WO2002012400A3 - Thermally stable, anthraquinone colorants containing copolymerizable vinyl groups - Google Patents

Thermally stable, anthraquinone colorants containing copolymerizable vinyl groups Download PDF

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Publication number
WO2002012400A3
WO2002012400A3 PCT/US2001/020347 US0120347W WO0212400A3 WO 2002012400 A3 WO2002012400 A3 WO 2002012400A3 US 0120347 W US0120347 W US 0120347W WO 0212400 A3 WO0212400 A3 WO 0212400A3
Authority
WO
WIPO (PCT)
Prior art keywords
compounds
vinyl groups
thermally stable
copolymerizable vinyl
containing copolymerizable
Prior art date
Application number
PCT/US2001/020347
Other languages
French (fr)
Other versions
WO2002012400A2 (en
Inventor
Michael John Cyr
Max Allen Weaver
Gerry Foust Rhodes
Jason Clay Pearson
Phillip Michael Cook
Original Assignee
Eastman Chem Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Chem Co filed Critical Eastman Chem Co
Priority to JP2002517694A priority Critical patent/JP2004506061A/en
Priority to EP01950510A priority patent/EP1307514A2/en
Publication of WO2002012400A2 publication Critical patent/WO2002012400A2/en
Publication of WO2002012400A3 publication Critical patent/WO2002012400A3/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F246/00—Copolymers in which the nature of only the monomers in minority is defined
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/006—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00
    • C08F283/008—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polymers provided for in C08G18/00 on to unsaturated polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/06—Polymers provided for in subclass C08G
    • C08F290/061—Polyesters; Polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/08—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated side groups
    • C08F290/14—Polymers provided for in subclass C08G
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/08—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated side groups
    • C08F290/14—Polymers provided for in subclass C08G
    • C08F290/141—Polyesters; Polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B69/00—Dyes not provided for by a single group of this subclass
    • C09B69/10—Polymeric dyes; Reaction products of dyes with monomers or with macromolecular compounds
    • C09B69/101—Polymeric dyes; Reaction products of dyes with monomers or with macromolecular compounds containing an anthracene dye
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00

Abstract

Disclosed are thermally-stable, anthraquinone colorant compounds (dyes) which contain one or more vinyl groups which render the compounds copolymerizable with reactive vinyl monomers to produce colored, polymeric compositions such as methacrylate polymeric materials. The compounds possess fastness (stability) to ultraviolet (UV) light, good solubility in vinyl monomers, good color strength and excellent thermal stability. Also disclosed are acrylic polymeric materials, i.e., polymers derived from acrylic acid esters, methacrylic acid esters and/or other copolymerizable vinyl compounds, having copolymerized therein one or more of the anthraquinone colorant compounds.
PCT/US2001/020347 2000-08-07 2001-06-27 Thermally stable, anthraquinone colorants containing copolymerizable vinyl groups WO2002012400A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
JP2002517694A JP2004506061A (en) 2000-08-07 2001-06-27 Thermally stable anthraquinone colorant containing copolymerizable vinyl groups
EP01950510A EP1307514A2 (en) 2000-08-07 2001-06-27 Thermally stable, anthraquinone colorants containing copolymerizable vinyl groups

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US63354800A 2000-08-07 2000-08-07
US09/633,548 2000-08-07

Publications (2)

Publication Number Publication Date
WO2002012400A2 WO2002012400A2 (en) 2002-02-14
WO2002012400A3 true WO2002012400A3 (en) 2002-04-18

Family

ID=24540075

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2001/020347 WO2002012400A2 (en) 2000-08-07 2001-06-27 Thermally stable, anthraquinone colorants containing copolymerizable vinyl groups

Country Status (4)

Country Link
US (1) US6689828B2 (en)
EP (1) EP1307514A2 (en)
JP (1) JP2004506061A (en)
WO (1) WO2002012400A2 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7802883B2 (en) 2007-12-20 2010-09-28 Johnson & Johnson Vision Care, Inc. Cosmetic contact lenses having a sparkle effect
WO2011074501A1 (en) * 2009-12-17 2011-06-23 株式会社メニコン Anthraquinone pigment, ocular lens material using same, ocular lens material manufacturing method, and ocular lens
EP2744834B1 (en) 2011-08-24 2014-12-24 Lambson Limited Polymers comprising photoinitiator moieties and dye moieties
CN113088101B (en) * 2014-05-21 2023-07-04 罗利克技术有限公司 Polymerizable dichroic dyes
JP6614996B2 (en) * 2016-02-18 2019-12-04 株式会社トクヤマデンタル Method for producing polymerizable monomer

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1046751A (en) * 1963-01-26 1966-10-26 Asahi Chemical Ind A process for producing coloured polymers from polymerizable dyestuffs, and uses of such dyestuffs
US3364186A (en) * 1960-05-20 1968-01-16 Basf Ag Colored terpolymers prepared from (1) dyes, (2) monomers containing crosslinkable groups, and (3) ethylenic unsaturated monomers
EP0396376A1 (en) * 1989-05-02 1990-11-07 BAUSCH & LOMB INCORPORATED Polymerizable dye
WO1998023689A1 (en) * 1996-11-27 1998-06-04 Eastman Chemical Company 1,5(8)-bis(substituted-n-propylamino)-4,8(5)-bis(arylthio) anthraquinone compounds

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3288778A (en) * 1964-10-05 1966-11-29 Polaroid Corp Azo and anthraquinone dye developers
US3689501A (en) 1969-02-27 1972-09-05 Eastman Kodak Co Anthraquinone compounds containing a triazolylthio group
US4115056A (en) 1975-05-26 1978-09-19 Ciba-Geigy Ag Methods for dyeing or printing using amino-anthraquinone reactive disperse dyes
US4267306A (en) 1979-02-15 1981-05-12 Eastman Kodak Company Polyester polymers containing residues of anthroquinone dyes
US4359570A (en) 1980-05-08 1982-11-16 Eastman Kodak Company Colored polyester containing copolymerized dyes as colorants
US4403092A (en) 1982-11-22 1983-09-06 Eastman Kodak Company Polyesters containing copolymerized, anthraquinone colorant compounds containing sulfonamido groups
DE3631841A1 (en) 1986-09-19 1988-03-24 Basf Ag LIQUID CRYSTALINE COPOLYMER
MX169697B (en) 1987-12-28 1993-07-19 Ppg Industries Inc IMPROVEMENTS TO RADIATION-FRAGABLE COMPOSITIONS BASED ON UNSATURATED POLYESTERS AND COMPOUNDS HAVING AT LEAST TWO GROUPS OF VINYL ETER
US4804719A (en) 1988-02-05 1989-02-14 Eastman Kodak Company Water-dissipatable polyester and polyester-amides containing copolymerized colorants
US5367039A (en) 1988-07-06 1994-11-22 Nippon Paint Company, Ltd. Production of colored vinyl polymer particles by polymerizing a vinyl polymerizable monomer with a polymerizable dye
US5032670A (en) * 1989-08-30 1991-07-16 Eastman Kodak Company Copolymerized anthraquinone-polyester color concentrates
US4999418A (en) * 1989-08-31 1991-03-12 Eastman Kodak Company Polyesters colored with the residue of heat stable anthraquinone compounds
US5109097A (en) 1990-09-07 1992-04-28 Minnesota Mining And Manufacturing Company Radiation curable coating
US5194463B1 (en) 1991-09-27 1995-06-20 Eastman Kodak Co Light-absorbing polyurethane compositions and thermoplastic polymers colored therewith
US5578419A (en) 1991-12-12 1996-11-26 Mitsui Toatsu Chemicals, Incorporated Dyes for color filters, and photosensitive resist resin composition containing the same
US5362812A (en) 1993-04-23 1994-11-08 Minnesota Mining And Manufacturing Company Reactive polymeric dyes
US5372864A (en) 1993-09-03 1994-12-13 Eastman Chemical Company Toners for polyesters
GB9411586D0 (en) 1994-06-09 1994-08-03 Zeneca Ltd Coating process
WO1996001283A1 (en) 1994-07-05 1996-01-18 Ppg Industries, Inc. Polyester and vinyl ether radiation curable compositions with reactive diluent
US5900445A (en) 1994-12-20 1999-05-04 Bic Corporation Erasable ink composition containing a polymer dye obtained from ethylenic monomers and marking instrument containing same
SE506958C2 (en) 1996-06-20 1998-03-09 Mcwhorter Technologies Ab Photopolymerizable polyester composition and varnish or paint formulation
US5962557A (en) 1996-09-30 1999-10-05 Eastman Chemical Corporation Polyesters containing copolymerized substituted 1,4-bis(2,6-dialkylanilino)-9, 10-anthraquinones as colorants
JP2002516621A (en) 1996-11-27 2002-06-04 イーストマン ケミカル カンパニー Method for producing light-absorbing polymer composition

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3364186A (en) * 1960-05-20 1968-01-16 Basf Ag Colored terpolymers prepared from (1) dyes, (2) monomers containing crosslinkable groups, and (3) ethylenic unsaturated monomers
GB1046751A (en) * 1963-01-26 1966-10-26 Asahi Chemical Ind A process for producing coloured polymers from polymerizable dyestuffs, and uses of such dyestuffs
EP0396376A1 (en) * 1989-05-02 1990-11-07 BAUSCH & LOMB INCORPORATED Polymerizable dye
US5055602A (en) * 1989-05-02 1991-10-08 Bausch & Lomb Incorporated Polymerizable dye
WO1998023689A1 (en) * 1996-11-27 1998-06-04 Eastman Chemical Company 1,5(8)-bis(substituted-n-propylamino)-4,8(5)-bis(arylthio) anthraquinone compounds
US5955564A (en) * 1996-11-27 1999-09-21 Eastman Chemical Company 1,5(8)-bis (substituted-N-propylamino)-4,8(5)-bis(arylthio)anthraquinone compounds

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
ASQUITH R S ET AL: "SELF-COLOURED POLYMERS BASED ON ANTHRAQUINONE RESIDUES", JOURNAL OF THE SOCIETY OF DYERS AND COLOURISTS, SOCIETY OF DYERS AND COLOURISTS. BRADFORD, GB, vol. 93, no. 4, 1 April 1977 (1977-04-01), pages 114 - 125, XP002033756, ISSN: 0037-9859 *

Also Published As

Publication number Publication date
WO2002012400A2 (en) 2002-02-14
EP1307514A2 (en) 2003-05-07
US6689828B2 (en) 2004-02-10
US20020068725A1 (en) 2002-06-06
JP2004506061A (en) 2004-02-26

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