WO2002064532A3 - A process for preparing a branched olefin, a method of using the branched olefin for making a surfactant, and a surfactant - Google Patents

A process for preparing a branched olefin, a method of using the branched olefin for making a surfactant, and a surfactant Download PDF

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Publication number
WO2002064532A3
WO2002064532A3 PCT/EP2002/001700 EP0201700W WO02064532A3 WO 2002064532 A3 WO2002064532 A3 WO 2002064532A3 EP 0201700 W EP0201700 W EP 0201700W WO 02064532 A3 WO02064532 A3 WO 02064532A3
Authority
WO
WIPO (PCT)
Prior art keywords
surfactant
branched
branched olefin
olefins
making
Prior art date
Application number
PCT/EP2002/001700
Other languages
French (fr)
Other versions
WO2002064532A2 (en
Inventor
Paul Marie Ayoub
Laurent Alain Fenouil
Brendan Dermot Murray
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to CA002438351A priority Critical patent/CA2438351A1/en
Priority to DE60224645T priority patent/DE60224645T2/en
Priority to JP2002564469A priority patent/JP2004529096A/en
Priority to AU2002231807A priority patent/AU2002231807B2/en
Priority to MXPA03007165A priority patent/MXPA03007165A/en
Priority to DZ023492A priority patent/DZ3492A1/en
Application filed by Shell Int Research filed Critical Shell Int Research
Priority to NZ526983A priority patent/NZ526983A/en
Priority to EP02711873A priority patent/EP1360161B1/en
Priority to BR0207129-0A priority patent/BR0207129A/en
Publication of WO2002064532A2 publication Critical patent/WO2002064532A2/en
Publication of WO2002064532A3 publication Critical patent/WO2002064532A3/en
Priority to HK04100549A priority patent/HK1058784A1/en

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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3335—Catalytic processes with metals
    • C07C5/3337—Catalytic processes with metals of the platinum group
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/16—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxo-reaction combined with reduction
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C303/00—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides
    • C07C303/24—Preparation of esters or amides of sulfuric acids; Preparation of sulfonic acids or of their esters, halides, anhydrides or amides of esters of sulfuric acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C9/00—Aliphatic saturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/143—Sulfonic acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron

Abstract

A process for preparing branched olefins which process comprises dehydrogenating an isoparaffinic composition comprising 0.5 % or less quaternary aliphatic carbon atoms over a suitable catalyst, which isoparaffinic composition comprises paraffins having a carbon number in the range of from 7 to 35, of which paraffins at least a portion of the molecules is branched, the average number of branches per paraffin molecule being from 0.7 to 2.5 and the branching comprising methyl and optionally ethyl branches, and which isoparaffinic composition may be obtained by hydrocracking and hydroisomerisation of a paraffinic wax, said branched olefins having a quaternary carbon content of 0.5 % or less; a process of using olefins for making an anionic surfactant, a nonionic surfactant or a cationic surfactant, in particular a surfactant sulphate or sulphonate, comprising converting the branched olefins into the surfactant, and an anionic surfactant, a nonionic surfactant or a cationinc surfactant which is obtainable by said process.
PCT/EP2002/001700 2001-02-15 2002-02-15 A process for preparing a branched olefin, a method of using the branched olefin for making a surfactant, and a surfactant WO2002064532A2 (en)

Priority Applications (10)

Application Number Priority Date Filing Date Title
DE60224645T DE60224645T2 (en) 2001-02-15 2002-02-15 PROCESS FOR PREPARING A BRANCHED OLEFINE, METHOD FOR USE OF THE OLEFINE FOR THE PRODUCTION OF A TENANT, AND SURFACTANT
JP2002564469A JP2004529096A (en) 2001-02-15 2002-02-15 Process for preparing branched olefins, use of the branched olefins for surfactant production, and surfactants
AU2002231807A AU2002231807B2 (en) 2001-02-15 2002-02-15 A process for preparing a branched olefin, a method of using the branched olefin for making a surfactant, and a surfactant
MXPA03007165A MXPA03007165A (en) 2001-02-15 2002-02-15 A process for preparing a branched olefin, a method of using the branched olefin for making a surfactant, and a surfactant.
DZ023492A DZ3492A1 (en) 2001-02-15 2002-02-15 PROCESS FOR THE PREPARATION OF A BRANCHED OLEFIN, PROCESS FOR THE USE OF THE BRANCHED OLEFIN FOR THE MANUFACTURE OF A SURFACTANT, AND SURFACTANT
CA002438351A CA2438351A1 (en) 2001-02-15 2002-02-15 A process for preparing a branched olefin, a method of using the branched olefin for making a surfactant, and a surfactant
NZ526983A NZ526983A (en) 2001-02-15 2002-02-15 A process for preparing a branched olefin, a method of using the branched olefin for making a surfactant, and a surfactant
EP02711873A EP1360161B1 (en) 2001-02-15 2002-02-15 A process for preparing a branched olefin, a method of using the branched olefin for making a surfactant, and a surfactant
BR0207129-0A BR0207129A (en) 2001-02-15 2002-02-15 Processes for the preparation of branched olefins, and alcohol sulfates, and for the use of olefins for the preparation of a surfactant, branched olefin and branched alcohol surfactant compositions, and isoparaffin composition
HK04100549A HK1058784A1 (en) 2001-02-15 2004-01-27 A process for preparing a branched olefin a methodof using the branched olefin for making a surfact ant and a surfactant

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US26987401P 2001-02-15 2001-02-15
US60/269,874 2001-02-15

Publications (2)

Publication Number Publication Date
WO2002064532A2 WO2002064532A2 (en) 2002-08-22
WO2002064532A3 true WO2002064532A3 (en) 2003-01-03

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PCT/EP2002/001700 WO2002064532A2 (en) 2001-02-15 2002-02-15 A process for preparing a branched olefin, a method of using the branched olefin for making a surfactant, and a surfactant

Country Status (18)

Country Link
US (2) US6765106B2 (en)
EP (2) EP1360161B1 (en)
JP (3) JP2004529096A (en)
CN (2) CN100384794C (en)
AT (2) ATE465141T1 (en)
AU (2) AU2002231807B2 (en)
BR (2) BR0207129A (en)
CA (2) CA2573297A1 (en)
DE (2) DE60224645T2 (en)
DZ (1) DZ3492A1 (en)
ES (1) ES2299559T3 (en)
HK (1) HK1058784A1 (en)
MX (1) MXPA03007165A (en)
NZ (2) NZ534608A (en)
RU (2) RU2296737C2 (en)
TW (1) TW593215B (en)
WO (1) WO2002064532A2 (en)
ZA (1) ZA200305647B (en)

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ES2299559T3 (en) 2008-06-01
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JP2007119487A (en) 2007-05-17
NZ534608A (en) 2005-07-29
BR0207129A (en) 2004-03-30
HK1058784A1 (en) 2004-06-04
US20020183567A1 (en) 2002-12-05
AU2002231807B2 (en) 2007-03-29
JP4990609B2 (en) 2012-08-01
US6765106B2 (en) 2004-07-20
RU2006142134A (en) 2008-06-10
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US20040133037A1 (en) 2004-07-08
RU2296737C2 (en) 2007-04-10
CA2438351A1 (en) 2002-08-22
EP1767512A3 (en) 2007-07-18
EP1360161A2 (en) 2003-11-12
DE60236116D1 (en) 2010-06-02
EP1767512A2 (en) 2007-03-28
ATE384031T1 (en) 2008-02-15
CN101024596A (en) 2007-08-29
NZ526983A (en) 2005-04-29
EP1360161B1 (en) 2008-01-16
CA2573297A1 (en) 2002-08-22
DZ3492A1 (en) 2002-08-22
TW593215B (en) 2004-06-21
WO2002064532A2 (en) 2002-08-22
CN1531516A (en) 2004-09-22
DE60224645T2 (en) 2009-01-15
RU2003127726A (en) 2005-03-20
AU2007200150A1 (en) 2007-02-01
JP2004529096A (en) 2004-09-24
DE60224645D1 (en) 2008-03-06
EP1767512B1 (en) 2010-04-21
ATE465141T1 (en) 2010-05-15
BR0216028A (en) 2007-09-04

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