WO2006072782A3 - Tetracyanoquinodimethane composite material and use in electrodes - Google Patents

Tetracyanoquinodimethane composite material and use in electrodes Download PDF

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Publication number
WO2006072782A3
WO2006072782A3 PCT/GB2006/000017 GB2006000017W WO2006072782A3 WO 2006072782 A3 WO2006072782 A3 WO 2006072782A3 GB 2006000017 W GB2006000017 W GB 2006000017W WO 2006072782 A3 WO2006072782 A3 WO 2006072782A3
Authority
WO
WIPO (PCT)
Prior art keywords
tetrathiafulvalene
molecule
tetracyanoquinodimethane
electrodes
composite material
Prior art date
Application number
PCT/GB2006/000017
Other languages
French (fr)
Other versions
WO2006072782A2 (en
Inventor
Danny O'hare
Original Assignee
Imp Innovations Ltd
Danny O'hare
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Imp Innovations Ltd, Danny O'hare filed Critical Imp Innovations Ltd
Publication of WO2006072782A2 publication Critical patent/WO2006072782A2/en
Publication of WO2006072782A3 publication Critical patent/WO2006072782A3/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12QMEASURING OR TESTING PROCESSES INVOLVING ENZYMES, NUCLEIC ACIDS OR MICROORGANISMS; COMPOSITIONS OR TEST PAPERS THEREFOR; PROCESSES OF PREPARING SUCH COMPOSITIONS; CONDITION-RESPONSIVE CONTROL IN MICROBIOLOGICAL OR ENZYMOLOGICAL PROCESSES
    • C12Q1/00Measuring or testing processes involving enzymes, nucleic acids or microorganisms; Compositions therefor; Processes of preparing such compositions
    • C12Q1/001Enzyme electrodes
    • C12Q1/004Enzyme electrodes mediator-assisted
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/315Compounds containing carbon-to-nitrogen triple bonds
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00Electrodes
    • H01M4/86Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/90Selection of catalytic material
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/16Biochemical fuel cells, i.e. cells in which microorganisms function as catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

A composite material comprising a charge transfer complex of a tetracyanoquinodimethane (TCNQ) molecule of general formula (I), a binder substance and an isoalloxazine molecule is provided, in which the TCNQ molecule of general formula (I) is represented by Formula (I); in which R is represented by H, (C1-C6) alkyl, halide, cyanide, nitro, nitroso, amino, sulfonyl, thiol, sulfonate, silanyl, sulfate or (C1-C6) alkyl substituted with one or more of these functional groups or substituted by one or more electron donor compounds including: tetrathiafulvalene (TTF) in which the sulfur atom is optionally replaced by O, Se or Te, N-methyl-phenazinium, hexamethylene-tetratellurofulvalene, tetramethylammonium, methyltriphenyl-phosphonium, methoxytrifluoro- phosphonium, methoxytrifluoro-methylphenylacetic acid, hexamethylene- tetrathiafulvalene, ethylenedithio-tetrathiafulvalene (BEDTTF), BTP. Such materials may be used in the composition of electrodes.
PCT/GB2006/000017 2005-01-07 2006-01-04 Tetracyanoquinodimethane composite material and use in electrodes WO2006072782A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0500289.4 2005-01-07
GBGB0500289.4A GB0500289D0 (en) 2005-01-07 2005-01-07 Electrodes

Publications (2)

Publication Number Publication Date
WO2006072782A2 WO2006072782A2 (en) 2006-07-13
WO2006072782A3 true WO2006072782A3 (en) 2007-02-15

Family

ID=34203757

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2006/000017 WO2006072782A2 (en) 2005-01-07 2006-01-04 Tetracyanoquinodimethane composite material and use in electrodes

Country Status (2)

Country Link
GB (1) GB0500289D0 (en)
WO (1) WO2006072782A2 (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0817041D0 (en) 2008-09-17 2008-10-22 Smith & Nephew Power generation
JP6975122B2 (en) * 2018-11-06 2021-12-01 信越化学工業株式会社 Resin composition, wavelength conversion material, wavelength conversion film, LED element, backlight unit and image display device
CN114628644B (en) * 2022-03-14 2022-11-11 浙江大学温州研究院 In-situ preparation method of TCNQ-based protective layer for zinc battery cathode

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2068637A (en) * 1980-01-24 1981-08-12 Matsushita Electric Ind Co Ltd Conductive device using conductive polymer compositions
JPS5769668A (en) * 1980-10-16 1982-04-28 Matsushita Electric Ind Co Ltd Enzyme electrode
EP0184909A2 (en) * 1984-11-13 1986-06-18 Genetics International, Inc. Bioelectrochemical assay and apparatus
US5378332A (en) * 1993-04-14 1995-01-03 The United States Of America As Represented By The Secretary Of Commerce Amperometric flow injection analysis biosensor for glucose based on graphite paste modified with tetracyanoquinodimethane
WO1997002359A1 (en) * 1995-07-05 1997-01-23 Saicom S.R.L. Electrochemical biosensors and process for their preparation
US20030152823A1 (en) * 1998-06-17 2003-08-14 Therasense, Inc. Biological fuel cell and methods

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2068637A (en) * 1980-01-24 1981-08-12 Matsushita Electric Ind Co Ltd Conductive device using conductive polymer compositions
JPS5769668A (en) * 1980-10-16 1982-04-28 Matsushita Electric Ind Co Ltd Enzyme electrode
EP0184909A2 (en) * 1984-11-13 1986-06-18 Genetics International, Inc. Bioelectrochemical assay and apparatus
US5378332A (en) * 1993-04-14 1995-01-03 The United States Of America As Represented By The Secretary Of Commerce Amperometric flow injection analysis biosensor for glucose based on graphite paste modified with tetracyanoquinodimethane
WO1997002359A1 (en) * 1995-07-05 1997-01-23 Saicom S.R.L. Electrochemical biosensors and process for their preparation
US20030152823A1 (en) * 1998-06-17 2003-08-14 Therasense, Inc. Biological fuel cell and methods

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
KHURANA M K ET AL: "DETECTION MECHANISM OF METALLIZED CARBON EPOXY OXIDASE ENZYME BASED SENSORS", ELECTROANALYSIS, VHC PUBLISHERS, INC, US, vol. 15, no. 12, August 2003 (2003-08-01), pages 1023 - 1030, XP009038424, ISSN: 1040-0397 *
P.D. HALE AND AL: "Cyclic coltammetry at TNCQ and TTF-TCNQ modified platinum electrodes : a study of the glucose oxidase/glucose and galactose oxidase/galactose systems", SYNTHETIC METALS, vol. 28, 1989, pages C853 - C858, XP002404085 *

Also Published As

Publication number Publication date
GB0500289D0 (en) 2005-02-16
WO2006072782A2 (en) 2006-07-13

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