WO2002024758A3 - Emulsion polymerization methods involving lightly modified clay and compositions comprising same - Google Patents

Emulsion polymerization methods involving lightly modified clay and compositions comprising same Download PDF

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Publication number
WO2002024758A3
WO2002024758A3 PCT/US2001/028991 US0128991W WO0224758A3 WO 2002024758 A3 WO2002024758 A3 WO 2002024758A3 US 0128991 W US0128991 W US 0128991W WO 0224758 A3 WO0224758 A3 WO 0224758A3
Authority
WO
WIPO (PCT)
Prior art keywords
disclosed
emulsion polymerization
compositions
same
lightly
Prior art date
Application number
PCT/US2001/028991
Other languages
French (fr)
Other versions
WO2002024758A2 (en
Inventor
Dennis Paul Lorah
Robert Victor Slone
Original Assignee
Rohm & Haas
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rohm & Haas filed Critical Rohm & Haas
Priority to JP2002529166A priority Critical patent/JP4030428B2/en
Priority to AU2001291026A priority patent/AU2001291026B2/en
Priority to KR1020037003962A priority patent/KR100867391B1/en
Priority to EP01971096A priority patent/EP1325038A2/en
Priority to BR0114001-9A priority patent/BR0114001A/en
Publication of WO2002024758A2 publication Critical patent/WO2002024758A2/en
Publication of WO2002024758A3 publication Critical patent/WO2002024758A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82B—NANOSTRUCTURES FORMED BY MANIPULATION OF INDIVIDUAL ATOMS, MOLECULES, OR LIMITED COLLECTIONS OF ATOMS OR MOLECULES AS DISCRETE UNITS; MANUFACTURE OR TREATMENT THEREOF
    • B82B3/00—Manufacture or treatment of nanostructures by manipulation of individual atoms or molecules, or limited collections of atoms or molecules as discrete units
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
    • C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
    • C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F292/00—Macromolecular compounds obtained by polymerising monomers on to inorganic materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/04—Ingredients treated with organic substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K9/00—Use of pretreated ingredients
    • C08K9/08—Ingredients agglomerated by treatment with a binding agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives

Abstract

Processes for utilizing various emulsion polymerization procedures for preparing aqueous nanocomposite dispersions are disclosed. The disclosed processes include both in-situ polymerization in the presence of at least partially exfoliated, lightly modified clays as well as admixtures of polymer dispersion with at least partially exfoliated, lightly modifies clay dispersions. The disclosed nanocomposite dispersions are useful for preparing a variety of materials, such as coatings, adhesives, caulks, sealants, plastics additives, and thermoplastic resins. Processes for preparing polymer nanocomposite powders and use of these powders as plastic resin and plastics additives are also disclosed.
PCT/US2001/028991 2000-09-21 2001-09-17 Emulsion polymerization methods involving lightly modified clay and compositions comprising same WO2002024758A2 (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
JP2002529166A JP4030428B2 (en) 2000-09-21 2001-09-17 Emulsion polymerization process involving lightly modified clay and composition comprising the same
AU2001291026A AU2001291026B2 (en) 2000-09-21 2001-09-17 Emulsion polymerization methods involving lightly modified clay and compositions comprising same
KR1020037003962A KR100867391B1 (en) 2000-09-21 2001-09-17 Aqueous nanocomposite dispersions: processes, compositions, and uses thereof
EP01971096A EP1325038A2 (en) 2000-09-21 2001-09-17 Emulsion polymerization methods involving lightly modified clay and compositions comprising same
BR0114001-9A BR0114001A (en) 2000-09-21 2001-09-17 Process for preparing a polymeric aqueous nanocomposite clay dispersion, aqueous nanocomposite dispersion, coating, plastic additive, thermoplastic resin, dry cement powder modifier, core and shell polymeric nanocomposite composition, impact modifier, coating product, adhesive, caulking or sealant, and method for preparing a plurality of hollow polymeric nanocomposite particles

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US23426300P 2000-09-21 2000-09-21
US60/234,263 2000-09-21

Publications (2)

Publication Number Publication Date
WO2002024758A2 WO2002024758A2 (en) 2002-03-28
WO2002024758A3 true WO2002024758A3 (en) 2002-06-06

Family

ID=22880628

Family Applications (4)

Application Number Title Priority Date Filing Date
PCT/US2001/028994 WO2002024760A2 (en) 2000-09-21 2001-09-17 Aqueous nanocomposite dispersions: processes, compositions, and uses thereof
PCT/US2001/028991 WO2002024758A2 (en) 2000-09-21 2001-09-17 Emulsion polymerization methods involving lightly modified clay and compositions comprising same
PCT/US2001/028990 WO2002024757A2 (en) 2000-09-21 2001-09-17 High acid aqueous nanocomposite dispersions
PCT/US2001/028993 WO2002055563A2 (en) 2000-09-21 2001-09-17 Methods and compositions involving polar monomers and multivalent cations

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/US2001/028994 WO2002024760A2 (en) 2000-09-21 2001-09-17 Aqueous nanocomposite dispersions: processes, compositions, and uses thereof

Family Applications After (2)

Application Number Title Priority Date Filing Date
PCT/US2001/028990 WO2002024757A2 (en) 2000-09-21 2001-09-17 High acid aqueous nanocomposite dispersions
PCT/US2001/028993 WO2002055563A2 (en) 2000-09-21 2001-09-17 Methods and compositions involving polar monomers and multivalent cations

Country Status (10)

Country Link
US (7) US6759463B2 (en)
EP (4) EP1325038A2 (en)
JP (5) JP3986959B2 (en)
KR (5) KR100818967B1 (en)
CN (5) CN1331893C (en)
AU (3) AU2001291026B2 (en)
BR (4) BR0113995A (en)
DE (1) DE60124940T2 (en)
TW (3) TW587083B (en)
WO (4) WO2002024760A2 (en)

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