WO2004060414A1 - Absorbent articles containing an activated carbon substrate - Google Patents
Absorbent articles containing an activated carbon substrate Download PDFInfo
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- WO2004060414A1 WO2004060414A1 PCT/US2003/032849 US0332849W WO2004060414A1 WO 2004060414 A1 WO2004060414 A1 WO 2004060414A1 US 0332849 W US0332849 W US 0332849W WO 2004060414 A1 WO2004060414 A1 WO 2004060414A1
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- WIPO (PCT)
- Prior art keywords
- activated carbon
- substrate
- absorbent article
- carbon coating
- nonwoven fabric
- Prior art date
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28033—Membrane, sheet, cloth, pad, lamellar or mat
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/42—Use of materials characterised by their function or physical properties
- A61L15/46—Deodorants or malodour counteractants, e.g. to inhibit the formation of ammonia or bacteria
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F13/00—Bandages or dressings; Absorbent pads
- A61F13/15—Absorbent pads, e.g. sanitary towels, swabs or tampons for external or internal application to the body; Supporting or fastening means therefor; Tampon applicators
- A61F13/84—Accessories, not otherwise provided for, for absorbent pads
- A61F13/8405—Additives, e.g. for odour, disinfectant or pH control
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/16—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons
- A61L15/18—Bandages, dressings or absorbent pads for physiological fluids such as urine or blood, e.g. sanitary towels, tampons containing inorganic materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/20—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28023—Fibres or filaments
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28033—Membrane, sheet, cloth, pad, lamellar or mat
- B01J20/28035—Membrane, sheet, cloth, pad, lamellar or mat with more than one layer, e.g. laminates, separated sheets
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
- B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2300/00—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices
- A61L2300/10—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices containing or releasing inorganic materials
- A61L2300/108—Elemental carbon, e.g. charcoal
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L2300/00—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices
- A61L2300/60—Biologically active materials used in bandages, wound dressings, absorbent pads or medical devices characterised by a special physical form
- A61L2300/606—Coatings
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/2481—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including layer of mechanically interengaged strands, strand-portions or strand-like strips
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2041—Two or more non-extruded coatings or impregnations
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2041—Two or more non-extruded coatings or impregnations
- Y10T442/2049—Each major face of the fabric has at least one coating or impregnation
- Y10T442/2057—At least two coatings or impregnations of different chemical composition
- Y10T442/2066—Different coatings or impregnations on opposite faces of the fabric
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2041—Two or more non-extruded coatings or impregnations
- Y10T442/2049—Each major face of the fabric has at least one coating or impregnation
- Y10T442/2057—At least two coatings or impregnations of different chemical composition
- Y10T442/2074—At least one coating or impregnation contains particulate material
- Y10T442/2082—At least one coating or impregnation functions to fix pigments or particles on the surface of a coating or impregnation
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2139—Coating or impregnation specified as porous or permeable to a specific substance [e.g., water vapor, air, etc.]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
- Y10T442/2508—Coating or impregnation absorbs chemical material other than water
Definitions
- odor control While the primary focus of absorbent articles remains the ability of the articles to absorb and retain fluids, additional functions, such as odor control, are also receiving increased attention.
- a wide range of compounds that result in the production of malodors may be contained in absorbed fluids or their degradation products and thus be present within an absorbent article during use. Examples of these compounds include fatty acids, ammonia, amines, sulfur-containing compounds, ketones and aldehydes.
- various odor-control agents have been used in absorbent articles to address the problems of malodor formation. For instance, activated carbon has been used to reduce a broad spectrum of odors.
- a multi- functional absorbent article contains a substrate applied with a first activated carbon coating.
- the substrate may contain a woven or nonwoven fabric. After being coated, the substrate remains porous such that from about 20 to about 500 cubic feet of air is capable of flowing through 1 square foot of the substrate per minute at an air pressure differential of 125 Pascals (0.5 inches of water).
- the activated carbon coating is formed from a polymeric material and an activation agent.
- the coating may become activated by being heated to a temperature of from about 100°C to about 300°C, and in some embodiments, from about 170°C to about 300°C.
- the polymeric material may be selected from the group consisting of polyacrylonitrile, phenolic resins, ethylene vinyl acetate or copolymers thereof, polyvinyl alcohol, cellulose or other natural or synthetic polysaccharides, cellulose derivatives or other polysaccharide derivatives, polystyrene, polypropylene, polyvinyl chloride, polymethacrylates, poiymethacrylic acids, polylactic acid, and combinations thereof.
- the activation agent may be selected from the group consisting of acids, metal halides, hydroxides, and combinations thereof.
- the activated carbon coating is configured to adsorb acidic compounds, basic compounds, or combinations thereof.
- the activated carbon coating may generally be applied in a variety of ways. For instance, in one embodiment, the activated carbon coating is applied in a preselected pattern on a first surface of the substrate. If desired, a second activated carbon coating may also be applied to the substrate. In one embodiment, the second activated carbon coating is applied to a second surface of the substrate. The second activated carbon coating may contain a different amount of activated carbon than the first activated carbon coating, e.g., different overall or local add-on level.
- a method for forming a multi-functional absorbent article comprises providing a substrate having a first surface and a second surface.
- a polymeric material and an activation agent are applied (e.g., printed, sprayed, contact coated, painted, etc.) to the first surface of the substrate.
- the polymeric material and activation agent are heated to a temperature of from about 100°C to about 300°C to form an activated carbon coating, wherein the activated carbon coating.
- the activated carbon substrate is incorporated into the absorbent article so that it is capable of performing multiple functions.
- Fig. 1 illustrates a perspective view of a sanitary napkin formed according to one embodiment of the present invention
- Fig. 2 illustrates the fabric formed according to the process set forth in Example 1 without activated carbon treatment
- Fig. 3 illustrates the fabric formed according to the process set forth in Example 1 with activated carbon treatment
- Fig. 4 illustrates an activated carbon fabric formed according to the process set forth in Example 2
- Fig. 5 is a scanned grayscale image of a nonwoven fabric sample treated with two different activated carbon precursor solutions, according to Example 17;
- Fig. 6 is another scanned grayscale image of a nonwoven fabric sample treated with two different activated carbon precursor solutions, according to Example 17.
- absorbent article refers to any article capable of absorbing water or other fluids.
- absorbent articles include, but are not limited to, personal care absorbent articles, such as diapers, training pants, absorbent underpants, adult incontinence products, feminine hygiene products (e.g., sanitary napkins), and the like; wound coverings; wipers; bed pads; shoe pads; clothing articles, such as perspiration pads, disposable swimming apparel, and the like; air and water filtration devices; and the like. Materials and processes suitable for forming such absorbent articles are well known to those skilled in the art.
- nonwoven fabric or web means a web having a structure of individual fibers or threads which are interlaid, but not in an identifiable manner as in a knitted fabric.
- Nonwoven fabrics or webs have been formed from many processes such as for example, meltblowing processes, spunbonding processes, bonded carded web processes, needle punching, apertured film production processes, etc.
- meltblown fibers refers to fibers formed by extruding a molten thermoplastic material through a plurality of fine, usually circular, die capillaries as molten fibers into converging high velocity gas (e.g.
- meltblown fibers may be microfibers that may be continuous or discontinuous, are generally smaller than 10 microns in diameter, and are generally tacky when deposited onto a collecting surface.
- spunbonded fibers refers to small diameter substantially continuous fibers that are formed by extruding a molten thermoplastic material from a plurality of fine, usually circular, capillaries of a spinnerette with the diameter of the extruded fibers then being rapidly reduced as by, for example, eductive drawing and/or other well-known spunbonding mechanisms.
- the production of spun-bonded nonwoven webs is described and illustrated, for example, in U.S. Patent Nos. 4,340,563 to Appel. et al.. 3,692,618 to Dorschner. et ak, 3,802,817 to Matsuki. et al.. 3,338,992 to Kinnev, 3,341 ,394 to Kinnev.
- Spunbond fibers are generally not tacky when they are deposited onto a collecting surface. Spunbond fibers can sometimes have diameters less than about 40 microns, and are often between about 5 to about 20 microns.
- coform generally refers to composite materials comprising a mixture or stabilized matrix of thermoplastic fibers and a second non- thermoplastic material.
- coform materials may be made by a process in which at least one meltblown die head is arranged near a chute through which other materials are added to the web while it is forming.
- Such other materials may include, but are not limited to, fibrous organic materials such as woody or non-woody pulp such as cotton, rayon, recycled paper, pulp fluff and also superabsorbent particles, inorganic absorbent materials, treated polymeric staple fibers and the like.
- the present invention is directed to an absorbent article that contains a substrate applied with an activated carbon coating.
- the activated carbon coating is formed from a mixture of a polymeric material and an activation agent.
- an activated carbon-coated substrate can be formed that, in one embodiment, is useful in handling body fluids in an absorbent article (e.g., is absorbent or is sufficiently liquid pervious to permit through-flow of liquids or can serve as an intake or distribution layer) and also capable of performing other functions, such as serving as an odor control agent.
- the activated carbon-coated substrate may also provide good mechanical properties due to its high tensile strength and flexibility, while also providing, for instance, odor-control benefits.
- the coating is activated at a relatively low temperature, a wide range of polymers remains available for use in the substrate.
- the resulting substrate can sometimes perform better than a homogenous activated carbon substrate.
- portions of a nonwoven web untreated with activated carbon may be able to allow fluid to flow through the web or be absorbed by the web more effectively than regions treated with activated carbon, while the treated regions remain available to adsorb odors or other chemicals.
- a substrate with both activated carbon treated regions and untreated regions can serve effectively for fluid handling purposes (intake or fluid absorption or fluid distribution), while also serving as an odor control layer or adsorption layer.
- a pattern of treated and untreated regions may also offer more visual appeal than a homogenous activated carbon substrates, such as a pattern of stripes, dots, or other shapes.
- one type may be well suited for adsorbing a certain class of compounds, while the other type(s) may be suited for adsorbing a another class of compounds, such that the heterogeneous activated carbon substrate is effective in adsorbing two or more classes of compounds more effectively than a homogenous activated carbon substrate.
- activated carbon coatings derived by activation of polyacrylonitrile may be well suited for adsorbing acidic compounds such as isovaleric acid or hydrochloric acid, while activated carbon coatings comprising acidic groups may be effective at adsorbing ammonia or other basic compounds.
- the activated carbon substrate for use in an absorbent article in accordance with the present invention, some or all of the substrate is coated with activated carbon.
- fibers may be coated before and/or after incorporation into the substrate.
- the activated carbon coating may be formed in a variety of different ways. One particularly desired method for forming the activated carbon coating is described in U.S. Patent Publication No. 2001/0024716, which is incorporated herein in its entirety by reference thereto for all purposes. For instance, in some embodiments, a coating mixture of a polymeric material and a chemical activation agent is applied to fibers that are then heated to induce carbon activation.
- the polymeric material of the coating may be any organic polymer that will react with a chemical activation agent to produce an activated carbon coating.
- suitable polymeric materials include, but are not limited to, phenolic resins, ethylene vinyl acetate or copolymers thereof, poly(vinyl alcohol) (PVA), polyacrylonitrile (PAN), cellulose or other natural or synthetic polysaccharides, cellulose derivatives or other polysaccharide derivatives, polystyrene, polypropylene, poly(vinyl chloride) (PVC), poly(meth)acrylates and poly(meth)acrylic acids, polylactic acid, and combinations thereof.
- PVA poly(vinyl alcohol)
- PAN polyacrylonitrile
- cellulose or other natural or synthetic polysaccharides cellulose derivatives or other polysaccharide derivatives
- polystyrene polystyrene
- polypropylene poly(vinyl chloride) (PVC)
- PVC poly(meth)acrylates and poly(me
- solvents examples include, but are not limited to, water; alcohols, such as ethanol or methanol; dimethylformamide (DMF); dimethyl sulfoxide; hydrocarbons, such as pentane, butane, heptane, hexane, toluene and xylene; ethers, such as diethyl ether and tetrahydrofuran; ketones and aldehydes, such as acetone and methyl ethyl ketone; acids, such as acetic acid and formic acid; amines, such as pyridine and hexamethylenetetramine; and halogenated solvents, such as dichloromethane and carbon tetrachloride; and the like.
- solvents include, but are not limited to, water; alcohols, such as ethanol or methanol; dimethylformamide (DMF); dimethyl sulfoxide; hydrocarbons, such as pentane, butane, heptane, he
- the activation agent reacts with the polymeric material to form the activated carbon coating at an elevated temperature.
- Lewis acids and bases may be employed as the activation agents in the present invention.
- Some examples of such activation agents are described in U.S. Patent No. 5,834,114 to Economy, et al.; WO 01/97972 to Economy, et al.; and U.S. Patent Publication No. 2001/0024716, which are incorporated herein in their entirety by reference thereto for all purposes.
- Specific examples include, but are not limited to, acids, such as phosphoric acid; metal halides, such as zinc chloride; and hydroxides, such as potassium hydroxide and sodium hydroxide.
- Friedel-Crafts compounds include Friedel-Crafts compounds; dehydrating agents; TiC 4 , ZnBr 2 , AIBr 3 , AICI3, BF 3 , CaO, Ca(OH) 2 , H 2 SO 4 , Mg(OH) 2 , MgO and LiOH.
- the amount of the activation agent within the mixture may generally vary as desired.
- the activation agent is present in the coating mixture in an amount of from about 0.1 wt.% to about 90 wt%. As the amount of activation agent is increased, the pore size of the resulting activated carbon coating also increases. After reaction has occurred, some or all of the remaining activation agent can be washed out of the activated carbon coating, if desired.
- substantially all of the remaining activation agent can be removed by washing with water or other substances, or a lesser portion of the remaining activation agent can be removed, such as from about 1% to about-99%, from about 10% to about 99%, or from about 20% to about 99%, or from about 50% to about 95%, or from about 60% to about 95% of the remaining activation agent.
- a portion of the activation agent e.g, a zinc salt or an acidic compound like phosphoric acid or its salts
- additional functions such as ion exchange, antimicrobial functions, removal of target species by chemical reaction or neutralization, pH control, viscosity control, surface tension modification, and the like.
- the percentage of the initial activation agent or its soluble reaction products that is retained in the activated carbon substrate may be at least about 1 %, in some embodiments at least about 10%, in some embodiments at least about 20%, and in some embodiments, at least about 30%.
- the activated carbon coating may include one or more catalytic materials that remain inert during processing but catalyze the decomposition of byproduct gases.
- suitable catalysts include, but are not limited to, free metals or compounds of metals, such as zinc, copper, platinum, palladium and titanium.
- the metal is present as the free metal or the oxide (such as zinc oxide, titanium dioxide, or copper oxide).
- the catalyst may be applied by mixing it or a compound of the metal of the catalyst into the coating mixture, or after activation by coating the activated carbon coating with a mixture of catalyst, or a compound containing the metal of the catalyst, and a solvent, and then vaporizing the solvent.
- the metal of the catalyst may be applied as the chloride salt with a solvent, and then heated to remove the solvent and convert the chloride salt to an oxide or the free metal.
- Any volatile solvent capable of dispersing or dissolving the catalyst or a compound of the metal of the catalyst is suitable, for example water; alcohols such as ethanol or methanol; dimethylformamide; dimethyl sulfoxide; hydrocarbons such as pentane, butane, heptane, hexane, toluene and xylene; ethers such as diethyl ether and tetrahydrofuran; ketones and aldehydes such as acetone and methyl ethyl ketone; acids such as acetic acid and formic acid; and halogenated solvents such as dichloromethane and carbon tetrachloride; as well as mixtures thereof.
- alcohols such as ethanol or methanol
- dimethylformamide dimethyl sulfoxide
- hydrocarbons such as pentane, butane, heptane, hexane, toluene and xylene
- ethers such as diethy
- the mixture is then heated to crosslink the polymeric material.
- the entire substrate or the entire coated portion of the substrate is heated to activate the coating, though a portion (e.g., less than 50%) of the substrate may be kept at a lower temperature than the remaining substrate if desired.
- the elevated temperature is generally maintained sufficiently long to at least partially activate the coating (e.g., from about 30 seconds to about 30 minutes).
- Heating is generally carried out at temperatures less than the melting point or decomposition point of the substrate. For example, in some embodiments, heating is carried out at a temperature of from about 100°C to about 300°C, in some embodiments from about 170°C to about 300°C, and in some embodiments, from about 170°C to about 250°C.
- low curing temperatures allow, in some embodiments, the resulting substrate to have an activated carbon coating without substantially sacrificing the flexibility or other mechanical properties of the substrate. Further, such low curing temperatures also allow for the use of polymers having low softening or decomposition temperatures (e.g., polyester) that are commonly employed in absorbent articles. In addition, not only does heating crosslink and activate the polymeric material, it also forms a durable coating that will generally remain present on the substrate during use. In one embodiment, the activated carbon coating on the substrate does not rub off to a significant degree when the coating is rubbed between the fingers of the human hand.
- an integral coating of activated carbon can be formed around fibers or other components of the substrate, as opposed to the discretely attached particles that would result by adhesively attaching activated carbon particles to the substrate.
- the activated carbon coating formed according to the present invention can be durably held in place on the substrate by either formation of a network that surrounds the substrate material and prevents release of the activated carbon, or by chemical bonds (covalent bonds, van derWaal bonds, etc.) between the activated carbon and the substrate material, or both.
- the coating can be substantially homogenous in chemical composition or in the mass distribution of activated carbon around the substrate material (e.g., a substantially uniform coating of integral activated carbon as opposed to discreet particles attached with an adhesive).
- activation may take place in one or more incremental steps over a succession of temperatures to increase the concentration of porosity in the coating and minimize the amount of coating that is volatilized.
- the cured coating may be further activated to produce a higher surface area by further heating in the presence of an inert gas or air.
- Selection of the specific polymeric material, chemical activation agent and its concentration, along with the activation temperature and time, will determine the specific surface area, pore size distribution and surface chemistry of the activated carbon coating. For example, low activation temperatures can be used to produce high surface area activated carbon coating fibers.
- the characteristics of the resulting activated carbon coating generally vary based on the amount and type of the polymeric material and activation agent utilized.
- the amount of carbon in the coating is less than about 85 wt%, in some embodiments less than about 80 wt%, in some embodiments, from about 50 wt% to about 80 wt%, and in some embodiments, from about 60 wt.% to about 75 wt% of the substrate.
- the yield of activated carbon in the coating (the weight of activated carbon coating divided by the weight of coating mixture) may be at least about 50%, in some embodiments at least about 60%, in some embodiments at least about 80%, and in some embodiments, at least about 90%.
- the resulting coating may have a B.E.T. surface area (measured using a "Quantachrome Autsorb-1" available from Quantachrome Instruments, Inc.
- the coating mixture Prior to heating, the coating mixture may have a surface area of up to about 10 m 2 /g.
- the solutions to be coated onto a substrate can have a viscosity of at least about 1 centipoise (cp), in some embodiments at least about 5 cp, in some embodiments at least about 10 cp, and in some embodiments, at least about 50 cp.
- thickeners and/or surfactants can be used to apply the coating material to the polymeric substrate.
- the coating Gan be prepared as a foam that can collapse during heat treatment to increase the basis weight of the applied coating.
- Foams can be prepared by agitation of the solution in the presence of a surfactant.
- Thickeners such as sodium alginate, xanthan gum, gum arabic, guar gum, sodium alginate, polyvinyl alcohol, bentonite, laponite, kaolin, and the like, may be used in the present invention.
- any of a variety of different substrates may be incorporated with the activated carbon coating in accordance with the present invention.
- nonwoven fabrics may include, but are not limited to, spunbonded webs (apertured or non- apertured), meltblown webs, bonded carded webs, air-laid webs, coform webs, hydraulically entangled webs, and the like.
- spunbonded webs apertured or non- apertured
- meltblown webs meltblown webs
- bonded carded webs bonded carded webs
- air-laid webs coform webs
- hydraulically entangled webs and the like.
- some or all of the fibers used to form the nonwoven fabric have a softening or melting temperature that is higher than the temperatures needed to form the activated carbon coating.
- One or more components of such fibers may have, for instance, a softening temperature of from about 100°C to about 400°C, in some embodiments from about 100°C to about 300°C, and in some embodiments, from about 150°C to about 250°C.
- Examples of such fibers may include, but are not limited to, synthetic fibers (e.g., polyethylene, polypropylene, polyethylene terephthalate, nylon 6, nylon 66,
- the substrate may also be characterized in terms of a degradation temperature, i.e., the temperature at which the uncoated fabric loses at least 50% of its tensile strength relative to an unheated fabric when the fabric is heated to that temperature for one hour in a normal atmosphere of air, then air cooled to room temperature over a period of two hours and then tested for tensile strength using a 3-inch wide sample with a gage length of 3 inches and a crosshead speed of 10 inches per minute.
- the degradation temperature can be less than about 450°C, in some embodiments less than about 250°C, and in some embodiments, less than about 200°C.
- the permeability of the substrate may be varied for a particular application.
- the substrates may contain a material having an average pore size that renders it permeable to liquids.
- Liquid permeability may enhance the absorption characteristics of the substrate, and also render it more flexible. For instance, relatively large pores do not tend to become as blocked by activated carbon as smaller pores. As a result, the open pores provide the substrate room to extend without constraint by activated carbon, which is relatively stiff. In this manner, the pore size can facilitate the flexibility of the substrate.
- average pore sizes that can improve substrate flexibility are those in the range of 0.1 to about 1000 micrometers, in some embodiments from about 0.1 to about 10 milllimeters, and in some embodiments, from about 0.3 to about 5 millimeters.
- the substrate When formed from a liquid-permeable substrate, it is typically desired that the substrate, after being coated with activated carbon, remain relatively porous so that it is absorbent when incorporated into an absorbent article.
- the porosity may be maintained in a variety of ways. For instance, the resulting substrate may be apertured using known techniques. Moreover, the activated carbon coating can be applied in such a manner that the particles do not substantially block the pores of the substrate. Regardless of the technique utilized to maintain porosity, it is generally desired that the activated carbon coated substrate have sufficient porosity such that about 20 cubic feet of air or greater can flow through 1 square foot of the substrate in 1 minute under an air pressure differential of 125 Pascals (0.5 inches of water).
- such a substrate is said to have an air permeability of about 20 cubic feet per minute (cfm) or greater.
- Air permeability volumetric air flow per square foot of material under an air pressure differential of 125 Pascals
- Frazier Air Permeability is determined according to Federal Test Standard 191 A, Method 5450 with a Frazier Air Permeability Tester (Frazier Precision Instrument Co., Gaithersburg, Md.), and is reported as an average of 3 sample readings. It should be understood, however, that other techniques may also be used to determine porosity. For instance, an alternative technique is described below in Example 13, which is believed to give essentially the same results as Frazier Air Permeability.
- the air permeability of a fabric formed according to the present invention may range from about 20 cfm to about 500 cfm, in some embodiments from about 50 cfm to about 400 cfm, and in some embodiments, from about 75 cfm to about 300 cfm, under an air pressure differential of 125 Pascals.
- other properties of the activated carbon coated substrate may also be controlled. For instance, to further enhance the flexibility of the substrate, it may contain a stretchable component that, upon application of a force, is stretchable to a stretched, biased length which is at least about 120%, and in some embodiments, at least about 150% its relaxed, unstretched length.
- the stretchable material will also recover at least about 50% of its elongation upon release of the stretching, biasing force.
- an elastomeric component can enhance the flexibility of the substrate by enabling it to be more easily bent and distorted.
- the elastomeric component can take on various forms.
- the elastomeric component can make up the entire substrate or form a portion of the substrate.
- the elastomeric component can contain elastic strands or sections uniformly or randomly distributed throughout the substrate.
- the elastomeric component can be an elastic film or an elastic nonwoven web, such as an apertured web of elastomeric material having at least about 25% open area.
- the elastomeric component may be a single layer or a multi-layered material.
- any elastomeric material may generally be used, it is often desired to select an elastomeric material that has a softening temperature greater than the activation temperature for the carbon coating.
- some suitable "high softening temperature" elastomeric materials include, but are not limited to, fluoropolymers such as Viton® polymers sold by DuPont that can withstand temperatures of up to about 200°C; Kalrez® perfluoropolymers sold by DuPont that can withstand temperatures of up to about 300°C; highly saturated nitrile polymers; silicone polymers; ethyl vinyl acetate polymers, polyacrylate elastomers; and other elastomers and flexible polymers known in the art.
- olefinic copolymers e.g., styrene-isoprene-styrene, styrene-butadiene-styrene, styrene- ethylene/butylene-styrene, or styrene-ethylene/propylene-styrene
- polyurethanes polyamides
- polyesters
- the elastomeric component When incorporating an elastomeric component containing an elastomeric material, such as described above, into a substrate, it is sometimes desired that the elastomeric component include an elastic laminate that contains an elastomeric material with one or more other layers, such as foams, films, apertured films, and/or nonwoven webs.
- An elastic laminate generally contains layers that can be bonded together so that at least one of the layers has the characteristics of an elastic polymer.
- the elastic material used in the elastic laminates may be made from materials, such as described above, that are formed into films, such as a microporous film, fibrous webs, such as a web made from meltblown fibers, spunbond fibers, foams, and the like.
- the elastic laminate can be a "neck- bonded” laminate.
- a “neck-bonded” laminate refers to a composite material having at least two layers in which one layer is a necked, non-elastic layer and the other layer is an elastic layer. The resulting laminate is thereby a material that is elastic in the cross-direction.
- neck-bonded laminates are described in U.S. Patent Nos. 5,226,992, 4,981,747, 4,965,122, and 5,336,545, all to Morman, all of which are incorporated herein in their entirety by reference thereto for all purposes.
- the elastic laminate can also be a "stretch-bonded" laminate, which refers to a composite material having at least two layers in which one layer is a gatherable layer and in which the other layer is an elastic layer. The layers are joined together when the elastic layer is in an extended condition so that upon relaxing the layers, the gatherable layer is gathered.
- a stretch-bonded laminate which refers to a composite material having at least two layers in which one layer is a gatherable layer and in which the other layer is an elastic layer. The layers are joined together when the elastic layer is in an extended condition so that upon relaxing the layers, the gatherable layer is gathered.
- one elastic member can be bonded to another member while the elastic member is extended at least about 25 percent of its relaxed length.
- Such a multilayer composite elastic material may be stretched until the nonelastic layer is fully extended.
- one suitable type of stretch-bonded laminate is a spunbonded laminate, such as disclosed in U.S. Patent No. 4,720,415 to VanderWielen et al., which is incorporated herein in its entirety by reference thereto for all purposes.
- Another suitable type of stretch-bonded laminate is a continuous filament spunbonded laminate, such as disclosed in U.S. Patent No. 5,385,775 to Wright, which is incorporated herein in its entirety by reference thereto for all purposes.
- Wright discloses a composite elastic material that includes: (1) an anisotropic elastic fibrous web having at least one layer of elastomeric meltblown fibers and at least one layer of elastomeric filaments autogenously bonded to at least a portion of the elastomeric meltblown fibers, and (2) at least one gatherable layer joined at spaced-apart locations to the anisotropic elastic fibrous web so that the gatherable layer is gathered between the spaced-apart locations.
- the gatherable layer is joined to the elastic fibrous web when the elastic web is in a stretched condition so that when the elastic web relaxes, the gatherable layer gathers between the spaced-apart bonding locations.
- Other composite elastic materials are described and disclosed in U.S. Patent Nos.
- the elastic laminate can also be a necked stretch bonded laminate.
- a necked stretch bonded laminate is defined as a laminate made from the combination of a neck-bonded laminate and a stretch- bonded laminate. Examples of necked stretch bonded laminates are disclosed in U.S. Patent Nos. 5,114,781 and 5,116,662, which are both incorporated herein in their entirety by reference thereto for all purposes. Of particular advantage, a necked stretch bonded laminate can be stretchable in both the machine and cross- machine directions. Creped nonwoven materials can also be used. Exemplary creped nonwoven webs are described in U.S. Patent Nos. 4,810,556 to Kobayashi, et al.: 6, 197,404 to Varona: and 6, 150,002 to Varona, which are incorporated herein in their entirety by reference thereto for all purposes.
- stretchable materials may also be used as the substrate.
- stretchable polymeric meshes such as polyester and nylon meshes
- polyester and nylon meshes may be used in the present invention.
- suitable polyester and nylon meshes include, but are not limited to, 0.8 mm Polyester Mosquito Netting (Product FMN008), 1.5 mm Polyester Hex-Mesh (Product FMN001), 3 mm Nylon Hex-Mesh (Product FMN003), 840 x 1680 Denier Nylon Leno Mesh (Product FLM168), 6 mm Nylon Hex-Mesh (Product FMN006), and Nylon Spectra/MeshTM, all of which are available from American Home & Habitat (King George, Virginia).
- Suitable meshes can have substantial open area in the relaxed state (while not actively being stretched), such as about 25% open area or greater, about 50% open area or greater, or about 80% open area or greater. Scrim materials are one form of mesh that can be considered.
- liquid crystal polymers such as VectraTM; Celanex® or Vandar® thermoplastic polyester
- Riteflex® thermoplastic polyester elastomer long fiber reinforced thermoplastics such as Compel®, Celstran®, and Fiberod® products
- Topas® cyclic-olefin copolymer Duracon®, Celcon®, and Hostaform® acetal copolymers
- Fortran® polyphenylene sulfide and DuranexTM thermoplastic polyester (PBT), all of which are available from Ticona Corp. (Summit, New Jersey).
- the substrate may be applied with various treatments to impart desirable characteristics.
- the substrate may be treated with liquid-repellency additives, antistatic agents, surfactants, colorants, antifogging agents, fluorochemical blood or alcohol repellents, lubricants, and/or antimicrobial agents.
- the substrate may also be subjected to an electret treatment.
- the electret treatment imparts an electrostatic charge to the substrate to improve its filtration efficiency.
- the charge may include layers of positive or negative charges trapped at or near the surface of the polymer, or charge clouds stored in the bulk of the polymer.
- the charge may also include polarization charges that are frozen in alignment of the dipoles of the molecules. Techniques for subjecting the substrate to an electret treatment are well known by those skilled in the art.
- the electret treatment is a corona discharge technique, which involves subjecting the substrate to a pair of electrical fields that have opposite polarities.
- Other methods for forming an electret material are described in U.S. Patent Nos. 4,215,682 to Kubik. et al.; 4,375,718 to Wadsworth; 4,592,815 to Nakao; 4,874,659 to Ando; 5,401 ,446 to Tsai.
- Activated Carbon Coating A variety of techniques may be utilized to apply the coating of the polymeric material and the activation agent to the substrate. For instance, in one embodiment, a polymeric material is initially dissolved in a solvent, mixed with a chemical activation agent, and then applied to the substrate material.
- the chemical activation agent may initially be applied to the substrate material. Thereafter, the polymeric material may be applied to the substrate material. Moreover, the polymeric material may also initially be applied to the substrate material prior to application of the chemical activation agent.
- any known method of application may be utilized, such as print, spraying, contact coated, blade, saturant, coating, droplet throw, paint, and foam applications.
- the polymeric material, the chemical activation agent, or a mixture thereof can be saturated into the substrate.
- the polymeric material, the chemical activation agent, or a mixture thereof can be printed onto at least one side of the substrate, and, in some cases to both outer surfaces of the substrate.
- the add-on level of the activated carbon coating to the substrate may generally be varied as desired.
- the "add-on level” refers to the mass of the activated carbon coating divided by the oven-dry mass of the uncoated substrate, multiplied by 100%. For example, a 5-gram non-woven web with 5 grams of added activated carbon would have an add-on of 100%.
- the add-on level can be expressed in terms of total activated carbon relative to total substrate weight, or, in the case of heterogeneously treated substrates, the "local” add-on value can be expressed in terms of the mass of the activated carbon in a particular region coated with activated carbon relative to the mass of the fraction of the substrate that for which at least one surface has been provided with the activated carbon coating.
- the activated carbon can have an add-on level of from about 1 % to about 300% of the mass of the substrate, in some embodiments from about 5% to about 200% of the mass of the substrate, in some embodiments from about 5% to about 100% of the mass of the substrate, and in some embodiments, from about 5% to about 50% of the mass of the substrate.
- the resulting activated carbon substrate is capable of performing multiple functions when incorporated into an absorbent article.
- an absorbent substrate may continue to function in its absorbent capacity within the article, but also have additional functions stemming from the presence of activated carbon therein, such as adsorbing odor-producing materials.
- the surface chemistry of the activated carbon coating may be tailored to optimize odor reduction or other additional functions performed by the substrate.
- basic groups are desired on the activated carbon substrate for adsorbing acidic compounds, such as isovaleric acid or hydrochloric acid. Basic groups can be introduced by treatment with ammonia at elevated temperatures or by other treatments known in the art.
- nitrogen containing polymeric materials may be used, such as polyacrylonitrile (PAN), with an activation agent (e.g., zinc chloride).
- PAN polyacrylonitrile
- an activation agent e.g., zinc chloride
- this coating mixture is heated to about 300°C to about 400°C for about 2 minutes to about 24 hours. The resulting assemblies have
- B.E.T. surface areas of about 400 and 1200 m 2 /g and a nitrogen content ranging from about 12 wt.% to about 20 wt.% based upon the weight percent of activated carbon coating.
- much higher temperatures e.g., up to about 900°C, may be used for increased surface areas.
- acidic groups are desired on the activated carbon substrate for adsorbing basic compounds, such as those having ammonium moieties. Acidic groups can be introduced by treating the fibers at elevated temperatures in the presence of steam, carbon dioxide, nitric acid, and the like.
- oxygen containing polymeric materials such as polyvinyl alcohol (PVA) or cellulose
- PVA polyvinyl alcohol
- cellulose may be used with an activation agent (e.g., phosphoric acid).
- an activation agent e.g., phosphoric acid
- such a coating mixture is heated to from about 150°C to about 300°C for about 2 minutes to about 24 hours.
- the polymeric material it may sometimes be desired to apply the polymeric material, the chemical activation agent, or a mixture thereof so as to cover less than about
- the polymeric material, the chemical activation agent, or a mixture thereof is applied to the substrate in a preselected pattern (e.g., reticular pattern, diamond-shaped grid, dots, and the like).
- a patterned coating may provide sufficient activation to the substrate without covering a substantial portion of the surface area of the substrate. This may be desirable to optimize flexibility, absorbency, or other characteristics of the resulting absorbent article.
- a patterned coating may also provide different functionality to each zone.
- the substrate is treated with two or more patterns of activated carbon regions that may or may not overlap. The regions may be on the same or different surfaces of the substrate.
- one surface of a substrate is treated with a polyacrylonitrile resin while another surface is treated with a polyvinyl alcohol resin.
- Each surface is then activated, such as described above, so that the resulting substrate has surfaces with different activated carbon coatings. This may allow, for instance, one surface to adsorb a basic odor-producing material, such as ammonia and/or triethylamine, while the other surface may adsorb an acidic odor-producing material, such as isovaleric acid.
- Other treatment conditions may also be varied to achieve different degrees of carbon activation.
- a single polymeric material is applied to the substrate.
- one portion of the substrate is exposed to a first activating gas, while another portion of the substrate is exposed to a second activating gas.
- additives may be used in the activated carbon coatings to vary theipore size and/or layer thickness of different coatings.
- the use of additives may also result in varied functional groups within each activated carbon coating.
- some suitable additives include, but are not limited to, metal compounds, organometallic compounds, pigments, mineral fillers, catalysts, acids or bases, and the like.
- the activated carbon substrates may also have various aesthetic benefits as well.
- the substrate may be incorporated with the activated carbon coating without having the black color commonly associated with activated carbon.
- a relatively thin layer of the activated carbon coating is applied to a white or light- colored substrate so that the resulting substrate has a grayish or bluish color.
- activation of the coating is halted prior to completion to leave a coating having a color other than black.
- the substrate may also be applied with patterned regions of the activated carbon coating to form a substrate having differently colored regions.
- the method of incorporating the substrate into an absorbent article may also be varied to optimize the functions of the substrate.
- the activated carbon substrate may be incorporated into regions of the absorbent article that are likely to remain relatively dry during use, such as the wings of a sanitary napkin, waistbands or leg cuffs of a diaper, or the remote ends or sides of an article positioned a certain distance from the zone configured to receive bodily fluids.
- the activated carbon substrate can reduce the odor of the article without having its odor-reducing capabilities substantially weakened by wetting.
- the activated carbon substrate may form the entire absorbent article, or may form only a portion of the article.
- the activated carbon substrate may constitute a surge layer, cover layer, transfer delay layer, etc. of an absorbent article, such as a sanitary napkin or diaper.
- the substrate may still function in the manner desired, but also be capable of reducing odor.
- cover layers of sanitary napkins are configured to quickly absorb fluids and wick them towards the inner layers of the napkin.
- the activated carbon substrate may still function to absorb fluids.
- an absorbent article 10 is shown in Fig. 1 as a sanitary napkin for feminine hygiene.
- the invention may be embodied in other types of absorbent articles, such as diapers, diaper pants, feminine napkins, children's training pants, and the like.
- the absorbent article 10 includes a cover 12, a baffle 14, and an absorbent core 16, any of which may contain the activated carbon substrate of the present invention.
- the absorbent core 16 is positioned inward from the outer periphery of the absorbent article 10 and includes a body-facing surface positioned adjacent the cover 12 and a garment-facing surface positioned adjacent the baffle 14.
- the cover 12 is generally designed to contact the body of the user and is liquid-permeable.
- the cover 12 can surround the absorbent core 16 so that it completely encases the absorbent article 10.
- the cover 12 and the baffle 14 can extend beyond the absorbent core 16 and be peripherally joined together, either entirely or partially, using known techniques.
- the cover 12 and the baffle 14 are joined by adhesive bonding, ultrasonic bonding, or any other suitable joining method known in the art.
- the liquid-permeable cover 12 is sanitary, clean in appearance, and somewhat opaque to hide bodily discharges collected in and absorbed by the absorbent core 16.
- the cover 12 further exhibits good strike-through and rewet characteristics permitting bodily discharges to rapidly penetrate through the cover 12 to the absorbent core 16, but not allow the body fluid to flow back through the cover 12 to the skin of the wearer.
- some suitable materials that can be used for the cover 12 include nonwoven materials, perforated thermoplastic films, or combinations thereof.
- a nonwoven fabric made from polyester, polyethylene, polypropylene, bicomponent, nylon, rayon, or like fibers may be utilized.
- a white uniform spunbond material is particularly desirable because the color exhibits good masking properties to hide menses that has passed through it.
- Patent Nos. 4,801,494 to Datta. et al. and 4,908 026 to Sukiennik. et al. teach various other cover materials that can be used in the present invention. If desired, the cover 12 may be incorporated with an activated carbon coating in accordance with the present invention to enable it to better function in reducing odors of bodily fluids.
- the cover 12 can also contain a plurality of apertures (not shown) formed therethrough to permit body fluid to pass more readily into the absorbent core 16.
- the apertures can be randomly or uniformly arranged throughout the cover 12, or they can be located only in the narrow longitudinal band or strip arranged along the longitudinal axis X-X of the absorbent article 10.
- the apertures permit rapid penetration of body fluid down into the absorbent core 16.
- the size, shape, diameter any number of apertures can be varied to suit one's particular needs.
- the absorbent article also includes a baffle 14.
- the baffle 14 is generally liquid-impermeable and designed to face the inner surface, i.e., the crotch portion of an undergarment (not shown).
- the baffle 14 can permit a passage of air or vapor out of the absorbent article 10, while still blocking the passage of liquids.
- Any liquid-impermeable material can generally be utilized to form the baffle 14.
- one suitable material that can be utilized is a microembossed polymeric film, such as polyethylene or polypropylene.
- a polyethylene film is utilized that has a thickness in the range of about 0.2 mils to about 5.0 mils, and particularly between about 0.5 to about 3.0 mils.
- the baffle 14 may be incorporated with an activated carbon coating in accordance with the present invention to enable it to better function in reducing odors of bodily fluids.
- the absorbent article 10 also contains an absorbent core 16 positioned between the cover 12 and the baffle 14.
- the absorbent core 16 contains three separate and distinct absorbent members 18, 20 and 22, any of which may contain the activated carbon substrate of the present invention. It should be understood, however, that any number of absorbent members can be utilized in the present invention. For example, in one embodiment, only the absorbent member 22 may be utilized.
- the first absorbent member 18, or intake member is positioned between the cover 12 and the second absorbent member 20, or transfer delay member.
- the intake member 18 represents a significant absorbing portion of the absorbent article 10 and has the capability of absorbing at least about 80%, particularly about 90%, and more particularly about 95% of the body fluid deposited onto the absorbent article 10. In terms of amount of body fluid, the intake member 18 can absorb at least about 20 grams, particularly about 25 grams, and more particularly, about 30 or more grams of body fluid.
- the intake member 18 can generally have any shape and/or size desired.
- the intake member 18 has a rectangular shape, with a length equal to or less than the overall length of the absorbent article 10, and a width less than the width of the absorbent article 10.
- a length of between about 150 mm to about 300 mm and a width of between about 10 mm to about 40 mm can be utilized.
- the intake member 18 is made of a material that is capable of rapidly transferring, in the z-direction, body fluid that is delivered to the cover 12.
- the intake member 18 is generally of a dimension narrower than the absorbent article 10, the sides of the intake member 18 are spaced away from the longitudinal sides of the absorbent article 10 and the body fluid is restricted to the area within the periphery of the intake member 18 before it passes down and is absorbed into the transfer delay member 20.
- This design enables the body fluid to be combined in the central area of the absorbent article 10 and to be wicked downward.
- any of a variety of different materials are capable of being used for the intake member 18 to accomplish the above-mentioned functions.
- airlaid cellulosic tissues may be suitable for use in the intake member 18.
- the airlaid cellulosic tissue can have a basis weight ranging from about 10 grams per square meter (gsm) to about 300 gsm, and in some embodiments, between about 100 gsm to about 250 gsm. In one embodiment, the airlaid cellulosic tissue has a basis weight of about 200 gsm.
- the airlaid tissue can be formed from hardwood and/or softwood fibers. The airlaid tissue has a fine pore structure and provides an excellent wicking capacity, especially for menses.
- a second absorbent member 20, or transfer delay member is also positioned vertically below the intake member 18.
- the transfer delay member 20 contains a material that is less hydrophilic than the other absorbent members, and may generally be characterized as being substantially hydrophobic.
- the transfer delay member 20 may be a nonwoven fibrous web composed of a relatively hydrophobic material, such as polypropylene, polyethylene, polyester or the like, and also may be composed of a blend of such materials.
- a material suitable for the transfer delay member 20 is a spunbond web composed of polypropylene, multi-lobal fibers.
- suitable transfer delay member materials include spunbond webs composed of polypropylene fibers, which may be round, tri-lobal or poly-lobal in cross-sectional shape and which may be hollow or solid in structure. Typically the webs are bonded, such as by thermal bonding, over about 3% to about 30% of the web area.
- suitable materials that may be used for the transfer delay member 20 are described in U.S. Patent Nos. 4,798,603 to Meyer, et al. and 5,248,309 to Portugalk. et al., which are incorporated herein in their entirety by reference thereto for all purposes.
- the transfer delay member 20 may also be treated with a selected amount of surfactant to increase its initial wettability.
- the transfer delay member 20 can generally have any size, such as a length of about 150 mm to about 300 mm. Typically, the length of the transfer delay member 20 is approximately equal to the length of the absorbent article 10.
- the transfer delay member 20 can also be equal in width to the intake member 18, but is typically wider. For example, the width of the transfer delay member 20 can be from between about 50 mm to about 75 mm, and particularly about 48 mm.
- the transfer delay member 20 of the absorbent core 16 typically has a basis weight less than that of the other absorbent members.
- the basis weight of the transfer delay member 20 is typically less than about 150 grams per square meter (gsm), and in some embodiments, between about 10 gsm to about 100 gsm.
- the transfer delay member 20 is formed from a spunbonded web having a basis weight of about 30 gsm.
- the absorbent core 16 also includes a composite member 22.
- the composite member 22 can be a coform material. In this instance, fluids can be wicked from the transfer delay member 20 into the absorbent member 22.
- the composite absorbent member 22 may be formed separately from the intake member 18 and/or transfer delay member 20, or can be formed simultaneously therewith. In one embodiment, for example, the composite absorbent member 22 can be formed on the transfer delay member 20 or intake member 18, which acts a carrier during the coform process described above.
- the absorbent article 10 may also contain other components as well.
- the lower surface of the baffle 14 can contain an adhesive for securing the absorbent article 10 to an undergarment.
- a backing (not shown) may be utilized to protect the adhesive side of the absorbent article 10 so that the adhesive remains clean prior to attachment to undergarment.
- the backing can generally have any desired shape or dimension.
- the backing can have a rectangular shape with dimension about 17 to about 21 cm in length and about 6.5 to 10.5 cm in width.
- the backing is designed to serve as a releasable peel strip to be removed by the user prior to attachment of the absorbent article 10 to the undergarment.
- the backing serving as a releasable peel strip can be a white Kraft paper that is coated on one side so that it can be released readily from the adhesive side of the absorbent article 10.
- the coating can be a silicone coating, such as a silicone polymer commercially available from Akrosil of Menasha, Wisconsin.
- the absorbent article 10 generally functions to absorb and retain fluids, such as menses, blood, urine, and other excrements discharged by the body during a menstrual period.
- the intake member 18 can allow the body fluid to be wicked downward in the z-direction and away from the cover 12 so that the cover 12 retains a dry and comfortable feel to the user.
- the intake member 18 can also absorb a significant amount of the fluid.
- the transfer delay member 20 initially accepts fluid from the intake member 18 and then wicks the fluid along its length and width (-x and -y axis) before releasing the fluid to the composite absorbent member 22.
- the composite absorbent member 22 then wicks the fluid along its length and width (-x and -y axis) utilizing a greater extent of the absorbent capacity than the transfer delay member 20. Therefore, the composite absorbent member 22 can become completely saturated before the fluid is taken up by the transfer delay member 20. The fluid is also wicked along the length of the transfer delay member 20 and the composite absorbent member 22, thereby keeping the fluid away from the edges of the absorbent article 10. This allows for a greater utilization of the absorbent core 16 and helps reduce the likelihood of side leakage.
- an absorbent article has been described above that may utilize the activated carbon substrate of the present invention, it should be understood that other absorbent article configurations are also included within the scope of the present invention. For instance, other absorbent configurations are described in U.S.
- et al. 5,267,992 to Van Tillburg; 4,687,478 to Van Tillburg; 4,285,343 to McNair; 4,608,047 to Mattinglv: 5,342,342 to Kitaoka; 5,190,563 to Herron.
- the activated carbon substrate of the present invention is used to form the leg cuff of a diaper.
- the present invention may be better understood with reference to the following examples.
- PAN Polyacrylonitrile
- DI water several times. 7. Dry the sample in oven at 120°C for 0.5 hours. Generally speaking, forced air ovens were used at low temperature (approximately 110°C) to dry the samples and then a convection oven or tube furnace (for temperatures above 200°C) was used to activate the samples. The oven can be run under vacuum during activation, if desired.
- EXAMPLE 1 The ability to form an activated carbon coating on a substrate was demonstrated.
- the substrate was a polymeric mesh, hereafter known as "Nylon Mesh D" and was taken from a commercial wash towel sold under the name
- Nylon Mesh D had a hexagonal pattern with openings approximately 2.8 millimeters wide and walls about 1 millimeter.
- Figure 2 shows a photograph of the mesh substrate 110 against a dark background. The melting point of the mesh was measured to be 252°C (within the normal range for nylon).
- a 12-inch by 12.5-inch rectangle of the mesh had a mass of 4.3 grams, giving a basis weight of about 44 grams per square meter (gsm).
- the mesh had fibers 112 primarily oriented in a first direction (longitudinal direction) 114, orthogonal to the traverse direction 116.
- Tensile testing was conducted using an MTS Alliance RT/1 testing device operating with TestWorks 4 software on a PC computer under Windows 98. The sample was cut to 1-inch wide and 5 inches long (in the longitudinal direction of the mesh) and tested for tensile properties with a crosshead speed of 10 inches per minute and a gage length of 4 inches.
- the mean peak load at failure was 6515 grams of force (standard deviation was 881 grams of force, with 4 samples tested), with a peak stretch of 42.3% (std. dev. of 5.25% stretch).
- the mean peak load at failure was 4351 grams of force (standard deviation was 379 grams of force, with 5 samples tested), with a peak stretch of 60.4% (std. dev. of 7.73% stretch).
- FIG. 3 shows a photograph of the treated sample 120, which comprises a solid network 122 defining isolated open regions 124 through which fluid can pass.
- the open regions 124 are partially occluded by flakes 126 attached to the solid network 122, which were apparently formed from the coating applied to the substrate. If desired, the flakes could be removed by further mechanical treatment, such as exposure to intense air flow from an air knife, brushing, flexing of the web as it bends around rollers, or other mechanical treatments.
- Tensile properties of the sample 120 in Figure 3 were tested using a 1-inch by 4-inch strip cut from the slightly larger material shown, with the 4-inch direction in the longitudinal direction (the direction of highest tensile strength in the original fabric). Tensile testing was done with a crosshead speed of 10 inches per minute with the MTS Alliance RT/1 test device and a gage length of 3 inches. The measurement for the sample gave a tensile strength of 2953 grams of force (gf), with a peak stretch of 27.8%, and a mean TEA (Total Energy Absorbed) value of 121 gf * cm/cm 2 .
- Nylon Mesh D was treated with PAN according to the protocol given above and activated at 225°C for 45 minutes, yielding an activated carbon fabric with 9.3% activated carbon.
- the fabric was relatively stiff.
- Nylon Mesh D was treated with cellulose in DMF and activated at 225°C for 45 minutes.
- the fabric was relatively stiff.
- Nylon Mesh D was dip coated with the PVA solution and activated under vacuum at 183°C, resulting in a pliable, stretchable mesh with 26.7 weight % activated carbon coating.
- Nylon Mesh A was treated with activated carbon according to the present invention.
- Nylon Mesh A was taken from the cover material on a Custom Auto Care Squeegee Washer, product 17004 manufactured by Custom Accessories, Inc., of Niles, Illinois. This mesh had a finer structure than Nylon Mesh D of Example 1 and had a basis weight of about 47 grams per meters squared. The melting point was approximately 250°C.
- the mesh was coated with PVA according to the PVA protocol above. In one run, the coating was activated at 170°C for 30 minutes, resulting in a flexible, extensible, permeable activated carbon fabric having an add-on level of 12.1% activated carbon. The melting point was approximately 250°C.
- the mesh was coated with PVA according to the PVA protocol above.
- the coating was activated at 170°C for 30 minutes, resulting in a flexible, extensible, permeable activated carbon fabric having 12.1- weight % activated carbon (13.6% add-on).
- Figure 4 shows the resulting activated carbon fabric 120, which has dimensions of approximately 6.8 cm by 3.1 cm. From left to right, there were 9 openings with a 2.7 cm length, and approximately 29 staggered rows of holes from top to bottom. The openings were slightly greater than 2 millimeters wide and slightly less than 2 millimeters tall.
- Nylon Mesh A was also treated with PVA at 225°C for 45 minutes. This treatment caused the substrate to be relatively stiff.
- a sample was cut from a ScotchBriteTM abrasive scrubbing pad from 3M (St. Paul, Minnesota) and treated with PVA, as described above, at 225°C and 45 minutes.
- the resulting substrate had 16.3 weight % activated carbon solids (addon of 19.5%) and was relatively coarse.
- Another run with another section of the pad gave an add-on level of 12.4%.
- Another sample was cut from the
- ScotchBriteTM pad was cut and treated with phenolic resin, as described above, at 225°C and 45 minutes.
- the resulting substrate had an add-on level of 35% and was relatively coarse.
- PGI 5928 is a nonwoven web made of 100% polyester (PET) and has a nominal basis weight of 42 gsm, a thickness of 0.46 millimeters, and MD tensile strength of 21 pounds per inch, a CD tensile strength of 10 pounds per inch, a MD elongation at peak load of 33%, and a CD elongation at peak load of 76%.
- the fabric was coated with PAN, per the above protocol, and activated at 230°C for 30 minutes in a vacuum, yielding a fabric with a 46.4% add-on level. The coating had a golden-bronze color rather than the black color typical of activated carbon.
- sample 4-A Another sample (Sample 4-A) of the fabric was coated with PVA, per the above protocol, and activated at 230°C for 30 minutes in a vacuum, yielding a fabric with an add-on level of 61.6%.
- sample 4-B Another sample (Sample 4-B) of the fabric was treated with PVA and activated at 170°C for 60 minutes, giving a fabric with a 52% add-on level.
- Still another sample of the fabric (sample 4-C) was coated with PVA, per the above protocol, and activated at 170°C for 30 minutes, followed by 2 minutes of washing with a residual acid content of 0.5%.
- the resulting fabric was black and had an add-on level of 55.8%.
- the fabric showed good flexibility and durability. Rubbing the fabric with the skin did not result in flakes or black dust coming off the fabric.
- a similar sample was washed for only 1 minute and had a measured residual acid content of 12% and a 55.8% add-on level. Washing a similar sample for 75 seconds resulted in a residual acid content of 6.1%.
- sample 4-D Another sample of the fabric (Sample 4-D) was coated with cellulose in DMF, per the above protocol, and activated at 230°C for 30 minutes in a vacuum, yielding a fabric with a 47.5% add-on level with a black color and golden-bronze tinge.
- Example 4-E Another sample of the fabric (Sample 4-E) was treated with phenolic resin and activated at 170°C for 60 minutes, yielding a relatively stiff fabric.
- Example 4-F Another sample of the fabric (Sample 4-F) was treated with a cellulose solution in DMF, as described above, at 170°C for 60 minutes. The resulting fabric was flexible and had an add-on level of 109%.
- EXAMPLE 5 A portion of reticulated "heavy duty" foam was applied with activated carbon.
- the foam was taken from a sponge-foam composite distributed by EGL Homecare of Essex, England under the name, the FairyTM Flipper Combination General Purpose Kitchen Sponge.
- the sponge portion was cut from the product and treated with PAN and activated at 275°C for 45 minutes.
- the resulting substrate was black and had an add-on level of 23.8%.
- the material was relatively stiff and some cells that had previously been open in the foam were occluded by black film.
- EXAMPLE 7 The abrasive cover of a ScotchBriteTM Dobie® Cleaning Pad (manufactured by 3M (St. Paul, Minnesota)) was coated with activated carbon.
- the substrate had a melting point of 248°C.
- the substrate was treated with phenolic resin and activated at 225°C for 45 minutes, resulting in an add-on level of 38%.
- the substrate was relatively stiff.
- the same substrate was also treated with PAN at the same activation conditions, resulting in an add-on level of 7.5%.
- the substrate was relatively stiff.
- the same substrate was also treated with PVA at the same activation conditions, resulting in an add-on level of 4%.
- the substrate was relatively stiff.
- EXAMPLE 8 A cotton T-shirt was cut into rectangular samples and coated with PAN, per the above protocol, and activated at 250°C for 45 minutes. The resulting substrate was black and relatively stiff. The substrate did not readily stretch under light loading. After pulling gently on the substrate by hand, many of the adjacent woven elements were separated without causing pieces of activated carbon to fall off. As a result, the substrate became elastically extensible. When pulled, light readily shined through the substrate. However, releasing tension allowed the fabric to contract again and return to high opacity.
- the substrate was also treated with PVA in one run and phenolic resin in another at the same activation conditions.
- the resulting substrates were relatively stiff.
- the substrate was also treated with cellulose in DMF at the same activation conditions.
- the resulting substrates were relatively flexible.
- EXAMPLE 9 A meltblown sample of Dow QuestraTM fiber (melting point of 264°C), provided by Dow, Inc., was treated with PVA per the above protocol and heated at 240°C for 45 minutes. The resulting substrate was black and had an add-on level of 73.3%. The substrate was relatively stiff. EXAMPLE 10
- a meltblown web formed from polybutylene terephthalate (PBT) was provided that had a basis weight of about 40 grams per square meter.
- the substrate was coated with the cellulosic solution in DMF, as described above, and activated at 195°C for 45 minutes.
- the resulting substrate was relatively flexible and had an add-on level of 61.3%.
- the substrate did not have openings sufficient to allow light to readily pass through the sample, but it appeared substantially opaque.
- EXAMPLE 11 The PGI 5928 PET meltblown fabric of Example 4 was coated with PVA and activated at 230°C for 30 minutes under vacuum, following the procedure used for
- Sample 4-A in Example 4 but with slightly less added coating, giving a sample with an add-on level of 43.9%.
- the sample was relatively stiff.
- EXAMPLE 12 A blue metallicized abrasive cover was taken from the Spontex® Flash All Purpose Scouring Pad, which is available from Spontex, Inc., Columbia,
- the substrate was treated with PAN according to the protocol above, except that PAN was applied using an airbrush and activated at 225°C for 45 minutes.
- the resulting substrate was black and bronze-colored and had an addon level of 4.6%.
- the previously blue metallicized portions tended to flake off readily, yielding flakes that were metallic (apparently aluminum-containing) on one side and dark black on the other side.
- the substrate (the Spontex® cover) was coated with PVA by airbrush and activated at 225°C for 45 minutes, resulting in a substrate that had an add-on level of 6.4% with good integrity.
- the substrate was coated with phenolic resin and activated at 225°C for 45 minutes, resulting in a substrate that had an add-on level of 33%. The substrate was relatively stiff.
- An airlaid mat comprising 92 wt.% bleached kraft softwood fibers and about 8 wt.% bicomponent binder fibers (polyethylene sheath / polyester core) was provided.
- the mat had a basis weight of about 95 grams per square meter.
- the substrate was coated with PVA per the above protocol, except that the PVA was applied using an airbrush and activated at 200°C for 30 minutes, yielding a bulky, flexible airlaid substrate having an add-on level of about 8.7%.
- Many portions of the resulting black mat appeared to have excellent penetration of the solution prior to activation such that the internal portions of the mat displayed black fibers as well as the outer portions.
- the mat maintained good porosity and allowed light to pass through numerous pores when viewed against a bright light source.
- Air permeability was measured with a FX 3300 Air Permeability device manufactured by Textest AG (Zurich, Switzerland), set to a pressure of 125 . Pascals with a 7-cm diameter opening.
- the substrate was instead tested as it rested on two layers of a single-ply tissue (Scott® handtowel). The two superposed tissue layers were tested for permeability and gave a reading of 73.3 cubic feet per minute (cfm). When the substrate was placed over the tissue, the measured permeability of the substrate and tissue layers was 52.4 cfm.
- a similar airlaid mat was treated with a higher level of applied coating (PVA) and activated at 170°C for 30 minutes, resulting in an add-on level of 19.9%. The mat was slightly stiff. A similar mat was treated under the same conditions but with less coating, resulting in an add-on level of 8.5% and a relatively flexible mat. In another run, an airlaid web treated with PVA was activated at 260°C for 30 minutes, resulting in a relatively stiff web that had an add-on level of 7.9%.
- PVA applied coating
- Dura-Glass 7529 (available from Johns Manville), a nonwoven fiberglass mat made from an E-glass material was treated with activated carbon.
- Dura-Glass 7529 had a basis weight of 90 grams per square meter and included fibers with a nominal 10-micron fiber diameter.
- the substrate had a thickness of 0.7 mm, a MD tensile strength greater than 100 lbs/3-inches, a CD tensile strength greater than 100 lbs/3-inches, and an air permeability of 575 CFM/sq. ft.
- the glass mat was coated with the phenolic coating per the above protocol and activated at 350°C for 30 minutes, yielding a substrate with an add-on level of 116%.
- the substrate allowed light to pass through in numerous low-basis weight regions that were not occluded by the coating, maintaining good porosity and permeability.
- Air permeability was measured in the same manner described above in Example 13.
- the fiberglass-based substrate when placed on two tissue layers, gave an aggregate air permeability of 55.4 cfm. When the substrate was placed on a single tissue layer, the aggregate air permeability was 85.4 cfm, which suggested that the air permeability of the substrate was substantially greater than, that of a single tissue layer.
- a related sample was prepared using cellulose with zinc chloride to coat the fiberglass, activated at 350°C for 30 minutes, yielding a fabric with 50.5% carbon (over 100% add-on).
- Another related sample was prepared using PAN as well under the same activation conditions, yielding a fabric with 27% added solids (37% add-on).
- Nylon Mesh B A polymeric web, termed Nylon Mesh B, was taken from the cover material of the Nylon Scouring Soap Pad of Arden Companies, Southfield Michigan, product M6030.
- the Nylon Mesh B was treated with PVA and activated at 170°C for 30 minutes.
- a high bulk, fibrous polymeric abrasive material was taken from the Quickie®
- a PET fabric as described in Example 4 (the PGI 5928 fabric was treated with both PAN and PVA solutions according to the protocols B and C above).
- Application was by spray painting, with some brush application by hand to adjust the patterns.
- a staggered array of roughly 1-inch circles of the treated areas was placed on an 8-inch by 11-inch section of the PET fabric. The result was about 50% of the fabric being covered with treated regions.
- FIG. 5 is a grayscale image of the treated sample 120, showing the golden- colored regions 142 corresponding to PAN treatment, the black regions 144 corresponding to PVA treatment, and white untreated regions 146.
- FIG. 6 is a grayscale image of the treated sample 120, showing the golden-colored regions 142 corresponding to PAN treatment, the black regions 144 corresponding to PVA treatment, and dual- treatment regions 148 where both PVA and PAN solutions had been applied (regions of overlap).
- EXAMPLE 18 An activated carbon fabric was prepared from a 150 gsm extruded mesh of EVA (ethylene vinyl acetate) having a thickness of 0.5 mm and approximately 50% open area with round holes about 0.5 mm in diameter arrayed in a staggered bilateral array. The web had elastic properties similar to a conventional rubber. The mesh was dip coated with PVA and activated at 170°C for 30 minutes, changing the initially white color of the mesh to black from the activated carbon coating. The mesh maintained a stretchable, elastic characteristic.
- EVA ethylene vinyl acetate
- Headspace Gas Chromatographv Adsorption testing was done with a headspace gas chromatography (headspace GC) procedure to measure the amount of an odoriferous compound removed from the gas phase by activated carbon materials.
- the headspace GC testing was conducted on an Agilent Technologies 5890, series II gas chromatograph with an Agilent Technology 7694 headspace sampler (Agilent Technologies, Waldbronn, Germany). Helium was used as the carrier gas (injection port pressure: 12.7 psig; headspace vial pressure: 15.8 psig; supply line pressure is at 60 psig).
- NH 3 ammonia
- a HayeSep P stainless steel column Alltech Associates, Inc.
- TEA triethylamine
- TMA trimethylamine
- DMDS dimethyldisulphide
- ethyl mercaptan a DB-624 column (J&W Scientific, Inc. of Folsom, California) was used that had a length of 30 meters, an internal diameter of 0.25 millimeters, and a 1.4-micron film.
- Table 1 The operating parameters for the headspace GC, as a function of the odoriferous agent being tested, are shown below in Table 1 : Table 1. Operating Parameters for the Headspace GC Device.
- the test procedure involved placing about 0.14 grams of the activated carbon material (unless otherwise specified) inside a 20-cubic centimeter headspace vial. The amount of sample can be adjusted to keep the measurement within range of the instrument for better accuracy. Using a syringe, an aliquot of an odoriferous agent was also placed in the vial, taking care not to let the liquid and activated carbon contact. The vial was then sealed with a cap and septum and placed in the headspace GC oven at a temperature of 37°C. After ten minutes, a hollow needle was inserted through the septum and into the vial. A 1 -cubic centimeter sample of the headspace (air inside the vial) was then injected into the headspace GC.
- a control vial with only the aliquot of odoriferous agent was tested to define 0% odoriferous agent adsorption.
- the peak area for the odoriferous agent from the vial with activated carbon is compared to the peak area from the odoriferous agent control vial (no activated carbon).
- Table 2 shows headspace gas chromatography results for the adsorption of ammonia for materials from Examples 4, 11 , and 14 above.
- the first column shows the sample being tested.
- the second column is the area (counts * seconds).
- Calibration results are shown for three control runs consisting of 6 microliters of 28% ammonia solution.
- the average area, 1.41 E+06 is proportional to the amount of ammonia used in the test (6 microliters).
- the fourth column shows the percent removed of the odorant, calculated as:
- the absolute amount removed is the percent removed multiplied by the amount of odorant injected, which was 1.5 milligrams.
- the absolute amount removed divided by the fabric sample mass is given in the third column as "mg/g fabric.”
- the amount removed is divided by the mass of the activated carbon coating on the fabric, the result is milligrams of odorant adsorbed / activated carbon mass, given under the heading "mg/g a.c.” in the sixth column.
- Repetition 1 (“Rep. 1") of the activated carbon fabric from Example 14 was made from an E-glass fabric coated with cellulose and chemically converted to activated carbon material. The sample was tested by placing 0.0718 grams of the fabric in the test device, having 0.0363 grams of activated carbon coating.
- Example 12 with relatively little activated carbon (0.0085 g of activated carbon in the 0.14 g samples - see the columns labeled "Carbon mass” and "Fabric mass”), gave the highest adsorption in terms of mg of ammonia adsorbed per gram of activated carbon material, with a mean of about 96 mg/g a.c.
- Table 4 shows test results for adsorption of DMDS by materials from Examples 4, 11 , and 14, as well as commercially available activated carbon granules in the form of Calgon RGC 40 x 1000 activated carbon marketed by
- Tables 5A and 5B show additional results from headspace GC testing for DMDS adsorption by materials from Examples 3, 14, and 16.
- the cellulose-treated fiberglass of Example 14 and the PVA-treated commercial scrub pad (Example 3) gave the highest levels of adsorption.
- any one kind of activated carbon material or an activated carbon fabric may not be suitable for all odorants, and low adsorption of one or more odorants may be compensated in commercial practice by excellent adsorption of other odorants or by other benefits such as improved strength, durability, or flexibility.
Abstract
Description
Claims
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BR0317122A BR0317122A (en) | 2002-12-23 | 2003-10-17 | Absorbent article containing activated carbon substrate |
MXPA05006064A MXPA05006064A (en) | 2002-12-23 | 2003-10-17 | Absorbent articles containing an activated carbon substrate. |
EP20030776431 EP1575626A1 (en) | 2002-12-23 | 2003-10-17 | Absorbent articles containing an activated carbon substrate |
AU2003284251A AU2003284251A1 (en) | 2002-12-23 | 2003-10-17 | Absorbent articles containing an activated carbon substrate |
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US10/328,729 | 2002-12-23 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006071333A2 (en) * | 2004-12-23 | 2006-07-06 | Kimberly-Clark Worldwide, Inc. | Odor control substrates |
Families Citing this family (45)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19909653A1 (en) | 1999-03-05 | 2000-09-07 | Stockhausen Chem Fab Gmbh | Powdery, crosslinked, aqueous liquids and blood-absorbing polymers, processes for their preparation and their use |
US20030065296A1 (en) * | 2001-02-26 | 2003-04-03 | Kaiser Thomas A. | Absorbent material of water absorbent polymer, thermoplastic polymer, and water and method for making same |
US7169843B2 (en) * | 2003-04-25 | 2007-01-30 | Stockhausen, Inc. | Superabsorbent polymer with high permeability |
DE10334286B4 (en) | 2003-07-25 | 2006-01-05 | Stockhausen Gmbh | Powdered, water-absorbing polymers with fine particles bound by means of thermoplastic adhesives, process for their preparation and chemical products and compounds containing them |
US7173086B2 (en) * | 2003-10-31 | 2007-02-06 | Stockhausen, Inc. | Superabsorbent polymer with high permeability |
US20050113771A1 (en) * | 2003-11-26 | 2005-05-26 | Kimberly-Clark Worldwide, Inc. | Odor control in personal care products |
US8025960B2 (en) * | 2004-02-02 | 2011-09-27 | Nanosys, Inc. | Porous substrates, articles, systems and compositions comprising nanofibers and methods of their use and production |
US20110039690A1 (en) * | 2004-02-02 | 2011-02-17 | Nanosys, Inc. | Porous substrates, articles, systems and compositions comprising nanofibers and methods of their use and production |
US7553371B2 (en) * | 2004-02-02 | 2009-06-30 | Nanosys, Inc. | Porous substrates, articles, systems and compositions comprising nanofibers and methods of their use and production |
US7163529B2 (en) * | 2004-12-15 | 2007-01-16 | Kimberly-Clark Worldwide, Inc. | Absorbent article having disposal wings with odor absorbency |
US7816285B2 (en) | 2004-12-23 | 2010-10-19 | Kimberly-Clark Worldwide, Inc. | Patterned application of activated carbon ink |
US7763061B2 (en) * | 2004-12-23 | 2010-07-27 | Kimberly-Clark Worldwide, Inc. | Thermal coverings |
US7338516B2 (en) * | 2004-12-23 | 2008-03-04 | Kimberly-Clark Worldwide, Inc. | Method for applying an exothermic coating to a substrate |
US8168852B2 (en) | 2004-12-23 | 2012-05-01 | Kimberly-Clark Worldwide, Inc. | Activated carbon substrates |
US7541398B2 (en) * | 2005-01-03 | 2009-06-02 | Board Of Regents, The University Of Texas System | Method for transformation of conventional and commercially important polymers into durable and rechargeable antimicrobial polymeric materials |
US20090075060A1 (en) * | 2005-02-16 | 2009-03-19 | Miller James R | Adsorptive coating formulation |
US7655829B2 (en) | 2005-07-29 | 2010-02-02 | Kimberly-Clark Worldwide, Inc. | Absorbent pad with activated carbon ink for odor control |
US20070062884A1 (en) | 2005-08-11 | 2007-03-22 | Board Of Regents, The University Of Texas System | N-halamines compounds as multifunctional additives |
US7998886B2 (en) * | 2005-10-24 | 2011-08-16 | Milliken & Company | Hindered amine treated textiles |
US7812082B2 (en) * | 2005-12-12 | 2010-10-12 | Evonik Stockhausen, Llc | Thermoplastic coated superabsorbent polymer compositions |
US20070141352A1 (en) * | 2005-12-15 | 2007-06-21 | Calhoun Patricia H | Cross-directional elastic films with machine direction stiffness |
US20070218562A1 (en) * | 2006-03-20 | 2007-09-20 | Shulong Li | Color indicator for halamine treated fabric |
US8486428B2 (en) * | 2006-03-27 | 2013-07-16 | Board Of Regents, The University Of Texas System | Compositions and methods for making and using acyclic N-halamine-based biocidal polymeric materials and articles |
US8066956B2 (en) * | 2006-12-15 | 2011-11-29 | Kimberly-Clark Worldwide, Inc. | Delivery of an odor control agent through the use of a presaturated wipe |
US8211361B2 (en) * | 2007-03-26 | 2012-07-03 | Board Of Regents, The University Of Texas System | N-halamine-based rechargeable biofilm-controlling tubular devices, method of making and using |
US7858539B2 (en) * | 2007-04-09 | 2010-12-28 | Milliken & Company | Processes for generating halamine compounds on textile substrates to produce antimicrobial finish |
JP2011501732A (en) * | 2007-09-19 | 2011-01-13 | ボード・オブ・リージエンツ,ザ・ユニバーシテイ・オブ・テキサス・システム | Colorant-based N-halamine compositions and methods of manufacture and use |
US20090110890A1 (en) * | 2007-10-30 | 2009-04-30 | 3M Innovative Properties Company | Color changing wear indicator |
DE102007054702B4 (en) * | 2007-11-14 | 2018-10-18 | Smartpolymer Gmbh | Process for the preparation of cellulosic shaped bodies, cellulosic shaped bodies and their use |
ES2910086T3 (en) | 2009-05-19 | 2022-05-11 | Oned Mat Inc | Nanostructured materials for battery applications |
US8623288B1 (en) | 2009-06-29 | 2014-01-07 | Nanosys, Inc. | Apparatus and methods for high density nanowire growth |
US8642833B2 (en) * | 2009-08-04 | 2014-02-04 | Harbor Linen Llc | Absorbent article containing structured fibers |
US8629316B2 (en) * | 2009-08-04 | 2014-01-14 | Harbor Linen Llc | Absorbent article containing structured fibers |
US20140087615A1 (en) * | 2012-09-21 | 2014-03-27 | Robinson Outdoor Products | Composite fabric with adsorbent polymer material |
CN104780950B (en) | 2012-11-12 | 2016-09-28 | Sca卫生用品公司 | Odour controlling materials, prepare the method for odour controlling materials and comprise the absorbent products of odour controlling materials |
US9301884B2 (en) | 2012-12-05 | 2016-04-05 | Kimberly-Clark Worldwide, Inc. | Liquid detection system having a signaling device and an absorbent article with graphics |
US9925096B2 (en) * | 2013-12-20 | 2018-03-27 | Sca Hygiene Products Ab | Absorbent product comprising an odor control material |
JP6340654B2 (en) | 2013-12-20 | 2018-06-13 | エスセーアー・ハイジーン・プロダクツ・アーベー | Absorbent products including odor control materials |
AT516414B1 (en) * | 2014-10-28 | 2017-07-15 | Chemiefaser Lenzing Ag | Liquid-soaked non-woven fabric containing zinc oxide-containing cellulose fibers |
WO2017100440A1 (en) | 2015-12-10 | 2017-06-15 | The Procter & Gamble Company | Article comprising odor control composition |
CN106198523A (en) * | 2016-07-06 | 2016-12-07 | 哈尔滨贝贝凯尔科技发展有限公司 | Trace element detection reagent paper and preparation method thereof |
RU2712654C1 (en) * | 2016-12-05 | 2020-01-30 | Эссити Хайджин Энд Хелт Актиеболаг | Absorbent product containing foam material |
FR3074047B1 (en) * | 2017-11-30 | 2019-12-20 | Biomerieux | NON-IMPLANTABLE MEDICAL DEVICES INCORPORATING A DEVICE FOR DETECTION AND / OR IDENTIFICATION OF MICROBIOLOGICAL INFECTIONS |
USD971555S1 (en) * | 2019-11-25 | 2022-12-06 | Joylux, Inc. | Women's undergarment |
US20230372894A1 (en) * | 2022-05-17 | 2023-11-23 | Freestyle World, Inc. | Disposable absorbent article with odor reducing agents |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0311364A2 (en) * | 1987-10-06 | 1989-04-12 | JOHNSON & JOHNSON | Wound dressing with activated carbon |
DE3816352A1 (en) * | 1988-05-13 | 1989-11-23 | Hartmann Paul Ag | Single-use cellulose hygiene article |
US5834114A (en) * | 1995-05-31 | 1998-11-10 | The Board Of Trustees Of The University Of Illinois | Coated absorbent fibers |
WO2001097972A1 (en) * | 2000-06-21 | 2001-12-27 | Board Of Trustees Of University Of Illinois | Activated organic coatings on a fiber substrate |
WO2002060496A2 (en) * | 2000-12-15 | 2002-08-08 | Kimberly-Clark Worldwide, Inc. | Coated activated carbon |
Family Cites Families (97)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3502763A (en) * | 1962-02-03 | 1970-03-24 | Freudenberg Carl Kg | Process of producing non-woven fabric fleece |
US3502538A (en) * | 1964-08-17 | 1970-03-24 | Du Pont | Bonded nonwoven sheets with a defined distribution of bond strengths |
DE2048006B2 (en) * | 1969-10-01 | 1980-10-30 | Asahi Kasei Kogyo K.K., Osaka (Japan) | Method and device for producing a wide nonwoven web |
US3658069A (en) * | 1970-02-17 | 1972-04-25 | Stanford Research Inst | Filter for reducing the level of carbon monoxide in tobacco smoke |
US3868955A (en) * | 1973-10-05 | 1975-03-04 | Personal Products Co | Aldehyde polysaccharide dressings |
US4100324A (en) * | 1974-03-26 | 1978-07-11 | Kimberly-Clark Corporation | Nonwoven fabric and method of producing same |
JPS5913244B2 (en) * | 1976-05-12 | 1984-03-28 | 本州製紙株式会社 | Adsorbent nonwoven fabric and its manufacturing method |
JPS5414478A (en) * | 1977-07-04 | 1979-02-02 | Kurashiki Boseki Kk | Method of uniformly pushing powdery substance to porous material |
US4323534A (en) * | 1979-12-17 | 1982-04-06 | The Procter & Gamble Company | Extrusion process for thermoplastic resin composition for fabric fibers with exceptional strength and good elasticity |
US4340563A (en) * | 1980-05-05 | 1982-07-20 | Kimberly-Clark Corporation | Method for forming nonwoven webs |
US4341216A (en) * | 1981-02-27 | 1982-07-27 | The Procter & Gamble Company | Breathable backsheet for disposable diapers |
US4375718A (en) * | 1981-03-12 | 1983-03-08 | Surgikos, Inc. | Method of making fibrous electrets |
US4374888A (en) * | 1981-09-25 | 1983-02-22 | Kimberly-Clark Corporation | Nonwoven laminate for recreation fabric |
DE3211322A1 (en) * | 1982-03-27 | 1983-09-29 | Hasso von 4000 Düsseldorf Blücher | AREA FILTER AND METHOD FOR THE PRODUCTION THEREOF |
US5085654A (en) * | 1982-11-15 | 1992-02-04 | The Procter & Gamble Company | Disposable garment with breathable leg cuffs |
WO1984003193A1 (en) * | 1983-02-04 | 1984-08-16 | Minnesota Mining & Mfg | Method and apparatus for manufacturing an electret filter medium |
DE3304349C3 (en) * | 1983-02-09 | 1995-10-26 | Bluecher Hubert | Surface filter and process for its manufacture |
US4565727A (en) * | 1983-09-12 | 1986-01-21 | American Cyanamid Co. | Non-woven activated carbon fabric |
US4802473A (en) * | 1983-11-07 | 1989-02-07 | Tecnol, Inc. | Face mask with ear loops |
JPS60168511A (en) * | 1984-02-10 | 1985-09-02 | Japan Vilene Co Ltd | Production of electret filter |
DE3418521A1 (en) * | 1984-05-18 | 1985-11-21 | Henkel KGaA, 4000 Düsseldorf | MENSTRUALTAMPON |
US4504290A (en) * | 1984-06-14 | 1985-03-12 | Columbus Industries, Inc. | Odor filter media |
DE3443900C2 (en) * | 1984-12-01 | 1997-03-06 | Bluecher Hubert | Protective material, process for its production and its use |
US4904343A (en) * | 1985-04-23 | 1990-02-27 | American Cyanamid Company | Non-woven activated carbon fabric |
US4663220A (en) * | 1985-07-30 | 1987-05-05 | Kimberly-Clark Corporation | Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers |
US4657802A (en) * | 1985-07-30 | 1987-04-14 | Kimberly-Clark Corporation | Composite nonwoven elastic web |
US4720415A (en) * | 1985-07-30 | 1988-01-19 | Kimberly-Clark Corporation | Composite elastomeric material and process for making the same |
US4655760A (en) * | 1985-07-30 | 1987-04-07 | Kimberly-Clark Corporation | Elasticized garment and method of making the same |
US4680040A (en) * | 1986-01-17 | 1987-07-14 | Xerox Corporation | Multipurpose filtering material |
US4797318A (en) * | 1986-07-31 | 1989-01-10 | Kimberly-Clark Corporation | Active particle-containing nonwoven material, method of formation thereof, and uses thereof |
CA1283764C (en) * | 1986-09-29 | 1991-05-07 | Mitsui Chemicals Inc. | Very soft polyolefin spunbonded nonwoven fabric and its production method |
US4758239A (en) * | 1986-10-31 | 1988-07-19 | Kimberly-Clark Corporation | Breathable barrier |
US4908026A (en) * | 1986-12-22 | 1990-03-13 | Kimberly-Clark Corporation | Flow distribution system for absorbent pads |
US4834738A (en) * | 1986-12-31 | 1989-05-30 | Kimberly-Clark Corporation | Disposable garment having elastic outer cover and integrated absorbent insert structure |
US4801494A (en) * | 1987-04-10 | 1989-01-31 | Kimberly-Clark Corporation | Nonwoven pad cover with fluid masking properties |
CA1309008C (en) * | 1987-05-21 | 1992-10-20 | Brian Farnworth | Skin tight chemical/biological protective suit |
US4920960A (en) * | 1987-10-02 | 1990-05-01 | Tecnol, Inc. | Body fluids barrier mask |
US5150703A (en) * | 1987-10-02 | 1992-09-29 | Tecnol Medical Products, Inc. | Liquid shield visor for a surgical mask with a bottom notch to reduce glare |
US4798603A (en) * | 1987-10-16 | 1989-01-17 | Kimberly-Clark Corporation | Absorbent article having a hydrophobic transport layer |
US5383869A (en) * | 1988-03-31 | 1995-01-24 | The Procter & Gamble Company | Thin, flexible sanitary napkin |
US5009653A (en) * | 1988-03-31 | 1991-04-23 | The Procter & Gamble Company | Thin, flexible sanitary napkin |
US4985023A (en) * | 1988-05-09 | 1991-01-15 | Dow Corning Corporation | Antimicrobial superabsorbent articles |
US5035892A (en) * | 1988-05-09 | 1991-07-30 | Dow Corning Corporation | Antimicrobial superabsorbent compositions and methods |
US4990338A (en) * | 1988-05-09 | 1991-02-05 | Dow Corning Corporation | Antimicrobial superabsorbent compositions and methods |
JPH0729052B2 (en) * | 1988-05-18 | 1995-04-05 | ニチアス株式会社 | Method for manufacturing activated carbon-supported honeycomb structure |
US5385772A (en) * | 1988-09-19 | 1995-01-31 | Adco Products, Inc. | Pressure-sensitive adhesive systems with filler |
US5226992A (en) * | 1988-09-23 | 1993-07-13 | Kimberly-Clark Corporation | Process for forming a composite elastic necked-bonded material |
US4981747A (en) * | 1988-09-23 | 1991-01-01 | Kimberly-Clark Corporation | Composite elastic material including a reversibly necked material |
US5190563A (en) * | 1989-11-07 | 1993-03-02 | The Proctor & Gamble Co. | Process for preparing individualized, polycarboxylic acid crosslinked fibers |
US5116662A (en) * | 1989-12-15 | 1992-05-26 | Kimberly-Clark Corporation | Multi-direction stretch composite elastic material |
US5114781A (en) * | 1989-12-15 | 1992-05-19 | Kimberly-Clark Corporation | Multi-direction stretch composite elastic material including a reversibly necked material |
AU657676B2 (en) * | 1990-02-12 | 1995-03-23 | Procter & Gamble Company, The | High capacity odor controlling compositions |
US5093422A (en) * | 1990-04-23 | 1992-03-03 | Shell Oil Company | Low stress relaxation extrudable elastomeric composition |
US4995976A (en) * | 1990-05-31 | 1991-02-26 | Water Technologies Corporation | Water purification straw |
US5213881A (en) * | 1990-06-18 | 1993-05-25 | Kimberly-Clark Corporation | Nonwoven web with improved barrier properties |
US5124856A (en) * | 1990-08-03 | 1992-06-23 | International Business Machines Corporation | Magnetic recording device with unitary filter medium to trap organic and inorganic chemical pollutants |
US5079004A (en) * | 1990-08-06 | 1992-01-07 | Dow Corning Corporation | Antimicrobial superabsorbent compositions and method |
CA2048905C (en) * | 1990-12-21 | 1998-08-11 | Cherie H. Everhart | High pulp content nonwoven composite fabric |
US5482773A (en) * | 1991-07-01 | 1996-01-09 | E. I. Du Pont De Nemours And Company | Activated carbon-containing fibrids |
US5716349A (en) * | 1991-07-23 | 1998-02-10 | The Procter & Gamble Company | Absorbent article having longitudinal side margins with tucks |
US5385775A (en) * | 1991-12-09 | 1995-01-31 | Kimberly-Clark Corporation | Composite elastic material including an anisotropic elastic fibrous web and process to make the same |
US5234422A (en) * | 1991-12-20 | 1993-08-10 | The Procter & Gamble Company | Elasticized sanitary napkin |
US5197659A (en) * | 1992-07-21 | 1993-03-30 | Wtpa, Incorporated | Disposable box by folding into a log-shaped configuration |
US5382400A (en) * | 1992-08-21 | 1995-01-17 | Kimberly-Clark Corporation | Nonwoven multicomponent polymeric fabric and method for making same |
KR100316167B1 (en) * | 1992-09-16 | 2001-12-12 | 메시에 삐에르 | A Combination Comprising A Demand Disinfectant Component And A Carrier Component And Dressing |
EP0825286A3 (en) * | 1992-11-18 | 2000-11-02 | AQF Technologies LLC | Fibrous structure containing immobilized particulate matter and process therefor |
BR9204863A (en) * | 1992-11-25 | 1994-03-01 | Johnson & Johnson Ind Com | DISPOSABLE FEMALE INTIMO ABSORBENT |
CA2101833A1 (en) * | 1992-12-14 | 1994-06-15 | Kimberly-Clark Worldwide, Inc. | Stretchable meltblown fabric with barrier properties |
US5322061B1 (en) * | 1992-12-16 | 1998-06-02 | Tecnol Med Prod Inc | Disposable aerosol mask |
CA2157465C (en) * | 1993-03-31 | 2001-07-31 | Toan Trinh | Absorbent articles for odor control with positive scent signal |
US5358500A (en) * | 1993-06-03 | 1994-10-25 | The Procter & Gamble Company | Absorbent articles providing sustained dynamic fit |
US5332613A (en) * | 1993-06-09 | 1994-07-26 | Kimberly-Clark Corporation | High performance elastomeric nonwoven fibrous webs |
US5401445A (en) * | 1993-06-25 | 1995-03-28 | Martin Marietta Energy Systems, Inc. | Fluid casting of particle-based articles |
CA2116953C (en) * | 1993-10-29 | 2003-08-19 | Kimberly-Clark Worldwide, Inc. | Absorbent article which includes superabsorbent material located in discrete elongate pockets placed in selected patterns |
US5425725A (en) * | 1993-10-29 | 1995-06-20 | Kimberly-Clark Corporation | Absorbent article which includes superabsorbent material and hydrophilic fibers located in discrete pockets |
CA2116081C (en) * | 1993-12-17 | 2005-07-26 | Ann Louise Mccormack | Breathable, cloth-like film/nonwoven composite |
DE9320208U1 (en) * | 1993-12-31 | 1994-03-31 | Kalthoff Luftfilter Und Filter | Multi-layer filter material |
US5732718A (en) * | 1994-08-23 | 1998-03-31 | Schweitzer-Mauduit International, Inc. | Selective filtration device |
US5736473A (en) * | 1994-09-14 | 1998-04-07 | Kimberly-Clark Corp. | Fibrous composite structure including particulates |
EP0871533A1 (en) * | 1995-05-12 | 1998-10-21 | Donaldson Company, Inc. | Filter device |
US6057262A (en) * | 1995-05-19 | 2000-05-02 | University Of Kentucky Research Foundation | Activated carbon and process for making same |
JPH11508185A (en) * | 1995-06-20 | 1999-07-21 | ドナルドソン カンパニー,インコーポレイティド | Filter and manufacturing method of filter |
US5908598A (en) * | 1995-08-14 | 1999-06-01 | Minnesota Mining And Manufacturing Company | Fibrous webs having enhanced electret properties |
US5571096A (en) * | 1995-09-19 | 1996-11-05 | The Procter & Gamble Company | Absorbent article having breathable side panels |
US5865823A (en) * | 1996-11-06 | 1999-02-02 | The Procter & Gamble Company | Absorbent article having a breathable, fluid impervious backsheet |
US6203810B1 (en) * | 1996-05-31 | 2001-03-20 | The Procter & Gamble Company | Breathable perspiration pads having odor control |
EP0811388A1 (en) * | 1996-06-07 | 1997-12-10 | The Procter & Gamble Company | Activated carbon free absorbent articles having a silica and zeolite odour control system |
US6248202B1 (en) * | 1996-12-04 | 2001-06-19 | The Procter & Gamble Company | Process for manufacturing individual layered structures comprising particulate material, and layered structures therefrom |
US6037281A (en) * | 1996-12-27 | 2000-03-14 | Kimberly-Clark Worldwide, Inc. | Cloth-like, liquid-impervious, breathable composite barrier fabric |
US5883026A (en) * | 1997-02-27 | 1999-03-16 | Kimberly-Clark Worldwide, Inc. | Face masks including a spunbonded/meltblown/spunbonded laminate |
US6197404B1 (en) * | 1997-10-31 | 2001-03-06 | Kimberly-Clark Worldwide, Inc. | Creped nonwoven materials |
US6245401B1 (en) * | 1999-03-12 | 2001-06-12 | Kimberly-Clark Worldwide, Inc. | Segmented conformable breathable films |
US6365088B1 (en) * | 1998-06-26 | 2002-04-02 | Kimberly-Clark Worldwide, Inc. | Electret treatment of high loft and low density nonwoven webs |
US6362389B1 (en) * | 1998-11-20 | 2002-03-26 | Kimberly-Clark Worldwide, Inc. | Elastic absorbent structures |
EP1218090B1 (en) * | 1999-08-23 | 2005-11-02 | Gore Enterprise Holdings, Inc. | Filter for removing contaminants from an enclosure |
US6238467B1 (en) * | 1999-09-24 | 2001-05-29 | Gore Enterprise Holdings, Inc. | Rigid multi-functional filter assembly |
US20030078552A1 (en) * | 2001-06-01 | 2003-04-24 | The Procter & Gamble Company | Odor-controlling disposal container |
-
2002
- 2002-12-23 US US10/328,729 patent/US20040121681A1/en not_active Abandoned
-
2003
- 2003-10-17 MX MXPA05006064A patent/MXPA05006064A/en unknown
- 2003-10-17 EP EP20030776431 patent/EP1575626A1/en not_active Withdrawn
- 2003-10-17 WO PCT/US2003/032849 patent/WO2004060414A1/en not_active Application Discontinuation
- 2003-10-17 AU AU2003284251A patent/AU2003284251A1/en not_active Abandoned
- 2003-10-17 KR KR1020057010352A patent/KR20050085435A/en not_active Application Discontinuation
- 2003-10-17 BR BR0317122A patent/BR0317122A/en not_active IP Right Cessation
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0311364A2 (en) * | 1987-10-06 | 1989-04-12 | JOHNSON & JOHNSON | Wound dressing with activated carbon |
DE3816352A1 (en) * | 1988-05-13 | 1989-11-23 | Hartmann Paul Ag | Single-use cellulose hygiene article |
US5834114A (en) * | 1995-05-31 | 1998-11-10 | The Board Of Trustees Of The University Of Illinois | Coated absorbent fibers |
WO2001097972A1 (en) * | 2000-06-21 | 2001-12-27 | Board Of Trustees Of University Of Illinois | Activated organic coatings on a fiber substrate |
WO2002060496A2 (en) * | 2000-12-15 | 2002-08-08 | Kimberly-Clark Worldwide, Inc. | Coated activated carbon |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2006071333A2 (en) * | 2004-12-23 | 2006-07-06 | Kimberly-Clark Worldwide, Inc. | Odor control substrates |
WO2006071333A3 (en) * | 2004-12-23 | 2006-08-31 | Kimberly Clark Co | Odor control substrates |
Also Published As
Publication number | Publication date |
---|---|
KR20050085435A (en) | 2005-08-29 |
BR0317122A (en) | 2005-10-25 |
MXPA05006064A (en) | 2005-08-16 |
EP1575626A1 (en) | 2005-09-21 |
US20040121681A1 (en) | 2004-06-24 |
AU2003284251A1 (en) | 2004-07-29 |
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