WO2006041848A2 - Water repellant fiberglass binder comprising a fluorinated polymer - Google Patents
Water repellant fiberglass binder comprising a fluorinated polymer Download PDFInfo
- Publication number
- WO2006041848A2 WO2006041848A2 PCT/US2005/035694 US2005035694W WO2006041848A2 WO 2006041848 A2 WO2006041848 A2 WO 2006041848A2 US 2005035694 W US2005035694 W US 2005035694W WO 2006041848 A2 WO2006041848 A2 WO 2006041848A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- binder
- fiberglass
- product
- polymer
- polyol
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J167/00—Adhesives based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Adhesives based on derivatives of such polymers
- C09J167/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
- C09J167/03—Polyesters derived from dicarboxylic acids and dihydroxy compounds the dicarboxylic acids and dihydroxy compounds having the carboxyl - and the hydroxy groups directly linked to aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J127/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers
- C09J127/02—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
- C09J127/12—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Adhesives based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/587—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives characterised by the bonding agents used
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/58—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives
- D04H1/64—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by applying, incorporating or activating chemical or thermoplastic bonding agents, e.g. adhesives the bonding agent being applied in wet state, e.g. chemical agents in dispersions or solutions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
- C08L33/16—Homopolymers or copolymers of esters containing halogen atoms
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
Definitions
- U.S. Patent No. 5,318,990 discloses a fibrous glass binder which comprises a polycarboxy polymer, a monomeric trihydric alcohol and a catalyst comprising an alkali metal salt of a phosphorous-containing organic acid.
- thermosetting acrylic resins have been found to be more hydrophilic than the traditional phenolic binders, however. This hydrophilicity can result in fiberglass insulation that is more prone to absorb liquid water, thereby possibly compromising the integrity of the product. Also, the thermosetting acrylic resins now being used as binding agents for fiberglass have been found to not react as effectively with silane coupling agents of the type traditionally used by the industry.
- the binder composition of the present invention comprises a polycarboxy polymer, a polyol, and a fluorinated polymer. It is also preferred that the binder comprise a catalyst, such as an alkaline metal salt of a phosphorus-containing organic acid.
- a catalyst such as an alkaline metal salt of a phosphorus-containing organic acid.
- An important aspect of the binder of the present invention is that the binder composition, in addition to the polycarboxy polymer and the polyol, contains a fluorinated polymer. The presence of the fluorinated polymer in the binder is believed to render the binder, and hence the fiberglass mat to which the binder is applied, essentially waterproof. As a result, fiberglass insulation made with the binder of the present invention avoids the possible problem of coming apart when subjected to water, as the binder of the present invention has been found to repel the water and maintain the integrity of the bond with the fiberglass.
- the formaldehyde-free curable aqueous binder composition of the present invention also contain a catalyst.
- the catalyst is a phosphorous-containing accelerator which may be a compound with a molecular weight less than about 1000 such as, for example, an alkali metal polyphosphate, an alkali metal dihydrogen phosphate, a polyphosphoric acid, and an alkyl phosphinic acid or it may be an oligomer or polymer bearing phosphorous-containing groups such as, for example, addition polymers of acrylic and/or maleic acids formed in the presence of sodium hypophosphite, addition polymers prepared from ethylenically unsaturated monomers in the presence of phosphorous salt chain transfer agents or terminators, and addition polymers containing acid-functional monomer residues such as, for example, copolymerized phosphoethyl methacrylate, and like phosphonic acid esters, and copolymerized vinyl sulfonic acid monomers, and their salts.
- the phosphorous- containing accelerator may be used at a level of from about 1 % to about 40%, by weight based on the combined weight of the polyacid and the polyol. Preferred is a level of phosphorous-containing accelerator of from about 2.5% to about 10%, by weight based on the combined weight of the polyacid and the polyol.
- the waterborne formaldehyde-free composition of the present invention after it is applied to a nonwoven, is heated to effect drying and curing.
- the duration and temperature of heating will affect the rate of drying, processability and handleability, and property development of the treated substrate.
- Heat treatment at about 120DC, to about 400DC, for a period of time between about 3 seconds to about 15 minutes may be carried out; treatment at about 150DC, to about 250DC, is preferred.
- the drying and curing functions may be effected in two or more distinct steps, if desired.
- the composition may be first heated at a temperature and for a time sufficient to substantially dry but not to substantially cure the composition and then heated for a second time at a higher temperature and/or for a longer period of time to effect curing.
Abstract
Description
Claims
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA 2582889 CA2582889A1 (en) | 2004-10-07 | 2005-10-04 | Water repellant fiberglass binder comprising a fluorinated polymer |
EP05809963A EP1805233A4 (en) | 2004-10-07 | 2005-10-04 | Water repellant fiberglass binder comprising a fluorinated polymer |
JP2007535755A JP2008515761A (en) | 2004-10-07 | 2005-10-04 | Water repellent glass fiber binder containing a fluorinated polymer |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US10/960,617 | 2004-10-07 | ||
US10/960,617 US20060078719A1 (en) | 2004-10-07 | 2004-10-07 | Water repellant fiberglass binder comprising a fluorinated polymer |
Publications (2)
Publication Number | Publication Date |
---|---|
WO2006041848A2 true WO2006041848A2 (en) | 2006-04-20 |
WO2006041848A3 WO2006041848A3 (en) | 2006-12-07 |
Family
ID=36145713
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2005/035694 WO2006041848A2 (en) | 2004-10-07 | 2005-10-04 | Water repellant fiberglass binder comprising a fluorinated polymer |
Country Status (7)
Country | Link |
---|---|
US (1) | US20060078719A1 (en) |
EP (1) | EP1805233A4 (en) |
JP (1) | JP2008515761A (en) |
KR (1) | KR20070088596A (en) |
CN (1) | CN101039968A (en) |
CA (1) | CA2582889A1 (en) |
WO (1) | WO2006041848A2 (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109280496A (en) * | 2018-11-22 | 2019-01-29 | 华美节能科技集团玻璃棉制品有限公司 | Agricultural cotton adhesive, agricultural cotton and preparation method thereof |
US11401639B2 (en) | 2016-09-06 | 2022-08-02 | Owens Corning Intellectual Capital, Llc | Corrosion-resistant non-woven for pipe liner pultrusion applications |
US11970801B2 (en) | 2022-07-01 | 2024-04-30 | Owens Corning Intellectual Capital, Llc | Corrosion-resistant non-woven for pipe liner pultrusion applications |
Families Citing this family (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4796836B2 (en) * | 2005-12-26 | 2011-10-19 | 旭ファイバーグラス株式会社 | Aqueous binder for inorganic fiber and heat insulating sound absorbing material for inorganic fiber |
DE102008062765A1 (en) | 2008-12-18 | 2010-07-01 | Vb Autobatterie Gmbh & Co. Kgaa | Textile sheet material for a battery electrode |
EP2401782B1 (en) | 2009-02-26 | 2020-06-03 | CPS Technology Holdings LLC | Battery electrode and method for manufacturing same |
JP5421730B2 (en) * | 2009-10-28 | 2014-02-19 | 日本無機株式会社 | Manufacturing method of glass fiber filter |
US8114197B2 (en) * | 2009-12-22 | 2012-02-14 | Hollingsworth & Vose Company | Filter media and articles including dendrimers and/or other components |
CN101880965A (en) * | 2010-06-30 | 2010-11-10 | 李世安 | Production process of reinforced fiberglass modified adhesive |
JP6418847B2 (en) * | 2014-08-25 | 2018-11-07 | 株式会社日本触媒 | Nonionic polyhydric alcohol-containing binder |
CN105887487B (en) * | 2016-05-17 | 2018-06-08 | 江西国桥实业有限公司 | The preparation method of water and oil repellant modified acroleic acid esters adhesive |
WO2018017262A1 (en) | 2016-07-20 | 2018-01-25 | Super Insulation, LLC | Hydrophobic fiberglass thermal insulation materials |
WO2019074865A1 (en) | 2017-10-09 | 2019-04-18 | Owens Corning Intellectual Capital, Llc | Aqueous binder compositions |
CN111201275B (en) | 2017-10-09 | 2022-07-01 | 欧文斯科宁知识产权资产有限公司 | Aqueous adhesive composition |
WO2021039556A1 (en) * | 2019-08-23 | 2021-03-04 | 日信化学工業株式会社 | Binder for inorganic fibers and inorganic fiber mat |
US11813833B2 (en) | 2019-12-09 | 2023-11-14 | Owens Corning Intellectual Capital, Llc | Fiberglass insulation product |
Family Cites Families (19)
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US3532659A (en) * | 1967-04-26 | 1970-10-06 | Pennsalt Chemicals Corp | Fluorinated organic compounds and polymers thereof |
US4032495A (en) * | 1972-03-10 | 1977-06-28 | Produits Chimiques Ugine Kuhlmann | Water-repellent and oil-repellent compositions based on fluorine compound |
DE2509237A1 (en) * | 1974-03-25 | 1975-10-09 | Rohm & Haas | PROCESS FOR CURING POLYMERS AND CURABLE POLYMER COMPOSITIONS |
US5143582A (en) * | 1991-05-06 | 1992-09-01 | Rohm And Haas Company | Heat-resistant nonwoven fabrics |
US5661213A (en) * | 1992-08-06 | 1997-08-26 | Rohm And Haas Company | Curable aqueous composition and use as fiberglass nonwoven binder |
US5318990A (en) * | 1993-06-21 | 1994-06-07 | Owens-Corning Fiberglas Technology Inc. | Fibrous glass binders |
US5340868A (en) * | 1993-06-21 | 1994-08-23 | Owens-Corning Fiberglass Technology Inc. | Fibrous glass binders |
US5427587A (en) * | 1993-10-22 | 1995-06-27 | Rohm And Haas Company | Method for strengthening cellulosic substrates |
US6238791B1 (en) * | 1997-12-18 | 2001-05-29 | Ppg Industries Ohio, Inc. | Coated glass fibers, composites and methods related thereto |
US6331350B1 (en) * | 1998-10-02 | 2001-12-18 | Johns Manville International, Inc. | Polycarboxy/polyol fiberglass binder of low pH |
JP5122048B2 (en) * | 1999-12-15 | 2013-01-16 | ホリングワース・アンド・ボーズ・カンパニー | Low boron content micro glass fiber filtration media |
US6399694B1 (en) * | 2000-06-30 | 2002-06-04 | Owens Corning Fiberglas Technology, Inc. | Colorable fiberglass insulation |
US20040002567A1 (en) * | 2002-06-27 | 2004-01-01 | Liang Chen | Odor free molding media having a polycarboxylic acid binder |
US6699945B1 (en) * | 2002-12-03 | 2004-03-02 | Owens Corning Fiberglas Technology, Inc. | Polycarboxylic acid based co-binder |
US7223455B2 (en) * | 2003-01-14 | 2007-05-29 | Certainteed Corporation | Duct board with water repellant mat |
US20050112374A1 (en) * | 2003-11-20 | 2005-05-26 | Alan Michael Jaffee | Method of making fibrous mats and fibrous mats |
US20050215153A1 (en) * | 2004-03-23 | 2005-09-29 | Cossement Marc R | Dextrin binder composition for heat resistant non-wovens |
US20060019568A1 (en) * | 2004-07-26 | 2006-01-26 | Toas Murray S | Insulation board with air/rain barrier covering and water-repellent covering |
US8163664B2 (en) * | 2004-07-30 | 2012-04-24 | Owens Corning Intellectual Capital, Llc | Fiberglass products for reducing the flammability of mattresses |
-
2004
- 2004-10-07 US US10/960,617 patent/US20060078719A1/en not_active Abandoned
-
2005
- 2005-10-04 KR KR1020077007928A patent/KR20070088596A/en not_active Application Discontinuation
- 2005-10-04 CN CNA2005800344408A patent/CN101039968A/en active Pending
- 2005-10-04 WO PCT/US2005/035694 patent/WO2006041848A2/en active Application Filing
- 2005-10-04 JP JP2007535755A patent/JP2008515761A/en active Pending
- 2005-10-04 EP EP05809963A patent/EP1805233A4/en not_active Withdrawn
- 2005-10-04 CA CA 2582889 patent/CA2582889A1/en not_active Abandoned
Non-Patent Citations (1)
Title |
---|
See references of EP1805233A4 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US11401639B2 (en) | 2016-09-06 | 2022-08-02 | Owens Corning Intellectual Capital, Llc | Corrosion-resistant non-woven for pipe liner pultrusion applications |
CN109280496A (en) * | 2018-11-22 | 2019-01-29 | 华美节能科技集团玻璃棉制品有限公司 | Agricultural cotton adhesive, agricultural cotton and preparation method thereof |
US11970801B2 (en) | 2022-07-01 | 2024-04-30 | Owens Corning Intellectual Capital, Llc | Corrosion-resistant non-woven for pipe liner pultrusion applications |
Also Published As
Publication number | Publication date |
---|---|
US20060078719A1 (en) | 2006-04-13 |
WO2006041848A3 (en) | 2006-12-07 |
JP2008515761A (en) | 2008-05-15 |
KR20070088596A (en) | 2007-08-29 |
EP1805233A2 (en) | 2007-07-11 |
CA2582889A1 (en) | 2006-04-20 |
CN101039968A (en) | 2007-09-19 |
EP1805233A4 (en) | 2008-01-16 |
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