WO2006072782A3 - Tetracyanoquinodimethane composite material and use in electrodes - Google Patents
Tetracyanoquinodimethane composite material and use in electrodes Download PDFInfo
- Publication number
- WO2006072782A3 WO2006072782A3 PCT/GB2006/000017 GB2006000017W WO2006072782A3 WO 2006072782 A3 WO2006072782 A3 WO 2006072782A3 GB 2006000017 W GB2006000017 W GB 2006000017W WO 2006072782 A3 WO2006072782 A3 WO 2006072782A3
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- tetrathiafulvalene
- molecule
- tetracyanoquinodimethane
- electrodes
- composite material
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12Q—MEASURING OR TESTING PROCESSES INVOLVING ENZYMES, NUCLEIC ACIDS OR MICROORGANISMS; COMPOSITIONS OR TEST PAPERS THEREFOR; PROCESSES OF PREPARING SUCH COMPOSITIONS; CONDITION-RESPONSIVE CONTROL IN MICROBIOLOGICAL OR ENZYMOLOGICAL PROCESSES
- C12Q1/00—Measuring or testing processes involving enzymes, nucleic acids or microorganisms; Compositions therefor; Processes of preparing such compositions
- C12Q1/001—Enzyme electrodes
- C12Q1/004—Enzyme electrodes mediator-assisted
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/315—Compounds containing carbon-to-nitrogen triple bonds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/16—Biochemical fuel cells, i.e. cells in which microorganisms function as catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Abstract
A composite material comprising a charge transfer complex of a tetracyanoquinodimethane (TCNQ) molecule of general formula (I), a binder substance and an isoalloxazine molecule is provided, in which the TCNQ molecule of general formula (I) is represented by Formula (I); in which R is represented by H, (C1-C6) alkyl, halide, cyanide, nitro, nitroso, amino, sulfonyl, thiol, sulfonate, silanyl, sulfate or (C1-C6) alkyl substituted with one or more of these functional groups or substituted by one or more electron donor compounds including: tetrathiafulvalene (TTF) in which the sulfur atom is optionally replaced by O, Se or Te, N-methyl-phenazinium, hexamethylene-tetratellurofulvalene, tetramethylammonium, methyltriphenyl-phosphonium, methoxytrifluoro- phosphonium, methoxytrifluoro-methylphenylacetic acid, hexamethylene- tetrathiafulvalene, ethylenedithio-tetrathiafulvalene (BEDTTF), BTP. Such materials may be used in the composition of electrodes.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB0500289.4 | 2005-01-07 | ||
GBGB0500289.4A GB0500289D0 (en) | 2005-01-07 | 2005-01-07 | Electrodes |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2006072782A2 WO2006072782A2 (en) | 2006-07-13 |
WO2006072782A3 true WO2006072782A3 (en) | 2007-02-15 |
Family
ID=34203757
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/GB2006/000017 WO2006072782A2 (en) | 2005-01-07 | 2006-01-04 | Tetracyanoquinodimethane composite material and use in electrodes |
Country Status (2)
Country | Link |
---|---|
GB (1) | GB0500289D0 (en) |
WO (1) | WO2006072782A2 (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB0817041D0 (en) | 2008-09-17 | 2008-10-22 | Smith & Nephew | Power generation |
JP6975122B2 (en) * | 2018-11-06 | 2021-12-01 | 信越化学工業株式会社 | Resin composition, wavelength conversion material, wavelength conversion film, LED element, backlight unit and image display device |
CN114628644B (en) * | 2022-03-14 | 2022-11-11 | 浙江大学温州研究院 | In-situ preparation method of TCNQ-based protective layer for zinc battery cathode |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2068637A (en) * | 1980-01-24 | 1981-08-12 | Matsushita Electric Ind Co Ltd | Conductive device using conductive polymer compositions |
JPS5769668A (en) * | 1980-10-16 | 1982-04-28 | Matsushita Electric Ind Co Ltd | Enzyme electrode |
EP0184909A2 (en) * | 1984-11-13 | 1986-06-18 | Genetics International, Inc. | Bioelectrochemical assay and apparatus |
US5378332A (en) * | 1993-04-14 | 1995-01-03 | The United States Of America As Represented By The Secretary Of Commerce | Amperometric flow injection analysis biosensor for glucose based on graphite paste modified with tetracyanoquinodimethane |
WO1997002359A1 (en) * | 1995-07-05 | 1997-01-23 | Saicom S.R.L. | Electrochemical biosensors and process for their preparation |
US20030152823A1 (en) * | 1998-06-17 | 2003-08-14 | Therasense, Inc. | Biological fuel cell and methods |
-
2005
- 2005-01-07 GB GBGB0500289.4A patent/GB0500289D0/en not_active Ceased
-
2006
- 2006-01-04 WO PCT/GB2006/000017 patent/WO2006072782A2/en not_active Application Discontinuation
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2068637A (en) * | 1980-01-24 | 1981-08-12 | Matsushita Electric Ind Co Ltd | Conductive device using conductive polymer compositions |
JPS5769668A (en) * | 1980-10-16 | 1982-04-28 | Matsushita Electric Ind Co Ltd | Enzyme electrode |
EP0184909A2 (en) * | 1984-11-13 | 1986-06-18 | Genetics International, Inc. | Bioelectrochemical assay and apparatus |
US5378332A (en) * | 1993-04-14 | 1995-01-03 | The United States Of America As Represented By The Secretary Of Commerce | Amperometric flow injection analysis biosensor for glucose based on graphite paste modified with tetracyanoquinodimethane |
WO1997002359A1 (en) * | 1995-07-05 | 1997-01-23 | Saicom S.R.L. | Electrochemical biosensors and process for their preparation |
US20030152823A1 (en) * | 1998-06-17 | 2003-08-14 | Therasense, Inc. | Biological fuel cell and methods |
Non-Patent Citations (2)
Title |
---|
KHURANA M K ET AL: "DETECTION MECHANISM OF METALLIZED CARBON EPOXY OXIDASE ENZYME BASED SENSORS", ELECTROANALYSIS, VHC PUBLISHERS, INC, US, vol. 15, no. 12, August 2003 (2003-08-01), pages 1023 - 1030, XP009038424, ISSN: 1040-0397 * |
P.D. HALE AND AL: "Cyclic coltammetry at TNCQ and TTF-TCNQ modified platinum electrodes : a study of the glucose oxidase/glucose and galactose oxidase/galactose systems", SYNTHETIC METALS, vol. 28, 1989, pages C853 - C858, XP002404085 * |
Also Published As
Publication number | Publication date |
---|---|
GB0500289D0 (en) | 2005-02-16 |
WO2006072782A2 (en) | 2006-07-13 |
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