WO2007075370A3 - Process for converting carbohydrates to hydrocarbons - Google Patents
Process for converting carbohydrates to hydrocarbons Download PDFInfo
- Publication number
- WO2007075370A3 WO2007075370A3 PCT/US2006/047807 US2006047807W WO2007075370A3 WO 2007075370 A3 WO2007075370 A3 WO 2007075370A3 US 2006047807 W US2006047807 W US 2006047807W WO 2007075370 A3 WO2007075370 A3 WO 2007075370A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- carbohydrates
- processes
- hydrocarbons
- solubility
- aromatic
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
- C07C51/377—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by splitting-off hydrogen or functional groups; by hydrogenolysis of functional groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B30/00—Preparation of starch, degraded or non-chemically modified starch, amylose, or amylopectin
- C08B30/12—Degraded, destructured or non-chemically modified starch, e.g. mechanically, enzymatically or by irradiation; Bleaching of starch
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/47—Catalytic treatment characterised by the catalyst used containing platinum group metals or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
- C10G3/48—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support
- C10G3/49—Catalytic treatment characterised by the catalyst used further characterised by the catalyst support containing crystalline aluminosilicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1011—Biomass
- C10G2300/1014—Biomass of vegetal origin
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/80—Additives
- C10G2300/805—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
Abstract
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BRPI0619976-3A BRPI0619976A2 (en) | 2005-12-16 | 2006-12-14 | process for converting carbohydrates into hydrocarbons |
CA2633446A CA2633446C (en) | 2005-12-16 | 2006-12-14 | Process for converting carbohydrates to hydrocarbons |
EP06845471.9A EP1968917A4 (en) | 2005-12-16 | 2006-12-14 | Process for converting carbohydrates to hydrocarbons |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/303,636 | 2005-12-16 | ||
US11/303,636 US7678950B2 (en) | 2005-12-16 | 2005-12-16 | Process for converting carbohydrates to hydrocarbons |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2007075370A2 WO2007075370A2 (en) | 2007-07-05 |
WO2007075370A3 true WO2007075370A3 (en) | 2008-05-02 |
Family
ID=38174600
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2006/047807 WO2007075370A2 (en) | 2005-12-16 | 2006-12-14 | Process for converting carbohydrates to hydrocarbons |
Country Status (5)
Country | Link |
---|---|
US (1) | US7678950B2 (en) |
EP (1) | EP1968917A4 (en) |
BR (1) | BRPI0619976A2 (en) |
CA (2) | CA2808278C (en) |
WO (1) | WO2007075370A2 (en) |
Families Citing this family (32)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8450542B2 (en) * | 2005-12-16 | 2013-05-28 | Phillips 66 Company | Integrated process for converting carbohydrates to hydrocarbons |
US8778034B2 (en) * | 2006-09-14 | 2014-07-15 | Afton Chemical Corporation | Biodegradable fuel performance additives |
CN101012387B (en) * | 2007-02-01 | 2011-05-11 | 淮北中润生物能源技术开发有限公司 | Technique for manufacturing liquid fuel from highly effective cellulose biomass |
US8697924B2 (en) * | 2008-09-05 | 2014-04-15 | Shell Oil Company | Liquid fuel compositions |
AU2014202232B2 (en) * | 2008-09-05 | 2015-03-26 | Shell Internationale Research Maatschappij B.V. | Liquid fuel compositions based on catalytically deoxygenated and condensated oxygenated carbohydrates |
EP2440515B1 (en) | 2009-06-13 | 2018-08-15 | Archer-Daniels-Midland Company | Production of adipic acid and derivatives from carbohydrate-containing materials |
US8669397B2 (en) | 2009-06-13 | 2014-03-11 | Rennovia, Inc. | Production of adipic acid and derivatives from carbohydrate-containing materials |
NZ596974A (en) | 2009-06-13 | 2014-03-28 | Rennovia Inc | Production of glutaric acid and derivatives from carbohydrate-containing materials |
US8314267B2 (en) | 2009-06-26 | 2012-11-20 | Uop Llc | Carbohydrate route to para-xylene and terephthalic acid |
WO2011025632A1 (en) | 2009-08-24 | 2011-03-03 | Conocophillips Company | Hydrotreating carbohydrates |
US8702822B2 (en) * | 2009-08-28 | 2014-04-22 | Regents Of The University Of Minnesota | Method and apparatus for producing a fuel from a biomass or bio-oil |
WO2011046690A1 (en) * | 2009-10-12 | 2011-04-21 | Conocophillips Company | Sugar alcohol split injection conversion |
CA2779140C (en) * | 2009-12-22 | 2017-11-21 | Jianhua Yao | Conversion of carbohydrates to hydrocarbons |
US20120315366A1 (en) * | 2009-12-23 | 2012-12-13 | Evonik Degussa Gmbh | Sweetener and method of production thereof |
US9303226B2 (en) * | 2009-12-31 | 2016-04-05 | Shell Oil Company | Direct aqueous phase reforming of bio-based feedstocks |
US9447347B2 (en) | 2009-12-31 | 2016-09-20 | Shell Oil Company | Biofuels via hydrogenolysis-condensation |
US8669393B2 (en) | 2010-03-05 | 2014-03-11 | Rennovia, Inc. | Adipic acid compositions |
US9193593B2 (en) | 2010-03-26 | 2015-11-24 | Dioxide Materials, Inc. | Hydrogenation of formic acid to formaldehyde |
WO2011139551A2 (en) | 2010-04-27 | 2011-11-10 | Conocophillips Company | Carbohydrates upgrading and hydrotreating to hydrocarbons |
CN102947248B (en) | 2010-05-12 | 2016-06-29 | 国际壳牌研究有限公司 | Including biomass hydrogenolysis and dehydrogenation subsequently and the aldol condensation method to produce alkane |
EP2569264A1 (en) | 2010-05-12 | 2013-03-20 | Shell Oil Company | Process including hydrogenolysis of biomass followed by dehydrogenation and aldol condensation for producing alkanes |
US9770705B2 (en) | 2010-06-11 | 2017-09-26 | Rennovia Inc. | Oxidation catalysts |
WO2012047435A1 (en) | 2010-10-07 | 2012-04-12 | Conocophillips Company | Co-production of renewable diesel and renewable gasoline |
WO2012050662A2 (en) | 2010-10-14 | 2012-04-19 | Conocophillips Company | Combination of zeolite upgrading with hydrogenation upgrading to produce renewable gasoline from biomass |
US8673805B2 (en) | 2011-02-17 | 2014-03-18 | Phillips 66 Company | MoS2 catalyst for the conversion of sugar alcohol to hydrocarbons |
PL2720991T3 (en) | 2011-06-14 | 2015-12-31 | Shell Int Research | Co-production of biofuels and glycols |
US8822745B2 (en) | 2011-12-06 | 2014-09-02 | Phillips 66 Company | Pyrolysis oil upgrading to gasoline range liquids |
JP6148720B2 (en) | 2012-03-12 | 2017-06-14 | アーチャー−ダニエルズ−ミッドランド カンパニー | Process for producing sugar and / or sugar alcohol dehydrate |
EP3143101B1 (en) | 2014-05-12 | 2021-02-24 | Katholieke Universiteit Leuven K.U. Leuven R&D | Biphasic solvent catalytic process for the direct production of light naphtha from carbohydrate-containing feedstock. |
HUE058236T2 (en) | 2014-08-19 | 2022-07-28 | Archer Daniels Midland Co | Catalyst and process for producing 2,5-furandicarboxylic acid from hydromethylfurfural in water |
DK3416740T3 (en) | 2016-02-19 | 2021-02-08 | Intercontinental Great Brands Llc | PROCEDURES FOR FORMATION OF MULTIPLE VALUE FLOWS FROM BIOMASS SOURCES |
WO2018116270A1 (en) * | 2016-12-23 | 2018-06-28 | Petiva Private Ltd. | Process for producing glucose and fructose from sucrose and separation of the glucose and fructose thereof |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4330625A (en) * | 1980-03-12 | 1982-05-18 | National Distillers & Chemical Corp. | Liquefying aqueous starch slurry followed by saccharification with ion exchange resin |
US4523928A (en) * | 1980-04-28 | 1985-06-18 | Battelle Development Corporation | Gasohol production from thermochemical conversion of biomass to ethanol |
US4549031A (en) * | 1984-01-30 | 1985-10-22 | Mobil Oil Corporation | Conversion of carbohydrates |
US5494602A (en) * | 1995-01-31 | 1996-02-27 | National Starch And Chemical Investment Holding Corporation | Method for preparing hydrophobically-terminated polysaccharide polymers and detergent compositions comprising the polysaccharide polymers |
US5600028A (en) * | 1992-01-31 | 1997-02-04 | Montecatini Technologie S.R.L. | Method for producing lower polyhydric alcohols and a new ruthenium-based catalyst used in this method |
US20050112739A1 (en) * | 2003-10-24 | 2005-05-26 | Swedish Biofuels Ab | Method for producing hydrocarbons and oxygen-containing compounds from biomass |
Family Cites Families (26)
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US1411203A (en) * | 1921-02-07 | 1922-03-28 | Stein Hall Mfg Co | Starch-conversion product |
US1411204A (en) * | 1921-02-07 | 1922-03-28 | Stein Hall Mfg Co | Method of preparing starch conversion products |
US2518235A (en) * | 1946-01-07 | 1950-08-08 | Shell Dev | Hydrogenation of carbohydrates |
US4011278A (en) * | 1963-02-27 | 1977-03-08 | Mobil Oil Corporation | Conversion of polar compounds using a zsm-5 zeolite catalyst |
US3630775A (en) * | 1970-05-08 | 1971-12-28 | Cpc International Inc | Spray-dried solubilized starch |
US3695933A (en) * | 1970-08-12 | 1972-10-03 | Cpc International Inc | Procfss for the production of a defatted starch conversion product |
US3998898A (en) * | 1973-08-09 | 1976-12-21 | Mobil Oil Corporation | Manufacture of gasoline |
US3963789A (en) * | 1974-12-12 | 1976-06-15 | Kruse Walter M | Polyhydric alcohol production using RU on clay supports |
US4148835A (en) * | 1978-04-14 | 1979-04-10 | Mobil Oil Corporation | Hydrocarbon manufacture from alcohols |
US4306106A (en) * | 1978-06-05 | 1981-12-15 | Mobil Oil Corporation | Conversion of polar compounds using a ZSM-5 zeolite catalyst |
US4300009A (en) * | 1978-12-28 | 1981-11-10 | Mobil Oil Corporation | Conversion of biological material to liquid fuels |
US4308411A (en) * | 1980-08-28 | 1981-12-29 | Occidental Research Corporation | Process for converting oxygenated hydrocarbons into hydrocarbons |
US4430253A (en) * | 1982-02-11 | 1984-02-07 | Ethyl Corporation | Sulfide-modified ruthenium catalyst |
US4380680A (en) * | 1982-05-21 | 1983-04-19 | Uop Inc. | Method for hydrogenating aqueous solutions of carbohydrates |
US4503278A (en) * | 1982-09-30 | 1985-03-05 | Mobil Oil Corporation | Process for converting carbohydrates to hydrocarbons |
CA1195311A (en) * | 1983-04-26 | 1985-10-15 | Peter H. Bird | Composite zeolite-asbestos catalysts |
US4933283A (en) * | 1985-05-15 | 1990-06-12 | Mobil Oil Corporation | Process for converting cellulosic materials to hydrocarbon products |
EP0329923B1 (en) * | 1988-02-22 | 1993-04-21 | Fina Research S.A. | Single-step catalytic process for the direct conversion of polysaccharides to polyhydric alcohols |
US5112739A (en) * | 1988-08-02 | 1992-05-12 | Polaroid Corporation | Enzyme controlled release system |
US5194094A (en) * | 1991-06-12 | 1993-03-16 | American Maize-Products Company | Fractionating starch hydrolysates |
US5348871A (en) * | 1992-05-15 | 1994-09-20 | Martin Marietta Energy Systems, Inc. | Process for converting cellulosic materials into fuels and chemicals |
JP2715186B2 (en) * | 1992-05-27 | 1998-02-18 | エクソン・ケミカル・パテンツ・インク | Production method of high purity olefin |
US5396016A (en) * | 1993-08-19 | 1995-03-07 | Mobil Oil Corp. | MCM-36 as a catalyst for upgrading paraffins |
PT101740A (en) * | 1995-07-21 | 1996-04-30 | Rar Refinarias Acucar Reunidas | PROCESS FOR REGENERATING IONIC PERFUME RESINS, USED FOR DECORATION OF ACUCAR, USING A SOLUTION OF SACRAROSE CONTAINING CALCIUM HYDROXIDE AND CALCIUM OR SODIUM CHLORIDE. |
US6570043B2 (en) * | 1999-09-03 | 2003-05-27 | Battelle Memorial Institute | Converting sugars to sugar alcohols by aqueous phase catalytic hydrogenation |
US6479713B1 (en) * | 2001-10-23 | 2002-11-12 | Battelle Memorial Institute | Hydrogenolysis of 5-carbon sugars, sugar alcohols, and other methods and compositions for reactions involving hydrogen |
-
2005
- 2005-12-16 US US11/303,636 patent/US7678950B2/en active Active
-
2006
- 2006-12-14 WO PCT/US2006/047807 patent/WO2007075370A2/en active Application Filing
- 2006-12-14 CA CA2808278A patent/CA2808278C/en active Active
- 2006-12-14 BR BRPI0619976-3A patent/BRPI0619976A2/en not_active Application Discontinuation
- 2006-12-14 CA CA2633446A patent/CA2633446C/en active Active
- 2006-12-14 EP EP06845471.9A patent/EP1968917A4/en not_active Withdrawn
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4330625A (en) * | 1980-03-12 | 1982-05-18 | National Distillers & Chemical Corp. | Liquefying aqueous starch slurry followed by saccharification with ion exchange resin |
US4523928A (en) * | 1980-04-28 | 1985-06-18 | Battelle Development Corporation | Gasohol production from thermochemical conversion of biomass to ethanol |
US4549031A (en) * | 1984-01-30 | 1985-10-22 | Mobil Oil Corporation | Conversion of carbohydrates |
US5600028A (en) * | 1992-01-31 | 1997-02-04 | Montecatini Technologie S.R.L. | Method for producing lower polyhydric alcohols and a new ruthenium-based catalyst used in this method |
US5494602A (en) * | 1995-01-31 | 1996-02-27 | National Starch And Chemical Investment Holding Corporation | Method for preparing hydrophobically-terminated polysaccharide polymers and detergent compositions comprising the polysaccharide polymers |
US20050112739A1 (en) * | 2003-10-24 | 2005-05-26 | Swedish Biofuels Ab | Method for producing hydrocarbons and oxygen-containing compounds from biomass |
Also Published As
Publication number | Publication date |
---|---|
US7678950B2 (en) | 2010-03-16 |
CA2633446C (en) | 2014-10-14 |
BRPI0619976A2 (en) | 2011-10-25 |
WO2007075370A2 (en) | 2007-07-05 |
EP1968917A4 (en) | 2014-05-21 |
US20070142633A1 (en) | 2007-06-21 |
CA2633446A1 (en) | 2007-07-05 |
CA2808278C (en) | 2015-02-24 |
EP1968917A2 (en) | 2008-09-17 |
CA2808278A1 (en) | 2007-07-05 |
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