WO2008089037A3 - Preparation of yttria-stabilized zirconia reaction sintered products - Google Patents

Preparation of yttria-stabilized zirconia reaction sintered products Download PDF

Info

Publication number
WO2008089037A3
WO2008089037A3 PCT/US2008/050748 US2008050748W WO2008089037A3 WO 2008089037 A3 WO2008089037 A3 WO 2008089037A3 US 2008050748 W US2008050748 W US 2008050748W WO 2008089037 A3 WO2008089037 A3 WO 2008089037A3
Authority
WO
WIPO (PCT)
Prior art keywords
yttria
stabilized zirconia
less
reaction sintered
green body
Prior art date
Application number
PCT/US2008/050748
Other languages
French (fr)
Other versions
WO2008089037A2 (en
Inventor
Ruthie Swartzlander
W Grover Coors
Original Assignee
Coorstek Inc
Ruthie Swartzlander
W Grover Coors
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Coorstek Inc, Ruthie Swartzlander, W Grover Coors filed Critical Coorstek Inc
Priority to EP08705842.6A priority Critical patent/EP2102132B1/en
Priority to ES08705842.6T priority patent/ES2643764T3/en
Priority to DK08705842.6T priority patent/DK2102132T3/en
Publication of WO2008089037A2 publication Critical patent/WO2008089037A2/en
Publication of WO2008089037A3 publication Critical patent/WO2008089037A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/01—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics
    • C04B35/48—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zirconium or hafnium oxides, zirconates, zircon or hafnates
    • C04B35/486—Fine ceramics
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M8/124—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte
    • H01M8/1246—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides
    • H01M8/1253—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the process of manufacturing or by the material of the electrolyte the electrolyte consisting of oxides the electrolyte containing zirconium oxide
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3224—Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
    • C04B2235/3225—Yttrium oxide or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3262—Manganese oxides, manganates, rhenium oxides or oxide-forming salts thereof, e.g. MnO
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3272—Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3275—Cobalt oxides, cobaltates or cobaltites or oxide forming salts thereof, e.g. bismuth cobaltate, zinc cobaltite
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/327—Iron group oxides, their mixed metal oxides, or oxide-forming salts thereof
    • C04B2235/3279—Nickel oxides, nickalates, or oxide-forming salts thereof
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/30—Constituents and secondary phases not being of a fibrous nature
    • C04B2235/32—Metal oxides, mixed metal oxides, or oxide-forming salts thereof, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
    • C04B2235/3281—Copper oxides, cuprates or oxide-forming salts thereof, e.g. CuO or Cu2O
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/5409—Particle size related information expressed by specific surface values
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5436—Particle size related information expressed by the size of the particles or aggregates thereof micrometer sized, i.e. from 1 to 100 micron
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50—Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54—Particle size related information
    • C04B2235/5418—Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5445—Particle size related information expressed by the size of the particles or aggregates thereof submicron sized, i.e. from 0,1 to 1 micron
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/74—Physical characteristics
    • C04B2235/76—Crystal structural characteristics, e.g. symmetry
    • C04B2235/762—Cubic symmetry, e.g. beta-SiC
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/74—Physical characteristics
    • C04B2235/77—Density
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
    • C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
    • C04B2235/9607—Thermal properties, e.g. thermal expansion coefficient
    • C04B2235/9623—Ceramic setters properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293—Fuel cells with solid oxide electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0068—Solid electrolytes inorganic
    • H01M2300/0071—Oxides
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Abstract

A method of making a solid electrolyte-YSZ product, where the method includes the step of providing a powdered mixture of zirconia, yttria and about 2%, by wt., or less of a metal oxide, where yttria-stabilized zirconia is not added to the mixture. The method also includes sintering the powdered mixture at about 1500°C or less, for about 5 hours or less, to form a reaction sintered YSZ. Also, a method of making a fuel cell electrolyte that includes the step of forming a green body that includes zirconia, yttria and about 2%, by wt., or less of a metal oxide, where yttria-stabilized zirconia is not added to the green body. The method also includes shaping the green body into a form of the electrolyte, and sintering the green body at about 1500°C or less to form a reaction sintered yttria-stabilized zirconia and metal oxide electrolyte.
PCT/US2008/050748 2007-01-19 2008-01-10 Preparation of yttria-stabilized zirconia reaction sintered products WO2008089037A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP08705842.6A EP2102132B1 (en) 2007-01-19 2008-01-10 Preparation of yttria-stabilized zirconia reaction sintered products
ES08705842.6T ES2643764T3 (en) 2007-01-19 2008-01-10  Preparation of sintered products by zirconia stabilized reaction with yttria
DK08705842.6T DK2102132T3 (en) 2007-01-19 2008-01-10 MANUFACTURE OF YTTRIA STABILIZED ZIRCONIA REACTION SINTERED PRODUCTS

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/625,207 US7833469B2 (en) 2004-12-15 2007-01-19 Preparation of yttria-stabilized zirconia reaction sintered products
US11/625,207 2007-01-19

Publications (2)

Publication Number Publication Date
WO2008089037A2 WO2008089037A2 (en) 2008-07-24
WO2008089037A3 true WO2008089037A3 (en) 2008-11-20

Family

ID=39247732

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2008/050748 WO2008089037A2 (en) 2007-01-19 2008-01-10 Preparation of yttria-stabilized zirconia reaction sintered products

Country Status (5)

Country Link
US (1) US7833469B2 (en)
EP (1) EP2102132B1 (en)
DK (1) DK2102132T3 (en)
ES (1) ES2643764T3 (en)
WO (1) WO2008089037A2 (en)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9162931B1 (en) * 2007-05-09 2015-10-20 The United States Of America As Represented By The Secretary Of The Air Force Tailored interfaces between two dissimilar nano-materials and method of manufacture
US9120245B1 (en) 2007-05-09 2015-09-01 The United States Of America As Represented By The Secretary Of The Air Force Methods for fabrication of parts from bulk low-cost interface-defined nanolaminated materials
US8617456B1 (en) 2010-03-22 2013-12-31 The United States Of America As Represented By The Secretary Of The Air Force Bulk low-cost interface-defined laminated materials and their method of fabrication
US20090286125A1 (en) * 2008-04-03 2009-11-19 The University Of Toledo Bi-electrode supported solid oxide fuel cells having gas flow plenum channels and methods of making same
US8546284B2 (en) * 2008-05-07 2013-10-01 Council Of Scientific & Industrial Research Process for the production of plasma sprayable yttria stabilized zirconia (YSZ) and plasma sprayable YSZ powder produced thereby
DE102008046336A1 (en) * 2008-09-09 2010-03-11 Osram Gesellschaft mit beschränkter Haftung LTCC layer stack
US8357474B2 (en) * 2008-12-17 2013-01-22 Saint-Gobain Ceramics & Plastics, Inc. Co-doped YSZ electrolytes for solid oxide fuel cell stacks
JP5667078B2 (en) 2008-12-19 2015-02-12 サン−ゴバン セラミックス アンド プラスティクス，インコーポレイティド Reduction-oxidation resistant electrodes for solid oxide fuel cells
FR2940856B1 (en) * 2009-01-05 2012-05-18 Commissariat Energie Atomique PROCESS FOR PRODUCING A CERMET NICKEL ELECTRODE
US10658705B2 (en) 2018-03-07 2020-05-19 Space Charge, LLC Thin-film solid-state energy storage devices
US9853325B2 (en) 2011-06-29 2017-12-26 Space Charge, LLC Rugged, gel-free, lithium-free, high energy density solid-state electrochemical energy storage devices
US20130170097A1 (en) * 2011-06-29 2013-07-04 Space Charge, LLC Yttria-stabilized zirconia based capacitor
US11527774B2 (en) 2011-06-29 2022-12-13 Space Charge, LLC Electrochemical energy storage devices
US10601074B2 (en) 2011-06-29 2020-03-24 Space Charge, LLC Rugged, gel-free, lithium-free, high energy density solid-state electrochemical energy storage devices
US10411288B2 (en) 2011-11-29 2019-09-10 Corning Incorporated Reactive sintering of ceramic lithium-ion solid electrolytes
DE102014211782A1 (en) * 2014-06-18 2015-12-24 Robert Bosch Gmbh Sensor element for detecting at least one property of a sample gas in a sample gas space
CN105565806B (en) * 2014-12-08 2017-04-05 比亚迪股份有限公司 A kind of ceramics and preparation method thereof
JP6897503B2 (en) * 2017-11-03 2021-06-30 株式会社デンソー Solid electrolyte, its manufacturing method, gas sensor
CN110391455B (en) * 2018-04-17 2022-10-04 阜阳师范学院 Yttrium-stabilized zirconium dioxide-low-melting-point glass powder compound and preparation method thereof
CN110600777B (en) * 2018-06-12 2023-03-10 阜阳师范学院 Double-doped zirconium dioxide and alkali metal salt compound and preparation method thereof
US20220149386A1 (en) * 2020-11-09 2022-05-12 Phillips 66 Company Anode catalysts for fuel cells
CN115354395B (en) * 2022-09-13 2023-11-03 中国地质大学（武汉） Blue cubic zirconia crystal and preparation method and application thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3503809A (en) * 1967-11-02 1970-03-31 Gen Electric Electrical device including nickel-containing stabilized zirconia electrode
US3607323A (en) * 1968-07-31 1971-09-21 Gen Electric Sintered stabilized zirconia containing discontinuous phase of cobalt-containing oxide
US4883497A (en) * 1988-03-28 1989-11-28 Arch Development Corporation Formation of thin walled ceramic solid oxide fuel cells
US5474800A (en) * 1991-06-20 1995-12-12 Tokyo Gas Company, Ltd. Method for preparing anode for solid oxide fuel cells
US20030219637A1 (en) * 2002-05-22 2003-11-27 Coors W. Grover Direct hydrocarbon reforming in protonic ceramic fuel cells by electrolyte steam permeation
US20060125157A1 (en) * 2004-12-15 2006-06-15 Coorstek, Inc. Preparation of yttria-stabilized zirconia reaction sintered products

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE634204A (en) * 1962-06-27 1900-01-01
US3558360A (en) * 1968-01-08 1971-01-26 Westinghouse Electric Corp Fuel cell comprising a stabilized zirconium oxide electrolyte and a doped indium or tin oxide cathode
US4465778A (en) * 1982-02-03 1984-08-14 National Research Development Corporation Sinterable fluorite oxide ceramics
US4767518A (en) * 1986-06-11 1988-08-30 Westinghouse Electric Corp. Cermet electrode
US4866014A (en) * 1987-04-13 1989-09-12 Ford Motor Company Method of making a stress resistant, partially stabilized zirconia ceramic
US4971830A (en) * 1990-02-01 1990-11-20 Westinghouse Electric Corp. Method of electrode fabrication for solid oxide electrochemical cells
US5286580A (en) * 1990-02-09 1994-02-15 Osaka Gas Company Limited Fuel electrode for solid electrolyte fuel cells and a method for manufacture of the electrode
IT1241403B (en) * 1990-03-02 1994-01-14 Eniricerche Spa PROCEDURE FOR THE PREPARATION OF MIXED ZIRCONIUM AND YELLOW OXIDES
US5035962A (en) * 1990-03-21 1991-07-30 Westinghouse Electric Corp. Layered method of electrode for solid oxide electrochemical cells
JPH04118861A (en) * 1990-09-10 1992-04-20 Fuji Electric Co Ltd Solid electrolyte type fuel cell and its manufacture
JP2513920B2 (en) * 1990-09-26 1996-07-10 日本碍子株式会社 Fuel electrode for solid electrolyte fuel cell and method for manufacturing the same
IT1248589B (en) * 1991-06-28 1995-01-19 Eniricerche Spa NICKEL CERMET AND PROCEDURE FOR ITS PREPARATION
US5368667A (en) * 1993-01-29 1994-11-29 Alliedsignal Inc. Preparation of devices that include a thin ceramic layer
US5543239A (en) * 1995-04-19 1996-08-06 Electric Power Research Institute Electrode design for solid state devices, fuel cells and sensors
IT1277439B1 (en) * 1995-08-04 1997-11-10 Eniricerche Spa NICKEL CERNET AND RELATED PREPARATION PROCEDURE
US5656387A (en) * 1995-10-10 1997-08-12 Northwestern University Solid-oxide fuel cells having nickel and yttria-stabilized zirconia anodes and method of manufacture
WO1998028808A1 (en) * 1996-12-20 1998-07-02 Tokyo Gas Co., Ltd. Fuel electrode of solid electrolyte type fuel cell and process for the preparation of the same
US6099985A (en) * 1997-07-03 2000-08-08 Gas Research Institute SOFC anode for enhanced performance stability and method for manufacturing same
US5908713A (en) * 1997-09-22 1999-06-01 Siemens Westinghouse Power Corporation Sintered electrode for solid oxide fuel cells
US5804131A (en) * 1997-10-07 1998-09-08 Eastman Kodak Company Method of manufacturing a ceramic article
EP1081778A4 (en) * 1998-04-21 2006-03-01 Toto Ltd Solid electrolyte fuel cell and method of producing the same
US6344426B1 (en) * 1998-05-20 2002-02-05 Nippon Shokubai Co., Ltd. Porous ceramic sheet, process for producing the same, and setter for use in the process
DE19908213B4 (en) * 1998-07-27 2005-03-10 Mitsubishi Heavy Ind Ltd Base tube for a fuel cell
US6248468B1 (en) * 1998-12-31 2001-06-19 Siemens Westinghouse Power Corporation Fuel electrode containing pre-sintered nickel/zirconia for a solid oxide fuel cell
US6589680B1 (en) * 1999-03-03 2003-07-08 The Trustees Of The University Of Pennsylvania Method for solid oxide fuel cell anode preparation
JP3996861B2 (en) * 2002-05-29 2007-10-24 京セラ株式会社 Fuel cell and fuel cell

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3503809A (en) * 1967-11-02 1970-03-31 Gen Electric Electrical device including nickel-containing stabilized zirconia electrode
US3607323A (en) * 1968-07-31 1971-09-21 Gen Electric Sintered stabilized zirconia containing discontinuous phase of cobalt-containing oxide
US4883497A (en) * 1988-03-28 1989-11-28 Arch Development Corporation Formation of thin walled ceramic solid oxide fuel cells
US5474800A (en) * 1991-06-20 1995-12-12 Tokyo Gas Company, Ltd. Method for preparing anode for solid oxide fuel cells
US20030219637A1 (en) * 2002-05-22 2003-11-27 Coors W. Grover Direct hydrocarbon reforming in protonic ceramic fuel cells by electrolyte steam permeation
US20060125157A1 (en) * 2004-12-15 2006-06-15 Coorstek, Inc. Preparation of yttria-stabilized zirconia reaction sintered products

Also Published As

Publication number Publication date
WO2008089037A2 (en) 2008-07-24
EP2102132A2 (en) 2009-09-23
EP2102132B1 (en) 2017-08-23
US7833469B2 (en) 2010-11-16
ES2643764T3 (en) 2017-11-24
US20070176332A1 (en) 2007-08-02
DK2102132T3 (en) 2017-10-02

Similar Documents

Publication Publication Date Title
WO2008089037A3 (en) Preparation of yttria-stabilized zirconia reaction sintered products
WO2010077945A3 (en) Co-doped ysz eletrolytes for solid oxide fuel cell stacks
HK1144735A1 (en) Interconnector for a high-temperature solid electrolyte fuel cell
UA98118C2 (en) Powdery zirconium oxide, method for its production and use, mold, substrate and fuel cell, containing it
EP2110872A4 (en) Lithium transition metal compound powder, process for production thereof, spray-dried product useful as firing precursor, and positive electrode for lithium secondary battery and lithium secondary battery made by using the same
WO2009024424A3 (en) Powdered niam1 bm2c(o)x(oh)ycompounds, method for the production thereof and use thereof in batteries
WO2008036962A3 (en) Porous clusters of silver powder promoted by zirconium oxide for use as a catalyst in gas diffusion electrodes, and method for the production thereof
WO2006044313A3 (en) Preparation of solid oxide fuel cell electrodes by electrodeposition
WO2006086457A3 (en) Palladium-cobalt particles as oxygen-reduction electrocatalysts
WO2007121443A3 (en) Differentiation of multi-lineage progenitor cells to respiratory epithelial cells
ATE385050T1 (en) ELECTRICALLY CONDUCTIVE STEEL-CERAMIC COMPOSITE AND ITS PRODUCTION
JP2010177187A5 (en)
RU2008134996A (en) POLYMERIZED INORGANIC-ORGANIC MIXTURE OF THE PREDEDENT FOR NANOSIZED METAL OXIDES, ITS APPLICATION FOR OBTAINING A SINTERED MEMBRANE AND ITS APPLICATION
PH12018500281A1 (en) Capacitor anode
EP2098495A3 (en) Method of manufacturing translucent ceramic and orthodontic member
WO2013190043A3 (en) CeO2-STABILIZED ZrO2 CERAMICS FOR DENTAL APPLICATIONS
Moreno et al. Fabrication and characterization of ceria-based buffer layers for solid oxide fuel cells
WO2012146465A3 (en) Method for the production of a porous element, and cell of a rechargeable oxide battery
WO2012036462A3 (en) Cathode active material precursor for lithium secondary battery, preparation method of cathode active material for lithium secondary battery using same, and lithium secondary battery containing the cathode active material for lithium secondary battery prepared thereby
CN109478651A (en) Electrochemical cell
Acchar et al. Mechanical performance of LaCrO3 doped with strontium and cobalt for SOFC interconnect
EP3056582A3 (en) Fuel cell interconnector and method for making a fuel cell interconnector
MY158139A (en) Zirconia-toughened-alumina ceramic cutting inserts with the addition of nano particle metal oxides as additives
WO2021231523A3 (en) Electrolyte materials for solid oxide electrolyzer cells
CN107056289A (en) A kind of Polycarbosilane prepares the method and its application of SiC base nano composite ceramics

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 08705842

Country of ref document: EP

Kind code of ref document: A2

REEP Request for entry into the european phase

Ref document number: 2008705842

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 2008705842

Country of ref document: EP

NENP Non-entry into the national phase

Ref country code: DE