WO2007026117A1 - Marking application method - Google Patents

Marking application method Download PDF

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Publication number
WO2007026117A1
WO2007026117A1 PCT/GB2006/003098 GB2006003098W WO2007026117A1 WO 2007026117 A1 WO2007026117 A1 WO 2007026117A1 GB 2006003098 W GB2006003098 W GB 2006003098W WO 2007026117 A1 WO2007026117 A1 WO 2007026117A1
Authority
WO
WIPO (PCT)
Prior art keywords
substrate
carrier
coating
mark
mark material
Prior art date
Application number
PCT/GB2006/003098
Other languages
French (fr)
Inventor
David Anthony Hulland
Stephen Donaghue
Original Assignee
Proteckta Steel Limited
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Proteckta Steel Limited filed Critical Proteckta Steel Limited
Priority to EP06779170A priority Critical patent/EP2007588A1/en
Publication of WO2007026117A1 publication Critical patent/WO2007026117A1/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/035—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/0256—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet the transferable ink pattern being obtained by means of a computer driven printer, e.g. an ink jet or laser printer, or by electrographic means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/035—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
    • B41M5/0355—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic characterised by the macromolecular coating or impregnation used to obtain dye receptive properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/025—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet
    • B41M5/035—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic
    • B41M5/0356—Duplicating or marking methods; Sheet materials for use therein by transferring ink from the master sheet by sublimation or volatilisation of pre-printed design, e.g. sublistatic characterised by the inks used for printing the pattern on the temporary support or additives therefor, e.g. dyes, transferable compounds, binders or transfer promoting additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5263—Macromolecular coatings characterised by the use of polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • B41M5/5272—Polyesters; Polycarbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5263—Macromolecular coatings characterised by the use of polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • B41M5/5281—Polyurethanes or polyureas

Definitions

  • This invention concerns a method of applying a marking, and particularly a method of applying a marking onto antimicrobial coated material, and especially coated metal, glass or plastics material.
  • marking is to be understood as covering, inter alia, a decoration, pattern, image, colour, wording, logo or other which may be applied on to a surface.
  • Antimicrobial coated steels have been in use for some time. With for instance the advent of MRSA, the use of such materials has increased significantly. One area where this use has grown significantly is in kitchen implements and appliances. It is often wished to decorate or otherwise mark such steel, with for instance to a trade mark or other indication. However, if a marking is simply printed or painted on the coating, this will sit on the surface thereof and interfere with the coating's performance and properties. Antimicrobial coatings are also provided on other materials such as glass or plastics material, for use in the home, kitchens or medical situations.
  • Anti graffiti coatings are used in a wide range of applications. Such coatings readily permit markings thereon to be wiped off or removed with one of a selection of solvents. This can mean that it is difficult to satisfactorily decorate or mark items or structures with such coatings.
  • a method of applying a marking onto a coated substrate including locating on a carrier mark material to be applied onto the substrate, the mark material being of a type which sublimes, bringing the carrier against the coated substrate such that the mark material is in contact with the coated substrate, applying heat such that the mark material sublimes to a gas, and retaining the carrier against the substrate until the mark material in gaseous form has moved from the carrier and entered the coating on the substrate.
  • the carrier may be a carrier film or could be paper.
  • the mark material may be a disperse dyestuff.
  • the mark material may be initially printed onto the carrier, and may be printed by any of inkjet, digital, electrostatic, screen, flexo, offset, or Gravure printing processes.
  • the substrate may have an antimicrobial coating.
  • the antimicrobial coating may include an active material within a host material.
  • the active material may include silver, and may include titanium dioxide and silver chloride. Alternatively the active material may be organic.
  • the host material may include any of polyester, polyester resin, polyether sulphone (PES) resin, PU (polyurethane), or PU copolymers.
  • PET polyether sulphone
  • PU polyurethane
  • the substrate may have an anti graffiti coating.
  • the coating may be polyester based.
  • the coating preferably includes greater than 80% polyester.
  • the coating may be in the form of a powder coating.
  • the carrier is preferably brought to a temperature of greater than
  • the substrate may comprise a metal which may be any one of steel, aluminium, copper or brass.
  • the metal may be a ferritic metal or may alternatively be a non-ferritic metal.
  • the substrate may comprise glass or plasties material.
  • the carrier is preferably retained against the substrate for greater than 15 seconds, and desirably greater than five minutes.
  • the method is carried out in an enclosure at reduced pressure.
  • the invention also provides a marked coated substrate, the marking on the substrate having been applied by a method according to any of the 15 preceding fifteen paragraphs.
  • the substrate may be any of metal, glass or plastics material.
  • stainless steel is slit down to a dimension of 720mm. This is then brushed to provide polishing to achieve a "scotch bright finish".
  • the steel is then painted with an antimicrobial coating in the form of titanium 5 dioxide and silver chloride in a clear polyester host. The painted steel is surface cleaned, cured and a protective film applied. If required an adhesive tape can be applied on the reverse.
  • a marking is then applied to the coated steel as follows.
  • appropriate marking of a disperse dyestuff is inkjet printed onto a plastics material carrier film.
  • the film is located against the coated steel with the marking in contact therewith. This may be carried out on a flat bed with the carrier above or below the steel.
  • similarly prepared steel is coated with an anti graffiti coating.
  • the coating is reinforced polyurethane such as lnterpon EC available from Akzo Nobel.
  • the coating is applied manually or automatically using electrostatic spray equipment, with excess material being reclaimed and recycled.
  • Such a coating is suitable for outdoor use in architectural applications, and readily permits graffiti to be removed by wiping or appropriate solvents.
  • a marking can then be applied as described above for decoration, to provide an indication or signage or otherwise.
  • the invention could be carried out on a polyester based anti graffiti coating, with greater than 80% polyester.
  • the invention could be used with coated metal substrates other than steel, and the substrates could be glass or plastics material.
  • a wide range of different markings can be used, and different temperatures and retention times may be required to provide sublimation of these materials into the coating.
  • the marking may be differently applied to the backing material, and different printing techniques such as digital, electrostatic, screen, flexo, offset or Gravure could be used. It may be that the marking is applied to the carrier material other than by printing.
  • the carrier material could be other than plastics film, and could be paper.
  • Any antimicrobial coating may include a different active silver agent, or may include an organic active agent.
  • the host material of the coating could be or could include a polyester resin, polyether sulphone (PES) resin, PU, or PU copolymer.

Abstract

A method of applying a marking onto a coated substrate, the method including ink jet printing a design of a disperse dyestuff onto a plastics material carrier film, bringing the film against the coated substrate, and applying heat and pressure such that the disperse dyestuff sublimes and then passes into the coating.

Description

MARKING APPLICATION METHOD
This invention concerns a method of applying a marking, and particularly a method of applying a marking onto antimicrobial coated material, and especially coated metal, glass or plastics material.
In this specification the term "marking" is to be understood as covering, inter alia, a decoration, pattern, image, colour, wording, logo or other which may be applied on to a surface.
Antimicrobial coated steels have been in use for some time. With for instance the advent of MRSA, the use of such materials has increased significantly. One area where this use has grown significantly is in kitchen implements and appliances. It is often wished to decorate or otherwise mark such steel, with for instance to a trade mark or other indication. However, if a marking is simply printed or painted on the coating, this will sit on the surface thereof and interfere with the coating's performance and properties. Antimicrobial coatings are also provided on other materials such as glass or plastics material, for use in the home, kitchens or medical situations.
Anti graffiti coatings are used in a wide range of applications. Such coatings readily permit markings thereon to be wiped off or removed with one of a selection of solvents. This can mean that it is difficult to satisfactorily decorate or mark items or structures with such coatings.
According to the present invention there is provided a method of applying a marking onto a coated substrate , the method including locating on a carrier mark material to be applied onto the substrate, the mark material being of a type which sublimes, bringing the carrier against the coated substrate such that the mark material is in contact with the coated substrate, applying heat such that the mark material sublimes to a gas, and retaining the carrier against the substrate until the mark material in gaseous form has moved from the carrier and entered the coating on the substrate.
The carrier may be a carrier film or could be paper. The mark material may be a disperse dyestuff. The mark material may be initially printed onto the carrier, and may be printed by any of inkjet, digital, electrostatic, screen, flexo, offset, or Gravure printing processes.
The substrate may have an antimicrobial coating.
The antimicrobial coating may include an active material within a host material. The active material may include silver, and may include titanium dioxide and silver chloride. Alternatively the active material may be organic.
The host material may include any of polyester, polyester resin, polyether sulphone (PES) resin, PU (polyurethane), or PU copolymers.
Alternatively the substrate may have an anti graffiti coating.
The coating may be polyester based.
The coating preferably includes greater than 80% polyester.
The coating may be in the form of a powder coating.
When the carrier is brought against the substrate, sufficient pressure is preferably applied to the carrier to substantially evacuate any air from between the carrier and the substrate.
The carrier is preferably brought to a temperature of greater than
18O0C to cause sublimation of the mark material. The substrate may comprise a metal which may be any one of steel, aluminium, copper or brass. The metal may be a ferritic metal or may alternatively be a non-ferritic metal.
5 The substrate may comprise glass or plasties material.
The carrier is preferably retained against the substrate for greater than 15 seconds, and desirably greater than five minutes.
I O In one arrangement the method is carried out in an enclosure at reduced pressure.
The invention also provides a marked coated substrate, the marking on the substrate having been applied by a method according to any of the 15 preceding fifteen paragraphs.
The substrate may be any of metal, glass or plastics material.
Embodiments of the present invention will now be described by way of 0 example only.
In a first example stainless steel is slit down to a dimension of 720mm. This is then brushed to provide polishing to achieve a "scotch bright finish". The steel is then painted with an antimicrobial coating in the form of titanium 5 dioxide and silver chloride in a clear polyester host. The painted steel is surface cleaned, cured and a protective film applied. If required an adhesive tape can be applied on the reverse.
A marking is then applied to the coated steel as follows. An
30 appropriate marking of a disperse dyestuff is inkjet printed onto a plastics material carrier film. The film is located against the coated steel with the marking in contact therewith. This may be carried out on a flat bed with the carrier above or below the steel.
Sufficient pressure is applied to remove any air from between the carrier and the steel. Heat is applied to bring the temperature of the marking on the carrier to around 21O0C. The disperse dyestuffs of the marking sublime and the marking passes into the antimicrobial coating, beneath the surface thereof. The carrier film is retained against the steel during heat application for around three to five minutes or more, to ensure that all of the marking has sublimed into the coating.
There is thus described a method of applying a marking onto antimicrobial coated steel. This provides a required marking which could be a decoration, trade mark, wording or other indication, but which marking is located within the coating so as not to affect the performance or properties thereof. The marking is also therefore durable, being as durable as the coating within which it is held.
In a second example similarly prepared steel is coated with an anti graffiti coating. The coating is reinforced polyurethane such as lnterpon EC available from Akzo Nobel. The coating is applied manually or automatically using electrostatic spray equipment, with excess material being reclaimed and recycled. Such a coating is suitable for outdoor use in architectural applications, and readily permits graffiti to be removed by wiping or appropriate solvents. A marking can then be applied as described above for decoration, to provide an indication or signage or otherwise.
The invention could be carried out on a polyester based anti graffiti coating, with greater than 80% polyester.
It is to be realised that a wide range of other modifications may be made without departing from the scope of the invention. For instance the invention could be used with coated metal substrates other than steel, and the substrates could be glass or plastics material. A wide range of different markings can be used, and different temperatures and retention times may be required to provide sublimation of these materials into the coating.
The marking may be differently applied to the backing material, and different printing techniques such as digital, electrostatic, screen, flexo, offset or Gravure could be used. It may be that the marking is applied to the carrier material other than by printing. The carrier material could be other than plastics film, and could be paper.
Any antimicrobial coating may include a different active silver agent, or may include an organic active agent. The host material of the coating could be or could include a polyester resin, polyether sulphone (PES) resin, PU, or PU copolymer.
Whilst endeavouring in the foregoing specification to draw attention to those features of the invention believed to be of particular importance it should be understood that the Applicant claims protection in respect of any patentable feature or combination of features hereinbefore referred to and/or shown in the drawings whether or not particular emphasis has been placed thereon.

Claims

1. A method of applying a marking onto a coated substrate , the method including locating on a carrier mark material to be applied onto the substrate, the mark material being of a type which sublimes, bringing the carrier against the coated substrate such that the mark material is in contact with the coated substrate, applying heat such that the mark material sublimes to a gas, and retaining the carrier against the substrate until the mark material in gaseous form has moved from the carrier and entered the coating on the substrate.
2. A method according to claim 1 , characterised in that the carrier is a carrier film.
3. A method according to claim 1 , characterised in that the carrier is paper.
4. A method according to any of the preceding claims, characterised in that the mark material is a disperse dyestuff.
5. A method according to any of the preceding claims, characterised in that the mark material is initially printed onto the carrier.
6. A method according to claim 5, characterised in that the mark material is printed by any of inkjet, digital, electrostatic, screen, flexo, offset, or
Gravure printing processes.
7. A method according to any of the preceding claims, characterised in that the substrate has an antimicrobial coating.
8. A method according to claim 7, characterised in that the antimicrobial coating includes an active material within a host material.
9. A method according to claim 8, characterised in that the active material includes silver.
10. A method according to claim 9, characterised in that the active material includes titanium dioxide and silver chloride.
11. A method according to claim 8, characterised in that the active material is organic.
12. A method according to any of claims 8 to 11 , characterised in that the host material includes any of polyester, polyester resin, polyether sulphone (PES) resin, PU (polyurethane), or PU copolymers.
13. A method according to any of claims 1 to 6, characterised in that the substrate has an anti graffiti coating.
14. A method according to any of the preceding claims, characterised in that the coating is polyester based.
15. A method according to claim 14, characterised in that the coating includes greater than 80% polyester.
16. A method according to any of the preceding claims, characterised in that the coating is in the form of a powder coating.
17. A method according to any of the preceding claims, characterised in that when the carrier is brought against the substrate, sufficient pressure is applied to the carrier to substantially evacuate any air from between the carrier and the substrate.
18. A method according to any of the preceding claims, characterised in that the carrier is brought to a temperature of greater than 18O0C to cause sublimation of the mark material.
19. A method according to any of the preceding claims, characterised in that the substrate comprises a metal.
20. A method according to claim 19, characterised in that the substrate comprises any one of steel, aluminium, copper or brass.
21. A method according to any of claims 1 to 18, characterised in that the substrate comprises glass.
22. A method according to any of claims 1 to 18, characterised in that the substrate comprises plastics material.
23. A method according to any of the preceding claims, characterised in that the carrier is retained against the substrate for greater than 15 seconds.
24. A method according to claim 23, characterised in that the carrier is retained against the substrate for greater than five minutes.
25. A method according to any of the preceding claims, characterised in that the method is carried out in an enclosure at reduced pressure.
26. A marked coated substrate, characterised in that the marking on the substrate has been applied by a method according to any of the preceding claims.
27. A substrate according to claim 26, characterised in that the substrate is of metal.
28. A substrate according to claim 26, characterised in that the substrate is glass.
29. A substrate according to claim 26, characterised in that the substrate is plastics material.
PCT/GB2006/003098 2005-09-01 2006-08-21 Marking application method WO2007026117A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
EP06779170A EP2007588A1 (en) 2005-09-01 2006-08-21 Marking application method

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0517750.6 2005-09-01
GB0517750A GB0517750D0 (en) 2005-09-01 2005-09-01 Marking application method

Publications (1)

Publication Number Publication Date
WO2007026117A1 true WO2007026117A1 (en) 2007-03-08

Family

ID=35220639

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2006/003098 WO2007026117A1 (en) 2005-09-01 2006-08-21 Marking application method

Country Status (3)

Country Link
EP (1) EP2007588A1 (en)
GB (1) GB0517750D0 (en)
WO (1) WO2007026117A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7875672B2 (en) 2007-08-24 2011-01-25 Perstorp France Two component waterborne polyurethane coatings for anti-graffiti application
US20110111188A1 (en) * 2009-11-12 2011-05-12 Ming Xu Process for forming an image on a transparent acrylic article

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1527396A (en) * 1975-07-25 1978-10-04 Sublistatic Holding Sa Transfer print carriers and their manufacture
WO1992000852A1 (en) * 1990-07-09 1992-01-23 Sawgrass Systems , Inc. D/B/A The Sawgrass Co. Transfer printing process
WO1995021739A1 (en) * 1994-02-10 1995-08-17 Sawgrass Systems, Inc. A printing method of applying a polymer surface preparation to a substrate
US5663023A (en) * 1996-01-11 1997-09-02 Xerox Corporation Simulated photographic-quality prints using a transparent substrate containing a wrong reading image and a backing sheet containing a right reading image of the same information
WO1997046623A1 (en) * 1996-06-05 1997-12-11 Basf Aktiengesellschaft Dye preparations
EP0881128A2 (en) * 1997-05-28 1998-12-02 Trip Industries Holding B.V. Manufacture of signs using sublimable dyes
DE19825201A1 (en) * 1998-06-05 1999-12-09 Basf Ag Dye formulation used as ink in sublimation transfer and ink-jet printing
US6137516A (en) * 1994-02-15 2000-10-24 Xerox Corporation Recording sheets containing mildew preventing agents
GB2372013A (en) * 2001-02-13 2002-08-14 Photofone Ltd Transfer printing an image onto a mobile phone casing using heat and pressure
US20040041894A1 (en) * 2002-09-04 2004-03-04 Martin Thomas W. Dye sublimation ink-jet ink and dye sublimation transfer process using the same

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1527396A (en) * 1975-07-25 1978-10-04 Sublistatic Holding Sa Transfer print carriers and their manufacture
WO1992000852A1 (en) * 1990-07-09 1992-01-23 Sawgrass Systems , Inc. D/B/A The Sawgrass Co. Transfer printing process
WO1995021739A1 (en) * 1994-02-10 1995-08-17 Sawgrass Systems, Inc. A printing method of applying a polymer surface preparation to a substrate
US6137516A (en) * 1994-02-15 2000-10-24 Xerox Corporation Recording sheets containing mildew preventing agents
US5663023A (en) * 1996-01-11 1997-09-02 Xerox Corporation Simulated photographic-quality prints using a transparent substrate containing a wrong reading image and a backing sheet containing a right reading image of the same information
WO1997046623A1 (en) * 1996-06-05 1997-12-11 Basf Aktiengesellschaft Dye preparations
EP0881128A2 (en) * 1997-05-28 1998-12-02 Trip Industries Holding B.V. Manufacture of signs using sublimable dyes
DE19825201A1 (en) * 1998-06-05 1999-12-09 Basf Ag Dye formulation used as ink in sublimation transfer and ink-jet printing
GB2372013A (en) * 2001-02-13 2002-08-14 Photofone Ltd Transfer printing an image onto a mobile phone casing using heat and pressure
US20040041894A1 (en) * 2002-09-04 2004-03-04 Martin Thomas W. Dye sublimation ink-jet ink and dye sublimation transfer process using the same

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7875672B2 (en) 2007-08-24 2011-01-25 Perstorp France Two component waterborne polyurethane coatings for anti-graffiti application
US20110111188A1 (en) * 2009-11-12 2011-05-12 Ming Xu Process for forming an image on a transparent acrylic article
GB2480721A (en) * 2009-11-12 2011-11-30 Sawgrass Technologies Inc Process for forming an image on a transparent acrylic article

Also Published As

Publication number Publication date
GB0517750D0 (en) 2005-10-12
EP2007588A1 (en) 2008-12-31

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