WO2008013783A3 - Efficient reversible electrodes for solid oxide electrolyzer cells - Google Patents

Efficient reversible electrodes for solid oxide electrolyzer cells Download PDF

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Publication number
WO2008013783A3
WO2008013783A3 PCT/US2007/016596 US2007016596W WO2008013783A3 WO 2008013783 A3 WO2008013783 A3 WO 2008013783A3 US 2007016596 W US2007016596 W US 2007016596W WO 2008013783 A3 WO2008013783 A3 WO 2008013783A3
Authority
WO
WIPO (PCT)
Prior art keywords
anode
cathode
solid oxide
oxygen
oxygen ion
Prior art date
Application number
PCT/US2007/016596
Other languages
French (fr)
Other versions
WO2008013783A2 (en
Inventor
S Elangovan
Joseph Hartvigsen
Original Assignee
Ceramatec Inc
S Elangovan
Joseph Hartvigsen
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ceramatec Inc, S Elangovan, Joseph Hartvigsen filed Critical Ceramatec Inc
Priority to JP2009520863A priority Critical patent/JP2009544843A/en
Priority to EP07810715A priority patent/EP2069556A4/en
Publication of WO2008013783A2 publication Critical patent/WO2008013783A2/en
Publication of WO2008013783A3 publication Critical patent/WO2008013783A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
    • C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
    • C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
    • C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
    • C25B11/075—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound
    • C25B11/077—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound the compound being a non-noble metal oxide
    • C25B11/0773—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of a single catalytic element or catalytic compound the compound being a non-noble metal oxide of the perovskite type
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90—Selection of catalytic material
    • H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
    • H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
    • H01M4/9033—Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
    • H01M2008/1293—Fuel cells with solid oxide electrolytes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells

Abstract

An electrolyzer cell (100) is disclosed which includes a cathode (104) to reduce an oxygen-containing molecule, such as H2O, CO2, or a combination thereof, to produce an oxygen ion and a fuel molecule, such as H2, CO, or a combination thereof. An electrolyte (106) is coupled to the cathode (104) to transport the oxygen ion to an anode (102). The anode (102) is coupled to the electrolyte (106) to receive the oxygen ion and produce oxygen gas therewith. In one embodiment, the anode (102) may be fabricated to include an electron-conducting phase having a perovskite crystalline structure or structure similar thereto. This perovskite may have a chemical formula of substantially (Pr(1-x)Lax)(z-y)A'yBO(3-∂), wherein 0≤x≤ 0.5,0≤y ≤ 0.5, and 0.8≤z≤1.1. In another embodiment, the cathode (104) includes an electron-conducting phase that contains nickel oxide intermixed with magnesium oxide.
PCT/US2007/016596 2006-07-22 2007-07-23 Efficient reversible electrodes for solid oxide electrolyzer cells WO2008013783A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2009520863A JP2009544843A (en) 2006-07-22 2007-07-23 Efficient reversible electrode for solid oxide cell
EP07810715A EP2069556A4 (en) 2006-07-22 2007-07-23 Efficient reversible electrodes for solid oxide electrolyzer cells

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US82010306P 2006-07-22 2006-07-22
US60/820,103 2006-07-22

Publications (2)

Publication Number Publication Date
WO2008013783A2 WO2008013783A2 (en) 2008-01-31
WO2008013783A3 true WO2008013783A3 (en) 2008-10-23

Family

ID=38982012

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2007/016596 WO2008013783A2 (en) 2006-07-22 2007-07-23 Efficient reversible electrodes for solid oxide electrolyzer cells

Country Status (4)

Country Link
US (1) US7976686B2 (en)
EP (1) EP2069556A4 (en)
JP (1) JP2009544843A (en)
WO (1) WO2008013783A2 (en)

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US10615444B2 (en) 2006-10-18 2020-04-07 Bloom Energy Corporation Anode with high redox stability
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US8366902B2 (en) * 2008-03-24 2013-02-05 Battelle Energy Alliance, Llc Methods and systems for producing syngas
JP5618485B2 (en) * 2009-01-08 2014-11-05 株式会社東芝 Electrochemical cell operation method
EP2244322A1 (en) * 2009-04-24 2010-10-27 Technical University of Denmark Composite oxygen electrode and method for preparing same
JP5290870B2 (en) * 2009-05-29 2013-09-18 日本電信電話株式会社 Solid oxide fuel cell
US8617763B2 (en) * 2009-08-12 2013-12-31 Bloom Energy Corporation Internal reforming anode for solid oxide fuel cells
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US8591718B2 (en) * 2010-04-19 2013-11-26 Praxair Technology, Inc. Electrochemical carbon monoxide production
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US9611144B2 (en) 2013-04-26 2017-04-04 Praxair Technology, Inc. Method and system for producing a synthesis gas in an oxygen transport membrane based reforming system that is free of metal dusting corrosion
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Also Published As

Publication number Publication date
WO2008013783A2 (en) 2008-01-31
EP2069556A2 (en) 2009-06-17
US7976686B2 (en) 2011-07-12
US20080029388A1 (en) 2008-02-07
EP2069556A4 (en) 2009-12-09
JP2009544843A (en) 2009-12-17

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