WO2006088520A2 - Process for sealing phosphoric acid anodized aluminums - Google Patents
Process for sealing phosphoric acid anodized aluminums Download PDFInfo
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- WO2006088520A2 WO2006088520A2 PCT/US2005/041425 US2005041425W WO2006088520A2 WO 2006088520 A2 WO2006088520 A2 WO 2006088520A2 US 2005041425 W US2005041425 W US 2005041425W WO 2006088520 A2 WO2006088520 A2 WO 2006088520A2
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- phosphoric acid
- aqueous solution
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/18—After-treatment, e.g. pore-sealing
- C25D11/24—Chemical after-treatment
- C25D11/246—Chemical after-treatment for sealing layers
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/18—After-treatment, e.g. pore-sealing
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/82—After-treatment
- C23C22/83—Chemical after-treatment
Definitions
- This invention relates to a process for depositing a film or coating onto aluminum and its alloys that have been phosphoric acid anodized.
- the coating system comprises phosphoric acid anodize aluminums, a supplemental post-treatment or seal coating, optimally, an adhesive bond primer or other supplemental coatings.
- Phosphoric acid anodized aluminum coatings are very porous and therefore have poor inherent corrosion resistance. These coatings do, however, have excellent adhesive properties. Accordingly these anodized coatings would benefit from a post-treatment or seal coating that enhances corrosion protection without adversely affecting the adhesion properties.
- the performance characteristics of this invention allows the phosphoric acid anodized coatings to be used in unpainted applications which are currently unfeasible; to replace chromic acid anodize aluminum and FPL Etch, both of which contain chromates for corrosion-prone fatigue-sensitive applications; in all adhesive bonding applications where the and, in general use applications to reduce fatigue debit and coating weight compared to other general use anodize coatings.
- This invention relates to a process for treating phosphoric acid anodized al ⁇ minum(s) to maintain and improve the corrosion-resistant properties. More specifically, this invention relates to the process of sealing phosphoric acid anodized aluminum and anodized aluminum alloys.
- the trivalent chromium post-treatment (TCP) process comprises an acidic aqueous solution containing effective amounts of at least one water-soluble trivalent chromium compound, an alkali metal hexafluorozirconate, at least one alkali metal tetrafluoroborate and/or hexafluorosilicate, at least one divalent zinc compound, and effective amounts of water-soluble thickeners and/or water-soluble surfactants.
- Anodized aluminum(s) are generally sealed or post-treated after anodizing by processes employing a variety of sealing processes and compositions.
- Current high- performance post treatments or sealers for anodized aluminum are based on hexavalent chromium chemistry. Hexavalent chromium is highly toxic and a known carcinogen. As a result, the solutions used to deposit these protective coatings and the coating per se are toxic. These films or coatings do, however, yield good adhesion and improved corrosion resistance to the anodized aluminum.
- seal coatings are deposited onto the anodized coating at elevated temperatures and are usually applied by immersion or spray processes. Post treatments can be required by the military and by commercial specifications that govern each coating being treated.
- hexavalent chromium-treatments are becoming more expensive as regulations tighten. Costs may become prohibitive with future restrictions imposed by the EPA.
- hexavalent chromium-treatments are outstanding in their technical performance in that they provide enhanced corrosion protection and adhesion bonding e.g. with coatings such as paint at a low application cost, from a life-cycle cost, environmental, and OSH perspective, hexavalent chromium coatings are detrimental to both people and the environment.
- adhesive bonding phosphoric acid anodize is being implemented as an alternative to chromic acid anodize. Phosphoric acid anodize coatings provide excellent adhesive bonding performance, but fail to adequately protect the base aluminum from corrosion.
- anodize sealers are typically applied to various other anodize coatings to boost corrosion performance, they are generally not applied to phosphoric acid anodize coatings because the adhesive bonding performance is significantly reduced.
- the corrosion protection of a phosphoric acid anodized coating is provided by chromated bond primers or general use primers.
- Phosphoric acid anodize coatings are characteristically columnar and porous, thus promoting excellent adhesive bonding performance.
- the columnar, porous structure also promotes corrosion making ⁇ hds ⁇ hM ⁇ &Md anotf ⁇ zti (T ⁇ Mags particularly difficult to protect against corrosion.
- phosphoric acid anodized "honeycomb" core commonly used in military aircraft, corrodes quickly in service when its protective coating is damaged and would greatly benefit from a corrosion protective sealer that does not adversely impact the adhesive bonding characteristics of the anodize coating.
- This invention relates to a process of post-treating or sealing phosphoric acid anodized aluminum and its alloys at ambient temperatures or higher e.g. ranging up to about 200 0 F. More specifically, this invention relates to post-treating phosphoric acid anodized aluminum and its alloys to improve the corrosion-resistance and maintain adhesion bonding properties e.g. paint adhesion and the like.
- the trivalent chromium post-treatment (TCP) composition of this invention comprises an acidic aqueous solution having a pH ranging from about 2.5 to 5.5 and preferably 2.5 to 4.5 or 3.7 to 4.0, and per liter of said acidic solution, from about 0.01 to 22 grams of a water-soluble trivalent chromium compound, about 0.01 to 12 grams of an alkali metal hexafluorozirconate, about 0.0 to 12 or 0.001 to 12 grams of at least one fluorocompound selected from the group consisting of an alkali metal tetrafluoroborate, an alkali metal hexafluorosilicate and various combinations or mixtures thereof in any ratio, 0.001 to 10 grams of a water soluble divalent zinc compound, from about 0 to 10 grams and preferable 0 to 2.0 grams of at least one water-soluble thickener, and from 0 to 10 and preferably 0 to 2.0 grams of at least one water-soluble non-ionic, cationic or anionic surfactant or
- Fig. 1 is a photo of phosphoric acid anodized aluminum, 2024-T3 with no post treatment after exposure to 24 hours (1 day) of ASTM-B 117 neutral salt fog test.
- Fig. " ⁇ Ts 1 a photo of phosphoric acid anodized 2024-T3 post treated with the composition of Example 5 (10 minute immersion at about 75 0 F) after exposure to 96 hours (4 days) of ASTM-B 117 neutral salt fog test.
- Fig.3 is a photo of a phosphoric acid anodized 2024-T3 post treated with the composition of Example 6 (10 minute immersion at about 75 0 F) after exposure to 96 hours (4 days) of ASTM-B 117 neutral salt fog test.
- Fig. 4 is a photo of phosphoric acid anodized 2024-T3 post treated with the composition of Example 5 (10 minutes at 100 0 F) after exposure to 1000 hours (42 days) of ASTM-B 117 neutral salt fog test.
- Fig. 5 is a photo of a phosphoric acid anodized 2024-T3 post treated with the composition of Example 7 (10 minutes at 100 0 F) after exposure to 1000 hours (42 days) of ASTM-B 117 neutral salt fog test.
- Fig. 6 is a photo of a phosphoric acid anodized 2024-T3 post treated with the composition of Example 5 (40 minutes at ambient (75 0 F)) after exposure to 1000 hours (42 days) of ASTM-B 117 neutral salt fog test.
- Fig. 7 is a photo of a phosphoric acid anodized 2024-T3 post treated with the composition of Example 7 (40 minutes at ambient (75 0 F)) after exposure to 1000 hours (42 days) of ASTM-B 117 neutral salt fog test.
- Fig. 8 is a photo of a phosphoric acid anodized 2024-T3 post treated with the composition of Example 5 (5 minutes at 150 0 F) after exposure to 1000 hours (42 days) of ASTM-B 117 neutral salt fog test.
- Fig. 9 is a photo of a phosphoric acid anodized 2024-T3 post treated with the composition of Example 6 (5 minutes at 150 0 F ) after exposure to 1000 hours (42 days) of ASTM-B 117 neutral salt fog test.
- this invention relates to the process of using an acidic aqueous solution having a pH ranging from about 2.5 to 5.5, and preferably from about 2.5 to 4.5 or 3.7 to 4.0 for sealing phosphoric acid anodized aluminum and its alloys to maintain its adhesion bonding and to substantially improve the corrosion-resistance properties of the anodized aluminum(s).
- the process preferably comprises the use of an acidic solution comprising from about 0.01 to 22 grams and preferably from about 4.0 to 8.0 grams e.g. 6.0 grams of at least one water soluble trivalent chromium compound e.g. chromium sulfate, about 0.01 to 12 grams and preferably about 6.0 to 10 grams e.g.
- At least one alkali metal hexafluorozirconate about 0.0 to 12 or about 0.001 to 12 grams and preferably about 0.12 to 1.2 grams e.g. 0.24 to 0.36 grams of at least one fluorocompound selected from the group consisting of alkali metal tetrafiuoroborates, alkali metal hexafluorosilicates and various mixtures or combinations thereof in any ratio, and from about 0. ⁇ 01 to 10 grams and preferably 0.1 to 5.0 or 1.0 to 2.0 grams of at least one divalent zinc compound such as zinc sulfate.
- a feature is the addition of a thickener to the solution that aids in optimum film formation during spray and wipe-on applications by slowing down solution evaporation. This also mitigates the formation of powdery deposits that degrade paint adhesion. Moreover, the addition of thickeners, aids in proper film formation during large area applications and mitigates the diluent effect of rinse water remaining on the substrate during processing from previous steps.
- This additive yields films that have no streaks and have better coloration and corrosion prl ⁇ tec1do ⁇ /"Tfil ⁇ ter- ⁇ luBf ⁇ 'tffickeners such as the cellulose compounds are known, and can be present in the acidic aqueous solution in amounts ranging from about 0.0 to 10 grams and preferably from 0.0 to 2.0 grams and more preferably from 0.5 to 1.5 e.g., about 1.0 gram per liter of the aqueous solution.
- an effective but small amount of at least one water-soluble surfactant or wetting agent can be added to the acidic solution in amounts ranging from about 0.0 to 10 grams and preferably from 0.0 to 2.0 grams and more preferably from 0.5 to 1.5 grams e.g. 1.0 grams per liter of the acidic solution.
- These water soluble surfactants or wetting agents are known in the prior art and are selected from the group consisting of non-ionic, cationic and anionic surfactants.
- the trivalent chromium is added as a water-soluble trivalent chromium compound, preferably as a trivalent chromium salt.
- the chromium salt can be added, conveniently, to the solution in its water soluble form wherein the valence of the chromium is plus 3.
- some of the preferred chromium compounds can be prepared in solution in the form of Cr 2 (SCXf) 3 , (NH 4 )Cr(SO,! ⁇ or KCr 2 (SO 4 ) 2 and any mixtures or combination of these compounds.
- the aluminum substrates are either phosphoric acid anodized aluminum or anodized aluminum alloys containing about 60% or more by weight of aluminum.
- a preferred example of trivalent chromium concentration is within the range of about 4.0 to 8.0 grams or 6.0 grams per liter of the aqueous solution. It has been found that particularly good results are obtained when the trivalent chromium compound is present in solution in these preferred ranges.
- the preferred metal fluorozirconate addition to the acidic solution ranges from about 6.0 to 10 grams or 8.0 grams per liter of solution.
- acid anodized aluminum can be carried out at low temperatures e.g. about ambient or room temperature or at temperatures ranging up to about 200 0 F.
- the seal coating may be air dried by any of the methods known in the art, for example, oven drying, forced air drying, exposure to infra-red lamps, and the like.
- phosphoric acid anodized aluminum and anodized aluminum alloys include aluminum and its alloys phosphoric acid anodized by methods known in the art.
- the alkali metal tetrafLuoroborates and/or hexafluorosilicates can be added to the acidic solution in amounts as low as 0.001 grams per liter up to the solubility limits of the compounds.
- about 50% weight percent of the fluorosilicate is added based on the weight of the fluorozirconate.
- about 4.0 grams per liter of fluorosilicate is added to the solution.
- an alternative is to add about 0.01 to 100 weight percent of the fluoroborate salt based on the weight of the fluorozirconate salt.
- about 1 to 10 weight percent e.g. about 3% of the fluoroborate salt can be added based on the weight of the fluorozirconate salt.
- a specific example comprises about 8.0 grams per liter of potassium hexafluorozirconate, about 6.0 grams per liter of chromium III sulfate basic, about 0.1 to 5.0 grams per liter of divalent zinc sulfate and about 0.12 to 1.2 grams per liter of potassium tetrafluoroborate and/or hexafluorosilicate.
- An important result of the addition of the stabilizing additives i.e. fluoroborates and/or fluorosilicates is that the solution is stable while the pH is maintained between about 2.5 and 5.5.
- the pretreatment solutions may require small amounts of a dilute acid or base to maintain the pH in the range of about 2.5 to 5.5 or lower e.g. from about 3.25 to 3.5.
- the composition or acid solution can also contain zinc compounds to further improve the corrosion protection of the phosphoric acid anodized coatings compared to compositions that do not contain divalent zinc compounds.
- the components of the solution are mixed together in water and can be used with no further chemical manipulation.
- the divalent zinc can be supplied by any chemical compound that dissolves in water at the required concentrations ranging from 0.001 to 10 grams and is compatible with the other components in the solution.
- Compounds that are particularly preferred include, for example, zinc acetate, zinc telluride, zinc tetrafluoroborate, zinc molybdate, zinc hexafluorosilicate, zinc sulfate and the like or any combination thereof in any ratio.
- a stable acidic aqueous solution having a pH ranging from about 3.45 to 4.0 for post-treating phosphoric acid anodized aluminum and aluminum alloys to provide a corrosion-resistant and a color recognized coating thereon which comprises, per liter of solution, about 3.0 grams of trivalent chromium sulfate basic, about 4.0 grams of potassium hexafluorozirconate and about 1.0 gram zinc sulfate.
- a stable acidic aqueous solution for post-treating phosphoric acid anodized aluminum and aluminum alloys to form a corrosion-resistant coating thereon which comprises, per liter of solution, about 3.0 grams of trivalent chromium sulfate basic, about 4.0 grams of potassium hexafluorozirconate, and about 0.12 grams of potassium tetrafluoroborate.
- a stable acidic aqueous solution for post-treating phosphoric acid anodized aluminum and aluminum alloys to provide a corrosion-resistant and a color recognized coating thereon which comprises, per liter of solution, about 3.0 grams of trivalent chromium sulfate basic, about 4.0 grams of potassium hexafluorozirconate, about 0.12 grams of potassium tetrafluoroborate and about 2.0 grams of divalent zinc sulfate.
- Table 1 shows the corrosion ratings of three Examples for post-treating phosphoric acid anodized aluminum alloys of this invention in comparison to the composition of Example 2 coatings.
- Example 3 (TCP5B3Z4) and Example 1 (TCP5PZ2) on average had higher ratings.
- Example 4 To Example 4, add 1.0 grams per liter of zinc sulfate during initial mixing. Solution is ready to use.
- Example 5 To Example 5, add 2.0 grams per liter of zinc sulfate during initial mixing.
- Post treatment coatings were applied to anodized aluminum as follows.
- the phosphoric acid anodize process per ASTM D 3933, "Standard Practice for Preparation of Aluminum Surfaces for Structural Adhesives Bonding (Phosphoric Acid Anodizing)," was followed throughout.
- anodizing 3" by 10" by 0.32" aluminum panels of 2024-T3 aluminum alloys by the Phosphoric Acid Anodize process the panels were rinsed thoroughly two times in deionized water.
- the panels were immersed into a solution of either Example 6 or 7 for 10 minutes at ambient conditions. The immersion was immediately followed by two deionized water rinses.
- the panels were air-dried at ambient conditions before being subjected to neutral salt fog per ASTM B 117.
- the coupons were held in a rack at 15 degrees for the duration of the test"
- Control coupons of pitiospt ⁇ c acid anodized (PAA) not sealed were tested alongside the subject coatings.
- Fig's.2 and 3 show the performance of post treatments from the compositions of Examples 5 and 6.
- Fig. 1 shows an unsealed PAA panel after exposure to ASTM B 117 neutral salt fog.
- the post treatments of Fig's.2. and 3 provide improved corrosion resistance compared to the no post-treatment coating of Fig. 1.
- Test specimens were anodized as in Example 8.
- the compositions (solutions) from Examples 5 and 7 were heated to 100° Fahrenheit and the panels were immersed for a total of 10 minutes.
- Fig's. 4 and 5 show corrosion performance of these coatings after 1000 hours of neutral salt fog per ASTM B 117. It is evident that the composition of example 7 is an improvement compared to the composition of Example 5.
- Test specimens were anodized as in Example 8.
- the compositions (solutions) from Examples 5 and 7 were kept at ambient conditions, about 75° Fahrenheit, and the panels were immersed for a total of 40 minutes.
- Fig's. 6 and 7 (photos) show the improved corrosion resistance of these coating after 1000 hours of neutral salt fog per ASTM B 117. 1 EXAMPLE I l
- Test specimens were anodized as in Example 8.
- the compositions (solutions) from Examples 5 and 6 were heated to 150° Fahrenheit, and the panels were immersed for a total of 5 minutes.
- Fig's. 7 and 8 (photos) show the corrosion resistance of these coatings after 1000 hours of neutral salt fog per ASTM B 117.
- Table 2 compares the corrosion resistance results of the Examples based on numerical ratings from ASTM D 1654. hi the ASTM rating method, the best possible score is 10, meaning substantially no corrosion is evident on the test panel. Ratings decrease to 1, which represents substantially 100% corrosion of the panel surface. From the data in Table 2, it is evident that the process of this invention is an improvement over previous processes used for post treating or sealing phosphoric acid anodized aluminum and its alloys.
- the water soluble surfactants or wetting agents can be added to the trivalent chromium solutions in amounts ranging from about 0 to 10 grams per liter and preferably 0.5 to about 1.5 grams per liter of the trivalent chromium solution.
- the surfactants are added to the aqueous solution to provide better wetting properties by lowering the surface tension thereby insuring complete coverage, and a more uniform film on the coated substrate.
- the surfactants include at least one water soluble compound selected from the group consisting of the non-ionic, anionic, and cationic surfactants.
- Some known water soluble surfactants having the solubility at the required concentrations include the monocarboxyl imidoazoline, alkyl sulfate sodium salts (DUPONOL®), tridecyloxy poly(alkyleneoxy ethanol) ethoxylated or propoxylated alkyl phenol (IGEPAL®), alkyl sulfonamides, alkaryl sulfonates, palmitic alkanol amides (CENTROL®), octylphenyl polyethoxy ethanol (TRITON®), sorbitan monopahnitate (SPAN®), dodecylphenyl polyethylene glycol ether e.g.
- TERGITROL® alkyl pyrrolidone, polyalkoxylated fatty acid esters, alkylbenzene sulfonates and mixtures thereof.
- Other known water soluble surfactants include the alkyl phenol alkyloxylates, ' preferably me n ⁇ nylphenol effiyloxylates, and the various anionic surfactants, having at least one sulfonate substituent in the phenyl ring, and the adducts of ethylene oxide with fatty amines.
- Other known water soluble compounds are found in "Surfactants and Detersive Systems", published by John Wiley & Sops in Kirk-Othmer's Encyclopedia of Chemical Technology, 3 rd Ed.
- thickening agents When large surfaces do not permit immersion or where vertical surfaces are to be sprayed, thickening agents are added to retain the aqueous solution on the surface for sufficient contact tune.
- the thickeners employed are known inorganic and organic water soluble thickeners which can be added to the trivalent chromium solutions in effective amounts e.g. a sufficient concentration ranging from about 0 to 10 grams per liter and preferably 0.5 to 1.5 grams per liter of the acidic solution.
- Specific examples of some preferred thickeners include the cellulose compounds, e.g. hydroxypropyl cellulose (e.g. Klucel), ethyl cellulose, hydroxyethyl cellulose, hydroxymethyl cellulose, methyl cellulose and mixtures thereof.
- Some of the less preferred thickeners include the water soluble inorganic thickeners such as colloidal silica, clays such as bentonite, starches, gum arabic, tragacanth, agar and various combinations.
- the solution can be applied by immersion, spray or wipe-on techniques.
- the solution also can be used at elevated temperatures up to 65°C and optimally applied by immersion to further improve the corrosion resistance of phosphoric acid anodize coatings.
- Solution dwell time is about 1 to 60 minutes, depending on the solution temperature and concentration of the solution. After dwelling, the remaining solution is then thoroughly rinsed from the substrate with tap or deionized water. No additional chemical manipulations of the deposited film are necessary for excellent performance.
- an application of a strong oxidizing solution can yield a film with improved corrosion resistance. The additional corrosion resistance is presumed to be due to the hexavalent chromium formed in the film from the trivalent chromium.
- the aqueous sealer composition may be sprayed from a spray tank apparatus designed to replace immersion tanks. This concept also reduces active chemical volume from about 1,000 gallons to about 30 to 50 gallons.
- Another feature of this invention is the ability of this protective seal coating to provide the phosphoric acid anodized coatings with corrosion resistance better or at least equivalent to other known sealed anodic coatings produced with sulfuric, chromic, boric- sulfuric, or other known compositions.
- This capability has not been available before and offers new potential applications for phosphoric acid anodized in corrosive environments that were not previously possible.
- Phosphoric acid anodized aluminums have a major advantage over these other coatings in that its coating weights are typically 10 to 50 times lower. This yields significant weight savings and lower fatigue debit to structural aluminum alloys.
- this invention has the ability to enhance the performance of phosphoric acid anodize coatings currently being implemented as an adhesive bonding alternative to chromic acid anodizing.
- Phosphoric acid anodize coatings that have not been post treated are known to have inferior corrosion resistance, but are known also to have excellent bonding characteristics.
- This invention increases the corrosion performance of the anodized aluminums, while mamtaining the adhesive bonding strength of the coatings.
- solubility and water soluble mean water solubility of the chemical compounds used in the solutions of this invention at least at the concentrations set-forth herein. While “ ItSs invention nas"been described by a number of specific examples, it is obvious that there are other variations and modifications which can be made without departing from the spirit and scope of the invention as particularly set forth in the appended claims.
Abstract
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Priority Applications (11)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP05851693A EP1853750B1 (en) | 2005-02-15 | 2005-11-14 | Process for sealing phosphoric acid anodized aluminums |
AT05851693T ATE506469T1 (en) | 2005-02-15 | 2005-11-14 | METHOD FOR SEALING ALUMINUM ANODIZED WITH PHOSPHORIC ACID |
CA002598390A CA2598390A1 (en) | 2005-02-15 | 2005-11-14 | Process for sealing phosphoric acid anodized aluminums |
DE602005027616T DE602005027616D1 (en) | 2005-02-15 | 2005-11-14 | DISTRESSED ALUMINUM |
KR1020077021174A KR101215772B1 (en) | 2005-02-15 | 2005-11-14 | Process for sealing phosphoric acid anodized aluminums |
MX2007009800A MX2007009800A (en) | 2005-02-15 | 2005-11-14 | Process for sealing phosphoric acid anodized aluminums. |
JP2007555079A JP4805280B2 (en) | 2005-02-15 | 2005-11-14 | Method for sealing pores of anodized aluminum phosphate |
AU2005327547A AU2005327547A1 (en) | 2005-02-15 | 2005-11-14 | Process for sealing phosphoric acid anodized aluminums |
BRPI0519983-2A BRPI0519983A2 (en) | 2005-02-15 | 2005-11-14 | process for sealing aluminum and phosphoric acid anodized aluminum alloys to improve corrosion resistance and maintain adhesive bond strength, and sealant anodized phosphoric acid aluminum and aluminum alloys |
DK05851693.1T DK1853750T3 (en) | 2005-02-15 | 2005-11-14 | Process for sealing aluminum anodized with phosphoric acid |
CN2005800483383A CN101146929B (en) | 2005-02-15 | 2005-11-14 | Process for sealing phosphoric acid anodized aluminums |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US11/058,533 | 2005-02-15 | ||
US11/058,533 US20060191599A1 (en) | 2005-02-15 | 2005-02-15 | Process for sealing phosphoric acid anodized aluminums |
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WO2006088520A2 true WO2006088520A2 (en) | 2006-08-24 |
WO2006088520A3 WO2006088520A3 (en) | 2007-01-18 |
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PCT/US2005/041425 WO2006088520A2 (en) | 2005-02-15 | 2005-11-14 | Process for sealing phosphoric acid anodized aluminums |
Country Status (14)
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US (1) | US20060191599A1 (en) |
EP (1) | EP1853750B1 (en) |
JP (1) | JP4805280B2 (en) |
KR (1) | KR101215772B1 (en) |
CN (1) | CN101146929B (en) |
AT (1) | ATE506469T1 (en) |
AU (1) | AU2005327547A1 (en) |
BR (1) | BRPI0519983A2 (en) |
CA (1) | CA2598390A1 (en) |
DE (1) | DE602005027616D1 (en) |
DK (1) | DK1853750T3 (en) |
ES (1) | ES2365403T3 (en) |
MX (1) | MX2007009800A (en) |
WO (1) | WO2006088520A2 (en) |
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FR3106837B1 (en) * | 2020-01-31 | 2023-05-12 | Safran Aerosystems | SURFACE TREATMENT PROCESS FOR ALUMINUM-BASED PARTS |
FR3140382A1 (en) | 2022-10-04 | 2024-04-05 | Safran Landing Systems | PROCESS FOR POST-ANODIZATION SEALING OF ALUMINUM AND ALUMINUM ALLOYS WITHOUT USING CHROME |
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ES452499A1 (en) * | 1976-10-05 | 1978-04-01 | Brugarolas Sa | Process for sealing anodic oxidation layers on aluminium surfaces and its alloys |
US4467028A (en) * | 1982-07-12 | 1984-08-21 | Polychrome Corporation | Acid interlayered planographic printing plate |
US4786336A (en) * | 1985-03-08 | 1988-11-22 | Amchem Products, Inc. | Low temperature seal for anodized aluminum surfaces |
JPH03122300A (en) * | 1989-10-06 | 1991-05-24 | Johoku Riken Kogyo:Kk | Surface treatment of aluminum alloy |
JP2579234B2 (en) * | 1990-04-25 | 1997-02-05 | スカイアルミニウム株式会社 | Aluminum fin material for heat exchanger and method for producing the same |
US5374347A (en) * | 1993-09-27 | 1994-12-20 | The United States Of America As Represented By The Secretary Of The Navy | Trivalent chromium solutions for sealing anodized aluminum |
US5304257A (en) * | 1993-09-27 | 1994-04-19 | The United States Of America As Represented By The Secretary Of The Navy | Trivalent chromium conversion coatings for aluminum |
GB9422952D0 (en) * | 1994-11-14 | 1995-01-04 | Secr Defence | Corrosion inhibitor |
JP2001152392A (en) * | 1999-11-24 | 2001-06-05 | Toyama Prefecture | Alkali resistant aluminum oxide composite film and producing method therefor |
US6663700B1 (en) * | 2000-10-31 | 2003-12-16 | The United States Of America As Represented By The Secretary Of The Navy | Post-treatment for metal coated substrates |
US6511532B2 (en) * | 2000-10-31 | 2003-01-28 | The United States Of America As Represented By The Secretary Of The Navy | Post-treatment for anodized aluminum |
US6669764B1 (en) * | 2000-10-31 | 2003-12-30 | The United States Of America As Represented By The Secretary Of The Navy | Pretreatment for aluminum and aluminum alloys |
US7018486B2 (en) * | 2002-05-13 | 2006-03-28 | United Technologies Corporation | Corrosion resistant trivalent chromium phosphated chemical conversion coatings |
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2005
- 2005-02-15 US US11/058,533 patent/US20060191599A1/en not_active Abandoned
- 2005-11-14 MX MX2007009800A patent/MX2007009800A/en active IP Right Grant
- 2005-11-14 CA CA002598390A patent/CA2598390A1/en not_active Abandoned
- 2005-11-14 CN CN2005800483383A patent/CN101146929B/en not_active Expired - Fee Related
- 2005-11-14 WO PCT/US2005/041425 patent/WO2006088520A2/en active Application Filing
- 2005-11-14 JP JP2007555079A patent/JP4805280B2/en not_active Expired - Fee Related
- 2005-11-14 DK DK05851693.1T patent/DK1853750T3/en active
- 2005-11-14 EP EP05851693A patent/EP1853750B1/en not_active Not-in-force
- 2005-11-14 ES ES05851693T patent/ES2365403T3/en active Active
- 2005-11-14 KR KR1020077021174A patent/KR101215772B1/en not_active IP Right Cessation
- 2005-11-14 BR BRPI0519983-2A patent/BRPI0519983A2/en not_active Application Discontinuation
- 2005-11-14 DE DE602005027616T patent/DE602005027616D1/en active Active
- 2005-11-14 AU AU2005327547A patent/AU2005327547A1/en not_active Abandoned
- 2005-11-14 AT AT05851693T patent/ATE506469T1/en not_active IP Right Cessation
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Title |
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See references of EP1853750A4 * |
Also Published As
Publication number | Publication date |
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JP4805280B2 (en) | 2011-11-02 |
CN101146929B (en) | 2010-08-11 |
EP1853750A2 (en) | 2007-11-14 |
KR20070121674A (en) | 2007-12-27 |
DK1853750T3 (en) | 2011-06-20 |
CA2598390A1 (en) | 2006-08-24 |
JP2008530362A (en) | 2008-08-07 |
AU2005327547A1 (en) | 2006-08-24 |
WO2006088520A3 (en) | 2007-01-18 |
EP1853750A4 (en) | 2009-04-29 |
DE602005027616D1 (en) | 2011-06-01 |
CN101146929A (en) | 2008-03-19 |
ATE506469T1 (en) | 2011-05-15 |
US20060191599A1 (en) | 2006-08-31 |
ES2365403T3 (en) | 2011-10-04 |
MX2007009800A (en) | 2007-09-27 |
EP1853750B1 (en) | 2011-04-20 |
BRPI0519983A2 (en) | 2009-08-18 |
KR101215772B1 (en) | 2013-01-10 |
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