WO2005087326A1 - Light emitting ball for ball game - Google Patents

Light emitting ball for ball game Download PDF

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Publication number
WO2005087326A1
WO2005087326A1 PCT/JP2005/003549 JP2005003549W WO2005087326A1 WO 2005087326 A1 WO2005087326 A1 WO 2005087326A1 JP 2005003549 W JP2005003549 W JP 2005003549W WO 2005087326 A1 WO2005087326 A1 WO 2005087326A1
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WO
WIPO (PCT)
Prior art keywords
light emitting
ball
light
panel
container
Prior art date
Application number
PCT/JP2005/003549
Other languages
French (fr)
Japanese (ja)
Inventor
Shiro Harada
Original Assignee
Lumica Corporation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lumica Corporation filed Critical Lumica Corporation
Priority to AT05719864T priority Critical patent/ATE534439T1/en
Priority to JP2006519388A priority patent/JP4598768B2/en
Priority to BRPI0508133-5A priority patent/BRPI0508133A/en
Priority to US10/592,234 priority patent/US20080132363A1/en
Priority to EP05719864A priority patent/EP1726336B1/en
Priority to ES05719864T priority patent/ES2373315T3/en
Publication of WO2005087326A1 publication Critical patent/WO2005087326A1/en

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Classifications

    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B43/00Balls with special arrangements
    • A63B43/06Balls with special arrangements with illuminating devices ; with reflective surfaces

Definitions

  • the present invention relates to a glowing ball game ball which can be used even at dusk or at night.
  • the term "pole" in the present invention means all balls such as volleyball, soccer ball, beach benole, / sket boner, notched bole, rugby ball, football, etc. Do.
  • Utility model application flat 4-8 7 1 6 5 has a pole body translucent, a bag is contained in it, and a chemiluminant is inserted into the bag to light up the whole. It was a pole and was different from the present invention.
  • the present invention provides a ball game ball that strikes with a hand, kicks, or strikes a floor even in practical use, and holds the performance of a regular pole used in various competitions, at dusk. Provide a ball that allows you to play ball games without losing sight of the pole that flew to a dark place, and judging the trajectory and rotation of the ball again It is also intended to Disclosure of the invention
  • the ball of the present invention contains a tube filled with air inside, and the outer side is covered with a surface layer.
  • this surface layer (1 in the figure) has a reinforcing layer (3 in the figure) and a surface layer (2 in the figure).
  • the surface is a combination of several units (one piece) with thread. Even a pole having no reinforcing layer is included in the scope of the present invention.
  • Spherical hollow tubes for injecting compressed air use butyl rubber with an air permeability of 1/10 of natural rubber, and use special compounded rubber that minimizes air leakage.
  • the air pressure of the ball is generally between 0.6 and 1.1 atmospheres (600: l l O O g Z c m2).
  • the skin is made of human leather of high quality and durability while leaving a soft touch. It may be natural leather.
  • the reinforcing layer is a composite of polyester and cotton blend cloth and natural rubber latex, and it takes into consideration the balance such as durability, feel and rebound, and changes the cloth type and the amount of latex according to the contents of the ball technique.
  • sewing thread use high-strength polyester twisting thread that is difficult to open.
  • a hole is made in the central part of the surface unit consisting of the reinforcing layer and the skin.
  • a hexagon is 20 units and a pentagon is 1 2
  • the order is a combination of these.
  • a plurality of holes will be attached to these units so that they have the same spacing.
  • multiple holes are provided so that the center of gravity of the pole does not deviate from the center.
  • the position of the hole is limited in order not to lose the balance which is the function of the pole.
  • the present invention sets the position of the hole depending on the application and purpose.
  • a light emitter attachment is interposed and fixed between the above-described surface layer and the tube.
  • This luminous body attachment is made of a synthetic rubber such as soft chloride, vinyl acetate, natural rubber, silicone rubber, etc. and is made of a material that has elasticity and transmits light. Since the light emitter attachment itself is elastic, it is possible to mold it to the curved surface of the ball surface, but the necessity will be small. In addition, since it is mounted between the surface layer and the tube, the overall shape is flat.
  • the light emitting panel exposed from the hole on the ball surface of the light emitting ball technology has a function as a weir inlet for attaching the chemical light emitter freely and a function of a light emitting surface from which light is emitted to the outside from the light emitting panel.
  • Chemiluminescent light sources used as light sources are far superior in impact resistance to batteries and LEDs, so they are best used for such products. By fitting this luminous body fixture to the outside of the tube and below the surface layer, the feel and durability of the surface layer are not compromised.
  • FIG. 1 is a plan view of the light emitter fixture according to the first embodiment of the present invention
  • FIG. 2 is a side view of the light emitter fixture according to the first embodiment of the present invention
  • FIG. FIG. 4 is a cross-sectional explanatory view of a light emitter attachment according to the first embodiment of the present invention
  • FIG. 4 is a view of a light emitting ball according to the first embodiment of the present invention
  • FIG. 5 is a view according to the first embodiment of the present invention.
  • FIG. 6 is a cross sectional view of the second embodiment
  • FIG. 7 is a cross sectional view of the chemical light emitter.
  • FIG. 4 is a light emitting ball game ball showing a first embodiment of the present invention.
  • a hole 1 3 of ⁇ 2 4 to ⁇ 2 5 m m is made in the center of the surface layer 1 of 1 2 pentagons.
  • the reinforcing layer forming the surface layer is made of a composite of polyester / cotton blend cloth and natural rubber latex, etc., the structure does not grow uniformly when injecting the compressed air, so the compressed air is previously compressed. Drill a hole of calculated shape so that it will become a circular hole after injection.
  • the light emitter fixture 5 is shown in FIGS.
  • Transparent soft chloride Bule resin is used as a material, and it is connected to the luminous object holder 9 which penetrates the inside of diameter 4 5 mm thickness 7 mm and forms cavity 8 and emits ⁇ 2 5 mm 3 mm high panel 6 is provided, and this luminous panel is also provided with a weir inlet 7 which is crossed, and the weir inlet 7 and the cavity 8 are connected.
  • the width of the inlet of this weir 7 is set to 3.5 mm to prevent the chemiluminant 11 from jumping out.
  • the size of the chemiluminescer is ⁇ 4.5 mm in diameter and 3 7 mm in total length.
  • an 8 m wide removal slot 10 is provided which traverses the insertion slot 7 and reaches the cavity 8.
  • the removal groove 10 is provided in the present embodiment, it is not always necessary. When the groove 10 is not provided, it may be taken out with a rod-like shape.
  • the upper surface of the light emitter support 9 is in contact with the back surface of the surface layer 1, that is, the reinforcing layer 3. Fix this contact surface with an adhesive or double-sided tape. After that, when the pole is formed by a general manufacturing method, the luminous body holding portion 9 is sandwiched between the tube 4 and the surface layer 1, and after forming, air is introduced into the tube 4 to narrow and fix it strongly. On the surface of the formed pole, only the surface of the light emitting panel which functions as a circular light emitting surface of ⁇ 25 mm appears in 12 places.
  • the chemiluminescent substance 11 used in the present invention is composed of a composition of a fluorescent liquid and an oxidizing liquid, and the fluorescent liquid is a solution of a sucrose ester and a fluorescent substance, and the oxidizing liquid is a solution of hydrogen peroxide and a catalyst. It may be of a generally known structure in which one of the fluorescent solution and the oxidizing solution is sealed in the glass ampoule 16 in the rod-like container 15 and the other is filled in the container outside the ampoule.
  • the dissolution of solid succinate reacts with it to emit light, so that light emission can be sustained for a long time.
  • both solutions in the light emitter are stirred and dissolved, and light emission continues at all times.
  • At least one or more solvents such as dibutyl phthalate or dimethyl phthalate or tributyl acetylate are added in an amount equal to or higher than the solubility of the solvent.
  • This sucrose ester is a bis
  • the fluorescent substance can be freely selected, for example, 1-bis-bis-biphenyl-bilanthracene. In order to emit colored light in one ball, this can be easily achieved by changing this fluorescent material.
  • bending the chemiluminescer 11 and breaking the glass container inside mixes the oxidizing solution and the fluorescent solution, and chemiluminescence starts.
  • the chemiluminescer 11 is inclined and inserted from the crucible inlet 7 of the light emitting panel 6 to the cavity 8 and held.
  • the length of the insertion port 7 is 25 mm, while the length of the chemiluminescer is 37 mm, and it does not fly out easily.
  • the inside of the rod-like tip is a hollow container as shown in FIG. 7 and the outside of the rod-like part is 44.5 mm. If the outer size of the bulging part is ⁇ 8.0 mm and the total length is 32 mm, the internal capacity of the luminescent liquid will increase, so the brightness of the light emitted from the luminescent panel will be high.
  • the second embodiment is shown in FIG.
  • a chemiluminescent body is provided with a linear cut on the surface of the luminescent panel, and this is used as a luminous body inlet port.
  • the luminous body is inclined from the luminous body inlet port 12 and forcibly inserted, and the luminous body holding portion 9 is If it is compressed, it will be held in an enclosed state by the elasticity of the holding part. Such a holding method does not jump out easily even if the ball is hit.
  • the light emitted from the chemiluminescer 11 travels both in the surface direction and in the inward direction, so a white or mirror light reflection layer is formed on the bottom of the luminous body holder 9. If 1 4 is provided, the light in the inward (center) direction is reflected to the surface and There is an effect that the brightness can be increased.
  • the light emitting ball technology pole according to the present invention can change the surface of various balls, such as a hand-stitched soccer ball, which has been considered impossible until now, to a light emitting surface scattered about.
  • the ball can be used at night as it does not lose sight of the ball, and by following the path of the glowing ball, the spectator can provide a very enjoyable ball game to players.
  • the structure is designed to minimize the loss of the original function, so it has the effect that it can be used in formal ball games.

Abstract

A light emitting ball for a ball game, comprising a surface layer and a tube on the inside of the surface layer. A plurality of transparent or semi-transparent and elastic light emitting body mounting fittings formed of light emitting panels and light emitting body holding parts are disposed so that the light emitting panels of the light emitting body mounting fittings can be exposed from a roughly circular holes bored in the surface layer of the ball to the outside. The outer periphery of the roughly circular light emitting body holding part larger in diameter than the light emitting panel is fixedly held by the surface layer and the tube. A light emitting body insert port formed by crossing the surface of the light emitting panel is connected to a hollow part formed by crossing the light emitting body holding part so that a light emitting body can be detachably installed. Thus, the ball for the ball game capable of withstanding practical use even if the ball is hit by hand, kicked by foot, or hits a floor can be provided.

Description

発光球技用ボール Flash ball for ball
技術分野 本発明は、 夕暮れや夜間におい明ても使用できる光る球技用ボールに関する ものである。 TECHNICAL FIELD The present invention relates to a glowing ball game ball which can be used even at dusk or at night.
書 背景技術 本発明におけるポールとは、 バレーボール、 サッカーボール、 ビーチボー ノレ、 / スケッ トボーノレ、 ノヽンドボ一ノレ、 ラグビーボール、 フッ トボール等の 内部がチューブで表面が表皮で縫い合わされたボールの全てを意味する。 こ の種のボールの先行技術を調査したが発見されなかった。実用新案出願平 4 - 8 7 1 6 5のひかるポールはポール本体が半透明で、 その中に袋が入って おり、 その袋の中に化学発光体を揷入して、 全体を光らす遊戯用ポールであ り、 本発明とは異なるものであった。 本発明は手で打ったり、 蹴ったり、 床に当たっても実用に耐える光る球技 用ボールを提供することおよぴ、 各種競技会に使用される正規なポールを、 その性能を保持して、 夕暮れ時や暗い所に飛んだポールを見失うことなく、 又ボールの軌跡や回転を判断しつつ、球技を行うことができるボールを提供 することを目的としたものでもある。 発明の開示 Background Art In the present invention, the term "pole" in the present invention means all balls such as volleyball, soccer ball, beach benole, / sket boner, notched bole, rugby ball, football, etc. Do. The prior art of this type of ball was investigated but not found. Utility model application flat 4-8 7 1 6 5 has a pole body translucent, a bag is contained in it, and a chemiluminant is inserted into the bag to light up the whole. It was a pole and was different from the present invention. The present invention provides a ball game ball that strikes with a hand, kicks, or strikes a floor even in practical use, and holds the performance of a regular pole used in various competitions, at dusk. Provide a ball that allows you to play ball games without losing sight of the pole that flew to a dark place, and judging the trajectory and rotation of the ball again It is also intended to Disclosure of the invention
本発明のボールは、 内部に空気を満たすチューブが入っており、 その外側 が表層でおおわれているもので、 一般的には、 この表層 (図中 1 ) は補強層 (図中 3 ) と表皮 (図中 2 ) からなつている。  The ball of the present invention contains a tube filled with air inside, and the outer side is covered with a surface layer. Generally, this surface layer (1 in the figure) has a reinforcing layer (3 in the figure) and a surface layer (2 in the figure).
表層はいくつかの単位 (一片) を糸で縫い合わせたものである。 なお、 補 強層のないポールであっても本発明の範囲に含まれるものである。  The surface is a combination of several units (one piece) with thread. Even a pole having no reinforcing layer is included in the scope of the present invention.
手縫いサッカーポールの構造の一例を下記に示す。圧搾空気を注入する球 形中空のチューブは、空気透過率が天然ゴムの 1 / 1 0というブチルゴムを 使用し、 空気の漏れを最小限におさえた特殊配合ゴムを使用する。 ボールの 空気圧は一般的には 0 . 6〜: 1 . 1気圧 (6 0 0〜: l l O O g Z c m2) で ある。 表皮はソフトなタツチを残しながら強靭性、 耐久性に富んだ品質の人 ェ皮革を使用する。 なお天然の皮革でもかまわない。  An example of the structure of a hand-stitched soccer pole is shown below. Spherical hollow tubes for injecting compressed air use butyl rubber with an air permeability of 1/10 of natural rubber, and use special compounded rubber that minimizes air leakage. The air pressure of the ball is generally between 0.6 and 1.1 atmospheres (600: l l O O g Z c m2). The skin is made of human leather of high quality and durability while leaving a soft touch. It may be natural leather.
補強層は、 ポリエステルとコッ トンの混紡布と天然ゴムラテックスの複合 体よりなり、耐久性、触感、リバウンドなどパランスを考慮したものであり、 球技内容に合わせて布種、 ラテックス量を変化させる。 縫い糸は、 縫い目が 開きにくい高強力のポリエステル撚糸を使用する。 この補強層と表皮からな る表層の一単位の中央部分に穴を空ける。  The reinforcing layer is a composite of polyester and cotton blend cloth and natural rubber latex, and it takes into consideration the balance such as durability, feel and rebound, and changes the cloth type and the amount of latex according to the contents of the ball technique. As sewing thread, use high-strength polyester twisting thread that is difficult to open. A hole is made in the central part of the surface unit consisting of the reinforcing layer and the skin.
例えば通常のサッカーボールの場合、 六角形が 2 0単位、 五角形が 1 2単 位、 これらを組み合わせて鏠ぃ合わせたものである。 これらの単位につける 穴は、 それぞれが同じ間隔となるように複数設ける。 つまりポールの重心が 中心からずれることのないように複数の穴を設けるものである。 このように、 穴の位置を限定するのはポール本来の機能であるパランスを損なわないよ うにするためである。 ただし、 たんなる遊戯に使用するのであれば、 限定す る必要もない。 本発明は用途、 目的により穴の位置を設定するものである。 上記した表層とチューブの間に発光体取り付け具を介在して固定させる。 この発光体取り付け具は軟質塩化ビュル、酢酸ビニルァセテ一ト、天然ゴム、 シリコンゴム等の合成ゴムで弾力性を有し、光を透す素材で成形されている。 この発光体取り付け具はそれ自体弾性を有する為、 ボール表面の曲面に合 わせた成形も可能であるが、 その必要性は少ないであろう。 また表層とチュ ーブの間に装着するものであるから、 全体の形状が扁平状となっている。 For example, in the case of a regular soccer ball, a hexagon is 20 units and a pentagon is 1 2 The order is a combination of these. A plurality of holes will be attached to these units so that they have the same spacing. In other words, multiple holes are provided so that the center of gravity of the pole does not deviate from the center. Thus, the position of the hole is limited in order not to lose the balance which is the function of the pole. However, there is no need to limit it if it is used for a mere game. The present invention sets the position of the hole depending on the application and purpose. A light emitter attachment is interposed and fixed between the above-described surface layer and the tube. This luminous body attachment is made of a synthetic rubber such as soft chloride, vinyl acetate, natural rubber, silicone rubber, etc. and is made of a material that has elasticity and transmits light. Since the light emitter attachment itself is elastic, it is possible to mold it to the curved surface of the ball surface, but the necessity will be small. In addition, since it is mounted between the surface layer and the tube, the overall shape is flat.
発光球技用ボール表層の穴から露出させた発光パネルは、化学発光体を着 脱自在に取着するための揷入口としての機能と、その発光パネルから外に光 が放出される発光面の機能をあわせもつている。発光源として使用する化学 発光体は、 電池と L E Dに比べてはるかに耐衝撃性にすぐれている為、 この ような商品に使用するのが最適である。 この発光体取り付け具をチューブの 外側で表層の下におさめることにより、表層の触感や耐久性をそこなうこと がない構造とした。 図面の簡単な説明 The light emitting panel exposed from the hole on the ball surface of the light emitting ball technology has a function as a weir inlet for attaching the chemical light emitter freely and a function of a light emitting surface from which light is emitted to the outside from the light emitting panel. Together. Chemiluminescent light sources used as light sources are far superior in impact resistance to batteries and LEDs, so they are best used for such products. By fitting this luminous body fixture to the outside of the tube and below the surface layer, the feel and durability of the surface layer are not compromised. Brief description of the drawings
第 1図は本発明の第一実施例の発光体取り付け具の平面図であり、第 2図 は本発明の第一実施例の発光体取り付け具の側面図であり、第 3図は本発明 の第一実施例の発光体取り付け具の断面説明図であり、第 4図は本発明の第 一実施例の発光球技用ボールの図であり、第 5図は本発明の第一実施例の断 面説明図であり、 第 6図は第二実施例の断面説明図であり、 第 7図は化学発 光体の断面説明図である。 発明を実施するための最良の形態  FIG. 1 is a plan view of the light emitter fixture according to the first embodiment of the present invention, FIG. 2 is a side view of the light emitter fixture according to the first embodiment of the present invention, and FIG. FIG. 4 is a cross-sectional explanatory view of a light emitter attachment according to the first embodiment of the present invention, FIG. 4 is a view of a light emitting ball according to the first embodiment of the present invention, and FIG. 5 is a view according to the first embodiment of the present invention. FIG. 6 is a cross sectional view of the second embodiment, and FIG. 7 is a cross sectional view of the chemical light emitter. BEST MODE FOR CARRYING OUT THE INVENTION
以下、本発明の発光球技用ボールの実施の形態を図面を参照しながら詳細 に説明する。  Hereinafter, an embodiment of a light emitting ball game ball of the present invention will be described in detail with reference to the drawings.
第 4図は、 本発明の第一の実施例を示す発光球技用ボールである。 1 2枚 の五角形の表層 1の中央に φ 2 4〜 φ 2 5 m mの穴 1 3を開ける。 なお上記 したように表層を形成している補強層は、 ポリエステルとコットンの混紡布 と天然ゴムラテックスの複合体等よりなる為、圧搾空気を注入時均一に組織 が伸びることはないので予め圧搾空気注入後円形の穴となるように伸び率 を計算した形状の穴を開ける。  FIG. 4 is a light emitting ball game ball showing a first embodiment of the present invention. 1 A hole 1 3 of φ 2 4 to φ 2 5 m m is made in the center of the surface layer 1 of 1 2 pentagons. As described above, since the reinforcing layer forming the surface layer is made of a composite of polyester / cotton blend cloth and natural rubber latex, etc., the structure does not grow uniformly when injecting the compressed air, so the compressed air is previously compressed. Drill a hole of calculated shape so that it will become a circular hole after injection.
発光体取り付け具 5は第 1、 2、 3図に示している。 透明軟質塩化ビュル 樹脂を素材として、直径 Φ 4 5 m m厚さ 7 m mの内部を横断貫通して空洞 8 を形成した発光体保持部 9に連接して、 φ 2 5 m m高さ 3 m mの発光パネル 6をつけ、 この発光パネルにも横断した揷入口 7を設けて、 前記揷入口 7と 空洞 8をつなぐ。 The light emitter fixture 5 is shown in FIGS. Transparent soft chloride Bule resin is used as a material, and it is connected to the luminous object holder 9 which penetrates the inside of diameter 4 5 mm thickness 7 mm and forms cavity 8 and emits φ 2 5 mm 3 mm high panel 6 is provided, and this luminous panel is also provided with a weir inlet 7 which is crossed, and the weir inlet 7 and the cavity 8 are connected.
この揷入口 7の入口の巾を 3 . 5 m mとして化学発光体 1 1が飛び出すの を防止する。 なお化学発光体のサイズは直径 Φ 4 . 5 m m全長 3 7 m mを使 用する。 次に、 挿入口 7を横断して空洞 8まで達する 8 m m巾の取り外し用 溝 1 0を設ける。 なお本実施例では取り外し用溝 1 0を設けたが、 必ずしも 必要ではなく溝 1 0を設けないときは棒状のもので取り出せばよい。  The width of the inlet of this weir 7 is set to 3.5 mm to prevent the chemiluminant 11 from jumping out. The size of the chemiluminescer is Φ 4.5 mm in diameter and 3 7 mm in total length. Next, an 8 m wide removal slot 10 is provided which traverses the insertion slot 7 and reaches the cavity 8. Although the removal groove 10 is provided in the present embodiment, it is not always necessary. When the groove 10 is not provided, it may be taken out with a rod-like shape.
発光パネル 6を表層 1の穴 1 3に挿入する。 表層 1の裏面、 すなわち補強 層 3に発光体保持部 9の上面が接触する。 この接触面には接着剤や両面テー プを使って固定する。 その後、 一般的な製法によりポールを成形するとチュ ープ 4と表層 1に発光体保持部 9が挟まれた状態となり、成形後チューブ 4 に空気を入れる事により、 強狭され固定される。 成形されたポールの表面に は 1 2ケ所に φ 2 5 m mの円形発光面として機能する発光パネルの表面の みが表われる。  Insert the light emitting panel 6 into the hole 13 in the surface layer 1. The upper surface of the light emitter support 9 is in contact with the back surface of the surface layer 1, that is, the reinforcing layer 3. Fix this contact surface with an adhesive or double-sided tape. After that, when the pole is formed by a general manufacturing method, the luminous body holding portion 9 is sandwiched between the tube 4 and the surface layer 1, and after forming, air is introduced into the tube 4 to narrow and fix it strongly. On the surface of the formed pole, only the surface of the light emitting panel which functions as a circular light emitting surface of φ 25 mm appears in 12 places.
なお、本発明に使用する化学発光体 1 1は蛍光液と酸化液の組成からなり、 蛍光液はシュゥ酸エステル及ぴ蛍光物質の溶液、酸化液は過酸化水素及び触 媒の溶液で、 この蛍光液と酸化液のいずれか一方を棒状容器 1 5の中のガラ スアンプル 1 6に密封し他方をアンプルの外側で容器の中に充填した一般 的に知られている構造のものでもかまわないが、ガラス容器の中のシュゥ酸 エステル及び蛍光物質の溶液に該シ ゥ酸エステル及ぴ又は蛍光物質が粉 状や結晶状でも存在する組成にすると、酸化液成分の過酸化水素は溶解した シユウ酸エステル及ぴ固体状のシュゥ酸エステルの表面で発光し、反応開始 時のシュゥ酸エステルが反応し減少しても、 固体状のシュゥ酸エステルの溶 解により、 これと反応して発光するため長時間にわたり発光を持続させるこ とが可能となる。 また球技時に発光体の中の両方の液が撹拌され溶解し常時 発光が継続する。 The chemiluminescent substance 11 used in the present invention is composed of a composition of a fluorescent liquid and an oxidizing liquid, and the fluorescent liquid is a solution of a sucrose ester and a fluorescent substance, and the oxidizing liquid is a solution of hydrogen peroxide and a catalyst. It may be of a generally known structure in which one of the fluorescent solution and the oxidizing solution is sealed in the glass ampoule 16 in the rod-like container 15 and the other is filled in the container outside the ampoule. A solution of succinic acid ester and a fluorescent substance in a glass container, the sicic acid ester and When the composition is present in the form of crystals or crystals, the hydrogen peroxide in the oxidation liquid component emits light on the surface of the dissolved oxalic acid ester and solid succinic acid ester, and the succinic acid ester at the start of the reaction reacts and decreases. However, the dissolution of solid succinate reacts with it to emit light, so that light emission can be sustained for a long time. At the time of ball game, both solutions in the light emitter are stirred and dissolved, and light emission continues at all times.
一例を上げると、 フタル酸ジブチル、 又はフタル酸ジメチル又はァセチル クェン酸トリブチル等の溶媒の少なく とも 1つ以上で、 この溶媒の溶解度以 上の量のシュゥ酸エステルが加えられている。 このシュゥ酸エステルはビス As an example, at least one or more solvents such as dibutyl phthalate or dimethyl phthalate or tributyl acetylate are added in an amount equal to or higher than the solubility of the solvent. This sucrose ester is a bis
( 2, 4, _ 5 — ト リ クロ口一カノレポイ ソペンチノレォキシフエ二ノレ) ォキザ レートゃビス ( 2 , 4 , — 5 — ト リ クロ口一カノレボペン トキシフエ-ノレ) ォ キザレートが代表例である。 なお蛍光物質は、 1 一クロ口ビスフエ二ルェチ 二ルアントラセン等、 自由に選択することが出来る。 1個のボールに色とり どりの光を発するようにするにはこの蛍光物質を変えることにより容易に 達成できる。 (2, 4, _ 5 — tri black mouth one cane poe sopenchino reoxi fenio nore) Oxarate or bis (2, 4, — 5 — tri black mouth one cane levo pen toki sihe-nore) For example It is. The fluorescent substance can be freely selected, for example, 1-bis-bis-biphenyl-bilanthracene. In order to emit colored light in one ball, this can be easily achieved by changing this fluorescent material.
使用する時は、化学発光体 1 1を曲げて中のガラス容器を割ると酸化液と 蛍光液が混合し化学発光がスタートする。 この化学発光体 1 1を傾斜させて、 発光パネル 6の揷入口 7より空洞 8まで挿入して保持させる。挿入口 7の長 さは 2 5 m mであるのに対し、 化学発光体の長さは 3 7 m mであり、 容易に 飛び出すことはない。 ポールの表面には、 φ 2 5 m mの円形の発光面が 1 2 ケ所点在することになる。 このボールを蹴ったり、 投げたり した時のポール の回転状態を判断でき、ポールのカーブ等の動きを暗いグラウンド等でも見 分けられる。 When used, bending the chemiluminescer 11 and breaking the glass container inside mixes the oxidizing solution and the fluorescent solution, and chemiluminescence starts. The chemiluminescer 11 is inclined and inserted from the crucible inlet 7 of the light emitting panel 6 to the cavity 8 and held. The length of the insertion port 7 is 25 mm, while the length of the chemiluminescer is 37 mm, and it does not fly out easily. On the surface of the pole, 1 2 It will be dotted everywhere. You can judge the rotation of the pole when you kick or throw this ball, and you can distinguish the movement of the curve of the pole even on a dark ground.
なお、 ガラス容器を薄肉とすることで割れ易く した化学発光体 1 1をあら かじめボールに装着しておき、使用時に床などに当てる等の衝撃により発光 させる事もできる。 なお化学発光体 1 1を外す時は溝 1 0に金具などで挟み 抜き出す。  In addition, it is possible to attach the chemiluminescent substance 11, which is easily broken by making the glass container thin, on a ball in advance, and to emit light by an impact such as hitting the floor during use. When removing the chemical luminaire 11, put it in the groove 10 with a metal fitting etc. and take it out.
さらに、 上記の実施例では単なる棒状の化学発光体を便用したが、 第 7図 に示すような棒状の先端が膨らんだ内部が空洞の容器とし、その棒状部分の 外形が Φ 4 . 5 m m、 膨らんだ部分の外形が φ 8 . 0 m m、 全長 3 2 m mの サイズにすると発光液の内容量が増加するので発光パネルからでる光の輝 度が高くなる。  Furthermore, although a simple rod-like chemiluminescent substance was used for convenience in the above example, the inside of the rod-like tip is a hollow container as shown in FIG. 7 and the outside of the rod-like part is 44.5 mm. If the outer size of the bulging part is φ 8.0 mm and the total length is 32 mm, the internal capacity of the luminescent liquid will increase, so the brightness of the light emitted from the luminescent panel will be high.
第二の実施例は第 6図に示している。化学発光体を発光パネル表面に線状 の切り込みを設けて、 これを発光体揷入口としこの発光体揷入口 1 2から傾 斜させて、 強制的に揷入し、 発光体保持部 9まで揷しこむと、 同保持部の弾 性により、 包みこんだ状態で保持される。 このような保持方法はボールに衝 撃を与えても容易にとび出すことはない。  The second embodiment is shown in FIG. A chemiluminescent body is provided with a linear cut on the surface of the luminescent panel, and this is used as a luminous body inlet port. The luminous body is inclined from the luminous body inlet port 12 and forcibly inserted, and the luminous body holding portion 9 is If it is compressed, it will be held in an enclosed state by the elasticity of the holding part. Such a holding method does not jump out easily even if the ball is hit.
また、 第一おょぴ第二の実施例において化学発光体 1 1から出る光は、 表 面方向にも内側方向にも向うため、発光体保持部 9の底面に白色や鏡面の光 反射層 1 4を設けておけば、 内側 (中心) 方向の光を表面に反射させて光の 輝度を増加できる効果がある。 産業上の利用可能性 Further, in the first and second embodiments, the light emitted from the chemiluminescer 11 travels both in the surface direction and in the inward direction, so a white or mirror light reflection layer is formed on the bottom of the luminous body holder 9. If 1 4 is provided, the light in the inward (center) direction is reflected to the surface and There is an effect that the brightness can be increased. Industrial applicability
以上のように、 本発明にかかるによる発光球技用ポールは、 今まで不可能 とされてきた、手縫いサッカーボールなどの各種のボールの表面を点在した 発光面に変えることが可能となるため、 ボールを見失うことが無いので夜間 での使用も可能となり、又光るボールの軌跡を追うことで観客ならぴ選手に とっても楽しい球技を提供できる。 又、 本来の機能を損なうことを最小限に おさえた構造であり、 従って正式な球技にも使用できる効果がある。  As described above, the light emitting ball technology pole according to the present invention can change the surface of various balls, such as a hand-stitched soccer ball, which has been considered impossible until now, to a light emitting surface scattered about. The ball can be used at night as it does not lose sight of the ball, and by following the path of the glowing ball, the spectator can provide a very enjoyable ball game to players. In addition, the structure is designed to minimize the loss of the original function, so it has the effect that it can be used in formal ball games.

Claims

請 求 の 範 囲 層とその内側のチューブからなる構造のボールにおいて、 光透過性で 弾性を有し発光パネル部及ぴ発光体保持部からなる発光体取り付け具 をポールの表面から発光パネル部が露出するように表層とチューブの 間に複数装着し、発光パネル表面の発光体挿入口から化学発光体を発光 体保持部まで着脱自在に挿入できる構造としたことを特徴とした発光 球技用ポール。 In the ball with the structure consisting of the request range layer and the tube inside it, the light-emitting panel attachment from the surface of the pole is a light-emitting, light-emitting, light-emitting panel part and a light-emitting body holding part A plurality of poles are mounted between the surface layer and the tube so as to be exposed, and the structure is such that the chemical luminescent body can be detachably inserted from the luminous body insertion port on the surface of the luminescent panel to the luminous body holding portion.
光パネルと、 同発光パネルよ り径の大なる発光体保持部を一体成型し た発光体取り付け具からなる請求の範囲 1記載の発光球技用ボール。 発光パネル表面の発光体揷入口の径を化学発光体の径ょりも小さく し、 この発光体揷入口と発光体保持部内の空洞部がつながった請求の範囲 1記載の発光球技用ポール。  The light emitting ball game ball according to claim 1, comprising a light emitting body mounting member integrally formed with a light emitting panel and a light emitting body holding portion having a larger diameter than the light emitting panel. The light emitting ball technology pole according to claim 1, wherein the diameter of the light emitter inlet on the surface of the light emitting panel is also reduced and the diameter of the light emitter inlet is connected to the hollow portion in the light emitter holding portion.
光パネル表面から発光体保持部まで切り込みをいれて、 発光パネル表 面の切り込みから化学発光体を挿入し弾性素材の伸縮性を利用して発 光体を保持する構造とした請求の範囲 1記載の発光球技用ボール。  A structure in which the light emitting body is held by making a cut from the surface of the light panel to the light emitting body holding portion, inserting the chemical light emitting body from the cut of the surface of the light emitting panel, and utilizing the stretchability of the elastic material. Ball for light emitting ball technique.
光パネル表面の発光体揷入口に、 この揷入口に直交した取り外し用溝 を設けた請求の範囲 1記載の発光球技用ポール。  The light emitting ball pole according to claim 1, wherein a removal groove orthogonal to the light inlet is provided at the light emitter inlet of the light panel surface.
ールの表層の複数の発光パネルの位置が互いに同じ間隔とした請求の 範囲 1記載の発光球技用ポール。 酸化水素水を主成分とした酸化液とシュゥ酸エステル及び蛍光物質を 主成分とした蛍光液の 2種類の液の混合により化学発光を生起する一 方の液を可撓性を有し光透過性の円筒状密閉容器に充填し、 この容器内 に収容された密封ガラス容器に他方の液を充填した化学発光体を使用 した請求の範囲 1記載の発光球技用ボール。 The light emitting ball game pole according to claim 1, wherein the positions of the plurality of light emitting panels on the surface layer of the ball are the same as each other. A liquid that has chemiluminescence by mixing two kinds of liquid consisting mainly of hydrogen peroxide water, an oxidation liquid with water and a sulfuric acid ester and a fluorescent substance as a main component has flexibility and transmits light. The luminous ball for ball according to claim 1, wherein a chemiluminescer filled in a rigid cylindrical closed container and the other liquid filled in the closed glass container housed in the container is used.
酸化水素水を主成分とした酸化液とシュゥ酸エステル及ぴ蛍光物質を 主成分とした蛍光液の 2種類の液の混合により化学発光を生起する系 において酸化液を可撓性を有し光透過性の円筒状密閉容器に充填し、 こ の容器内に収容された密封ガラス容器内にシュゥ酸エステル及ぴ蛍光 物質の溶液及び該シユウ酸エステル及ぴ又は蛍光物質が紛体ゃ結晶な どの固体状でも存在する化学発光体を使用した請求の範囲 1記載の発 光球技用ボール。  A system that produces chemiluminescence by mixing two kinds of solutions, an oxidizing solution mainly composed of hydrogen oxide water and a fluorescent solution mainly composed of succinic acid ester and a fluorescent substance. In a sealed glass container which is packed in a transparent cylindrical closed container and accommodated in this container, a solution of a succinic acid ester and a fluorescent substance, and a solid such as a powder of an ester and / or a fluorescent substance and crystals thereof. The light emitting ball according to claim 1, wherein a chemiluminant is also present.
酸化水素水を主成分とした酸化液とシュゥ酸エステル及ぴ蛍光物質を 主成分とした蛍光液の 2種類の液の混合により化学発光を生起する系 においてシュゥ酸エステル及び蛍光物質の溶液及び該シュゥ酸エステ ル及ぴ又は蛍光物質が紛体ゃ結晶などの固体状でも存在する蛍光液を 可撓性を有し光透過性の円筒状密閉容器に充填し、 この容器内に収容さ れた密封ガラス容器内に酸化液を入れた化学発光体を使用した請求の 範囲 1記載の発光球技用ポール。 A solution of a sulfate and a fluorescent substance in a system in which chemiluminescence is caused by mixing two kinds of liquids, an oxidizing solution mainly composed of hydrogen oxide water and a fluorescent solution mainly composed of a succinic acid ester and a fluorescent substance A flexible, light-transmissive, cylindrical hermetic container is filled with a fluorescent liquid which is present as a solid such as a sucrose ester and a fluorescent substance in the form of a powder or a crystal, and the container is housed in the container. A light emitting ball pole according to claim 1, wherein a chemiluminescer in which an oxidizing solution is contained in a glass container.
. 発光体保持部の底面に光反射層を形成した請求の範囲 1記載の発光球 技用ポール。 The light emitting sphere according to claim 1, wherein a light reflecting layer is formed on the bottom surface of the light emitting body holding portion. Technical pole.
PCT/JP2005/003549 2004-03-10 2005-02-24 Light emitting ball for ball game WO2005087326A1 (en)

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AT05719864T ATE534439T1 (en) 2004-03-10 2005-02-24 LIGHT BALL FOR BALL GAME
JP2006519388A JP4598768B2 (en) 2004-03-10 2005-02-24 Luminous ball game ball
BRPI0508133-5A BRPI0508133A (en) 2004-03-10 2005-02-24 light emitting ball
US10/592,234 US20080132363A1 (en) 2004-03-10 2005-02-24 Light Emitting Ball for Ball Game
EP05719864A EP1726336B1 (en) 2004-03-10 2005-02-24 Light emitting ball for ball game
ES05719864T ES2373315T3 (en) 2004-03-10 2005-02-24 BALL LIGHTING STATION FOR BALL GAMES.

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8021252B2 (en) 2005-04-08 2011-09-20 Geodoen Holding FZC Sports ball with a woven fabric and method for manufacturing such a sports ball
JP2013500387A (en) * 2009-07-27 2013-01-07 サイリューム・テクノロジーズ・インコーポレイテッド Combined heat and chemiluminescence reaction system
JP2014012232A (en) * 2013-10-22 2014-01-23 Molten Corp Ball

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20080116643A1 (en) * 2006-07-20 2008-05-22 Miranda Gregory A Football playing piece
GB2441743B (en) * 2006-09-13 2011-02-09 David Leslie Brown Illuminated tennis ball and tennis playing kit
US20110177894A1 (en) * 2010-01-19 2011-07-21 Corrie Brewster Antennabilia
US20110218065A1 (en) * 2010-03-04 2011-09-08 Cavallaro Richard H Ball
US20120244969A1 (en) 2011-03-25 2012-09-27 May Patents Ltd. System and Method for a Motion Sensing Device
US8663040B2 (en) * 2011-07-29 2014-03-04 Bede Kortegast Illuminated game ball and kit
US9448002B2 (en) * 2011-12-15 2016-09-20 Ignacio Marc Asperas Snow man making device for making a snow person having light emitting structures
US9211446B2 (en) * 2013-03-15 2015-12-15 Nike, Inc. Sport ball bladder with a pocket
USD754862S1 (en) * 2013-11-27 2016-04-26 Tracey Huff Decorated bandage clip
US20160001137A1 (en) * 2014-07-07 2016-01-07 Bradley Gene Phillips Illumination system for a sports ball
CN105318279A (en) * 2014-07-17 2016-02-10 应后右 Mirror surface ball
US10799769B2 (en) 2015-03-19 2020-10-13 Gigglicious, LLC Two layer recreational air-tight object having a patterned illuminated surface
TWM520923U (en) * 2016-01-30 2016-05-01 和碩聯合科技股份有限公司 Ball
TWI589334B (en) * 2016-02-26 2017-07-01 和碩聯合科技股份有限公司 Ball
USD783099S1 (en) * 2016-03-04 2017-04-04 Intersell Ventures Ball
USD811609S1 (en) * 2016-05-22 2018-02-27 Tracey Jean Huff Bandage clip
RU195571U1 (en) * 2019-12-31 2020-01-31 Леонид Евгеньевич Селявко Hexagonal chip for group lessons on the restoration of visual memory in patients with a neurological clinic
US11559725B1 (en) 2021-08-26 2023-01-24 Southern Telecom Inc. Lighted sports ball, kit, and method of use thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0487165A (en) 1990-07-26 1992-03-19 Japan Aviation Electron Ind Ltd Contact
JPH0675608B2 (en) * 1985-06-28 1994-09-28 ブリヂストンスポーツ株式会社 Luminous golf ball
US5779575A (en) * 1996-06-18 1998-07-14 Hsieh; Frank Lumious games spherical body
WO2000010646A2 (en) * 1998-08-25 2000-03-02 Fire Flyz, Inc. Illuminated game balls and balloons
JP2003229002A (en) * 2002-02-04 2003-08-15 Lumica Corp Luminous case

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2387433A (en) * 1944-10-16 1945-10-23 Sun Rubber Co Valve for hollow inflatable articles
JPS4924358U (en) * 1972-06-01 1974-03-01
US4577865A (en) * 1983-06-16 1986-03-25 Molten Corporation Athletic ball
JPS60199474A (en) * 1984-03-26 1985-10-08 株式会社モルテン Athletic ball
US4776589A (en) * 1987-01-28 1988-10-11 Yang Chao Ming Lighted inflatable ball
US4930776A (en) * 1989-08-03 1990-06-05 Newcomb Nelson F Game ball
US4963117A (en) * 1989-10-30 1990-10-16 Gualdoni Kevin G Selectively illuminated toy ball
US5102131A (en) * 1990-07-24 1992-04-07 Bruce Remington Luminous game balls
US5186458A (en) * 1991-10-21 1993-02-16 Redondo Ronald E Illuminated playing ball
US5236383A (en) * 1991-11-27 1993-08-17 I & K Trading Corporation Illuminated toy ball
JPH0639035U (en) * 1992-11-06 1994-05-24 壽 中村 Hikaru Ball
US5403000A (en) * 1993-02-24 1995-04-04 Woosley; John Illuminated game ball apparatus
US5683316A (en) * 1995-11-28 1997-11-04 Campbell; Daniel Scott Illuminated sports ball
US5639076A (en) * 1996-01-03 1997-06-17 Counter Punch Group Lighted inflatable device with long battery life
US5762573A (en) * 1996-06-13 1998-06-09 Lisco, Inc. Game ball with a hologram image
US6656066B2 (en) * 2001-07-18 2003-12-02 Michael Joseph Barker Lighted strap assembly for a ball
US6726580B2 (en) * 2002-04-19 2004-04-27 Peterson Lloyd E Football style thrown objects having light sticks
US20040220001A1 (en) * 2003-05-01 2004-11-04 Oister Michael J. Lighted sports game
US7179181B2 (en) * 2005-07-19 2007-02-20 Li-Lin Ko Illuminating ball

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0675608B2 (en) * 1985-06-28 1994-09-28 ブリヂストンスポーツ株式会社 Luminous golf ball
JPH0487165A (en) 1990-07-26 1992-03-19 Japan Aviation Electron Ind Ltd Contact
US5779575A (en) * 1996-06-18 1998-07-14 Hsieh; Frank Lumious games spherical body
WO2000010646A2 (en) * 1998-08-25 2000-03-02 Fire Flyz, Inc. Illuminated game balls and balloons
JP2003229002A (en) * 2002-02-04 2003-08-15 Lumica Corp Luminous case

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8021252B2 (en) 2005-04-08 2011-09-20 Geodoen Holding FZC Sports ball with a woven fabric and method for manufacturing such a sports ball
JP2013500387A (en) * 2009-07-27 2013-01-07 サイリューム・テクノロジーズ・インコーポレイテッド Combined heat and chemiluminescence reaction system
JP2014012232A (en) * 2013-10-22 2014-01-23 Molten Corp Ball

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ATE534439T1 (en) 2011-12-15
EP1726336B1 (en) 2011-11-23
EP1726336A1 (en) 2006-11-29
US20080132363A1 (en) 2008-06-05
JP4598768B2 (en) 2010-12-15
KR100726047B1 (en) 2007-06-08
CN1917923A (en) 2007-02-21
KR20060116854A (en) 2006-11-15
JPWO2005087326A1 (en) 2008-01-24
ES2373315T3 (en) 2012-02-02
EP1726336A4 (en) 2009-12-23

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