WO2001042310A3 - Wässrige primärdispersionen und beschichtungsstoffe, verfahren zu ihrer herstellung und ihre verwendung - Google Patents

Wässrige primärdispersionen und beschichtungsstoffe, verfahren zu ihrer herstellung und ihre verwendung Download PDF

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Publication number
WO2001042310A3
WO2001042310A3 PCT/EP2000/011006 EP0011006W WO0142310A3 WO 2001042310 A3 WO2001042310 A3 WO 2001042310A3 EP 0011006 W EP0011006 W EP 0011006W WO 0142310 A3 WO0142310 A3 WO 0142310A3
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WO
WIPO (PCT)
Prior art keywords
radicals
substituted
monomer
arylalkyl
stand
Prior art date
Application number
PCT/EP2000/011006
Other languages
English (en)
French (fr)
Other versions
WO2001042310A2 (de
WO2001042310A9 (de
Inventor
Maximilian Bendix
Reinhold Clauss
Ralf Nickolaus
Wolfgang Bremser
Original Assignee
Basf Coatings Ag
Maximilian Bendix
Reinhold Clauss
Ralf Nickolaus
Wolfgang Bremser
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basf Coatings Ag, Maximilian Bendix, Reinhold Clauss, Ralf Nickolaus, Wolfgang Bremser filed Critical Basf Coatings Ag
Priority to EP00984984A priority Critical patent/EP1301547B1/de
Priority to DE50007824T priority patent/DE50007824D1/de
Priority to CA002393524A priority patent/CA2393524A1/en
Priority to AU21560/01A priority patent/AU2156001A/en
Priority to JP2001543605A priority patent/JP2003526709A/ja
Priority to AT00984984T priority patent/ATE276286T1/de
Priority to BR0016312-0A priority patent/BR0016312A/pt
Priority to MXPA02005549A priority patent/MXPA02005549A/es
Priority to US10/148,428 priority patent/US6884839B1/en
Publication of WO2001042310A2 publication Critical patent/WO2001042310A2/de
Publication of WO2001042310A3 publication Critical patent/WO2001042310A3/de
Publication of WO2001042310A9 publication Critical patent/WO2001042310A9/de

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08Processes
    • C08G18/0838Manufacture of polymers in the presence of non-reactive compounds
    • C08G18/0842Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents
    • C08G18/0861Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers
    • C08G18/0866Manufacture of polymers in the presence of non-reactive compounds in the presence of liquid diluents in the presence of a dispersing phase for the polymers or a phase dispersed in the polymers the dispersing or dispersed phase being an aqueous medium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium
    • C08F2/22Emulsion polymerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/62Polymers of compounds having carbon-to-carbon double bonds
    • C08G18/6216Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
    • C08G18/622Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
    • C08G18/6225Polymers of esters of acrylic or methacrylic acid
    • C08G18/6229Polymers of hydroxy groups containing esters of acrylic or methacrylic acid with aliphatic polyalcohols
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/80Masked polyisocyanates
    • C08G18/8061Masked polyisocyanates masked with compounds having only one group containing active hydrogen
    • C08G18/807Masked polyisocyanates masked with compounds having only one group containing active hydrogen with nitrogen containing compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/14Methyl esters, e.g. methyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/20Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate

Abstract

Wässrige Primärdispersionen und Beschichtungsstoffe, enthaltend dispergierte und/oder emulgierte, feste und/oder flüssige Polymerpartikel und/oder dispergierte feste Kern-Schale-Partikel eines Teilchendurchmesser ≤ 500 nm, Herstellbar durch kontrollierte radikalische Mikro- oder Miniemulsionspolymerisation von (A) mindestens einem olefinisch ungesättigten Monomer und (B) mindestens einem von olefinisch ungesättigten Monomer (A) verschiedenen olefinisch ungesättigten Monomer der allgemeinen Formel (I): R?1R2C=CR3R4¿, worin die Reste R?1, R2, R3 und R4¿ jeweils unabhängig voneinander für Wasserstoffatome oder substituierte oder unsubstituierte Alkyl-, Cycloalkyl-, Alkylcycloalkyl-, Cycloalkylalkyl-, Aryl, Alkylaryl-, Cycloalkylaryl-Arylalkyl- oder Arylcycloalkylreste stehen, mit der Massgabe, dass mindestens zwei der Variablen R?1, R2, R3 und R4¿ für substituierte oder unsubstituierte Aryl-, Arylalkyl- oder Arylcycloalkylreste, insbesondere substituierte oder unsubstituierte Arylreste, stehen; in der Gegenwart von zumindest (C) mindestens einem hydrophoben Vernetzungsmittel für das aus den Ausgangsprodukten (A) und (B) resultierende Copolymerisat; sowie ihre Verwendung.
PCT/EP2000/011006 1999-12-11 2000-11-08 Wässrige primärdispersionen und beschichtungsstoffe, verfahren zu ihrer herstellung und ihre verwendung WO2001042310A2 (de)

Priority Applications (9)

Application Number Priority Date Filing Date Title
EP00984984A EP1301547B1 (de) 1999-12-11 2000-11-08 Wässrige primärdispersionen und beschichtungsstoffe, verfahren zu ihrer herstellung und ihre verwendung
DE50007824T DE50007824D1 (de) 1999-12-11 2000-11-08 Wässrige primärdispersionen und beschichtungsstoffe, verfahren zu ihrer herstellung und ihre verwendung
CA002393524A CA2393524A1 (en) 1999-12-11 2000-11-08 Aqueous primary dispersions and coating matters, a method for producing same and the use thereof
AU21560/01A AU2156001A (en) 1999-12-11 2000-11-08 Aqueous primary dispersions and coating matters, a method for producing same andthe use thereof
JP2001543605A JP2003526709A (ja) 1999-12-11 2000-11-08 水性一次分散液および被覆材料、その製造方法およびその使用
AT00984984T ATE276286T1 (de) 1999-12-11 2000-11-08 Wässrige primärdispersionen und beschichtungsstoffe, verfahren zu ihrer herstellung und ihre verwendung
BR0016312-0A BR0016312A (pt) 1999-12-11 2000-11-08 Dispersões primárias aquosas e substâncias de revestimento, processos para a sua preparação e sua aplicação
MXPA02005549A MXPA02005549A (es) 1999-12-11 2000-11-08 Dispersiones acuosas primarias y materias de revestimiento metodo para su produccion y uso.
US10/148,428 US6884839B1 (en) 1999-12-11 2000-11-08 Aqueous primary dispersions and coating matters, a method for producing same and the use thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19959923A DE19959923A1 (de) 1999-12-11 1999-12-11 Wäßrige Primärdispersionen und Beschichtungsstoffe, Verfahren zu ihrer Herstellung und ihre Verwendung
DE19959923.8 1999-12-11

Publications (3)

Publication Number Publication Date
WO2001042310A2 WO2001042310A2 (de) 2001-06-14
WO2001042310A3 true WO2001042310A3 (de) 2002-08-08
WO2001042310A9 WO2001042310A9 (de) 2002-11-28

Family

ID=7932386

Family Applications (1)

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PCT/EP2000/011006 WO2001042310A2 (de) 1999-12-11 2000-11-08 Wässrige primärdispersionen und beschichtungsstoffe, verfahren zu ihrer herstellung und ihre verwendung

Country Status (11)

Country Link
US (1) US6884839B1 (de)
EP (1) EP1301547B1 (de)
JP (1) JP2003526709A (de)
AT (1) ATE276286T1 (de)
AU (1) AU2156001A (de)
BR (1) BR0016312A (de)
CA (1) CA2393524A1 (de)
DE (2) DE19959923A1 (de)
ES (1) ES2226959T3 (de)
MX (1) MXPA02005549A (de)
WO (1) WO2001042310A2 (de)

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DE50007824D1 (de) 2004-10-21
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DE19959923A1 (de) 2001-06-28
EP1301547B1 (de) 2004-09-15
AU2156001A (en) 2001-06-18
US6884839B1 (en) 2005-04-26
ATE276286T1 (de) 2004-10-15
BR0016312A (pt) 2003-07-08
ES2226959T3 (es) 2005-04-01
JP2003526709A (ja) 2003-09-09
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MXPA02005549A (es) 2002-09-02
CA2393524A1 (en) 2001-06-14

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