WO2004071947A3 - Renewable energy operated hydrogen reforming system - Google Patents

Renewable energy operated hydrogen reforming system Download PDF

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Publication number
WO2004071947A3
WO2004071947A3 PCT/US2004/003439 US2004003439W WO2004071947A3 WO 2004071947 A3 WO2004071947 A3 WO 2004071947A3 US 2004003439 W US2004003439 W US 2004003439W WO 2004071947 A3 WO2004071947 A3 WO 2004071947A3
Authority
WO
WIPO (PCT)
Prior art keywords
hydrogen
renewable energy
reforming system
hydrogen reforming
energy operated
Prior art date
Application number
PCT/US2004/003439
Other languages
French (fr)
Other versions
WO2004071947A2 (en
Inventor
Michael S Hsu
Original Assignee
Ztek Corp
Michael S Hsu
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ztek Corp, Michael S Hsu filed Critical Ztek Corp
Priority to US10/544,737 priority Critical patent/US20060207178A1/en
Priority to CA002515321A priority patent/CA2515321A1/en
Priority to EP04709041A priority patent/EP1606216A2/en
Publication of WO2004071947A2 publication Critical patent/WO2004071947A2/en
Publication of WO2004071947A3 publication Critical patent/WO2004071947A3/en

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/062—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes being installed in a furnace
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/248—Reactors comprising multiple separated flow channels
    • B01J19/249—Plate-type reactors
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/342—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents with the aid of electrical means, electromagnetic or mechanical vibrations, or particle radiations
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04201—Reactant storage and supply, e.g. means for feeding, pipes
    • H01M8/04208—Cartridges, cryogenic media or cryogenic reservoirs
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
    • H01M8/0606—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants
    • H01M8/0612—Combination of fuel cells with means for production of reactants or for treatment of residues with means for production of gaseous reactants from carbon-containing material
    • H01M8/0618—Reforming processes, e.g. autothermal, partial oxidation or steam reforming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/00008—Controlling the process
    • B01J2208/00017—Controlling the temperature
    • B01J2208/00504—Controlling the temperature by means of a burner
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
    • B01J2208/02—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles
    • B01J2208/021—Processes carried out in the presence of solid particles; Reactors therefor with stationary particles comprising a plurality of beds with flow of reactants in parallel
    • B01J2208/022—Plate-type reactors filled with granular catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2476—Construction materials
    • B01J2219/2477—Construction materials of the catalysts
    • B01J2219/2481—Catalysts in granular from between plates
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0205—Processes for making hydrogen or synthesis gas containing a reforming step
    • C01B2203/0227—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step
    • C01B2203/0233—Processes for making hydrogen or synthesis gas containing a reforming step containing a catalytic reforming step the reforming step being a steam reforming step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/06—Integration with other chemical processes
    • C01B2203/066—Integration with other chemical processes with fuel cells
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/08—Methods of heating or cooling
    • C01B2203/0805—Methods of heating the process for making hydrogen or synthesis gas
    • C01B2203/0861—Methods of heating the process for making hydrogen or synthesis gas by plasma
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C01B2203/1058—Nickel catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/84—Energy production
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
    • C01B2203/86—Carbon dioxide sequestration
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry

Abstract

A hydrogen production system (300) incorporating use of electricity from renewable energy sources in hydrogen reforming plants. The system includes compressor (320) for hydrogen compression for high-pressure storage (330) electrical heating supply for the endothermic reforming reaction. The compressed hydrogen, produced using renewable energy sources, provides means of stored mechanical energy. Another embodiment combines conventional chemical reforming process with electrolysis (350) to provide leveled hydrogen generation.
PCT/US2004/003439 2003-02-06 2004-02-06 Renewable energy operated hydrogen reforming system WO2004071947A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US10/544,737 US20060207178A1 (en) 2003-02-06 2004-02-06 Renewable energy operated hydrogen reforming system
CA002515321A CA2515321A1 (en) 2003-02-06 2004-02-06 Renewable energy operated hydrogen reforming system
EP04709041A EP1606216A2 (en) 2003-02-06 2004-02-06 Renewable energy operated hydrogen reforming system

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US44548503P 2003-02-06 2003-02-06
US60/445,485 2003-02-06
US44913103P 2003-02-21 2003-02-21
US60/449,131 2003-02-21

Publications (2)

Publication Number Publication Date
WO2004071947A2 WO2004071947A2 (en) 2004-08-26
WO2004071947A3 true WO2004071947A3 (en) 2006-02-02

Family

ID=32871947

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2004/003439 WO2004071947A2 (en) 2003-02-06 2004-02-06 Renewable energy operated hydrogen reforming system

Country Status (4)

Country Link
US (1) US20060207178A1 (en)
EP (1) EP1606216A2 (en)
CA (1) CA2515321A1 (en)
WO (1) WO2004071947A2 (en)

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US7556736B2 (en) * 2004-11-26 2009-07-07 Leslie Dean Price Process and system for converting biomass materials into energy to power marine vessels
US20060236608A1 (en) * 2005-04-22 2006-10-26 Amjad Khan System for dispensing hydrogen to a vehicle
US8614364B2 (en) 2005-07-06 2013-12-24 Inentec Inc. Renewable electricity conversion of liquid fuels from hydrocarbon feedstocks
DE102006009974A1 (en) * 2006-03-03 2007-09-06 W.L. Gore & Associates Gmbh Shoe stabilizing material, useful in water-proof but water vapor permeable sole structures, comprises thermally consolidated fiber composite with at least two fiber components of different melting points
US20090304574A1 (en) * 2006-06-27 2009-12-10 Fluor Technologies Corporation Configurations And Methods Of Hydrogen Fueling
US8721868B2 (en) * 2009-03-16 2014-05-13 GM Global Technology Operations LLC Integrated solar-powered high-pressure hydrogen production and battery charging system
RU2591985C2 (en) * 2010-11-22 2016-07-20 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Method for production of liquid hydrogen and electrical energy
US20160060537A1 (en) * 2011-05-04 2016-03-03 Ztek Corporation Renewable energy storage and zero emission power system
WO2013135710A2 (en) 2012-03-13 2013-09-19 Bayer Intellectual Property Gmbh Method for performing the rwgs reaction in a multi-tube reactor
WO2013135667A1 (en) 2012-03-13 2013-09-19 Bayer Intellectual Property Gmbh Method for producing synthesis gas
WO2013135657A1 (en) 2012-03-13 2013-09-19 Bayer Intellectual Property Gmbh Method for producing synthesis gas in alternating operation between two operating modes
CN109019699B (en) * 2018-09-30 2020-08-18 东北农业大学 Preparation method of rod-like ferroferric oxide particle-loaded biochar composite material
DE102020107590A1 (en) 2020-03-19 2021-09-23 Airbus Defence and Space GmbH Energy recovery assembly, fuel cell system and vehicle with energy recovery assembly
CN112290570A (en) * 2020-10-20 2021-01-29 浙江大学 Clean multifunctional complementary system and method based on bioethanol reforming
DE22787208T1 (en) 2021-04-15 2024-03-21 lOGEN Corporation Process and system for producing renewable hydrogen with low carbon intensity
WO2022221954A1 (en) 2021-04-22 2022-10-27 Iogen Corporation Process and system for producing fuel
US20220397118A1 (en) * 2021-06-14 2022-12-15 Air Products And Chemicals, Inc. Process and apparatus for compressing hydrogen gas in a hybrid compression system
US20240014662A1 (en) * 2021-12-09 2024-01-11 Warner Denis PRIEST System for collecting, generating, and transmitting gigawatt scale energy from a plurality of distributed sources dispersed over an area
US11807530B2 (en) 2022-04-11 2023-11-07 Iogen Corporation Method for making low carbon intensity hydrogen
US11952276B1 (en) 2022-09-23 2024-04-09 Kraken Technology Holdings, LLC Process for producing hydrogen product having reduced carbon intensity
WO2024063808A1 (en) * 2022-09-23 2024-03-28 Kraken Technology Holdings, LLC Process for producing hydrogen product having reduced carbon intensity

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US4161657A (en) * 1975-02-21 1979-07-17 Shaffer Marlin R Jr Hydrogen supply and utility systems and components thereof
US4729891A (en) * 1984-08-16 1988-03-08 Prabhakar Kulkarni Hydrogen generating method

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US4087976A (en) * 1976-08-13 1978-05-09 Massachusetts Institute Of Technology Electric power plant using electrolytic cell-fuel cell combination
US4729891A (en) * 1984-08-16 1988-03-08 Prabhakar Kulkarni Hydrogen generating method

Also Published As

Publication number Publication date
WO2004071947A2 (en) 2004-08-26
CA2515321A1 (en) 2004-08-26
EP1606216A2 (en) 2005-12-21
US20060207178A1 (en) 2006-09-21

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