WO2004082819A3 - Partial oxidation reactors and syngas coolers using nickel-containing components - Google Patents

Partial oxidation reactors and syngas coolers using nickel-containing components Download PDF

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Publication number
WO2004082819A3
WO2004082819A3 PCT/US2004/007788 US2004007788W WO2004082819A3 WO 2004082819 A3 WO2004082819 A3 WO 2004082819A3 US 2004007788 W US2004007788 W US 2004007788W WO 2004082819 A3 WO2004082819 A3 WO 2004082819A3
Authority
WO
WIPO (PCT)
Prior art keywords
nickel
partial oxidation
containing components
methods
zone
Prior art date
Application number
PCT/US2004/007788
Other languages
French (fr)
Other versions
WO2004082819A2 (en
Inventor
Chien-Ping Pan
Harold A Wright
Original Assignee
Conocophillips Co
Chien-Ping Pan
Harold A Wright
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Conocophillips Co, Chien-Ping Pan, Harold A Wright filed Critical Conocophillips Co
Publication of WO2004082819A2 publication Critical patent/WO2004082819A2/en
Publication of WO2004082819A3 publication Critical patent/WO2004082819A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0006—Controlling or regulating processes
    • B01J19/002—Avoiding undesirable reactions or side-effects, e.g. avoiding explosions, or improving the yield by suppressing side-reactions
    • B01J19/0026—Avoiding carbon deposits
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/02—Apparatus characterised by being constructed of material selected for its chemically-resistant properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/0242—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical
    • B01J8/025—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid flow within the bed being predominantly vertical in a cylindrical shaped bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
    • B01J8/1836—Heating and cooling the reactor
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22C—ALLOYS
    • C22C19/00—Alloys based on nickel or cobalt
    • C22C19/03—Alloys based on nickel or cobalt based on nickel
    • C22C19/05—Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/058—Alloys based on nickel or cobalt based on nickel with chromium without Mo and W
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00106—Controlling the temperature by indirect heat exchange
    • B01J2208/00115—Controlling the temperature by indirect heat exchange with heat exchange elements inside the bed of solid particles
    • B01J2208/00132—Tubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00245—Avoiding undesirable reactions or side-effects
    • B01J2219/00247—Fouling of the reactor or the process equipment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/02—Apparatus characterised by their chemically-resistant properties
    • B01J2219/025—Apparatus characterised by their chemically-resistant properties characterised by the construction materials of the reactor vessel proper
    • B01J2219/0277—Metal based
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/062—Hydrocarbon production, e.g. Fischer-Tropsch process
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0872—Methods of cooling
    • C01B2203/0883—Methods of cooling by indirect heat exchange
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1276—Mixing of different feed components

Abstract

Disclosed are methods and apparatus for producing synthesis gas and higher hydrocarbons from light hydrocarbons and molecular oxygen as well as the higher hydrocarbons produced by the disclosed methods and apparatus. The methods and apparatus disclosed utilize components comprising nickel and nickel alloys. The apparatus comprises a synthesis gas reactor (10) having a mixing zone (30), a reaction zone (100) housing a catalyst zone (60), a catalyst shield (90), and a cooling zone (40) comprising a series of tubes.
PCT/US2004/007788 2003-03-14 2004-03-12 Partial oxidation reactors and syngas coolers using nickel-containing components WO2004082819A2 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/389,068 2003-03-14
US10/389,068 US7125913B2 (en) 2003-03-14 2003-03-14 Partial oxidation reactors and syngas coolers using nickel-containing components

Publications (2)

Publication Number Publication Date
WO2004082819A2 WO2004082819A2 (en) 2004-09-30
WO2004082819A3 true WO2004082819A3 (en) 2004-11-18

Family

ID=32962190

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2004/007788 WO2004082819A2 (en) 2003-03-14 2004-03-12 Partial oxidation reactors and syngas coolers using nickel-containing components

Country Status (2)

Country Link
US (1) US7125913B2 (en)
WO (1) WO2004082819A2 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7932296B2 (en) * 2003-03-16 2011-04-26 Kellogg Brown & Root Llc Catalytic partial oxidation reforming for syngas processing and products made therefrom
US8273139B2 (en) * 2003-03-16 2012-09-25 Kellogg Brown & Root Llc Catalytic partial oxidation reforming
WO2008027181A2 (en) * 2006-08-25 2008-03-06 Exxonmobil Chemical Patents Inc. Production of aromatics from methane
DE102007022723A1 (en) * 2007-05-11 2008-11-13 Basf Se Process for the production of synthesis gas
US8752615B2 (en) 2008-01-08 2014-06-17 General Electric Company Methods and systems for controlling temperature in a vessel
US8168687B2 (en) 2009-11-30 2012-05-01 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Process for decreasing or eliminating unwanted hydrocarbon and oxygenate products caused by Fisher Tropsch synthesis reactions in a syngas treatment unit
US8163809B2 (en) * 2009-11-30 2012-04-24 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Process for decreasing or eliminating unwanted hydrocarbon and oxygenate products caused by Fisher Tropsch Synthesis reactions in a syngas treatment unit
US8202914B2 (en) * 2010-02-22 2012-06-19 L'air Liquide Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude Process for decreasing or eliminating unwanted hydrocarbon and oxygenate products caused by Fisher Tropsch Synthesis reactions in a syngas treatment unit
US8354082B2 (en) * 2010-03-17 2013-01-15 General Electric Company System for heat integration with methanation system
CN113461478A (en) * 2020-03-30 2021-10-01 中国石油化工股份有限公司 Reactor for oxidative coupling of methane and application thereof

Citations (3)

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US4822521A (en) * 1983-06-09 1989-04-18 Uop Integrated process and apparatus for the primary and secondary catalytic steam reforming of hydrocarbons
US5112527A (en) * 1991-04-02 1992-05-12 Amoco Corporation Process for converting natural gas to synthesis gas
US5254318A (en) * 1992-07-20 1993-10-19 Stone & Webster Engineering Corporation Lined reformer tubes for high pressure reformer reactors

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JP2737914B2 (en) * 1988-04-13 1998-04-08 三菱瓦斯化学株式会社 Prussic acid reactor
JPH0751527B2 (en) * 1988-10-31 1995-06-05 ポリプラスチックス株式会社 Equipment for handling formaldehyde-containing gas or liquid
SA05260056B1 (en) * 1991-03-08 2008-03-26 شيفرون فيليبس كيميكال كمبني ال بي Hydrocarbon processing device
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US5545337A (en) * 1994-11-29 1996-08-13 Modar, Inc. Ceramic coating system or water oxidation environments
US6187226B1 (en) * 1995-03-14 2001-02-13 Bechtel Bwxt Idaho, Llc Thermal device and method for production of carbon monoxide and hydrogen by thermal dissociation of hydrocarbon gases
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US6368997B2 (en) * 1998-05-22 2002-04-09 Conoco Inc. Fischer-Tropsch processes and catalysts using fluorided supports
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EP1315670B1 (en) * 2000-09-05 2007-07-25 Conocophillips Company Process for producing synthesis gas with lanthanide-promoted rhodium catalysts
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US5112527A (en) * 1991-04-02 1992-05-12 Amoco Corporation Process for converting natural gas to synthesis gas
US5254318A (en) * 1992-07-20 1993-10-19 Stone & Webster Engineering Corporation Lined reformer tubes for high pressure reformer reactors

Also Published As

Publication number Publication date
US20040180975A1 (en) 2004-09-16
WO2004082819A2 (en) 2004-09-30
US7125913B2 (en) 2006-10-24

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