WO2004048437A3 - A multi-component catalyst system for the polycondensation manufacture of polyesters - Google Patents

A multi-component catalyst system for the polycondensation manufacture of polyesters Download PDF

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Publication number
WO2004048437A3
WO2004048437A3 PCT/CA2003/001842 CA0301842W WO2004048437A3 WO 2004048437 A3 WO2004048437 A3 WO 2004048437A3 CA 0301842 W CA0301842 W CA 0301842W WO 2004048437 A3 WO2004048437 A3 WO 2004048437A3
Authority
WO
WIPO (PCT)
Prior art keywords
polycondensation
polyesters
catalyst system
component catalyst
component
Prior art date
Application number
PCT/CA2003/001842
Other languages
French (fr)
Other versions
WO2004048437A2 (en
Inventor
Andrew Wallace
Philip James Martin
Alan David Farnaby
Original Assignee
Teck Cominco Metals Ltd
Andrew Wallace
Philip James Martin
Alan David Farnaby
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Teck Cominco Metals Ltd, Andrew Wallace, Philip James Martin, Alan David Farnaby filed Critical Teck Cominco Metals Ltd
Priority to AU2003286061A priority Critical patent/AU2003286061A1/en
Publication of WO2004048437A2 publication Critical patent/WO2004048437A2/en
Publication of WO2004048437A3 publication Critical patent/WO2004048437A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/87—Non-metals or inter-compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/826—Metals not provided for in groups C08G63/83 - C08G63/86
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/83—Alkali metals, alkaline earth metals, beryllium, magnesium, copper, silver, gold, zinc, cadmium, mercury, manganese, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/84—Boron, aluminium, gallium, indium, thallium, rare-earth metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • C08G63/86—Germanium, antimony, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/34—Manganese
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C08G63/183—Terephthalic acids

Abstract

This invention relates to new multi-component catalyst systems for the polycondensation of polyesters. More particularly, this invention pertains to novel multi-component, germanium based catalyst systems for the polycondensation of PET (polyethylene terephthalate) used in the manufacture of bottles, fibre or film. A multi-component catalyst system for the polycondensation of a polyester comprising the element germanium and one or more catalyst enhancers selected from the group of elements consisting of aluminium, silicon, molybdenum, manganese, lithium and combinations thereof, said elements being in the form of compounds, acids, bases, salts, compositions, oxides or organic complexes.
PCT/CA2003/001842 2002-11-26 2003-11-24 A multi-component catalyst system for the polycondensation manufacture of polyesters WO2004048437A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2003286061A AU2003286061A1 (en) 2002-11-26 2003-11-24 A multi-component catalyst system for the polycondensation manufacture of polyesters

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US10/303,977 US6953768B2 (en) 2002-11-26 2002-11-26 Multi-component catalyst system for the polycondensation manufacture of polyesters
US10/303,977 2002-11-26

Publications (2)

Publication Number Publication Date
WO2004048437A2 WO2004048437A2 (en) 2004-06-10
WO2004048437A3 true WO2004048437A3 (en) 2004-08-19

Family

ID=32325105

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CA2003/001842 WO2004048437A2 (en) 2002-11-26 2003-11-24 A multi-component catalyst system for the polycondensation manufacture of polyesters

Country Status (4)

Country Link
US (2) US6953768B2 (en)
AU (1) AU2003286061A1 (en)
TW (1) TW200420601A (en)
WO (1) WO2004048437A2 (en)

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WO2005123385A1 (en) * 2004-06-17 2005-12-29 Teijin Dupont Films Japan Limited Laminated film for reflection plate
US20060287471A1 (en) * 2005-06-16 2006-12-21 Schreiber Benjamin R Accelerated acetaldehyde testing of polymers
US8557950B2 (en) 2005-06-16 2013-10-15 Grupo Petrotemex, S.A. De C.V. High intrinsic viscosity melt phase polyester polymers with acceptable acetaldehyde generation rates
US7655746B2 (en) 2005-09-16 2010-02-02 Eastman Chemical Company Phosphorus containing compounds for reducing acetaldehyde in polyesters polymers
US7932345B2 (en) 2005-09-16 2011-04-26 Grupo Petrotemex, S.A. De C.V. Aluminum containing polyester polymers having low acetaldehyde generation rates
US8431202B2 (en) * 2005-09-16 2013-04-30 Grupo Petrotemex, S.A. De C.V. Aluminum/alkaline or alkali/titanium containing polyesters having improved reheat, color and clarity
US7838596B2 (en) * 2005-09-16 2010-11-23 Eastman Chemical Company Late addition to effect compositional modifications in condensation polymers
US9267007B2 (en) * 2005-09-16 2016-02-23 Grupo Petrotemex, S.A. De C.V. Method for addition of additives into a polymer melt
US7625992B2 (en) * 2006-04-18 2009-12-01 E. I. Du Pont De Nemours And Company Processes for polyurethane polymerization using polysilyl derivatives of germanium and tin as catalysts
US7709593B2 (en) * 2006-07-28 2010-05-04 Eastman Chemical Company Multiple feeds of catalyst metals to a polyester production process
US7709595B2 (en) * 2006-07-28 2010-05-04 Eastman Chemical Company Non-precipitating alkali/alkaline earth metal and aluminum solutions made with polyhydroxyl ether solvents
US7745368B2 (en) * 2006-07-28 2010-06-29 Eastman Chemical Company Non-precipitating alkali/alkaline earth metal and aluminum compositions made with organic hydroxyacids
US20080027207A1 (en) * 2006-07-28 2008-01-31 Jason Christopher Jenkins Non-precipitating alkali/alkaline earth metal and aluminum compositions made with mono-ol ether solvents
US8563677B2 (en) * 2006-12-08 2013-10-22 Grupo Petrotemex, S.A. De C.V. Non-precipitating alkali/alkaline earth metal and aluminum solutions made with diols having at least two primary hydroxyl groups
US8058360B2 (en) 2007-06-01 2011-11-15 Grupo Petrotemex, S.A. De C.V. Polyester blends exhibiting low temperature toughness
US8307653B2 (en) * 2009-02-02 2012-11-13 Siemens Energy, Inc. Combined catalysts for the combustion of fuel in gas turbines
FR3027906B1 (en) 2014-10-29 2017-01-06 Roquette Freres METHOD FOR MANUFACTURING POLYESTER CONTAINING AT LEAST ONE IMPROVED COLORATION 1,4: 3,6-DIANHYDROHEXITOL

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Also Published As

Publication number Publication date
US20040224842A1 (en) 2004-11-11
AU2003286061A1 (en) 2004-06-18
US6953768B2 (en) 2005-10-11
TW200420601A (en) 2004-10-16
WO2004048437A2 (en) 2004-06-10
US7153811B2 (en) 2006-12-26
US20040102316A1 (en) 2004-05-27
AU2003286061A8 (en) 2004-06-18

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