WO2005104674A2 - Projectile, projectile core, and method of making - Google Patents

Projectile, projectile core, and method of making Download PDF

Info

Publication number
WO2005104674A2
WO2005104674A2 PCT/US2004/037946 US2004037946W WO2005104674A2 WO 2005104674 A2 WO2005104674 A2 WO 2005104674A2 US 2004037946 W US2004037946 W US 2004037946W WO 2005104674 A2 WO2005104674 A2 WO 2005104674A2
Authority
WO
WIPO (PCT)
Prior art keywords
core
projectile
projectile core
carrier
colorant
Prior art date
Application number
PCT/US2004/037946
Other languages
French (fr)
Other versions
WO2005104674A3 (en
Inventor
John E. Campo
Michael J. Wood
Original Assignee
National Paintball Supply, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by National Paintball Supply, Inc. filed Critical National Paintball Supply, Inc.
Priority to US10/579,002 priority Critical patent/US7934454B2/en
Priority to CA2546004A priority patent/CA2546004C/en
Priority to EP04821793A priority patent/EP1706700A2/en
Publication of WO2005104674A2 publication Critical patent/WO2005104674A2/en
Publication of WO2005104674A3 publication Critical patent/WO2005104674A3/en
Priority to US11/726,947 priority patent/US20080000464A1/en
Priority to US12/581,518 priority patent/US20100101400A1/en

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F42AMMUNITION; BLASTING
    • F42BEXPLOSIVE CHARGES, e.g. FOR BLASTING, FIREWORKS, AMMUNITION
    • F42B12/00Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material
    • F42B12/02Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect
    • F42B12/36Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect for dispensing materials; for producing chemical or physical reaction; for signalling ; for transmitting information
    • F42B12/40Projectiles, missiles or mines characterised by the warhead, the intended effect, or the material characterised by the warhead or the intended effect for dispensing materials; for producing chemical or physical reaction; for signalling ; for transmitting information of target-marking, i.e. impact-indicating type

Definitions

  • the present invention is directed to an improved marking projectile core, a marking projectile and method of making same.
  • Paintball has increased dramatically. Paintball is now a recognized and popular sporting activity. In one form of this game, players on two teams are each supplied with a paintball marker (paintball gun) and a number of marking projectiles, or “paintballs,” which are rounds of ammunition.
  • the terms “projectile” and “marking projectile” are used interchangeably.
  • the projectiles comprise a spherical gelatin or starch shell filled with a non-toxic, water-soluble, biodegradable paint (referred to herein "liquid dye”). Paintball markers fire these paintballs using compressed gas (e.g. C02, N2, etc.) as a propellant.
  • compressed gas e.g. C02, N2, etc.
  • liquid dye compositions used in paint balls contain a dye in conjunction with hydrophilic carriers containing a mixture of high and low molecular weight polyethylene glycols (PEG).
  • PEG polyethylene glycols
  • disadvantages associated with currently available dye compositions include tenacious or permanent staining of target fabrics, freezing and solidification of the dye composition during exposure to colder temperatures, separation and precipitation of dye composition ingredients during storage, and a thin consistency.
  • Various liquid dyes are discussed in U.S. Patent No. 6,530,962, which is incorporated by reference.
  • a marking projectile impacts a target at a high velocity, which produces an impact force upon the projectile. Projectiles are formed so that the shells do not rupture until a sufficient impact force is imparted.
  • Currently available projectiles formed from gelatin or starch shells and filled with marking liquid dye suffer various deficiencies, both in manufacture, and in use. These types of paintballs are expensive to manufacture, and may suffer breakage problems. Known projectile filled with liquid dye also suffer from accuracy problems, as the liquid dye tends to shift during flight.
  • the present invention is directed to a novel projectile core, a projectile having the novel core of the present invention, and a method of making the same.
  • a projectile core according to the present invention generally comprises a carrier mixed with a colorant, formed into a predetermined projectile core shape.
  • the projectile core is substantially firm, and retains its shape prior to impact with a target.
  • the projectile core Upon impact with a target, the projectile core at least partially disintegrates or disperses, marking the target with the color of the colorant.
  • the carrier is a fibrous, absorbent material, such material capable of absorbing liquid dye.
  • the projectile core of the present invention can then be coated or sealed to form a projectile of the present invention.
  • the carrier is a powder.
  • the powder is blended with a colorant, and formed into a predetermined projectile shape.
  • An outer coating may be applied to the projectile core, forming the outer coating, and finishing the projectile.
  • the outer coating may be applied by any acceptable method, including, but not limited to spraying, vat immersion, etc.
  • Figure 1 is a diagrammatic cross sectional view of a projectile core of the present invention.
  • Figure 2 is a diagrammatic representation of the combination of materials to form a mixture used in a core of the present invention.
  • Figure 3 is a diagrammatic representation the addition of a carrier to a colorant.
  • Figure 4 is a diagrammatic cross sectional view of a molding process for forming a projectile core of the present invention.
  • Figure 5 is a diagrammatic cross sectional view of an alternate molding process for forming a projectile core of the present invention.
  • Figure 6 is a diagrammatic cross sectional view of another embodiment of a projectile core of the present invention.
  • Figure 7 is a diagrammatic cross sectional view of a further alternate molding process for forming a projectile core of the present invention.
  • Figure 8 is a diagrammatic cross sectional view of another embodiment of a projectile core of the present invention.
  • Figure 9 is a diagrammatic cross sectional view of another embodiment of a projectile core of the present invention.
  • Figure 10 is a diagrammatic cross sectional view of a curing process for forming a projectile core of the present invention.
  • Figure 11 is a diagrammatic cross sectional view of an embodiment of a projectile of the present invention.
  • Figure 12 is a schematic representation of a mixture of materials to form an alternate embodiment of a projectile core of the present invention.
  • Figure 13 is a diagrammatic cross sectional view of an alternate embodiment of a projectile core of the present invention.
  • Figure 14 is a diagrammatic cross sectional view of a molding process to form an alternate embodiment of a projectile core of the present invention.
  • Figure 15 is a diagrammatic cross sectional view of a molding process to form an alternate embodiment of a projectile core of the present invention.
  • Figure 16 is a diagrammatic cross sectional view of another embodiment of a projectile of the present invention.
  • Figure 1 depicts a projectile core 10, having a carrier 12.
  • the carrier comprises an absorbent material.
  • the absorbent material is preferably a fibrous, absorbent material, such as a cellulosic material, or an absorbent powder, each of which is discussed in detail below.
  • the projectile core 10 further comprises a colorant 14 for marking a target. As shown by Figure 2, the carrier 12 and colorant 14 are mixed or otherwise blended to form a core mixture 16.
  • a novel aspect of the projectile core 10 of the present invention is that the carrier 12 or core mixture 16 is shaped into a predetermined core shape prior to coating or sealing.
  • the predetermined core shape refers to the overall shape of the projectile core 10.
  • the predetermined core shape is formed prior to any optional coating or sealing of the projectile core 10.
  • the projectile core 10, once formed into the predetermined core shape is at least partially cured, either with ambient air, heat, or cold, until it is substantially firm.
  • the term "substantially firm” is used to designate a state whereby the projectile core 10 generally retains its predetermined core shape prior to impact with a target.
  • the predetermined core shape is not defined by, or otherwise a function of, any outer coating, capsule, or shell.
  • the projectile core 10 of the present invention may be adapted to support a coating, wherein the coating conforms to the predetermined core shape.
  • the predetermined core shape is preferably a sphere, such as for use in the sport of paintball. Upon impact, at least a portion of the projectile core 10 disperses or disintegrates, marking the color of the selected colorant 14 on the target.
  • the carrier 12 is a cellulosic material, capable of absorbing a colorant 14.
  • the colorant 14 may be a pigment, a liquid dye, a powder dye, a water soluble dye, a permanent dye, an infra red dye, an ultra violet dye, a "disappearing" ink or dye that initially marks and fades over a period of time, or a dye that glows in the dark, and any equivalents or substitutes.
  • the combination of the carrier 12 and the colorant 14 is referred to herein as the core mixture 16.
  • the carrier 12 or core mixture 16 is formed into a predetermined core shape forming a projectile core, which preferably has a spherical shape, and is sized and weighted for use as a marking projectile.
  • a marking projectile or “projectile” are used interchangeably, and describe a projectile which at least partially disintegrates or disperses and marks a target upon impact, being useful in the sport of paintball, as well as by military or law enforcement training.
  • the projectile core 10 comprises a colorant 14 for marking a target.
  • the colorant 14 in a paintball is a liquid dye that is non-toxic and non-caustic, water-soluble and usually formed from biodegradable or naturally-occurring ingredients.
  • Colorant 14, as used herein, refers to any of the known liquid dyes, such as food colorings, or other water- soluble, non-toxic marking liquids, sometimes referred to as "paint," used in the sport of paintball, or in connection with non-lethal rupturable marking projectiles such as those used by law enforcement such as, for example, training.
  • Food dyes (pigments) and polyethylene glycol may be used.
  • the liquid dye may also be a mixture of propylene glycol, sorbitol, color dye and wax.
  • cellulosic material is recovered as agricultural waste, which can also be termed biomass.
  • the terms "cellulosic material” and “cellulosic materials” refer to any of the fibrous materials containing cellulose, including materials characterized as lignocellulose or hemicellulose.
  • the cellulosic material can be any suitable fibrous substance or substances that will absorb the colorant 14.
  • typical cellulosic materials for use in the present invention include, but are not limited to, agricultural fiber such as rice straw, wheat straw, or combinations thereof.
  • Cellulosic materials include the biomass of aspen chips, sawmill and logging residues, wheat straw, wheat chaff, barley straw, rice straw, corn stover, sugarcane bagasse, kochia stems, and the like. However, no specific source of cellulosic material is required. Preferably, the cellulosic material absorbs a liquid dye.
  • nonwood plants which produce fibers having absorbent properties. These nonwood plants are often referred to in the art as "agricultural residues” or “fiber crops”. Examples of plants for each of these categories include agricultural residues fiber crops including: wheat straw, kenaf, rice straw, industrial hemp, corn stalks, sisal bagasse (sugar cane), textile flax straw, rye grass, straw, Hesperaloe, seed flax, straw flax, and straw.
  • agricultural residues fiber crops including: wheat straw, kenaf, rice straw, industrial hemp, corn stalks, sisal bagasse (sugar cane), textile flax straw, rye grass, straw, Hesperaloe, seed flax, straw flax, and straw.
  • the cellulosic material usable for the present invention may be a lignocellulose material selected from plant fiber materials including wood pieces, wood meals, wood fibers, wood chips, veneer scraps, plywood scraps, waste-paper, pulps, rice straw, rice hulls, kaoliang straw, bagasse, bamboo, and wheat straw.
  • the preferred cellulosic material is rice straw.
  • Rice straw is a fibrous composition, capable of absorbing liquid such as the liquid dye necessary for use in the sport of paintball. Rice straw is resistant to bacterial decomposition and therefore suitable to serve as a projectile core, which will be stored and may not be used immediately.
  • cellulosic materials may be used for the carrier 12 as an alternative to rice straw, including but not limited to straws, grasses, palm waste, wheat straw, plant waste or paper mill waste, corn stover, kenaf, industrial hemp, sisal, rye grass straw, wheat straw, bagasse, hesperaloe, flax straw, non-woody fibers liberated from sugar cane, bagasse, sabai grass, banana leaves, paper mulberry (i.e., bast fiber), abaca leaves, pineapple leaves, esparto grass leaves.
  • straws grasses, palm waste, wheat straw, plant waste or paper mill waste
  • corn stover kenaf, industrial hemp, sisal, rye grass straw, wheat straw, bagasse, hesperaloe, flax straw, non-woody fibers liberated from sugar cane, bagasse, sabai grass, banana leaves, paper mulberry (i.e., bast fiber), abaca leaves, pineapple leaves, esparto grass
  • Lignocellulose refers to plant materials made up primarily of lignin, cellulose, and hemicellulose.
  • suitable materials are wood, wood flour, wheat straw, rice straw, corn straw, hemp, dried grass, rice hulls, bagasse, flax, stalks of other plants such as soya, cotton including recycled and shredded cotton fabrics, shredded regenerated cellulose fibers and fabrics such as rayon, shredded paper, etc.
  • recycled fibers which may contain any of the above cellulosic materials in different percentages can be used in the present invention.
  • the terms “carrier” includes any of the above-listed cellulosic materials or combinations thereof, as well as any other fibrous, absorbent materials having properties desirous for the formation of a projectile core as described herein.
  • Rice straw is used as the primary example of a cellulosic material used for the carrier.
  • the projectile core of the present invention is formed from materials that are capable of carbonizing, such as by heating or partial burning. Those materials which carbonize and thicken when exposed to heat are preferred, as described in greater detail below.
  • the carrier 12 is introduced to a colorant
  • the core mixture 16 is essentially a mixture of: the carrier 12, such as the rice straw as the fibrous, absorbent material, and the colorant 14. Other materials, ingredients or additives, such as binders, surfactants, emulsifiers, or desiccants, may be incorporated into the core mixture 16 to achieve desired properties, or to increase the performance or properties of the projectile core of the present invention.
  • the carrier 12 may be ground, granulated, compacted, or otherwise pulverized prior to introduction of the colorant 14. Any method of grinding, compacting, granulating, or pulverizing the carrier 12 is acceptable.
  • the carrier 12 may also be dried to remove moisture.
  • the porosity of rice straw may be controlled by grinding and drying. It is possible to produce a core mixture 16 formed from rice straw as a carrier 12, where the void fraction is up to 80% of the volume of the core mixture 16.
  • the colorant 14 may be introduced to the carrier 12 in any acceptable method whereby an amount of colorant 14 will be absorbed by the carrier 12.
  • the colorant 14 is a liquid dye
  • an amount of liquid dye may be introduced to the carrier 12 via soaking the carrier 12 in the liquid dye, dipping the carrier 12 into the liquid dye or a liquid dye bath, spraying the liquid dye onto the carrier 12, or the liquid dye may be injected into the carrier 12, or the liquid dye may be poured into an amount of the carrier 12, thus forming the core mixture 16.
  • the core mixture 16 may be mixed or otherwise blended, such as to produce a substantially uniform distribution of color throughout the core mixture 16.
  • the projectile core 10 Upon curing the core mixture 16, the projectile core 10 comprises a substantially firm mass that retains the predetermined core shape of the projectile core 10 until impacting a target.
  • the core mixture 16 is of such a dryness that it may be formed into the substantially firm projectile core 10 without further curing.
  • the carrier 12 is ground, granulated, compacted, or pulverized, and then shaped by a mold to form the predetermined core shape of the projectile core 10, prior to the addition of the colorant 14.
  • the colorant 14 may be added to the carrier 12 prior to molding or shaping.
  • the carrier 12 or core mixture 14 is formed into the predetermined core shape and size of a projectile 18 by molds, by the use of a press, by stamping, by dies, or any other suitable means.
  • the carrier 12 may be placed between first and second mold halves 20a, 20b forming two halves of a projectile, which are brought together, capturing the carrier 12 within the mold portions 20a, 20b.
  • the projectile core 10 is made by grinding, granulating, compacting, or pulverizing the carrier 12 into a particulate, granular or powdery substance.
  • Colorant 14 such as a liquid dye, is added to the carrier 12, forming the core mixture 16.
  • Binders such as cellulose, gelatin, plasticizers, various gums, waxes, cellulose derivatives, gelatin, lignin, PVP, PVA and a complex magnesium silicate and lubricants such as metal stearates, fatty alcohols, fatty acids and/or oils, oils, butters, lipids, surfactants, starch, dextrin, sodium alginate, sodium acrylate, polyvinyl pyrrolidone, a monosaccharide or an oligosaccharide such as sucrose, lactose, or acceptable substitutes of these materials, or combinations thereof, may be added to the core mixture 16, to adjust the properties of the core mixture 16.
  • Emulsifiers may also be added to the core mixture 16.
  • the colorant 14 may be introduced to the carrier 12 before or after the carrier 12 is formed into the desired final projectile core shape, or may be introduced during each of those steps.
  • the colorant 14 may be added to granulated, ground or pulverized carrier 12 prior to shaping.
  • the colorant 14 may be introduced to the carrier 12 after the carrier 12 has been shaped.
  • the carrier 12, previously formed into the predetermined projectile core shape such as a sphere, may be introduced to colorant 14, for a selected period of time, whereby the carrier absorbs the liquid dye.
  • Any acceptable method of incorporating or otherwise introducing the colorant 14 to the carrier 12 may be used, such as spraying, dipping, or using a bath.
  • the liquid dye may be added to the carrier 12 by injecting the colorant 14 into a mold 20 during formation of the projectile core 10.
  • a projectile according to the present invention may be formed by a mold.
  • mold 20 may have mold portions 20a, 20b, each mold portion having a cavity 22 that has a contour, defining the final projectile core shape.
  • the predetermined core shape is a sphere, so that a spherical projectile 18 is formed
  • each mold portion 20a, 20b defines half of a sphere.
  • the cavities can be formed into any desired projectile shape, so that the core (and resulting projectile) need not be spherical in shape.
  • the mold portions 20a, 20b are brought together, capturing a quantity of carrier 12 or core mixture 16 ( Figure 5), within the mold 20 to form a projectile core 10.
  • the mold may then be heated, such as by an external heat source or by utilizing molds that include heating elements, to cure and harden the carrier 12 or core mixture 16 to a desired firmness.
  • the shaped projectile core 10 may be removed from the mold, and cured, such as by heating or drying, for example, by baking, heat lamps, or any other acceptable curing means.
  • the mold and core mixture 16 may also be dried by ambient air, to produce a projectile core 10 that is substantially firm.
  • the projectile core 10 may have portions, such as adjacent the inner portion 36, that remain wet or soggy, particularly where a liquid dye is used as the colorant 14.
  • the projectile core 10 of the present invention is cured so that it is substantially firm whereby it retains its overall predetermined core shape, regardless of these inner wet or soggy portions.
  • any type of mold capable of shaping the core mixture 16 may be used to produce a projectile core 10 of a predetermined core shape according to the present invention.
  • the carrier 12 or core mixture 16 in any desired state of dryness may be compacted by use of molds, presses and/or dies into the desired shape, density and size.
  • the projectile core 10 may be formed to .68 caliber, and the weight may be adjusted to between approximately 2.5g to 4g, and preferably 2.8g to 3.5g, so that a projectile 18 formed having a projectile core 10 according to the present invention operates with known paintball markers, paintball hoppers, and other equipment.
  • Figure 7 depicts an alternative method wherein a carrier 12 such as rice straw, or core mixture 16, is injected via a channel 24 into mold 26, having separable portions 26a, 26b.
  • the mold portions 26a, 26b are heated thereby drying, to any desired amount, and setting the carrier or core mixture in order to retain the shape defined by the cavity 28 of the mold 26.
  • Figures 6, 8, and 9 depict cross sections of various examples of projectiles 18 and projectile cores 10 of the present invention.
  • the application of high temperature to the outside of the projectile core may be used in order to sear, burn, carbonize, or otherwise singe the outer surface 30 of the projectile core 10, forming an outer layer 32 of the projectile core 10 that is hardened, crisp and/or brittle, in comparison to the other portions of the projectile core 10.
  • the outer layer 32 comprises the portion of the projectile core 10 adjacent the outer surface 32 that has hardened in relation to the other portions of the projectile core nearer the center 34 of the projectile core 10.
  • the thickness of the outer layer 32 may be controlled by controlling the time of exposure to heat, the carrier 12 selected, any other ingredients added to the core mixture 16, or other factors.
  • the inner portion 36 of the projectile core 10 may remain wet, moist, or soggy.
  • the outer layer 32 will disintegrate, disperse, burst and/or crack upon impact, and the inner portion 36 of the projectile core 10, which is a moist, colored mass, will hit the target producing a "splat," marking the target.
  • the core mixture 16 that has been formed into the desired shape of a projectile 18 is cured until a substantially firm projectile core 10 is formed.
  • the projectile core 10 once formed, may be cured until the projectile core 10 is essentially dry. In this case, essentially dry does not mean completely free of all moisture, but instead refers to a state where the core is no longer wet or soggy.
  • the projectile core 10 may also be cured until it reaches a chalky or powdery state throughout. Upon impact, such a projectile core 10 will at least partially disintegrate or disperse, producing a dry powder "splat" marking the target.
  • the projectile core 10 may also be heat treated such as by hot rollers 38, shown in Figure 10.
  • the projectile core 10 is turned on the hot rollers 38 for a selected time at a selected temperature, until the outer surface 30 of the projectile core 10 is singed, burned, or carbonized, forming an outer layer 32 as previously discussed.
  • the outer surface 30 of the projectile core 10 will burn, singe, bake and/or char while turned on the hot rollers 38. The longer the projectile core 10 is in contact with the hot rollers 38, the thicker the outer layer 32.
  • the projectile core 10 is turned on the hot rollers 38 until a desired outer layer 32 thickness T is achieved.
  • the core mixture 14, once formed into the desired projectile core 10 shape, is freeze dried, by rapid freezing and drying. This step removes moisture, and produces a hardened projectile core 10 impregnated with liquid dye 12.
  • the freeze dried projectile core 10 may then be subjected to heat, producing an outer layer 32 formed such as by heating, as described above.
  • the projectile core 10 may thus be considered a finished and useable projectile 18, and is therefore ready for use.
  • a projectile core 10 of the present invention need not be sealed or coated with gelatin or starch compounds, as there is no need for a coating in order to retain the shape of the projectile core 10.
  • outer coating 40 which may act as a sealant, protectant, or simply to present a finished cosmetic appearance of the projectile.
  • Gelatin compositions, starch compositions, wax compositions, or plastic compositions may be used in forming the outer coating 40.
  • outer coating 40 can be made from hydrophilic colloidal materials such as, but not limited to, gelatin, albumin, gum arabic, alginate, casein, agar or pectins, acceptable substitutes, or combinations of those materials.
  • Outer coating 40 could also be made from a synthetic organic compound such as, but not limited to, polystyrene, polypropylene, polyethylene, poloycarbonate, polyamide, polysulfane or polyvinylchloride.
  • the outer coating 40 is formed from albumin, or a mixture of albumin and other suitable materials, which is applied to the projectile core 10.
  • the outer coating 40 may be applied in any acceptable manner, such as through soaking or dipping in a bath, spraying, and/or rollers.
  • the outer coating 40 will conform to the predetermined core shape of the projectile core 10.
  • the outer coating 40 is capable of protecting the projectile core 10 until the projectile 18 is fired and impacts a target.
  • the outer coating 40 provides resistance to projectile core breakage prior to being fired from a projectile marker, and impacting a target.
  • the coated projectile 18 of the present invention can be formed having no seam to disturb the projectiles flight when fired at a target.
  • the projectile core 10 of the present invention can be controlled and manipulated in order to alter the characteristics, makeup and performance of a projectile formed utilizing the projectile core 10 of the present invention.
  • the degree the core material 12 is ground, pulverized, compacted, or granulated can be controlled to alter the particle size and/or porosity.
  • the degree the projectile core 10 is compacted during formation can be controlled in order to alter the density.
  • the carrier 12 is molded prior to the addition of colorant 14, the denser the core, the less the colorant 14 will permeate through the carrier 12.
  • the viscosity, flexibility, dampness, dryness, or other properties, of the inner portion 36 can also be controlled in order to alter the amount of amount of wet or soggy "splatter" when a target is struck with the projectile 18.
  • the amount the carrier 12 and colorant 14 are dried may also be controlled.
  • the granular size of the particles of carrier 12, such as rice straw, can be controlled to alter the absorption properties, and therefore the final weight of the projectile formed with the core of the present invention.
  • a projectile core 42 comprising a base powder material 44 as the carrier.
  • acceptable base powder materials 44 include, but are in no way limited to, calcium carbonate, chalk (calcite), zinc oxide or talc, fullers earth, kaolin, starch, gums, colloidal silica, bismuth oxychloride, titanated mica, silica, polymethylmethacrylate, micronized TEFLON, boron nitride, acrylate copolymers, aluminum silicate, aluminum starch octenylsuccinate, bentonite, calcium silicate, cellulose, corn starch, diatomaceous earth, fuller's earth, glyceryl starch, hectorite, hydrated silica, kaolin, magnesium aluminum silicate, magnesium trisilicate, maltodextrin, montmorillonite, microcrystalline cellulose, rice starch, mica, titanium dioxide, zinc laurate, zinc myristate, zinc roninate, alumina, attapulgite
  • a colorant 46 is preferably added to the base powder material 44.
  • a binder which may be a solid, semi-solid, or liquid, can also be added to the base powder material to assist in molding the material into the desired shape.
  • the base powder material 44 may have a natural color, even without the addition of a colorant.
  • the base powder material 44 may be mixed with a suitable binder, and formed into a projectile core according to the present invention.
  • the colorant may take the form of liquid dye, as discussed above, or make take the form of a pigment. For example, lake dyes, micas or pearls, iron oxides, titanium oxides, calcium carbonates, treated pigments, and mixtures thereof, may be mixed with the base powder to form a colored mixture for use as the core mixture.
  • Organic pigments include aromatic dyes such as azo, indigo, triphenylmethane, anthraquinone, and xanthine dyes which are designated as D&C and FD&C blues, browns, greens, oranges, reds, yellows and so forth.
  • Organic pigments also include insoluble metallic salts of certified color additives, lakes.
  • Inorganic pigments include iron oxides, ultramarines, chromium, chromium hydroxide colors and mixtures of these materials. All of these would be considered suitable colorants. [0077]
  • the base powder material 44 is selected so as to be compactable in its dry state.
  • the base powder material 44 could be poured into a first mold cavity and then compacted with a second mold cavity into the predetermined core shape.
  • the pressure applied by the mold compresses the base powder material 44 and any added binder or excipients, into the substantially firm projectile core.
  • an outer coating may or may not be needed.
  • the base powder material 44 (with or without added ingredients) or core mixture 52 may be mixed with a suitable binder.
  • the base powder material 44 (with or without added ingredients) or core mixture 52 may then be injected or otherwise channeled into a mold cavity where the material is formed into a predetermined core shape.
  • the base powder material 44 (with or without added ingredients) or core mixture 52 is then cured, as described above, until it is substantially firm.
  • a first method to form a projectile core 42 from a base powder material 44 utilizes a base powder material 44 that is compactable in its dry state. Any conventional molding operation can be used to form the projectile core 42.
  • the base powder material can be poured into a first mold cavity 48 and then compacted with a second mold cavity 50 to form the desired shape.
  • Another method of forming the base powder material 44 projectile core is by the preparation of a damp core mixture 52 of base powder material 44 combined with a colorant 46.
  • the core mixture 52 may be further mixed with a suitable binding agent to form a pourable, moldable core mixture 52.
  • this core mixture 52 is then injected or directed into a mold cavity 56 where the core mixture 52 forms the desired shape.
  • the molded projectile 54 ( Figure 16) is allowed to dry or cure by ambient or heated air. Alternatively, the mold can be heated to cause the mixture to set. It is also contemplated that a drying agent can be added to the core mixture 52, e.g., silica, calcium chloride, etc.
  • the projectile core formed with a base powder material 44 may be coated with an outer coating, as discussed above.
  • a cellulosic material may comprise a powdery substance.
  • "powder” as used herein therefore encompasses the cellulosic materials that have been dried and ground into powder, previously discussed, as well the base powder material discussed.
  • the projectile core and projectile described herein are most preferably intended for use as a paintball in the sport of paintball. Marking projectiles such as paintballs must maintain their shape and integrity during firing from, for example, compressed gas powered paintball markers. Such paintballs then must at least partially disintegrate or disperse upon impact with a target at impact velocity, namely, the speed at which the paintball strikes a target such as a human paintball sport player equipped with the appropriate protective gear.
  • Known paintballs that are essentially capsules filled with liquid must break, rupture, or other disperse the liquid dye upon impact at ranges of between 25 to 300 feet, with the ideal range being between 50-100 feet. Accordingly, it is appreciated that the projectile core and projectile of the present invention are preferably formed to meet the parameters necessary for use in the sport of paintball.
  • Paintball markers may have a muzzle speed of between approximately 175 to 500 fps, with the preferred muzzle velocity being approximately between 250-350 fps.
  • the velocity at which a paintball marker fires a paintball from its barrel is sometimes limited to 300 fps or less to protect the paintball sport players from harm.
  • the impact velocity of a paintball is generally less than the muzzle velocity, but greater than 50 fps to be effective.
  • the projectile core and projectile of the present invention are preferably formed to retain the predetermined core shape under the conditions of the muzzle velocities described herein, and at least partially disintegrate or disperse upon impacting a target at the described impact velocity, in order to present a colored "mark” or “splat” comparable to the mark made upon impact of known liquid dye filled paintballs.
  • the new projectile core and/or projectile can be made to hold a favorable shape for projectile flight more closely than existing projectiles because it is shaped by the projectile core, and not the shell or coating.
  • An existing projectile is an elastic material filled with a liquid, that is deformable. This means that during shipment and storage an existing projectile can and will change shape. The change in dimension will adversely effect loading and flight of the ball. Breakage is also an issue.
  • a projectile made according to the present invention is substantially firm and will resist deformation under transport and storage. The substantially firm shape is produced during manufacturing and can be formed in a consistent way with existing machinery.
  • Another benefit of the present invention is the ability to control carrier characteristics, core mixture characteristics, and projectile shape.
  • fibrous materials can be added to the mixture of solids. By changing the type, length, thickness, weave and/or amount of these fibers the strength of the projectile and resistance to breakage can be controlled. The shape of the projectile can also be controlled using similar methods.
  • the present invention is not limited to the particular embodiments shown and described herein, but that various changes and modifications may be made without departing from the scope and spirit of the invention.

Abstract

A projectile (18) core is provided formed from a carrier and a colorant. The carrier and colorant are mixed into a core mixture (16), which is formed into a predetermined core shape. The core mixture (16) is cured until substantially firm, such as by drying, heating or freezing. An outer layer (32) may be formed adjacent the surface of the projectile (18) core by heating. An outer coating may also be applied to the projectile core.

Description

Express Mail Label No. EV441640993US
[0001] PROJECTILE, PROJECTILE CORE, AND METHOD OF MAKING
[0002] FIELD OF THE INVENTION
[0003] The present invention is directed to an improved marking projectile core, a marking projectile and method of making same.
[0004] BACKGROUND
[0005] In recent years, the popularity of the combat game known as
"Paintball" has increased dramatically. Paintball is now a recognized and popular sporting activity. In one form of this game, players on two teams are each supplied with a paintball marker (paintball gun) and a number of marking projectiles, or "paintballs," which are rounds of ammunition. The terms "projectile" and "marking projectile" are used interchangeably. The projectiles comprise a spherical gelatin or starch shell filled with a non-toxic, water-soluble, biodegradable paint (referred to herein "liquid dye"). Paintball markers fire these paintballs using compressed gas (e.g. C02, N2, etc.) as a propellant. When a player is hit with a paintball, the paintball ruptures, "painting" or "marking" the target providing dramatic evidence of the hit, without injuring the player.
[0006] Soft and hard capsules, shells or casings have been used in the sports and leisure fields, as well as in law enforcement and military training, with liquid dye formulations within projectiles adapted to rupture upon impact with an intended target. Generally, such projectiles have the physical properties in which the casing is hard and impact resistant enough to survive normal loading and firing forces, while at the same time adapted to rupture and release the liquid dye composition upon high velocity contact with a target surface. Thus, known marking projectiles are essentially a capsule or shell filled with a liquid. The capsule or shell defines the shape of the projectile, and the fill material, which is a liquid or semi-solid, is shapeless or amorphous, and moves within the capsule or shell. [0007] Some currently available liquid dye compositions used in paint balls contain a dye in conjunction with hydrophilic carriers containing a mixture of high and low molecular weight polyethylene glycols (PEG). Among the disadvantages associated with currently available dye compositions include tenacious or permanent staining of target fabrics, freezing and solidification of the dye composition during exposure to colder temperatures, separation and precipitation of dye composition ingredients during storage, and a thin consistency. Various liquid dyes are discussed in U.S. Patent No. 6,530,962, which is incorporated by reference.
[0008] A marking projectile impacts a target at a high velocity, which produces an impact force upon the projectile. Projectiles are formed so that the shells do not rupture until a sufficient impact force is imparted. [0009] Currently available projectiles formed from gelatin or starch shells and filled with marking liquid dye suffer various deficiencies, both in manufacture, and in use. These types of paintballs are expensive to manufacture, and may suffer breakage problems. Known projectile filled with liquid dye also suffer from accuracy problems, as the liquid dye tends to shift during flight.
[0010] While gelatin capsule or starch shell production may be expensive and time consuming, there currently exists an abundance of agricultural biomass, which may be defined as the biodegradable fraction of products, waste and residues from agriculture, or as plant material processing waste. Various types of biomass are discussed in U.S. Patent No. 5,171,592, which is incorporated herein by reference. In particular, there is an abundance of cellulosic fibrous material produced as a waste byproduct of agriculture. For example, rice straw is produced throughout the world as a byproduct of rice cultivation. The options for the disposition of rice straw are limited by the great bulk of material, slow degradation in the soil, harboring of rice stem diseases, and high mineral content. Fields must be cleared of rice straw to make way for the next crop. Accordingly, alternate uses are sought for rice straw and other biomass. [0011] Many pigments, powders, emulsifiers and binders are also freely available and inexpensive, and used in many industries. Powders are useful for their absorbent properties and their compactibility, and pigments are useful for their colorant properties.
[0012] There exists a need for improved technology relating to marking projectiles.
[0013] In particular, there is a need to improve the attributes of projectiles, by providing a projectile that is efficient to manufacture, low cost, and safe to the environment.
[0014] There is yet a further need for a projectile that is formed other than as a liquid filled capsule.
[0015] In addition, there exists the need for a paintball formed from freely available materials that may be acquired and processed at low cost.
[0016] SUMMARY OF THE INVENTION
[0017] The present invention is directed to a novel projectile core, a projectile having the novel core of the present invention, and a method of making the same.
[0018] A projectile core according to the present invention generally comprises a carrier mixed with a colorant, formed into a predetermined projectile core shape. The projectile core is substantially firm, and retains its shape prior to impact with a target. Upon impact with a target, the projectile core at least partially disintegrates or disperses, marking the target with the color of the colorant. In a preferred embodiment, the carrier is a fibrous, absorbent material, such material capable of absorbing liquid dye. The projectile core of the present invention can then be coated or sealed to form a projectile of the present invention.
[0019] In another embodiment of the present invention, the carrier is a powder. The powder is blended with a colorant, and formed into a predetermined projectile shape.
[0020] An outer coating may be applied to the projectile core, forming the outer coating, and finishing the projectile. The outer coating may be applied by any acceptable method, including, but not limited to spraying, vat immersion, etc.
[0021] BRIEF DESCRIPTION OF THE DRAWINGS
[0022] Figure 1 is a diagrammatic cross sectional view of a projectile core of the present invention.
[0023] Figure 2 is a diagrammatic representation of the combination of materials to form a mixture used in a core of the present invention.
[0024] Figure 3 is a diagrammatic representation the addition of a carrier to a colorant.
[0025] Figure 4 is a diagrammatic cross sectional view of a molding process for forming a projectile core of the present invention.
[0026] Figure 5 is a diagrammatic cross sectional view of an alternate molding process for forming a projectile core of the present invention.
[0027] Figure 6 is a diagrammatic cross sectional view of another embodiment of a projectile core of the present invention.
[0028] Figure 7 is a diagrammatic cross sectional view of a further alternate molding process for forming a projectile core of the present invention.
[0029] Figure 8 is a diagrammatic cross sectional view of another embodiment of a projectile core of the present invention.
[0030] Figure 9 is a diagrammatic cross sectional view of another embodiment of a projectile core of the present invention.
[0031] Figure 10 is a diagrammatic cross sectional view of a curing process for forming a projectile core of the present invention.
[0032] Figure 11 is a diagrammatic cross sectional view of an embodiment of a projectile of the present invention.
[0033] Figure 12 is a schematic representation of a mixture of materials to form an alternate embodiment of a projectile core of the present invention.
[0034] Figure 13 is a diagrammatic cross sectional view of an alternate embodiment of a projectile core of the present invention. [0035] Figure 14 is a diagrammatic cross sectional view of a molding process to form an alternate embodiment of a projectile core of the present invention.
[0036] Figure 15 is a diagrammatic cross sectional view of a molding process to form an alternate embodiment of a projectile core of the present invention.
[0037] Figure 16 is a diagrammatic cross sectional view of another embodiment of a projectile of the present invention.
[0038] DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT(S) [0039] Referring to the figures wherein like elements are represented by like numerals, Figure 1 depicts a projectile core 10, having a carrier 12. In a preferred embodiment, the carrier comprises an absorbent material. The absorbent material is preferably a fibrous, absorbent material, such as a cellulosic material, or an absorbent powder, each of which is discussed in detail below. The projectile core 10 further comprises a colorant 14 for marking a target. As shown by Figure 2, the carrier 12 and colorant 14 are mixed or otherwise blended to form a core mixture 16.
[0040] A novel aspect of the projectile core 10 of the present invention, is that the carrier 12 or core mixture 16 is shaped into a predetermined core shape prior to coating or sealing. As used herein, the predetermined core shape refers to the overall shape of the projectile core 10. The predetermined core shape is formed prior to any optional coating or sealing of the projectile core 10. The projectile core 10, once formed into the predetermined core shape, is at least partially cured, either with ambient air, heat, or cold, until it is substantially firm. As used herein, the term "substantially firm" is used to designate a state whereby the projectile core 10 generally retains its predetermined core shape prior to impact with a target. The predetermined core shape is not defined by, or otherwise a function of, any outer coating, capsule, or shell. The projectile core 10 of the present invention may be adapted to support a coating, wherein the coating conforms to the predetermined core shape. The predetermined core shape is preferably a sphere, such as for use in the sport of paintball. Upon impact, at least a portion of the projectile core 10 disperses or disintegrates, marking the color of the selected colorant 14 on the target.
[0041] FIBROUS, ABSORBENT MATERIAL
[0042] In one embodiment, the carrier 12 is a cellulosic material, capable of absorbing a colorant 14. The colorant 14 may be a pigment, a liquid dye, a powder dye, a water soluble dye, a permanent dye, an infra red dye, an ultra violet dye, a "disappearing" ink or dye that initially marks and fades over a period of time, or a dye that glows in the dark, and any equivalents or substitutes. The combination of the carrier 12 and the colorant 14 is referred to herein as the core mixture 16. The carrier 12 or core mixture 16 is formed into a predetermined core shape forming a projectile core, which preferably has a spherical shape, and is sized and weighted for use as a marking projectile. As used herein, the term "marking projectile" or "projectile" are used interchangeably, and describe a projectile which at least partially disintegrates or disperses and marks a target upon impact, being useful in the sport of paintball, as well as by military or law enforcement training. [0043] The projectile core 10 comprises a colorant 14 for marking a target. The colorant 14 in a paintball, by way of example, is a liquid dye that is non-toxic and non-caustic, water-soluble and usually formed from biodegradable or naturally-occurring ingredients. Colorant 14, as used herein, refers to any of the known liquid dyes, such as food colorings, or other water- soluble, non-toxic marking liquids, sometimes referred to as "paint," used in the sport of paintball, or in connection with non-lethal rupturable marking projectiles such as those used by law enforcement such as, for example, training. Food dyes (pigments) and polyethylene glycol, may be used. The liquid dye may also be a mixture of propylene glycol, sorbitol, color dye and wax.
[0044] Certain cellulosic material is recovered as agricultural waste, which can also be termed biomass. As used herein, the terms "cellulosic material" and "cellulosic materials" refer to any of the fibrous materials containing cellulose, including materials characterized as lignocellulose or hemicellulose. The cellulosic material can be any suitable fibrous substance or substances that will absorb the colorant 14. For example, typical cellulosic materials for use in the present invention include, but are not limited to, agricultural fiber such as rice straw, wheat straw, or combinations thereof. Cellulosic materials include the biomass of aspen chips, sawmill and logging residues, wheat straw, wheat chaff, barley straw, rice straw, corn stover, sugarcane bagasse, kochia stems, and the like. However, no specific source of cellulosic material is required. Preferably, the cellulosic material absorbs a liquid dye.
[0045] There are a variety of nonwood plants which produce fibers having absorbent properties. These nonwood plants are often referred to in the art as "agricultural residues" or "fiber crops". Examples of plants for each of these categories include agricultural residues fiber crops including: wheat straw, kenaf, rice straw, industrial hemp, corn stalks, sisal bagasse (sugar cane), textile flax straw, rye grass, straw, Hesperaloe, seed flax, straw flax, and straw.
[0046] The cellulosic material usable for the present invention may be a lignocellulose material selected from plant fiber materials including wood pieces, wood meals, wood fibers, wood chips, veneer scraps, plywood scraps, waste-paper, pulps, rice straw, rice hulls, kaoliang straw, bagasse, bamboo, and wheat straw.
[0047] The preferred cellulosic material is rice straw. Rice straw is a fibrous composition, capable of absorbing liquid such as the liquid dye necessary for use in the sport of paintball. Rice straw is resistant to bacterial decomposition and therefore suitable to serve as a projectile core, which will be stored and may not be used immediately.
[0048] Other cellulosic materials may be used for the carrier 12 as an alternative to rice straw, including but not limited to straws, grasses, palm waste, wheat straw, plant waste or paper mill waste, corn stover, kenaf, industrial hemp, sisal, rye grass straw, wheat straw, bagasse, hesperaloe, flax straw, non-woody fibers liberated from sugar cane, bagasse, sabai grass, banana leaves, paper mulberry (i.e., bast fiber), abaca leaves, pineapple leaves, esparto grass leaves.
[0049] Lignocellulose refers to plant materials made up primarily of lignin, cellulose, and hemicellulose. Examples of suitable materials are wood, wood flour, wheat straw, rice straw, corn straw, hemp, dried grass, rice hulls, bagasse, flax, stalks of other plants such as soya, cotton including recycled and shredded cotton fabrics, shredded regenerated cellulose fibers and fabrics such as rayon, shredded paper, etc. Also, recycled fibers which may contain any of the above cellulosic materials in different percentages can be used in the present invention.
[0050] All of the above materials are referred to herein, individually or in combination, as "cellulosic material" or "cellulosic materials." As used herein, the terms "carrier" includes any of the above-listed cellulosic materials or combinations thereof, as well as any other fibrous, absorbent materials having properties desirous for the formation of a projectile core as described herein. Rice straw is used as the primary example of a cellulosic material used for the carrier. In one embodiment, the projectile core of the present invention is formed from materials that are capable of carbonizing, such as by heating or partial burning. Those materials which carbonize and thicken when exposed to heat are preferred, as described in greater detail below. [0051] As shown in Figure 3, the carrier 12 is introduced to a colorant
14, which is absorbed by the carrier 12. The core mixture 16 is essentially a mixture of: the carrier 12, such as the rice straw as the fibrous, absorbent material, and the colorant 14. Other materials, ingredients or additives, such as binders, surfactants, emulsifiers, or desiccants, may be incorporated into the core mixture 16 to achieve desired properties, or to increase the performance or properties of the projectile core of the present invention. [0052] The carrier 12 may be ground, granulated, compacted, or otherwise pulverized prior to introduction of the colorant 14. Any method of grinding, compacting, granulating, or pulverizing the carrier 12 is acceptable. The carrier 12 may also be dried to remove moisture. By way of example, the porosity of rice straw may be controlled by grinding and drying. It is possible to produce a core mixture 16 formed from rice straw as a carrier 12, where the void fraction is up to 80% of the volume of the core mixture 16. [0053] The colorant 14 may be introduced to the carrier 12 in any acceptable method whereby an amount of colorant 14 will be absorbed by the carrier 12. For example, where the colorant 14 is a liquid dye, an amount of liquid dye may be introduced to the carrier 12 via soaking the carrier 12 in the liquid dye, dipping the carrier 12 into the liquid dye or a liquid dye bath, spraying the liquid dye onto the carrier 12, or the liquid dye may be injected into the carrier 12, or the liquid dye may be poured into an amount of the carrier 12, thus forming the core mixture 16. The core mixture 16 may be mixed or otherwise blended, such as to produce a substantially uniform distribution of color throughout the core mixture 16. Mixing the carrier 12 and a liquid dye, or other liquid colorant 14, produces a core mixture 16 which is a semi-solid or slurry, that may be molded, shaped, stamped, compacted, or otherwise formed into a predetermined core shape for a projectile core 10 and/or a projectile 18, as described in further detail below. Upon curing the core mixture 16, the projectile core 10 comprises a substantially firm mass that retains the predetermined core shape of the projectile core 10 until impacting a target. In an alternate embodiment, the core mixture 16 is of such a dryness that it may be formed into the substantially firm projectile core 10 without further curing.
[0054] In one embodiment, the carrier 12 is ground, granulated, compacted, or pulverized, and then shaped by a mold to form the predetermined core shape of the projectile core 10, prior to the addition of the colorant 14. Alternately, the colorant 14 may be added to the carrier 12 prior to molding or shaping. The carrier 12 or core mixture 14 is formed into the predetermined core shape and size of a projectile 18 by molds, by the use of a press, by stamping, by dies, or any other suitable means. As shown by Figure 4, the carrier 12 may be placed between first and second mold halves 20a, 20b forming two halves of a projectile, which are brought together, capturing the carrier 12 within the mold portions 20a, 20b. [0055] In one embodiment of the invention, the projectile core 10 is made by grinding, granulating, compacting, or pulverizing the carrier 12 into a particulate, granular or powdery substance. Colorant 14, such as a liquid dye, is added to the carrier 12, forming the core mixture 16. Binders such as cellulose, gelatin, plasticizers, various gums, waxes, cellulose derivatives, gelatin, lignin, PVP, PVA and a complex magnesium silicate and lubricants such as metal stearates, fatty alcohols, fatty acids and/or oils, oils, butters, lipids, surfactants, starch, dextrin, sodium alginate, sodium acrylate, polyvinyl pyrrolidone, a monosaccharide or an oligosaccharide such as sucrose, lactose, or acceptable substitutes of these materials, or combinations thereof, may be added to the core mixture 16, to adjust the properties of the core mixture 16. Emulsifiers may also be added to the core mixture 16. [0056] It is appreciated that the colorant 14 may be introduced to the carrier 12 before or after the carrier 12 is formed into the desired final projectile core shape, or may be introduced during each of those steps. Thus, as discussed, the colorant 14 may be added to granulated, ground or pulverized carrier 12 prior to shaping. Alternately, the colorant 14 may be introduced to the carrier 12 after the carrier 12 has been shaped. The carrier 12, previously formed into the predetermined projectile core shape such as a sphere, may be introduced to colorant 14, for a selected period of time, whereby the carrier absorbs the liquid dye. Any acceptable method of incorporating or otherwise introducing the colorant 14 to the carrier 12 may be used, such as spraying, dipping, or using a bath. Furthermore, the liquid dye may be added to the carrier 12 by injecting the colorant 14 into a mold 20 during formation of the projectile core 10.
[0057] By way of example, a projectile according to the present invention may be formed by a mold. In this example, mold 20 may have mold portions 20a, 20b, each mold portion having a cavity 22 that has a contour, defining the final projectile core shape. In the case where the predetermined core shape is a sphere, so that a spherical projectile 18 is formed, each mold portion 20a, 20b defines half of a sphere. However, it should be readily apparent that the cavities can be formed into any desired projectile shape, so that the core (and resulting projectile) need not be spherical in shape.
[0058] The mold portions 20a, 20b are brought together, capturing a quantity of carrier 12 or core mixture 16 (Figure 5), within the mold 20 to form a projectile core 10. The mold may then be heated, such as by an external heat source or by utilizing molds that include heating elements, to cure and harden the carrier 12 or core mixture 16 to a desired firmness. Alternately, the shaped projectile core 10 may be removed from the mold, and cured, such as by heating or drying, for example, by baking, heat lamps, or any other acceptable curing means. The mold and core mixture 16 may also be dried by ambient air, to produce a projectile core 10 that is substantially firm. It is appreciated that the projectile core 10 may have portions, such as adjacent the inner portion 36, that remain wet or soggy, particularly where a liquid dye is used as the colorant 14. However, the projectile core 10 of the present invention is cured so that it is substantially firm whereby it retains its overall predetermined core shape, regardless of these inner wet or soggy portions. [0059] It is appreciated that any type of mold capable of shaping the core mixture 16 may be used to produce a projectile core 10 of a predetermined core shape according to the present invention. The carrier 12 or core mixture 16 in any desired state of dryness may be compacted by use of molds, presses and/or dies into the desired shape, density and size.
[0060] There may be standard industry sizes that are used to determine the size, weight, or other dimensions of the projectile core 10. Generally, marking projectiles in the sport of paintball, or paintballs, come in sizes ranging from .40-.75 caliber (inches diameter), with the common caliber being .68 (0.68 inches diameter), or an approximation of .68 caliber. An average paintball weighs between approximately 2.5g and 4g. Accordingly, the projectile core 10 may be formed to .68 caliber, and the weight may be adjusted to between approximately 2.5g to 4g, and preferably 2.8g to 3.5g, so that a projectile 18 formed having a projectile core 10 according to the present invention operates with known paintball markers, paintball hoppers, and other equipment. [0061] Figure 7 depicts an alternative method wherein a carrier 12 such as rice straw, or core mixture 16, is injected via a channel 24 into mold 26, having separable portions 26a, 26b. The mold portions 26a, 26b are heated thereby drying, to any desired amount, and setting the carrier or core mixture in order to retain the shape defined by the cavity 28 of the mold 26. [0062] Figures 6, 8, and 9 depict cross sections of various examples of projectiles 18 and projectile cores 10 of the present invention. In addition to any other curing, the application of high temperature to the outside of the projectile core may be used in order to sear, burn, carbonize, or otherwise singe the outer surface 30 of the projectile core 10, forming an outer layer 32 of the projectile core 10 that is hardened, crisp and/or brittle, in comparison to the other portions of the projectile core 10. The outer layer 32 comprises the portion of the projectile core 10 adjacent the outer surface 32 that has hardened in relation to the other portions of the projectile core nearer the center 34 of the projectile core 10. The thickness of the outer layer 32 may be controlled by controlling the time of exposure to heat, the carrier 12 selected, any other ingredients added to the core mixture 16, or other factors. [0063] In one embodiment, depicted in Figure 9, where high temperature is applied to the outer surface 30 and an outer layer 32 is formed, the inner portion 36 of the projectile core 10 may remain wet, moist, or soggy. Thus, when a projectile 18 formed having such a projectile core 10 is shot from a projectile marker and impacts a target, the outer layer 32 will disintegrate, disperse, burst and/or crack upon impact, and the inner portion 36 of the projectile core 10, which is a moist, colored mass, will hit the target producing a "splat," marking the target.
[0064] As shown in Figure 8, the core mixture 16 that has been formed into the desired shape of a projectile 18 is cured until a substantially firm projectile core 10 is formed. In another embodiment of the present invention, the projectile core 10, once formed, may be cured until the projectile core 10 is essentially dry. In this case, essentially dry does not mean completely free of all moisture, but instead refers to a state where the core is no longer wet or soggy. The projectile core 10 may also be cured until it reaches a chalky or powdery state throughout. Upon impact, such a projectile core 10 will at least partially disintegrate or disperse, producing a dry powder "splat" marking the target.
[0065] The projectile core 10 may also be heat treated such as by hot rollers 38, shown in Figure 10. The projectile core 10 is turned on the hot rollers 38 for a selected time at a selected temperature, until the outer surface 30 of the projectile core 10 is singed, burned, or carbonized, forming an outer layer 32 as previously discussed. The outer surface 30 of the projectile core 10 will burn, singe, bake and/or char while turned on the hot rollers 38. The longer the projectile core 10 is in contact with the hot rollers 38, the thicker the outer layer 32. The projectile core 10 is turned on the hot rollers 38 until a desired outer layer 32 thickness T is achieved.
[0066] In an alternate embodiment, the core mixture 14, once formed into the desired projectile core 10 shape, is freeze dried, by rapid freezing and drying. This step removes moisture, and produces a hardened projectile core 10 impregnated with liquid dye 12. The freeze dried projectile core 10 may then be subjected to heat, producing an outer layer 32 formed such as by heating, as described above.
[0067] It is appreciated that, once the outer layer 32 has been formed, the projectile core 10 may thus be considered a finished and useable projectile 18, and is therefore ready for use. Thus, a projectile core 10 of the present invention need not be sealed or coated with gelatin or starch compounds, as there is no need for a coating in order to retain the shape of the projectile core 10.
[0068] However, it may be desirable to coat the projectile core 10, as shown in Figure 11, with an outer coating 40, which may act as a sealant, protectant, or simply to present a finished cosmetic appearance of the projectile. Gelatin compositions, starch compositions, wax compositions, or plastic compositions may be used in forming the outer coating 40. For example, outer coating 40 can be made from hydrophilic colloidal materials such as, but not limited to, gelatin, albumin, gum arabic, alginate, casein, agar or pectins, acceptable substitutes, or combinations of those materials. Outer coating 40 could also be made from a synthetic organic compound such as, but not limited to, polystyrene, polypropylene, polyethylene, poloycarbonate, polyamide, polysulfane or polyvinylchloride.
[0069] Preferably, the outer coating 40 is formed from albumin, or a mixture of albumin and other suitable materials, which is applied to the projectile core 10. The outer coating 40 may be applied in any acceptable manner, such as through soaking or dipping in a bath, spraying, and/or rollers. The outer coating 40 will conform to the predetermined core shape of the projectile core 10.
[0070] The outer coating 40 is capable of protecting the projectile core 10 until the projectile 18 is fired and impacts a target. The outer coating 40 provides resistance to projectile core breakage prior to being fired from a projectile marker, and impacting a target. Unlike known projectiles formed as the joining of two gelatin or starch sphere halves, the coated projectile 18 of the present invention can be formed having no seam to disturb the projectiles flight when fired at a target.
[0071] Several properties of the projectile core 10 of the present invention can be controlled and manipulated in order to alter the characteristics, makeup and performance of a projectile formed utilizing the projectile core 10 of the present invention. For example, the degree the core material 12 is ground, pulverized, compacted, or granulated, can be controlled to alter the particle size and/or porosity. The degree the projectile core 10 is compacted during formation can be controlled in order to alter the density. Where the carrier 12 is molded prior to the addition of colorant 14, the denser the core, the less the colorant 14 will permeate through the carrier 12. The viscosity, flexibility, dampness, dryness, or other properties, of the inner portion 36 can also be controlled in order to alter the amount of amount of wet or soggy "splatter" when a target is struck with the projectile 18. The amount the carrier 12 and colorant 14 are dried may also be controlled. The granular size of the particles of carrier 12, such as rice straw, can be controlled to alter the absorption properties, and therefore the final weight of the projectile formed with the core of the present invention. [0072] Because of the various properties that can be easily and efficiently controlled when making a projectile core of the present invention, it is appreciated that a projectile formed according to the present invention can be of any size and weight required by a projectile marker.
[0073] POWDER CORE
[0074] In a further embodiment of the present invention, Figures 12 and
13 depict a projectile core 42 comprising a base powder material 44 as the carrier. Examples of acceptable base powder materials 44 include, but are in no way limited to, calcium carbonate, chalk (calcite), zinc oxide or talc, fullers earth, kaolin, starch, gums, colloidal silica, bismuth oxychloride, titanated mica, silica, polymethylmethacrylate, micronized TEFLON, boron nitride, acrylate copolymers, aluminum silicate, aluminum starch octenylsuccinate, bentonite, calcium silicate, cellulose, corn starch, diatomaceous earth, fuller's earth, glyceryl starch, hectorite, hydrated silica, kaolin, magnesium aluminum silicate, magnesium trisilicate, maltodextrin, montmorillonite, microcrystalline cellulose, rice starch, mica, titanium dioxide, zinc laurate, zinc myristate, zinc roninate, alumina, attapulgite, calcium silicate, dextran, nylon, silica silylate, silk powder, nylon spheres, ceramic spheres, synthetic polymer powders, powdered natural organic compounds such as ground solid algaes, encapsulated and unencapsulated grain starches, mixtures or combinations of any of these materials, or acceptable substitutes. The base powder material 44 may have absorbent properties, adsorbent properties, or combinations of each of these properties.
[0075] A colorant 46 is preferably added to the base powder material 44.
A binder which may be a solid, semi-solid, or liquid, can also be added to the base powder material to assist in molding the material into the desired shape. In some cases, it is appreciated that the base powder material 44 may have a natural color, even without the addition of a colorant. In that case, the base powder material 44 may be mixed with a suitable binder, and formed into a projectile core according to the present invention. [0076] The colorant may take the form of liquid dye, as discussed above, or make take the form of a pigment. For example, lake dyes, micas or pearls, iron oxides, titanium oxides, calcium carbonates, treated pigments, and mixtures thereof, may be mixed with the base powder to form a colored mixture for use as the core mixture. Organic pigments include aromatic dyes such as azo, indigo, triphenylmethane, anthraquinone, and xanthine dyes which are designated as D&C and FD&C blues, browns, greens, oranges, reds, yellows and so forth. Organic pigments also include insoluble metallic salts of certified color additives, lakes. Inorganic pigments include iron oxides, ultramarines, chromium, chromium hydroxide colors and mixtures of these materials. All of these would be considered suitable colorants. [0077] In order to form the core, any of the methods discussed above may be used. Further descriptions of acceptable methods follow. In one method, the base powder material 44 is selected so as to be compactable in its dry state. Any conventional molding operation case be used to form the projectile core. For example, the base powder material 44 could be poured into a first mold cavity and then compacted with a second mold cavity into the predetermined core shape. The pressure applied by the mold compresses the base powder material 44 and any added binder or excipients, into the substantially firm projectile core. Depending on the compressibility of the selected base powder material 44, an outer coating may or may not be needed. [0078] The base powder material 44 (with or without added ingredients) or core mixture 52 may be mixed with a suitable binder. The base powder material 44 (with or without added ingredients) or core mixture 52 may then be injected or otherwise channeled into a mold cavity where the material is formed into a predetermined core shape. The base powder material 44 (with or without added ingredients) or core mixture 52 is then cured, as described above, until it is substantially firm.
[0079] A first method to form a projectile core 42 from a base powder material 44, shown in Figure 14, utilizes a base powder material 44 that is compactable in its dry state. Any conventional molding operation can be used to form the projectile core 42. The base powder material can be poured into a first mold cavity 48 and then compacted with a second mold cavity 50 to form the desired shape.
[0080] Another method of forming the base powder material 44 projectile core is by the preparation of a damp core mixture 52 of base powder material 44 combined with a colorant 46. In this embodiment, the core mixture 52 may be further mixed with a suitable binding agent to form a pourable, moldable core mixture 52. As shown in Figure 15, this core mixture 52 is then injected or directed into a mold cavity 56 where the core mixture 52 forms the desired shape. The molded projectile 54 (Figure 16) is allowed to dry or cure by ambient or heated air. Alternatively, the mold can be heated to cause the mixture to set. It is also contemplated that a drying agent can be added to the core mixture 52, e.g., silica, calcium chloride, etc. [0081] The projectile core formed with a base powder material 44 may be coated with an outer coating, as discussed above.
[0082] It is appreciated that, once a cellulosic material is ground, granulated, or pulverized, it may comprise a powdery substance. Thus, "powder" as used herein therefore encompasses the cellulosic materials that have been dried and ground into powder, previously discussed, as well the base powder material discussed.
[0083] It is appreciated that those skilled in the art would be readily capable of selecting suitable materials for the preparation of the projectile core and projectile of the present invention based on the present disclosure. [0084] The projectile core and projectile described herein are most preferably intended for use as a paintball in the sport of paintball. Marking projectiles such as paintballs must maintain their shape and integrity during firing from, for example, compressed gas powered paintball markers. Such paintballs then must at least partially disintegrate or disperse upon impact with a target at impact velocity, namely, the speed at which the paintball strikes a target such as a human paintball sport player equipped with the appropriate protective gear. Known paintballs that are essentially capsules filled with liquid must break, rupture, or other disperse the liquid dye upon impact at ranges of between 25 to 300 feet, with the ideal range being between 50-100 feet. Accordingly, it is appreciated that the projectile core and projectile of the present invention are preferably formed to meet the parameters necessary for use in the sport of paintball.
[0085] Paintball markers may have a muzzle speed of between approximately 175 to 500 fps, with the preferred muzzle velocity being approximately between 250-350 fps. In paintball sport competitions, the velocity at which a paintball marker fires a paintball from its barrel is sometimes limited to 300 fps or less to protect the paintball sport players from harm. The impact velocity of a paintball, the speed at which the marking projectile hits a target, for example, a human paintball sport player wearing the appropriate protective gear, is generally less than the muzzle velocity, but greater than 50 fps to be effective. The projectile core and projectile of the present invention are preferably formed to retain the predetermined core shape under the conditions of the muzzle velocities described herein, and at least partially disintegrate or disperse upon impacting a target at the described impact velocity, in order to present a colored "mark" or "splat" comparable to the mark made upon impact of known liquid dye filled paintballs.
[0086] One of the benefits that can be provided by the present invention is dimensional stability. Using the present invention, the new projectile core and/or projectile can be made to hold a favorable shape for projectile flight more closely than existing projectiles because it is shaped by the projectile core, and not the shell or coating. An existing projectile is an elastic material filled with a liquid, that is deformable. This means that during shipment and storage an existing projectile can and will change shape. The change in dimension will adversely effect loading and flight of the ball. Breakage is also an issue. A projectile made according to the present invention is substantially firm and will resist deformation under transport and storage. The substantially firm shape is produced during manufacturing and can be formed in a consistent way with existing machinery.
[0087] Another benefit of the present invention is the ability to control carrier characteristics, core mixture characteristics, and projectile shape. During manufacture, fibrous materials can be added to the mixture of solids. By changing the type, length, thickness, weave and/or amount of these fibers the strength of the projectile and resistance to breakage can be controlled. The shape of the projectile can also be controlled using similar methods. [0088] It is understood that the present invention is not limited to the particular embodiments shown and described herein, but that various changes and modifications may be made without departing from the scope and spirit of the invention.

Claims

What is claimed is: 1. A projectile core, comprising: a carrier and a colorant mixed and formed into a substantially firm predetermined core shape that is retained by the projectile core prior to impact of the projectile core upon a target.
2. The projectile core of claim 1, wherein the projectile core is adapted to support a coating, wherein the coating conforms to the predetermined core shape.
3. The projectile core of claim 1, wherein the colorant is at least one of a pigment and a liquid dye.
4. The projectile core of claim 1, wherein at least a portion of the projectile core is adapted to disintegrate or disperse upon impact with a target.
5. The projectile core of claim 1, wherein the carrier comprises one of a fibrous, absorbent material and a powder.
6. The projectile core of claim 1, wherein the carrier comprises a plant fiber.
7. The projectile core of claim 1, wherein the carrier comprises a cellulosic material.
8. The projectile core of claim 7, wherein the cellulosic material comprises rice straw.
9. The projectile core of claim 1, wherein the carrier comprises a powder.
10. A projectile for marking a target, comprising: a projectile core comprising a carrier and a colorant mixed and formed into a substantially firm predetermined core shape that is retained by the projectile core prior to impact of the projectile core upon a target; and, an outer coating.
11. The projectile of claim 10, wherein the coating conforms to the predetermined core shape.
12. The projectile core of claim 10, wherein the colorant is one of a pigment and a liquid dye.
13. The projectile core of claim 10, wherein at least a portion of the projectile core is adapted to disintegrate or disperse upon impact with a target.
14. The projectile core of claim 10, wherein the carrier comprises at least one of a fibrous, absorbent material and a powder.
15. The projectile core of claim 10, wherein the carrier comprises a plant fiber.
16. The projectile core of claim 10, wherein the carrier comprises a cellulosic material.
17. The projectile core of claim 16, wherein the cellulosic material comprises rice straw.
18. The projectile core of claim 1, wherein the carrier comprises a powder.
19. A method of forming a projectile core, comprising: (a) mixing a carrier and a colorant to form a core mixture; (b) forming the core mixture into a predetermined core shape; and, (c) curing the core mixture until a substantially firm projectile core is formed.
20. The method of forming a projectile core according to claim 19, wherein the projectile core is further heated until an outer layer is formed adjacent the projectile core's outer surface.
21. A method of forming a projectile, comprising: (a) mixing a carrier and a colorant to form a core mixture; (b) forming the core mixture into a predetermined core shape; (c) curing the core mixture until a substantially firm projectile core is formed; and, (d) coating the outer surface of the projectile with an outer coating.
PCT/US2004/037946 2003-11-12 2004-11-12 Projectile, projectile core, and method of making WO2005104674A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
US10/579,002 US7934454B2 (en) 2003-11-12 2004-11-12 Projectile, projectile core, and method of making
CA2546004A CA2546004C (en) 2003-11-12 2004-11-12 Projectile, projectile core, and method of making
EP04821793A EP1706700A2 (en) 2003-11-12 2004-11-12 Projectile, projectile core, and method of making
US11/726,947 US20080000464A1 (en) 2003-11-12 2007-03-23 Projectile, projectile core, and method of making
US12/581,518 US20100101400A1 (en) 2003-11-12 2009-10-19 Projectile, projectile core, and method of making

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US51930703P 2003-11-12 2003-11-12
US60/519,307 2003-11-12
US52539403P 2003-11-26 2003-11-26
US60/525,394 2003-11-26

Related Child Applications (2)

Application Number Title Priority Date Filing Date
US11/579,002 A-371-Of-International US7521844B2 (en) 2004-04-30 2004-10-28 Piezoelectric single-crystal device and method of manufacturing the same
US11/726,947 Continuation US20080000464A1 (en) 2003-11-12 2007-03-23 Projectile, projectile core, and method of making

Publications (2)

Publication Number Publication Date
WO2005104674A2 true WO2005104674A2 (en) 2005-11-10
WO2005104674A3 WO2005104674A3 (en) 2006-08-10

Family

ID=35242109

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2004/037946 WO2005104674A2 (en) 2003-11-12 2004-11-12 Projectile, projectile core, and method of making

Country Status (4)

Country Link
US (3) US7934454B2 (en)
EP (1) EP1706700A2 (en)
CA (1) CA2546004C (en)
WO (1) WO2005104674A2 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2905169A1 (en) * 2006-08-28 2008-02-29 Bruno Thellier Mist-producing, non-lethal projectile, useful e.g. in hunting, comprises compressed mixture of biodegradable particles and fragments, disintegrating on impact to produce mist
US20130014666A1 (en) * 2007-03-06 2013-01-17 KEE Action Sports Technology Holdings, Inc. Spreader box apparatus and method of forming bi-laminar paintball shell material and paintballs for use with paintball gun
US8920918B2 (en) 2005-10-31 2014-12-30 Kee Action Sports Technology Holdings, Llc Oil and polyethylene glycol fill material for use in paintball shells

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102004035385A1 (en) * 2003-08-05 2005-03-03 Ruag Ammotec Gmbh Partial decomposition projectile with solid core and core of pressed powder
US20060124118A1 (en) * 2004-07-16 2006-06-15 National Paintball Supply, Inc. Variable pneumatic sear for paintball gun
US8479656B2 (en) * 2005-02-05 2013-07-09 Hydro-Caps, Llc Water based paintball and method for fabricating water based paintballs
US7905181B2 (en) * 2005-02-05 2011-03-15 Ciesiun Paul M Bioluminescent paintball
US20070240601A1 (en) * 2006-04-14 2007-10-18 Ming Cherng Chou Biodegradable BB Pellet
DE102008038258B8 (en) * 2008-08-11 2010-06-10 Deutsches Zentrum für Luft- und Raumfahrt e.V. projectile
US20100218695A1 (en) * 2008-09-26 2010-09-02 Grudge Tactical Inc. Dry Marking System for Ballistic Pellets
US20110146524A1 (en) * 2009-12-17 2011-06-23 Tornee Pang Modified Starch of Enhanced Water Soluble Dye Composition in Core Projectile and Method of Making
US8584589B2 (en) * 2010-03-18 2013-11-19 Jakks Pacific, Inc. Dehydrated, pulp-based projectile
US8186275B1 (en) * 2010-05-17 2012-05-29 The United States Of America As Represented By The Secretary Of The Navy Non-lethal projectile for dispersing payload upon target impact
US20110308419A1 (en) * 2010-06-16 2011-12-22 Crosman Corporation Dry marking projectile
CN101982721B (en) * 2010-10-13 2013-11-06 宜宾北方川安化工有限公司 Method for coating grains
US20120115625A1 (en) * 2010-11-08 2012-05-10 Todd Comi System, device, and method for improving sports swing striking accuracy
DE102010044001B3 (en) * 2010-11-16 2012-02-09 Deutsches Zentrum für Luft- und Raumfahrt e.V. Positioning device for accelerator, for supporting, positioning and accelerating projectile, and executing projectile manufacturing method, has base for supporting, positioning and accelerating projectile and counterpart to base
JP6130302B2 (en) * 2011-01-28 2017-05-17 アピカ カーディオヴァスキュラー リミテッド System for sealing tissue wall stings
CA2857576C (en) 2011-11-30 2021-10-26 Alliant Techsystems, Inc. Polymer projectile having an integrated driving band
WO2013109634A1 (en) 2012-01-16 2013-07-25 Alliant Techsystems Inc. Spin stabilized non-lethal projectile with a shear-thinning fluid
EP2850381A1 (en) * 2012-05-15 2015-03-25 Selectamark Security Systems PLC Tagging system
US9115966B2 (en) * 2013-05-14 2015-08-25 Kerry Thaddeus Bowden Airsoft marking round
US9366516B2 (en) * 2013-07-31 2016-06-14 Shawn C. Hook Resueable polyurethane projectile
US9719763B2 (en) 2013-07-31 2017-08-01 Shawn C. Hook Reusable polyurethane projectile
US9157712B2 (en) * 2014-01-10 2015-10-13 Minima Technology Co., Ltd. Environmentally friendly biodegradable BB pellet and manufacturing method thereof
US10184765B1 (en) * 2015-04-21 2019-01-22 Briana Gardell Throwable paint balls and method of manufacture
US11226183B1 (en) * 2015-04-21 2022-01-18 Mezzimatic LLC Throwable paint balls, kit, and method of manufacture
US11209254B2 (en) * 2016-03-09 2021-12-28 Msato, Llc Pellet shaped marking round for air rifles and pistols
US9982976B1 (en) 2016-11-27 2018-05-29 Luke Alexander Van Valin Paint arrow and game
US20180156588A1 (en) * 2016-12-07 2018-06-07 Russell LeBlanc Frangible Projectile and Method of Manufacture
US11733012B1 (en) 2023-01-16 2023-08-22 Umarex Usa, Inc. Solid core less-lethal projectile

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4637616A (en) * 1985-10-10 1987-01-20 Whiting Carolyn C Marking projectile
US4686905A (en) * 1985-07-26 1987-08-18 Attila Szabo Cartridge for frangible projectile
US4921250A (en) * 1988-10-17 1990-05-01 Ayres John A Frangible article
US6283037B1 (en) * 1999-12-20 2001-09-04 Procopio J. Sclafani Non-lethal shot-gun round

Family Cites Families (98)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US542160A (en) * 1895-07-02 Thomas iiampson
US2288327A (en) * 1935-10-08 1942-06-30 Robert P Scherer Apparatus for forming and filling capsules
GB1268635A (en) 1968-04-25 1972-03-29 Scherer Ltd R P Capsules for marking objects
US4596392A (en) * 1983-08-01 1986-06-24 John M. Blayden Practice ball for golfers
US4656092A (en) 1985-10-15 1987-04-07 R. P. Scherer Corporation Target shooting capsules
JP2545833B2 (en) * 1987-02-28 1996-10-23 アイシン精機株式会社 Headless equipment
GB8725589D0 (en) * 1987-10-31 1987-12-02 Saxby M E Training/marking bullets
US4886275A (en) * 1988-12-15 1989-12-12 Walker Grant W Golf ball
DK0455742T3 (en) 1989-01-26 1995-05-01 Scherer Corp R P Textured softgels and methods and apparatus for making them
US5246635A (en) 1989-01-26 1993-09-21 R. P. Scherer Corporation Method and apparatus for the manufacture of textured softgels
US5171592A (en) 1990-03-02 1992-12-15 Afex Corporation Biomass refining process
US5001880A (en) 1990-04-25 1991-03-26 Smith Henry J Method for producing luminescent paintballs
US5018450A (en) 1990-04-25 1991-05-28 Smith Henry J Luminescent paintball for marking nighttime impacts
US5270064A (en) * 1991-04-12 1993-12-14 Avian Allure Encapsulated food product with readily removable capsule
US5698155A (en) 1991-05-31 1997-12-16 Gs Technologies, Inc. Method for the manufacture of pharmaceutical cellulose capsules
ATE147995T1 (en) 1991-06-26 1997-02-15 Procter & Gamble ABSORBENT DISPOSABLE ITEMS WITH BIODEGRADABLE PROTECTIVE FILMS
US5254379A (en) 1991-10-21 1993-10-19 Perfect Circle Paint Ball Inc. Paint ball
US5623781A (en) * 1991-11-21 1997-04-29 Incotec B.V. Pills or pellets containing seeds and inert carrier material and method for their preparation
US5353712A (en) 1991-12-31 1994-10-11 Olson Christy L Marking pellet gun and rigid, fracturable pellet therefor
US5288772A (en) 1992-06-23 1994-02-22 Clemson University Pre-treated cellulosic materials for producing molded composite articles therefrom and process
DE4221868C1 (en) 1992-07-03 1993-12-02 Scherer Gmbh R P Use of inks containing an aluminum compound for printing on molded articles or foils which contain gelatin
US5672300A (en) 1992-08-10 1997-09-30 R. P. Scherer Corporation Method for striping or marbleizing capsules
GB9223172D0 (en) 1992-11-05 1992-12-16 Scherer Corp R P Capsule construction
US5303496A (en) * 1993-01-19 1994-04-19 David Kowalkowski Scent distributing method for hunters
GB9313329D0 (en) 1993-06-28 1993-08-11 Scherer Ltd R P Softgel capsule shell compositions
US5450795A (en) * 1993-08-19 1995-09-19 Adelman Associates Projectile for small firearms
DE69426408T2 (en) 1993-09-28 2001-07-12 Scherer Gmbh R P Manufacture of soft gelatin capsules
US5361700A (en) * 1993-12-10 1994-11-08 Academy Of Applied Science Ball-firing cartridge and method
GB9325965D0 (en) 1993-12-20 1994-02-23 Scherer Ltd R P Soft gelatin capsules containing particulate material
US5393054A (en) 1994-03-09 1995-02-28 Zap Paintball Corporation Paint ball
US5456036A (en) * 1994-06-14 1995-10-10 Butz; Scott A. Animal scent dispensing pistol assembly
US5519985A (en) 1995-03-27 1996-05-28 Dyck; Rudolph H. Machine for producing straw-filled tubes of flexible netting material
US5569466A (en) 1995-05-17 1996-10-29 R. P. Scherer Corporation Fill compositions for soft elastic gel capsules
US5921840A (en) * 1995-10-16 1999-07-13 Diresta; Joseph G. Squeezable ball-like toy simulating organic object
CN1085684C (en) * 1996-01-05 2002-05-29 纳幕尔杜邦公司 Liquid crystalline polymer composition
US5773752A (en) 1996-02-02 1998-06-30 Kevin L. Blume Coating compositions with impact marking capability and method
US5896692A (en) * 1996-02-29 1999-04-27 Collora; Samuel C. Freeze dried scent lures
GB9605891D0 (en) 1996-03-20 1996-05-22 Scherer Corp R P Ribbon printing for gelatin capsules
US5908636A (en) 1996-06-28 1999-06-01 Mcneil-Ppc, Inc. Fill material for soft gelatin pharmaceutical dosage form containing an antiflatulent
US5919481A (en) 1996-06-28 1999-07-06 Ncneil-Ppc, Inc. Fill material for soft gelatin pharmaceutical dosage form
US5779968A (en) 1996-08-22 1998-07-14 Advanced Elastomer Systems, L.P. Sports ball bladder and method of manufacture
US5711795A (en) * 1996-08-23 1998-01-27 Battelle Memorial Institute Compressible and moldable toy sand composition
US6045823A (en) 1996-09-19 2000-04-04 Dragoco Gerberding & Co. Ag Process for producing solid anhydrous composition, and pharmaceutical and cosmetic products comprising same
US6543365B1 (en) * 1996-11-18 2003-04-08 Jaycor Tactical Systems, Inc. Non-lethal projectile systems
US6393992B1 (en) * 1996-11-18 2002-05-28 Jaycor Tactical Systems, Inc. Non-lethal projectile for delivering an inhibiting substance to a living target
US7194960B2 (en) 1996-11-18 2007-03-27 Pepperball Technologies, Inc. Non-lethal projectiles for delivering an inhibiting substance to a living target
GB9705770D0 (en) 1997-03-20 1997-05-07 Scherer Corp R P Gelatin encapsulation techniques
CA2262669A1 (en) * 1997-06-06 1998-12-10 Showa Denko K.K. Seedling culture mat
US5885671A (en) 1997-07-17 1999-03-23 R.P. Scherer North America Polyoxyalkylene glycol gelatin capsule fill formulations comprising crosslinked carboxylic copolymers
US6083623A (en) 1997-09-19 2000-07-04 Carbocol Systems Inc. Bonding of solid lignocellulosic materials
US6242489B1 (en) 1997-09-25 2001-06-05 Ecological Technologies Corporation Malodorant compositions
US5967916A (en) 1998-02-04 1999-10-19 Lazer Ball Technologies, Llc Lazer ball
AU2661799A (en) 1998-02-11 1999-08-30 North Carolina State University Method for the simple and environmentally benign pulping of nonwood fibrous materials
US6145441A (en) 1998-04-02 2000-11-14 The United States Of America As Represented By The Secretary Of The Navy Frangible payload-dispensing projectile
US6223658B1 (en) 1998-11-06 2001-05-01 Steven P. Rosa Non-lethal weapon firing a frangible, weighted paint ball
US6248210B1 (en) 1998-11-13 2001-06-19 Fort James Corporation Method for maximizing water removal in a press nip
US6221391B1 (en) 1998-11-23 2001-04-24 Accucaps Industries Limited Self-emulsifying ibuprofen solution and soft gelatin capsule for use therewith
US6230630B1 (en) 1999-03-10 2001-05-15 Perfect Circle Paintball, Inc. Aerodynamic projectiles and methods of making the same
US6199311B1 (en) * 1999-05-10 2001-03-13 Wes Foster Scent pellet and method
US6340473B1 (en) 1999-07-07 2002-01-22 R.P. Scherer Technologies, Inc. Film forming compositions comprising modified starches and iota-carrageenan and methods for manufacturing soft capsules using same
GB9916033D0 (en) 1999-07-09 1999-09-08 Bioprogress Tech Int Inc A multiple delivery capsule
US6302997B1 (en) 1999-08-30 2001-10-16 North Carolina State University Process for producing a pulp suitable for papermaking from nonwood fibrous materials
US6675789B2 (en) 1999-12-09 2004-01-13 Nch Corporation Control agent delivery system
JP2002162652A (en) 2000-01-31 2002-06-07 Fujitsu Ltd Sheet-like display device, resin spherical body and microcapsule
US6450100B1 (en) 2000-02-24 2002-09-17 Acar, L.L.C. Method for making an improved paintball grenade
GB0005016D0 (en) 2000-03-01 2000-04-26 Jumik Technologies Limited PVA-Containing compositions
EP1151844B1 (en) * 2000-05-03 2003-11-26 Swiss Caps Rechte und Lizenzen AG Method and apparatus for manufacturing a flexible band from at least two different materials flowable under the action of heat
US6375981B1 (en) 2000-06-01 2002-04-23 A. E. Staley Manufacturing Co. Modified starch as a replacement for gelatin in soft gel films and capsules
US20020046486A1 (en) 2000-07-10 2002-04-25 Wild Peter M. Woody plant injection method and apparatus
US6475500B2 (en) 2000-07-10 2002-11-05 The Procter & Gamble Company Anhydrous cosmetic compositions
US6513439B2 (en) 2000-10-23 2003-02-04 Don-B Corporation Apparatus for marking a target
US6759395B2 (en) 2000-12-18 2004-07-06 Orchid Chemicals & Pharmaceuticals, Ltd. Soft-gelatin capsule comprising S-adenosylmethionine and a method for producing the same
US6479040B1 (en) 2001-02-06 2002-11-12 Coty Inc. Cosmetic formulation
US6574945B2 (en) * 2001-03-21 2003-06-10 Lumitek Llc Method for manufacturing a projectile containing chemiluminescent compounds
US20020134274A1 (en) * 2001-03-21 2002-09-26 Raul Martinez Projectile containing chemiluminescent compounds for marking a target
US6634523B2 (en) 2001-04-06 2003-10-21 Summithood Enterprises, Llc Pepper agent system
US6509040B1 (en) 2001-06-22 2003-01-21 R.P. Scherer Corporation Fast dispersing dosage forms essentially free of mammalian gelatin
WO2003002480A1 (en) * 2001-06-28 2003-01-09 Haun Michael J Method for making product from fiber glass waste
AU773534B2 (en) 2001-08-15 2004-05-27 Nch Corporation Control agent delivery system and method of use
US6604946B2 (en) 2001-08-29 2003-08-12 Mike Glen Oakes Non-lethal small arms projectile for use with a reader-target for amusement, sports and training
US6530962B1 (en) 2001-08-31 2003-03-11 R.P. Scherer Technologies, Inc. Emulsion of water soluble dyes in a lipophilic carrier
US6949256B2 (en) 2002-01-18 2005-09-27 Banner Pharmacaps, Inc. Non-gelatin capsule shell formulation
AU2003215489A1 (en) 2002-04-04 2003-10-20 Alain Guigan Modular accomodation system (bmas)
AU2003238238A1 (en) 2002-06-13 2003-12-31 Paul M. Ciesiun A device and method for illuminating luminescent paintballs
US20030230296A1 (en) 2002-06-14 2003-12-18 Farrell Kenneth R. Pneumatic gun recock flow control
US7134978B2 (en) 2003-07-28 2006-11-14 Sagittarius Life Science Corporation Seamless BB paintball
US7017497B1 (en) * 2003-12-22 2006-03-28 Smart Parts, Inc. Method for making paintballs
US7096793B2 (en) 2004-01-15 2006-08-29 Barry Belog Projectile and related gun
AT413942B (en) 2004-04-16 2006-07-15 Constantia Packaging Ag METHOD FOR PRODUCING PACKAGING SYSTEMS FOR TECHNICAL AND PHARMACEUTICAL INDIVIDUAL DOSING
US20060141026A1 (en) 2004-12-27 2006-06-29 Aldo Perrone Imprinted paintball and apparatus and method for manufacturing same
US7905181B2 (en) 2005-02-05 2011-03-15 Ciesiun Paul M Bioluminescent paintball
US20060230999A1 (en) 2005-04-13 2006-10-19 Mike Long Seed preparation and method of using same
US20070054762A1 (en) 2005-09-06 2007-03-08 Tocco Todd J Phosphorescent paintballs that glow in the dark
US8920918B2 (en) 2005-10-31 2014-12-30 Kee Action Sports Technology Holdings, Llc Oil and polyethylene glycol fill material for use in paintball shells
CA2572937A1 (en) 2005-12-27 2007-06-27 Christopher Black Paintball and method of manufacture
US20070193914A1 (en) 2006-02-21 2007-08-23 Scarabino Mario J Biodegradable transport sphere
US20070240601A1 (en) * 2006-04-14 2007-10-18 Ming Cherng Chou Biodegradable BB Pellet
US20080134927A1 (en) 2006-10-05 2008-06-12 Skellern Michael J Projectile with dispersible contents and method of manufacturing the same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4686905A (en) * 1985-07-26 1987-08-18 Attila Szabo Cartridge for frangible projectile
US4637616A (en) * 1985-10-10 1987-01-20 Whiting Carolyn C Marking projectile
US4921250A (en) * 1988-10-17 1990-05-01 Ayres John A Frangible article
US6283037B1 (en) * 1999-12-20 2001-09-04 Procopio J. Sclafani Non-lethal shot-gun round

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8920918B2 (en) 2005-10-31 2014-12-30 Kee Action Sports Technology Holdings, Llc Oil and polyethylene glycol fill material for use in paintball shells
FR2905169A1 (en) * 2006-08-28 2008-02-29 Bruno Thellier Mist-producing, non-lethal projectile, useful e.g. in hunting, comprises compressed mixture of biodegradable particles and fragments, disintegrating on impact to produce mist
US20130014666A1 (en) * 2007-03-06 2013-01-17 KEE Action Sports Technology Holdings, Inc. Spreader box apparatus and method of forming bi-laminar paintball shell material and paintballs for use with paintball gun

Also Published As

Publication number Publication date
US7934454B2 (en) 2011-05-03
WO2005104674A3 (en) 2006-08-10
US20080000464A1 (en) 2008-01-03
US20100101400A1 (en) 2010-04-29
CA2546004A1 (en) 2005-11-10
CA2546004C (en) 2010-09-14
US20080163779A1 (en) 2008-07-10
EP1706700A2 (en) 2006-10-04

Similar Documents

Publication Publication Date Title
CA2546004C (en) Projectile, projectile core, and method of making
CA2131494C (en) High specific gravity material
US5639526A (en) Paint ball
US5448951A (en) Rigid, fracturable projectiles for air powered guns
US5046730A (en) Golf tee
CN1038612C (en) Precision shooting aerodynamic non-spherical safety-oriented projectile
US5967916A (en) Lazer ball
US5316313A (en) Frangible biodegradable clay target
EP3818324A1 (en) Biodegradable wadding cup for a shotgun cartridge
US5389142A (en) Method and composition for making an improved frangible biodegradable clay target
US7134978B2 (en) Seamless BB paintball
CA2260806C (en) Environmentally safe projectable targets
US5915695A (en) Biodegradable target
AU676866B2 (en) Target for shooting
CN100565087C (en) Army and police use non-lethal fragmentation bomb---the little kinetic energy weapon that compares of shell-type
WO2022003455A1 (en) Recoverable four-sided calcium carbonate paintball
WO1992010246A1 (en) Moldable composition of matter
KR20230157213A (en) Eco-friendly bullets for toys, manufacturing method thereof and bullet-launching device
AU708023B2 (en) Improvements in gelatin capsules
CA3182460A1 (en) Recoverable four-sided calcium carbonate paintball
US20230341215A1 (en) Projectile
JP2002350097A (en) Rocket firework shell
CA2471537C (en) Non-lead composition and method of manufacturing non-lead projectiles and projectile cores therewith
JPH06307799A (en) Paint ball, paint ball shell and manufacture thereof
WO1996008293A1 (en) Injection molded water-soluble golf ball

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BW BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EC EE EG ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NA NI NO NZ OM PG PH PL PT RO RU SC SD SE SG SK SL SY TJ TM TN TR TT TZ UA UG US UZ VC VN YU ZA ZM ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GM KE LS MW MZ NA SD SL SZ TZ UG ZM ZW AM AZ BY KG KZ MD RU TJ TM AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LU MC NL PL PT RO SE SI SK TR BF BJ CF CG CI CM GA GN GQ GW ML MR NE SN TD TG

WWE Wipo information: entry into national phase

Ref document number: 2546004

Country of ref document: CA

WWE Wipo information: entry into national phase

Ref document number: 2004821793

Country of ref document: EP

WWP Wipo information: published in national office

Ref document number: 2004821793

Country of ref document: EP

WWE Wipo information: entry into national phase

Ref document number: 10579002

Country of ref document: US