WO2000056853A1 - Antimicrobial acid cleaner for use on organic soil - Google Patents
Antimicrobial acid cleaner for use on organic soil Download PDFInfo
- Publication number
- WO2000056853A1 WO2000056853A1 PCT/US2000/006149 US0006149W WO0056853A1 WO 2000056853 A1 WO2000056853 A1 WO 2000056853A1 US 0006149 W US0006149 W US 0006149W WO 0056853 A1 WO0056853 A1 WO 0056853A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition
- acid
- alkyl
- ether
- amine
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/42—Amino alcohols or amino ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0026—Low foaming or foam regulating compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/36—Organic compounds containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/08—Acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/261—Alcohols; Phenols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/263—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/26—Organic compounds containing oxygen
- C11D7/265—Carboxylic acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3227—Ethers thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/36—Organic compounds containing phosphorus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5004—Organic solvents
- C11D7/5022—Organic solvents containing oxygen
Definitions
- carbohydrate soils including cellulosics, monosaccharides, disaccharides, oligosaccharides, starches, gums and other complex materials, when dried, can form tough, hard to remove soils particularly when combined with other soil types.
- other materials arising from foodstuffs including proteins, enzymes, fats and oils can also form contaminating, hard to remove soil, residues.
- the acidic cleaning compositions of this invention are formed from a major proportion of water, a food grade or food compatable acidic component comprising an inorganic acid or organic acid or combinations thereof.
- the acidic component used to prepare the acidic compositions of the invention that can be dissolved in the aqueous organic cosolvent system of the invention to produce an acidic pH in the range of about 1 to 5.
- N pH substantially less than about 1 can result in substantial corrosion of metal and other surfaces common in the cleaning environment, while a pH greater than about 5 can unacceptably reduce the cleaning efficiency of the composition.
- the weight ratio of phosphoric acid to hydroxyacetic acid is preferably about 15:1 to 1 :1, most preferably about 8-1.5:1.
- carbohydrate soils that can be contaminated with proteinaceous soils and inorganic soils such as CaHPO 4 , etc.
- This component is part of many soils and can be a result of the interaction between hardness components and acid-containing cleaners using phosphoric acid as the acidic component.
- the phosphate content permitted in cleansing compositions is restricted or must be limited to a negligible amount.
- Water conditioning agents function to inactivate water hardness and prevent calcium and magnesium ions from interacting with soils, surfactants, carbonate and hydroxide. Water conditioning agents therefore improve detergency and prevent long term effects such as insoluble soil redepositions, mineral scales and mixtures thereof. Water conditioning can be achieved by different mechanisms including sequestration, precipitation, ion-exchange and dispersion (threshold effect). Metal ions such as calcium and magnesium do not exist in aqueous solution as simple positively charged ions. Because they have a positive charge, they tend to surround themselves with water molecules and become solvated. Other molecules or anionic groups are also capable of being attracted by metallic cations. When these moieties replace water molecules, the resulting metal complexes are called coordination compounds.
- Water conditioning can also be affected by an in situ exchange of hardness ions from the detersive water solution to a solid (ion exchanger) incorporated as an ingredient in the detergent.
- this ion exchanger is an aluminosilicate of amorphoric or crystalline structure and of naturally occurring or synthetic origin commercially designated as zeolite. To function properly, the zeolite must be of small particle size of about 0.1 to about 10 microns in diameter for maximum surface exposure and kinetic ion exchange.
- the water conditioning mechanisms of precipitation, sequestration and ion exchange are stoichiometric interactions requiring specific mass action proportions of water conditioner to calcium and magnesium ion concentrations.
- the water soluble aminopolyphosphonic acids, or salts thereof, compounds are excellent water conditioning agents and may be advantageously used in the present invention. Suitable examples include soluble salts, e.g. sodium, lithium or potassium salts, of amino-(trimethylenephosphonic acid) di ethylene diamine pentamethylene phosphonic acid, ethylene diamine tetramethylene phosphonic acid, hexamethylenediamine tetramethylene phosphonic acid, and nitrilotrimethylene phosphonic acid; and, mixtures thereof.
- Water soluble short chain carboxylic acid salts constitute another class of water conditioner for use herein. Examples include citric acid, gluconic acid and phytic acid.
- polyacrylate solutions useful in the present cleaning compositions include the sodium polyacrylate solution, Colloid (R) 207 (Colloids, Inc., Newark, NJ.); the polyacrylic acid solution, Aquatreat® AR- 602- A (Alco Chemical Corp., Chattanooga, Term.); the polyacrylic acid solutions (50-65% solids) and the sodium polyacrylate powers (M.W. 2,100 and 6,000) and solutions (45% solids) available as the Goodrite ( ) K-700 series from B. F. Goodrich Co.; and the sodium or partial sodium salts of polyacrylic acid solutions (M.W. 1000 to 4500) available as the Acusol (R) series from Rohm and Haas.
- combinations and admixtures of any of the above enumerated water conditioning agents may be advantageously utilized within the embodiments of the present invention.
- Suitable substances are alkyl ether alcohols such as mefhoxyefhanol, methoxyethanol acetate, butyoxy ethanol (butyl cellosolve), propylene glycol, polyethylene glycol, polypropylene glycol, diethylene glycol monoefhyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, tripropylene glycol methyl ether, propylene glycol methyl ether (PM), dipropylene glycol methyl ether (DPM), propylene glycol methyl ether acetate (PMA), dipropylene glycol methyl ether acetate (CPMA), ethylene glycol n-butyl ether, 1 ,2-dimethoxyethane, 2- ethoxy ethanol, 2-ethoxy-ethylacetate, phenoxy ethanol, and ethylene glycol n-propyl ether.
- alkyl ether alcohols such as mefhoxyefhanol, me
- the aqueous cleaners of the invention comprises an amine compound.
- the amine compound functions to enhance compositional cleaning, further antimicrobial character, and reduce or eliminate the formation of various precipitates resulting from the dilution of water and/or contaminants on the surface of application.
- the amine compound is an alkyl ether amine compound of the formulae,
- Ri may be a linear saturated or unsaturated C 6 . 18 alkyl
- R 2 may be a linear or branched C ⁇ _ 8 alkyl
- R3 may be a linear or branched C ⁇ - 8 alkyl.
- the use dilution of the concentrate is preferably calculated to get disinfectant or sanitizing efficacy in the intended application or use.
- the active amine compound concentration in the composition of the invention ranges from about 10 ppm to 10000 ppm, preferably from about 20 ppm to 7500 ppm, and most preferably about 40 ppm to 5000 ppm.
- quaternary ammonium compounds can be used as a substitute for all or a part of the ether amine compound described above.
- Suitable quaternary compounds include generally the quaternary ammonium salt compounds which may be described as containing, in addition to the usual halide (chloride, bromide, iodide, etc.), sulfate, phosphate, or other anion, aliphatic and/or alicyclic radicals, preferably aldyl and/or aralkyl, bonded through carbon atoms therein to the remaining 4 available positions of the nitrogen atom, 2 or 3 of which radicals may be joined to form a heterocycle with the nitrogen atom, at least one of such radicals being aliphatic with at least 8, up to 22 or more, carbon atoms.
- Suitable agents which may be incorporated are quaternary ammonium salts of the formula:
- Ri, R 2 , R 3 , and R 4 is an organic radical containing a group selected from a C 16 -C 2 2 aliphatic radical, or an alkyl phenyl or alkyl benzyl radical having 10-16 atoms in the alkyl chain, the remaining group or groups being selected from hydrocarbyl groups containing from 1 to about 4 carbon atoms, or C 2 -C 4 hydroxyl alkyl groups and cyclic structures in which the nitrogen atom forms part of the ring, and Y is an anion such as halide, methylsulphate, or ethylsulphate.
- the hydrophobic moiety i.e. the C 16 -
- cationic detergents there may be mentioned distearyl dimethyl ammonium chloride, stearyl dimethyl benzyl ammonium chloride, coconut alkyl dimethyl benzyl ammonium chloride, dicoconut alkyl dimethyl ammonium bromide, cetyl pyridinium iodide, and cetyl pyridinium iodide, and cetyl trimethyl ammonium bromide and the like.
- the particular surfactant or surfactant mixture chosen for use in the process and products of this invention depends upon the conditions of final utility, including method of manufacture, physical product form, use pH, use temperature, foam control, and soil type.
- the preferred surfactant system of the invention is selected from nonionic surfactant types. Anionics are incompatible and precipitate in these systems. Nonionic surfactants offer diverse and comprehensive commercial selection, low price; and, most important, excellent detersive effect ⁇ meaning surface wetting, soil penetration, soil removal from the surface being cleaned, and soil suspension in the detergent solution.
- Soil suspension is as important a surfactant property in CLP detersive systems as soil removal to prevent soil redeposition on cleaned surfaces during recirculation and later re-use in CLP systems which save and re-employ the same detersive solution again for several cleaning cycles.
- concentration of surfactant or surfactant mixture useful in use-dilution, use solutions of the present invention ranges from about 0.002% (20 ppm) by weight to about 2% (20,000 ppm) by weight, preferably from about 0.005% (50 ppm) by weight to about 0.1% (1000 ppm) by weight, and most preferably from about 0.05% (500 ppm) by weight to about 0.005% (50 ppm) by weight.
- nonionic low foaming surfactants include:
- additional primary, secondary or tertiary amino groups can be introduced or the amino nitrogen can be quaternized with low molecular weight alkyl groups, further, the nitrogen can be a member of branched or straight chain moiety of varying degrees of unsaturation; or, of a saturated or unsaturated heterocyclic ring.
- cationic surfactants may contain complex linkages having more than one cationic nitrogen atom.
- Use solutions are typically prepared by dilution with water resulting in an active concentration of about 100 ppm to about 20,000 ppm.
- the objective of the analysis was to determine the sanitizing efficacy of Ex. 19 and Ex. 20 against Staphylococcus aureus ATCC 6538, Escherichia coli ATCC 11229 and a 1 :1 mixed inoculum of yeast.
Abstract
Description
Claims
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP00913838A EP1163321A1 (en) | 1999-03-23 | 2000-03-09 | Antimicrobial acid cleaner for use on organic soil |
AU35206/00A AU766254B2 (en) | 1999-03-23 | 2000-03-09 | Antimicrobial acid cleaner for use on organic soil |
CA002367719A CA2367719C (en) | 1999-03-23 | 2000-03-09 | Antimicrobial acid cleaner for use on organic or food soil |
NZ514334A NZ514334A (en) | 1999-03-23 | 2000-03-09 | Antimicrobial acid center cleaner for use on organic or food soil |
BRPI0009103-0A BR0009103B1 (en) | 1999-03-23 | 2000-03-09 | cleaning composition Low foaming acid and on-site cleaning process of a beverage manufacturing plant. |
JP2000606712A JP5198696B2 (en) | 1999-03-23 | 2000-03-09 | Antimicrobial acid cleaner for use against organic contamination |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/275,065 | 1999-03-23 | ||
US09/275,065 US5998358A (en) | 1999-03-23 | 1999-03-23 | Antimicrobial acid cleaner for use on organic or food soil |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2000056853A1 true WO2000056853A1 (en) | 2000-09-28 |
Family
ID=23050748
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US2000/006149 WO2000056853A1 (en) | 1999-03-23 | 2000-03-09 | Antimicrobial acid cleaner for use on organic soil |
Country Status (11)
Country | Link |
---|---|
US (2) | US5998358A (en) |
EP (1) | EP1163321A1 (en) |
JP (2) | JP5198696B2 (en) |
AR (1) | AR023113A1 (en) |
AU (1) | AU766254B2 (en) |
BR (1) | BR0009103B1 (en) |
CA (1) | CA2367719C (en) |
CO (1) | CO5210967A1 (en) |
NZ (1) | NZ514334A (en) |
WO (1) | WO2000056853A1 (en) |
ZA (1) | ZA200107760B (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1679361A1 (en) * | 2003-10-27 | 2006-07-12 | Wako Pure Chemical Industries, Ltd. | Cleaning agent for substrate and cleaning method |
US7494963B2 (en) | 2004-08-11 | 2009-02-24 | Delaval Holding Ab | Non-chlorinated concentrated all-in-one acid detergent and method for using the same |
US7786063B2 (en) | 2003-07-14 | 2010-08-31 | Kao Corporation | Detergent composition for CIP comprising a C10-C14 aliphatic hydrocarbon and nonionic surfactant |
Families Citing this family (79)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6010729A (en) | 1998-08-20 | 2000-01-04 | Ecolab Inc. | Treatment of animal carcasses |
ES2226697T3 (en) * | 1999-03-24 | 2005-04-01 | Johnsondiversey, Inc. | METHOD FOR DETECTING PROTEIN AND KIT THAT USES THE SAME. |
AU4462000A (en) * | 1999-04-14 | 2000-11-14 | Charvid Limited Liability Company | Method and composition for cleaning beverage lines |
US6737028B1 (en) | 1999-06-02 | 2004-05-18 | Sunburst Chemicals, Inc. | Solid cast container |
US6743764B1 (en) * | 1999-07-30 | 2004-06-01 | Dow Global Technologies Inc. | Low viscosity alkyl diphenyl oxide sulfonic acid blends |
JP4301382B2 (en) * | 2000-01-24 | 2009-07-22 | ジョンソンディバーシー株式会社 | Acid detergent for beer brewing equipment |
US6218349B1 (en) * | 2000-03-17 | 2001-04-17 | Ecolab, Inc. | Composition suitable for removing proteinaceous material |
MXPA02010640A (en) | 2000-04-28 | 2003-05-14 | Ecolab Inc | Antimicrobial composition. |
US6316398B1 (en) * | 2000-05-09 | 2001-11-13 | Diversey Lever, Inc. | General purpose cleaning composition |
US7795199B2 (en) * | 2000-06-29 | 2010-09-14 | Ecolab Inc. | Stable antimicrobial compositions including spore, bacteria, fungi, and/or enzyme |
US7150884B1 (en) | 2000-07-12 | 2006-12-19 | Ecolab Inc. | Composition for inhibition of microbial growth |
US6479454B1 (en) | 2000-10-05 | 2002-11-12 | Ecolab Inc. | Antimicrobial compositions and methods containing hydrogen peroxide and octyl amine oxide |
US6835702B2 (en) * | 2000-11-07 | 2004-12-28 | Ecolab Inc. | Compositions and methods for mitigating corrosion of applied color designs |
US6514556B2 (en) | 2000-12-15 | 2003-02-04 | Ecolab Inc. | Method and composition for washing poultry during processing |
US6906019B2 (en) * | 2001-04-02 | 2005-06-14 | Aprion Digital Ltd. | Pre-treatment liquid for use in preparation of an offset printing plate using direct inkjet CTP |
US6472199B1 (en) * | 2001-04-04 | 2002-10-29 | West Agro, Inc. | Method of cleaning dairy pipelines using enzyme pretreatment |
US20030015219A1 (en) * | 2001-04-20 | 2003-01-23 | Kravitz Joseph I. | Cleaning process and composition |
US20030153536A1 (en) * | 2001-10-25 | 2003-08-14 | Mitchell Glass | Compounds and methods of treating transplant rejection |
AU2003202265A1 (en) * | 2002-01-09 | 2003-07-30 | Summerdale, Inc. | Fungicide compositions |
US7041177B2 (en) | 2002-08-16 | 2006-05-09 | Ecolab Inc. | High temperature rapid soil removal method |
US6818609B2 (en) * | 2002-08-21 | 2004-11-16 | Houghton Technical Corp. | Metal deformation compositions and uses thereof |
ATE405622T1 (en) * | 2002-10-22 | 2008-09-15 | Ekc Technology Inc | AQUEOUS PHOSPHORIC ACID COMPOSITION FOR CLEANING SEMICONDUCTOR DEVICES |
US7820594B2 (en) * | 2003-01-09 | 2010-10-26 | Coleman Robert D | Pesticide compositions and methods for their use |
US7622606B2 (en) | 2003-01-17 | 2009-11-24 | Ecolab Inc. | Peroxycarboxylic acid compositions with reduced odor |
AU2004243183B2 (en) * | 2003-05-28 | 2009-08-06 | Otsuka Pharmaceutical Co., Ltd. | Aqueous olanexidine solution, method of preparing the same, and disinfectant |
US7727568B2 (en) * | 2003-06-05 | 2010-06-01 | Purac Biochem B.V. | Antimicrobial composition comprising a mixture of lactic acid or a derivative thereof and an inorganic acid |
US7468346B2 (en) * | 2003-06-30 | 2008-12-23 | Ecolab Inc. | Low foaming washing liquid |
JP2005206794A (en) * | 2003-11-21 | 2005-08-04 | Daisan Kogyo Kk | Cip cleaning agent composition and cleaning method using the same |
WO2005049774A1 (en) * | 2003-11-21 | 2005-06-02 | Johnson Diversey Inc. | Cip cleaning agent composition and method of cleaning therewith |
US8999175B2 (en) | 2004-01-09 | 2015-04-07 | Ecolab Usa Inc. | Methods for washing and processing fruits, vegetables, and other produce with medium chain peroxycarboxylic acid compositions |
US7504123B2 (en) * | 2004-01-09 | 2009-03-17 | Ecolab Inc. | Methods for washing poultry during processing with medium chain peroxycarboxylic acid compositions |
EP1703791B1 (en) | 2004-01-09 | 2014-07-23 | Ecolab Inc. | Medium chain peroxycarboxylic acid compositions |
US7771737B2 (en) | 2004-01-09 | 2010-08-10 | Ecolab Inc. | Medium chain peroxycarboxylic acid compositions |
US7507429B2 (en) | 2004-01-09 | 2009-03-24 | Ecolab Inc. | Methods for washing carcasses, meat, or meat products with medium chain peroxycarboxylic acid compositions |
US7887641B2 (en) | 2004-01-09 | 2011-02-15 | Ecolab Usa Inc. | Neutral or alkaline medium chain peroxycarboxylic acid compositions and methods employing them |
EP1561801A1 (en) * | 2004-01-28 | 2005-08-10 | JohnsonDiversey Inc. | Sanitizing and cleaning composition and its use for sanitizing and/or cleaning hard surfaces |
DE602004023269D1 (en) * | 2004-03-25 | 2009-11-05 | Procter & Gamble | Liquid acid cleaning composition for hard surfaces |
US7094742B2 (en) * | 2004-04-23 | 2006-08-22 | Jelmar, Llc | Hard surface cleaning compositions containing a sultaine and a mixture of organic acids |
JP4578853B2 (en) * | 2004-04-30 | 2010-11-10 | 花王株式会社 | Cleaning composition for CIP |
US8114222B2 (en) * | 2004-08-27 | 2012-02-14 | Ecolab Usa Inc. | Method for cleaning industrial equipment with pre-treatment |
US8398781B2 (en) * | 2004-08-27 | 2013-03-19 | Ecolab Usa Inc. | Methods for cleaning industrial equipment with pre-treatment |
JP2006124627A (en) * | 2004-09-29 | 2006-05-18 | Daisan Kogyo Kk | Cip agent composition and cleaning agent composition for manufacturing apparatus of food and drink, and method of using the same |
US8110538B2 (en) * | 2005-01-11 | 2012-02-07 | Biomed Protect, Llc | Peracid/peroxide composition and use thereof as an anti-microbial and a photosensitizer |
DE102005019658A1 (en) * | 2005-04-26 | 2006-11-02 | Henkel Kgaa | Aqueous disinfectant, useful for cleaning and disinfecting hard surfaces, comprises combination of benzalkonium chloride, phenoxyethanol and aminotrimethylenephosphonic acid |
US20060293214A1 (en) * | 2005-06-28 | 2006-12-28 | Lily Cheng | Synergistic acidic ternary biocidal compositions |
US7148187B1 (en) * | 2005-06-28 | 2006-12-12 | The Clorox Company | Low residue cleaning composition comprising lactic acid, nonionic surfactant and solvent mixture |
US7754670B2 (en) | 2005-07-06 | 2010-07-13 | Ecolab Inc. | Surfactant peroxycarboxylic acid compositions |
US7771542B1 (en) * | 2006-05-30 | 2010-08-10 | Stone Chemical Company | Compositions and methods for removing lead from metal surfaces |
US7923425B2 (en) * | 2006-08-21 | 2011-04-12 | Henkel Ag & Co. Kgaa | Low-foaming, acidic low-temperature cleaner and process for cleaning surfaces |
US8075857B2 (en) | 2006-10-18 | 2011-12-13 | Ecolab Usa Inc. | Apparatus and method for making a peroxycarboxylic acid |
US7547421B2 (en) | 2006-10-18 | 2009-06-16 | Ecolab Inc. | Apparatus and method for making a peroxycarboxylic acid |
US8133403B2 (en) * | 2007-07-31 | 2012-03-13 | Behr Process Corporation | System and method for controlling the application of acid etchers or cleaners by means of color-changing dye |
US7470331B1 (en) | 2007-11-01 | 2008-12-30 | The Clorox Company | Acidic cleaning composition |
US7414016B1 (en) * | 2007-11-01 | 2008-08-19 | The Clorox Company | Acidic cleaning compositions |
US20090288683A1 (en) * | 2008-05-21 | 2009-11-26 | Ecolab Inc. | Alkaline peroxygen food soil cleaner |
US7964548B2 (en) | 2009-01-20 | 2011-06-21 | Ecolab Usa Inc. | Stable aqueous antimicrobial enzyme compositions |
US7723281B1 (en) | 2009-01-20 | 2010-05-25 | Ecolab Inc. | Stable aqueous antimicrobial enzyme compositions comprising a tertiary amine antimicrobial |
US20140014137A1 (en) | 2009-09-18 | 2014-01-16 | Ecolab Usa Inc. | Treatment of non-trans fats with acidic tetra sodium l-glutamic acid, n, n-diacetic acid (glda) |
CN102905562A (en) | 2010-05-20 | 2013-01-30 | 艺康美国股份有限公司 | Rheology modified low foaming liquid antimicrobial compositions and methods of use thereof |
US8575084B2 (en) | 2010-11-12 | 2013-11-05 | Jelmar, Llc | Hard surface cleaning composition for personal contact areas |
US8569220B2 (en) | 2010-11-12 | 2013-10-29 | Jelmar, Llc | Hard surface cleaning composition |
WO2014018309A1 (en) | 2012-07-26 | 2014-01-30 | The Procter & Gamble Company | Low ph liquid cleaning compositions with enzymes |
US10253281B2 (en) | 2012-08-20 | 2019-04-09 | Ecolab Usa Inc. | Method of washing textile articles |
US9752105B2 (en) | 2012-09-13 | 2017-09-05 | Ecolab Usa Inc. | Two step method of cleaning, sanitizing, and rinsing a surface |
US20140308162A1 (en) | 2013-04-15 | 2014-10-16 | Ecolab Usa Inc. | Peroxycarboxylic acid based sanitizing rinse additives for use in ware washing |
US9873854B2 (en) | 2013-01-16 | 2018-01-23 | Jelmar, Llc | Stain removing solution |
US9434910B2 (en) | 2013-01-16 | 2016-09-06 | Jelmar, Llc | Mold and mildew stain removing solution |
ES2795009T3 (en) | 2015-01-29 | 2020-11-20 | Ecolab Usa Inc | Method for treating stains on textiles |
CA2991407A1 (en) * | 2015-07-07 | 2017-01-12 | Delaval Holding Ab | Acid detergent |
JP6644498B2 (en) * | 2015-08-24 | 2020-02-12 | 株式会社Adeka | CIP cleaning method |
JP6904979B2 (en) | 2016-03-01 | 2021-07-21 | エコラボ ユーエスエー インコーポレイティド | Sterilized rinse based on the synergistic effect of quaternary anionic surfactant |
WO2018005341A1 (en) | 2016-06-28 | 2018-01-04 | Ecolab USA, Inc. | Composition, method and use for enhanced oil recovery |
EP3496540A4 (en) | 2016-08-11 | 2020-07-15 | Ecolab USA Inc. | Interaction between antimicrobial quaternary compounds and anionic surfactants |
EP3528632A4 (en) * | 2016-10-21 | 2020-04-08 | Ecolab USA Inc. | REDUCED INHALATION HAZARD OF QUATERNARY AMMONIUM COMPOUNDS-pH DRIVEN PHYSIOLOGICAL RESPONSE |
US10865367B2 (en) * | 2017-06-26 | 2020-12-15 | Ecolab Usa Inc. | Method of dishwashing comprising detergent compositions substantially free of polycarboxylic acid polymers |
EP3752278A1 (en) | 2018-02-14 | 2020-12-23 | Ecolab USA Inc. | Compositions and methods for the reduction of biofilm and spores from membranes |
WO2020027797A1 (en) | 2018-07-31 | 2020-02-06 | Kimberly-Clark Worldwide, Inc. | Composition including an antimicrobial boosting agent including an amphocarboxylate and methods of increasing the antimicrobial effectiveness of a composition |
US11421191B1 (en) | 2018-11-15 | 2022-08-23 | Ecolab Usa Inc. | Acidic cleaner |
JP2020059859A (en) * | 2020-01-07 | 2020-04-16 | 株式会社Adeka | Detergent composition for acidic cip and cip cleaning method |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1487715A (en) * | 1975-02-20 | 1977-10-05 | Hoechst Ag | Multipurpose acid cleaning compositions |
US5000867A (en) * | 1986-10-20 | 1991-03-19 | Lever Brothers Company | Disinfectant compositions |
FR2690848A1 (en) * | 1992-05-06 | 1993-11-12 | Francais Prod Ind Cfpi | Cleaning and disinfecting compsn. |
FR2735788A1 (en) * | 1995-06-23 | 1996-12-27 | Francais Prod Ind Cfpi | Acid aq. detergent compsn. contg. poly-carboxylic acid and strong mineral acid, |
Family Cites Families (37)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4396521A (en) * | 1976-04-22 | 1983-08-02 | Giuseppe Borrello | Solid detergent spotter |
US4124523A (en) * | 1977-03-07 | 1978-11-07 | Dow Corning Corporation | Silicone-containing acidic cleaner and conditioner |
JPS5826399B2 (en) * | 1978-06-05 | 1983-06-02 | 花王株式会社 | liquid cleaning composition |
US4597975A (en) * | 1981-11-06 | 1986-07-01 | Woodward Fred E | Iodine surface active compositions |
US4587030A (en) * | 1983-07-05 | 1986-05-06 | Economics Laboratory, Inc. | Foamable, acidic cleaning compositions |
US4501680A (en) * | 1983-11-09 | 1985-02-26 | Colgate-Palmolive Company | Acidic liquid detergent composition for cleaning ceramic tiles without eroding grout |
US4594175A (en) * | 1984-08-29 | 1986-06-10 | Economics Laboratory, Inc. | Mechanical dishwashing rinse composition having a low foaming sulfonic acid rinsing agent, a hydrotrope and a source of active halogen |
US4624713A (en) * | 1984-11-15 | 1986-11-25 | Economics Laboratory, Inc. | Solid rinse aids and methods of warewashing utilizing solid rinse aids |
US4579676A (en) * | 1984-12-17 | 1986-04-01 | Economics Laboratory, Inc. | Low-phosphate liquid cleaning composition |
US4749508A (en) * | 1985-02-05 | 1988-06-07 | Kay Chemical Company | Floor cleaning compositions and their use |
US4699728A (en) * | 1986-05-29 | 1987-10-13 | Ecolab, Inc. | Aqueous acidic composition for cleaning fiberglass |
US4935065A (en) * | 1986-08-22 | 1990-06-19 | Ecolab Inc. | Phosphate-free alkaline detergent for cleaning-in-place of food processing equipment |
GB8625974D0 (en) * | 1986-10-30 | 1986-12-03 | Unilever Plc | Non-aqueous liquid detergent |
US4921627A (en) * | 1986-11-14 | 1990-05-01 | Ecolab Inc. | Detersive system and low foaming aqueous surfactant solutions containing a mono(C1-4 alkyl)-di(C6-20) alkylamine oxide compound |
US5411585A (en) * | 1991-02-15 | 1995-05-02 | S. C. Johnson & Son, Inc. | Production of stable hydrolyzable organosilane solutions |
NZ240355A (en) * | 1991-06-04 | 1994-09-27 | Ecolab Inc | Sanitising composition comprising sorbic and benzoic acids |
US5437868A (en) * | 1991-07-23 | 1995-08-01 | Ecolab Inc. | Peroxyacid antimicrobial composition |
US5464477A (en) * | 1992-09-18 | 1995-11-07 | Crest Ultrasonics Corporation | Process for cleaning and drying ferrous surfaces without causing flash rusting |
NZ248582A (en) * | 1992-09-24 | 1995-02-24 | Colgate Palmolive Co | Acidic, thickened cleaner containing dicarboxylic acids and aminoalkylene phosphonic acid for cleaning lime scale from acid-resistant or zirconium white enamel hard surfaces |
US5436008A (en) * | 1992-12-11 | 1995-07-25 | Ecolab Inc. | Sanitizing compositions |
US5409713A (en) * | 1993-03-17 | 1995-04-25 | Ecolab Inc. | Process for inhibition of microbial growth in aqueous transport streams |
JPH08510770A (en) * | 1993-06-01 | 1996-11-12 | エコラブ, インコーポレイテッド | Foam surface cleaner |
US5370729A (en) * | 1993-09-15 | 1994-12-06 | Ecolab Inc. | Food safe composition to facilitate soil removal |
US5364551A (en) * | 1993-09-17 | 1994-11-15 | Ecolab Inc. | Reduced misting oven cleaner |
US5462681A (en) * | 1993-11-12 | 1995-10-31 | Ecolab, Inc. | Particulate suspending antimicrobial additives |
US5912219A (en) * | 1994-02-03 | 1999-06-15 | The Procter & Gamble Company | Acidic cleaning compositions |
AU685302B2 (en) * | 1994-06-29 | 1998-01-15 | Ecolab Inc. | Composition and improved pH driven method for wastewater separation using an amphoteric carboxylate and a cationic destabilizer composition |
US5861366A (en) * | 1994-08-31 | 1999-01-19 | Ecolab Inc. | Proteolytic enzyme cleaner |
CA2454516C (en) * | 1995-02-01 | 2005-01-25 | Ecolab Inc. | Method of cleaning floors |
CA2167971C (en) * | 1995-02-01 | 2008-08-26 | Paula J. Carlson | Solid acid cleaning block and method of manufacture |
GB2297976A (en) * | 1995-02-01 | 1996-08-21 | Reckitt & Colmann Prod Ltd | Improvements in or relating to a bleaching process |
US5716260A (en) * | 1995-02-03 | 1998-02-10 | Ecolab Inc. | Apparatus and method for cleaning and restoring floor surfaces |
US5712241A (en) * | 1996-04-08 | 1998-01-27 | Colgate-Palmolive Co. | Light duty liquid cleaning composition |
US5707952A (en) * | 1996-04-24 | 1998-01-13 | Colgate-Palmolive Company | Thickened acid composition |
US5723418A (en) * | 1996-05-31 | 1998-03-03 | Ecolab Inc. | Alkyl ether amine conveyor lubricants containing corrosion inhibitors |
US5871590A (en) * | 1997-02-25 | 1999-02-16 | Ecolab Inc. | Vehicle cleaning and drying compositions |
US5935921A (en) * | 1999-01-26 | 1999-08-10 | Colgate-Palmolive Co. | Liquid descaling composition |
-
1999
- 1999-03-23 US US09/275,065 patent/US5998358A/en not_active Expired - Lifetime
- 1999-08-10 US US09/371,231 patent/US6121219A/en not_active Expired - Lifetime
-
2000
- 2000-03-09 BR BRPI0009103-0A patent/BR0009103B1/en not_active IP Right Cessation
- 2000-03-09 AU AU35206/00A patent/AU766254B2/en not_active Expired
- 2000-03-09 JP JP2000606712A patent/JP5198696B2/en not_active Expired - Lifetime
- 2000-03-09 EP EP00913838A patent/EP1163321A1/en not_active Withdrawn
- 2000-03-09 CA CA002367719A patent/CA2367719C/en not_active Expired - Lifetime
- 2000-03-09 NZ NZ514334A patent/NZ514334A/en not_active IP Right Cessation
- 2000-03-09 WO PCT/US2000/006149 patent/WO2000056853A1/en not_active Application Discontinuation
- 2000-03-21 AR ARP000101250A patent/AR023113A1/en active IP Right Grant
- 2000-03-22 CO CO00020381A patent/CO5210967A1/en not_active Application Discontinuation
-
2001
- 2001-09-20 ZA ZA200107760A patent/ZA200107760B/en unknown
-
2010
- 2010-09-21 JP JP2010211264A patent/JP2010280917A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1487715A (en) * | 1975-02-20 | 1977-10-05 | Hoechst Ag | Multipurpose acid cleaning compositions |
US5000867A (en) * | 1986-10-20 | 1991-03-19 | Lever Brothers Company | Disinfectant compositions |
FR2690848A1 (en) * | 1992-05-06 | 1993-11-12 | Francais Prod Ind Cfpi | Cleaning and disinfecting compsn. |
FR2735788A1 (en) * | 1995-06-23 | 1996-12-27 | Francais Prod Ind Cfpi | Acid aq. detergent compsn. contg. poly-carboxylic acid and strong mineral acid, |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7786063B2 (en) | 2003-07-14 | 2010-08-31 | Kao Corporation | Detergent composition for CIP comprising a C10-C14 aliphatic hydrocarbon and nonionic surfactant |
EP1679361A1 (en) * | 2003-10-27 | 2006-07-12 | Wako Pure Chemical Industries, Ltd. | Cleaning agent for substrate and cleaning method |
EP1679361A4 (en) * | 2003-10-27 | 2010-07-28 | Wako Pure Chem Ind Ltd | Cleaning agent for substrate and cleaning method |
US8900371B2 (en) | 2003-10-27 | 2014-12-02 | Wako Pure Chemical Industries, Ltd. | Cleaning agent for substrate and cleaning method |
US7494963B2 (en) | 2004-08-11 | 2009-02-24 | Delaval Holding Ab | Non-chlorinated concentrated all-in-one acid detergent and method for using the same |
US7501027B2 (en) | 2004-08-11 | 2009-03-10 | Delaval Holding Ab | Non-chlorinated concentrated all-in-one acid detergent and method for using the same |
Also Published As
Publication number | Publication date |
---|---|
AR023113A1 (en) | 2002-09-04 |
JP2010280917A (en) | 2010-12-16 |
BR0009103B1 (en) | 2010-08-24 |
AU3520600A (en) | 2000-10-09 |
CA2367719A1 (en) | 2000-09-28 |
CA2367719C (en) | 2008-08-19 |
NZ514334A (en) | 2003-06-30 |
BR0009103A (en) | 2001-12-18 |
US5998358A (en) | 1999-12-07 |
AU766254B2 (en) | 2003-10-09 |
ZA200107760B (en) | 2003-02-12 |
CO5210967A1 (en) | 2002-10-30 |
JP5198696B2 (en) | 2013-05-15 |
US6121219A (en) | 2000-09-19 |
JP2002540253A (en) | 2002-11-26 |
EP1163321A1 (en) | 2001-12-19 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US6121219A (en) | Antimicrobial acid cleaner for use on organic or food soil | |
AU702565B2 (en) | Improved proteolytic enzyme cleaner | |
AU676066B2 (en) | Thickened hard surface cleaner | |
US6686325B2 (en) | Alkaline sensitive metal cleaning composition, method for cleaning an alkaline sensitive metal surface, and washing facility | |
US5861366A (en) | Proteolytic enzyme cleaner | |
EP2297290B1 (en) | Biodegradable scale control composition for use in highly concentrated alkaline detergents | |
US8802611B2 (en) | Highly concentrated caustic block for ware washing | |
JP5788880B2 (en) | Method for removing / preventing redeposits of protein soils | |
AU2001243452B2 (en) | Composition suitable for removing proteinaceous material | |
JP2000096098A (en) | Aqueous liquid cleanser | |
EP1373448B1 (en) | Removing adherent organic material | |
JP2019104793A (en) | Liquid detergent composition | |
CN114207101A (en) | Deliming composition free of personal protective equipment | |
CA2197314C (en) | Improved proteolytic enzyme cleaner | |
CN110546248A (en) | Formulations and methods for cryogenic cleaning of dairy equipment | |
JP4166319B2 (en) | Hard surface cleaning composition | |
JP2019104792A (en) | Liquid detergent composition |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AE AL AM AT AT AU AZ BA BB BG BR BY CA CH CN CR CU CZ CZ DE DE DK DK DM EE EE ES FI FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK SK SL TJ TM TR TT TZ UA UG UZ VN YU ZA ZW |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): GH GM KE LS MW SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
WWE | Wipo information: entry into national phase |
Ref document number: 2001/07760 Country of ref document: ZA Ref document number: 200107760 Country of ref document: ZA |
|
ENP | Entry into the national phase |
Ref document number: 2367719 Country of ref document: CA Kind code of ref document: A Ref document number: 2367719 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 514334 Country of ref document: NZ Ref document number: 35206/00 Country of ref document: AU |
|
ENP | Entry into the national phase |
Ref document number: 2000 606712 Country of ref document: JP Kind code of ref document: A |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2000913838 Country of ref document: EP |
|
WWP | Wipo information: published in national office |
Ref document number: 2000913838 Country of ref document: EP |
|
REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |
|
WWG | Wipo information: grant in national office |
Ref document number: 35206/00 Country of ref document: AU |
|
WWW | Wipo information: withdrawn in national office |
Ref document number: 2000913838 Country of ref document: EP |