WO2005070855A1 - Integrated process for acetic acid and methanol - Google Patents
Integrated process for acetic acid and methanol Download PDFInfo
- Publication number
- WO2005070855A1 WO2005070855A1 PCT/CY2004/000002 CY2004000002W WO2005070855A1 WO 2005070855 A1 WO2005070855 A1 WO 2005070855A1 CY 2004000002 W CY2004000002 W CY 2004000002W WO 2005070855 A1 WO2005070855 A1 WO 2005070855A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- stream
- methanol
- acetic acid
- syngas
- preceeding
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
- C07C29/1516—Multisteps
- C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
- C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
- C07C53/08—Acetic acid
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/04—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds
- C07C67/05—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides onto unsaturated carbon-to-carbon bonds with oxidation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
Definitions
- VAM vinyl acetate monomer
- Methanol is a major chemical raw material.
- present invention permits the construction of highly efficient single-train
- Patent Nos. 1,961,736 to Carlin et al (Tennessee Products); 3,769,329 to Paulik et al (Monsanto); 5,155,261 to Marston et al (Reilly Industries);
- the primary raw materials for acetic acid manufacture are, of
- Banquy discloses in U.S. Patent Nos. 4,888,130 and 4,999,133, a process
- autothermal reforming can be used when the feedstock is light natural gas, but he
- syngas having an SN between 1.4 and 2.1.
- reformer can be better matched for methanol production by integrating an acetic
- the present invention integrates a methanol synthesis process with
- the invention takes advantage of having a carbon monoxide
- the invention provides a method that produces methanol, acetic
- the invention provides an integrated method
- the process comprises separating a
- hydrocarbon source into first and second hydrocarbon streams, reforming the first
- the SN can be adjusted by importing a C02 stream into the methanol synthesis gas makeup stream to increase the C02 content, or by
- the C02-rich stream can be obtained from the separation of the syngas
- a purge gas stream from the methanol synthesis loop is preferably
- the separation step preferably includes supplying
- Carbon dioxide emissions (measured as
- carbon dioxide mass for the integrated complex are preferably less than 10 percent
- the process can further include synthesizing acetic acid from at
- associated process preferably uses the acetic acid as a reactant, uses the methanol
- the method can also include supplying an imported carbon dioxide stream
- At least a portion of the acetic acid produced can be supplied to a
- VAM vinyl acetate monomer
- VAM VAM
- the feed stream can also be pretreated by hydrogenation to allow a lower steam to carbon ratio to be employed while avoiding soot formation in the
- hydrogen-rich stream is added to a feed gas stream containing higher hydrocarbons
- stream is preferably a purge gas or fraction thereof from a methanol synthesis loop
- the hydrogen-rich stream is
- temperature can preferably be from 300°C to 550°C.
- embodiment includes a feed gas supply comprising higher hydrocarbons; a pre-
- base metals such as
- alumina or a zeolite are commonly used as catalyst; an autothermal reformer for
- the method can also include providing at least a portion of the
- a C02-rich stream is
- Fig. 1 is a simplified block flow diagram of an embodiment
- Fig. 2 is a simplified block flow of an embodiment similar to Fig.
- the plant for the process can be a new plant, but it could also be a
- Natural gas 102 is provided as both fuel 103 for the plant as well
- the natural gas is supplied to a conventional
- the first stream 111 is fed to either an adiabatic
- the steam reformer 109 operates at
- oxygen 114 obtained from an air separation unit (ASU) 116, and a
- Air is compressed in compressor 115 and fed to
- ASU 116 which is operated in a conventional manner to obtain the oxygen
- syngas stream 120 is conventionally produced
- a portion of the syngas stream 120 is fed to C02 removal unit
- the amount of syngas in stream 119 depends primarily on the amount of CO
- ASU can be exceeded, requiring the excessive capital cost of a second ASU
- C02 removal unit 122 can use conventional C02 removal
- the methanol synthesis loop purge gas stream 124 all or a portion of
- a combination thereof can also, if desired, be fed to the removal unit via line 119.
- the C02 removal unit produces a C02-rich stream 110 and a mixed CO/H2 stream 128 essentially free of C02.
- the C02-rich stream 110 is
- Separation unit 130 which is preferably a conventional cold box,
- the separation unit 130 can be, for example, a partial condensation box
- the CO-rich stream 132 can be supplied to the acetic acid
- the SN of the syngas is between 2.0
- synthesis unit 140 is preferably recycled to the C02 removal unit 122, as
- the purge gas stream 124 is necessary to
- cold box 130 has the advantage of recycling the C02, CO and hydrogen from the
- Purified methanol is exported as product via line 144, or a portion may be supplied to the
- the acetic acid synthesis unit 136 employs conventional acetic acid
- stream 135 and methanol via stream 145 such as, for example, from one or more
- reaction mixture comprising carbon monoxide, water, a solvent and
- a catalyst system comprising at least one halogenated promoter and at least one
- reaction mixture a compound of rhodium, iridium, or a combination thereof.
- reaction comprises
- reaction mixture preferably contains a nonzero quantity of
- a portion of the acetic acid from line 146 can be fed via
- VAM vinyl acetate monomer
- a liquid product stream 152 is processed in
- VAM via line 158. Carbon dioxide by-product from the VAM
- the oxygen in line 114 can be obtained, for example, using a conventional
- VAM production is mainly achieved by the acetoxylation of
- the main by-product is C02 formed by the reaction: C2H4 + 302 --> 2C02 + 2H2 O [0034] Selectivity for this process yields approximately 7-8% C02 by
- VAM plant producing approximately 100,000 metric tons per year
- Utilities 160 which typically include the steam system, cooling
- associated integrated unit can be used to drive or supply steam to the boiler feed
- steam is produced by steam reforming, there is preferably no steam exported by
- An auxiliary boiler can supply
- Example 1 In this example, flow rates, compositions and
- Natural gas 102 is provided at 194,000 Nm3/h as
- the natural gas has a composition of approximately 89.5% methane,
- the ATR 118 consumes a
- the C02-rich stream 110 is described
- the C02-lean stream comprises 116,000 Nm3/h of gas with a composition of 25% CO, 71.6% hydrogen, 2% methane, 1.3% nitrogen and less
- the cold box 130 produces a 19,400 Nm3/h stream 132
- a 65,000 Nm3/h tail gas stream 134 comprising 11% CO, 84%
- Nm3/h stream 131 comprising 90% hydrogen, 8.5% CO and less than 1% each of
- the unit 140 produces the purge gas stream 124
- Stream 145 supplies 26,000 kg/h of methanol to the acetic acid
- a portion of the acetic acid from line 146 is fed at a rate of
- VAM synthesis unit 148 22,000 kg/h to VAM synthesis unit 148 where it is reacted with 10,000 Nm3/h of polymerization grade ethylene comprising more than 99.9% ethylene, and less
- VAM production is mainly achieved by
- a C02 stream comprising more than 98% C02, is
- Example 2 In this example, flow rates, compositions and
- Natural gas 102 is provided at 182,000 Nm3/h as
- the natural gas has a composition of approximately 89.5%>
- desulfurization unit 104 exits via line 112 and is fed to the autothermal reformer
- the ATR 118 consumes a 117,000 kg/h
- the C02 removal unit 122 via 119.
- the C02-rich stream 110 is described above,
- the C02-lean stream comprises 235,000 Nm3/h of gas with a composition of 23%) CO, 68% hydrogen, 5% methane, 3% nitrogen and trace amounts of argon,
- the cold box is based on a methane wash process
- stream 214 comprises nitrogen and CO in approximately the same
- This stream is treated in a VSA (Vacuum Swing Absorber)
- VSA 206 also produces nitrogen stream 204.
- Cold box 130 produces a 44,000
- tail gas stream 202 of 9,200 Nm3/h comprising more than
- Tail gas stream 202 can
- Nm3/h of makeup gas comprising 68%> hydrogen, 22%> CO, 7.5% C02, 1.6%
- Stream 145 supplies 65,000 kg/h of methanol to acetic acid
- a portion of the acetic acid product 146 is fed via 147 to VAM
- ethylene comprising more than 99.9%) ethylene, and less than 0.1% of impurities
- VAM production is mainly achieved by the acetoxylation of ethylene.
- the integrated methanol acetic acid plant produces methanol and acetic
Abstract
Description
Claims
Priority Applications (17)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA2551223A CA2551223C (en) | 2004-01-22 | 2004-01-22 | Integrated process for acetic acid and methanol |
KR1020107026583A KR20100131528A (en) | 2004-01-22 | 2004-01-22 | Integrated process for acetic acid and methanol |
NZ548230A NZ548230A (en) | 2004-01-22 | 2004-01-22 | Integrated process for making acetic acid and methanol from natural gas |
YUP-2006/0418A RS20060418A (en) | 2004-01-22 | 2004-01-22 | Integrated process for acetic acid and methanol |
PCT/CY2004/000002 WO2005070855A1 (en) | 2004-01-22 | 2004-01-22 | Integrated process for acetic acid and methanol |
AU2004314237A AU2004314237B2 (en) | 2004-01-22 | 2004-01-22 | Integrated process for acetic acid and methanol |
KR1020067016763A KR101046116B1 (en) | 2004-01-22 | 2004-01-22 | Integrated method for acetic acid and methanol |
PL380241A PL209862B1 (en) | 2004-01-22 | 2004-01-22 | Integrated process for acetic acid and methanol |
US10/596,955 US7470811B2 (en) | 2004-01-22 | 2004-01-22 | Integrated process for acetic acid and methanol |
MXPA06007682A MXPA06007682A (en) | 2004-01-22 | 2004-01-22 | Integrated process for acetic acid and methanol. |
JP2006549841A JP4633741B2 (en) | 2004-01-22 | 2004-01-22 | Integrated process of acetic acid and methanol |
EP04738452A EP1708982A1 (en) | 2004-01-22 | 2004-01-22 | Integrated process for acetic acid and methanol |
UAA200609271A UA85579C2 (en) | 2004-01-22 | 2004-01-22 | Integrated process for acetic acid and methanol production |
BRPI0418477-7A BRPI0418477B1 (en) | 2004-01-22 | 2004-01-22 | Method for the manufacture of methanol and acetic acid |
CN2004800405271A CN1906145B (en) | 2004-01-22 | 2004-01-22 | Integrated process for acetic acid and methanol |
ZA2006/05928A ZA200605928B (en) | 2004-01-22 | 2006-07-18 | Integrated process for acetic acid and methanol |
NO20063692A NO20063692L (en) | 2004-01-22 | 2006-08-17 | Integrated process for acetic acid and methanol |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/CY2004/000002 WO2005070855A1 (en) | 2004-01-22 | 2004-01-22 | Integrated process for acetic acid and methanol |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2005070855A1 true WO2005070855A1 (en) | 2005-08-04 |
Family
ID=34800359
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/CY2004/000002 WO2005070855A1 (en) | 2004-01-22 | 2004-01-22 | Integrated process for acetic acid and methanol |
Country Status (16)
Country | Link |
---|---|
US (1) | US7470811B2 (en) |
EP (1) | EP1708982A1 (en) |
JP (1) | JP4633741B2 (en) |
KR (2) | KR101046116B1 (en) |
CN (1) | CN1906145B (en) |
AU (1) | AU2004314237B2 (en) |
BR (1) | BRPI0418477B1 (en) |
CA (1) | CA2551223C (en) |
MX (1) | MXPA06007682A (en) |
NO (1) | NO20063692L (en) |
NZ (1) | NZ548230A (en) |
PL (1) | PL209862B1 (en) |
RS (1) | RS20060418A (en) |
UA (1) | UA85579C2 (en) |
WO (1) | WO2005070855A1 (en) |
ZA (1) | ZA200605928B (en) |
Cited By (5)
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---|---|---|---|---|
WO2007053261A2 (en) * | 2005-11-01 | 2007-05-10 | Celanese International Corporation | Steam generation apparatus and method |
WO2011018233A1 (en) | 2009-08-14 | 2011-02-17 | Saudi Basic Industries Corporation (Sabic) | Combined reforming process for methanol production |
GB2585477A (en) * | 2019-06-12 | 2021-01-13 | Johnson Matthey Davy Technologies Ltd | Process for synthesising methanol |
GB2585478A (en) * | 2019-06-12 | 2021-01-13 | Johnson Matthey Davy Technologies Ltd | Process for synthesising methanol |
WO2023166438A1 (en) * | 2022-03-03 | 2023-09-07 | Politecnico Di Milano | Zero-emission self-sustainable process for producing chemicals from organic sources |
Families Citing this family (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
MY146697A (en) * | 2004-07-09 | 2012-09-14 | Acetex Cyprus Ltd | Preparation of syngas for acetic acid synthesis by partial oxidation of methanol feedstock |
US7569085B2 (en) * | 2004-12-27 | 2009-08-04 | General Electric Company | System and method for hydrogen production |
GB0510823D0 (en) * | 2005-05-27 | 2005-07-06 | Johnson Matthey Plc | Methanol synthesis |
EP2228358A1 (en) * | 2009-03-13 | 2010-09-15 | Methanol Casale S.A. | Recovery of CO2 in a process for synthesis of methanol |
US20120067079A1 (en) * | 2010-03-25 | 2012-03-22 | Sethna Rustam H | Nitrogen rejection and liquifier system for liquified natural gas production |
CN201768471U (en) * | 2010-07-23 | 2011-03-23 | 镇海石化建安工程有限公司 | Low temperature methanol washing raw gas cooler |
US9561476B2 (en) | 2010-12-15 | 2017-02-07 | Praxair Technology, Inc. | Catalyst containing oxygen transport membrane |
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US9486735B2 (en) | 2011-12-15 | 2016-11-08 | Praxair Technology, Inc. | Composite oxygen transport membrane |
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US9453644B2 (en) | 2012-12-28 | 2016-09-27 | Praxair Technology, Inc. | Oxygen transport membrane based advanced power cycle with low pressure synthesis gas slip stream |
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US9255051B2 (en) | 2013-03-15 | 2016-02-09 | Gas Technologies Llc | Efficiency, flexibility, and product value of a direct alkanes to oxygenates process |
US20140275634A1 (en) | 2013-03-15 | 2014-09-18 | Gas Technologies Llc | Ether Blends Via Reactive Distillation |
US9296671B2 (en) | 2013-04-26 | 2016-03-29 | Praxair Technology, Inc. | Method and system for producing methanol using an integrated oxygen transport membrane based reforming system |
US9611144B2 (en) | 2013-04-26 | 2017-04-04 | Praxair Technology, Inc. | Method and system for producing a synthesis gas in an oxygen transport membrane based reforming system that is free of metal dusting corrosion |
US9938145B2 (en) | 2013-04-26 | 2018-04-10 | Praxair Technology, Inc. | Method and system for adjusting synthesis gas module in an oxygen transport membrane based reforming system |
US9115045B2 (en) | 2013-04-26 | 2015-08-25 | Praxair Technology, Inc. | Method and system for producing methanol using an oxygen transport membrane based reforming system |
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US9365422B2 (en) | 2013-04-26 | 2016-06-14 | Praxair Technology, Inc. | Method and system for producing a synthesis gas in an oxygen transport membrane based reforming system with recycling of the produced synthesis gas |
US9023245B2 (en) | 2013-04-26 | 2015-05-05 | Praxair Technology, Inc. | Method and system for producing a synthesis gas using an oxygen transport membrane based reforming system with secondary reforming |
RU2664516C2 (en) | 2013-09-05 | 2018-08-20 | Праксайр Текнолоджи, Инк. | Method and system for producing methanol using integrated oxygen transport membrane based reforming system |
US9587189B2 (en) | 2013-10-01 | 2017-03-07 | Gas Technologies L.L.C. | Diesel fuel composition |
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US9573094B2 (en) | 2013-10-08 | 2017-02-21 | Praxair Technology, Inc. | System and method for temperature control in an oxygen transport membrane based reactor |
CN105764842B (en) | 2013-12-02 | 2018-06-05 | 普莱克斯技术有限公司 | Use the method and system of the production hydrogen of the reforming system based on oxygen transport film with two process transform |
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WO2015165818A1 (en) * | 2014-04-29 | 2015-11-05 | Haldor Topsøe A/S | Process for production of methanol |
WO2016057164A1 (en) | 2014-10-07 | 2016-04-14 | Praxair Technology, Inc | Composite oxygen ion transport membrane |
CN107001036B (en) * | 2014-11-25 | 2019-05-28 | 托普索公司 | A method of synthesis gas is generated by flue gas recirculation |
US10441922B2 (en) | 2015-06-29 | 2019-10-15 | Praxair Technology, Inc. | Dual function composite oxygen transport membrane |
US10118823B2 (en) | 2015-12-15 | 2018-11-06 | Praxair Technology, Inc. | Method of thermally-stabilizing an oxygen transport membrane-based reforming system |
US9938146B2 (en) | 2015-12-28 | 2018-04-10 | Praxair Technology, Inc. | High aspect ratio catalytic reactor and catalyst inserts therefor |
CN109070014A (en) | 2016-04-01 | 2018-12-21 | 普莱克斯技术有限公司 | Oxygen transport membrane containing catalyst |
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WO2019212072A1 (en) * | 2018-05-02 | 2019-11-07 | 한국과학기술원 | Acetic acid production method using dry reforming process using carbon dioxide and system for same |
EP3797085A1 (en) | 2018-05-21 | 2021-03-31 | Praxair Technology, Inc. | Otm syngas panel with gas heated reformer |
JP2024503110A (en) | 2021-01-15 | 2024-01-24 | セエルイ フルタフェラク | methanol synthesis reactor |
US11407667B1 (en) | 2021-06-06 | 2022-08-09 | Christopher R. Moylan | Systems and methods for removal of carbon dioxide from seawater |
US11685673B2 (en) | 2021-06-06 | 2023-06-27 | Christopher R. Moylan | Systems and methods for removal of carbon dioxide from seawater |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003097523A2 (en) * | 2002-05-20 | 2003-11-27 | Acetex (Cyprus) Limited | Integrated process for making acetic acid and methanol |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2372116A1 (en) * | 1977-03-22 | 1978-06-23 | Banquy David | SYNTHESIS GAS PRODUCTION PROCESS |
US6781014B1 (en) * | 1999-11-01 | 2004-08-24 | Acetex (Cyprus) Limited | Methanol plant retrofit for manufacture of acetic acid |
US6444712B1 (en) * | 2000-09-28 | 2002-09-03 | Exxonmobil Chemical Patents, Inc. | Methanol, olefin, and hydrocarbon synthesis process |
US6495609B1 (en) * | 2000-11-03 | 2002-12-17 | Exxonmobil Chemical Patents Inc. | Carbon dioxide recovery in an ethylene to ethylene oxide production process |
US7151198B2 (en) * | 2002-12-30 | 2006-12-19 | Exxonmobil Chemical Patents Inc. | Integration of a methanol synthesis system with a methanol to olefin reaction system |
US6846951B1 (en) * | 2003-10-09 | 2005-01-25 | Acetex (Cyprus) Limited | Integrated process for acetic acid and methanol |
US7199276B2 (en) * | 2003-11-19 | 2007-04-03 | Exxonmobil Chemical Patents Inc. | Controlling the ratio of ethylene to propylene produced in an oxygenate to olefin conversion process |
US7304197B2 (en) * | 2003-11-24 | 2007-12-04 | Exxonmobil Chemical Patents Inc. | Recycling oxygenate-rich streams in oxygenate-to-olefin processes |
-
2004
- 2004-01-22 EP EP04738452A patent/EP1708982A1/en not_active Withdrawn
- 2004-01-22 US US10/596,955 patent/US7470811B2/en not_active Expired - Fee Related
- 2004-01-22 UA UAA200609271A patent/UA85579C2/en unknown
- 2004-01-22 KR KR1020067016763A patent/KR101046116B1/en not_active IP Right Cessation
- 2004-01-22 JP JP2006549841A patent/JP4633741B2/en not_active Expired - Fee Related
- 2004-01-22 CN CN2004800405271A patent/CN1906145B/en not_active Expired - Fee Related
- 2004-01-22 RS YUP-2006/0418A patent/RS20060418A/en unknown
- 2004-01-22 KR KR1020107026583A patent/KR20100131528A/en not_active Application Discontinuation
- 2004-01-22 PL PL380241A patent/PL209862B1/en unknown
- 2004-01-22 MX MXPA06007682A patent/MXPA06007682A/en active IP Right Grant
- 2004-01-22 WO PCT/CY2004/000002 patent/WO2005070855A1/en active Application Filing
- 2004-01-22 NZ NZ548230A patent/NZ548230A/en not_active IP Right Cessation
- 2004-01-22 AU AU2004314237A patent/AU2004314237B2/en not_active Ceased
- 2004-01-22 CA CA2551223A patent/CA2551223C/en not_active Expired - Fee Related
- 2004-01-22 BR BRPI0418477-7A patent/BRPI0418477B1/en not_active IP Right Cessation
-
2006
- 2006-07-18 ZA ZA2006/05928A patent/ZA200605928B/en unknown
- 2006-08-17 NO NO20063692A patent/NO20063692L/en not_active Application Discontinuation
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2003097523A2 (en) * | 2002-05-20 | 2003-11-27 | Acetex (Cyprus) Limited | Integrated process for making acetic acid and methanol |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007053261A2 (en) * | 2005-11-01 | 2007-05-10 | Celanese International Corporation | Steam generation apparatus and method |
WO2007053261A3 (en) * | 2005-11-01 | 2007-11-22 | Celanese Int Corp | Steam generation apparatus and method |
WO2011018233A1 (en) | 2009-08-14 | 2011-02-17 | Saudi Basic Industries Corporation (Sabic) | Combined reforming process for methanol production |
CN102498060A (en) * | 2009-08-14 | 2012-06-13 | 沙特基础工业公司 | Combined reforming process for methanol production |
US9079770B2 (en) | 2009-08-14 | 2015-07-14 | Saudi Basic Industries Corporation | Combined reforming process for methanol production |
GB2585477A (en) * | 2019-06-12 | 2021-01-13 | Johnson Matthey Davy Technologies Ltd | Process for synthesising methanol |
GB2585478A (en) * | 2019-06-12 | 2021-01-13 | Johnson Matthey Davy Technologies Ltd | Process for synthesising methanol |
GB2585477B (en) * | 2019-06-12 | 2021-08-11 | Johnson Matthey Davy Technologies Ltd | Process for synthesising methanol |
GB2585478B (en) * | 2019-06-12 | 2021-10-06 | Johnson Matthey Davy Technologies Ltd | Process for synthesising methanol |
US11851393B2 (en) | 2019-06-12 | 2023-12-26 | Johnson Matthey Davy Technologies Limited | Process for synthesising methanol |
US11851394B2 (en) | 2019-06-12 | 2023-12-26 | Johnson Matthey Davy Technologies Limited | Process for synthesising methanol |
WO2023166438A1 (en) * | 2022-03-03 | 2023-09-07 | Politecnico Di Milano | Zero-emission self-sustainable process for producing chemicals from organic sources |
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BRPI0418477A (en) | 2007-06-19 |
PL380241A1 (en) | 2007-01-08 |
RS20060418A (en) | 2008-09-29 |
CN1906145A (en) | 2007-01-31 |
MXPA06007682A (en) | 2007-01-26 |
BRPI0418477B1 (en) | 2015-04-22 |
EP1708982A1 (en) | 2006-10-11 |
NO20063692L (en) | 2006-10-19 |
JP2007518745A (en) | 2007-07-12 |
NZ548230A (en) | 2009-08-28 |
CA2551223C (en) | 2011-05-03 |
ZA200605928B (en) | 2008-01-08 |
US20080039652A1 (en) | 2008-02-14 |
KR20100131528A (en) | 2010-12-15 |
CN1906145B (en) | 2010-09-29 |
KR101046116B1 (en) | 2011-07-01 |
AU2004314237A1 (en) | 2005-08-04 |
JP4633741B2 (en) | 2011-02-16 |
AU2004314237B2 (en) | 2011-03-10 |
PL209862B1 (en) | 2011-10-31 |
CA2551223A1 (en) | 2005-08-04 |
UA85579C2 (en) | 2009-02-10 |
US7470811B2 (en) | 2008-12-30 |
KR20070001962A (en) | 2007-01-04 |
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