weiterer Gegenstand der vorliegenden Anmeldung ein Verfahren zur nicht-therapeutischen Schweißreduktion, dass dadurch gekennzeichnet ist, dass eine erfindungsgemäße oder eine erfindungsgemäß bevorzugte Zusammensetzung auf die Haut, insbesondere die Achselhaut, aufgetragen wird.  Thus, a further subject of the present application is a method for non-therapeutic sweat reduction, which is characterized in that a composition according to the invention or a preferred composition according to the invention is applied to the skin, in particular the underarm skin.
Bezüglich weiterer bevorzugter Ausführungsformen des erfindungsgemäßen Verfahrens gilt mutatis mutandis das zu den erfindungsgemäßen Zusammensetzungen Gesagte.  With regard to further preferred embodiments of the method according to the invention, what has been said about the compositions according to the invention applies mutatis mutandis.
Liste der verwendeten Rohstoffe List of raw materials used
Komponente INCI Lieferant/Hersteller Component INCI Supplier / Manufacturer
DCW 245 Cyclopentasiloxan Dow CorningDC W 245 cyclopentasiloxane Dow Corning
Dow Corning 345 Fluid Cyclomethicone (Decamethylcyclo- Dow Corning Dow Corning 345 Fluid Cyclomethicone (Decamethylcyclo Dow Corning
pentasiloxan, Dodecamethylcyclo- hexasiloxan)  pentasiloxane, dodecamethylcyclohexasiloxane)
Dow Corning 5225 C Formulation Cyclomethicone, PEG/PPG-18/18 Dow Corning Aid Dimethicone im Gewichtsverhältnis 9:1  Dow Corning 5225 C Formulation Cyclomethicone, PEG / PPG-18/18 Dow Corning Aid Dimethicone in the weight ratio 9: 1
Dow Corning ES 5227 DM Dimethicone (5 cSt), PEG/PPG-18/18 Dow Corning Formulation Aid Dimethicone im Gewichtsverhältnis 3:1  Dow Corning ES 5227 DM Dimethicone (5 cSt), PEG / PPG-18/18 Dow Corning Formulation Aid Dimethicone in the weight ratio 3: 1
Microdry® Aluminium Chlorohydrate Reheis Microdry ® aluminum chlorohydrate Reheis
Plantaren® 1200 LAURYL GLUCOSIDE, ca. 50 % BASF Plantar ® 1200 Lauryl Glucoside, about 50%, BASF
Aktivsubstanz  active substance
Plantaren® 2000 DECYL GLUCOSIDE, BASF Plantar ® 2000 DECYL GLUCOSIDE, BASF
ca. 50 % Aktivsubstanz  about 50% active substance

Claims

Patentansprüche claims
1 . Deodorant- oder Antitranspirant-Zusammensetzung , enthaltend 1 . Deodorant or antiperspirant composition containing
a) 5 - 97 Gew.-% freies Wasser,  a) 5 to 97% by weight of free water,
b) 0, 1 - 30 Gew.-% mindestens eines Tensids,  b) 0, 1 - 30 wt .-% of at least one surfactant,
c) 0, 1 - 50 Gew.-% mindestens eines Deodorant- oder Antitranspirant-Wirkstoffs, wobei sich alle Mengenangaben auf das Gesamtgewicht der treibmittelfreien Deodorant- oder Antitranspirant-Zusammensetzung beziehen,  c) 0.1-50% by weight of at least one deodorant or antiperspirant active ingredient, all quantities being based on the total weight of the deodorant or antiperspirant composition without blowing agent,
d) mindestens ein Treibmittel, ausgewählt aus mindestens einer Verbindung mit 3 s 10 Kohlenstoffatomen gemäß Formel (I)
Figure imgf000071_0001
d) at least one blowing agent selected from at least one compound having 3 s 10 carbon atoms according to formula (I)
Figure imgf000071_0001
worin die Reste R , R2, R3 und R4 unabhängig voneinander ein Wasserstoffatom, ein Bromatom, ein Fluoratom oder eine mit mindestens einem Fluoratom substituierte (CT - C6)-Alkylgruppe bedeuten, in which the radicals R, R 2 , R 3 and R 4, independently of one another, denote a hydrogen atom, a bromine atom, a fluorine atom or a (CT - C 6 ) -alkyl group substituted by at least one fluorine atom,
oder zwei der Reste R , R2, R3 und R4 einen fünf- oder sechsgliedrigen Ring bilden, mit der Maßgabe, dass: or two of the radicals R, R 2 , R 3 and R 4 form a five- or six-membered ring, with the proviso that:
- mindestens einer der Reste R , R2, R3 oder R4 für ein Wasserstoffatom oder ein Fluoratom steht, und at least one of R, R 2 , R 3 or R 4 is a hydrogen atom or a fluorine atom, and
- mindestens einer der Reste R , R2, R3 oder R4 für eine mit mindestens einem Fluoratom substituierte (C^ bis C6)-Alkylgruppe steht oder mindestens zwei der Reste R , R2, R3 und R4 einen fünf- oder sechsgliedrigen Ring bilden . at least one of the radicals R, R 2 , R 3 or R 4 is a (C 1 to C 6 ) -alkyl group substituted by at least one fluorine atom or at least two of the radicals R, R 2 , R 3 and R 4 represent a or form a six-membered ring.
2. Zusammensetzung nach Anspruch 1 , dadurch gekennzeichnet, dass R , R2, R3 oder R4 gemäß Formel (I) unabhängig voneinander ein Wasserstoffatom, ein Fluoratom oder eine mit mindestens einem Fluoratom substituierte (C-^ bis C6)-Alkylgruppe bedeuten, mit der Maßgabe, dass: 2. Composition according to claim 1, characterized in that R, R 2 , R 3 or R 4 according to formula (I) independently of one another a hydrogen atom, a fluorine atom or a substituted with at least one fluorine atom (C ^ -C 6 ) alkyl group mean, with the proviso that:
- mindestens einer der Reste R , R2, R3 oder R4 für ein Wasserstoffatom oder ein Fluoratom steht, und at least one of R, R 2 , R 3 or R 4 is a hydrogen atom or a fluorine atom, and
- mindestens einer der Reste R , R2, R3 oder R4 für eine mit mindestens einem Fluoratom substituierte (C^ bis C6)-Alkylgruppe steht. - At least one of the radicals R, R 2 , R 3 or R 4 is a substituted with at least one fluorine atom (C ^ to C 6 ) alkyl group.
3. Zusammensetzung nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass das Treibmittel d) Treibmittel der Formel (I) aus mindestens einer Verbindung der Gruppe gewählt wird, die gebildet wird aus einem Fluorkohlenstoff oder einem Fluorkohlenwasserstoff aus der Gruppe, bestehend aus einem Fluorkohlenwasserstoff mit der Formel £-R CH=CHR2 oder Z-R CH=CHR2, worin R und R2 unabhängig voneinander eine perfluorierte Cr bis C6-Alkylgruppe darstellen, sowie aus Mischungen der vorgenannten Substanzen, oder 3. The composition according to claim 1 or 2, characterized in that the blowing agent d) blowing agent of the formula (I) is selected from at least one compound of the group formed from a fluorocarbon or a fluorohydrocarbon selected from the group consisting of a fluorohydrocarbon having the formula ε-R CH = CHR 2 or ZR CH = CHR 2 , wherein R and R 2 independently represent a perfluorinated C r to C 6 alkyl group, and from Mixtures of the aforementioned substances, or
einem Fluorkohlenstoff oder einem Fluorkohlenwasserstoff aus der Gruppe, bestehend aus CF3CF=CHF, CF3CH=CF2, CHF2CF=CF2, CHF2CH=CHF, CF3CF=CH2, CF3CH=CHF, CH2FCF=CF2, CHF2CH=CF2, CHF2CF=CHF, CHF2CF=CH2, CF3CH=CH2, CH3CF=CF2, CH2FCH=CF2, CH2FCF=CHF, CHF2CH=CHF, CF3CF=CFCF3, CF3CF2CF=CF2, CF3CF=CHCF3, CF3CF2CF=CH2, CF3CH=CHF3, CF3CF2CH=CH2, CF2=CHCF2CF3, CF2=CHCF2CF3, CF2=CFCHFCF3, CF2=CFCF2CHF2, CHF2CH=CHCF3, (CF3)2C=CHCF3, CF3CF=CHCF2CF3, CF3CH=CFCF2CF3, (CF3)2CFCH=CH2, CF3CF2CF2CH=CH2, CF3(CF2)3CF=CF2, CF3CF2CF=CFCF2CF3, (CF3)2C=C(CF3)2, (CF3)2CFCF=CHCF3, CF2=CFCF2CH2F, CF2=CFCHFCHF2, CH2=C(CF3)2, CH2CF2CF=CF2, CH2FCF=CFCHF2, CH2FCF2CF=CF2, CF2=C(CF3)(CH3), CH2=C(CHF2)(CF3), CH2=CHCF2CHF2, CF2=C(CHF2)(CH3), CHF=C(CF3)(CH3), CH2=C(CHF2)2, CF3CF=CFCH3, CH3CF=CHCF3, CF2=CF(CF2)2CF3, CHF=CF(CF2)2CF3, CF2=CH(CF2)2CF3, CF2=CF(CF2)2CHF2, CHF2CF=CFCF2CF3, CF3CF=CFCF2CHF2, CF3CF=CFCHFCF3, CHF=CFCF(CF3)2, CF2=CFCH(CF3)2, CF3CH=C(CF3)2, CF2=CHCF(CF3)2, CH2=CF(CF2)2CF3, CHF=CF(CF2)2CHF2, CH2=C(CF3)C2F5, CF2=CHCH(CF3)2, CHF=CHCF(CF3)2, CF2=C(CF3)CH2CF3, CH2=CF(CF2)2CHF2, CF2=CHCF2CH2CF3, CF3CF=C(CF3)CH3, CH2=CFCH(CF3)2, CHF=CHCH(CF3)2, CH2FCH=C(CF3)2, CH3CF=C(CF3)2, CH2=CHCF2CHFCF3, CH2=C(CF3)CH2CF3, (CF3)2C=CHC2F5, CH2=CHC(CF3)3, (CF3)2C=C(CH3)CF3, CH2=CFCF2CH(CF3)2, CF3CF=C(CH3)C2F5, CF3CH=CHCH(CF3)2, CH2=CH(CF2)3CHF2, (CF3)2C=CHCF2CH3, CH2=C(CF3)CH2C2F5, CH2=CHCH2CF2CF2CF3, C2F5CF=CFC2H5, CH2=CHCH2CF(CF3)2,a fluorocarbon or a fluorohydrocarbon selected from CF 3 CF = CHF, CF 3 CH = CF 2 , CHF 2 CF = CF 2 , CHF 2 CH = CHF, CF 3 CF = CH 2 , CF 3 CH = CHF, CH 2 FCF = CF 2 , CHF 2 CH = CF 2 , CHF 2 CF = CHF, CHF 2 CF = CH 2 , CF 3 CH = CH 2 , CH 3 CF = CF 2 , CH 2 FCH = CF 2 , CH 2 FCF = CHF, CHF 2 CH = CHF, CF 3 CF = CFCF 3 , CF 3 CF 2 CF = CF 2 , CF 3 CF = CHCF 3 , CF 3 CF 2 CF = CH 2 , CF 3 CH = CHF 3 , CF 3 CF 2 CH = CH 2 , CF 2 = CHCF 2 CF 3 , CF 2 = CHCF 2 CF 3 , CF 2 = CFCHFCF 3 , CF 2 = CFCF 2 CHF 2 , CHF 2 CH = CHCF 3 , (CF 3 ) 2 C = CHCF 3 , CF 3 CF = CHCF 2 CF 3 , CF 3 CH = CFCF 2 CF 3 , (CF 3 ) 2 CFCH = CH 2 , CF 3 CF 2 CF 2 CH = CH 2 , CF 3 (CF 2 ) 3 CF = CF 2 , CF 3 CF 2 CF = CFCF 2 CF 3 , (CF 3 ) 2 C = C (CF 3 ) 2 , (CF 3 ) 2 CFCF = CHCF 3 , CF 2 = CFCF 2 CH 2 F, CF 2 = CFCHFCHF 2 , CH 2 = C (CF 3 ) 2 , CH 2 CF 2 CF = CF 2 , CH 2 FCF = CFCHF 2 , CH 2 FCF 2 CF = CF 2 , CF 2 = C (CF 3 ) ( CH 3 ), CH 2 = C (CHF 2 ) (CF 3 ), CH 2 = CHCF 2 CHF 2 , CF 2 = C (CHF 2 ) (CH 3 ), CHF = C (CF 3 ) (CH 3 ), CH 2 = C (CHF 2) 2, CF 3 CF = CFCH 3, CH 3 CF = CHCF 3 , CF 2 = CF (CF 2 ) 2 CF 3 , CHF = CF (CF 2 ) 2 CF 3 , CF 2 = CH (CF 2 ) 2 CF 3 , CF 2 = CF (CF 2 ) 2 CHF 2 , CHF 2 CF = CFCF 2 CF 3 , CF 3 CF = CFCF 2 CHF 2 , CF 3 CF = CFCHFCF 3 , CHF = CFCF (CF 3 ) 2 , CF 2 = CFCH (CF 3 ) 2 , CF 3 CH = C (CF 3 ) 2 , CF 2 = CHCF (CF 3 ) 2 , CH 2 = CF (CF 2 ) 2 CF 3 , CHF = CF (CF 2 ) 2 CHF 2 , CH 2 = C (CF 3 ) C 2 F 5 , CF 2 = CHCH (CF 3 ) 2 , CHF = CHCF (CF 3 ) 2 , CF 2 = C (CF 3 ) CH 2 CF 3 , CH 2 = CF (CF 2 ) 2 CHF 2 , CF 2 = CHCF 2 CH 2 CF 3 , CF 3 CF = C (CF 3 ) CH 3 , CH 2 = CFCH (CF 3 ) 2 , CHF = CHCH (CF 3 ) 2 , CH 2 FCH = C (CF 3 ) 2 , CH 3 CF = C (CF 3 ) 2 , CH 2 = CHCF 2 CHFCF 3 , CH 2 = C (CF 3 ) CH 2 CF 3 , (CF 3 ) 2 C = CHC 2 F 5 , CH 2 = CHC (CF 3 ) 3 , (CF 3 ) 2 C = C (CH 3 ) CF 3 , CH 2 = CFCF 2 CH (CF 3 ) 2 , CF 3 CF = C (CH 3 ) C 2 F 5 , CF 3 CH = CHCH (CF 3 ) 2 , CH 2 = CH (CF 2 ) 3 CHF 2 , (CF 3 ) 2 C = CHCF 2 CH 3 , CH 2 = C (CF 3 ) CH 2 C 2 F 5 , CH 2 = CHCH 2 CF 2 CF 2 CF 3 , C 2 F 5 CF = CFC 2 H 5 , CH 2 = CHCH 2 CF (CF 3 ) 2 ,
CF3CF=CHCH(CF3)(CH3), (CF3)2C=CFC2H5, cyclo-CF2CF2CF2CH=CH-, cyclo- CF2CF2CH=CH-, CF3CF2CF2C(CH3)=CH2, CF3CF2CF2CH=CHCH3, cyclo- CF2CF2CF=CF-, cyclo-CF2CF=CFCF2CF2-, cyclo-CF2CF=CFCF2CF2CF2-,CF 3 CF = CHCH (CF 3 ) (CH 3 ), (CF 3 ) 2 C = CFC 2 H 5 , cyclo-CF 2 CF 2 CF 2 CH = CH-, cyclo-CF 2 CF 2 CH = CH-, CF 3 CF 2 CF 2 C (CH 3 ) = CH 2 , CF 3 CF 2 CF 2 CH = CHCH 3 , cycloCF 2 CF 2 CF = CF-, cyclo-CF 2 CF = CFCF 2 CF 2 -, cyclo -CF 2 CF = CFCF 2 CF 2 CF 2 -,
CF3CF2CF2CF2CH=CH2, CF3CH=CHC2F5, C2F5CH=CHC2F5, CF3CH=CHCF2CF2CF3, CF3CF=CFC2F5, CF3CF=CFCF2CF2CF2CF3, C2F5CF=CFCF2CF2CF3,CF 3 CF 2 CF 2 CF 2 CH = CH 2 , CF 3 CH = CHC 2 F 5 , C 2 F 5 CH = CHC 2 F 5 , CF 3 CH = CHCF 2 CF 2 CF 3 , CF 3 CF = CFC 2 F 5 , CF 3 CF = CFCF 2 CF 2 CF 2 CF 3 , C 2 F 5 CF = CFCF 2 CF 2 CF 3 ,
CF3CH=CFCF2CF2CF2CF3, CF3CF=CHCF2CF2CF2CF3, C2F5CH=CFCH2CH2CH3, C2F5CF=CHCF2CF2CF3, CF3CF2CF2CF=CHCH3, C2F5CF=CHCH3, (CF3)2C=CHCH3, CF3C(CH3)=CHCF3, CHF=CFC2F5, CHF2CF=CFCF3, (CF3)2C=CHF, CH2FCF=CFCF3, CHF=CHC2F5, CHF2CH=CFCF3, CHF=CFCHFCF3, CF3CH=CFCHF2, CHF=CFCF2CHF2, CHF2CF=CFCHF2, CH2CF=CFCF3, CH2FCH=CFCF3, CH2=CFCHFCF3, CH2=CFCF2CHF7,2 CF3CH=CFCH2F, CHF=CFCH2CF3, CHF=CHCHFCF3, CHF=CHCF2CHF2, CHF2CF=CHCHF2, CHF=CFCHFCHF2, CF3CF=CHCH3, CF2=CHCF2Br, CHF=CBrCHF2, CHBr=CHCF3, CF3CBr=CFCF3, CH2=CBrC2F5, CHBr=CHC2F5, CH2=CH(CF2)2Br, CH2=CHCBrFCF3, CH3CBr=CHCF3, CF3CBr=CHCH3, (CF3)2C=CHBr, CF3CF=CBrC2F5, £-CHF2CBr=CFC2F5, Z-CHF2CBr=CFC2F5, CF2=CBrCHFC2F5, (CF3)2CFCBr=CH2, CHBr=CF(CF2)2CHF2, CH2=CBrCF2CF2CF3, CF2=C(CH2Br)CF3, CH2=C(CBrF2)CF3, (CF3)2CHCH=CHBr, (CF3)2C=CHCH2Br, CH2=CHCF(CF3)CBrF2, CF2=CHCF2CH2CBrF2, CFBr=CHCF3, CFBr=CFCF3 und CH2=CBrCF2CF2CF2CF3, jeweils in der E-Form oder der Z-Form, sowie aus Mischungen der vorgenannten Substanzen. CF 3 CH = CFCF 2 CF 2 CF 2 CF 3 , CF 3 CF = CHCF 2 CF 2 CF 2 CF 3 , C 2 F 5 CH = CFCH 2 CH 2 CH 3 , C 2 F 5 CF = CHCF 2 CF 2 CF 3 , CF 3 CF 2 CF 2 CF = CHCH 3 , C 2 F 5 CF = CHCH 3 , (CF 3 ) 2 C = CHCH 3 , CF 3 C (CH 3 ) = CHCF 3 , CHF = CFC 2 F 5 , CHF 2 CF = CFCF 3 , (CF 3 ) 2 C = CHF, CH 2 FCF = CFCF 3 , CHF = CHC 2 F 5 , CHF 2 CH = CFCF 3 , CHF = CFCHFCF 3 , CF 3 CH = CFCHF 2 , CHF = CFCF 2 CHF 2 , CHF 2 CF = CFCHF 2 , CH 2 CF = CFCF 3 , CH 2 FCH = CFCF 3 , CH 2 = CFCHFCF 3 , CH 2 = CFCF 2 CHF 7 , 2 CF 3 CH = CFCH 2 F, CHF = CFCH 2 CF 3 , CHF = CHCHFCF 3 , CHF = CHCF 2 CHF 2 , CHF 2 CF = CHCHF 2 , CHF = CFCHFCHF 2 , CF 3 CF = CHCH 3 , CF 2 = CHCF 2 Br, CHF = CBrCHF 2 , CHBr = CHCF 3 , CF 3 CBr = CFCF 3 , CH 2 = CBrC 2 F 5 , CHBr = CHC 2 F 5 , CH 2 = CH (CF 2 ) 2 Br, CH 2 = CHCBrFCF 3 , CH 3 CBr = CHCF 3 , CF 3 CBr = CHCH 3 , (CF 3 ) 2 C = CHBr, CF 3 CF = CBrC 2 F 5 , £ -CHF 2 CBr = CFC 2 F 5 , Z-CHF 2 CBr = CFC 2 F 5 , CF 2 = CBrCHFC 2 F 5 , (CF 3 ) 2 CFCBr = CH 2 , CHBr = CF (CF 2 ) 2 CHF 2 , CH 2 = CBrCF 2 CF 2 CF 3 , CF 2 = C (CH 2 Br) CF 3 , CH 2 = C (CBrF 2 ) CF 3 , (CF 3 ) 2 CHCH = CHBr, (CF 3 ) 2 C = CHCH 2 Br, CH 2 = CHCF (CF 3 ) CBrF 2 , CF 2 = CHCF 2 CH 2 CBrF 2 , CFBr = CHCF 3 , CFBr = CFCF 3 and CH 2 = CBrCF 2 CF 2 CF 2 CF 3 , each in the E Form or Z-form, as well as mixtures of the aforementioned substances.
Zusammensetzung nach Anspruch 1 , 2 oder 3, dadurch gekennzeichnet, dass das Treibmittel d) £-CF3CH=CHF (£-1 ,3,3,3-Tetrafluorpropen-1) ist. A composition according to claim 1, 2 or 3, characterized in that the propellant is d) £ -CF 3 CH = CHF (£ -1, 3,3,3-tetrafluoropropene-1).
Zusammensetzung nach Anspruch 1 , 2, 3 oder 4, dadurch gekennzeichnet, dass, bezogen auf das Gesamtgewicht der treibmittelfreien Deodorant- oder Antitranspirant-Zusammenset- zung, 10 - 85 Gew.-%, bevorzugt 15 - 75 Gew.-%, besonders bevorzugt 20 - 65 Gew.-%, freies Wasser enthalten ist. A composition according to claim 1, 2, 3 or 4, characterized in that, based on the total weight of the propellant-free deodorant or antiperspirant composition, 10 to 85 wt .-%, preferably 15 to 75 wt .-%, particularly preferably 20-65 wt .-%, free water is included.
Zusammensetzung nach Anspruch 1 , 2, 3, 4 oder 5, dadurch gekennzeichnet, dass der mindestens eine Deodorant-Wirkstoff ausgewählt ist aus Arylsulfatase-Inhibitoren, beta-Glucuro- nidase-lnhibitoren, Aminoacylase-Inhibitoren, Esterase-Inhibitoren, Lipase-Inhibitoren und Lipoxigenase-Inhibitoren, alpha-Monoalkylglycerinethern mit einem verzweigten oder linearen gesättigten oder ungesättigten, gegebenenfalls hydroxylierten C6 - C22-Alkylrest, insbesondere alpha-(2-Ethylhexyl)glycerinether, Silbersalzen, Trialkylcitronensäureestern, insbesondere Triethylcitrat, Wrkstoffen, die die Zahl der an der Geruchsbildung beteiligten Hautkeime aus der Gruppe der Staphylokokken, Corynebakterien, Anaerokokken und Mikrokokken reduzieren bzw. deren Wachstum hemmen, Zinkverbindungen, insbesondere Zinkphenolsulfonat und Zinkricinoleat, Organohalogenverbindungen, insbesondere Triclosan, Chlorhexidin, Chlorhexidingluconat und Benzalkoniumhalogeniden, quartären Ammoniumverbindungen, insbesondere Cetylpyridiniumchlorid, Geruchsabsorbern, insbesondere Silikaten und Zeo- lithen, Doppelsalzen vom Alaun-Typ mit der allgemeinen Formel M'M'"(S04)2 ■ x H20 enthalten, wobei M1 ein einwertiges Kation, ausgewählt aus Kalium-, Natrium-, Rubidium-, Cäsium- und Ammonium-Ionen, M1" ein dreiwertiges Kation, ausgewählt aus Aluminium-, Gallium-, Indium-, Scandium-, Titan- und Vanadium-Ionen, und x eine rationale Zahl im Bereich von 0 bis 12, einschließlich 0, darstellen, aromatischen Alkohol der Struktur (AA-1), A composition according to claim 1, 2, 3, 4 or 5, characterized in that the at least one deodorant active ingredient is selected from arylsulfatase inhibitors, beta-glucuronidase inhibitors, aminoacylase inhibitors, esterase inhibitors, lipase inhibitors and Lipoxigenase inhibitors, alpha-monoalkylglycerol ethers having a branched or linear saturated or unsaturated, optionally hydroxylated C 6 -C 22 -alkyl radical, in particular alpha- (2-ethylhexyl) glycerol ethers, silver salts, trialkylcitric acid esters, in particular triethyl citrate, active compounds which have the number of Skin odors from the group of staphylococci, corynebacteria, anaerococci and micrococci which inhibit the growth or inhibit their growth, zinc compounds, in particular zinc phenolsulfonate and zinc ricinoleate, organohalogen compounds, in particular triclosan, chlorhexidine, chlorhexidine gluconate and benzalkonium halides, quaternary ammonium compounds, in particular cetyl pyridinium chloride, odor absorbers, in particular silicates and Zeo- Lithen, double salts of the alum type having the general formula M'M "(S0 4) 2 x H 2 0 ■ contain, where M 1 is a monovalent cation selected from potassium, sodium , Rubidium, cesium and ammonium ions, M 1 "is a trivalent cation selected from aluminum, gallium, indium, scandium, titanium and vanadium ions, and x is a rational number in the range of 0 to 12, including 0, represent aromatic alcohol of structure (AA-1),
Figure imgf000074_0001
Figure imgf000074_0001
wobei die Struktur (AA-1) folgendermaßen gekennzeichnet ist: wherein the structure (AA-1) is characterized as follows:
R - R6 = unabhängig voneinander ein Wasserstoffatom, eine Alkylgruppe mit 1 bis 10 Kohlenstoffatomen, die linear oder verzweigt sein kann und die substituiert sein kann mit OH- Gruppen oder Alkoxy-Gruppen mit 1 bis 5 Kohlenstoffatomen, oder eine Alkenylgruppe mit 2 bis 10 Kohlenstoffatomen, die linear oder verzweigt sein kann und die substituiert sein kann mit OH-Gruppen oder Alkoxy-Gruppen mit 1 bis 5 Kohlenstoffatomen, R7 - R = unabhängig voneinander ein Wasserstoffatom, ein Halogenatom, insbesondere ein Chloratom, oder eine Alkylgruppe mit 1 bis 10 Kohlenstoffatomen, die linear oder verzweigt sein kann und die substituiert sein kann mit OH-Gruppen oder Alkoxy-Gruppen mit 1 bis 5 Kohlenstoffatomen, insbesondere mit einer Methoxygruppe, m = 0 oder 1 ist, n, o, p = unabhängig voneinander ganze Zahlen von 0 bis 10 sein können, wobei mindestens einer der Werte n, o, p 0 ist, weiterhin 1 ,2-Alkandiolen mit 7 bis 16 Kohlenstoffatomen im Molekül, Tropolon, sowie Mischungen der vorgenannten Substanzen. R - R 6 = independently a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, which may be linear or branched and which may be substituted by OH groups or alkoxy groups having 1 to 5 carbon atoms, or an alkenyl group having 2 to 10 Carbon atoms which may be linear or branched and which may be substituted by OH groups or alkoxy groups having 1 to 5 carbon atoms, R 7 - R = independently a hydrogen atom, a halogen atom, in particular a chlorine atom, or an alkyl group having 1 to 10 carbon atoms, which may be linear or branched and which may be substituted by OH groups or alkoxy groups having 1 to 5 carbon atoms, in particular having a methoxy group, m = 0 or 1, n, o, p = are independently integers may be from 0 to 10, wherein at least one of n, o, p is 0, further 1, 2-alkanediols having 7 to 16 carbon atoms in the molecule, tropolone, and mixtures of the above ate substances.
7. Zusammensetzung nach Anspruch 1 , 2, 3, 4, 5 oder 6, dadurch gekennzeichnet, dass der mindestens eine Deodorant-Wrkstoff in einer Gesamtmenge von 0,1 - 20 Gew.-%, bevorzugt 0,2 - 10 Gew.-%, besonders bevorzugt 0,3 - 5 Gew.-% und außerordentlich bevorzugt 1 - 3 Gew.-%, jeweils bezogen auf das Gesamtgewicht der Deodorant-Wirkstoffe in der treibmittelfreien Zusammensetzung, enthalten ist. 7. The composition of claim 1, 2, 3, 4, 5 or 6, characterized in that the at least one deodorant active ingredient in a total amount of 0.1 to 20 wt .-%, preferably 0.2 to 10 wt. %, particularly preferably 0.3 to 5 wt .-% and most preferably 1 to 3 wt .-%, each based on the total weight of the deodorant active ingredients in the propellant-free composition is included.
8. Zusammensetzung nach Anspruch 1 , 2, 3, 4, 4, 5, 6 oder 7, dadurch gekennzeichnet, dass der mindestens eine Antitranspirant-Wrkstoff ausgewählt ist aus Aluminiumchlorhydroxiden (= Aluminiumchlorhydraten) und deren Derivaten und Komplexverbindungen, sowie Diolen der Struktur (DIOL)
Figure imgf000074_0002
8. The composition of claim 1, 2, 3, 4, 4, 5, 6 or 7, characterized in that the at least one Antitranspirant-Wrkstoff is selected from aluminum chlorhydroxides (= aluminum chlorohydrates) and their derivatives and complex compounds, and diols of the structure ( DIOL)
Figure imgf000074_0002
R2  R2
(DIOL) wobei der Rest R1 ausgewählt ist aus einem Phenylrest, CH3- und H-, und die Reste R2, R3 und R4 unabhängig voneinander ausgewählt sind aus den Gruppen OH-, -CH2OH, CH3-, C2H5-, H-, mit der Maßgabe, dass zwei OH-Gruppen im Molekül vorhanden sind und dass die Kohlenstoffanzahl aller Reste R2, R3 und R4 maximal 6 ist. (DIOL) wherein the radical R 1 is selected from a phenyl radical, CH 3 - and H-, and the radicals R 2 , R 3 and R 4 are independently selected from the groups OH, -CH 2 OH, CH 3 -, C 2 H 5 -, H, with the proviso that two OH groups are present in the molecule and that the carbon number of all radicals R2, R3 and R4 is at most 6.
9. Zusammensetzung nach Anspruch 1 , 2, 3, 4, 5, 6, 7 oder 8, dadurch gekennzeichnet, dass der mindestens eine Antitranspirant-Wirkstoff, der ausgewählt ist aus Aluminiumchlorhydroxi- den (= Aluminiumchlorhydraten) und deren Derivaten und Komplexverbindungen, in einer Gesamtmenge von 5 - 40 Gew.-%, bevorzugt 10 - 38 Gew.-% und besonders bevorzugt 13 - 35 Gew.-%, enthalten ist, bezogen auf das Gesamtgewicht der kristallwasserfreien Aktivsubstanz (USP) in der treibmittelfreien Zusammensetzung, enthalten ist. 9. Composition according to claim 1, 2, 3, 4, 5, 6, 7 or 8, characterized in that the at least one antiperspirant active ingredient which is selected from Aluminiumchlorhydroxi- the (= aluminum chlorohydrates) and their derivatives and complex compounds, in a total amount of 5 to 40 wt .-%, preferably 10 to 38 wt .-% and particularly preferably 13 to 35 wt .-%, is contained, based on the total weight of the water-free active substance (USP) in the propellant-free composition ,
10. Zusammensetzung nach Anspruch 1 , 2, 3, 4, 5, 6, 7, 8 oder 9, dadurch gekennzeichnet, dass sie als Wasser-in-ÖI-Emulsion vorliegt und 10 - 85 Gew.-% freies Wasser, mindestens einen Antitranspirant-Wirkstoff und/oder mindestens einen Deodorant-Wrkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, 0,1 - 30 Gew.-% Tensid, darunter mindestens einen Wasser-in- Öl-Emulgator, insbesondere einen Silicon-basierten Wasser-in-ÖI-Emulgator, und 1 - 40 Gew.-% mindestens eines kosmetischen Öls, ausgewählt aus Zweier- und Dreier-Mischungen von C8-C 6-lsoalkanen, linearen Dimethylpolysiloxanen mit kinematischen Viskositäten im Bereich von 5 - 100 cSt (25°C) und Estern der linearen oder verzweigten gesättigten oder ungesättigten Fettalkohole mit 2 - 30 Kohlenstoffatomen mit linearen oder verzweigten gesättigten oder ungesättigten Fettsäuren mit 2 - 30 Kohlenstoffatomen, die hydroxyliert sein können, enthält und frei ist von Cyclomethiconen. 10. The composition of claim 1, 2, 3, 4, 5, 6, 7, 8 or 9, characterized in that it is present as a water-in-oil emulsion and 10 to 85 wt .-% free water, at least one Antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1-50 wt .-%, 0.1-30 wt .-% surfactant, including at least one water-in-oil emulsifier, in particular a silicone water-in-oil emulsifier, and 1-40% by weight of at least one cosmetic oil selected from two and three mixtures of C 8 -C 6 -alkanes, linear dimethylpolysiloxanes with kinematic viscosities in the range of 5 - 100 cSt (25 ° C) and esters of linear or branched saturated or unsaturated fatty alcohols having 2 to 30 carbon atoms with linear or branched saturated or unsaturated fatty acids having 2 to 30 carbon atoms, which may be hydroxylated, and is free of cyclomethicones.
1 1 . Zusammensetzung nach Anspruch 1 , 2, 3, 4, 5, 6, 7, 8, 9 oder 10, dadurch gekennzeichnet, dass sie als Wasser-in-ÖI-Emulsion vorliegt und mindestens einen Wasser-in-ÖI-Emulgator, mindestens einen nichtionischen Polyalkylenglycolether mit einem HLB-Wert > 7, der bevorzugt ausgewählt ist aus lsoceteth-20, und mindestens ein C8-C 6 Isoparaffin enthält. 1 1. A composition according to claim 1, 2, 3, 4, 5, 6, 7, 8, 9 or 10, characterized in that it is present as a water-in-oil emulsion and at least one water-in-oil emulsifier, at least one nonionic polyalkylene glycol ethers having an HLB value> 7, which is preferably selected from isoceteth-20, and contains at least one C 8 -C 6 isoparaffin.
12. Zusammensetzung gemäß Anspruch 1 , 2, 3, 4, 5, 6, 7, 8, 9, 10 oder 1 1 , enthaltend 12. The composition according to claim 1, 2, 3, 4, 5, 6, 7, 8, 9, 10 or 11, containing
a) 10 - 85 Gew.-%, bevorzugt 15 - 75 Gew.-%, besonders bevorzugt 20 - 65 Gew.-%, freies Wasser,  a) 10 to 85% by weight, preferably 15 to 75% by weight, particularly preferably 20 to 65% by weight, free water,
b) mindestens ein Tensid in einer Gesamtmenge von 0,2 - 20 Gew.-%, besonders bevorzugt 0,5 - 10 Gew.-%, außerordentlich bevorzugt 1 - 8 Gew.-%, c) mindestens einen Antitranspirant-Wirkstoff und/oder mindestens einen Deodorant- Wirkstoff in einer Gesamtmenge von 0,1 - 50 Gew.-%, b) at least one surfactant in a total amount of 0.2-20% by weight, more preferably 0.5-10% by weight, most preferably 1-8% by weight, c) at least one antiperspirant active ingredient and / or at least one deodorant active ingredient in a total amount of 0.1-50% by weight,
wobei sich die Mengenangaben auf das Gesamtgewicht der treibmittelfreien Zusammensetzung beziehen, wherein the quantities are based on the total weight of the blowing agent-free composition,
d) £-CF3CH=CHF (£-1 ,3,3,3-Tetrafluorpropen-1) als Treibmittel. d) £ -CF 3 CH = CHF (£ -1,3,3,3-tetrafluoropropene-1) as blowing agent.
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