WO2003059849A8 - Stabilisation of acid catalysts - Google Patents

Stabilisation of acid catalysts

Info

Publication number
WO2003059849A8
WO2003059849A8 PCT/US2002/034114 US0234114W WO03059849A8 WO 2003059849 A8 WO2003059849 A8 WO 2003059849A8 US 0234114 W US0234114 W US 0234114W WO 03059849 A8 WO03059849 A8 WO 03059849A8
Authority
WO
WIPO (PCT)
Prior art keywords
directed
stabilisation
acid catalysts
molecular sieves
feedstock
Prior art date
Application number
PCT/US2002/034114
Other languages
French (fr)
Other versions
WO2003059849A1 (en
Inventor
Filip Mees
Etienne Vansant
Marcel J Janssen
Luc R M Martens
Original Assignee
Exxonmobil Chem Patents Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Chem Patents Inc filed Critical Exxonmobil Chem Patents Inc
Priority to JP2003559958A priority Critical patent/JP2005514319A/en
Priority to EP02806437A priority patent/EP1472202A4/en
Priority to AU2002367007A priority patent/AU2002367007A1/en
Publication of WO2003059849A1 publication Critical patent/WO2003059849A1/en
Publication of WO2003059849A8 publication Critical patent/WO2003059849A8/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates (SAPO compounds)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/24—After treatment, characterised by the effect to be obtained to stabilize the molecular sieve structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/38—Base treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/40—Ethylene production

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The invention is directed to a method of stabilizing metalloaluminophosphate molecular sieves and catalysts derived therefrom. In particular, the invention is directed to a method of treating such molecular sieves with chemisorbed ammonia, which may be easily desorbed before or during use and after storage. The invention is also directed to formulating the molecular sieve into a catalyst useful in a process for producing olefin(s), preferably ethylene and/or propylene, from a feedstock, preferably an oxygenate containing feedstock.
PCT/US2002/034114 2002-01-03 2002-10-24 Stabilisation of acid catalysts WO2003059849A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2003559958A JP2005514319A (en) 2002-10-24 2002-10-24 Stabilization of acid catalyst
EP02806437A EP1472202A4 (en) 2002-01-03 2002-10-24 Stabilisation of acid catalysts
AU2002367007A AU2002367007A1 (en) 2002-01-03 2002-10-24 Stabilisation of acid catalysts

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP02250030 2002-01-03
EP02250030.0 2002-01-03

Publications (2)

Publication Number Publication Date
WO2003059849A1 WO2003059849A1 (en) 2003-07-24
WO2003059849A8 true WO2003059849A8 (en) 2004-09-02

Family

ID=8185623

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2002/034114 WO2003059849A1 (en) 2002-01-03 2002-10-24 Stabilisation of acid catalysts

Country Status (8)

Country Link
US (2) US6897180B2 (en)
EP (1) EP1472202A4 (en)
CN (1) CN1282632C (en)
AU (1) AU2002367007A1 (en)
MY (1) MY134303A (en)
TW (1) TWI270407B (en)
WO (1) WO2003059849A1 (en)
ZA (1) ZA200405065B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9138732B2 (en) 2007-02-27 2015-09-22 Basf Corporation Copper CHA zeolite catalysts

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL1020603C2 (en) * 2002-05-15 2003-11-18 Tno Process for drying a product using a regenerative adsorbent.
US7268094B2 (en) * 2003-08-18 2007-09-11 Chevron U.S.A. Inc. Mixed matrix membrane with super water washed silica containing molecular sieves and methods for making and using the same
US7241716B2 (en) 2003-11-10 2007-07-10 Exxonmobil Chemical Patents Inc. Protecting catalytic sites of metalloaluminophosphate molecular sieves
CN1993167A (en) * 2004-08-03 2007-07-04 科罗拉多州立大学董事会 Membranes for highly selective separations
US7592282B2 (en) * 2004-11-11 2009-09-22 Battelle Energy Alliance, Llc Enhancement of alkylation catalysts for improved supercritical fluid regeneration
CN101443298A (en) * 2006-05-15 2009-05-27 科罗拉多州立大学董事会 High flux and selectivity SAPO-34 membranes for CO/CH4 separations
TW200904752A (en) * 2007-03-09 2009-02-01 Univ Colorado Regents Synthesis of zeolites and zeolite membranes using multiple structure directing agents
JP5777339B2 (en) 2007-04-26 2015-09-09 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーＪｏｈｎｓｏｎ Ｍａｔｔｈｅｙ Ｐｕｂｌｉｃｌｉｍｉｔｅｄ Ｃｏｍｐａｎｙ Transition metal / zeolite SCR catalyst
US20090196812A1 (en) 2008-01-31 2009-08-06 Basf Catalysts Llc Catalysts, Systems and Methods Utilizing Non-Zeolitic Metal-Containing Molecular Sieves Having the CHA Crystal Structure
US10583424B2 (en) 2008-11-06 2020-03-10 Basf Corporation Chabazite zeolite catalysts having low silica to alumina ratios
US8530528B2 (en) * 2010-02-01 2013-09-10 Clariant Corporation Water-forming hydrogenation reactions utilizing enhanced catalyst supports and methods of use
EP2552862B1 (en) * 2010-03-31 2015-09-09 Dow Global Technologies LLC Process to increase selectivity to ethylene in oxygenates-to-olefins conversions
US8679227B2 (en) 2010-04-29 2014-03-25 The Regents Of The University Of Colorado High flux SAPO-34 membranes for CO2/CH4 separation and template removal method
US9162942B2 (en) 2010-08-26 2015-10-20 Exxonmobil Chemical Patents Inc. Catalyst regeneration process
US9802182B2 (en) * 2013-03-13 2017-10-31 Basf Corporation Stabilized metal-exchanged SAPO material
CN103230810B (en) * 2013-04-25 2015-11-04 武汉凯迪工程技术研究总院有限公司 The fischer-tropsch synthetic catalyst of preparation of low carbon olefines by synthetic gas, modified molecular screen carrier and preparation method

Family Cites Families (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4440871A (en) 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
US4677242A (en) 1982-10-04 1987-06-30 Union Carbide Corporation Production of light olefins
US4499327A (en) 1982-10-04 1985-02-12 Union Carbide Corporation Production of light olefins
US4677243A (en) 1982-10-04 1987-06-30 Union Carbide Corporation Production of light olefins from aliphatic hetero compounds
FR2582130B1 (en) 1985-05-20 1987-08-14 Menn Roger TRICHROME ELECTROLUMINESCENT MATRIX SCREEN AND MANUFACTURING METHOD
US4681864A (en) * 1985-07-15 1987-07-21 W. R. Grace & Co. Cracking catalyst
EP0230005A3 (en) * 1985-12-23 1987-08-26 W.R. Grace & Co.-Conn. Cracking catalyst
US4861938A (en) * 1987-07-07 1989-08-29 Uop Chemical conversion process
US4873390A (en) 1987-07-07 1989-10-10 Uop Chemical conversion process
US4874896A (en) * 1987-12-23 1989-10-17 Uop Process for the production of alkylamines
US5013699A (en) * 1988-04-07 1991-05-07 Uop Novel zeolite compositions derived from zeolite Y
US4874590A (en) * 1988-04-07 1989-10-17 Uop Catalytic reduction of nitrogen oxides
US5095163A (en) 1991-02-28 1992-03-10 Uop Methanol conversion process using SAPO catalysts
US5248647A (en) * 1991-02-28 1993-09-28 Uop Sapo catalysts and use thereof in methanol conversion processes
US5250484A (en) * 1991-11-26 1993-10-05 Mobil Oil Corporation Surface modified porous acidic crystalline catalyst
US5185310A (en) * 1992-01-31 1993-02-09 Mobil Oil Corp. Activating silicoaluminophosphate compositions
JPH07155614A (en) * 1993-12-07 1995-06-20 Toyota Motor Corp Production of exhaust gas purifying catalyst
US5714662A (en) 1995-08-10 1998-02-03 Uop Process for producing light olefins from crude methanol
US6051746A (en) * 1997-06-18 2000-04-18 Exxon Chemical Patents Inc. Oxygenate conversions using modified small pore molecular sieve catalysts
TWI234556B (en) * 1997-07-23 2005-06-21 Mitsubishi Gas Chemical Co Catalysts for methanol conversion reactions
US6051745A (en) * 1999-03-04 2000-04-18 Phillips Petroleum Company Silicoaluminophosphate material, a method of making such improved material and the use thereof in the conversion of oxygenated hydrocarbons to olefins
US6316683B1 (en) 1999-06-07 2001-11-13 Exxonmobil Chemical Patents Inc. Protecting catalytic activity of a SAPO molecular sieve
US6225254B1 (en) 1999-06-07 2001-05-01 Exxon Mobil Chemical Patents Inc. Maintaining acid catalyst sites in sapo molecular sieves
US6395674B1 (en) 1999-06-07 2002-05-28 Exxon Mobil Chemical Patents, Inc. Heat treating a molecular sieve and catalyst
US6166282A (en) 1999-08-20 2000-12-26 Uop Llc Fast-fluidized bed reactor for MTO process
WO2001025150A1 (en) 1999-10-01 2001-04-12 Pop, Grigore Process for the synthesis of silicoaluminophosphate molecular sieves
US6756516B2 (en) * 2001-07-02 2004-06-29 Exxonmobil Chemical Patents Inc. Treatment of acid catalysts

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9138732B2 (en) 2007-02-27 2015-09-22 Basf Corporation Copper CHA zeolite catalysts
US9162218B2 (en) 2007-02-27 2015-10-20 Basf Corporation Copper CHA zeolite catalysts
US11845067B2 (en) 2007-02-27 2023-12-19 Basf Corporation Copper CHA zeolite catalysts

Also Published As

Publication number Publication date
CN1282632C (en) 2006-11-01
TW200302133A (en) 2003-08-01
WO2003059849A1 (en) 2003-07-24
EP1472202A1 (en) 2004-11-03
ZA200405065B (en) 2006-06-28
EP1472202A4 (en) 2008-01-23
US6897180B2 (en) 2005-05-24
CN1617841A (en) 2005-05-18
AU2002367007A1 (en) 2003-07-30
US7193122B2 (en) 2007-03-20
TWI270407B (en) 2007-01-11
MY134303A (en) 2007-12-31
US20050148462A1 (en) 2005-07-07
US20030149321A1 (en) 2003-08-07

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