WO2001036323A3 - Cobalt-based catalysts and process for producing synthesis gas - Google Patents

Cobalt-based catalysts and process for producing synthesis gas Download PDF

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Publication number
WO2001036323A3
WO2001036323A3 PCT/US2000/031451 US0031451W WO0136323A3 WO 2001036323 A3 WO2001036323 A3 WO 2001036323A3 US 0031451 W US0031451 W US 0031451W WO 0136323 A3 WO0136323 A3 WO 0136323A3
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WO
WIPO (PCT)
Prior art keywords
cobalt
conversion
hydrocarbon feedstock
synthesis gas
based catalysts
Prior art date
Application number
PCT/US2000/031451
Other languages
French (fr)
Other versions
WO2001036323A2 (en
Inventor
Anne M Gaffney
Roger Song
Robert Oswald
David Corbin
Original Assignee
Conoco Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Conoco Inc filed Critical Conoco Inc
Priority to EP00980414A priority Critical patent/EP1230146A2/en
Priority to AU17679/01A priority patent/AU1767901A/en
Priority to CA002392106A priority patent/CA2392106A1/en
Publication of WO2001036323A2 publication Critical patent/WO2001036323A2/en
Publication of WO2001036323A3 publication Critical patent/WO2001036323A3/en

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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/40—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts characterised by the catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/005—Spinels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8913—Cobalt and noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • C01B3/386—Catalytic partial combustion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/025—Processes for making hydrogen or synthesis gas containing a partial oxidation step
    • C01B2203/0261—Processes for making hydrogen or synthesis gas containing a partial oxidation step containing a catalytic partial oxidation step [CPO]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1023—Catalysts in the form of a monolith or honeycomb
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1005—Arrangement or shape of catalyst
    • C01B2203/1029—Catalysts in the form of a foam
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1082—Composition of support materials
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1094—Promotors or activators
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

A process is disclosed for the catalytic partial oxidation of light hydrocarbons such as methane. The process involves the conversion of a hydrocarbon feedstock by contacting a feed stream comprising the hydrocarbon feedstock and an oxygen-containing gas with a catalyst in a reaction zone maintained at conversion-promoting conditions in a millisecond contact time reactor effective to produce an effluent stream containing primarily carbon monoxide and hydrogen. Certain preferred catalysts of the invention comprise cobalt metal and/or cobalt containing compound(s), a promoter, and a refractory support are capable of efficiently producing syngas at high selectivities for CO and H2 products.
PCT/US2000/031451 1999-11-17 2000-11-15 Cobalt-based catalysts and process for producing synthesis gas WO2001036323A2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP00980414A EP1230146A2 (en) 1999-11-17 2000-11-15 Cobalt-based catalysts and process for producing synthesis gas
AU17679/01A AU1767901A (en) 1999-11-17 2000-11-15 Cobalt-based catalysts and process for producing synthesis gas
CA002392106A CA2392106A1 (en) 1999-11-17 2000-11-15 Cobalt-based catalysts and process for producing synthesis gas

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US16598199P 1999-11-17 1999-11-17
US60/165,981 1999-11-17
US71260700A 2000-11-14 2000-11-14
US09/712,607 2000-11-14

Publications (2)

Publication Number Publication Date
WO2001036323A2 WO2001036323A2 (en) 2001-05-25
WO2001036323A3 true WO2001036323A3 (en) 2002-02-14

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EP (1) EP1230146A2 (en)
AU (1) AU1767901A (en)
CA (1) CA2392106A1 (en)
WO (1) WO2001036323A2 (en)

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GB0214383D0 (en) 2002-06-21 2002-07-31 Isis Innovation Catalyst
US6958309B2 (en) 2002-08-01 2005-10-25 Conocophillips Company Hydrothermal pretreatment for increasing average pore size in a catalyst support
US7041621B2 (en) 2003-01-17 2006-05-09 Conocophillips Company Sulfided catalysts for improved performance in hydrocarbon processing
ATE510620T1 (en) 2003-12-18 2011-06-15 Chiyoda Corp CATALYST FOR PRODUCING SYNTHESIS GAS AND METHOD FOR PRODUCING SYNTHESIS GAS THEREFROM
RU2483799C2 (en) * 2010-12-24 2013-06-10 Российская Федерация, от имени которой выступает Министерство промышленности и торговли Российской Федерации (Минпромторг России) Method of producing catalyst of methane-bearing hydrocarbon steam conversion
US9598290B2 (en) 2011-06-23 2017-03-21 Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center Process for producing ammonia and urea
WO2012177136A1 (en) 2011-06-23 2012-12-27 Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center Process for producing a syngas intermediate suitable for the production of hydrogen
WO2013062413A1 (en) 2011-10-26 2013-05-02 Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center Method for producing synthesis gas for methanol production
US9102532B2 (en) 2011-10-26 2015-08-11 Stamicarbon B.V. Method for producing synthesis gas for methanol production
US9340494B2 (en) 2011-12-19 2016-05-17 Stamicarbon B.V. Acting Under The Name Of Mt Innovation Center Process for producing ammonia and urea
KR101437072B1 (en) * 2011-12-26 2014-09-03 한국화학연구원 Catalyst for efficient co2 conversion and method for preparing thereof
US9616414B2 (en) 2013-05-09 2017-04-11 Sabic Global Technologies B.V. Alkaline earth metal/metal oxide supported catalysts
US9499403B2 (en) 2013-07-10 2016-11-22 Saudi Arabian Oil Company Catalyst and process for thermo-neutral reforming of liquid hydrocarbons
CN105473224A (en) 2013-07-31 2016-04-06 沙特基础工业公司 Catalyst and process for the production of olefins from syngas
CN103464164B (en) * 2013-08-27 2015-11-18 中国华能集团清洁能源技术研究院有限公司 Tartaric acid complexometry prepares the method for methanation catalyst
CN103586028B (en) * 2013-10-25 2015-05-20 中国华能集团清洁能源技术研究院有限公司 Method for preparing methanation catalyst through glucose complexation process
RU2016140372A (en) * 2014-03-14 2018-04-16 Басф Се Yttrium CONTAINING CATALYST FOR HIGH CARBON DIOXIDE HYDROGENATION FOR COMBINED HIGH hydrogenation of carbon dioxide and reforming and / or reforming, as well as ways HIGH HYDROGENATION OF CARBON DIOXIDE, COMBINED HIGH HYDROGENATION OF CARBON DIOXIDE AND REFORMING AND / OR REFORMING
US10196348B2 (en) 2014-07-15 2019-02-05 Stamicarbon B.V. Method for revamping a urea production complex
PT3362405T (en) 2015-10-15 2022-11-17 Stamicarbon B V Acting Under The Name Of Mt Innovation Center Process for the production of methanol
US10046309B2 (en) 2016-06-28 2018-08-14 Yasin Khani Supported nanocatalyst for catalytic reforming reactions
CN109678551B (en) * 2019-01-21 2021-04-20 河北工业大学 Porous pyrochlore ceramic composite material and preparation method thereof
CN112675863B (en) * 2019-10-17 2023-04-28 中国石油化工股份有限公司 Catalyst for methane combustion and preparation method and application thereof
CN111185165B (en) * 2020-03-20 2022-09-20 北京工业大学 Preparation method and application of aluminum-magnesium-holmium composite oxide supported samarium-platinum catalyst prepared from hydrotalcite and carbon precursor
CN111889101B (en) * 2020-08-13 2021-10-12 清华大学 Modified composite oxide catalyst for synergistic purification of VOCs and NO and preparation method thereof
CN114984959A (en) * 2022-06-07 2022-09-02 福州大学 Catalyst for catalytic combustion of copper-cobalt spinel by using methane and preparation method thereof

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WO2001036323A2 (en) 2001-05-25
EP1230146A2 (en) 2002-08-14
CA2392106A1 (en) 2001-05-25
AU1767901A (en) 2001-05-30

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