WO2003040281A1 - The active soluble cleaning composite of natural state using soybean fatty acids and the making method thereof - Google Patents

The active soluble cleaning composite of natural state using soybean fatty acids and the making method thereof Download PDF

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Publication number
WO2003040281A1
WO2003040281A1 PCT/KR2002/001990 KR0201990W WO03040281A1 WO 2003040281 A1 WO2003040281 A1 WO 2003040281A1 KR 0201990 W KR0201990 W KR 0201990W WO 03040281 A1 WO03040281 A1 WO 03040281A1
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WO
WIPO (PCT)
Prior art keywords
weight
parts
detergent
soybean fatty
fatty acid
Prior art date
Application number
PCT/KR2002/001990
Other languages
French (fr)
Inventor
Kwang-Hwa Choi
Original Assignee
Green & Clean, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Green & Clean, Inc. filed Critical Green & Clean, Inc.
Priority to JP2003542320A priority Critical patent/JP4133823B2/en
Priority to AU2002353558A priority patent/AU2002353558B2/en
Priority to US10/494,190 priority patent/US7247607B2/en
Publication of WO2003040281A1 publication Critical patent/WO2003040281A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/835—Mixtures of non-ionic with cationic compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
    • C11D17/0017—Multi-phase liquid compositions
    • C11D17/0021—Aqueous microemulsions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/26—Organic compounds containing nitrogen
    • C11D3/33—Amino carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/38—Cationic compounds
    • C11D1/52—Carboxylic amides, alkylolamides or imides or their condensation products with alkylene oxides
    • C11D1/523—Carboxylic alkylolamides, or dialkylolamides, or hydroxycarboxylic amides (R1-CO-NR2R3), where R1, R2 or R3 contain one hydroxy group per alkyl group
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Definitions

  • the present invention pertains to an active and water-soluble natural detergent composite using lecithin and soybean fatty acid which is wholly vegetable, and a method of producing the same.
  • the conventional synthetic detergent generally has an amphiphilic molecular structure including a lipophilic molecular structure, mostly consisting of hydrocarbon-based fat molecules, and a hydrophilic molecular structure mostly consisting of sulphate, so the molecular size of the conventional synthetic detergent is bulky, due to characteristics of the above amphiphilic molecular structure. Therefore, the conventional synthetic detergent or its micelle does not move in water according to Brownian movement, that is to say, molecules of the conventional synthetic detergent or its micelle do not actively move for themselves without any assistance from external physical forces.
  • the conventional detergent is disadvantageous in that it is necessary to form foams, acting as a main factor of water pollution, in abundance, and to frequently contact the detergent molecules with the contaminants by physical action, for example, agitating, rubbing, and beating, so that the synthetic detergent molecules desirably penetrate contaminants attached to the subject. Furthermore, it is also necessary to agitate, rub, and beat the subject so as to detach the detergent molecules attached to the contaminants, and so as to smoothly disperse and diffuse the detergent molecules and contaminants detached from the subjective in water.
  • an object ofthe present invention is to provide a detergent, which easily removes contaminants attached to a surface of a person's skin and various organic and inorganic materials, and has multiple functions of penetration, moisturization, emulsification, dispersion, washing, and decomposition, and a method of producing the same.
  • the above object can be accomplished by providing an active and water-soluble natural detergent composite produced by a method comprising speedily agitating a mixture consisting of natural vegetable fatty acid such as natural soybean fatty acid and rice bran fatty acid, lecithin, alkanolamide, and an organic solvent such as higher alcohol and polyhydric alcohol, and saponifying the mixture while adding a predetermined activating component and additives to the mixture to form microscopic detergent particles moving according to Brownian movement.
  • the resulting detergent is controlled in terms of pH to be in a neutral or alkaline state, as desired.
  • the molecular structure constituting the vegetable fat is partially destructed, thus being converted into a water-soluble molecular structure.
  • the vegetable fat is mixed with an eggyolk
  • the vegetable fat is partially destructed in terms of its molecular structure to be converted into a water-soluble compound such as mayonnaise.
  • the molecular structure of the vegetable fatty acid is easily and partially destructed. The present invention is based on this theoretical background.
  • the detergent has a lipophilic hydrocarbon-based molecular structure, and the molecules or micelles of its molecule actively move according to Brownian movement without any physical action, thus being rapidly diffused, thus they irregularly and freely move in water.
  • the detergent of the present invention comes into contact with the contaminants, penetrates them and collides with the contaminants according to Brownian movement without physical action, and then detaches the contaminants from the subject by the kinetic energy and collision energy of the detergent molecules.
  • the water-soluble natural detergent composite of the present invention comprises 14 to 22 parts by weight of soybean fatty acid, 2 to 4 parts by weight of lecithin, 6 to 14 parts by weight of alkanolamide, 15 parts by weight of isooctylphenoxy polyoxyethoxy ethanol, 42 parts by weight of distilled water, 10 parts by weight of p-tert-oxyphenoxy polyethoxy ethanol, and 3 parts by weight of ethylene diamine tetracetic acid.
  • soybean fatty acid be used as a vegetable higher fatty acid extracted from natural plants.
  • other vegetable fatty acids such as rice bran fatty acid may be used instead of soybean fatty acid.
  • An active and water-soluble natural detergent composite according to the present invention was produced by following a method comprising the three steps: the first step of speedily agitating a mixture including 14 to 22 parts by weight of soybean fatty acid, 2 to 4 parts by weight of lecithin, 6 to 14 parts by weight of alkanolamide, 15 parts by weight of isooctylphenoxy polyoxyethoxy ethanol, 10 parts by weight of p-tert-oxyphenoxy polyethoxy ethanol, 3 parts by weight of ethylene diamine tetracetic acid acting as an auxiliary additive, and 42 parts by weight of distilled water; the second step of saponifying the mixture to form microscopic detergent molecules moving according to Brownian movement; and the third step of controlling the resulting detergent in terms of moisture and pH to allow the resulting detergent to be in a neutral or alkaline state, as desired.
  • the detergent of the present invention came into contact with the contaminants, penetrated them and collided with the contaminants according to Brownian movement without physical action, and then detached the contaminants from the subject by the kinetic energy and collision energy of the detergent molecules. Furthermore, the detergent of the present invention maintained its improved washability and biodegradability in hard water, soft water, and brine, and was environmentally friend because it did not contain hazardous compounds such as sulphate, phosphate, nitrate, and nitrilo triacetic acid.
  • an active and water-soluble natural detergent composite using soybean fatty acid and lecithin according to the present invention is advantageous in that it is not necessary to form foam in order to smoothly contact detergent molecules to contaminants, or to use various hazardous compounds as additives, unlike a conventional synthetic detergent, thus being environmentally friend and harmless to humans.
  • water-soluble natural detergent composite ofthe present invention has washability is caused by the Brownian movement of its molecules to reduce efforts required to wash and rinse a subject which is to be washed, so washing time, and consumption amount of electricity and water are reduced in the case of applying the detergent of the present invention to a washing machine or dishwasher.

Abstract

Disclosed is an active and water-soluble natural detergent composite using soybean fatty acid and lecithin, and a method of producing the same. The method comprises agitating a mixture consisting of a natural vegetable fatty acid, lecithin, alkanolamide, and an organic solvent such as higher alcohol or polyhydric alcohol, saponifying the mixture to form microscopic detergent particles moving according to Brownian movement, and controlling the resulting detergent in terms of moisture and pH to allow the resulting detergent to be in a neutral or alkaline state. The detergent composite comprises 14 to 22 parts by weight of soybean fatty acid, 2 to 4 parts by weight of lecithin, 6 to 14 parts by weight of alkanolamide, 15 parts by weight of isooctylphenoxy polyoxyethoxy ethanol, 42 parts by weight of distilled water, 10 parts by weight of p-tert-oxyphenoxy polyethoxy ethanol, and 3 parts by weight of ethylene diamine tetracetic acid.

Description

THE ACTIVE SOLUBLE CLEANING COMPOSITE OF NATURAL STATE USING SOYBEAN FATTY ACIDS AND THE MAKING METHOD
THEREOF
Technical Field
The present invention pertains to an active and water-soluble natural detergent composite using lecithin and soybean fatty acid which is wholly vegetable, and a method of producing the same.
Background Art
Mostly consisting of polypropylene benzene sulfonate-type hard compounds of propylene tetramer, conventional synthetic detergents cause environmental pollution and negatively affect humans, thus increasingly being restricted in their use.
Although a conventional linear benzene sulfonate-type soft synthetic detergent is suggested instead ofthe above hard-type synthetic detergent, the soft synthetic detergent has a drawback in that it emits harmful pollutants in water even though it has excellent degradability in water. Additionally, conventional sulphate and sulfonate detergents have disadvantages of requiring additives which emit submicron calcium carbonate, nitrilo triacetic acid, hexamethylene diamine tetracetic acid, and diethylene triamine pentacetic acid in water. Accordingly, there remains a need to develop an environmentally-friendly natural detergent replacing the above conventional detergents.
Furthermore, the conventional synthetic detergent generally has an amphiphilic molecular structure including a lipophilic molecular structure, mostly consisting of hydrocarbon-based fat molecules, and a hydrophilic molecular structure mostly consisting of sulphate, so the molecular size of the conventional synthetic detergent is bulky, due to characteristics of the above amphiphilic molecular structure. Therefore, the conventional synthetic detergent or its micelle does not move in water according to Brownian movement, that is to say, molecules of the conventional synthetic detergent or its micelle do not actively move for themselves without any assistance from external physical forces. Meanwhile, a washing process using conventional synthetic detergent is conducted while being based on a mechanism that lipophilic molecules of the synthetic detergent stick to contaminants or are penetrated into the contaminants, and then detached in conjunction with the contaminants from a subject which is to be washed. Accordingly, the conventional detergent is disadvantageous in that it is necessary to form foams, acting as a main factor of water pollution, in abundance, and to frequently contact the detergent molecules with the contaminants by physical action, for example, agitating, rubbing, and beating, so that the synthetic detergent molecules desirably penetrate contaminants attached to the subject. Furthermore, it is also necessary to agitate, rub, and beat the subject so as to detach the detergent molecules attached to the contaminants, and so as to smoothly disperse and diffuse the detergent molecules and contaminants detached from the subjective in water.
Other disadvantages of the conventional detergent are that it is difficult to satisfy a desired washability without physical actions such as agitating, rubbing, and beating provided by washers or humans, and water contaminating foam is formed and various compounds constituting such conventional detergents negatively affect environments and human bodies.
Disclosure ofthe Invention
Accordingly, the present invention has been made keeping in mind the above problems occurring in the prior art, and an object ofthe present invention is to provide a detergent, which easily removes contaminants attached to a surface of a person's skin and various organic and inorganic materials, and has multiple functions of penetration, moisturization, emulsification, dispersion, washing, and decomposition, and a method of producing the same.
Based on the present invention, the above object can be accomplished by providing an active and water-soluble natural detergent composite produced by a method comprising speedily agitating a mixture consisting of natural vegetable fatty acid such as natural soybean fatty acid and rice bran fatty acid, lecithin, alkanolamide, and an organic solvent such as higher alcohol and polyhydric alcohol, and saponifying the mixture while adding a predetermined activating component and additives to the mixture to form microscopic detergent particles moving according to Brownian movement. At this time, the resulting detergent is controlled in terms of pH to be in a neutral or alkaline state, as desired.
Generally, if lecithin is mixed with a vegetable fat, the molecular structure constituting the vegetable fat is partially destructed, thus being converted into a water-soluble molecular structure. For example, when the vegetable fat is mixed with an eggyolk, the vegetable fat is partially destructed in terms of its molecular structure to be converted into a water-soluble compound such as mayonnaise. In the case of using the vegetable fatty acid instead of the vegetable fat, the molecular structure of the vegetable fatty acid is easily and partially destructed. The present invention is based on this theoretical background.
According to the present invention, the detergent has a lipophilic hydrocarbon-based molecular structure, and the molecules or micelles of its molecule actively move according to Brownian movement without any physical action, thus being rapidly diffused, thus they irregularly and freely move in water. Hence, the detergent of the present invention comes into contact with the contaminants, penetrates them and collides with the contaminants according to Brownian movement without physical action, and then detaches the contaminants from the subject by the kinetic energy and collision energy of the detergent molecules. Best Mode for Carrying Out the Invention
There will be given a more detailed description of an active and water- soluble natural detergent composite using soybean fatty acid and lecithin, and a method of producing the same, below. The water-soluble natural detergent composite of the present invention comprises 14 to 22 parts by weight of soybean fatty acid, 2 to 4 parts by weight of lecithin, 6 to 14 parts by weight of alkanolamide, 15 parts by weight of isooctylphenoxy polyoxyethoxy ethanol, 42 parts by weight of distilled water, 10 parts by weight of p-tert-oxyphenoxy polyethoxy ethanol, and 3 parts by weight of ethylene diamine tetracetic acid.
For example, when a content of soybean fatty acid is more than 22 parts by weight, viscosity of the water-soluble detergent of the present invention is excessively increased, causing difficulty in spraying the detergent to the contaminants. On the other hand, when the content is less than 14 parts by weight, biodegradability of the detergent of the present invention is poor. Likewise, when alkanolamide is added to the detergent ofthe present invention in a content more than 14 parts by weight, the viscosity of the water-soluble detergent of the present invention is increased, causing difficulty in spraying the detergent to the contaminants, but when alkanolamide is added in the content less than 6 parts by weight, biodegradability of the detergent of the present invention is poor.
According to the present invention, it is preferable that soybean fatty acid be used as a vegetable higher fatty acid extracted from natural plants. Alternatively, other vegetable fatty acids such as rice bran fatty acid may be used instead of soybean fatty acid.
A better understanding of the present invention may be obtained in light ofthe following example which is set forth to illustrate, but is not to be construed to limit the present invention.
An active and water-soluble natural detergent composite according to the present invention was produced by following a method comprising the three steps: the first step of speedily agitating a mixture including 14 to 22 parts by weight of soybean fatty acid, 2 to 4 parts by weight of lecithin, 6 to 14 parts by weight of alkanolamide, 15 parts by weight of isooctylphenoxy polyoxyethoxy ethanol, 10 parts by weight of p-tert-oxyphenoxy polyethoxy ethanol, 3 parts by weight of ethylene diamine tetracetic acid acting as an auxiliary additive, and 42 parts by weight of distilled water; the second step of saponifying the mixture to form microscopic detergent molecules moving according to Brownian movement; and the third step of controlling the resulting detergent in terms of moisture and pH to allow the resulting detergent to be in a neutral or alkaline state, as desired.
Molecules of the resulting detergent or micelles of its molecule actively moved according to Brownian movement for themselves without any physical action, thus being rapidly diffused, thus they irregularly and freely moved in water. Therefore, the detergent of the present invention came into contact with the contaminants, penetrated them and collided with the contaminants according to Brownian movement without physical action, and then detached the contaminants from the subject by the kinetic energy and collision energy of the detergent molecules. Furthermore, the detergent of the present invention maintained its improved washability and biodegradability in hard water, soft water, and brine, and was environmentally friend because it did not contain hazardous compounds such as sulphate, phosphate, nitrate, and nitrilo triacetic acid.
A test for biodegradability of the active and water-soluble natural detergent composite according to the present invention was conducted by Korea Merchandise Testing and Research Institute (Test method: KS M2714-92), and the results are described in Table 1.
TABLE 1
Figure imgf000006_0001
Figure imgf000007_0001
From the results of Table 1, it can be seen that the biodegradability ofthe natural detergent composite of the present invention is 99 %. This value cannot be obtained from the conventional synthetic detergent.
Industrial Applicability
As described above, an active and water-soluble natural detergent composite using soybean fatty acid and lecithin according to the present invention is advantageous in that it is not necessary to form foam in order to smoothly contact detergent molecules to contaminants, or to use various hazardous compounds as additives, unlike a conventional synthetic detergent, thus being environmentally friend and harmless to humans.
Other advantages of the water-soluble natural detergent composite ofthe present invention are that its washability is caused by the Brownian movement of its molecules to reduce efforts required to wash and rinse a subject which is to be washed, so washing time, and consumption amount of electricity and water are reduced in the case of applying the detergent of the present invention to a washing machine or dishwasher.
The present invention has been described in an illustrative manner, and it is to be understood that the terminology used is intended to be in the nature of description rather than of limitation. Many modifications and variations of the present invention are possible in light of the above teachings. Therefore, it is to be understood that within the scope ofthe appended claims, the invention may be practiced otherwise than as specifically described.

Claims

Claims
1. The active soluble cleaning composite of natural state using soybean fatty acids , comprising 14 to 22 parts by weight of soybean fatty acid, 2 to 4 parts by weight of lecithin, 6 to 14 parts by weight of alkanolamide, 15 parts by weight of isooctylphenoxy polyoxyethoxy ethanol, 42 parts by weight of distilled water,
10 parts by weight of p-tert-oxyphenoxy polyethoxy ethanol, and 3 parts by weight of ethylene diamine tetracetic acid.
2. A method of making the active soluble cleaning composite of natural state using soybean fatty acids , comprising: sufficiently agitating a mixture including 14 to 22 parts by weight of soybean fatty acid, 2 to 4 parts by weight of lecithin, 6 to 14 parts by weight of alkanolamide, 15 parts by weight of isooctylphenoxy polyoxyethoxy ethanol, 42 parts by weight of distilled water, 10 parts by weight of p-tert-oxyphenoxy polyethoxy ethanol, and 3 parts by weight of ethylene diamine tetracetic acid; and saponifying the mixture to form microscopic detergent molecules moving according to Brownian movement.
PCT/KR2002/001990 2001-11-08 2002-10-25 The active soluble cleaning composite of natural state using soybean fatty acids and the making method thereof WO2003040281A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2003542320A JP4133823B2 (en) 2001-11-08 2002-10-25 Active water-soluble natural detergent composition using soybean fatty acid and lecithin and method for producing the same
AU2002353558A AU2002353558B2 (en) 2001-11-08 2002-10-25 The active soluble celaning composite of natural state using soybean fatty acids and the making method thereof
US10/494,190 US7247607B2 (en) 2001-11-08 2002-10-25 Active soluble cleaning composite of natural state using soybean fatty acids and the making method thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KRPCT/KR01/01899 2001-11-08
PCT/KR2001/001899 WO2003040280A1 (en) 2001-11-08 2001-11-08 Active natural cleaning material using soybean fatty acids and its manufacture

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PCT/KR2002/001990 WO2003040281A1 (en) 2001-11-08 2002-10-25 The active soluble cleaning composite of natural state using soybean fatty acids and the making method thereof

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CN (1) CN1226404C (en)
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2371399A1 (en) * 2010-06-11 2012-01-02 Universitat Politècnica De Catalunya Detergent for washing wool items. (Machine-translation by Google Translate, not legally binding)
WO2023287837A1 (en) * 2021-07-16 2023-01-19 Dow Global Technologies Llc Cleaning booster
WO2023287836A1 (en) * 2021-07-16 2023-01-19 Dow Global Technologies Llc Liquid laundry detergent formulation

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105154248A (en) * 2015-10-19 2015-12-16 湖北穆兰同大科技有限公司 Wood floor cleaner and preparation method thereof

Citations (5)

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Publication number Priority date Publication date Assignee Title
US4297251A (en) * 1977-05-02 1981-10-27 The Procter & Gamble Company Process for removing hard-to-remove soils from hardware
JPH0196112A (en) * 1987-10-07 1989-04-14 Taiyo Kagaku Co Ltd Production of shampoo composition
JPH05927A (en) * 1991-06-19 1993-01-08 Shiseido Co Ltd Hair cleaner
US5415787A (en) * 1994-09-20 1995-05-16 Citra Science Ltd. Leather cleaner and conditioner
JPH0812995A (en) * 1994-04-29 1996-01-16 Lion Corp Food detergent composition

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JPH0739380B2 (en) * 1986-10-14 1995-05-01 ライオン株式会社 Method for producing fatty acid alkanolamide
JP2829887B2 (en) * 1990-11-05 1998-12-02 株式会社楽 Detergent composition
KR960014358B1 (en) * 1992-08-31 1996-10-15 주식회사 엘지화학 Liquid detergent composition

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4297251A (en) * 1977-05-02 1981-10-27 The Procter & Gamble Company Process for removing hard-to-remove soils from hardware
JPH0196112A (en) * 1987-10-07 1989-04-14 Taiyo Kagaku Co Ltd Production of shampoo composition
JPH05927A (en) * 1991-06-19 1993-01-08 Shiseido Co Ltd Hair cleaner
JPH0812995A (en) * 1994-04-29 1996-01-16 Lion Corp Food detergent composition
US5415787A (en) * 1994-09-20 1995-05-16 Citra Science Ltd. Leather cleaner and conditioner

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2371399A1 (en) * 2010-06-11 2012-01-02 Universitat Politècnica De Catalunya Detergent for washing wool items. (Machine-translation by Google Translate, not legally binding)
WO2023287837A1 (en) * 2021-07-16 2023-01-19 Dow Global Technologies Llc Cleaning booster
WO2023287836A1 (en) * 2021-07-16 2023-01-19 Dow Global Technologies Llc Liquid laundry detergent formulation

Also Published As

Publication number Publication date
WO2003040280A1 (en) 2003-05-15
CN1483073A (en) 2004-03-17
CN1226404C (en) 2005-11-09
JP2005508443A (en) 2005-03-31
AU2002353558B2 (en) 2007-01-11
JP4133823B2 (en) 2008-08-13

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