WO2002070857A1 - Improved mud motor - Google Patents

Improved mud motor Download PDF

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Publication number
WO2002070857A1
WO2002070857A1 PCT/US2002/006191 US0206191W WO02070857A1 WO 2002070857 A1 WO2002070857 A1 WO 2002070857A1 US 0206191 W US0206191 W US 0206191W WO 02070857 A1 WO02070857 A1 WO 02070857A1
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WO
WIPO (PCT)
Prior art keywords
drilling motor
alloy
stator
drilling
rotor
Prior art date
Application number
PCT/US2002/006191
Other languages
French (fr)
Other versions
WO2002070857B1 (en
Inventor
Robert D. Bertin
William D. Nielsen, Jr.
Dlane M. Ryan
Original Assignee
Brush Wellman Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Brush Wellman Inc. filed Critical Brush Wellman Inc.
Publication of WO2002070857A1 publication Critical patent/WO2002070857A1/en
Publication of WO2002070857B1 publication Critical patent/WO2002070857B1/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/02Alloys based on copper with tin as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/03Alloys based on nickel or cobalt based on nickel
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C21/00Alloys based on aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/06Alloys based on copper with nickel or cobalt as the next major constituent
    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21BEARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B47/00Survey of boreholes or wells
    • E21B47/02Determining slope or direction
    • E21B47/022Determining slope or direction of the borehole, e.g. using geomagnetism
    • E21B47/0228Determining slope or direction of the borehole, e.g. using geomagnetism using electromagnetic energy or detectors therefor
    • EFIXED CONSTRUCTIONS
    • E21EARTH DRILLING; MINING
    • E21BEARTH DRILLING, e.g. DEEP DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B7/00Special methods or apparatus for drilling
    • E21B7/04Directional drilling
    • E21B7/06Deflecting the direction of boreholes
    • E21B7/068Deflecting the direction of boreholes drilled by a down-hole drilling motor
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S415/00Rotary kinetic fluid motors or pumps
    • Y10S415/901Drilled well-type pump

Definitions

  • a fluid-powered drilling motor or "mud motor” In drilling oil wells and other subterranean bore holes, the motive power to drive the drill bit on the tip of the drill string is normally provided by a fluid-powered drilling motor or "mud motor.”
  • Conventional drilling motors are composed of two principle components, a stator housing or “stator” and a rotating screw or impeller (hereinafter “rotor") located inside the stator.
  • a fluid, typically drilling mud in the case of oil wells is pumped down the inside of the drill string at high pressure where it passes through the drilling motor between the stator and rotor to the outside the drill string.
  • the rotor and stator are structured such that movement of fluid between them imparts a rotary motion to the rotor, this rotary motion being transferred to the drill bit for drilling the bore hole. See, for example, US 3,878,903; US 4,484,753; US 5,195,754 and US 5,956,995, the disclosures of which are incorporated herein by reference.
  • a guidance system which senses the location of the drill bit and other parameters.
  • Such systems typically include a sensor positioned in the drill string at or near the drill bit and a receiver located at the surface for receiving signals transmitted by the sensor. Based on the sensed location, various actions can be taken to direct, or redirect, the direction of the drill bit so that the bore hole produced achieves the desired location. This is especially important in directional well drilling where the path of the bore hole is changed at some preselected depth from vertically downward to laterally outward. See US 5,467,832 and US 5,448,227, the disclosures of which are also incorporated herein by reference.
  • the present invention is based on the discovery that greater accuracy can be achieved in sensing the underground location of drill bits and/or drilling motors during drilling of a subterranean bore hole if the drilling motor is made from non-magnetic components which . are substantially iron- free.
  • the inability of current guidance systems to sense the location of underground drill bits with high accuracy is due at least in part to magnetic interference caused by the drilling motor or its components.
  • non-magnetic alloys are typically used for making the rotors and stators of many drilling motors, over time these alloys can develop localized areas or regions of significant magnetism.
  • the drilling motor is formed from alloys which are not only non-magnetic but also substantially iron-free as well. As a result, the tendency of the drilling motor to develop areas of magnetism over use is largely eliminated.
  • the present invention provides an improved drilling motor for use in drilling subterranean bore holes in which the significant components of the drilling motor are formed from alloys which are not only non-magnetic but also contain less than 0.1 weight percent iron.
  • the drilling motor is made from components such that the drilling motor, as a whole, contains less than 0.1 weight percent iron, based on the entire weight of the drilling motor.
  • Stator 12 is composed of a hollow metallic cylinder whose inside cylindrical walls are lined with a polymer insert 14.
  • Rotor 16 is composed of an elongated cylindrical shaft 18, the outer cylindrical surface of which is provided with a helical thread or rib 20 for sealing engagement with polymer insert 14.
  • the distal end 22 of cylindrical shaft 18 is provided with means (not shown) for attaching rotor 16 to a drill bit.
  • Conventional drilling motors of this type are normally made from iron-based alloys, some of which may be non-magnetic (i.e. having a magnetic permeability of less than 1.01. These alloys, however, even if non-magnetic, still develop regions of significant magnetism over time. This magnetism is enough to interfere with the signals transmitted by the downhole sensor in the guidance system, thereby reducing the accuracy of the sensed location of the drill bit and other variables.
  • this problem is overcome by forming the significant components of the motor, or at least some of them, from non-magnetic alloys which contain 0.10 wt.% iron or less, preferably 0.05 wt.% iron or less, more preferably 0.01 wt.% iron or less.
  • alloys which contain no more than trace amounts of iron, i.e. no more than 0.005 wt.% iron. Such alloys should also have a magnetic permeability of less than 1.01, preferably less than 1.005, more preferably less than 1.001.
  • significant component is meant any component of the drilling motor representing at least 10 percent of the mass (i.e. weight) of the drilling motor as a whole.
  • the Figure schematically shows only two significant components in the inventive drilling motor, the rotor and the stator, real drilling motors are typically made from many different components assembled together. Accordingly, in actual practice, the rotor and/or stator of a drilling motor could be made from multiple rather than a single component.
  • all significant components of the drilling motor that is all metallic components constituting at least 10 wt.% of the total drilling motor mass, be made from non-magnetic alloys which contain 0.10 wt.% iron or less, preferably 0.05 wt.% iron or less, more preferably 0.01 wt.% iron or less, even more preferably 0.005 wt.% iron or less.
  • the drilling motor is made from materials such that the drilling motor, as a whole, contains 0.10 wt.% iron or less, preferably 0.05 wt.% iron or less, more preferably 0.01 wt.% iron or less, even more preferably 0.005 wt.% iron or less.
  • Forming a drilling motor to have a total iron content of less than 0.10 wt.% in accordance with the present invention can be done in a variety of different ways.
  • all of the metallic components of the drilling motor can be made from alloys having an iron content less that 0.10 wt.%.
  • the metallic components of the drilling motor can be formed from different alloys some containing more than 0.10 wt.% iron others containing less, with the amounts of these different alloys being selected such that the total amount of iron in the drilling motor as a whole is less than 0.10 wt. %.
  • the alloys selected for making the rotor, stator and other significant components of the inventive drilling motor such as the bearings into which the rotor and the driving shafts of the drill bit are mounted, in addition to being nonmagnetic and containing no more than 0.1 wt.% iron, also have a 0.2% yield strength of at least 100 ksi, preferably at least 110 ksi, and an electrical conductivity of at least 6 %IACS, preferably at least 8 %IACS.
  • such alloys further have a corrosion cracking resistance in boiling MgCl of greater than 1000 hours, preferably greater than 10,000 hours, as measured by the relative degree of the absence of alloy cracking observed after exposure to boiling MgCl over extended time versus the same alloy not so exposed, a wear resistance not more than 100 x 10e "9 cu. in., preferably not more than 50 x lOe "9 cu. in., as measured by the volume of material worn away from the alloy after prolonged sliding contact with another metal, and a modulus of elasticity of not more than 20,000 ksi, preferably not more than 18,000 ksi.
  • Especially preferred alloys are also non-sparking, anti-galling, machineable, plateable and cavitation erosion resistant.
  • non-sparking is meant that no sparks are created by striking the alloy against steel or other metal.
  • anti-galling is meant that the threshold stress above which stress galling may occur, when a force is applied by another metal such as steel to the alloy surface in a direction normal to the alloy surface, is greater than 75 ksi.
  • machineable is meant that the alloy has a machinablilty rating of 35 compared to the standard rating given for free cutting brass of 100.
  • plateable is meant that the alloys is significantly easier to electroplate with chromium than iron metal in terms of the energy taken for the plating operation and/or the quality of the plating layer obtained.
  • cavitation resistant is meant that the alloy exhibits less than 0.5% weight loss after 500 minutes exposure to a cavitation fluid flow environment.
  • One especially useful type of alloy is composed of at least about 90 wt.% of a base metal comprising copper, nickel or aluminum plus up to about 10 wt.% beryllium, preferably up to about 5 wt.% Be, more preferably up to about 3 wt.% Be.
  • the addition of as little as 0.05 wt.% Be to these base metals produces dramatic enhancements in a number of properties including strength, oxidation resistance, castability, workability, electrical conductivity and thermal conductivity making them ideally suited for making the some or all of the metallic components of the inventive drilling motor. Be additions on the order of at least 0.1 wt.%, more typically 0.2 wt.% are more typical.
  • alloys may contain additional elements such as Co, Si, Sn, W, Zn, Zr, Ti and others usually in amounts not exceeding 2 wt.%, preferably not exceeding 1 wt.%, per element.
  • each of these base metal alloys can contain another of these base metals as an additional ingredient.
  • the Be-Cu alloy can contain Ni or Al as an additional ingredient, again in an amount usually not exceeding 2 wt.%, preferably not exceeding 1 wt.% per element.
  • alloys are described, generally, in Harkness et al., Beryllium-Copper and Other Beryllium-Containing Alloys, Metals Handbook. Vol. 2, 10th Edition, ⁇ 1993 ASM International, the disclosure of which is incorporated by reference herein.
  • a preferred class of this type of alloy is the 81000 series and the 82000 series of high copper alloys as designated by the Copper Development Association, Inc. of New York, New York.
  • Another preferred class of these alloys are the lean, high conductivity, relation resistant BeNiCu alloys described in US Patent No. 6,001,196, the disclosure of which is also incorporated herein by reference.
  • These later alloys contain 0.15 to 0.5 wt.% Be, 0.4 to 1.25 wt.% Ni and/or Co, 0 to 0.25 wt.% Sn and 0.06 to 1.0 wt.% Zr and/or Ti.
  • Another preferred alloys can be described as containing more than 1.5 wt.% Be, with the balance being composed mainly of copper and other elements.
  • Cu-Ni-Sn spinodal alloys Another type of alloy that is especially useful in making the inventive drilling motors is the Cu-Ni-Sn spinodal alloys. These alloys, which contain about 8 to 16 wt.% Ni and 5 to 8 wt.% Sn, spinodally decompose upon final age hardening to provide alloys which are both strong and ductile as well as exhibiting good electrical conductivity, corrosion resistance in Cl " , and cavitation erosion resistant. In addition, they are machineable, grindable, plateable and exhibit good non-sparking and anti-galling characteristics. These alloys are described in US Application SN 08/552,582, filed November 3, 1995, the disclosure of which is also incorporated by reference.
  • alloys of this type include those whose nominal compositions are 15Ni-8Sn-Cu (15 wt.% Ni, 8 wt.% Sn, balance Cu) and 9Ni-6Sn-Cu, which are commonly known as Alloys C72700, C72900 and C96900 under the designation scheme of the Copper Development Association.
  • these alloys may also contain additional elements for enhancing various properties in accordance with known technology as well as incidental impurities. Examples of additional elements are B, Zr, Ti, P, Si and Nb.
  • Iron may also be used, but if so the iron content should be maintained less than 0.1 wt.%, preferably less than 0.05 wt.%, more preferably less than 0.005 wt.%, in accordance with the present invention.
  • the rotor, stator, bearings and/or other significant components of the inventive drilling motor in accordance with the present invention can be made from alloys which are either in the wrought or the unwrought forms. As well understood in metallurgy, most commercially-available alloys can be characterized as either cast or wrought. See, for example, the APPLICATION DATA SHEET, Standard Designation for Wrought and Cast Copper and Copper Alloys, Revision 1999, published by the Copper Development Association.
  • Wrought alloys are those in which the alloy, after being cast in molten form into a solid article (a "casting” or an “ingot") are subjected to significant, uniform, mechanical working (deformation without cutting), typically on the order of 40 % or more in terms of area reduction, before being sold.
  • Working may have a significant effect on the crystal structure of an as-cast alloy, and accordingly working is done so as to achieve significant and substantially uniform deformation of the as-cast alloy throughout its entire mass.
  • Cast products on the other hand, are those alloys which are not worked significantly before being sold. In other words, they are unwrought.
  • Alloys useful for making shaped articles are sold commercially in bulk in a variety of different forms including rods, bars, strips, large castings and the like. Transforming these bulk products into discrete, shaped products in final form usually requires subdividing the bulk alloy into sections and then shaping the sections into final form. Shaping often includes some type of cutting operation for removing part of the section and may also include a mechanical deformation step such as bending for imparting a curved or other non-uniform, non-rectilinear or non-orthogonal shape to the section. In some instances, the part fabricator may also work the alloy, before or after sectioning and/or before or after final solution anneal, to affect its crystal structure throughout its bulk.
  • the drilling motor or at least some of its significant components, such as the bearings are made from alloys in unwrought form.
  • unwrought form is meant that the alloy forming the component has not been subjected to significant wrought processing anytime during its history. In other words at no time has the alloy forming the part, starting from when it solidified into an as cast ingot and ending when it was transformed into the finished component, been subjected to a wrought processing step for effecting mechanical deformation of the alloy uniformly throughout its bulk by an amount greater than 10% in terms of area ratio.
  • Shaping by mechanical deformation may also affect the crystal structure of the alloy, but this effect typically does not occur uniformly throughout the alloy's bulk, at least where the shaping is done to impart a curved or other non-uniform, non-rectilinear or non- orthogonal shape to the article. Therefore, a component that has been mechanically deformed for imparting a curved or other non-uniform, non-rectilinear or non-orthogonal shape thereto may still be "unwrought in form" even though localized areas of the part have been deformed by more than 10%.
  • the drilling motor or at least some of its significant components are made from alloys which have been wrought processed.
  • alloys have been subjected to significant uniform mechanical deformation at some time during manufacture of the final component so that the alloy forming the component exhibits enhanced bulk properties compared with an alloy of identical composition not having been so deformed.
  • Such wrought processing may occur before or after final solution annealing.
  • alloys which are age hardenable i.e. alloys whose properties can be further enhanced by modest heat treatment after final solution annealing such as the Cu-Ni-Sn spinodal alloys mentioned above, wrought processing can occur before or after age hardening.
  • the drilling motor or at least some of its significant components are made from the above-mentioned Cu-Ni-Sn spinodal alloys which are made by the technology described in ' the above-noted US Application SN 08/552,582, filed November 3, 1995.
  • the alloys In order to effect good spinodal decomposition of such alloys, it is necessary that the alloys have a relatively fine, uniform grain structure when subjected to age hardening. In prior technology, this enhanced grain structure was achieved by significant mechanical deformation (wrought processing) of the as cast ingot prior to age hardening.
  • wrought processing inherently limits the size and complexity of the products which can be produced due to practical constraints on the size and expense of the wrought processing equipment. In the
  • molten alloy is introduced into the continuous casting die in a manner such that turbulence is created in zone where the liquid alloy solidifies into solid (referred to hereinafter as "turbocasting").
  • Turbocasting a relatively fine, uniform grain structure is achieved in the as cast ingot without wrought processing, thereby making a separate wrought processing step prior to age hardening unnecessary.
  • final products with fully developed spinodal properties can be achieved in bigger sizes and/or more complex shapes, since constraints due to wrought processing before age hardening have been eliminated.
  • some or all of the significant parts of the inventive drilling motor are made with this technology.
  • these components are made from an alloy which has been derived from a turbocast ingot that has not been wrought processed prior to age hardening and which contains sufficient Cu, Ni and Sn so that the alloy will undergo significant spinodal decomposition on age hardening.
  • a turbocast ingot that has not been wrought processed prior to age hardening and which contains sufficient Cu, Ni and Sn so that the alloy will undergo significant spinodal decomposition on age hardening.
  • rotors for the inventive mud motors can be advantageously made by turbocasting in the manner described above, then annealing, hot working, annealing again and then age hardening.
  • Stators can be advantageously made by the same approach, optionally including a cold working step after hot working and before age hardening.
  • the inventive drilling motors are especially adapted for use in drilling subterranean bore holes.
  • the rotors of these drilling motors will typically range in size from as little as 0.5 inch to as large as 10 inches or even larger.
  • Rotors with diameters of at least 1, at least 2, at least 3 and at least 4 inches are contemplated.
  • These motors are therefore entirely different from small scale motors, such as dentists' drill, whose rotors are typically less than 0.25 inch in diameter and which develop less than 1 horsepower of power.

Abstract

An improved mud motor for drilling bore holes in subterranean formations is formed from a non-magnetic alloy containing no more than 0.1 wt. % iron.

Description

IMPROVED MUD MOTOR
BACKGROUND
Field of the Invention The present invention relates to fluid-powered drilling motors useful for drilling oil wells and other subterranean bore holes Background of the Invention
In drilling oil wells and other subterranean bore holes, the motive power to drive the drill bit on the tip of the drill string is normally provided by a fluid-powered drilling motor or "mud motor." Conventional drilling motors are composed of two principle components, a stator housing or "stator" and a rotating screw or impeller (hereinafter "rotor") located inside the stator. A fluid, typically drilling mud in the case of oil wells is pumped down the inside of the drill string at high pressure where it passes through the drilling motor between the stator and rotor to the outside the drill string. The rotor and stator are structured such that movement of fluid between them imparts a rotary motion to the rotor, this rotary motion being transferred to the drill bit for drilling the bore hole. See, for example, US 3,878,903; US 4,484,753; US 5,195,754 and US 5,956,995, the disclosures of which are incorporated herein by reference.
In order to direct the path of the bore hole, modern drilling equipment often includes a guidance system which senses the location of the drill bit and other parameters. Such systems typically include a sensor positioned in the drill string at or near the drill bit and a receiver located at the surface for receiving signals transmitted by the sensor. Based on the sensed location, various actions can be taken to direct, or redirect, the direction of the drill bit so that the bore hole produced achieves the desired location. This is especially important in directional well drilling where the path of the bore hole is changed at some preselected depth from vertically downward to laterally outward. See US 5,467,832 and US 5,448,227, the disclosures of which are also incorporated herein by reference.
Although the location of bore hole pathways can be controlled with reasonable accuracy using current technology, greater accuracy is still desired.
Accordingly, it is an object of the present invention to provide improved drilling equipment which allows the pathways of bore holes produced in subterranean formations to be controlled more accurately than currently possible.
SUMMARY OF THE INVENTION
This and other objects are accomplished by the present invention which is based on the discovery that greater accuracy can be achieved in sensing the underground location of drill bits and/or drilling motors during drilling of a subterranean bore hole if the drilling motor is made from non-magnetic components which . are substantially iron- free. In particular, it has been determined in accordance with the present invention that the inability of current guidance systems to sense the location of underground drill bits with high accuracy is due at least in part to magnetic interference caused by the drilling motor or its components. Although non-magnetic alloys are typically used for making the rotors and stators of many drilling motors, over time these alloys can develop localized areas or regions of significant magnetism. These areas of magnetism, in turn, interfere with the signals transmitted by the sensor of the guidance systems to indicate drill bit location. In accordance with the present invention, therefore, the drilling motor is formed from alloys which are not only non-magnetic but also substantially iron-free as well. As a result, the tendency of the drilling motor to develop areas of magnetism over use is largely eliminated.
Thus, the present invention provides an improved drilling motor for use in drilling subterranean bore holes in which the significant components of the drilling motor are formed from alloys which are not only non-magnetic but also contain less than 0.1 weight percent iron. Preferably, the drilling motor is made from components such that the drilling motor, as a whole, contains less than 0.1 weight percent iron, based on the entire weight of the drilling motor.
BRIEF DESCRIPTION OF THE DRAWINGS The present invention may be more easily understood by reference to the drawing which is a schematic sectional view of the stator and rotor of a drilling motor made in accordance with the present invention.
DETAILED DESCRIPTION The stator and rotor of a drilling motor made in accordance with the present invention are schematically illustrated in the Figure. Stator 12 is composed of a hollow metallic cylinder whose inside cylindrical walls are lined with a polymer insert 14. Rotor 16 is composed of an elongated cylindrical shaft 18, the outer cylindrical surface of which is provided with a helical thread or rib 20 for sealing engagement with polymer insert 14. The distal end 22 of cylindrical shaft 18 is provided with means (not shown) for attaching rotor 16 to a drill bit. When a drilling fluid is charged between rotor 16 and polymer insert 16, rotor 16 rotates inside stator 12 in response to the force imparted on helical rib 20 by the drilling fluid impinging on this member. This rotation, in turn, powers drilling of the bore hole by the drill bit attached to the rotor.
Conventional drilling motors of this type are normally made from iron-based alloys, some of which may be non-magnetic (i.e. having a magnetic permeability of less than 1.01. These alloys, however, even if non-magnetic, still develop regions of significant magnetism over time. This magnetism is enough to interfere with the signals transmitted by the downhole sensor in the guidance system, thereby reducing the accuracy of the sensed location of the drill bit and other variables. In accordance with the present invention, this problem is overcome by forming the significant components of the motor, or at least some of them, from non-magnetic alloys which contain 0.10 wt.% iron or less, preferably 0.05 wt.% iron or less, more preferably 0.01 wt.% iron or less. Especially preferred are alloys which contain no more than trace amounts of iron, i.e. no more than 0.005 wt.% iron. Such alloys should also have a magnetic permeability of less than 1.01, preferably less than 1.005, more preferably less than 1.001. By "significant component" is meant any component of the drilling motor representing at least 10 percent of the mass (i.e. weight) of the drilling motor as a whole.
In this connection, although the Figure schematically shows only two significant components in the inventive drilling motor, the rotor and the stator, real drilling motors are typically made from many different components assembled together. Accordingly, in actual practice, the rotor and/or stator of a drilling motor could be made from multiple rather than a single component. In accordance with the present invention, it is desirable that all significant components of the drilling motor, that is all metallic components constituting at least 10 wt.% of the total drilling motor mass, be made from non-magnetic alloys which contain 0.10 wt.% iron or less, preferably 0.05 wt.% iron or less, more preferably 0.01 wt.% iron or less, even more preferably 0.005 wt.% iron or less. Preferably, the drilling motor is made from materials such that the drilling motor, as a whole, contains 0.10 wt.% iron or less, preferably 0.05 wt.% iron or less, more preferably 0.01 wt.% iron or less, even more preferably 0.005 wt.% iron or less.
Forming a drilling motor to have a total iron content of less than 0.10 wt.% in accordance with the present invention can be done in a variety of different ways. For example, all of the metallic components of the drilling motor can be made from alloys having an iron content less that 0.10 wt.%. Alternatively, the metallic components of the drilling motor can be formed from different alloys some containing more than 0.10 wt.% iron others containing less, with the amounts of these different alloys being selected such that the total amount of iron in the drilling motor as a whole is less than 0.10 wt. %. In a preferred embodiment of the present invention, the alloys selected for making the rotor, stator and other significant components of the inventive drilling motor such as the bearings into which the rotor and the driving shafts of the drill bit are mounted, in addition to being nonmagnetic and containing no more than 0.1 wt.% iron, also have a 0.2% yield strength of at least 100 ksi, preferably at least 110 ksi, and an electrical conductivity of at least 6 %IACS, preferably at least 8 %IACS. More preferably, such alloys further have a corrosion cracking resistance in boiling MgCl of greater than 1000 hours, preferably greater than 10,000 hours, as measured by the relative degree of the absence of alloy cracking observed after exposure to boiling MgCl over extended time versus the same alloy not so exposed, a wear resistance not more than 100 x 10e"9 cu. in., preferably not more than 50 x lOe"9 cu. in., as measured by the volume of material worn away from the alloy after prolonged sliding contact with another metal, and a modulus of elasticity of not more than 20,000 ksi, preferably not more than 18,000 ksi.
Especially preferred alloys are also non-sparking, anti-galling, machineable, plateable and cavitation erosion resistant. By "non-sparking" is meant that no sparks are created by striking the alloy against steel or other metal. By "anti-galling" is meant that the threshold stress above which stress galling may occur, when a force is applied by another metal such as steel to the alloy surface in a direction normal to the alloy surface, is greater than 75 ksi. By machineable is meant that the alloy has a machinablilty rating of 35 compared to the standard rating given for free cutting brass of 100. By "plateable" is meant that the alloys is significantly easier to electroplate with chromium than iron metal in terms of the energy taken for the plating operation and/or the quality of the plating layer obtained. By "cavitation resistant" is meant that the alloy exhibits less than 0.5% weight loss after 500 minutes exposure to a cavitation fluid flow environment.
Many different commercially available alloys can be used for making the inventive drilling motors. One especially useful type of alloy is composed of at least about 90 wt.% of a base metal comprising copper, nickel or aluminum plus up to about 10 wt.% beryllium, preferably up to about 5 wt.% Be, more preferably up to about 3 wt.% Be. The addition of as little as 0.05 wt.% Be to these base metals produces dramatic enhancements in a number of properties including strength, oxidation resistance, castability, workability, electrical conductivity and thermal conductivity making them ideally suited for making the some or all of the metallic components of the inventive drilling motor. Be additions on the order of at least 0.1 wt.%, more typically 0.2 wt.% are more typical.
These alloys may contain additional elements such as Co, Si, Sn, W, Zn, Zr, Ti and others usually in amounts not exceeding 2 wt.%, preferably not exceeding 1 wt.%, per element. In addition, each of these base metal alloys can contain another of these base metals as an additional ingredient. For example, the Be-Cu alloy can contain Ni or Al as an additional ingredient, again in an amount usually not exceeding 2 wt.%, preferably not exceeding 1 wt.% per element.
These alloys are described, generally, in Harkness et al., Beryllium-Copper and Other Beryllium-Containing Alloys, Metals Handbook. Vol. 2, 10th Edition, © 1993 ASM International, the disclosure of which is incorporated by reference herein. A preferred class of this type of alloy is the 81000 series and the 82000 series of high copper alloys as designated by the Copper Development Association, Inc. of New York, New York. Another preferred class of these alloys are the lean, high conductivity, relation resistant BeNiCu alloys described in US Patent No. 6,001,196, the disclosure of which is also incorporated herein by reference. These later alloys contain 0.15 to 0.5 wt.% Be, 0.4 to 1.25 wt.% Ni and/or Co, 0 to 0.25 wt.% Sn and 0.06 to 1.0 wt.% Zr and/or Ti. Another preferred alloys can be described as containing more than 1.5 wt.% Be, with the balance being composed mainly of copper and other elements.
Another type of alloy that is especially useful in making the inventive drilling motors is the Cu-Ni-Sn spinodal alloys. These alloys, which contain about 8 to 16 wt.% Ni and 5 to 8 wt.% Sn, spinodally decompose upon final age hardening to provide alloys which are both strong and ductile as well as exhibiting good electrical conductivity, corrosion resistance in Cl", and cavitation erosion resistant. In addition, they are machineable, grindable, plateable and exhibit good non-sparking and anti-galling characteristics. These alloys are described in US Application SN 08/552,582, filed November 3, 1995, the disclosure of which is also incorporated by reference. Especially preferred alloys of this type include those whose nominal compositions are 15Ni-8Sn-Cu (15 wt.% Ni, 8 wt.% Sn, balance Cu) and 9Ni-6Sn-Cu, which are commonly known as Alloys C72700, C72900 and C96900 under the designation scheme of the Copper Development Association. In addition to Ni and Sn, these alloys may also contain additional elements for enhancing various properties in accordance with known technology as well as incidental impurities. Examples of additional elements are B, Zr, Ti, P, Si and Nb. Iron may also be used, but if so the iron content should be maintained less than 0.1 wt.%, preferably less than 0.05 wt.%, more preferably less than 0.005 wt.%, in accordance with the present invention.
The rotor, stator, bearings and/or other significant components of the inventive drilling motor in accordance with the present invention can be made from alloys which are either in the wrought or the unwrought forms. As well understood in metallurgy, most commercially-available alloys can be characterized as either cast or wrought. See, for example, the APPLICATION DATA SHEET, Standard Designation for Wrought and Cast Copper and Copper Alloys, Revision 1999, published by the Copper Development Association. Wrought alloys are those in which the alloy, after being cast in molten form into a solid article (a "casting" or an "ingot") are subjected to significant, uniform, mechanical working (deformation without cutting), typically on the order of 40 % or more in terms of area reduction, before being sold. Working may have a significant effect on the crystal structure of an as-cast alloy, and accordingly working is done so as to achieve significant and substantially uniform deformation of the as-cast alloy throughout its entire mass. Cast products on the other hand, are those alloys which are not worked significantly before being sold. In other words, they are unwrought.
Alloys useful for making shaped articles are sold commercially in bulk in a variety of different forms including rods, bars, strips, large castings and the like. Transforming these bulk products into discrete, shaped products in final form usually requires subdividing the bulk alloy into sections and then shaping the sections into final form. Shaping often includes some type of cutting operation for removing part of the section and may also include a mechanical deformation step such as bending for imparting a curved or other non-uniform, non-rectilinear or non-orthogonal shape to the section. In some instances, the part fabricator may also work the alloy, before or after sectioning and/or before or after final solution anneal, to affect its crystal structure throughout its bulk.
In accordance with one embodiment of the invention, the drilling motor or at least some of its significant components, such as the bearings, are made from alloys in unwrought form. By "unwrought form" is meant that the alloy forming the component has not been subjected to significant wrought processing anytime during its history. In other words at no time has the alloy forming the part, starting from when it solidified into an as cast ingot and ending when it was transformed into the finished component, been subjected to a wrought processing step for effecting mechanical deformation of the alloy uniformly throughout its bulk by an amount greater than 10% in terms of area ratio. Shaping by mechanical deformation may also affect the crystal structure of the alloy, but this effect typically does not occur uniformly throughout the alloy's bulk, at least where the shaping is done to impart a curved or other non-uniform, non-rectilinear or non- orthogonal shape to the article. Therefore, a component that has been mechanically deformed for imparting a curved or other non-uniform, non-rectilinear or non-orthogonal shape thereto may still be "unwrought in form" even though localized areas of the part have been deformed by more than 10%. In accordance with another embodiment of the invention, the drilling motor or at least some of its significant components are made from alloys which have been wrought processed. These alloys have been subjected to significant uniform mechanical deformation at some time during manufacture of the final component so that the alloy forming the component exhibits enhanced bulk properties compared with an alloy of identical composition not having been so deformed. Such wrought processing may occur before or after final solution annealing. In those alloys which are age hardenable, i.e. alloys whose properties can be further enhanced by modest heat treatment after final solution annealing such as the Cu-Ni-Sn spinodal alloys mentioned above, wrought processing can occur before or after age hardening.
In an especially preferred embodiment of the invention, the drilling motor or at least some of its significant components are made from the above-mentioned Cu-Ni-Sn spinodal alloys which are made by the technology described in' the above-noted US Application SN 08/552,582, filed November 3, 1995. In order to effect good spinodal decomposition of such alloys, it is necessary that the alloys have a relatively fine, uniform grain structure when subjected to age hardening. In prior technology, this enhanced grain structure was achieved by significant mechanical deformation (wrought processing) of the as cast ingot prior to age hardening. However, wrought processing inherently limits the size and complexity of the products which can be produced due to practical constraints on the size and expense of the wrought processing equipment. In the
* technology of US SN 08/552,582, molten alloy is introduced into the continuous casting die in a manner such that turbulence is created in zone where the liquid alloy solidifies into solid (referred to hereinafter as "turbocasting"). As a result, a relatively fine, uniform grain structure is achieved in the as cast ingot without wrought processing, thereby making a separate wrought processing step prior to age hardening unnecessary. Accordingly, final products with fully developed spinodal properties can be achieved in bigger sizes and/or more complex shapes, since constraints due to wrought processing before age hardening have been eliminated. In an especially preferred embodiment of the invention, some or all of the significant parts of the inventive drilling motor are made with this technology. That is to say, these components are made from an alloy which has been derived from a turbocast ingot that has not been wrought processed prior to age hardening and which contains sufficient Cu, Ni and Sn so that the alloy will undergo significant spinodal decomposition on age hardening. With this approach, bigger and more complex parts from these spinodal alloys can be made more easily and inexpensively than possible with other techniques.
Finally, it is also possible in accordance with this aspect of the invention to subject the age hardened components made in this way to wrought processing, before and/or after age hardening, to further enhance their properties. For example, rotors for the inventive mud motors can be advantageously made by turbocasting in the manner described above, then annealing, hot working, annealing again and then age hardening. Stators can be advantageously made by the same approach, optionally including a cold working step after hot working and before age hardening.
The inventive drilling motors are especially adapted for use in drilling subterranean bore holes. To this end, the rotors of these drilling motors will typically range in size from as little as 0.5 inch to as large as 10 inches or even larger. Rotors with diameters of at least 1, at least 2, at least 3 and at least 4 inches are contemplated. These motors are therefore entirely different from small scale motors, such as dentists' drill, whose rotors are typically less than 0.25 inch in diameter and which develop less than 1 horsepower of power. Although only a few embodiments of the invention have been described above, many modifications can be made without departing from the spirit and scope of the invention. All such modifications are intended to be included within the scope of the present invention, which is to be limited only by the following claims:

Claims

We claim:
1. A fluid-powered drilling motor for drilling bore-holes in subterranean formations, wherein the iron content of the drilling motor, as a whole, is no more than 0.1 weight percent, based on the entire weight of the drilling motor.
2. The drilling motor of claim 1, wherein the total iron content of the drilling motor, as a whole, is no more than 0.05 weight percent.
3. The drilling motor of claim 1, wherein the drilling motor includes a rotor and a stator, at least one of the rotor and stator being formed from a non-magnetic alloy containing no more than 0.1 wt.% iron.
4. The drilling motor of claim 3, wherein both the rotor and the stator are made from non-magnetic alloys containing no more than 0.1 wt.% iron.
5. The drilling motor of claim 3, wherein the alloy has a 0.2% yield strength of at least 100 ksi and an electrical conductivity of at least 6 %IACS.
6. The drilling motor of claim 3, wherein the alloy is composed of at least about 90 wt.% of a base metal comprising copper, nickel or aluminum plus about 0.05 to about 10 wt.% beryllium.
7. The drilling motor of claim 6, wherein the alloy contains about 0.1 to about 5 wt.% Be.
8. The drilling motor of claim 3, wherein the alloy is a spinodal copper alloy containing about 5 to 16 wt.% Ni and about 5 to 10 wt.% Sn.
9. The drilling motor of claim 8, wherein the alloy is 15Ni-8Sn-Cu or 9Ni-6Sn-Cu.
10. The drilling motor claim 8, wherein the alloy has been derived from a turbocast ingot.
11. A fluid powered drilling motor including a rotor and a stator, at least one significant component of the drilling motor being formed from a non-magnetic metal alloy substantially free of iron, wherein the iron content of the drilling motor, as a whole, is no more than 0.1 weight percent, based on the entire weight of the drilling motor.
12. The drilling motor claim 11, wherein the alloy is composed of at least about 90 wt.% of a base metal comprising copper, nickel or aluminum plus about 0.05 to about 10 wt.% beryllium.
13. The drilling motor of claim 12, wherein the alloy contains about 0.1 to about 5 wt.% Be.
14. The drilling motor of claim 11, wherein the alloy is a spinodal copper alloy containing about 5 to 16 wt.% Ni and 5 to 10 wt.% Sn.
15. The drilling motor of claim 14, wherein the alloy is 15Ni-8Sn-Cu or 9Ni-6Sn-Cu.
16. The drilling motor claim 14, wherein the alloy has been derived from a turbocast ingot.
17. The drilling motor of claim 11, wherein the stator is formed from an alloy composed of at least about 90 wt.% of a base metal comprising copper, nickel or aluminum plus about 0.05 to about 10 wt.% beryllium.
18. The drilling motor of claim 17, wherein the stator is formed from an alloy composed of at least about 90% Cu and about 0.1 to about 3 wt.% Be.
19. The drilling motor of claim 11, wherein the stator is formed from a spinodal copper alloy containing about 5 to 16 wt.% Ni and 5 to 10 wt.% Sn.
20. A stator for use in a fluid-powered drilling motor adapted for drilling subterranean bore holes, the stator being formed from a non-magnetic alloy containing no more than 0.1 wt.% iron.
21. The stator of claim 20, wherein the alloy is composed of at least about 90 wt.% of a base metal comprising copper, nickel or aluminum plus about 0.05 to about 10 wt.% beryllium.
22. The stator of claim 21, wherein the stator is formed from a spinodal copper alloy containing about 5 to 16 wt.% Ni and 5 to 10 wt.% Sn.
23. The stator of claim 22, wherein the alloy has been derived from a turbocast ingot.
24. A rotor for use in a fluid-powered drilling motor adapted for drilling subterranean bore holes, the rotor being formed from a non-magnetic alloy containing no more than 0.1 wt.% iron.
25. The rotor of claim 24, wherein the alloy is composed of at least about 90 wt.% of a base metal comprising copper, nickel or aluminum plus about 0.05 to about 10 wt.% beryllium.
26. The rotor of claim 25, wherein the rotor is formed from a spinodal copper alloy containing about 5 to 16 wt.% Ni and 5 to 10 wt.% Sn.
27. The rotor of claim 24, wherein the alloy has been derived from a turbocast ingot.
PCT/US2002/006191 2001-03-01 2002-03-01 Improved mud motor WO2002070857A1 (en)

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Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7096712B2 (en) * 2003-04-21 2006-08-29 Conocophillips Company Material testing system for turbines
US7168510B2 (en) * 2004-10-27 2007-01-30 Schlumberger Technology Corporation Electrical transmission apparatus through rotating tubular members
CN1325678C (en) * 2005-03-15 2007-07-11 王胜军 Composite metal materials without magnetism and process for making same
US20070011873A1 (en) * 2005-07-14 2007-01-18 Teale David W Methods for producing even wall down-hole power sections
US8960329B2 (en) * 2008-07-11 2015-02-24 Schlumberger Technology Corporation Steerable piloted drill bit, drill system, and method of drilling curved boreholes
US8469104B2 (en) 2009-09-09 2013-06-25 Schlumberger Technology Corporation Valves, bottom hole assemblies, and method of selectively actuating a motor
US8777598B2 (en) 2009-11-13 2014-07-15 Schlumberger Technology Corporation Stators for downwhole motors, methods for fabricating the same, and downhole motors incorporating the same
US20110116961A1 (en) * 2009-11-13 2011-05-19 Hossein Akbari Stators for downhole motors, methods for fabricating the same, and downhole motors incorporating the same
US9347266B2 (en) 2009-11-13 2016-05-24 Schlumberger Technology Corporation Stator inserts, methods of fabricating the same, and downhole motors incorporating the same
US20110226219A1 (en) * 2010-03-17 2011-09-22 Caterpillar Inc. Fuel lubricated pump and common rail fuel system using same
US9309884B2 (en) 2010-11-29 2016-04-12 Schlumberger Technology Corporation Downhole motor or pump components, method of fabrication the same, and downhole motors incorporating the same
ES2697748T3 (en) * 2013-03-15 2019-01-28 Materion Corp Procedure to produce a uniform grain size in a hot worked spinodal alloy
EP2989223B1 (en) * 2013-04-23 2019-08-14 Materion Corporation Method for producing copper-nickel-tin alloy with high toughness
US10087758B2 (en) 2013-06-05 2018-10-02 Rotoliptic Technologies Incorporated Rotary machine
US9631157B2 (en) * 2013-10-18 2017-04-25 Weatherford Technology Holdings, Llc Cu—Ni—Sn alloy overlay for bearing surfaces on oilfield equipment
KR102394420B1 (en) * 2014-03-24 2022-05-06 마테리온 코포레이션 Drilling component
US10844671B2 (en) 2014-03-24 2020-11-24 Materion Corporation Low friction and high wear resistant sucker rod string
JP6651464B2 (en) 2014-06-05 2020-02-19 マテリオン コーポレイション Coupling for rod
US10844670B2 (en) 2014-06-05 2020-11-24 Materion Corporation Couplings for well pumping components
US10358913B2 (en) * 2014-12-22 2019-07-23 Schlumberger Technology Corporation Motor MWD device and methods
EP3850189A4 (en) 2018-09-11 2022-06-15 Rotoliptic Technologies Incorporated Sealing in helical trochoidal rotary machines
RU200806U1 (en) * 2019-07-09 2020-11-12 Общество с ограниченной ответственностью "Инновационные Буровые Технологии" (ООО "ИнБурТех") Device for drilling directional and horizontal wells
US11815094B2 (en) 2020-03-10 2023-11-14 Rotoliptic Technologies Incorporated Fixed-eccentricity helical trochoidal rotary machines
US11802558B2 (en) 2020-12-30 2023-10-31 Rotoliptic Technologies Incorporated Axial load in helical trochoidal rotary machines

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2005889A (en) * 1932-11-12 1935-06-25 Westinghouse Electric & Mfg Co Automatic drilling system for rotary drilling equipment
US4852666A (en) * 1988-04-07 1989-08-01 Brunet Charles G Apparatus for and a method of drilling offset wells for producing hydrocarbons
EP0366567A2 (en) * 1988-10-28 1990-05-02 Magrange Inc. Downhole combination tool
US5368109A (en) * 1993-11-04 1994-11-29 Slim Dril International Inc. Apparatus for arcuate drilling
EP0841407A1 (en) * 1996-10-28 1998-05-13 BRUSH WELLMAN Inc. Copper-nickel-beryllium alloy
US20020007879A1 (en) * 1995-06-07 2002-01-24 Wiliam D. Nielsen Jr. Unwrought continuous cast copper-nickel-tin spinodal alloy

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3112801A (en) * 1959-03-05 1963-12-03 Clark Wallace Well drilling apparatus
US3878903A (en) 1973-12-04 1975-04-22 Martin Dee Cherrington Apparatus and process for drilling underground arcuate paths
US3982859A (en) * 1975-07-11 1976-09-28 Smith International Corporation, Inc. Floating flow restrictors for fluid motors
US4484753A (en) 1983-01-31 1984-11-27 Nl Industries, Inc. Rotary shaft seal
US4842516A (en) * 1988-02-10 1989-06-27 Choisser George P Disposable hand tool for health care procedures
US4915552A (en) * 1988-10-07 1990-04-10 Hillestad Tollief O Portable power tool for milling tube ends
US5195754A (en) 1991-05-20 1993-03-23 Kalsi Engineering, Inc. Laterally translating seal carrier for a drilling mud motor sealed bearing assembly
NO306522B1 (en) 1992-01-21 1999-11-15 Anadrill Int Sa Procedure for acoustic transmission of measurement signals when measuring during drilling
US5337840A (en) * 1993-01-06 1994-08-16 International Drilling Systems, Inc. Improved mud motor system incorporating fluid bearings
US5956995A (en) 1997-09-18 1999-09-28 Pegasus Drilling Technologies, L.L.C. Lubricant level detection system for sealed mud motor bearing assembly

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2005889A (en) * 1932-11-12 1935-06-25 Westinghouse Electric & Mfg Co Automatic drilling system for rotary drilling equipment
US4852666A (en) * 1988-04-07 1989-08-01 Brunet Charles G Apparatus for and a method of drilling offset wells for producing hydrocarbons
EP0366567A2 (en) * 1988-10-28 1990-05-02 Magrange Inc. Downhole combination tool
US5368109A (en) * 1993-11-04 1994-11-29 Slim Dril International Inc. Apparatus for arcuate drilling
US20020007879A1 (en) * 1995-06-07 2002-01-24 Wiliam D. Nielsen Jr. Unwrought continuous cast copper-nickel-tin spinodal alloy
EP0841407A1 (en) * 1996-10-28 1998-05-13 BRUSH WELLMAN Inc. Copper-nickel-beryllium alloy

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
HARNESS J C ET AL: "BERYLLIUM-COPPER AND OTHER BERYLLIUM-CONTAINING ALLOYS", PROPERTIES AND SELECTION: NONFERROUS ALLOYS AND SPECIAL PURPOSE MATERIALS, METALS HANDBOOK, METALS PARK, ASM, US, vol. 2, 1990, pages 403 - 423, XP002045188 *

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