WO2001030565A1 - Graphic transfer laminate - Google Patents

Graphic transfer laminate Download PDF

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Publication number
WO2001030565A1
WO2001030565A1 PCT/ZA2000/000204 ZA0000204W WO0130565A1 WO 2001030565 A1 WO2001030565 A1 WO 2001030565A1 ZA 0000204 W ZA0000204 W ZA 0000204W WO 0130565 A1 WO0130565 A1 WO 0130565A1
Authority
WO
WIPO (PCT)
Prior art keywords
layer
display
adhesive
carrier
layers
Prior art date
Application number
PCT/ZA2000/000204
Other languages
French (fr)
Inventor
Hugh Neville Glenister
Original Assignee
Hugh Neville Glenister
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hugh Neville Glenister filed Critical Hugh Neville Glenister
Priority to AU18221/01A priority Critical patent/AU1822101A/en
Publication of WO2001030565A1 publication Critical patent/WO2001030565A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B38/00Ancillary operations in connection with laminating processes
    • B32B38/0036Heat treatment
    • B32B38/004Heat treatment by physically contacting the layers, e.g. by the use of heated platens or rollers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/30Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/408Matt, dull surface
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2309/00Parameters for the laminating or treatment process; Apparatus details
    • B32B2309/02Temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2309/00Parameters for the laminating or treatment process; Apparatus details
    • B32B2309/12Pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2327/00Polyvinylhalogenides
    • B32B2327/06PVC, i.e. polyvinylchloride
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2367/00Polyesters, e.g. PET, i.e. polyethylene terephthalate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2451/00Decorative or ornamental articles

Definitions

  • This invention relates to laminates used for transferring graphics onto substrates such as fabrics.
  • graphics includes 2D designs, lettering for example.
  • the adhesive can be activated by heat, pressure, solvents or other suitable means.
  • a problem with one known method is that because the graphics are bonded to the fabric one by one (in the case of a design comprising more than one graphic, such as numbers), it is difficult to align the graphics properly. The method is also time-consuming.
  • a pigmented vinyl (e.g. PVC) graphic can be transferred onto a substrate (e.g. a garment) by making use of a layered material.
  • the material consists of an adhesive layer, a so-called display layer (which is the pigmented vinyl layer) and a carrier layer.
  • the display layer forms the centre of the laminate and is attached to the carrier layer either by adhesive or melt fusion of the carrier layer.
  • the method of applying the graphic to the substrate using the aforementioned material comprises the steps of first cutting the outlines of the graphic through the adhesive and display layers, but not through the carrier layer. The portions of the adhesive and display layers not forming part of the graphic are then peeled away from the carrier layer. This leaves only the graphic consisting of an adhesive and display layers laminated on the carrier layer.
  • the sheet is turned upside down, leaving the carrier layer on top and the adhesive layer at the bottom.
  • the sheet is laid down on the material and the adhesive is activated through the action of heat and pressure, causing the adhesive layer to bond with the material.
  • the carrier layer is removed from the display layer. This leaves the display layer bonded to the fabric by the action of the adhesive layer. This is the type of process described by Liebe in US Patent 3,660,212.
  • a problem with this method is the fact that for most of the commercially available laminates, the carrier and display are bonded to each other by the action of an adhesive layer.
  • the laminate then includes a first adhesive layer between the carrier and display layers) and a second adhesive layer (between the display layer and the material).
  • the first adhesive layer is selected to have lower adhesion than the second adhesive layer at the temperature of application to the material.
  • the carrier layer can therefor only be removed from the display layer whilst it is still hot. These are known as hot peel laminates.
  • the adhesive layer is also bonded to the display layer by adhering the adhesive layer to the newly cured display layer while it's temperature is still greater than the melting point of the adhesive layer. It also provides that pressure sensitive or solvent activated adhesives can be applied to the display layer instead of the thermally activated adhesives.
  • a process for the manufacturing of laminate for use in transferring a graphic onto a substrate and having a display layer and a carrier layer comprising the steps of laminating a display layer and a carrier layer of suitable synthetic resin materials by subjecting the layers under tension to sufficient heat and pressure to adhere the layers together at a temperature below the softening of either layer and thereafter applying a suitable adhesive to the unlaminated surface of the display layer.
  • the invention also provides for the tension, heat and pressure to be applied by passing the layers together over at least one hot roller.
  • the adhesive layer is further provided for the adhesive layer to be applied by spraying, casting or laminating. There is still further provided for the adhesive to be thermally activated or pressure sensitive or solvent activated or any combination of the above and having a bonding strength greater than that formed between the carrier and display layers.
  • the display layer is formed from PVC and for the carrier layer to be formed from polyester and for the temperature applied to the display and carrier layers during lamination to be between 110 C and 149 C.
  • a further feature of the invention provides for at least one of the surfaces of the carrier layer to be matted, and for the matting to be done by scouring the surface with a scouring means.
  • the scouring means prefferably be sandpaper or the like.
  • FIG. 1 is a diagrammatic representation of a process for producing a laminate used for transferring a graphic onto a substrate.
  • FIG. 2 is an enlarged view of laminate comprising a polyester carrier layer and PVC display layer.
  • FIG. 3 is an enlarged view of a laminate comprising a polyester carrier layer, PVC display layer and thermally activated adhesive layer.
  • a process of manufacturing a laminate is provided.
  • the laminate is for use in the transfer of a PVC graphic to the fabric of a garment.
  • Figure 1 shows a layout of the lamination process.
  • PVC film (1 ) and polyester film (2) are fed over a heated roller (3).
  • the two films are then passed over a siliconised cold roller (4).
  • the films (1 , 2) are kept at a constant tension by the use of feed rolls (not shown).
  • the effect of the heat of the hot roller (3) and pressure caused by the tension in the films is to cause the two films to adhere to each other at a temperature below the softening temperature of either the PVC or the polyester.
  • the product formed is a laminate (5) of which greater detail is shown in Figure 2.
  • the laminate consists of a carrier layer (20), which is the polyester film (2), and a display layer (21), which is the PVC film (1 ).
  • the bond (22) between the carrier layer (20) and display layer (21 ) is semi-permanent. This means that the display layer (21 ) will adhere to the carrier layer (20) with enough strength to permit handling of the laminate, but not so much that it does not permit removal of the carrier layer (20) from the display layer (21) by what is known as "cold peeling".
  • the force required for separating the carrier layer (20) and display layer (21) is about 1 N force at operative temperatures.
  • the laminate (5) is passed through a spraying station (6) where a hot melt adhesive (7) is sprayed on the display layer (21).
  • the adhesive (7) bonds with the display layer (21).
  • the melting point of the adhesive (7) is around 110 C and that of the display layer (21 ) is around 180 C.
  • the melting point of the carrier layer (20) is around 240 C.
  • the adhesive (7) is heated to its melting point before spraying it on the display layer (21).
  • the three layer laminate (8) is coiled into a roll (10) using a suitable upcoiler (11 ).
  • the process is run on a continuous basis by using an accumulator (9) between the spraying station (6) and upcoiler (11).
  • the three-layer laminate coil (10) is packed and is ready for use.
  • This use is effected generally in the conventional manner by placing the laminate on a surface with the adhesive (23) side facing upwards. Next the outlines of a graphic is cut through the adhesive (23) and display (21) layers, without cutting into the carrier layer (20). All of the adhesive (23) and display (21 ) layers falling outside the outlines of the cut graphic are then peeled away. This leaves only the cut graphic layer comprising the adhesive (23) and display (21 ) layers on the carrier (20) layer. The laminate is then turned around, which leaves the carrier layer (20) on top. The adhesive layer (23) is then bonded to the fabric (not shown) by heat applied to the carrier layer to cause the temperature of the adhesive layer (23) to rise above its softening point but not to above the softening point of the display layer (21). This causes the adhesive layer (23) to bond the display layer (21 ) and material (not shown) to each other.
  • the carrier layer (20) can be removed. It can be removed immediately, during the cooling down of the laminate or after the laminate has cooled down.
  • an adhesive layer (23) that is activated by a mechanism other than temperature, such as pressure, solvents etc.
  • polyester of which one surface has been matted for the carrier layer.
  • the polyester is matted by sanding it with sandpaper. This gives the polyester a mat finish which appeals to some customers.
  • the adhesive (7) can also be applied in any convenient manner at the spraying station (6) and not only spraying. It can, for example, be applied using knife spread casting, lamination etc.

Abstract

A process for the manufacture of a graphic transfer laminate (8) having a display layer (1, 21) and a carrier layer (2, 20) comprises the steps of laminating the layers by the application of tension, heat and pressure, and applying an adhesive layer (7, 23) to the laminate (8).

Description

GRAPHIC TRANSFER LAMINATE
FIELD OF THE INVENTION
This invention relates to laminates used for transferring graphics onto substrates such as fabrics. In this specification the term "graphic" includes 2D designs, lettering for example.
BACKGROUND TO THE INVENTION
It is well known in the art of applying graphics to fabrics (such as garments), that a graphic can be bonded to the fabric by coating one side of the graphic with an adhesive and applying it to the fabric material.
The adhesive can be activated by heat, pressure, solvents or other suitable means.
Various methods for applying graphics to fabrics are known. A problem with one known method is that because the graphics are bonded to the fabric one by one (in the case of a design comprising more than one graphic, such as numbers), it is difficult to align the graphics properly. The method is also time-consuming.
To overcome the mentioned problem it is known that a pigmented vinyl (e.g. PVC) graphic, can be transferred onto a substrate (e.g. a garment) by making use of a layered material. The material consists of an adhesive layer, a so-called display layer (which is the pigmented vinyl layer) and a carrier layer. The display layer forms the centre of the laminate and is attached to the carrier layer either by adhesive or melt fusion of the carrier layer.
The method of applying the graphic to the substrate using the aforementioned material comprises the steps of first cutting the outlines of the graphic through the adhesive and display layers, but not through the carrier layer. The portions of the adhesive and display layers not forming part of the graphic are then peeled away from the carrier layer. This leaves only the graphic consisting of an adhesive and display layers laminated on the carrier layer.
At this point the sheet is turned upside down, leaving the carrier layer on top and the adhesive layer at the bottom. The sheet is laid down on the material and the adhesive is activated through the action of heat and pressure, causing the adhesive layer to bond with the material.
Once the adhesive layer has bonded with the fabric, the carrier layer is removed from the display layer. This leaves the display layer bonded to the fabric by the action of the adhesive layer. This is the type of process described by Liebe in US Patent 3,660,212.
The advantage of this system over the first mentioned is that the problem with alignment is overcome as the graphics are maintained relative to each other by their attachment to the carrier layer. Bonding all or several graphics at the same time to the material also saves time.
A problem with this method is the fact that for most of the commercially available laminates, the carrier and display are bonded to each other by the action of an adhesive layer. This means that the laminate then includes a first adhesive layer between the carrier and display layers) and a second adhesive layer (between the display layer and the material).
To enable the carrier layer to be removed, the first adhesive layer is selected to have lower adhesion than the second adhesive layer at the temperature of application to the material. The carrier layer can therefor only be removed from the display layer whilst it is still hot. These are known as hot peel laminates.
There have also been other attempts to create laminates consisting of adhesive, display and carrier layers. In US patent 5,441 ,785 this is effected by casting and curing partially carboxylated PVC onto a carrier layer causing it to fuse with the carrier layer. This method also uses knife-spread casting to form the display layer on the carrier layer.
In this patent the use of partially carboxylated PVC is necessary to achieve a greater degree of adhesion between the carrier and display layers. In this method the adhesive layer is also bonded to the display layer by adhering the adhesive layer to the newly cured display layer while it's temperature is still greater than the melting point of the adhesive layer. It also provides that pressure sensitive or solvent activated adhesives can be applied to the display layer instead of the thermally activated adhesives.
Although these processes are affective, they are costly to utilise because of the knife spread casting method used in them.
OBJECT OF THE INVENTION
It is an object of this invention to provide a laminate suitable for the transfer of graphics to a substrate that at least partially alleviates some of the problems described above.
SUMMARY OF THE INVENTION
In accordance with this invention there is provided a process for the manufacturing of laminate for use in transferring a graphic onto a substrate and having a display layer and a carrier layer, the process comprising the steps of laminating a display layer and a carrier layer of suitable synthetic resin materials by subjecting the layers under tension to sufficient heat and pressure to adhere the layers together at a temperature below the softening of either layer and thereafter applying a suitable adhesive to the unlaminated surface of the display layer.
The invention also provides for the tension, heat and pressure to be applied by passing the layers together over at least one hot roller.
There is further provided for the adhesive layer to be applied by spraying, casting or laminating. There is still further provided for the adhesive to be thermally activated or pressure sensitive or solvent activated or any combination of the above and having a bonding strength greater than that formed between the carrier and display layers.
There is also provided for the display layer to be formed from PVC and for the carrier layer to be formed from polyester and for the temperature applied to the display and carrier layers during lamination to be between 110 C and 149 C.
A further feature of the invention provides for at least one of the surfaces of the carrier layer to be matted, and for the matting to be done by scouring the surface with a scouring means.
There is further provided for the scouring means to be sandpaper or the like.
BRIEF DESCRIPTION OF THE DRAWING
Embodiments of the invention are described below by way of example and with reference to the accompanying drawings, in which:
FIG. 1 is a diagrammatic representation of a process for producing a laminate used for transferring a graphic onto a substrate.
FIG. 2 is an enlarged view of laminate comprising a polyester carrier layer and PVC display layer.
FIG. 3 is an enlarged view of a laminate comprising a polyester carrier layer, PVC display layer and thermally activated adhesive layer.
DETAILED DESCRIPTION WITH REFERENCE TO THE DRAWINGS
In this example of the invention a process of manufacturing a laminate is provided. The laminate is for use in the transfer of a PVC graphic to the fabric of a garment. Figure 1 shows a layout of the lamination process. PVC film (1 ) and polyester film (2) are fed over a heated roller (3). After having passed over the heated roller (3) the two films are then passed over a siliconised cold roller (4). The films (1 , 2) are kept at a constant tension by the use of feed rolls (not shown). The effect of the heat of the hot roller (3) and pressure caused by the tension in the films is to cause the two films to adhere to each other at a temperature below the softening temperature of either the PVC or the polyester.
The product formed is a laminate (5) of which greater detail is shown in Figure 2. The laminate consists of a carrier layer (20), which is the polyester film (2), and a display layer (21), which is the PVC film (1 ). The bond (22) between the carrier layer (20) and display layer (21 ) is semi-permanent. This means that the display layer (21 ) will adhere to the carrier layer (20) with enough strength to permit handling of the laminate, but not so much that it does not permit removal of the carrier layer (20) from the display layer (21) by what is known as "cold peeling". The force required for separating the carrier layer (20) and display layer (21) is about 1 N force at operative temperatures.
After the lamination process, the laminate (5) is passed through a spraying station (6) where a hot melt adhesive (7) is sprayed on the display layer (21). The adhesive (7) bonds with the display layer (21).
The melting point of the adhesive (7) is around 110 C and that of the display layer (21 ) is around 180 C. The melting point of the carrier layer (20) is around 240 C. The adhesive (7) is heated to its melting point before spraying it on the display layer (21).
Finally, the three layer laminate (8) is coiled into a roll (10) using a suitable upcoiler (11 ). The process is run on a continuous basis by using an accumulator (9) between the spraying station (6) and upcoiler (11).
The three-layer laminate coil (10) is packed and is ready for use.
This use is effected generally in the conventional manner by placing the laminate on a surface with the adhesive (23) side facing upwards. Next the outlines of a graphic is cut through the adhesive (23) and display (21) layers, without cutting into the carrier layer (20). All of the adhesive (23) and display (21 ) layers falling outside the outlines of the cut graphic are then peeled away. This leaves only the cut graphic layer comprising the adhesive (23) and display (21 ) layers on the carrier (20) layer. The laminate is then turned around, which leaves the carrier layer (20) on top. The adhesive layer (23) is then bonded to the fabric (not shown) by heat applied to the carrier layer to cause the temperature of the adhesive layer (23) to rise above its softening point but not to above the softening point of the display layer (21). This causes the adhesive layer (23) to bond the display layer (21 ) and material (not shown) to each other.
After the display layer (21) has bonded to the material (not shown) as described, the carrier layer (20) can be removed. It can be removed immediately, during the cooling down of the laminate or after the laminate has cooled down.
After removing the carrier layer (20), only the graphic is left bonded to the fabric.
It will be appreciated that this is only one embodiment of the invention and that there are other embodiments of a graphic transfer laminate falling within the scope of the invention.
It is, for example, possible to use different types of display layers (21) or carrier layers (20) besides the described PVC film (1 ) and polyester film (2). It is also possible to use different temperatures and tensions to accommodate the use of these other materials.
It is further possible to use an adhesive layer (23) that is activated by a mechanism other than temperature, such as pressure, solvents etc.
It is also possible to use polyester of which one surface has been matted for the carrier layer. The polyester is matted by sanding it with sandpaper. This gives the polyester a mat finish which appeals to some customers.
The adhesive (7) can also be applied in any convenient manner at the spraying station (6) and not only spraying. It can, for example, be applied using knife spread casting, lamination etc.

Claims

1. A process for the manufacturing of laminate having a display layer and a carrier layer of suitable synthetic resin materials, comprising the steps of:
laminating the display layer and the carrier layer by subjecting the layers under tension to sufficient heat and pressure to cause the layers to adhere together at a temperature insufficient to cause softening of either layer;
and applying an adhesive to the unlaminated surface of the display layer.
2. A process as claimed in claim 1 in which the tension, heat and pressure is applied by passing the layers together over at least one hot roller.
3. A process as claimed in claim 1 in which the adhesive layer is applied to the unlaminated surface of the display layer by any one of the methods of spraying, casting or laminating.
4. A process as claimed in claim 1 in which the adhesive is any one or more of thermally activated, pressure sensitive, or solvent activated.
5. A process as claimed in claim 1 in which the adhesive has a bonding strength greater than the bond formed between the carrier and display layers.
6. A process as claimed in claim 1 in which the display layer is formed from PVC, the carrier layer is formed from polyester and the temperature applied to the display and carrier layers during lamination is between 110 C and
149°C.
7. A process as claimed in claim 1 comprising the further step of matting at least one of the surfaces of the carrier layer.
8. A process as claimed in claim 7 in which the matting is carried out by means of a scouring agent.
PCT/ZA2000/000204 1999-10-28 2000-10-27 Graphic transfer laminate WO2001030565A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU18221/01A AU1822101A (en) 1999-10-28 2000-10-27 Graphic transfer laminate

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ZA996784 1999-10-28
ZA99/6784 1999-10-28

Publications (1)

Publication Number Publication Date
WO2001030565A1 true WO2001030565A1 (en) 2001-05-03

Family

ID=25587964

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/ZA2000/000204 WO2001030565A1 (en) 1999-10-28 2000-10-27 Graphic transfer laminate

Country Status (2)

Country Link
AU (1) AU1822101A (en)
WO (1) WO2001030565A1 (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4544590A (en) * 1982-03-17 1985-10-01 Miller Products, Inc. Laminated member and method of making same
US4767654A (en) * 1985-10-18 1988-08-30 United Merchants & Manufacturers, Inc. Detachable coupon label
EP0569921A1 (en) * 1992-05-14 1993-11-18 Decora, Incorporated Self-adhesive decorative surface covering material

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4544590A (en) * 1982-03-17 1985-10-01 Miller Products, Inc. Laminated member and method of making same
US4767654A (en) * 1985-10-18 1988-08-30 United Merchants & Manufacturers, Inc. Detachable coupon label
EP0569921A1 (en) * 1992-05-14 1993-11-18 Decora, Incorporated Self-adhesive decorative surface covering material

Also Published As

Publication number Publication date
AU1822101A (en) 2001-05-08

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