WO2006110660A1 - Method and catalyst for producing a crude product having a reduced mcr content - Google Patents
Method and catalyst for producing a crude product having a reduced mcr content Download PDFInfo
- Publication number
- WO2006110660A1 WO2006110660A1 PCT/US2006/013328 US2006013328W WO2006110660A1 WO 2006110660 A1 WO2006110660 A1 WO 2006110660A1 US 2006013328 W US2006013328 W US 2006013328W WO 2006110660 A1 WO2006110660 A1 WO 2006110660A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- grams
- catalyst
- column
- crude
- metal
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 441
- 239000012043 crude product Substances 0.000 title claims abstract description 193
- 238000000034 method Methods 0.000 title claims abstract description 117
- 230000002829 reductive effect Effects 0.000 title description 37
- 239000000203 mixture Substances 0.000 claims abstract description 92
- 239000000047 product Substances 0.000 claims abstract description 77
- 239000007788 liquid Substances 0.000 claims abstract description 20
- 229910052751 metal Inorganic materials 0.000 claims description 354
- 239000002184 metal Substances 0.000 claims description 354
- 239000011148 porous material Substances 0.000 claims description 266
- 150000002739 metals Chemical class 0.000 claims description 102
- 238000009826 distribution Methods 0.000 claims description 74
- 230000000737 periodic effect Effects 0.000 claims description 74
- 150000007524 organic acids Chemical class 0.000 claims description 66
- 150000001875 compounds Chemical class 0.000 claims description 63
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 55
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 39
- 239000001257 hydrogen Substances 0.000 claims description 38
- 229910052739 hydrogen Inorganic materials 0.000 claims description 38
- 238000012545 processing Methods 0.000 claims description 29
- 239000002253 acid Substances 0.000 claims description 14
- 150000007513 acids Chemical class 0.000 claims description 9
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 6
- 239000000446 fuel Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 5
- 239000011707 mineral Substances 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 239000000314 lubricant Substances 0.000 claims description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 87
- 235000005985 organic acids Nutrition 0.000 description 64
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 59
- 150000003839 salts Chemical class 0.000 description 54
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 44
- 229910052757 nitrogen Inorganic materials 0.000 description 44
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 34
- 238000009835 boiling Methods 0.000 description 34
- 229930195733 hydrocarbon Natural products 0.000 description 33
- 150000002430 hydrocarbons Chemical class 0.000 description 33
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 32
- 229910052750 molybdenum Inorganic materials 0.000 description 31
- 239000011733 molybdenum Substances 0.000 description 31
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 28
- 230000008569 process Effects 0.000 description 26
- 238000000926 separation method Methods 0.000 description 26
- 229910052783 alkali metal Inorganic materials 0.000 description 25
- 150000001340 alkali metals Chemical class 0.000 description 24
- 239000007789 gas Substances 0.000 description 23
- 238000011144 upstream manufacturing Methods 0.000 description 23
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 21
- 239000001301 oxygen Substances 0.000 description 21
- 229910052760 oxygen Inorganic materials 0.000 description 21
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 20
- 150000001342 alkaline earth metals Chemical class 0.000 description 20
- 239000011593 sulfur Substances 0.000 description 20
- 229910052717 sulfur Inorganic materials 0.000 description 20
- 229910052759 nickel Inorganic materials 0.000 description 19
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 18
- -1 for example Substances 0.000 description 18
- 229910052698 phosphorus Inorganic materials 0.000 description 18
- 239000011574 phosphorus Substances 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 239000008186 active pharmaceutical agent Substances 0.000 description 17
- 230000005484 gravity Effects 0.000 description 17
- 239000000377 silicon dioxide Substances 0.000 description 17
- 125000005842 heteroatom Chemical group 0.000 description 16
- 238000002156 mixing Methods 0.000 description 16
- 238000002360 preparation method Methods 0.000 description 16
- 229910052720 vanadium Inorganic materials 0.000 description 15
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 15
- 229910052799 carbon Inorganic materials 0.000 description 14
- 238000005470 impregnation Methods 0.000 description 14
- 239000002002 slurry Substances 0.000 description 14
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 13
- 229910010271 silicon carbide Inorganic materials 0.000 description 13
- 229910052742 iron Inorganic materials 0.000 description 12
- 229910001868 water Inorganic materials 0.000 description 12
- 239000011230 binding agent Substances 0.000 description 11
- 230000008859 change Effects 0.000 description 11
- 239000010941 cobalt Substances 0.000 description 11
- 229910017052 cobalt Inorganic materials 0.000 description 11
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 11
- 150000004831 organic oxygen compounds Chemical class 0.000 description 11
- 239000012159 carrier gas Substances 0.000 description 10
- 230000001276 controlling effect Effects 0.000 description 10
- 230000015556 catabolic process Effects 0.000 description 9
- 230000007797 corrosion Effects 0.000 description 9
- 238000005260 corrosion Methods 0.000 description 9
- 238000006731 degradation reaction Methods 0.000 description 9
- 230000009467 reduction Effects 0.000 description 9
- 239000010457 zeolite Substances 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 7
- 150000001735 carboxylic acids Chemical class 0.000 description 7
- 239000012018 catalyst precursor Substances 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 7
- 239000008367 deionised water Substances 0.000 description 6
- 229910021641 deionized water Inorganic materials 0.000 description 6
- 150000002736 metal compounds Chemical class 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 6
- 229910052721 tungsten Inorganic materials 0.000 description 6
- 239000010937 tungsten Substances 0.000 description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 5
- 238000002441 X-ray diffraction Methods 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 5
- 239000011651 chromium Substances 0.000 description 5
- 239000000356 contaminant Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 238000005755 formation reaction Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229910017604 nitric acid Inorganic materials 0.000 description 5
- 239000000758 substrate Substances 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 229910052785 arsenic Inorganic materials 0.000 description 4
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 239000000571 coke Substances 0.000 description 4
- 230000000875 corresponding effect Effects 0.000 description 4
- 230000007423 decrease Effects 0.000 description 4
- 239000003085 diluting agent Substances 0.000 description 4
- 238000005189 flocculation Methods 0.000 description 4
- 230000016615 flocculation Effects 0.000 description 4
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 239000011591 potassium Substances 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 150000003751 zinc Chemical class 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 238000013019 agitation Methods 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000003292 diminished effect Effects 0.000 description 3
- 238000004821 distillation Methods 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000002203 pretreatment Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- 229910001928 zirconium oxide Inorganic materials 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- YZCKVEUIGOORGS-UHFFFAOYSA-N Hydrogen atom Chemical compound [H] YZCKVEUIGOORGS-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229910021398 atomic carbon Inorganic materials 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004939 coking Methods 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 238000011033 desalting Methods 0.000 description 2
- 238000006477 desulfuration reaction Methods 0.000 description 2
- 230000023556 desulfurization Effects 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000012634 fragment Substances 0.000 description 2
- 239000008246 gaseous mixture Substances 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 239000012685 metal catalyst precursor Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 2
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 2
- FBUKVWPVBMHYJY-UHFFFAOYSA-N noncarboxylic acid Natural products CCCCCCCCC(O)=O FBUKVWPVBMHYJY-UHFFFAOYSA-N 0.000 description 2
- 238000001935 peptisation Methods 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 238000007670 refining Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 238000005987 sulfurization reaction Methods 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 150000003573 thiols Chemical class 0.000 description 2
- ZNOKGRXACCSDPY-UHFFFAOYSA-N tungsten trioxide Chemical compound O=[W](=O)=O ZNOKGRXACCSDPY-UHFFFAOYSA-N 0.000 description 2
- 238000005292 vacuum distillation Methods 0.000 description 2
- 239000011800 void material Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- YASYEJJMZJALEJ-UHFFFAOYSA-N Citric acid monohydrate Chemical compound O.OC(=O)CC(O)(C(O)=O)CC(O)=O YASYEJJMZJALEJ-UHFFFAOYSA-N 0.000 description 1
- 229910021503 Cobalt(II) hydroxide Inorganic materials 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 241000158500 Platanus racemosa Species 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 241001164238 Zulia Species 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000003868 ammonium compounds Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000001201 calcium disodium ethylene diamine tetra-acetate Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229960004106 citric acid Drugs 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 229960002303 citric acid monohydrate Drugs 0.000 description 1
- 229910021446 cobalt carbonate Inorganic materials 0.000 description 1
- 229910000428 cobalt oxide Inorganic materials 0.000 description 1
- ZOTKGJBKKKVBJZ-UHFFFAOYSA-L cobalt(2+);carbonate Chemical compound [Co+2].[O-]C([O-])=O ZOTKGJBKKKVBJZ-UHFFFAOYSA-L 0.000 description 1
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(ii) oxide Chemical compound [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000010779 crude oil Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000011066 ex-situ storage Methods 0.000 description 1
- 229910001657 ferrierite group Inorganic materials 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000004949 mass spectrometry Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 229910052976 metal sulfide Inorganic materials 0.000 description 1
- CZDSWLXAULJYPZ-UHFFFAOYSA-J molybdenum(4+);dicarbonate Chemical compound [Mo+4].[O-]C([O-])=O.[O-]C([O-])=O CZDSWLXAULJYPZ-UHFFFAOYSA-J 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 125000005608 naphthenic acid group Chemical group 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 229910000008 nickel(II) carbonate Inorganic materials 0.000 description 1
- ZULUUIKRFGGGTL-UHFFFAOYSA-L nickel(ii) carbonate Chemical compound [Ni+2].[O-]C([O-])=O ZULUUIKRFGGGTL-UHFFFAOYSA-L 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 229910017464 nitrogen compound Inorganic materials 0.000 description 1
- 150000002830 nitrogen compounds Chemical class 0.000 description 1
- 239000004058 oil shale Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 125000001477 organic nitrogen group Chemical group 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 229910052762 osmium Inorganic materials 0.000 description 1
- SYQBFIAQOQZEGI-UHFFFAOYSA-N osmium atom Chemical compound [Os] SYQBFIAQOQZEGI-UHFFFAOYSA-N 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 238000002459 porosimetry Methods 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- WUAPFZMCVAUBPE-UHFFFAOYSA-N rhenium atom Chemical compound [Re] WUAPFZMCVAUBPE-UHFFFAOYSA-N 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 150000003464 sulfur compounds Chemical class 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229910052713 technetium Inorganic materials 0.000 description 1
- GKLVYJBZJHMRIY-UHFFFAOYSA-N technetium atom Chemical compound [Tc] GKLVYJBZJHMRIY-UHFFFAOYSA-N 0.000 description 1
- UUUGYDOQQLOJQA-UHFFFAOYSA-L vanadyl sulfate Chemical compound [V+2]=O.[O-]S([O-])(=O)=O UUUGYDOQQLOJQA-UHFFFAOYSA-L 0.000 description 1
- 229910000352 vanadyl sulfate Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
- B01J21/04—Alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/12—Silica and alumina
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/882—Molybdenum and cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/883—Molybdenum and nickel
-
- B01J35/60—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0213—Preparation of the impregnating solution
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
- C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/02—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used
- C10G49/04—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 characterised by the catalyst used containing nickel, cobalt, chromium, molybdenum, or tungsten metals, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/04—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including only refining steps
-
- B01J35/647—
-
- B01J35/66—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0203—Impregnation the impregnation liquid containing organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/20—Sulfiding
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1033—Oil well production fluids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1074—Vacuum distillates
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1077—Vacuum residues
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/10—Lubricating oil
Definitions
- Disadvantaged crudes may include acidic components that contribute to the total acid number ("TAN") of the crude feed.
- TAN total acid number
- Disadvantaged crudes with a relatively high TAN may contribute to corrosion of metal components during transporting and/or processing of the disadvantaged crudes.
- Removal of acidic components from disadvantaged crudes may involve chemically neutralizing acidic components with various bases.
- corrosion-resistant metals may be used in transportation equipment and/or processing equipment. The use of corrosion-resistant metal often involves significant expense, and thus, the use of corrosion-resistant metal in existing equipment may not be desirable.
- Another method to inhibit corrosion may involve addition of corrosion inhibitors to disadvantaged crudes before transporting and/or processing of the disadvantaged crudes. The use of corrosion inhibitors may negatively affect equipment used to process the crudes and/or the quality of products produced from the crudes.
- Disadvantaged crudes often contain relatively high levels of residue. Disadvantaged crudes having high levels of residue tend to be difficult and expensive to transport and/or process using conventional facilities. Disadvantaged crudes often contain organically bound heteroatoms (for example, sulfur, oxygen, and nitrogen). Organically bound heteroatoms may, in some situations, have an adverse effect on catalysts used to process disadvantaged crudes. Disadvantaged crades may include relatively high amounts of metal contaminants, for example, nickel, vanadium, and/or iron. During processing of such crudes, metal contaminants and/or compounds of metal contaminants, may deposit on a surface of the catalyst or in the void volume of the catalyst. Such deposits may cause a decline in the activity of the catalyst.
- Disadvantaged crudes may have components that contribute coke and/or to thermal degradation of the disadvantaged crude.
- the coke and/or thermally degraded components may form and/or deposit on catalyst surfaces at a rapid rate during processing of disadvantaged crudes. It may be costly to regenerate the catalytic activity of a catalyst contaminated with coke and/or thermally degraded crude. Additionally, high temperatures used during regeneration of a catalyst may also diminish the activity of the catalyst and/or cause the catalyst to deteriorate.
- Organic oxygen compounds when heated during processing, may form higher oxidation compounds (for example, ketones and/or acids formed by oxidation of alcohols, and/or acids formed by oxidation of ethers) that are difficult to remove from the treated crude and/or may corrode/contaminate equipment during processing and cause plugging in transportation lines.
- Disadvantaged crudes may include hydrogen deficient hydrocarbons. When processing hydrogen deficient hydrocarbons, consistent quantities of hydrogen generally need to be added, particularly if unsaturated fragments resulting from cracking processes are produced. Hydrogenation during processing, which typically involves the use of an active hydrogenation catalyst, may be needed to inhibit unsaturated fragments from forming coke. Hydrogen is costly to produce and/or costly to transport to treatment facilities.
- the invention provides a method of producing a crude product, comprising: contacting a crude feed with one or more catalysts to produce a total product that includes the crude product, wherein the crude product is a liquid mixture at 25 0 C and 0.101 MPa; the crude feed has a micro-carbon residue ("MCR") content of at least 0.0001 grams per gram of crude feed; and at least one of the catalysts is a Column 6 metal catalyst that comprises: one or more metals from Column 6 of the Periodic Table and/or one or more compounds of one or more metals from Column 6 of the Periodic Table; a pore size distribution with a median pore diameter of greater than 110 A; and a pore volume in which pores having a pore diameter of at least 350 A provide at most 10% of the pore volume, wherein pore volume and pore diameter are as determined by ASTM Method D4282; and controlling contacting conditions such that the crude product has a MCR content of at most 90% of the MCR content of the crude feed, wherein MCR content is as determined
- Crude product having reduced content of metals in metal salts of organic acids relative to the content of metals in metal salts of organic acids of the crude feed is produced by contacting the crude feed with the catalyst that includes Columns 5-10 metal(s) and theta alumina. Crude product having reduced MCR content relative to the MCR content of the crude feed is produced by contacting the crude feed with the bulk metal catalyst.
- the crude product has, per gram of crude product, from about 1 x 10 "7 grams to about 5 x 10 "5 grams, about 5 x 10 "7 grams to about 1 x 10 "5 grams, or about 1 x 10 "6 grams to about 5 x 10 "6 grams of alkali metal and alkaline-earth metal in metal salts of organic acids.
- API gravity of the crude product produced from contact of the crude feed with catalyst, at the contacting conditions is about 70% to about 130%, about 80% to about 120%, about 90% to about 110%, or about 100% to about 130% of the API gravity of the crude feed.
- API gravity of the crude product is from about 14 to about 40, about 15 to about 30, or about 16 to about 25.
- the crude product has a viscosity of at most 90%, at most
- the crude product has a total heteroatoms content of at most 90%, at most 50%, at most 30%, at most 10%, or at most 5% of the total heteroatoms content of the crude feed. In certain embodiments, the crude product has a total heteroatoms content of at least 1%, at least 30%, at least 80%, or at least 99% of the total heteroatoms content of the crude feed.
- the sulfur content of the crude product may be at most 90%, at most 50%, at most 30%, at most 10%, or at most 5% of the sulfur content of the crude feed. In certain embodiments, the crude product has a sulfur content of at least 1%, at least 30%, at least 80%, or at least 99% of the sulfur content of the crude feed.
- the crude product in certain embodiments, has an oxygen content of at most 90%, at most 80%, at most 70%, or at most 50% of the oxygen content of the crude feed, and TAN of the crude product is at most 90%, at most 70%, at most 50%, at most 30% or at most 40% of the TAN of the crude feed, hi certain embodiments, the oxygen content of the crude product may be at least 1%, at least 30%, at least 80%, or at least 99% of the oxygen content of the crude feed, and the crude product has a TAN of at least 1%, at least 30%, at least 80%, or at least 99% of the TAN of the crude feed.
- the crude product has a residue content of at most 90%, at most 70%, at most 50%, at most 30%, or at most 10% of the residue content of the crude feed. In certain embodiments, the crude product has a residue content of about 70% to about 130%, about 80% to about 120%, or about 90% to about 110% of the residue content of the crude feed.
- the crude product may have, per gram of crude product, a residue content in a range from about 0.00001 grams to about 0.8 grams, about 0.0001 grams to about 0.5 grams, about 0.0005 grams to about 0.4 grams, about 0.001 grams to about 0.3 grams, about 0.005 grams to about 0.2 grams, or about 0.01 grams to about 0.1 grams.
- the C 5 asphaltenes content is at most 90%, at most 80%, at most 70%, at most 50%, at most 30%, or at most 10% of the C 5 asphaltenes content of the crude feed. In certain embodiments, the C 5 asphaltenes content of the crude product is at least 10%, at least 60%, or at least 70% of the C 5 asphaltenes content of the crude feed.
- the crude product may have a C 5 asphaltenes content in a range from about 0.1% to about 75%, from about 0.5% to about 45%, from about 1% to about 25%, or from about 2% to about 9% of the C 5 asphaltenes content of the crude feed.
- the crude product has, in some embodiments, from about 0.0001 grams to about 0.1 grams, from about 0.005 grams to about 0.08 grams, or from about 0.01 grams to about 0.05 grams of C 5 asphaltenes per gram of crude product.
- the catalyst includes a combination of Column 6 metal(s) with one or more metals from Columns 7-10.
- the catalyst may have, per gram of catalyst, a total Column 7-10 metal(s) content in a range from about 0.0001 grams to about 0.1 grams, from about 0.001 grams to about 0.05 grams, or from about 0.01 grams to about 0.03 grams, m certain embodiments, the catalyst includes, per gram of catalyst, from about 0.01 grams to about 0.15 grams of molybdenum and from about 0.001 grams to about 0.05 grams of nickel.
- the catalyst in some embodiments, also includes from about 0.001 grams to about 0.05 grams of iron per gram of catalyst.
- amines include, but are not limited to, alkanolamines, ammonia, alkyl amines, aromatic amines, and substituted ammonium compounds.
- Organic acids include, but are not limited to, citric acid, tartaric acid, oxalic acid, malonic acid, malic acid, or mixtures thereof.
- the support may be combined with a metal solution having a pH of up to about 3.
- the pH of the metal solution may range from about 1 to about 3, or from about 1.5 to about 2.5. Controlling the pH of the metal solution may facilitate dispersion of metals into the support.
- the catalyst may be heat-treated in the presence of air at temperatures in a range from about 35 °C to about 500 °C for a period of time in a range from 1 hour to about 3 hours to remove a majority of the volatile components without substantially converting the Columns 5-10 metal(s) to metal oxide(s).
- Catalysts prepared by such a method are generally referred to as "uncalcined" catalysts.
- the active metals maybe substantially dispersed on the support. Preparations of such catalysts are described in U.S. Patent Nos. 6,218,333 to Gabrielov et al. and 6,290,841 to Gabrielov et al.
- An amount of alkali compound maybe at least 0.5 moles, at least 0.7 moles, at least 0.8 moles, at least, 0.9 moles or at most 2 mole per mole of Columns 6-10 metal(s), based on the oxide form of the Columns 6-10 metal(s).
- the binder may be silica, alumina, silica/alumina, titanium oxide, zirconium oxide, or mixtures thereof.
- the Columns 6-10 metal/binder slurry may be held at ambient and/or at the slurry temperature for a period of time (for example, at least 10 minutes, at least 30 minutes, or at least 240 minutes) and then cooled, if necessary.
- the second catalyst support has, per gram of support, at least 0.9 grams of gamma alumina.
- the second catalyst is generally capable of: removing at least a portion of the components from the crude feed that contribute to thermal degradation as measured by MCR; removing at least a portion of organic nitrogen containing compounds; and removing at least a portion of the C 5 asphaltenes from the crude feed.
- the second catalyst in some embodiments, also removes at least a portion of the residue, removes at least a portion of the Ni/Fe/V, removes at least a portion of the components that contribute to high viscosities, and/or removes at least a portion of the components that contribute to low API gravity.
- the fourth catalyst(s) may have a Column 6 metal(s) content in a range from about 0.0001 grams to about 0.1 grams, about 0.005 grams to about 0.05 grams, or about 0.001 grams to about 0.01 grams and a Column 10 metal(s) content in a range from about 0.0001 grams to about 0.05 grams, about 0.005 grams to about 0.03 grams, or about 0.001 grams to about 0.01 grams per gram of fourth catalyst(s).
- Loss on ignition was performed by heating the extrudates to 540 0 C for 15 minutes to 50 minutes, and then determining the relative amount of weight lost by the extrudates.
- the extrudates were further heat-treated at 918 °C (1685 0 F) for 1 hour.
- the support had an average pore diameter of 125 A, a surface area of 281 m 2 /g, a pore volume of 0.875 cm 3 /g, and pores with a diameter of at least 350 A, which provided 0.9% of the total pore volume of the support.
- Example 1 demonstrates preparation of a support that has an average pore diameter of at least 90 A and pores having a pore diameter of at least 350 A provide at most 15% of the pore volume of the support.
- Example 3 Contact of a Crude Feed With Two Catalysts.
- a tubular reactor with a centrally positioned thermowell was equipped with thermocouples to measure temperatures throughout a catalyst bed.
- the catalyst bed was formed by filling the space between the thermowell and an inner wall of the reactor with catalysts and silicon carbide (20-grid, Stanford Materials; Aliso Viejo, CA).
- silicon carbide is believed to have low, if any, catalytic properties under the process conditions described herein.
- AU catalysts were mixed with silicon carbide in a volume ratio of 2 parts silicon carbide to 1 part catalyst before placing the mixture into the contacting zone portions of the reactor.
- the contacting zones were then heated to 204 °C over 2 hours and the crude feed (BC-10, Brazil) having the properties summarized in Table 2 was fed to the top of the reactor.
- the crude feed flowed through the preheat zone, top contacting zone, bottom contacting zone, and bottom support of the reactor.
- the crude feed was contacted with each of the catalysts in the presence of hydrogen gas. Contacting conditions were as follows: ratio of hydrogen gas to the crude feed provided to the reactor was 656 Nm 3 W (4000 SCFB), LHSV was 0.5 h "1 , and pressure was 13.8 MPa (2014.7 psi).
- the crude product had a nitrogen content of 0.0047 grams, a MCR content of 0.072 grams and a C 5 asphaltenes content of 0.05 grams, per gram of crude product.
- the crude product also had 0.5 wtppm of calcium, 1.5 wtppm of potassium, and 0.6 wtppm of sodium.
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2008506576A JP2008536003A (en) | 2005-04-11 | 2006-04-07 | Method and catalyst for producing crude product with low MCR content |
CA2604012A CA2604012C (en) | 2005-04-11 | 2006-04-07 | Method and catalyst for producing a crude product having a reduced mcr content |
BRPI0610670A BRPI0610670B1 (en) | 2005-04-11 | 2006-04-07 | method for producing a crude product, catalyst for producing a crude product, and method for producing a catalyst |
CN200680014647.3A CN101166808B (en) | 2005-04-11 | 2006-04-07 | Method and catalyst for producing a crude product having a reduced MCR content |
EP06740811A EP1874897A1 (en) | 2005-04-11 | 2006-04-07 | Method and catalyst for producing a crude product having a reduced mcr content |
NO20075770A NO20075770L (en) | 2005-04-11 | 2007-11-09 | Process and catalyst for the preparation of a crude oil product with a reduced content of MCR |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US67013705P | 2005-04-11 | 2005-04-11 | |
US60/670,137 | 2005-04-11 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2006110660A1 true WO2006110660A1 (en) | 2006-10-19 |
Family
ID=36636649
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2006/013328 WO2006110660A1 (en) | 2005-04-11 | 2006-04-07 | Method and catalyst for producing a crude product having a reduced mcr content |
Country Status (10)
Country | Link |
---|---|
US (2) | US7918992B2 (en) |
EP (1) | EP1874897A1 (en) |
JP (2) | JP2008536003A (en) |
CN (1) | CN101166808B (en) |
BR (1) | BRPI0610670B1 (en) |
CA (1) | CA2604012C (en) |
NL (1) | NL2000050C2 (en) |
NO (1) | NO20075770L (en) |
RU (1) | RU2424275C2 (en) |
WO (1) | WO2006110660A1 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009135227A2 (en) * | 2008-04-10 | 2009-11-05 | Shell Oil Company | Catalysts, preparation of such catalysts, methods of using such catalysts, products obtained in such methods and uses of products obtained |
US8734634B2 (en) | 2008-04-10 | 2014-05-27 | Shell Oil Company | Method for producing a crude product, method for preparing a diluted hydrocarbon composition, crude products, diluents and uses of such crude products and diluents |
CN109999873A (en) * | 2019-03-07 | 2019-07-12 | 江苏大学 | A kind of preparation method and applications of boron nitride load molybdenum dioxide material |
Families Citing this family (50)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6923257B2 (en) | 2001-04-24 | 2005-08-02 | Shell Oil Company | In situ thermal processing of an oil shale formation to produce a condensate |
WO2003036039A1 (en) | 2001-10-24 | 2003-05-01 | Shell Internationale Research Maatschappij B.V. | In situ production of a blending agent from a hydrocarbon containing formation |
US7780844B2 (en) | 2003-12-19 | 2010-08-24 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
US20100098602A1 (en) | 2003-12-19 | 2010-04-22 | Opinder Kishan Bhan | Systems, methods, and catalysts for producing a crude product |
US7745369B2 (en) | 2003-12-19 | 2010-06-29 | Shell Oil Company | Method and catalyst for producing a crude product with minimal hydrogen uptake |
US7972499B2 (en) | 2004-09-10 | 2011-07-05 | Chevron U.S.A. Inc. | Process for recycling an active slurry catalyst composition in heavy oil upgrading |
US7678732B2 (en) | 2004-09-10 | 2010-03-16 | Chevron Usa Inc. | Highly active slurry catalyst composition |
BRPI0609416A2 (en) | 2005-04-11 | 2011-10-11 | Shell Int Research | method to produce a gross product |
US7575052B2 (en) | 2005-04-22 | 2009-08-18 | Shell Oil Company | In situ conversion process utilizing a closed loop heating system |
US8048292B2 (en) | 2005-12-16 | 2011-11-01 | Chevron U.S.A. Inc. | Systems and methods for producing a crude product |
US7931796B2 (en) | 2008-09-18 | 2011-04-26 | Chevron U.S.A. Inc. | Systems and methods for producing a crude product |
US7938954B2 (en) | 2005-12-16 | 2011-05-10 | Chevron U.S.A. Inc. | Systems and methods for producing a crude product |
US7431822B2 (en) | 2005-12-16 | 2008-10-07 | Chevron U.S.A. Inc. | Process for upgrading heavy oil using a reactor with a novel reactor separation system |
US7943036B2 (en) | 2009-07-21 | 2011-05-17 | Chevron U.S.A. Inc. | Systems and methods for producing a crude product |
US8435400B2 (en) | 2005-12-16 | 2013-05-07 | Chevron U.S.A. | Systems and methods for producing a crude product |
US8372266B2 (en) * | 2005-12-16 | 2013-02-12 | Chevron U.S.A. Inc. | Systems and methods for producing a crude product |
WO2007149622A2 (en) | 2006-04-21 | 2007-12-27 | Shell Oil Company | Sulfur barrier for use with in situ processes for treating formations |
US20080085225A1 (en) | 2006-10-06 | 2008-04-10 | Bhan Opinder K | Systems for treating a hydrocarbon feed |
RU2451170C2 (en) | 2006-10-20 | 2012-05-20 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | Process of incremental heating of hydrocarbon containing formation in chess-board order |
US8327681B2 (en) | 2007-04-20 | 2012-12-11 | Shell Oil Company | Wellbore manufacturing processes for in situ heat treatment processes |
EP3078726A1 (en) | 2007-05-03 | 2016-10-12 | Auterra, Inc. | Product containing monomer and polymers of titanyls and methods for making same |
AU2008312713B2 (en) | 2007-10-19 | 2012-06-14 | Shell Internationale Research Maatschappij B.V. | Systems, methods, and processes utilized for treating subsurface formations |
CN101434861B (en) * | 2007-11-15 | 2013-03-20 | 中国石油化工股份有限公司 | Preparation method of hydrogenation catalyst |
US9206359B2 (en) | 2008-03-26 | 2015-12-08 | Auterra, Inc. | Methods for upgrading of contaminated hydrocarbon streams |
US9061273B2 (en) | 2008-03-26 | 2015-06-23 | Auterra, Inc. | Sulfoxidation catalysts and methods and systems of using same |
US8298404B2 (en) | 2010-09-22 | 2012-10-30 | Auterra, Inc. | Reaction system and products therefrom |
US8894843B2 (en) | 2008-03-26 | 2014-11-25 | Auterra, Inc. | Methods for upgrading of contaminated hydrocarbon streams |
US8764973B2 (en) | 2008-03-26 | 2014-07-01 | Auterra, Inc. | Methods for upgrading of contaminated hydrocarbon streams |
US8236169B2 (en) | 2009-07-21 | 2012-08-07 | Chevron U.S.A. Inc | Systems and methods for producing a crude product |
US7935243B2 (en) | 2008-09-18 | 2011-05-03 | Chevron U.S.A. Inc. | Systems and methods for producing a crude product |
US7931797B2 (en) * | 2009-07-21 | 2011-04-26 | Chevron U.S.A. Inc. | Systems and methods for producing a crude product |
US7897035B2 (en) | 2008-09-18 | 2011-03-01 | Chevron U.S.A. Inc. | Systems and methods for producing a crude product |
US7897036B2 (en) | 2008-09-18 | 2011-03-01 | Chevron U.S.A. Inc. | Systems and methods for producing a crude product |
US8759242B2 (en) | 2009-07-21 | 2014-06-24 | Chevron U.S.A. Inc. | Hydroprocessing catalysts and methods for making thereof |
US9068132B2 (en) | 2009-07-21 | 2015-06-30 | Chevron U.S.A. Inc. | Hydroprocessing catalysts and methods for making thereof |
US8927448B2 (en) | 2009-07-21 | 2015-01-06 | Chevron U.S.A. Inc. | Hydroprocessing catalysts and methods for making thereof |
US9828557B2 (en) | 2010-09-22 | 2017-11-28 | Auterra, Inc. | Reaction system, methods and products therefrom |
US8802586B2 (en) | 2010-12-30 | 2014-08-12 | Chevron U.S.A. Inc. | Hydroprocessing catalysts and methods for making thereof |
FR2984761B1 (en) * | 2011-12-21 | 2014-12-26 | IFP Energies Nouvelles | PROCESS FOR THE PREPARATION OF A CATALYST BASED ON A GROUP VIII METAL PREPARED USING AT LEAST ONE ORGANIC ADDITIVE AND METHOD OF SELECTIVE HYDROGENATION USING SAID CATALYST |
US9321037B2 (en) | 2012-12-14 | 2016-04-26 | Chevron U.S.A., Inc. | Hydroprocessing co-catalyst compositions and methods of introduction thereof into hydroprocessing units |
US9687823B2 (en) | 2012-12-14 | 2017-06-27 | Chevron U.S.A. Inc. | Hydroprocessing co-catalyst compositions and methods of introduction thereof into hydroprocessing units |
US11440815B2 (en) | 2013-02-22 | 2022-09-13 | Anschutz Exploration Corporation | Method and system for removing hydrogen sulfide from sour oil and sour water |
CA2843041C (en) | 2013-02-22 | 2017-06-13 | Anschutz Exploration Corporation | Method and system for removing hydrogen sulfide from sour oil and sour water |
US9364773B2 (en) | 2013-02-22 | 2016-06-14 | Anschutz Exploration Corporation | Method and system for removing hydrogen sulfide from sour oil and sour water |
US9708196B2 (en) | 2013-02-22 | 2017-07-18 | Anschutz Exploration Corporation | Method and system for removing hydrogen sulfide from sour oil and sour water |
US10246647B2 (en) | 2015-03-26 | 2019-04-02 | Auterra, Inc. | Adsorbents and methods of use |
US10450516B2 (en) | 2016-03-08 | 2019-10-22 | Auterra, Inc. | Catalytic caustic desulfonylation |
US10604709B2 (en) | 2017-02-12 | 2020-03-31 | Magēmā Technology LLC | Multi-stage device and process for production of a low sulfur heavy marine fuel oil from distressed heavy fuel oil materials |
US20190233741A1 (en) | 2017-02-12 | 2019-08-01 | Magēmā Technology, LLC | Multi-Stage Process and Device for Reducing Environmental Contaminates in Heavy Marine Fuel Oil |
US11788017B2 (en) | 2017-02-12 | 2023-10-17 | Magëmã Technology LLC | Multi-stage process and device for reducing environmental contaminants in heavy marine fuel oil |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3928176A (en) * | 1974-04-01 | 1975-12-23 | Exxon Research Engineering Co | Heavy crude conversion |
US4191635A (en) * | 1977-12-21 | 1980-03-04 | Standard Oil Company (Indiana) | Process for the cracking of heavy hydrocarbon streams |
US4357263A (en) * | 1979-10-22 | 1982-11-02 | Mobil Oil Corporation | Catalyst for the upgrading of aromatic liquids |
US4447314A (en) * | 1982-05-05 | 1984-05-08 | Mobil Oil Corporation | Demetalation, desulfurization, and decarbonization of petroleum oils by hydrotreatment in a dual bed system prior to cracking |
US4588709A (en) * | 1983-12-19 | 1986-05-13 | Intevep, S.A. | Catalyst for removing sulfur and metal contaminants from heavy crudes and residues |
US4886594A (en) * | 1982-12-06 | 1989-12-12 | Amoco Corporation | Hydrotreating catalyst and process |
EP0525259A1 (en) * | 1988-05-13 | 1993-02-03 | Texaco Development Corporation | Catalyst composition and method for hydro-processing petroleum feedstocks |
US5215955A (en) * | 1991-10-02 | 1993-06-01 | Chevron Research And Technology Company | Resid catalyst with high metals capacity |
Family Cites Families (260)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1111580A (en) | 1914-02-09 | 1914-09-22 | Samuel M Herber | Oil distillation. |
GB496779A (en) | 1937-01-04 | 1938-12-06 | Bataafsche Petroleum | A process for removing naphthenic acids from mineral lubricating oils or lubricating oil fractions |
US2552431A (en) * | 1948-11-02 | 1951-05-08 | Janowski Edward | Welding electrode |
US2902429A (en) | 1955-06-17 | 1959-09-01 | California Research Corp | Demetallization of hydrocarbon fractions |
US2850435A (en) | 1956-02-06 | 1958-09-02 | Pure Oil Co | Method of removing high molecular weight naphthenic acids from hydrocarbon oils |
US2921023A (en) | 1957-05-14 | 1960-01-12 | Pure Oil Co | Removal of naphthenic acids by hydrogenation with a molybdenum oxidesilica alumina catalyst |
NL267291A (en) | 1959-05-14 | 1900-01-01 | ||
US3025231A (en) | 1959-06-03 | 1962-03-13 | Texaco Inc | Catalytic hydrogenation of heavy oils such as shale oil |
NL264945A (en) | 1960-05-23 | |||
US3080435A (en) | 1960-07-18 | 1963-03-05 | Shell Oil Co | Dehydrogenation process |
NL275200A (en) | 1961-07-31 | |||
NL285285A (en) | 1961-11-10 | |||
GB1115122A (en) | 1965-08-23 | 1968-05-29 | Universal Oil Prod Co | Hydrotreatment of alkyl aromatic hydrocarbons |
US3488716A (en) | 1967-10-03 | 1970-01-06 | Exxon Research Engineering Co | Process for the removal of naphthenic acids from petroleum distillate fractions |
US3553279A (en) | 1968-03-29 | 1971-01-05 | Texas Instruments Inc | Method of producing ethylene |
US3617501A (en) * | 1968-09-06 | 1971-11-02 | Exxon Research Engineering Co | Integrated process for refining whole crude oil |
US3558474A (en) | 1968-09-30 | 1971-01-26 | Universal Oil Prod Co | Slurry process for hydrorefining petroleum crude oil |
US3547585A (en) | 1968-11-26 | 1970-12-15 | Universal Oil Prod Co | Combination of a hydrocarbon conversion process with a waste water treating process |
US3679577A (en) | 1968-11-29 | 1972-07-25 | Shell Oil Co | Molten salt hydrofining process |
US3576737A (en) | 1969-03-25 | 1971-04-27 | Chevron Res | Vanadium removal from hydrocarbons |
US3663431A (en) | 1969-10-15 | 1972-05-16 | Union Oil Co | Two-phase hydrocarbon conversion system |
BE758565A (en) | 1969-11-18 | 1971-05-06 | Shell Int Research | PROCEDURE FOR THE CATALYTIC HYDROGENATING CONVERSION OF A RESIDUAL CARBON HYDROGEN OIL |
GB1232173A (en) | 1969-11-18 | 1971-05-19 | ||
US3696027A (en) | 1970-01-12 | 1972-10-03 | Chevron Res | Multi-stage desulfurization |
US3622495A (en) | 1970-01-22 | 1971-11-23 | Universal Oil Prod Co | Multiple-stage slurry processing for black oil conversion |
US3669027A (en) * | 1970-01-23 | 1972-06-13 | American Chain & Cable Co | Tow truck conveyor system |
US3716478A (en) | 1970-02-10 | 1973-02-13 | Agency Ind Science Techn | Hydrogenation treatment of hydrocarbon oil |
GB1310283A (en) | 1970-06-12 | 1973-03-14 | Shell Int Research | Process for hydrogenative cracking of carbonaceous material |
GB1364238A (en) | 1970-08-04 | 1974-08-21 | Topsoe H F A | Process for the hydrodesulphurisation of heavy hydrocarbon oils |
US3745109A (en) | 1970-10-01 | 1973-07-10 | North American Rockwell | Hydrocarbon conversion process |
US3712861A (en) | 1970-10-19 | 1973-01-23 | Mobil Oil Corp | Upgrading a hydrocarbon utilizing a catalyst of metal sulfides dispersed in alumina |
US3730876A (en) | 1970-12-18 | 1973-05-01 | A Sequeira | Production of naphthenic oils |
US3716479A (en) | 1970-12-23 | 1973-02-13 | Mobil Oil Corp | Demetalation of hydrocarbon charge stocks |
US3766054A (en) | 1970-12-23 | 1973-10-16 | Mobil Oil Corp | Demetalation of hydrocarbon charge stocks |
US3684688A (en) | 1971-01-21 | 1972-08-15 | Chevron Res | Heavy oil conversion |
US3677932A (en) | 1971-03-12 | 1972-07-18 | Shell Oil Co | Molten salt hydroconversion process |
US3812028A (en) | 1971-05-18 | 1974-05-21 | Standard Oil Co | Hydrotreatment of fossil fuels |
US3786138A (en) | 1971-08-16 | 1974-01-15 | Atlantic Richfield Co | Hydrogen generation |
US3847797A (en) | 1971-10-05 | 1974-11-12 | Exxon Research Engineering Co | Visbreaking a heavy hydrocarbon feedstock in a regenerable molten medium |
JPS5319071B2 (en) | 1971-10-18 | 1978-06-19 | ||
US3901792A (en) | 1972-05-22 | 1975-08-26 | Hydrocarbon Research Inc | Multi-zone method for demetallizing and desulfurizing crude oil or atmospheric residual oil |
US3841981A (en) | 1972-12-29 | 1974-10-15 | Hydrocarbon Research Inc | Hydrogenation of tar sand bitumen |
JPS5139645B2 (en) | 1972-12-30 | 1976-10-29 | ||
US3876532A (en) | 1973-02-27 | 1975-04-08 | Gulf Research Development Co | Method for reducing the total acid number of a middle distillate oil |
US3948759A (en) | 1973-03-28 | 1976-04-06 | Exxon Research And Engineering Company | Visbreaking a heavy hydrocarbon feedstock in a regenerable molten medium in the presence of hydrogen |
US3902991A (en) | 1973-04-27 | 1975-09-02 | Chevron Res | Hydrodesulfurization process for the production of low-sulfur hydrocarbon mixture |
US3960712A (en) | 1973-04-30 | 1976-06-01 | Universal Oil Products Company | Hydrodesulfurization of asphaltene-containing black oil with a gamma-alumina composite catalyst of specified particle density |
US3846288A (en) | 1973-07-05 | 1974-11-05 | Gulf Research Development Co | Acid number reduction of hydrocarbon fractions using a solid catalyst and methanol |
US3891541A (en) | 1973-08-29 | 1975-06-24 | Mobil Oil Corp | Process for demetalizing and desulfurizing residual oil with hydrogen and alumina-supported catalyst |
US3931052A (en) | 1973-08-29 | 1976-01-06 | Mobil Oil Corporation | Alumina-supported catalyst for residua demetalation and desulfurization |
US3876523A (en) | 1973-08-29 | 1975-04-08 | Mobil Oil Corp | Catalyst for residua demetalation and desulfurization |
US3920538A (en) | 1973-11-30 | 1975-11-18 | Shell Oil Co | Demetallation with nickel-vanadium on silica in a hydrocarbon conversion process |
US3887455A (en) | 1974-03-25 | 1975-06-03 | Exxon Research Engineering Co | Ebullating bed process for hydrotreatment of heavy crudes and residua |
US3960706A (en) | 1974-05-31 | 1976-06-01 | Standard Oil Company | Process for upgrading a hydrocarbon fraction |
US3960708A (en) | 1974-05-31 | 1976-06-01 | Standard Oil Company | Process for upgrading a hydrocarbon fraction |
US3923635A (en) | 1974-06-17 | 1975-12-02 | Exxon Research Engineering Co | Catalytic upgrading of heavy hydrocarbons |
US3954620A (en) * | 1974-10-25 | 1976-05-04 | Hydrotechnic Corporation | Filtration and backwashing apparatus for use with a water filtration system |
US4016067A (en) | 1975-02-21 | 1977-04-05 | Mobil Oil Corporation | Process for demetalation and desulfurization of petroleum oils |
JPS51122105A (en) | 1975-04-18 | 1976-10-26 | Toa Nenryo Kogyo Kk | Process for hydrofining of hydrocarbon oil |
US4062757A (en) | 1975-07-18 | 1977-12-13 | Gulf Research & Development Company | Residue thermal cracking process in a packed bed reactor |
US4196102A (en) | 1975-12-09 | 1980-04-01 | Chiyoda Chemical Engineering & Construction Co., Ltd. | Catalysts for demetallization treatment of _hydrocarbons supported on sepiolite |
GB1561629A (en) | 1975-12-10 | 1980-02-27 | Ici Ltd | Catalyst |
US4048060A (en) * | 1975-12-29 | 1977-09-13 | Exxon Research And Engineering Company | Two-stage hydrodesulfurization of oil utilizing a narrow pore size distribution catalyst |
US4051015A (en) | 1976-06-11 | 1977-09-27 | Exxon Research & Engineering Co. | Hydroconversion of heavy hydrocarbons using copper chloride catalyst |
US4067799A (en) | 1976-07-02 | 1978-01-10 | Exxon Research And Engineering Company | Hydroconversion process |
US4115324A (en) | 1977-06-10 | 1978-09-19 | Nippon Mining Co., Ltd | Catalyst for treating heavy oils |
US4127470A (en) | 1977-08-01 | 1978-11-28 | Exxon Research & Engineering Company | Hydroconversion with group IA, IIA metal compounds |
US4119528A (en) | 1977-08-01 | 1978-10-10 | Exxon Research & Engineering Co. | Hydroconversion of residua with potassium sulfide |
US4271042A (en) | 1977-12-20 | 1981-06-02 | Mobil Oil Corporation | Process for demetalation and desulfurization of petroleum oils |
US4231858A (en) | 1978-06-15 | 1980-11-04 | Suntech, Inc. | Processing shale oil to jet fuel |
US4212729A (en) * | 1978-07-26 | 1980-07-15 | Standard Oil Company (Indiana) | Process for demetallation and desulfurization of heavy hydrocarbons |
US4297242A (en) | 1978-07-26 | 1981-10-27 | Standard Oil Company (Indiana) | Process for demetallation and desulfurization of heavy hydrocarbons |
JPS5579043A (en) | 1978-12-13 | 1980-06-14 | Chiyoda Chem Eng & Constr Co Ltd | Hydrogenation catalyst for heavy hydrocarbon oil |
JPS55102684A (en) | 1979-01-06 | 1980-08-06 | Mitsui Eng & Shipbuild Co Ltd | Thermal cracking of hydrocarbon and its device |
JPS55104920A (en) | 1979-01-30 | 1980-08-11 | Nippon Mining Co Ltd | Manufacture of lightened oil and hydrogen from heavy oil |
US4191653A (en) * | 1979-02-27 | 1980-03-04 | Hampton Quentin L | Self washing belt strainer |
US4446244A (en) | 1979-09-26 | 1984-05-01 | Chevron Research Company | Hydrocarbons hydroprocessing with imogolite catalyst |
US4358361A (en) | 1979-10-09 | 1982-11-09 | Mobil Oil Corporation | Demetalation and desulfurization of oil |
CA1121293A (en) | 1979-11-26 | 1982-04-06 | Jaroslav F. Kriz | Catalytic hydrotreating or hydrocracking of hydrocarbon oils |
JPS594182B2 (en) * | 1979-11-27 | 1984-01-28 | 千代田化工建設株式会社 | Catalyst for hydrotreating heavy hydrocarbon oil and method for producing the same |
JPS595011B2 (en) | 1979-11-27 | 1984-02-02 | 千代田化工建設株式会社 | Catalyst for hydrotreating heavy hydrocarbon oil and its production method |
JPS601056B2 (en) | 1980-02-19 | 1985-01-11 | 千代田化工建設株式会社 | Hydrotreatment of heavy hydrocarbon oils containing asphaltenes |
US4324645A (en) | 1980-05-06 | 1982-04-13 | Mobil Oil Corporation | Upgrading residual oil |
US4306964A (en) | 1980-09-16 | 1981-12-22 | Mobil Oil Corporation | Multi-stage process for demetalation and desulfurization of petroleum oils |
FI803329L (en) | 1980-10-23 | 1982-04-24 | Farmos Oy | VAEXTSUBSTRATBAEDD |
JPS5830334A (en) * | 1980-12-24 | 1983-02-22 | アメリカン・サイアナミド・カンパニ− | Modified catalyst for hydrogenation of heavy hydrocarbon |
US4411824A (en) | 1981-05-12 | 1983-10-25 | Chevron Research Company | Method of making a catalyst suitable for hydrometalation of hydrocarbonaceous feedstocks |
US4549957A (en) | 1981-06-17 | 1985-10-29 | Amoco Corporation | Hydrotreating catalyst and process |
US4456699A (en) | 1981-06-17 | 1984-06-26 | Standard Oil Company (Indiana) | Catalyst and support, and their methods of preparation |
US4591426A (en) | 1981-10-08 | 1986-05-27 | Intevep, S.A. | Process for hydroconversion and upgrading of heavy crudes of high metal and asphaltene content |
US4389301A (en) | 1981-10-22 | 1983-06-21 | Chevron Research Company | Two-step hydroprocessing of heavy hydrocarbonaceous oils |
US4376037A (en) | 1981-10-16 | 1983-03-08 | Chevron Research Company | Hydroprocessing of heavy hydrocarbonaceous oils |
US4427535A (en) | 1981-11-02 | 1984-01-24 | Hydrocarbon Research, Inc. | Selective operating conditions for high conversion of special petroleum feedstocks |
CA1209510A (en) | 1981-12-29 | 1986-08-12 | Chevron Research And Technology Company | Process for hydrodemetallation of hydrocarbon oils such as petroleum residua |
JPS58219293A (en) | 1982-06-15 | 1983-12-20 | Chiyoda Chem Eng & Constr Co Ltd | Hydrocracking of heavy oil |
FR2528721B1 (en) | 1982-06-17 | 1986-02-28 | Pro Catalyse Ste Fse Prod Cata | SUPPORTED CATALYST HAVING INCREASED RESISTANCE TO POISONS AND ITS USE IN PARTICULAR FOR THE HYDROTREATMENT OF OIL FRACTIONS CONTAINING METALS |
US4437980A (en) | 1982-07-30 | 1984-03-20 | Rockwell International Corporation | Molten salt hydrotreatment process |
US4405441A (en) | 1982-09-30 | 1983-09-20 | Shell Oil Company | Process for the preparation of hydrocarbon oil distillates |
US4450068A (en) | 1982-12-20 | 1984-05-22 | Phillips Petroleum Company | Demetallization of hydrocarbon containing feed streams |
US4460707A (en) | 1982-12-28 | 1984-07-17 | Union Oil Company Of California | Hydroprocessing catalyst and method for preparing it |
FR2538813A1 (en) | 1982-12-31 | 1984-07-06 | Inst Francais Du Petrole | HYDROTREATMENT PROCESS CONVERTING IN AT LEAST TWO STEPS A HEAVY FRACTION OF HYDROCARBONS CONTAINING SULFUR IMPURITIES AND METAL IMPURITIES |
JPS59132945A (en) | 1983-01-21 | 1984-07-31 | Shokubai Kasei Kogyo Kk | Hydro-demetalation catalyst and use thereof |
US4592827A (en) | 1983-01-28 | 1986-06-03 | Intevep, S.A. | Hydroconversion of heavy crudes with high metal and asphaltene content in the presence of soluble metallic compounds and water |
US4525472A (en) | 1983-02-23 | 1985-06-25 | Intevep, S.A. | Process for catalyst preparation for the hydrodemetallization of heavy crudes and residues |
US4473462A (en) | 1983-04-20 | 1984-09-25 | Chemroll Enterprises Inc | Treatment of petroleum and petroleum residues |
FR2546175B1 (en) | 1983-05-20 | 1989-12-22 | Intevep Sa | PROCESS FOR PRODUCING A HYDRODEMETALLATION CATALYST OF HEAVY CRUDE AND RESIDUES |
US4498979A (en) | 1983-09-12 | 1985-02-12 | Exxon Research & Engineering Co. | Hydrodesulfurization process with conversion of heavy hydrocarbons utilizing a catalyst containing a group IIA metal component |
US4587012A (en) | 1983-10-31 | 1986-05-06 | Chevron Research Company | Process for upgrading hydrocarbonaceous feedstocks |
US4514279A (en) * | 1983-11-25 | 1985-04-30 | Standard Oil Company (Indiana) | Solid hydrocarbon liquefaction with a catalyst having chromium and molybdenum |
US4520128A (en) | 1983-12-19 | 1985-05-28 | Intevep, S.A. | Catalyst having high metal retention capacity and good stability for use in the demetallization of heavy crudes and method of preparation of same |
US4572778A (en) | 1984-01-19 | 1986-02-25 | Union Oil Company Of California | Hydroprocessing with a large pore catalyst |
US4530757A (en) | 1984-03-29 | 1985-07-23 | Mobil Oil Corporation | Process for upgrading heavy crude oils |
US4560468A (en) | 1984-04-05 | 1985-12-24 | Phillips Petroleum Company | Hydrofining process for hydrocarbon containing feed streams |
CA1258439A (en) | 1984-04-16 | 1989-08-15 | Karl-Heinz W. Robschlager | Process for the catalytic conversion of heavy hydrocarbon oils |
JPS60227833A (en) | 1984-04-27 | 1985-11-13 | Nippon Oil Co Ltd | Hydrogenation treatment catalyst of heavy hydrocarbon oil |
US4564439A (en) | 1984-06-29 | 1986-01-14 | Chevron Research Company | Two-stage, close-coupled thermal catalytic hydroconversion process |
US4844792A (en) | 1984-08-07 | 1989-07-04 | Union Oil Company Of California | Hydroprocessing with a specific pore sized catalyst containing non-hydrolyzable halogen |
GB2167430B (en) | 1984-11-22 | 1988-11-30 | Intevep Sa | Process for hydroconversion and upgrading of heavy crudes of high metal and asphaltene content |
US4581012A (en) * | 1984-12-05 | 1986-04-08 | I-Flow Corporation | Multilumen catheter set |
US5264183A (en) | 1984-12-14 | 1993-11-23 | Monsanto Company | Method and apparatus for carrying out catalyzed chemical reactions and for studying catalysis |
US4626412A (en) | 1984-12-14 | 1986-12-02 | Monsanto Company | Method and apparatus for carrying out catalyzed chemical reactions and for studying catalysts |
US4659454A (en) | 1984-12-21 | 1987-04-21 | Mobil Oil Corporation | Hydrocracking of heavy feeds plus light fractions with dispersed dual function catalyst |
US4600503A (en) | 1984-12-28 | 1986-07-15 | Mobil Oil Corporation | Process for hydrotreating residual petroleum oil |
US4665261A (en) | 1985-06-21 | 1987-05-12 | Atlantic Richfield Company | Hydrocarbon conversion process using a molten salt |
US5108581A (en) | 1985-09-09 | 1992-04-28 | Exxon Research And Engineering Company | Hydroconversion of heavy feeds by use of both supported and unsupported catalysts |
US4661265A (en) | 1985-09-30 | 1987-04-28 | Amoco Corporation | Catalyst deoiling process |
US4746419A (en) | 1985-12-20 | 1988-05-24 | Amoco Corporation | Process for the hydrodemetallation hydrodesulfuration and hydrocracking of a hydrocarbon feedstock |
US4729826A (en) | 1986-02-28 | 1988-03-08 | Union Oil Company Of California | Temperature controlled catalytic demetallization of hydrocarbons |
US4738884A (en) | 1986-03-03 | 1988-04-19 | Owens-Corning Fiberglas Corporation | Asphalt adhesives superimposed on asphalt-based roofing sheet |
US4670134A (en) | 1986-05-02 | 1987-06-02 | Phillips Petroleum Company | Catalytic hydrofining of oil |
DE3623430A1 (en) | 1986-07-11 | 1988-01-28 | Veba Oel Entwicklungs Gmbh | METHOD FOR HYDROGENATING TREATMENT WITH CHLORBIPHENYLENE AND THE LIKE CONTAMINATED MINERAL OILS |
US4830736A (en) | 1986-07-28 | 1989-05-16 | Chevron Research Company | Graded catalyst system for removal of calcium and sodium from a hydrocarbon feedstock |
US5166118A (en) | 1986-10-08 | 1992-11-24 | Veba Oel Technologie Gmbh | Catalyst for the hydrogenation of hydrocarbon material |
DE3634275A1 (en) | 1986-10-08 | 1988-04-28 | Veba Oel Entwicklungs Gmbh | METHOD FOR HYDROGENATING CONVERSION OF HEAVY AND RESIDUAL OILS |
US4917789A (en) | 1987-02-03 | 1990-04-17 | Fina Technology, Inc. | Catalytic dewaxing process |
JPH0811184B2 (en) | 1987-02-06 | 1996-02-07 | 日本石油株式会社 | Hydroprocessing catalyst for heavy oil |
DE3710021A1 (en) | 1987-03-30 | 1988-10-20 | Veba Oel Entwicklungs Gmbh | METHOD FOR HYDROGENATING CONVERSION OF HEAVY AND RESIDUAL OILS |
DE3737370C1 (en) | 1987-11-04 | 1989-05-18 | Veba Oel Entwicklungs Gmbh | Process for the hydroconversion of heavy and residual soils, waste and waste allogols mixed with sewage sludge |
US4973218A (en) * | 1988-06-22 | 1990-11-27 | Wirtz Manufacturing Company, Inc. | Battery plate stacker |
US4954473A (en) | 1988-07-18 | 1990-09-04 | Uop | Method of preparing a catalyst for the hydroconversion of asphaltene-containing hydrocarbonaceous charge stocks |
JP2631712B2 (en) | 1988-08-18 | 1997-07-16 | コスモ石油株式会社 | Catalyst composition for hydrotreating heavy hydrocarbon oil and hydrotreating method using the same |
US4992157A (en) | 1988-08-29 | 1991-02-12 | Uop | Process for improving the color and color stability of hydrocarbon fraction |
US4937218A (en) * | 1988-09-06 | 1990-06-26 | Intevep, S.A. | Catalytic system for the hydroconversion of heavy oils |
US4976848A (en) | 1988-10-04 | 1990-12-11 | Chevron Research Company | Hydrodemetalation and hydrodesulfurization using a catalyst of specified macroporosity |
US5089463A (en) | 1988-10-04 | 1992-02-18 | Chevron Research And Technology Company | Hydrodemetalation and hydrodesulfurization catalyst of specified macroporosity |
EP0367021B1 (en) | 1988-10-19 | 1993-12-29 | Research Association For Petroleum Alternatives Development | Process for hydrogenation of heavy oil |
US4937221A (en) | 1989-06-09 | 1990-06-26 | Institute Of Gas Technology | Mixed-solid solution tri-metallic oxide/sulfide catalyst and process for its preparation |
US5124027A (en) | 1989-07-18 | 1992-06-23 | Amoco Corporation | Multi-stage process for deasphalting resid, removing catalyst fines from decanted oil and apparatus therefor |
US5124024A (en) | 1989-11-20 | 1992-06-23 | Nova Husky Research Corporation | Method for extending hydroconversion catalyst life |
US5916529A (en) | 1989-07-19 | 1999-06-29 | Chevron U.S.A. Inc | Multistage moving-bed hydroprocessing reactor with separate catalyst addition and withdrawal systems for each stage, and method for hydroprocessing a hydrocarbon feed stream |
US4988434A (en) | 1989-12-13 | 1991-01-29 | Exxon Research And Engineering Company | Removal of metallic contaminants from a hydrocarbonaceous liquid |
US4992163A (en) | 1989-12-13 | 1991-02-12 | Exxon Research And Engineering Company | Cat cracking feed preparation |
US5164078A (en) | 1989-12-28 | 1992-11-17 | Chevron Research And Technology Company | Process for removal of calcium from a hydrocarbon feedstock |
US5039489A (en) | 1990-04-17 | 1991-08-13 | Gleaves John T | Apparatus for catalyst analysis |
EP0460300A1 (en) | 1990-06-20 | 1991-12-11 | Akzo Nobel N.V. | Process for the preparation of a presulphided catalyst; Process for the preparation of a sulphided catalyst, and use of said catalyst |
US5089453A (en) | 1990-06-25 | 1992-02-18 | Chevron Research And Technology Company | Hydroconversion catalyst and method for making the catalyst |
US5053117A (en) | 1990-07-25 | 1991-10-01 | Mobil Oil Corporation | Catalytic dewaxing |
US5851381A (en) | 1990-12-07 | 1998-12-22 | Idemitsu Kosan Co., Ltd. | Method of refining crude oil |
US5200060A (en) | 1991-04-26 | 1993-04-06 | Amoco Corporation | Hydrotreating process using carbides and nitrides of group VIB metals |
US5374350A (en) | 1991-07-11 | 1994-12-20 | Mobil Oil Corporation | Process for treating heavy oil |
US5358634A (en) | 1991-07-11 | 1994-10-25 | Mobil Oil Corporation | Process for treating heavy oil |
US5215954A (en) * | 1991-07-30 | 1993-06-01 | Cri International, Inc. | Method of presulfurizing a hydrotreating, hydrocracking or tail gas treating catalyst |
US5171727A (en) | 1991-08-26 | 1992-12-15 | Uop | Method of preparing a catalyst for the hydroconversion of asphaltene-containing hydrocarbonaceous charge stocks |
US5474977A (en) | 1991-08-26 | 1995-12-12 | Uop | Catalyst for the hydroconversion of asphaltene-containing hydrocarbonaceous charge stocks |
US5210061A (en) | 1991-09-24 | 1993-05-11 | Union Oil Company Of California | Resid hydroprocessing catalyst |
JP3416177B2 (en) * | 1991-10-02 | 2003-06-16 | シェブロン リサーチ アンド テクノロジー カンパニー | Method for producing highly active resid catalyst |
JP2966985B2 (en) | 1991-10-09 | 1999-10-25 | 出光興産株式会社 | Catalytic hydrotreating method for heavy hydrocarbon oil |
US5320741A (en) | 1992-04-09 | 1994-06-14 | Stone & Webster Engineering Corporation | Combination process for the pretreatment and hydroconversion of heavy residual oils |
US5223472A (en) * | 1992-04-14 | 1993-06-29 | Union Oil Company Of California | Demetallation catalyst |
US5399259A (en) | 1992-04-20 | 1995-03-21 | Texaco Inc. | Hydroconversion process employing catalyst with specified pore size distribution |
US5827421A (en) | 1992-04-20 | 1998-10-27 | Texaco Inc | Hydroconversion process employing catalyst with specified pore size distribution and no added silica |
EP0569092A1 (en) | 1992-05-05 | 1993-11-10 | Shell Internationale Researchmaatschappij B.V. | Hydrotreating process |
US5322617A (en) | 1992-08-07 | 1994-06-21 | Her Majesty The Queen In Right Of Canada As Represented By The Minister Of Energy, Mines And Resources | Upgrading oil emulsions with carbon monoxide or synthesis gas |
US5300212A (en) | 1992-10-22 | 1994-04-05 | Exxon Research & Engineering Co. | Hydroconversion process with slurry hydrotreating |
FR2701270B1 (en) | 1993-02-08 | 1995-04-14 | Inst Francais Du Petrole | Process for removing mercury from hydrocarbons by passing over a presulfurized catalyst. |
US5397456A (en) | 1993-02-19 | 1995-03-14 | Texaco Inc. | Hydroconversion process employing catalyst with specified pore size distribution |
US5395536A (en) | 1993-05-07 | 1995-03-07 | Baker Hughes, Inc. | Wastewater organic acid removal process |
US5462651A (en) | 1994-08-09 | 1995-10-31 | Texaco Inc. | Hydrodearomatization of hydrocarbon oils using novel "phosphorus treated carbon" supported metal sulfide catalysts |
US5928499A (en) | 1993-10-01 | 1999-07-27 | Texaco Inc | Hydroconversion process employing catalyst with specified pore size distribution, median pore diameter by surface area, and pore mode by volume |
US5514273A (en) | 1993-10-01 | 1996-05-07 | Texaco Inc. | Hydroconversion process employing catalyst with specified pore size distribution |
US5468371A (en) | 1994-04-11 | 1995-11-21 | Texaco Inc. | Catalyst for residual conversion demonstrating reduced toluene insolubles |
US5620592A (en) | 1994-07-29 | 1997-04-15 | Chevron U.S.A. Inc. | Low macropore resid conversion catalyst |
NO303837B1 (en) | 1994-08-29 | 1998-09-07 | Norske Stats Oljeselskap | Process for removing substantially naphthenic acids from a hydrocarbon oil |
JP3504984B2 (en) | 1994-09-19 | 2004-03-08 | 日本ケッチェン株式会社 | Hydrodesulfurization demetallization catalyst for heavy hydrocarbon oil |
DE19600684A1 (en) | 1995-02-17 | 1996-08-22 | Linde Ag | Hydrocarbon splitting method and device |
US5885441A (en) | 1997-04-11 | 1999-03-23 | Intevep, S.A. | Steam conversion process and catalyst |
US5635056A (en) | 1995-05-02 | 1997-06-03 | Exxon Research And Engineering Company | Continuous in-situ process for upgrading heavy oil using aqueous base |
US5961815A (en) | 1995-08-28 | 1999-10-05 | Catalytic Distillation Technologies | Hydroconversion process |
US5807469A (en) | 1995-09-27 | 1998-09-15 | Intel Corporation | Flexible continuous cathode contact circuit for electrolytic plating of C4, tab microbumps, and ultra large scale interconnects |
US5817229A (en) | 1995-11-06 | 1998-10-06 | Texaco Inc | Catalytic hydrocarbon upgrading process requiring no external hydrogen supply |
WO1997029841A2 (en) * | 1996-02-14 | 1997-08-21 | Texaco Development Corporation | Low pressure process for the hydroconversion of heavy hydrocarbo ns |
US6210564B1 (en) | 1996-06-04 | 2001-04-03 | Exxon Research And Engineering Company | Process for desulfurization of petroleum feeds utilizing sodium metal |
US5856609A (en) | 1996-09-12 | 1999-01-05 | Phillips Petroleum Company | Aromatic hydrodealkylation process with sulfur oxide containing catalyst |
EP0848992B1 (en) * | 1996-12-17 | 2002-03-27 | Institut Francais Du Petrole | Boron and silicon containing catalyst and its application in the hydrotreatment of hydrocarbon feeds |
US6086749A (en) | 1996-12-23 | 2000-07-11 | Chevron U.S.A. Inc. | Catalyst and method for hydroprocessing a hydrocarbon feed stream in a reactor containing two or more catalysts |
FR2758278B1 (en) | 1997-01-15 | 1999-02-19 | Inst Francais Du Petrole | CATALYST COMPRISING A MIXED SULFIDE AND USE IN HYDRO-REFINING AND HYDROCONVERSION OF HYDROCARBONS |
US5744025A (en) * | 1997-02-28 | 1998-04-28 | Shell Oil Company | Process for hydrotreating metal-contaminated hydrocarbonaceous feedstock |
FR2764213B1 (en) | 1997-06-10 | 1999-07-16 | Inst Francais Du Petrole | HYDROCARBON CHARGE HYDROTREATMENT CATALYST IN A FIXED BED REACTOR |
US6582590B1 (en) | 1997-07-15 | 2003-06-24 | Exxonmobil Research And Engineering Company | Multistage hydroprocessing using bulk multimetallic catalyst |
US6620313B1 (en) | 1997-07-15 | 2003-09-16 | Exxonmobil Research And Engineering Company | Hydroconversion process using bulk group VIII/Group VIB catalysts |
US6162350A (en) | 1997-07-15 | 2000-12-19 | Exxon Research And Engineering Company | Hydroprocessing using bulk Group VIII/Group VIB catalysts (HEN-9901) |
US6635599B1 (en) | 1997-07-15 | 2003-10-21 | Exxonmobil Research & Engineering Company | Mixed metal catalyst, its preparation by co-precipitation, and its use |
US6783663B1 (en) | 1997-07-15 | 2004-08-31 | Exxonmobil Research And Engineering Company | Hydrotreating using bulk multimetallic catalysts |
US6755963B2 (en) | 1997-07-15 | 2004-06-29 | Exxonmobil Chemical Patents Inc. | Hydrogenation process for hydrocarbon resins |
US5847249A (en) | 1997-07-28 | 1998-12-08 | Catalytic Distillation Technologies | Apparatus and process for catalytic distillations |
US5910242A (en) | 1997-08-29 | 1999-06-08 | Exxon Research And Engineering Company | Process for reduction of total acid number in crude oil |
US5928502A (en) | 1997-08-29 | 1999-07-27 | Exxon Research And Engineering Co. | Process for reducing total acid number of crude oil |
US5871636A (en) | 1997-08-29 | 1999-02-16 | Exxon Research And Engineering Company | Catalytic reduction of acidity of crude oils in the absence of hydrogen |
US5914030A (en) | 1997-08-29 | 1999-06-22 | Exxon Research And Engineering. Co. | Process for reducing total acid number of crude oil |
US5897769A (en) * | 1997-08-29 | 1999-04-27 | Exxon Research And Engineering Co. | Process for selectively removing lower molecular weight naphthenic acids from acidic crudes |
ZA989153B (en) | 1997-10-15 | 1999-05-10 | Equistar Chem Lp | Method of producing olefins and feedstocks for use in olefin production from petroleum residua which have low pentane insolubles and high hydrogen content |
US5942101A (en) | 1997-12-09 | 1999-08-24 | Exxon Research And Engineering Co. | Method for decreasing the conradson carbon number of petroleum streams |
US5928501A (en) | 1998-02-03 | 1999-07-27 | Texaco Inc. | Process for upgrading a hydrocarbon oil |
US6248230B1 (en) | 1998-06-25 | 2001-06-19 | Sk Corporation | Method for manufacturing cleaner fuels |
US6096192A (en) | 1998-07-14 | 2000-08-01 | Exxon Research And Engineering Co. | Producing pipelinable bitumen |
FR2787041B1 (en) | 1998-12-10 | 2001-01-19 | Inst Francais Du Petrole | HYDROCARBON CHARGE HYDROTREATMENT CATALYST IN A FIXED BED REACTOR |
FR2787040B1 (en) | 1998-12-10 | 2001-01-19 | Inst Francais Du Petrole | HYDROTREATMENT OF HYDROCARBON CHARGES IN A BOILING BED REACTOR |
US6534437B2 (en) | 1999-01-15 | 2003-03-18 | Akzo Nobel N.V. | Process for preparing a mixed metal catalyst composition |
JP4303820B2 (en) | 1999-01-26 | 2009-07-29 | 日本ケッチェン株式会社 | Hydrotreating catalyst and hydrotreating method |
US7056422B2 (en) | 1999-01-27 | 2006-06-06 | Sector Capital Corporation | Batch thermolytic distillation of carbonaceous material |
US6218333B1 (en) | 1999-02-15 | 2001-04-17 | Shell Oil Company | Preparation of a hydrotreating catalyst |
US6554994B1 (en) | 1999-04-13 | 2003-04-29 | Chevron U.S.A. Inc. | Upflow reactor system with layered catalyst bed for hydrotreating heavy feedstocks |
FR2792851B1 (en) | 1999-04-29 | 2002-04-05 | Inst Francais Du Petrole | LOW-DISPERSE NOBLE METAL-BASED CATALYST AND USE THEREOF FOR THE CONVERSION OF HYDROCARBON CHARGES |
GB9912842D0 (en) | 1999-06-02 | 1999-08-04 | Bp Exploration Operating | Process for reducing the acidity of oil |
AU2001229692A1 (en) | 2000-01-24 | 2001-07-31 | Arthur D. Little, Inc. | Apparatus and methods for conversion of hydrocarbon feed streams into liquid products |
US6509291B2 (en) | 2000-04-11 | 2003-01-21 | Akzo Nobel N.V. | Process for sulfiding a catalyst containing an S-containing additive |
US6524469B1 (en) | 2000-05-16 | 2003-02-25 | Trans Ionics Corporation | Heavy oil upgrading process |
RU2186090C2 (en) | 2000-05-18 | 2002-07-27 | Королева Наталья Владиславовна | Method for production of liquid hydrocarbons by hydrogenation and demetallization of heavy oil feedstock |
WO2001094009A1 (en) | 2000-06-08 | 2001-12-13 | Japan Energy Corporation | Method for preparing catalyst for use in hydro-refining and method for recovering metal |
JP2003171671A (en) | 2000-06-08 | 2003-06-20 | Japan Energy Corp | Method for hydrogenation refining of heavy oil |
US6203313B1 (en) | 2000-06-09 | 2001-03-20 | Rebbecca L. Holmes | Candle having reconfigurable shape |
US6454932B1 (en) | 2000-08-15 | 2002-09-24 | Abb Lummus Global Inc. | Multiple stage ebullating bed hydrocracking with interstage stripping and separating |
US20020056664A1 (en) | 2000-09-07 | 2002-05-16 | Julie Chabot | Extension of catalyst cycle length in residuum desulfurization processes |
US6547957B1 (en) | 2000-10-17 | 2003-04-15 | Texaco, Inc. | Process for upgrading a hydrocarbon oil |
EP1350830A4 (en) | 2000-10-24 | 2004-12-01 | Jgc Corp | Refined oil and process for producing the same |
JP2002129171A (en) | 2000-10-27 | 2002-05-09 | Ngk Insulators Ltd | Decomposition method for heavy oil |
US20020112987A1 (en) | 2000-12-15 | 2002-08-22 | Zhiguo Hou | Slurry hydroprocessing for heavy oil upgrading using supported slurry catalysts |
RU2282784C2 (en) | 2001-04-20 | 2006-08-27 | Эксонмобил Апстрим Рисерч Компани | Method and device for enriching heavy oil |
US6581777B2 (en) * | 2001-06-14 | 2003-06-24 | Westvaco Packaging Group, Inc. | Product packaging creating a visual impression of a packaged item floating within a frame and methods for making same |
US20030042174A1 (en) | 2001-06-18 | 2003-03-06 | Petronetiics Llc. | Method to treat emulsified hydrocarbon mixtures |
US6841062B2 (en) | 2001-06-28 | 2005-01-11 | Chevron U.S.A. Inc. | Crude oil desulfurization |
CN1151235C (en) | 2001-07-02 | 2004-05-26 | 中国石油化工股份有限公司 | process and reactor for hydrogenating heavy hydrocarbon kind of raw materials |
US6887369B2 (en) | 2001-09-17 | 2005-05-03 | Southwest Research Institute | Pretreatment processes for heavy oil and carbonaceous materials |
US20030070808A1 (en) | 2001-10-15 | 2003-04-17 | Conoco Inc. | Use of syngas for the upgrading of heavy crude at the wellhead |
SG96702A1 (en) * | 2001-11-13 | 2003-06-16 | Glashuetter Uhrenbetrieb Gmbh | Device for winding and setting the time of a timepiece such as a date-watch including a date disc |
US6759364B2 (en) * | 2001-12-17 | 2004-07-06 | Shell Oil Company | Arsenic removal catalyst and method for making same |
US20030149317A1 (en) | 2002-02-04 | 2003-08-07 | Rendina David Deck | Hydrogenation catalysts and methods |
US7338795B2 (en) | 2002-03-11 | 2008-03-04 | Intevep, S.A. | Biodesulfurization of hydrocarbons |
US6808919B2 (en) | 2002-03-11 | 2004-10-26 | Intevep, S.A. | Biodesulfurization of hydrocarbons |
GB0209222D0 (en) | 2002-04-23 | 2002-06-05 | Bp Oil Int | Purification process |
US20040106516A1 (en) * | 2002-12-03 | 2004-06-03 | Schulz Lawrence E. | Hydroconversion catalyst and method for making the catalyst |
CN1307290C (en) | 2002-12-06 | 2007-03-28 | 阿尔伯麦尔荷兰有限公司 | Hydro processing of hydrocarbon using a mixture of catalysts |
AR043242A1 (en) * | 2003-02-24 | 2005-07-20 | Shell Int Research | PREPARATION AND USE OF A CATALYST COMPOSITION |
AR043243A1 (en) * | 2003-02-24 | 2005-07-20 | Shell Int Research | CATALYST COMPOSITION, ITS PREPARATION AND USE |
US7745369B2 (en) * | 2003-12-19 | 2010-06-29 | Shell Oil Company | Method and catalyst for producing a crude product with minimal hydrogen uptake |
BRPI0405576A (en) * | 2003-12-19 | 2005-10-04 | Shell Int Research | Methods of Producing a Transportable Fuel and Crude Oil Product, Heating Fuel, Lubricants or Chemicals, and Crude Oil Product |
US7780844B2 (en) | 2003-12-19 | 2010-08-24 | Shell Oil Company | Systems, methods, and catalysts for producing a crude product |
FR2866897B1 (en) | 2004-03-01 | 2007-08-31 | Inst Francais Du Petrole | USE OF GAS FOR THE PRE-REFINING OF CONVENTIONAL OIL AND OPTIONALLY SEQUESTRATION OF CO2 |
EP1869144A1 (en) * | 2005-04-11 | 2007-12-26 | Shell International Research Maatschappij B.V. | Method and catalyst for producing a crude product having a reduced nitrogen content |
US20080085225A1 (en) * | 2006-10-06 | 2008-04-10 | Bhan Opinder K | Systems for treating a hydrocarbon feed |
-
2006
- 2006-04-07 US US11/400,542 patent/US7918992B2/en not_active Expired - Fee Related
- 2006-04-07 CA CA2604012A patent/CA2604012C/en not_active Expired - Fee Related
- 2006-04-07 CN CN200680014647.3A patent/CN101166808B/en not_active Expired - Fee Related
- 2006-04-07 JP JP2008506576A patent/JP2008536003A/en active Pending
- 2006-04-07 WO PCT/US2006/013328 patent/WO2006110660A1/en active Application Filing
- 2006-04-07 BR BRPI0610670A patent/BRPI0610670B1/en not_active IP Right Cessation
- 2006-04-07 RU RU2007141710/04A patent/RU2424275C2/en not_active IP Right Cessation
- 2006-04-07 EP EP06740811A patent/EP1874897A1/en not_active Ceased
- 2006-04-11 NL NL2000050A patent/NL2000050C2/en not_active IP Right Cessation
-
2007
- 2007-11-09 NO NO20075770A patent/NO20075770L/en not_active Application Discontinuation
-
2011
- 2011-03-09 US US13/044,248 patent/US8481450B2/en not_active Expired - Fee Related
-
2012
- 2012-11-19 JP JP2012253510A patent/JP2013067808A/en active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3928176A (en) * | 1974-04-01 | 1975-12-23 | Exxon Research Engineering Co | Heavy crude conversion |
US4191635A (en) * | 1977-12-21 | 1980-03-04 | Standard Oil Company (Indiana) | Process for the cracking of heavy hydrocarbon streams |
US4357263A (en) * | 1979-10-22 | 1982-11-02 | Mobil Oil Corporation | Catalyst for the upgrading of aromatic liquids |
US4447314A (en) * | 1982-05-05 | 1984-05-08 | Mobil Oil Corporation | Demetalation, desulfurization, and decarbonization of petroleum oils by hydrotreatment in a dual bed system prior to cracking |
US4886594A (en) * | 1982-12-06 | 1989-12-12 | Amoco Corporation | Hydrotreating catalyst and process |
US4588709A (en) * | 1983-12-19 | 1986-05-13 | Intevep, S.A. | Catalyst for removing sulfur and metal contaminants from heavy crudes and residues |
EP0525259A1 (en) * | 1988-05-13 | 1993-02-03 | Texaco Development Corporation | Catalyst composition and method for hydro-processing petroleum feedstocks |
US5215955A (en) * | 1991-10-02 | 1993-06-01 | Chevron Research And Technology Company | Resid catalyst with high metals capacity |
Non-Patent Citations (1)
Title |
---|
J.G. SPEIGHT: "FUEL SCIENCE AND TECHNOLOGY HANDBOOK", 1990, DEKKER, US, XP002389850 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009135227A2 (en) * | 2008-04-10 | 2009-11-05 | Shell Oil Company | Catalysts, preparation of such catalysts, methods of using such catalysts, products obtained in such methods and uses of products obtained |
WO2009135227A3 (en) * | 2008-04-10 | 2010-08-05 | Shell Oil Company | Catalysts, preparation of such catalysts, methods of using such catalysts, products obtained in such methods and uses of products obtained |
US8178468B2 (en) * | 2008-04-10 | 2012-05-15 | Shell Oil Company | Catalysts, preparation of such catalysts, methods of using such catalysts, products obtained in such methods and uses of products obtained |
US8734634B2 (en) | 2008-04-10 | 2014-05-27 | Shell Oil Company | Method for producing a crude product, method for preparing a diluted hydrocarbon composition, crude products, diluents and uses of such crude products and diluents |
CN109999873A (en) * | 2019-03-07 | 2019-07-12 | 江苏大学 | A kind of preparation method and applications of boron nitride load molybdenum dioxide material |
Also Published As
Publication number | Publication date |
---|---|
EP1874897A1 (en) | 2008-01-09 |
NL2000050C2 (en) | 2007-07-27 |
RU2424275C2 (en) | 2011-07-20 |
CN101166808A (en) | 2008-04-23 |
CN101166808B (en) | 2013-03-27 |
US8481450B2 (en) | 2013-07-09 |
CA2604012C (en) | 2013-11-19 |
US20060231465A1 (en) | 2006-10-19 |
CA2604012A1 (en) | 2006-10-19 |
RU2007141710A (en) | 2009-05-20 |
US20110160044A1 (en) | 2011-06-30 |
JP2008536003A (en) | 2008-09-04 |
JP2013067808A (en) | 2013-04-18 |
BRPI0610670B1 (en) | 2016-01-19 |
NO20075770L (en) | 2007-11-09 |
BRPI0610670A2 (en) | 2012-10-30 |
US7918992B2 (en) | 2011-04-05 |
NL2000050A1 (en) | 2006-10-12 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US7918992B2 (en) | Systems, methods, and catalysts for producing a crude product | |
US7678264B2 (en) | Systems, methods, and catalysts for producing a crude product | |
CA2604015C (en) | Systems, methods, and catalysts for producing a crude product | |
US20060234876A1 (en) | Systems, methods, and catalysts for producing a crude product | |
US7588681B2 (en) | Systems, methods, and catalysts for producing a crude product | |
US7749374B2 (en) | Methods for producing a crude product | |
US20060231457A1 (en) | Systems, methods, and catalysts for producing a crude product |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 200680014647.3 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 4085/CHENP/2007 Country of ref document: IN |
|
ENP | Entry into the national phase |
Ref document number: 2604012 Country of ref document: CA |
|
ENP | Entry into the national phase |
Ref document number: 2008506576 Country of ref document: JP Kind code of ref document: A |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2006740811 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2007141710 Country of ref document: RU |
|
ENP | Entry into the national phase |
Ref document number: PI0610670 Country of ref document: BR Kind code of ref document: A2 Effective date: 20071010 |