WO2008009424A3 - Nonaqueous emulsion polymerisation - Google Patents
Nonaqueous emulsion polymerisation Download PDFInfo
- Publication number
- WO2008009424A3 WO2008009424A3 PCT/EP2007/006345 EP2007006345W WO2008009424A3 WO 2008009424 A3 WO2008009424 A3 WO 2008009424A3 EP 2007006345 W EP2007006345 W EP 2007006345W WO 2008009424 A3 WO2008009424 A3 WO 2008009424A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- nonaqueous emulsion
- emulsion
- nonaqueous
- emulsion polymerisation
- emulsifier
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/79—Interfacial processes, i.e. processes involving a reaction at the interface of two non-miscible liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
- C08F2/08—Organic solvent with the aid of dispersing agents for the polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/14—Organic medium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/81—Preparation processes using solvents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G64/00—Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
- C08G64/20—General preparatory processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L95/00—Compositions of bituminous materials, e.g. asphalt, tar, pitch
- C08L95/005—Aqueous compositions, e.g. emulsions
Abstract
The present invention relates to a nonaqueous emulsion comprising a solvent system and an emulsifier and to a process of reacting monomer educts to give a polymer in that nonaqueous emulsion. For stabilizing the emulsion, a copolymer is used as emulsifier. The nonaqueous emulsion is in particular suitable for carrying out water-sensitive, catalytic and oxidative polymerizations and polycondensations. The invention further relates to nanoparticles produced according to said process and their use.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US83146906P | 2006-07-18 | 2006-07-18 | |
US60/831,469 | 2006-07-18 |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2008009424A2 WO2008009424A2 (en) | 2008-01-24 |
WO2008009424A3 true WO2008009424A3 (en) | 2008-03-20 |
Family
ID=38578561
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/EP2007/006345 WO2008009424A2 (en) | 2006-07-18 | 2007-07-17 | Nonaqueous emulsion polymerisation |
Country Status (1)
Country | Link |
---|---|
WO (1) | WO2008009424A2 (en) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109575247B (en) * | 2018-11-21 | 2022-12-06 | 华东理工大学 | Method for preparing polycaprolactone porous material based on non-aqueous high internal phase emulsion |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3580880A (en) * | 1966-11-25 | 1971-05-25 | Balm Paints Ltd | Dispersions of particulate solids in either lipophilic or hydrophilic liquids stabilized with a polymeric amphipathic stabiliser and process for preparing said dispersions |
US3981839A (en) * | 1973-06-18 | 1976-09-21 | Imperial Chemical Industries Limited | Process for the preparation of polymer dispersions |
US4098980A (en) * | 1976-06-24 | 1978-07-04 | The Goodyear Tire & Rubber Company | Non-aqueous dispersion polymerization of conjugated diolefins |
US4687811A (en) * | 1985-08-14 | 1987-08-18 | Mitsubishi Rayon Co., Ltd. | Polymerization process for polyester |
US4783502A (en) * | 1987-12-03 | 1988-11-08 | Ppg Industries, Inc. | Stable nonaqueous polyurethane microparticle dispersion |
US4833177A (en) * | 1987-12-03 | 1989-05-23 | Ppg Industries, Inc. | Method for preparing stably dispersed nonaqueous microparticle dispersion |
EP1082376B1 (en) * | 1998-03-19 | 2002-10-16 | Ticona GmbH | Manufacturing methods, based on non aqueous dispersion techniques, to produce spherical polyester particles with narrow particle size distributions and tailorable mean particle sizes |
US6964994B1 (en) * | 1999-07-22 | 2005-11-15 | Max-Planck-Gesellschaft Zur Forderung Der Wissenschaften E.V. | Polyreactions in non-aqueous miniemulsions |
-
2007
- 2007-07-17 WO PCT/EP2007/006345 patent/WO2008009424A2/en active Application Filing
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3580880A (en) * | 1966-11-25 | 1971-05-25 | Balm Paints Ltd | Dispersions of particulate solids in either lipophilic or hydrophilic liquids stabilized with a polymeric amphipathic stabiliser and process for preparing said dispersions |
US3981839A (en) * | 1973-06-18 | 1976-09-21 | Imperial Chemical Industries Limited | Process for the preparation of polymer dispersions |
US4098980A (en) * | 1976-06-24 | 1978-07-04 | The Goodyear Tire & Rubber Company | Non-aqueous dispersion polymerization of conjugated diolefins |
US4687811A (en) * | 1985-08-14 | 1987-08-18 | Mitsubishi Rayon Co., Ltd. | Polymerization process for polyester |
US4783502A (en) * | 1987-12-03 | 1988-11-08 | Ppg Industries, Inc. | Stable nonaqueous polyurethane microparticle dispersion |
US4833177A (en) * | 1987-12-03 | 1989-05-23 | Ppg Industries, Inc. | Method for preparing stably dispersed nonaqueous microparticle dispersion |
EP1082376B1 (en) * | 1998-03-19 | 2002-10-16 | Ticona GmbH | Manufacturing methods, based on non aqueous dispersion techniques, to produce spherical polyester particles with narrow particle size distributions and tailorable mean particle sizes |
US6964994B1 (en) * | 1999-07-22 | 2005-11-15 | Max-Planck-Gesellschaft Zur Forderung Der Wissenschaften E.V. | Polyreactions in non-aqueous miniemulsions |
Non-Patent Citations (9)
Title |
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BARRÈRE M., LANDFESTER K.: "Polyester synthesis in aqueous miniemulsion", POLYMER, vol. 44, 2003, pages 2833 - 2841, XP002455941 * |
BUNN A., GRIFFIN B.P., MACDONALD W.A., RANCE D.G.: "A novel high-temperature non-aqueous dispersion polymerization route to fully aromatic main-chain liquid-crystal polymers", POLYMER, vol. 33, no. 14, 1992, pages 3066 - 3072, XP002455946 * |
CLOUTET E., RADHAKRISHNAN B., CRAMAIL H.: "o-OH polystyrene and o-OH poly(n-butyl acrylate) as reactive stabilizers for the preparation of uniform polyurethane particles in a dispersed medium", POLYMER INTERNATIONAL, vol. 51, 2002, pages 978 - 985, XP002455944 * |
MORRIN A ET AL: "Novel biosensor fabrication methodology based on processable conducting polyaniline nanoparticles", ELECTROCHEMISTRY COMMUNICATION, ELSEVIER, AMSTERDAM, NL, vol. 7, no. 3, March 2005 (2005-03-01), pages 317 - 322, XP004741129, ISSN: 1388-2481 * |
MÜLLER K., KLAPPER M., MÜLLEN K.: "Synthesis of conjugated polymer nanoparticles in non-aqueous emulsions", MACROMOLECULAR RAPID COMMUNICATIONS, vol. 27, 21 April 2006 (2006-04-21), pages 586 - 593, XP002455940 * |
RAMANATHAN L.S., BASKARAN D., SHUKLA P.G., SIVARAM S.: "Preparation of polyurethane microspheres via dispersion polycondensation using poly (1,4-isoprene)-block-poly(ethylene oxide) as steric stabilizer", MACROMOLECULAR CHEMISTRY AND PHYSICS, vol. 203, 2002, pages 998 - 1002, XP002455945 * |
RIESS G., LABBE C.: "Block copolymers in enulsion and dispersion polymerization", MACROMOLECULAR RAPID COMMUNICATIONS, vol. 25, 2004, pages 401 - 435, XP002455947 * |
RIESS G.: "Etude des propriétés surfactives des copolymères séquencés", DIE MAKROMOLEKULÄRE CHEMIE; SUPPLEMENT, vol. 13, 1985, pages 157 - 169, XP002455942 * |
ZWEERS M. L.T., GRIJPMA D.W., ENGBERTS G. H.M., FEIJEN J., JOURNAL OF BIOMEDICAL MATERIALS RESEARCH : PART B APPLIED BIOMATERIALS, vol. 66b, 2003, pages 559 - 566, XP002455943 * |
Also Published As
Publication number | Publication date |
---|---|
WO2008009424A2 (en) | 2008-01-24 |
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