WO2001022836A1 - Method for extending the flavor shelf life of aqueous compositions flavored with moisture and acid sensitive flavors and flavor compositions having extended flavor shelf lives - Google Patents
Method for extending the flavor shelf life of aqueous compositions flavored with moisture and acid sensitive flavors and flavor compositions having extended flavor shelf lives Download PDFInfo
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- WO2001022836A1 WO2001022836A1 PCT/US2000/026514 US0026514W WO0122836A1 WO 2001022836 A1 WO2001022836 A1 WO 2001022836A1 US 0026514 W US0026514 W US 0026514W WO 0122836 A1 WO0122836 A1 WO 0122836A1
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- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/385—Concentrates of non-alcoholic beverages
- A23L2/39—Dry compositions
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/40—Effervescence-generating compositions
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Their preparation
- A23L2/42—Preservation of non-alcoholic beverages
- A23L2/44—Preservation of non-alcoholic beverages by adding preservatives
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L27/00—Spices; Flavouring agents or condiments; Artificial sweetening agents; Table salts; Dietetic salt substitutes; Preparation or treatment thereof
- A23L27/70—Fixation, conservation, or encapsulation of flavouring agents
Definitions
- the present invention is directed to a method of extending the flavor shelf life of aqueous compositions flavored with moisture and acid sensitive flavors and flavor compositions having extended flavor shelf lives.
- the method embodiment of the present invention delays the transformation of flavor compounds into less desirable compounds, thereby prolonging the useful life of said flavor compounds.
- the flavor compositions of the present invention are used to flavor aqueous compositions, they provide the aqueous composition with an extended flavor shelf life.
- aqueous compositions It is common for aqueous compositions to contain moisture and acid sensitive flavor compounds that mask off-flavors or otherwise increase the consumer's enjoyment of aqueous compositions.
- many of the flavors used in aqueous compositions have such a short flavor shelf life that by the time the aqueous composition is consumed, the composition's flavoring has been chemically transformed to such an extent that the consumer does not enjoy the full benefit of the flavoring compound. This is especially true with ready to drink beverages where the flavoring compounds may be almost completely transformed into less desirable compounds by the time the beverage reaches the consumer.
- references such as "The Acid Catalysed Hydration of Sabinene and alpha-Thujene"; Cooper, M.A.; Holden, CM.; Whittaker, D.; J.C.S. Perkin II, pp. 665-667 (1973) indicate that sabinene, a flavor compound found in citrus fruits, berries, juniper oils, and plant seeds, such as black peppercorn, is transformed into 1-terpinen-4-ol and other terpinenes in the presence of water or acids.
- the degradation of moisture and acid sensitive flavor compounds is noted indirectly by Japikse et. al., in the U.S. Pat. No.
- Japikse et. al. disclose compounds which are found in the juice, membrane, and peel of oranges after processing.
- terpineol a decomposition product of orange flavor.
- flavor components of fresh oranges, such as monoterpene and sabinene were absent, Japikse et. al. does not appear to recognize the loss of flavor that is associated with the rate of loss of monoterpene and sabinene nor does Japikse et. al. offer a solution to the problem.
- Boskovic, et. al. in the U.S. Pat. No. 5,124,162 disclose the spray drying encapsulation of flavorants in a carbohydrate matrix. Although the flavorants are protected from loss and chemical transformation while in the carbohydrate matrix, upon exposing the encapsulated flavorant in a carbohydrate matrix to an aqueous composition, the carbohydrate matrix readily dissolves thus exposing the flavorants to moisture and subsequent chemical transformations.
- Porzio et. al. teaches an encapsulation composition comprising a glassy carbohydrate matrix, a plasticizer and flavor oils which is hot melt extruded to produce a glassy matrix.
- the extruded encapsulation composition readily dissolves when exposed to an aqueous compositions thus allowing for the subsequent chemical transformation of moisture and acid sensitive flavor compounds.
- Chen et. al. disclose a method for preserving fresh fruit wherein a solution comprising calcium ions, ascorbate ions or erythorbate ions and water is applied to the surface of the freshly cut fruit to prevent browning and other spoilage. While this invention teaches how to preserve the key characteristics of fresh fruit, this invention does not teach a method of extending the flavor shelf life of an aqueous composition flavored with isolated moisture and acid sensitive flavor compounds. Further, this invention does not recognize the problem nor teach the solution to protecting moisture and acid sensitive flavors from chemical transformation due to hydrolysis, which occurs when the flavors are combined with an aqueous composition to form a product such as a beverage.
- the art has failed to recognize the problem of protecting moisture and acid sensitive flavors from chemical transformation, due to hydrolysis, when the moisture and acid sensitive flavors are combined with aqueous compositions.
- the art teaches that flavor compounds can be preserved by delaying or preventing their exposure to aqueous compositions. Since the art does not appear to recognize the problem nor teach the solution to protecting moisture and acid sensitive flavors from the chemical transformations that occur when the flavors are mixed with aqueous compositions, the consumer and possibly the manufacturers of aqueous compositions flavored with moisture and acid sensitive flavors may be unaware of the flavor benefits that are lost. In short, the consumer is deprived of the full benefits that flavor compounds are meant to provide.
- an object of the present invention is to provide a method for extending the flavor shelf lives of aqueous compositions that are flavored by or with moisture and acid sensitive flavor compounds.
- Another object of this invention is to provide flavor compositions that have extended flavor shelf lives.
- a method for extending the flavor shelf life of an aqueous composition that is flavored by or with a moisture and acid sensitive flavor comprising the steps of: a) providing a moisture and acid sensitive flavor, b) providing an edible organic acid component, c) providing an edible divalent salt component, d) combining said flavor and said edible organic acid component and said edible divalent salt component prior to exposing said moisture and acid sensitive flavor to moisture or acid.
- a moisture and acid sensitive flavor composition comprising a moisture and acid sensitive flavor, an edible organic acid component and an edible divalent salt component wherein said flavor composition is a powder or tablet.
- the phrase "extending the flavor shelf life of a moisture and acid sensitive flavor” means retaining or extending the chemical identity of a moisture or acid sensitive flavor while the flavor is exposed to water or acid.
- moisture and acid sensitive flavor means a flavor that can be transformed to less desirable compounds when exposed to moist or acidic environments.
- flavor shelf life of a flavoring compound begins at the point at which the flavoring compound is combined with an aqueous composition.
- combining means placing said components in intimate physical contact and includes, but is not limited to processing methods such as blending, mixing, milling, stirring, and folding.
- processing methods such as blending, mixing, milling, stirring, and folding.
- aqueous composition means a composition of matter that comprises at least 30% water as determined by the Association of Analytical Chemists (AOAC), "Official Methods of Analysis” (1990), 15th edition, Methods, 950.27, AOAC, Arlington, Virginia.
- solid means an essentially dry material in powder or granular form that can be reconstituted or diluted with water or other aqueous liquid to form a premix or added directly in dry form to an aqueous composition.
- solid means an essentially dry material in powder or granular form that can be reconstituted or diluted with water or other aqueous liquid to form a premix or added directly in dry form to an aqueous composition.
- sebene means a monoterpene as defined in Adv. Food
- an edible divalent salt or “an edible organic acid” is understood to mean at least one of the components that are claimed or described.
- salt means a compound that has one cation and at least one anion. All percentages herein are by weight unless otherwise specified.
- the methods described herein have been shown to extend the flavor shelf life of aqueous compositions flavored with moisture and acid sensitive flavors. Specifically, the methods comprise the steps of providing a moisture and acid sensitive flavor, providing an edible organic acid component, providing an edible divalent salt component, and combining said flavor and said edible organic acid component and said edible divalent salt component prior to exposing said moisture and acid sensitive flavor to moisture or acid.
- An optional step comprises combining said edible organic acid component with said edible divalent salt component to form a salt, prior to adding said edible organic acid component and said edible divalent salt component to said moisture and acid sensitive flavor.
- An additional optional, but less preferred, step is the step of adding said edible organic acid component and said edible divalent salt component, whether pre- combined to form a salt or as separate components, and a moisture and acid sensitive flavor to an aqueous composition, prior to providing the aqueous composition to the consumer.
- the edible organic acid component, edible divalent salt component and moisture and acid sensitive flavor are added separately to the aqueous composition
- the edible divalent salt component is added to the aqueous composition first, next the edible organic acid component is added to the aqueous composition, and then the moisture and acid sensitive flavor is added to aqueous composition.
- the edible organic acid component, edible divalent salt component and moisture and acid sensitive flavor are added separately to the aqueous composition, the edible organic acid component is added to the aqueous composition first, next the edible divalent salt component is added to the aqueous composition, and then the moisture and acid sensitive flavor is added to aqueous composition. Most preferably, the edible organic acid component, edible divalent salt component and moisture and acid sensitive flavor are simultaneously added to the aqueous composition.
- the edible organic acid component, edible divalent salt component and moisture and acid sensitive flavor can be functional in a variety of forms, including but not limited to powders, liquids, liquid concentrates and premixes.
- the flavorings be essentially dry or encapsulated. Most preferably the flavorings are in the form of a dry powder.
- the preferred state of the edible organic acid component and edible divalent salt component, whether pre-combined to form a salt or separate components, is an essentially dry powder or equilibrium hydrate salt.
- the method can include the additional optional step of forming tablets from each solid or from the combined mixture of solids, prior to introducing the solids or mixture of solids to an aqueous composition.
- Flavors whose flavor shelf life can be extended by practicing the method of the present invention can be obtained from a natural source or can be synthetically produced and include, but are not limited, to moisture and acid sensitive flavors containing at least one compound selected from the group consisting of monoterpenes, aldehydes, terpenes and esters.
- Preferred, flavors whose flavor shelf life can be extended by practicing the method of the present invention include moisture and acid sensitive flavors that contain at least one compound selected from the group consisting of sabinene, citronellal, citral, cinnamic aldehyde, ethyl isobutyrate, ethyl acetate and mixtures thereof.
- Non-limiting examples of flavors whose flavor shelf life can be extended by practicing the method of the present invention include: orange, lemon, lime, grapefruit, apple, grape, pear, cherry, watermelon, pineapple, cranberry, strawberry, juniper, raspberry, blackberry, nectarine, rhubarb, plum, passion fruit, kiwi, raspberry; and mixtures thereof.
- the following flavors are preferred: orange, lemon, lime, grapefruit, apple, grape, pear, cherry, watermelon, pineapple, cranberry, strawberry, juniper; and mixtures thereof.
- the following flavors are even more preferred: orange, lemon, lime, grapefruit, apple, grape, pear, cherry and mixtures thereof.
- the most preferred flavors are orange, lemon, lime, grapefruit and mixtures thereof.
- Optical isomers of malic acid, gluconic acid, lactic acid and mixtures thereof may be used as well.
- Preferred edible organic acids are citric acid, malic acid, optical isomers of malic acid and mixtures thereof.
- the molar ratio of edible divalent salt component and edible organic acid component is from about 1 :1 to about 1 :4.
- Edible divalent salts that can be used to practice the method of the present invention include, but are not limited to, calcium salts or magnesium salts.
- Non-limiting examples of calcium salts or magnesium salts that can be used to practice the method of the present include: calcium carbonate, calcium hydroxide, calcium oxide, calcium gluconate, calcium fumarate, calcium lactate, calcium phosphate monobasic, calcium phosphate dibasic, calcium phosphate t basic, calcium chloride, calcium sulfate, magnesium carbonate, magnesium hydroxide, magnesium oxide, magnesium sulfate, magnesium chloride, magnesium citrate, and mixtures thereof.
- Preferred divalent salts include: calcium carbonate, calcium hydroxide, calcium oxide, calcium phosphate monobasic, calcium phosphate dibasic, calcium phosphate t basic, calcium chloride, calcium sulfate and mixtures thereof.
- the edible divalent salt component is a magnesium or calcium salt or mixture thereof
- the salt provides a sufficient amount of cations, when combined with an aqueous composition, to provide the aqueous composition with at least 0.02% by weight cations which comprise magnesium, calcium or mixtures thereof.
- the salt when the edible divalent salt component is a magnesium or calcium salt or mixture thereof, the salt provides a sufficient amount of cations, when combined with an aqueous composition, to provide the aqueous composition with at least 0.03% to about 1.5% by weight cations which comprise magnesium, calcium or mixtures thereof. Most preferably, when the edible divalent salt component is a magnesium or calcium salt or mixture thereof, the salt provides a sufficient amount of cations, when combined with an aqueous composition, to provide the aqueous composition with about 0.05% to about 0.6% by weight cations which comprise magnesium, calcium or mixtures thereof.
- the method of this invention can be used by manufacturers of beverages and other aqueous compositions, and single strength and concentrated solids, such as powders or tablets, that are designed to be mixed with an aqueous composition to form a product.
- the invention is particularly useful when applied to essentially dry single strength or concentrated solids, that contain at least one moisture and acid sensitive flavor, as the invention can extend the flavor of the product that results when the essentially dry solid is mixed with the aqueous composition.
- the flavor shelf life of an aqueous composition that is flavored with a moisture and acid sensitive flavor can be extended up to 127 hours at which time, at least about 10% of the flavoring compound is still present when measured per the protocol identified as Solid-Phase Microextraction Gas Chromatography-Mass Spectrometry "SPME-GC/MS Analysis of Volatiles of Beverages".
- the flavor shelf life of an aqueous composition that is flavored with a moisture and acid sensitive flavor can be extended up to 36 hours at which time, at least about 50% of the flavoring compound is still present as measured per the protocol identified as Solid- Phase Microextraction Gas Chromatography-Mass Spectrometry "SPME-GC/MS Analysis of Volatiles of Beverages”.
- the SPME-GC/MS protocol is disclosed below.
- Solid-Phase Microextraction Gas Chromatography-Mass Spectrometry is a sampling and analysis technique well suited for flavor analysis.
- SPME manual sampling assembly comprising a 2 cm Stableflex® fiber with a dual coating of carboxen and divinylbenzene (30 ⁇ m/50 ⁇ m) suspended in polydimethylsiloxane, obtained from Supelco, Inc.
- GC Gas Chromatograph
- HP Hewlett Packard (HP) model 6890 having an injector temperature of about 250 °C and the following temperature program: i) an initial temperature of about 50 °C which is held for about 2 minutes, ii) increase the initial temperature at a rate of about 5 °C/min until a temperature of about 200 °C is reached, iii) next, the temperature is increased at about 10 °C/min until a temperature of about 250 °C is reached, iv) hold at about 250 °C for about 3 minutes.
- GC Gas Chromatograph
- HP Hewlett Packard
- the total run time is about 40 minutes; c) GC column: Durabond® (30 meters in length, 252 ⁇ m column ID and 1.0 ⁇ m film thickness) obtained from J&W Scientific of Folsom, California, USA; d) Carrier gas: Helium having a flow rate of 2ml/min.; e) The Detector was a model HP 5973 Mass Selective Detector (MSD) obtained from Hewlett Packard, Santa Clarita, California, USA having a i) source temperature of about 230 C C, and ii) a Mass Spectrometer Quad temperature of about 150 °C.
- MSD Mass Selective Detector
- Sample preparation a) Separately equilibrate the moisture and acid sensitive flavor compound and the desired aqueous composition to about 22 °C. b) Add the moisture and acid sensitive flavor compound to the desired aqueous composition. c) Equilibrate the aqueous composition containing a moisture and acid sensitive flavor compound at about 22 °C for about 5 minutes. 3. Flavor analysis by SPME-GC/MS a) Transfer 60 mis of the combined moisture and acid sensitive flavor compound and aqueous composition to a 100 ml headspace sampling glass vial containing a
- Teflon® coated magnetic stirring bar b) Seal the vial with a standard Teflon® gas tight crimp seal. c) Equilibrate the contents of the vial at about 22 °C for about 15 minutes. d) Initiate sampling i) sampling time should be about 15 minutes. ii) the desorption time for the SPME fiber should be about 3 minutes. e) Identify flavor compounds using the MS spectral libraries of John Wiley & Sons and the National Institute of Standards and Technology (NIST), purchased and licensed through Hewlett Packard. f) Integrate the peaks using the Chemstation® software obtained from Hewlett Packard,
- Citric and malic acids were analyzed using the protocol disclosed in the AOAC
- Lactic and acetic acids are analyzed by the protocol disclosed in the Journal of
- Adipic acid is analyzed by the protocol disclosed in Bunseki-Kagaku, Oct 1988, K. Fujimura et al., 37 (10), 549-553.
- the protocol for determining the level and type of flavor contained in an aqueous composition is titled "SPME-GC/MS Analysis of Volatiles of Beverages" and is the same protocol that is used to determine flavor shelf life extension.
- the flavor compositions described herein have been shown to provide aqueous compositions with extended flavor shelf lives.
- the flavor compositions of the present invention comprise a moisture and acid sensitive flavor, an edible organic acid component and an edible divalent salt component.
- the edible organic acid component, edible divalent salt component and moisture and acid sensitive flavor can comprise a variety of functional forms, including but not limited to powders, liquids, liquid concentrates and premixes. However, as moisture and acid sensitive flavorings are moisture and acid sensitive, it is preferred that the flavorings be essentially dry. Most preferably the flavorings are in the form of a dry powder.
- the preferred state of the edible organic acid component and edible divalent salt component, whether pre-combined to form a salt or separate components, is an essentially dry powder or an equilibrium hydrate salt.
- tablets may be formed from the solids or mixture of solids prior to combining the solids with an aqueous composition.
- Flavors that can be used to produce the flavor composition of the present invention can be obtained from a natural source or can be synthetically produced and include, but are not limited, to moisture and acid sensitive flavors containing at least one compound selected from the group consisting of monoterpenes, aldehydes, terpenes and esters.
- flavors that can be preserved by practicing the method of the present invention include moisture and acid sensitive flavors that contain a compound selected from the group consisting of sabinene, citronellal, citral, cinnamic aldehyde, ethyl isobutyrate, ethyl acetate and mixtures thereof.
- Non-limiting examples of flavors that can be preserved by practicing the method of the present invention include: orange, lemon, lime, grapefruit, apple, grape, pear, cherry, watermelon, pineapple, cranberry, strawberry, juniper, raspberry, blackberry, nectarine, rhubarb, plum, passion fruit, kiwi, raspberry; and mixtures thereof.
- flavors are preferred: orange, lemon, lime, grapefruit, apple, grape, pear, cherry, watermelon, pineapple, cranberry, strawberry, juniper; and mixtures thereof.
- flavors are even more preferred: orange, lemon, lime, grapefruit, apple, grape, pear, cherry and mixtures thereof.
- the most preferred flavors are orange, lemon, lime, grapefruit and mixtures thereof.
- Optical isomers of malic acid, gluconic acid, lactic acid and mixtures thereof may be used as well.
- Preferred edible organic acids are citric acid, malic acid, optical isomers of malic acid and mixtures thereof.
- the molar ratio of edible divalent salt component and edible organic acid component is from about 1 :1 to about 1 :4.
- Edible divalent salts that can be used to produce the flavoring composition of the present invention include, but are not limited to, calcium salts or magnesium salts.
- Non-limiting examples of calcium salts or magnesium salts that can be used to practice the method of the present include: calcium carbonate, calcium hydroxide, calcium oxide, calcium gluconate, calcium fumarate, calcium iactate, calcium phosphate monobasic, calcium phosphate dibasic, calcium phosphate thbasic, calcium chloride, calcium sulfate, magnesium carbonate, magnesium hydroxide, magnesium oxide, magnesium sulfate, magnesium chloride, magnesium citrate, and mixtures thereof.
- Preferred divalent salts include: calcium carbonate, calcium hydroxide, calcium oxide, calcium phosphate monobasic, calcium phosphate dibasic, calcium phosphate thbasic, calcium chloride, calcium sulfate and mixtures thereof.
- the edible divalent salt component is a magnesium or calcium salt or mixture thereof
- the salt provides a sufficient amount of cations, when combined with an aqueous composition, to provide the aqueous composition with at least 0.02% by weight cations which comprise magnesium, calcium or mixtures thereof.
- the salt when the edible divalent salt component is a magnesium or calcium salt or mixture thereof, the salt provides a sufficient amount of cations, when combined with an aqueous composition, to provide the aqueous composition with at least 0.03% to about 1.5% by weight cations which comprise magnesium, calcium or mixtures thereof. Most preferably, when the edible divalent salt component is a magnesium or calcium salt or mixture thereof, the salt provides a sufficient amount of cations, when combined with an aqueous composition, to provide the aqueous composition with about 0.05% to about 0.6% by weight cations which comprise magnesium, calcium or mixtures thereof.
- the flavoring composition of this invention can be used by manufactures of beverages and single strength and concentrated solids, such as powders or tablets, that are designed to be mixed with an aqueous composition to form a product.
- the invention is particularly useful when incorporated into essentially dry single strength or concentrated solids, such as a powder drink mix, as the invention can extend the flavor of the product that results when the essentially dry solid is mixed with the aqueous composition.
- the flavor shelf life of an aqueous composition containing a flavoring composition of the present invention can be extended up to 127 hours at which time, at least about 10% of the flavoring compound is still present as measured per the protocol identified as Solid-Phase Microextraction Gas Chromatography-Mass Spectrometry "SPME-GC/MS Analysis of Volatiles of Beverages".
- the flavor shelf life of an aqueous composition that is flavored with a flavor composition of the present invention can be extended up to 36 hours at which time, at least about 50% of the flavoring compound is still present as measured per the protocol identified as Solid-Phase Microextraction Gas Chromatography-Mass Spectrometry "SPME-GC/MS Analysis of Volatiles of Beverages”.
- the SPME-GC/MS protocol is disclosed in the "Methods Embodiment" Section of the present application.
- the protocol for determining the levels and types of cations of the edible divalent salt components used in the flavor compositions of the present invention is the same as and is disclosed in the "Methods Embodiment” Section of the present application.
- the protocol for determining the levels and types of moisture and acid sensitive flavors used in the flavor compositions of the present invention is the same as and is disclosed in the "Methods Embodiment” Section of the present application.
- Optional ingredients which can be combined with the flavor composition described herein, without detracting from the present invention, include, but are not limited to, clouding agents (e.g. titanium dioxide, creamers), colors, dyes, thickeners, carbohydrates, artificial and natural sweeteners, starches, fibers, water, fruit solids, vitamins, minerals (other than the Ca, Mg listed), carbonating agents, preservatives, and flow agents (e.g. Si02).
- clouding agents e.g. titanium dioxide, creamers
- Nonlimiting examples of natural carbohydrates include monosaccharides such as: erythrose, threose, ribose, arabinose, xylose, hbulose, glucose, galactose, mannose, fructose and sorbose, disaccharides such as sucrose, maltose, maltulose and lactose, and complex carbohydrates such as: raffinose, maltotriose, maltotetraose, glycogen, amylose, amylopectin and maltodextrins.
- monosaccharides such as: erythrose, threose, ribose, arabinose, xylose, hbulose, glucose, galactose, mannose, fructose and sorbose
- disaccharides such as sucrose, maltose, maltulose and lactose
- complex carbohydrates such as: raffinose, maltotriose, maltot
- Nonlimiting examples of non-caloric sweeteners include aspartame, saccharin, cyclamates, sucralose, acesulfame-potassium, L-aspartyl-L-phenylalanine lower alkyl ester sweeteners, L-aspartyl-D-alanine amides as disclosed in US patent 4,411 ,925 to Brennan, et al (1983), L-aspartyl-D-serine amides disclosed in US 4,399,163 to Brennan et al (1983), L-aspartyl-hydroxymethyl alkane amide sweeteners disclosed in U.S.
- the flavor composition of the present invention can be prepared by blending the proper amounts and ratios of all the required dry ingredients together.
- the process of making comprises the steps of providing a moisture and acid sensitive flavor, providing an edible organic acid component, providing an edible divalent salt component, and combining said flavor and said edible organic acid component and said edible divalent salt component prior to exposing said moisture and acid sensitive flavor to moisture or acid.
- An optional step comprises combining said edible organic acid component with said edible divalent salt component to form a salt, prior to adding said edible organic acid component and said edible divalent salt component to said moisture and acid sensitive flavor.
- the resulting flavor compositions are solids and include granules and bulk powders.
- a final optional step is to form tablets or capsules from the flavor compositions.
- Tablets may contain suitable binders, lubricants, diluents, disintegrating agents, coloring agents, flavoring agents, flow-inducing agents and melting agents.
- suitable carriers and excipients that may be used to formulate dry forms of the present invention are described in U.S. Patent 3,903,297, Rober, issued September 2, 1975. Techniques and compositions for making dry forms useful in the methods of this invention are described in the following references: H.W. Houghton (ed.), Developments in Soft Drinks Technology, vol.
- the essentially dry mixture can later be dissolved in a proper amount of water, carbonated or non-carbonated, or other aqueous liquid to make a final drinkable beverage or other aqueous composition.
- the edible organic acid component, edible divalent salt component and moisture and acid sensitive flavor are added separately to an aqueous composition
- the edible divalent salt component is added to the aqueous composition first, next the edible organic acid component is added to the aqueous composition, and then the moisture and acid sensitive flavor is added to aqueous composition.
- dry forms of the present invention may be incorporated in other products, including but not limited to nutrient bars, cereal bars and energy bars, candy, to impart to such products an extended flavor shelf life.
- the orange flavors used in the following examples comprise mixtures of Natural Orange Durarome obtained from Firmenich, Anaheim, California, U.S.A., and Safety Harbor, Florida, U.S.A., and Natural Orange Juice flavor obtained from Firmenich, Anaheim, California, U.S.A., and Natural & Artificial Orange Flavor, and Artificial Orange Booster Flavor, and Flavorburst® Artificial Fruit Topnote obtained from Givaudan-Roure, East Hanover, New Jersey, U.S.A.
- a powdered flavor composition was prepared according to the present invention by: Formulation:
- aqueous composition was analyzed via the SPME-GC/MS protocol and found to contain about 30% more sabinene and at least 10% more citronellal after 40 minutes than a similar beverage containing the same level and type of materials except for the edible divalent salt component.
- aqueous composition flavored with a moisture and acid sensitive flavor compound, edible organic acid component and edible divalent salt. 4. The aqueous composition was analyzed via the SPME-GC/MS protocol and found to contain about 37% more sabinene and at least 10% more citronellal after 40 minutes than a similar beverage containing the same level and type of materials except for the edible divalent salt component.
- a powdered flavor composition containing sufficient optional ingredients, to allow said powder flavor composition to serve as a powder drink mix was prepared by:
- the aqueous composition was analyzed via the SPME-GC/MS protocol and found to contain about 65% more sabinene and at least 10% more citronellal after 40 minutes than a similar beverage containing the same level and type of materials except for the edible divalent salt component.
- the aqueous composition was analyzed after 24 hours and was found to contain about 53% of its original level of sabinene while a similar beverage containing the same level and type of materials, except for the edible divalent salt component, was found to have less than 1 % of its original level of sabinene.
- the aqueous composition was analyzed after 120 hours and was found to contain about 15% of its original level of sabinene while a similar beverage containing the same level and type of materials, except for the edible divalent salt component, was found to have less than 1% of its original level of sabinene.
- a powdered flavor composition containing sufficient optional ingredients, to allow said powder flavor composition to serve as a powder drink mix was prepared by:
- CCM powder is calcium-citrate-malate salt (20-26% elemental calcium by weight) obtained from Jost Chemicals, St. Louis, Missouri, U.S.A.
- the aqueous composition was analyzed via the SPME-GC/MS protocol and found to contain about 55% more sabinene and at least 10% more citronellal after 40 minutes than a similar beverage containing the same level and type of materials except for the edible divalent salt component.
- the aqueous composition was analyzed after 24 hours and was found to contain about 49% of its original level of sabinene, while a similar beverage containing the same level and type of materials, except for the edible divalent salt component, was found to have less than 1 % of its original level of sabinene. 6.
- the aqueous composition was analyzed after 24 hours and was found to contain about 11 % of its original level of sabinene, while a similar beverage containing the same level and type of materials, except for the edible divalent salt component, was found to have less than 1 % of its original level of sabinene.
- a powdered flavor composition was prepared according to the present invention by: Formulation:
- the ingredients are then mixed to a uniform appearance. 3. 2.6 grams of the flavor composition is combined with 200 grams of water containing 22 grams of sugar leading to an aqueous composition flavored with a moisture and acid sensitive flavor compound, edible organic acid component and edible divalent salt. 4. The aqueous composition is analyzed via the SPME-GC/MS protocol and found to contain at least 10% more sabinene and at least 10% more citronellal after 40 minutes than a similar beverage containing the same level and type of materials except for the edible divalent salt component.
- a powdered flavor composition was prepared according to the present invention by: Formulation:
- the ingredients are then mixed to a uniform appearance. 3. 2.6 grams of the flavor composition is combined with 200 grams of water containing 22 grams of sugar leading to an aqueous composition flavored with a moisture and acid sensitive flavor compound, edible organic acid component and edible divalent salt. 4. The aqueous composition is analyzed via the SPME-GC/MS protocol and found to contain at least 10% more sabinene and at least 10% more citronellal after 40 minutes than a similar beverage containing the same level and type of materials except for the edible divalent salt component.
- a powdered flavor composition is prepared according to the present invention by: Formulation:
- aqueous composition flavored with a moisture and acid sensitive flavor compound, edible organic acid component and edible divalent salt. 4.
- the aqueous composition is analyzed via the SPME-GC/MS protocol and found to contain at least 10% more sabinene and at least 10% more citronellal after 40 minutes than a similar beverage containing the same level and type of materials except for the edible divalent salt component.
- a powdered flavor composition containing sufficient optional ingredients, to allow said powder flavor composition to serve as a powder drink mix is prepared by:
- the ingredients are then mixed to a uniform appearance. 3. 25 grams of the powder drink mix are combined with 200 grams of water leading to an aqueous composition flavored with a moisture and acid sensitive flavor compound, edible organic acid component and edible divalent salt. 4. The aqueous composition are analyzed via the SPME-GC/MS protocol and found to contain at least 10% more sabinene and at least 10% more citronellal after 40 minutes than a similar beverage containing the same level and type of materials except for the edible divalent salt component.
- Example 9 A powdered flavor composition is prepared according to the present invention by: Formulation:
- the aqueous composition is analyzed via the SPME-GC/MS protocol and found to contain at least 10% more ethyl acetate after 40 minutes than a similar beverage containing the same level and type of materials except for the edible divalent salt component.
- a powdered flavor composition is prepared according to the present invention by: Formulation:
- the aqueous composition is analyzed via the SPME-GC/MS protocol and found to contain at least 10% more sabinene after 40 minutes than a similar beverage containing the same level and type of materials except for the edible divalent salt -component.
- a powdered flavor composition is prepared according to the present invention by: Formulation:
- the aqueous composition is analyzed via the SPME-GC/MS protocol and found to contain at least 10% more sabinene after 40 minutes than a similar beverage containing the same level and type of materials except for the edible divalent salt component.
- a powdered flavor composition is prepared according to the present invention by: Formulation: Ingredients wt/wt %
- the aqueous composition is analyzed via the SPME-GC/MS protocol and found to contain at least 10% more sabinene after 40 minutes than a similar beverage containing the same level and type of materials except for the edible divalent salt component.
- Example 13 A powdered flavor composition is prepared according to the present invention by:
- the aqueous composition is analyzed via the SPME-GC/MS protocol and found to contain at least 10% more cinnamic aldehyde after 40 minutes than a similar beverage containing the same level and type of materials except for the edible divalent salt component.
- a powdered flavor composition is prepared according to the present invention by: Formulation:
- aqueous composition flavored with a moisture and acid sensitive flavor compound, edible organic acid component and edible divalent salt. 4.
- the aqueous composition is analyzed via the SPME-GC/MS protocol and found to contain at least 10% more ethyl isobutyrate after 40 minutes than a similar beverage containing the same level and type of materials except for the edible divalent salt component.
- Example 15 A powdered flavor composition is prepared according to the present invention by:
- the aqueous composition is analyzed via the SPME-GC/MS protocol and found to contain at least 10% more ethyl acetate after 40 minutes than a similar beverage containing the same level and type of materials except for the edible divalent salt component.
- Example 16 A powdered flavor composition is prepared according to the present invention by:
- Malic Acid 22.4 1. All of the ingredients are weighed and placed into a stainless steel mixing bowl having a dry powder mixer equipped with a blunt stainless steel blade.
- the aqueous composition is analyzed via the SPME-GC/MS protocol and found to contain at least 10% more sabinene after 40 minutes than a similar beverage containing the same level and type of materials except for the edible divalent salt component.
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP00965474A EP1215971A1 (en) | 1999-09-30 | 2000-09-27 | Method for extending the flavor shelf life of aqueous compositions flavored with moisture and acid sensitive flavors |
JP2001526060A JP2003510058A (en) | 1999-09-30 | 2000-09-27 | Method for extending the flavor shelf life of an aqueous composition flavored with a moisture and acid reactive flavor, and flavor composition having an extended flavor shelf life |
MXPA02003148A MXPA02003148A (en) | 1999-09-30 | 2000-09-27 | Method for extending the flavor shelf life of aqueous compositions flavored with moisture and acid sensitive flavors and flavor compositions having extended flavor shelf lives. |
BR0014672-2A BR0014672A (en) | 1999-09-30 | 2000-09-27 | Method for extending the aroma life of aqueous compositions flavored with aromas sensitive to moisture and acid, and aroma compositions that have extended aroma shelf lives |
CA002383995A CA2383995A1 (en) | 1999-09-30 | 2000-09-27 | Method for extending the flavor shelf life of aqueous compositions flavored with moisture and acid sensitive flavors and flavor compositions having extended flavor shelf lives |
AU76188/00A AU7618800A (en) | 1999-09-30 | 2000-09-27 | Method for extending the flavor shelf life of aqueous compositions flavored withmoisture and acid sensitive flavors and flavor compositions having extended fla vor shelf lives |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US15680599P | 1999-09-30 | 1999-09-30 | |
US60/156,805 | 1999-09-30 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2001022836A1 true WO2001022836A1 (en) | 2001-04-05 |
Family
ID=22561165
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2000/026514 WO2001022836A1 (en) | 1999-09-30 | 2000-09-27 | Method for extending the flavor shelf life of aqueous compositions flavored with moisture and acid sensitive flavors and flavor compositions having extended flavor shelf lives |
Country Status (9)
Country | Link |
---|---|
EP (1) | EP1215971A1 (en) |
JP (1) | JP2003510058A (en) |
CN (1) | CN1377237A (en) |
AU (1) | AU7618800A (en) |
BR (1) | BR0014672A (en) |
CA (1) | CA2383995A1 (en) |
MX (1) | MXPA02003148A (en) |
WO (1) | WO2001022836A1 (en) |
ZA (1) | ZA200201893B (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007146452A3 (en) * | 2006-03-06 | 2008-03-06 | Coca Cola Co | Methods and apparatuses for making compostitions comprising an acid and an acid degradable component and/or compositions comprising a plurality of selectable components. |
US8162176B2 (en) | 2007-09-06 | 2012-04-24 | The Coca-Cola Company | Method and apparatuses for providing a selectable beverage |
US8293299B2 (en) | 2009-09-11 | 2012-10-23 | Kraft Foods Global Brands Llc | Containers and methods for dispensing multiple doses of a concentrated liquid, and shelf stable Concentrated liquids |
US20150024064A1 (en) * | 2007-02-14 | 2015-01-22 | Nutra Products, Inc. | pKa Buffered Vitamin C Composition and Method |
US11013248B2 (en) | 2012-05-25 | 2021-05-25 | Kraft Foods Group Brands Llc | Shelf stable, concentrated, liquid flavorings and methods of preparing beverages with the concentrated liquid flavorings |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011152095A (en) * | 2010-01-28 | 2011-08-11 | House Foods Corp | Method for improving apple flavor of apple flavor food composition |
CN105747270A (en) * | 2014-07-28 | 2016-07-13 | 邹玉华 | Electronic cigarette liquid and preparation method thereof |
EP3442352A4 (en) * | 2016-04-14 | 2020-03-11 | Mars, Incorporated | Compounds that modulate calcium-sensing receptor activity for modulating kokumi taste and pet food products containing the same |
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EP0168956A1 (en) * | 1984-06-15 | 1986-01-22 | General Foods Corporation | The method for fixing food ingredients on a magnesium salt substrate |
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2000
- 2000-09-27 WO PCT/US2000/026514 patent/WO2001022836A1/en not_active Application Discontinuation
- 2000-09-27 EP EP00965474A patent/EP1215971A1/en not_active Withdrawn
- 2000-09-27 MX MXPA02003148A patent/MXPA02003148A/en unknown
- 2000-09-27 JP JP2001526060A patent/JP2003510058A/en not_active Withdrawn
- 2000-09-27 CA CA002383995A patent/CA2383995A1/en not_active Abandoned
- 2000-09-27 CN CN00813711A patent/CN1377237A/en active Pending
- 2000-09-27 AU AU76188/00A patent/AU7618800A/en not_active Abandoned
- 2000-09-27 BR BR0014672-2A patent/BR0014672A/en not_active IP Right Cessation
-
2002
- 2002-03-07 ZA ZA200201893A patent/ZA200201893B/en unknown
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GB883169A (en) * | 1958-09-05 | 1961-11-22 | Henry Brout | Dry effervescent concentrate |
GB1024408A (en) * | 1964-10-30 | 1966-03-30 | Sandoz Products Ltd | Improvements in or relating to beverage concentrates |
US3939289A (en) * | 1973-04-02 | 1976-02-17 | General Foods Corporation | Dry carbonation source for a beverage concentrate and method of preparing the same |
EP0040654A2 (en) * | 1980-05-20 | 1981-12-02 | Vitapharm Pharmaceutical Pty Ltd. | Electrolyte drink concentrate |
EP0075429A2 (en) * | 1981-09-14 | 1983-03-30 | Philip Morris Incorporated | Dry phosphoric acid composition |
EP0168956A1 (en) * | 1984-06-15 | 1986-01-22 | General Foods Corporation | The method for fixing food ingredients on a magnesium salt substrate |
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2007146452A3 (en) * | 2006-03-06 | 2008-03-06 | Coca Cola Co | Methods and apparatuses for making compostitions comprising an acid and an acid degradable component and/or compositions comprising a plurality of selectable components. |
EP2384649A1 (en) * | 2006-03-06 | 2011-11-09 | The Coca-Cola Company | Apparatus for Making Beverages From a Plurality of Selectable Beverage Components |
US10631558B2 (en) | 2006-03-06 | 2020-04-28 | The Coca-Cola Company | Methods and apparatuses for making compositions comprising an acid and an acid degradable component and/or compositions comprising a plurality of selectable components |
US10631560B2 (en) | 2006-03-06 | 2020-04-28 | The Coca-Cola Company | Methods and apparatuses for making compositions comprising an acid and an acid degradable component and/or compositions comprising a plurality of selectable components |
US20150024064A1 (en) * | 2007-02-14 | 2015-01-22 | Nutra Products, Inc. | pKa Buffered Vitamin C Composition and Method |
US8162176B2 (en) | 2007-09-06 | 2012-04-24 | The Coca-Cola Company | Method and apparatuses for providing a selectable beverage |
US8434642B2 (en) | 2007-09-06 | 2013-05-07 | The Coca-Cola Company | Method and apparatus for providing a selectable beverage |
US8814000B2 (en) | 2007-09-06 | 2014-08-26 | The Coca-Cola Company | Method and apparatuses for providing a selectable beverage |
US10046959B2 (en) | 2007-09-06 | 2018-08-14 | The Coca-Cola Company | Method and apparatuses for providing a selectable beverage |
US8293299B2 (en) | 2009-09-11 | 2012-10-23 | Kraft Foods Global Brands Llc | Containers and methods for dispensing multiple doses of a concentrated liquid, and shelf stable Concentrated liquids |
US8603557B2 (en) | 2009-09-11 | 2013-12-10 | Kraft Foods Group Brands Llc | Containers and methods for dispensing multiple doses of a concentrated liquid, and shelf stable concentrated liquids |
US11013248B2 (en) | 2012-05-25 | 2021-05-25 | Kraft Foods Group Brands Llc | Shelf stable, concentrated, liquid flavorings and methods of preparing beverages with the concentrated liquid flavorings |
Also Published As
Publication number | Publication date |
---|---|
CA2383995A1 (en) | 2001-04-05 |
ZA200201893B (en) | 2002-12-24 |
JP2003510058A (en) | 2003-03-18 |
BR0014672A (en) | 2002-06-11 |
AU7618800A (en) | 2001-04-30 |
CN1377237A (en) | 2002-10-30 |
EP1215971A1 (en) | 2002-06-26 |
MXPA02003148A (en) | 2002-09-30 |
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