WO2004080826B1 - Reusable closures for packages and methods of making and using the same - Google Patents

Reusable closures for packages and methods of making and using the same

Info

Publication number
WO2004080826B1
WO2004080826B1 PCT/US2004/007106 US2004007106W WO2004080826B1 WO 2004080826 B1 WO2004080826 B1 WO 2004080826B1 US 2004007106 W US2004007106 W US 2004007106W WO 2004080826 B1 WO2004080826 B1 WO 2004080826B1
Authority
WO
WIPO (PCT)
Prior art keywords
adhesive
package
article
removable
substrate
Prior art date
Application number
PCT/US2004/007106
Other languages
French (fr)
Other versions
WO2004080826A2 (en
WO2004080826A3 (en
Inventor
Driesten Sjoerd Johannes Van
Original Assignee
Avery Dennison Corp
Driesten Sjoerd Johannes Van
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Avery Dennison Corp, Driesten Sjoerd Johannes Van filed Critical Avery Dennison Corp
Priority to CA 2518892 priority Critical patent/CA2518892A1/en
Priority to BRPI0408289 priority patent/BRPI0408289A/en
Priority to AU2004220101A priority patent/AU2004220101B2/en
Priority to EP04718821A priority patent/EP1601579A4/en
Priority to EP10003070.9A priority patent/EP2228211B1/en
Publication of WO2004080826A2 publication Critical patent/WO2004080826A2/en
Publication of WO2004080826A3 publication Critical patent/WO2004080826A3/en
Publication of WO2004080826B1 publication Critical patent/WO2004080826B1/en
Priority to KR1020057017024A priority patent/KR101099054B1/en
Priority to AU2010200953A priority patent/AU2010200953B2/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/10Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/20Adhesives in the form of films or foils characterised by their carriers
    • C09J7/29Laminated material
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38Pressure-sensitive adhesives [PSA]
    • C09J7/381Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/385Acrylic polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38Pressure-sensitive adhesives [PSA]
    • C09J7/381Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/387Block-copolymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/16Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer
    • C09J2301/162Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the structure of the carrier layer the carrier being a laminate constituted by plastic layers only
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/20Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself
    • C09J2301/204Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself the adhesive coating being discontinuous
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/20Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself
    • C09J2301/21Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive itself the adhesive layer being formed by alternating adhesive areas of different nature
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/30Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/312Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/40Additional features of adhesives in the form of films or foils characterized by the presence of essential components
    • C09J2301/408Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2401/00Presence of cellulose
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2401/00Presence of cellulose
    • C09J2401/006Presence of cellulose in the substrate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2423/00Presence of polyolefin
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2423/00Presence of polyolefin
    • C09J2423/006Presence of polyolefin in the substrate
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/14Layer or component removable to expose adhesive
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/14Layer or component removable to expose adhesive
    • Y10T428/149Sectional layer removable
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/28Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/28Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2835Web or sheet containing structurally defined element or component and having an adhesive outermost layer including moisture or waterproof component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/28Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2852Adhesive compositions
    • Y10T428/2861Adhesive compositions having readily strippable combined with readily readhearable properties [e.g., stick-ons, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/28Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2852Adhesive compositions
    • Y10T428/2878Adhesive compositions including addition polymer from unsaturated monomer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/28Web or sheet containing structurally defined element or component and having an adhesive outermost layer
    • Y10T428/2852Adhesive compositions
    • Y10T428/2896Adhesive compositions including nitrogen containing condensation polymer [e.g., polyurethane, polyisocyanate, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31507Of polycarbonate
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31551Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31725Of polyamide
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31786Of polyester [e.g., alkyd, etc.]
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/31504Composite [nonstructural laminate]
    • Y10T428/31855Of addition polymer from unsaturated monomers

Abstract

Adhesive articles, particularly useful as reusable closures, comprising a moisture resistant substrate and a removable adhesive covering at least a portion substrate surface, the adhesive having a Moist Loop Test result of at least about 25 N/25mm at a test plate temperature of 5°C. The closure may also include a permanent adhesive covering another portion of the substrate surface. The adhesive articles provide easy application to packages and exhibit good adhesion performance in the presence of moisture, such as from refrigerated or frozen food packaging.

Claims

AMENDED CLAIMS[Received by the International Bureau on 16 May 2005 (16.05.2005): original claims 1-44 replaced by amended claims 1-44]
1. An adhesive article comprising (a) a moisture resistant substrate having a first and second surface, and (b) a removable and resealable adhesive covering at least a first portion of the first surface of the Substrate; wherein the removable adhesive has a Moist Loop Test result of at least about 0.25 N/25mm at a test plate temperature of 5°C.
2. The article of claim 1 wherein the moisture resistant substrate comprises a polymer coated paper facestoc .
3. The article of claim 1 wherein the moisture resistant substrate comprises a moπolayer or multilayer polymeric film.
4. The article of claim 1 wherein the substrate comprises a multilayer film.
5. The article of claim 1 wherein the substrate comprises a film selected from polystyrenes, polyolefins, polyamides, polyesters, polycarbonates, polyurethanes, polyacrylates, polyviπyl alcohol, po!y(ethyIeπe vinyl alcohol), poly(alkylene vinyl acetates), poly(alkylene acrylates), ionomers, and mixtures thereof.
6. The article of claim 1 wherein the substrate comprises a polyolefin film.
7. The article of claim 1 wherein the substrate comprises an ethylene or propylene polymer or copolymer.
8. The article of claim 1 wherein the removable adhesive comprises an acrylic based or rubber based pressure sensitive adhesive.
9. The article of claim 1 wherein the removable adhesive has a Moist Loop Test result of at least about 0.28 N/25mm at a test plate temperature of 5°C.
10. The article of claim 1 where the removable adhesive comprises a hot melt pressure sensitive adhesive.
11. The article of claim 1 wherein the removable adhesive comprises a rubber based adhesive.
12- The article of claim 1 wherein the removable adhesive comprises a styrene isoprene or styrene butadiene copolymer.
39
13. comprises a a mixture of
14. comprises a
Figure imgf000003_0001
(a) a first elastomer selected from the group consisting of a styrene-butadiene block copolymer, a styrene-butadiene-styrene block copolymer and mixtures thereof, the first elastomer exhibiting a first glass transition temperature and a first value of tangent delta measured as a function of temperature; (b) a second elastomer selected from the group consisting of styrene-isoprene-styrene block copolymers, styrene-isoprene block copolymers, multiarmed styrene-isoprene block copolymers and mixtures thereof, the second elastomer exhibiting a second glass transition temperature greater than the first glass transition temperature and a second value of tangent delta measured as a function of temperature, the second elastomer being immiscible in the first elastomer, wherein the weight ratio of the first to the second elastomers is 0.5:1 to 5:1 and in which a dynamic mechanical spectrum plot of tangent delta as a function of temperature exhibits a polybutadiene-attributable first glass transition temperature peak determinable separate from and lower than a polyisoprene-attributable second glass transition temperature peak; (c) a first tackifier comprising a normally solid tackifying component having a softening point of about 95° C. and obtained by polymerization of a stream solely composed of aliphatic petroleum derivatives in the form of dϊeπes and monoolefins containing 5 or 6 carbon atoms, said tackifying component being preferentially miscible with the polyisoprene blocks of the second elastomer and present in an amount sufficient to cause an increase in second glass transition temperature and an increase in the temperature difference between the polybutadiene-attributable glass transition temperature peak and the polyisoprene-attributable glass transition temperature peak and an
40 increase in the tangent delta value attributed to the polyisoprene- attributable peak; and (d) a second tackifier selected from the group consisting of rosins, rosin esters, and polyterpenes, wherein the total amount of the first and second tackiflers ranges from about 50 percent to about 70 percent by weight of the elastomers and tackifiers.
15. The article of claim 1 wherein the removable adhesive comprises a pressure-sensitive adhesive comprising: (a) a first elastomer selected from the group consisting of a styrene-butadiene block copolymer, a styrene-butadiene-styrene block copolymer and mixtures thereof, the first elastomer exhibiting a first glass transition temperature and a first value of tangent delta measured as a function of temperature; (b) a second elastomer selected from the group consisting of styrene-isoprene-styrene block copolymers, styrene-isoprene block copolymers, multiarmed styrene-isoprene block copolymers and mixtures thereof, said second elastomer exhibiting a second glass transition temperature greater than the first glass transition temperature and a second value of tangent delta measured as function of temperature, the second elastomer being immiscible in the first elastomer, said first and second elastomers provided in proportions of 0.5:1 to 5:1 and in which a dynamic mechanical spectrum plot of tangent delta as a function of temperature exhibits a polybutadiene- attributable first glass transition temperature peak determinable separate from and lower than polyisoprene-attributable second glass transition temperature peak; and (c) a tackifying system comprising a normally solid tackifying component having a softening point of about 95° C. and obtained by polymerization of a stream solely composed of aliphatic petroleum derivatives in the form of dienes and monoolefiπs containing 5 to 6 carbon atoms, said tackifying component being preferentially miscible with the polyisoprene blocks of the second elastomer and present in an amount of from about 50 percent to about 70 percent by weight of the
41 elastomers and tackifying system and sufficient to cause an increase in the second glass transition temperature and an increase in the temperature difference between the polybutadiene-attributable glass transition temperature peak and the polyisoprene-attributable glass transition temperature peak and an increase in the tangent delta value attributed to the polyisoprene-attributable peak.
16. The article of claim 14 wherein the first tackifier further comprises a compound selected from the group consisting of a normally liquid tackifying resins obtained by the polymerization of a stream of aliphatic petroleum derivatives in the form of dienes and monoolefins containing 5 or 6 carbon atoms, a plasticizing oil and mixtures thereof.
17. The article of claim 15 wherein the tackifying system further comprises a compound selected from the group consisting of a normally liquid tackifying resins obtained by the polymerization of a stream of aliphatic petroleum derivatives in the form of dienes and monoolefins containing 5 or 6 carbon atoms, a plasticizing oil and mixtures thereof.
18. The article of claim 1 further comprising (c) at least one permanent adhesive covering a second portion of the first surface of the substrate.
19. The article of claim 18 wherein the removable adhesive comprises a rubber based adhesive, an acrylic adhesive, a vinyl ether adhesive, a silicone adhesive, or mixtures of two or more thereof.
20. The article of claim 18 wherein the permanent adhesive comprises an acrylic based or rubber based pressure sensitive adhesive.
21. An adhesive article comprising (a) a moisture resistant substrate having a first and second surface, and (b) a removable and resealable adhesive covering at least a first portion of the first surface of the substrate, wherein the removable adhesive has a cohesive strength of less than about 250,000 at 5°C.
22. The article of claim 21 further comprising (c) at least one permanent adhesive covering a second portion of the first surface of the substrate.
23. The article of claim 22 wherein the removable adhesive (b) comprises a rubber based adhesive, an acrylic adhesive, a vinyl ether adhesive, a silicone adhesive, or mixtures of two or more thereof.
24. The article of claim 22 wherein the permanent adhesive comprises an acrylic based or rubber based pressure sensitive adhesive.
25. A method of providing a reusable closure for packages, comprising (a) providing a package having a folding portion and a main portion wherein the folding portion is able to be folded over to cover the main portion of the package, (b) folding the portion over to close the package and (c) applying an adhesive article to the folded portion and the main portion so that the package remains closed, wherein the adhesive article comprises (i) a moisture resistant substrate having a first and second surface, and (ii) a removable adhesive covering at least a first portion of the first surface, wherein the removable adhesive has a Moist Loop Test result of at least about 0.25 N/25mm at a test plate temperature of 5°C.
26. The method of claim 25 wherein the package comprises a flexible package.
27. The method of claim 25 wherein the package comprises a food package,
28. The method of claim 25 wherein the package comprises a frozen food package.
29. A method of providing a reusable closure for packages, comprising (a) providing a package having a folding portion and a main portion wherein the folding portion is able to be folded over to cover the main portion of the package, (b) folding the portion over to close the package and (c) applying an adhesive article to the folded portion and the main portion so that the package remains closed wherein the adhesive article comprises (i) a moisture resistant substrate having a first and second surface, (ii) a removable adhesive covering a first portion of the first surface and wherein the removable adhesive has a moist loop test result of at least about 0.25 N/25mm at a test plate temperature of 5°C, and (c) at least one permanent adhesive covering a second portion of the first surface of the substrate.
30. The method of claim 29 wherein the package comprises a flexible package.
43
31. The method of claim 29 wherein the package comprises a food package.
32. The method of claim 29 wherein the package comprises a frozen food package.
33. A method of providing a reusable closure for packages, comprising (a) providing a package having a folding portion and a main portion wherein the folding portion is able to be folded over to cover the main portion of the package, (b) folding the portion over to close the package and (c) applying an adhesive article to the folded portion and the main portion so that the package remains closed wherein the adhesive article comprising (i) a moisture resistant substrate having a first and second surface, and (ii) a removable adhesive covering at least a portion of the first surface and wherein the removable adhesive has a cohesive strength of less than about 250,000 at 5°C.
34. The method of claim 33 wherein the package comprises a flexible package.
35. The method of claim 33 wherein the package comprises a food package.
36. The method of claim 33 wherein the package comprises a frozen food package.
37. A method of providing a reusable closure for packages, comprising (a) providing a package having a folding portion and a main portion wherein the folding portion is able to be folded over to cover the main portion of the package, (b) folding the portion over to close the package and (c) applying an adhesive article to the folded portion and the main portion so that the package remains closed wherein the adhesive article comprises (i) a moisture resistant substrate having a first and second surface, (ii) a removable adhesive covering a first portion of the first surface and wherein the removable adhesive has a cohesive strength of less than about 250,000 at 5°C, and (iii) a permanent adhesive covering a second portion of the first surface of the substrate.
38. The method of claim 37 wherein the package comprises a flexible package.
44
39. The method of claim 37 wherein the package comprises a food package.
40. The method of claim 37 wherein the package comprises a frozen food package.
41. A sheet of adhesive closures comprising: a carrier sheet having a release surface; and a plurality of adhesive articles releasably adhered to the release surface of the sheet, each article comprising (a) a moisture resistant substrate having a first and second surface, and (b) a removable and resealable adhesive covering at least a first portion of the first surface of the substrate; wherein the removable adhesive has a Moist Loop Test result of at least about 0.25 N/25mm at a test plate temperature of 5°C.
42. The sheet of claim 41 wherein the adhesive article further comprises (c) at least one permanent adhesive covering a second portion of the first surface of the substrate.
43. A roll of adhesive closures comprising: a wound carrier having a release surface; and a plurality of adhesive articles releasably adhered to the release surface of wound carrier, each article comprising (a) a moisture resistant substrate having a first and second surface, and (b) a removable and resealable adhesive covering at least a first portion of the first surface of the substrate; wherein the removable adhesive has a Moist Loop Test result of at least about 0.25 N/25mm at a test plate temperature of 5QC.
44. The roll of claim 43 wherein the adhesive article further comprises (c) at least one permanent adhesive covering a second portion of the first surface of the substrate.
45
PCT/US2004/007106 2003-03-12 2004-03-09 Reusable closures for packages and methods of making and using the same WO2004080826A2 (en)

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CA 2518892 CA2518892A1 (en) 2003-03-12 2004-03-09 Reusable closures for packages and methods of making and using the same
BRPI0408289 BRPI0408289A (en) 2003-03-12 2004-03-09 adhesive article, method of providing a reusable closure for packaging, adhesive closure sheet and adhesive closure roll
AU2004220101A AU2004220101B2 (en) 2003-03-12 2004-03-09 Reusable closures for packages and methods of making and using the same
EP04718821A EP1601579A4 (en) 2003-03-12 2004-03-09 Reusable closures for packages and methods of making and using the same
EP10003070.9A EP2228211B1 (en) 2003-03-12 2004-03-09 Methods of making reusable closures for packages
KR1020057017024A KR101099054B1 (en) 2003-03-12 2005-09-12 Reusable closures for packages and methods of making and using the same
AU2010200953A AU2010200953B2 (en) 2003-03-12 2010-03-12 Reusable closures for packages and methods of making and using the same

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US45419203P 2003-03-12 2003-03-12
US60/454,192 2003-03-12

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EP2228211B1 (en) 2019-07-17
US7073309B2 (en) 2006-07-11
EP1601579A2 (en) 2005-12-07
US20040191459A1 (en) 2004-09-30
RU2005131594A (en) 2006-02-27
WO2004080826A2 (en) 2004-09-23
KR20050107516A (en) 2005-11-11
EP1601579A4 (en) 2007-09-12
EP2332720A3 (en) 2011-10-12
AU2004220101A1 (en) 2004-09-23
KR101099054B1 (en) 2011-12-26
CA2518892A1 (en) 2004-09-23
EP2228211A3 (en) 2011-03-16
US20050042445A1 (en) 2005-02-24
AU2004220101B2 (en) 2010-03-25
WO2004080826A3 (en) 2005-06-23
CN100340394C (en) 2007-10-03
EP2332720A2 (en) 2011-06-15
AU2010200953A1 (en) 2010-04-01
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AU2010200953B2 (en) 2011-11-24
EP2228211A2 (en) 2010-09-15

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