WO2004041524A2

WO2004041524A2 - High strength dimensionally stable core

Info

Publication number: WO2004041524A2
Application number: PCT/US2003/034318
Authority: WO
Inventors: Gopal Iyengar; Jeffrey G. Dicks; Mark D. Ellis; Gary G. Glodoski
Original assignee: Stora Enso North America Corporation
Priority date: 2002-10-31
Filing date: 2003-10-30
Publication date: 2004-05-21
Also published as: AU2003288955A1; AU2003288955A8; US20060021725A1; WO2004041524A3

Abstract

A paperboard having improved strength and water resistance comprises a standard paperboard furnish modified by adding 5-60 lbs/ton alum, 3-40 lbs/ton of liquid size, and 16-50 lbs/ton modified cationic starch. A more preferred formulation has a paperboard furnish, 4-40 lbs of alum per ton of furnish, 3-12 lbs of liquid size per ton of furnish, and 30-40 lbs of cationic starch per ton of furnish Other additives such as a dry strength agent and microparticle silica may be added. Paperboard cores spirally wound from the paperboard of the invention exhibit shorter cure time, higher strength, improved dimensional stability, and reduced moisture migration.

Description

HIGH STRENGTH DIMENSIONALITY STABLE CORE

Field of the Invention

This invention relates to paperboard, paperboard cores and tubes, and to a method for making cores and tubes.

Background of the Invention

In the manufacture of paper, paper is wound onto cores. Cores are conventionally manufactured from laminated, spirally wound paperboard. It is important that cores have sufficient crush strength. Dimensional stability of cores is also important in roll handing operations.

Moisture content in paper varies considerably from grade to grade depending on the manufacturing process. Similarly, paperboard cores are made at different moisture levels, depending on the absorption characteristics of the paperboard from which it is made and the adhesive used to glue the board layers to form a laminated core. As a result, in the winding of paper onto cores, there is typically a moisture content difference between the paper and the core. A difference in moisture content between the paper and core causes moisture to migrate. Moisture migration from the core to the paper and vice versa can cause corrugations and wrinkling in the paper, and in some cases core bursts, resulting in paper losses.

Papermills today make wide paper rolls by winding different webs of paper onto a single core. Often, the different webs have different moisture contents, aggravating moisture migration problems. Further, these wide rolls require high strength cores to support the substantial weight of the paper.

Summary of the Invention

It is an object of the invention to provide a high strength, dimensional stable paperboard core, with improved resistance to moisture migration. It is a further object of the invention to provide a high strength, water resistant paperboard that has utility in the fabrication of such cores.

The core of the invention is manufactured from spirally wound paperboard having improved water resistance. The paperboard is made from a standard paperboard furnish. A preferred furnish comprises a mixture of 25- 70% doubleliner kraft ("DLK"), and 25-70% recycled corrugated containers ("OCC"), and 30-50% recycled cores and/or other cores waste ("corebale"). The furnish should have a freeness of 150-275 CSF. The furnish is modified by adding 5-60 lbs/ton alum, 3-40 lbs/ton of liquid size, and 16-50 lbs/ton modified cationic starch. Other additives may optionally include 0.2 - 1. lbs/ton microparticle silica, and/or 2-8 lbs/ton of a dry strength agent, but are not required.

A more preferred formulation has a paperboard furnish, 4-40 lbs of alum per ton of furnish (more ideally 4-12 lbs/ton of alum); 3-12 lbs of liquid size per ton of furnish, and 30-40 lbs of cationic starch per ton of furnish.

It has been discovered that the combination of alum and a liquid size substantially improves water resistance. The alum improves drainage and helps reduce the swelling of wood fibers. Wood fibers swell when absorbing water. Significant drying energy or time is required to remove moisture absorbed by the fiber. Desirably the resulting paperboard has water absorption less than 400 cgs.

A suitable alum product is aluminum sulfate solution available from General Alum & Chemical Corporation, Holland, Ohio.

A preferred liquid size is Ultra-pHase® cationic dispersed size manufactured by Hercules Incorporated, Wilmington, Delaware.

The modified cationic starch improves strength, especially in combination with alum. Cationic starch also contributes to drainage, thereby allowing for a reduction in the quantity of alum used. A preferred starch product is Penford Topcat 776 cationic additive, manufactured by Penford Products Co., Cedar Rapids, Iowa. Other suitable starch products are Avebee Amylofax 3300C and Amylofax-HS. The microparticle silica is added to improve the drainage in the paperboard making process. A preferred microparticle silica is Nalco 8692

Papermaking Aid, an aqueous dispersion of an inorganic hydrous oxide microparticle, manufactured by Nalco Chemical Company, Naperville, Illinois. Other microparticle silica products may be used as well.

The dry strength agent improves strength and contributes somewhat to improvement in water resistance. Suitable dry strength agent is Callaway 911 dry strength agent, manufactured by Vulcan Performance Chemicals, Birmingham, Alabama. However, most dry strength agents are expensive additives and for this reason are less preferred.

The forgoing optional additives are selected and added as required to produce the required properties of the core. For example, if a high strength is not required, one could use little or no starch or dry strength agents. Other additives could be used, for example a wet strength agent. The modified furnish is manufactured into paperboard by known manufacturing techniques, such as fourdrinier or multiple cylinder papermachine, to produce a finished paperboard having a basis weight of 50- 142 lbs per 1000 sq/ft, a caliper of about 0.013 to .041 inches, a density of 0.7 to 1.0 g/cm and a moisture content of between about 3-6 percent. The moisture content of the cores preferably should be as close as possible to the moisture content of the paper to be wound onto the cores.

The paperboard is then wound with conventional core machinery to form paperboard cores having between 3-32 plies. For example, one embodiment of the invention comprises high strength cores for paper rolls, which have 20-32 plies. Another application of the invention is for cores for adhesive tape and other small tube applications, which have 3-7 plies. In smaller cores made in accordance with this disclosure have a lower core crush variability due to humidity and improved dimensional stability. The preferred adhesive used in winding the cores is polymer base, such as latex or polyvinyl alcohol; however, other adhesives like dextrins may be used. Testing on the cores made in accordance with the foregoing exhibited increased crush strength, and increased water holdout. The cores exhibited reduced moisture carry over, and low core length shrinkage. Other benefits include reduced core warpage and less variability in core inner and outer diameter.

Detailed Description of Preferred Embodiments

Examples of the improved high strength, dimensional stable cores of the invention are provided as follows: GP1 Standard

The furnish comprised: 950 lbs DLK, 1,000 lbs OCC and 1,400 lbs corebale. Paperboard was manufactured from the furnish on a conventional board machine. The resulting paperboard had a caliper of about 0.02 inches and a basis weight of about 80 lbs/1,000 square feet. The core was wound in conventional process, having a lead-in ply and 30 structural plies formed with the above furnish. The cores had an internal diameter of 3.025 inches and a wall thickness of 0.66 inches.

Paperboard and cores were tested for water absorption and strength. The paperboard had a water absorption of less than about 950 - 1150 cgs based on the amount of water absorbed by a 6" x 6" paper board sample submerged in a water bath for 10 minutes (Tappi test method T491-om-99). The paperboard had a ZDT bond strength of 100 "Z"directional internal bond strength of board tested on a ZDT tester. Core crush strength was 800-850 lbs on a 4" length of core, and Dynamic load strength of 26-29 lbs/4" section. The moisture content of the core was 9-11%.

Example PI The same paperboard and cores as in Example GP1 were manufactured, except that the following constituents were added to the furnish: Callaway 911 dry strength agent @ 6 lbs/ton dry weight Ultra-Phase liquid size @ 31 lbs/ton dry weight

Alum was varied between 20 and 60 lbs/ton dry weight Paperboard and cores were tested for water absorption and strength. The paperboard had a water absorption of less than 400 cgs based on the amount of water absorbed by a 6" x 6" paper board sample submerged in a water bath for 10 minutes. The paperboard had a ZDT bond strength 105-112 - "Z"directional internal bond strength of board tested on a ZDT tester. Core crush strength was 1135 lbs on a 4" length of core, and Dynamic load strength of 35.2 lbs/4" section. The moisture content of the core was 7.86%.

Example P2 The same paperboard and cores as in Example GP1 were manufactured, except that the following constituents were added to the furnish:

Callaway 91 ldry strength agent @ 6 lbs/ton dry weight Ultra-Phase size @ 16 lbs/ton dry weight Avebe Amylofax-HS starch was varied between 33 and 50 lbs/ton dry weight. Alum was varied between 20 and 60 lbs/ton dry weight

Paperboard and cores were tested for water absorption and strength. The paperboard had a water absorption of less than 300 cgs based on the amount of water absorbed by a 6" x 6" paper board sample submerged in a water bath for 10 minutes. The paperboard had a ZDT bond strength 112-124 - "Z"directional internal bond strength of board tested on a ZDT tester. Core crush strength was 1238 lbs on a 4" length of core, and Dynamic load strength of 36.3 lbs/4" section. The moisture content of the core was 8.43%.

Example P5 The same paperboard and cores as in Example GP1 were manufactured, except that the following constituents were added to the furnish:

Penford Topcat 776 cationic starch @ 30 lbs/ton dry weight Ultra-pHase size @ 3 lbs/ton dry weight Alum @ 4 lbs/ton dry weight. Paperboard and cores was tested for water absorption and strength. The paperboard had a water absorption of less than 700 cgs based on the amount of water absorbed by a 6" x 6" paper board sample submerged in a water bath for 10 minutes. The paperboard had a ZDT bond strength 125-141 - "Z"directional internal bond strength of board tested on a ZDT tester. Core crush strength was 1299 lbs on a 4" length of core, and Dynamic load strength of 36.5 lbs/4" section. The moisture content of the core was 7.23%.

Example P5A Example P5A was prepared in the same manner as Example P5, with the following modifications to the alum and size constituents: Ultra-pHase size @ 12 lbs/ton dry weight Alum @ 4-5 lbs/ton dry weight.

Attached as Figures 1-10 are graphs that summarize comparative testing on the cores of examples GPl, PI, P2 and P5. Figs. 1-7 show the effects of ambient air drying on standard core samples made in accordance with this disclosure, namely PI, P2 and P5 as compared to a standard core sample GPl. Uniformly, the samples PI, P2 and P5 exhibit significantly less variability than the standard GPl core. Conventionally cores must be dried either by ambient air drying or by oven drying to reach a target moisture content and other criteria specified by the mill, i.e., the cores must be cured prior to use. Ambient drying takes time and storage space. Oven drying requires a capital expenditure plus energy. Cores made in accordance with this disclosure reduce or eliminate these costs.

Fig. 1, shows that core moisture varies considerably with the GPl standard core. Core samples PI, P2 and P5 showed considerably less moisture variability. Core sample P5 showed nearly nil core moisture variability. Fig. 2 shows the effect of ambient drying on core crush strength.

The GPl standard core is typical of conventional cores. Crush strength varies considerable as the core cures. Also, crush strength increases with time from its initial green strength. In contrast the core samples PI, P2 and P5 performed considerably better exhibiting less variability and less cure time. Also, the P5 core exhibited superior crush strength. Fig. 3 illustrates the effect of ambient drying time on dynamic load strength. The dynamic load strength test simulates the dynamic loads that cores experience when being wound with paper or other material. As with core crush strength, core sample GPl standard exhibited considerable variability, while core samples PI, P2 and P5 exhibited comparatively less variability.

Fig. 4 shows the effect of ambient drying on length shrinkage. Core samples PI, P2 and P5 show less variability as compared to GPl standard.

Fig. 5 shows the effect of ambient drying on core warp. Core waφ is measured as the differential height between high and low spots on the core, when the core is held in a level, horizontal position. The Fig. 5 graph shows considerable variability in warp in the GPl standard core as it cures.

Core samples PI and P5 exhibit considerable less waφ during the same period.

Fig. 6 illustrates the effect of ambient drying time on core outer diameter, and Fig 7 shows the effect on core inner diameter. The graphs show comparatively less variability in diameter in samples PI, P2 and P5, as contrasted with the GPl- standard.

Fig. 8 shows the effect of oven drying on core moisture. Core samples PI, P2 and P5 had lower moisture contents than the GPl standard core.

Fig. 9 shows the effect of oven drying on core moisture on core crush strength and dynamic load strength. In both cases core sample P5 exhibited increased core crush strength.

Fig. 10 shows moisture migration from the core to the paper. Paper of a uniform, low moisture content (1.5%) was wound onto the core samples, and held for a period of 7 days to 3 weeks time. The paper was then un-wound and the moisture content of the paper was measured at various locations measured radially from the core. The graph shows that there is little difference between core samples on paper located radially more than 3 inches from the core. However, in the range of 3 inches to 0.5 inch radially from the core, the paper wound onto the GPl standard core picked up more moisture from the core (moisture migration), as compared to either the PI or P2 sample cores. In the range of 0.5 inch and less radially outward from the core, the paper wound on to the GPl standard core exhibited greater moisture migration to the paper as compared to the P2 core sample.

Further testing on Example P5A has shown strength improvements in addition to reduced variability and improved moisture migration resistance. The following Tables 1-3 compare properties of standard GPl core samples (Table 1) with core samples having the same furnish as GPl but with the additives of Example P5A (Table 2), and a conventional high strength core, designated GPl-X (Table 3). The GPl-X core is spirally wound from high strength Pori paperboard, available from Coresno AB, Finland. Pori board is considerably more expensive that the conventional paperboard used to make the GPl standard. Specifically, the direct costs (material, setup and running) for GPl-X cores is approximately 26% greater than standard GPl cores. In contrast, the P5A core direct costs is only marginally greater (approximately 3.5%) than the standard GPl core.

Table-1 GP1 Standard Core

The data of Tables 1-3 show that the cores made with comparatively low cost furnish with the additives of Example P5A, produce a core that with essentially no ambient drying has a crush strength that is substantially higher than the standard GPl core and comparable to more expensive, high strength GP-1 cores. Dynamic load data for the P5A core is also significantly higher than the standard GP-1 core.

Tables 1-3 further show that the amount of ambient drying time necessary to reach a target moisture content is substantially lower in Example P5A cores. With essentially no drying time, the P5A core had a 9.7% moisture. To achieve the same moisture content required at least 4 days for the GPl standard core and 7 days for the GPl-X core. It is believed that the combination of alum and size improves weatheφroof characteristics of the paperboard & a combination of alum and modified cationic starch facilitates more effective drainage and therefore improved drying and efficiencies on the paperboard machine as well.

The following Tables 4-6 compare properties of oven dried standard GPl core samples (Table 4) with oven dried core samples having the same furnish as GPl but with the additives of Example P5A (Table 5), and an oven dried conventional high strength GPl-X core (Table 6). Table-4 GP1 Standard Core

Tables 4-6 show that in the oven dried cores, the P5A core exhibits substantially higher crush strength and dynamic load strength than the standard GPl core. The oven P5A cores had strength comparable to the more expensive GPl-X cores. In addition, the P5A cores had substantially lower moisture content after the same drying time, and a lower temperature, as compared to both the GPl standard and GP-X cores.

While presently preferred embodiments of the invention have been herein described, it is to be appreciated that various changes, rearrangements and modifications may be made therein without departing from the scope of the invention as defined by the appended claims.

Claims

What is claimed is:

1. Paperboard having improved resistance to moisture migration, comprises a paperboard furnish, 5-60 lbs of alum per ton of furnish, 3-40 lbs of size per ton of furnish, and 16-50 lbs of cationic starch per ton of furnish.

2. Paperboard as in claim 1, wherein said furnish comprises 25- 70 percent doubleliner Kraft, 25-70% recycled paperboard containers, and 30- 50% core waste.

3. Paperboard as in claim 2, having a freeness of 150-270 csf.

4. Paperboard as in claim 1 further comprising 2-8 lbs of dry strength agent per ton of furnish.

5. Paperboard as in claim 1, further comprising 0.2-1. lb of microparticle silica per ton of furnish.

6. Paperboard having improved strength and resistance to moisture migration, comprises a paperboard furnish, 4-40 lbs of alum per ton of furnish, 3-12 lbs of size per ton of furnish, and 30-40 lbs of cationic starch per ton of furnish.

7. Paperboard as in claim 6, wherein said furnish comprises 25- 70 percent doubleliner Kraft, 25-70% recycled paperboard containers, and 30-

50%) core waste.

8. Paperboard as in claim 6, the paperboard having a water absoφtion of less than 400 cgs.

9. Paperboard as in claim 6 further comprising 2-8 lbs of dry strength agent per ton of furnish.

10. Paperboard as in claim 6, further comprising 0.2-1. lb of microparticle silica per ton of furnish.

11. Paperboard as in claim 9, wherein said alum is about 4-12 lbs per ton of furnish.

12. A high strength, dimensional stable paperboard core, comprising a plurality of spirally wound paperboard plies, said paperboard comprising a paperboard furnish, 5-60 lbs of alum per ton of furnish, 3-40 lbs of size per ton of furnish, and 16-50 lbs of cationic starch per ton of furnish.

13. A core as in claim 12, wherein said paperboard further comprises 2-8 lbs of dry strength agent per ton of furnish.

14. A core as in claim 12 wherein said paperboard further comprises 0.2-1. lb of microparticle silica per ton of furnish.

15. A high strength, dimensional stable paperboard core, comprising a plurality of spirally wound paperboard plies, said paperboard comprising a paperboard furnish comprised of 25-70 percent doubleliner Kraft, 25-70% recycled paperboard containers and 30-50% core waste; 5-60 lbs of alum per ton of furnish; 3-40 lbs of size per ton of furnish; and 16-50 lbs of cationic starch per ton of furnish; said paperboard having a water absoφtion of less than 400cgs.