WO2000040779A8 - Method, chemistry, and apparatus for high deposition rate solder electroplating on a microelectronic workpiece - Google Patents

Method, chemistry, and apparatus for high deposition rate solder electroplating on a microelectronic workpiece

Info

Publication number
WO2000040779A8
WO2000040779A8 PCT/US1999/015850 US9915850W WO0040779A8 WO 2000040779 A8 WO2000040779 A8 WO 2000040779A8 US 9915850 W US9915850 W US 9915850W WO 0040779 A8 WO0040779 A8 WO 0040779A8
Authority
WO
WIPO (PCT)
Prior art keywords
workpiece
electroplating
electroplating solution
deposition rate
tin
Prior art date
Application number
PCT/US1999/015850
Other languages
French (fr)
Other versions
WO2000040779A1 (en
Inventor
Robert W Batz
Scot Conrady
Thomas L Ritzdorf
Original Assignee
Semitool Inc
Robert W Batz
Scot Conrady
Thomas L Ritzdorf
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Semitool Inc, Robert W Batz, Scot Conrady, Thomas L Ritzdorf filed Critical Semitool Inc
Priority to US09/386,213 priority Critical patent/US6334937B1/en
Publication of WO2000040779A1 publication Critical patent/WO2000040779A1/en
Publication of WO2000040779A8 publication Critical patent/WO2000040779A8/en
Priority to US09/884,003 priority patent/US6669834B2/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/30Electroplating: Baths therefor from solutions of tin
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D17/00Constructional parts, or assemblies thereof, of cells for electrolytic coating
    • C25D17/001Apparatus specially adapted for electrolytic coating of wafers, e.g. semiconductors or solar cells
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D3/00Electroplating: Baths therefor
    • C25D3/02Electroplating: Baths therefor from solutions
    • C25D3/34Electroplating: Baths therefor from solutions of lead
    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25DPROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
    • C25D7/00Electroplating characterised by the article coated
    • C25D7/12Semiconductors
    • C25D7/123Semiconductors first coated with a seed layer or a conductive layer

Abstract

The invention is directed to an electroplating apparatus for selectively depositing tin/lead solder bumps at a high deposition rate. The apparatus comprises a reactor bowl (35) containing an electroplating solution having free ions of tin and lead for plating onto a workpiece (25). A chemical delivery system is used to deliver the electroplating solution to the reactor bowl at a high flow rate. A workpiece support includes a contact assembly (85) for providing electroplating power to a surface at a side of the workpiece that is to be plated. The assembly contacts the workpiece at a large plurality of discrete flexure contacts (90) that are isolated from exposure to the electroplating solution. An anode (55) is spaced from the workpiece support within the reactor assembly (20) and is in contact with the electroplating solution. The electroplating solution comprises a concentration of a lead compound, a concentration of a tin compound, water and methane sulfonic acid.
PCT/US1999/015850 1998-12-31 1999-07-12 Method, chemistry, and apparatus for high deposition rate solder electroplating on a microelectronic workpiece WO2000040779A1 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
US09/386,213 US6334937B1 (en) 1998-12-31 1999-08-31 Apparatus for high deposition rate solder electroplating on a microelectronic workpiece
US09/884,003 US6669834B2 (en) 1998-12-31 2001-06-18 Method for high deposition rate solder electroplating on a microelectronic workpiece

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11445098P 1998-12-31 1998-12-31
US60/114,450 1998-12-31

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US09/386,213 Continuation US6334937B1 (en) 1998-12-31 1999-08-31 Apparatus for high deposition rate solder electroplating on a microelectronic workpiece

Publications (2)

Publication Number Publication Date
WO2000040779A1 WO2000040779A1 (en) 2000-07-13
WO2000040779A8 true WO2000040779A8 (en) 2001-02-22

Family

ID=22355289

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1999/015850 WO2000040779A1 (en) 1998-12-31 1999-07-12 Method, chemistry, and apparatus for high deposition rate solder electroplating on a microelectronic workpiece

Country Status (3)

Country Link
US (2) US6334937B1 (en)
TW (1) TW483950B (en)
WO (1) WO2000040779A1 (en)

Families Citing this family (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6156167A (en) * 1997-11-13 2000-12-05 Novellus Systems, Inc. Clamshell apparatus for electrochemically treating semiconductor wafers
US6900132B2 (en) * 1998-03-13 2005-05-31 Semitool, Inc. Single workpiece processing system
US6423642B1 (en) * 1998-03-13 2002-07-23 Semitool, Inc. Reactor for processing a semiconductor wafer
US6228232B1 (en) 1998-07-09 2001-05-08 Semitool, Inc. Reactor vessel having improved cup anode and conductor assembly
US6497801B1 (en) * 1998-07-10 2002-12-24 Semitool Inc Electroplating apparatus with segmented anode array
US6962649B2 (en) * 1998-07-10 2005-11-08 Semitool, Inc. Contact assemblies, methods for making contact assemblies, and machines with contact assemblies for electrochemical processing of microelectronic workpieces
US6497800B1 (en) 2000-03-17 2002-12-24 Nutool Inc. Device providing electrical contact to the surface of a semiconductor workpiece during metal plating
US7204924B2 (en) * 1998-12-01 2007-04-17 Novellus Systems, Inc. Method and apparatus to deposit layers with uniform properties
US7425250B2 (en) * 1998-12-01 2008-09-16 Novellus Systems, Inc. Electrochemical mechanical processing apparatus
US7217325B2 (en) * 1999-01-22 2007-05-15 Semitool, Inc. System for processing a workpiece
US6969682B2 (en) * 1999-01-22 2005-11-29 Semitool, Inc. Single workpiece processing system
US6930046B2 (en) * 1999-01-22 2005-08-16 Semitool, Inc. Single workpiece processing system
US20030038035A1 (en) * 2001-05-30 2003-02-27 Wilson Gregory J. Methods and systems for controlling current in electrochemical processing of microelectronic workpieces
US6916412B2 (en) * 1999-04-13 2005-07-12 Semitool, Inc. Adaptable electrochemical processing chamber
US6673216B2 (en) * 1999-08-31 2004-01-06 Semitool, Inc. Apparatus for providing electrical and fluid communication to a rotating microelectronic workpiece during electrochemical processing
US6355153B1 (en) * 1999-09-17 2002-03-12 Nutool, Inc. Chip interconnect and packaging deposition methods and structures
JP2001188254A (en) * 1999-10-21 2001-07-10 Matsushita Electric Ind Co Ltd Selective electrochemical processor within substrate, selective chemical processor within substrate, and examination and correction method of active substrate
DE19962170A1 (en) * 1999-12-22 2001-07-12 Steag Micro Tech Gmbh Sub-beam holder
US6852208B2 (en) 2000-03-17 2005-02-08 Nutool, Inc. Method and apparatus for full surface electrotreating of a wafer
US20050109627A1 (en) * 2003-10-10 2005-05-26 Applied Materials, Inc. Methods and chemistry for providing initial conformal electrochemical deposition of copper in sub-micron features
US20050145499A1 (en) * 2000-06-05 2005-07-07 Applied Materials, Inc. Plating of a thin metal seed layer
US6921551B2 (en) * 2000-08-10 2005-07-26 Asm Nutool, Inc. Plating method and apparatus for controlling deposition on predetermined portions of a workpiece
US7754061B2 (en) * 2000-08-10 2010-07-13 Novellus Systems, Inc. Method for controlling conductor deposition on predetermined portions of a wafer
JP4656275B2 (en) * 2001-01-15 2011-03-23 日本電気株式会社 Manufacturing method of semiconductor device
US6869515B2 (en) 2001-03-30 2005-03-22 Uri Cohen Enhanced electrochemical deposition (ECD) filling of high aspect ratio openings
US7189647B2 (en) 2001-04-05 2007-03-13 Novellus Systems, Inc. Sequential station tool for wet processing of semiconductor wafers
JP2002332597A (en) * 2001-05-11 2002-11-22 Tokyo Electron Ltd Solution treatment apparatus and solution treatment method
US7118658B2 (en) * 2002-05-21 2006-10-10 Semitool, Inc. Electroplating reactor
TW567545B (en) * 2002-06-04 2003-12-21 Merck Kanto Advanced Chemical Electropolishing electrolytic solution formulation
US6875331B2 (en) 2002-07-11 2005-04-05 Applied Materials, Inc. Anode isolation by diffusion differentials
US20040134775A1 (en) * 2002-07-24 2004-07-15 Applied Materials, Inc. Electrochemical processing cell
US7128823B2 (en) 2002-07-24 2006-10-31 Applied Materials, Inc. Anolyte for copper plating
US7223323B2 (en) * 2002-07-24 2007-05-29 Applied Materials, Inc. Multi-chemistry plating system
US7247222B2 (en) * 2002-07-24 2007-07-24 Applied Materials, Inc. Electrochemical processing cell
US20040217005A1 (en) * 2002-07-24 2004-11-04 Aron Rosenfeld Method for electroplating bath chemistry control
US20040084318A1 (en) * 2002-11-05 2004-05-06 Uri Cohen Methods and apparatus for activating openings and for jets plating
US20040154926A1 (en) * 2002-12-24 2004-08-12 Zhi-Wen Sun Multiple chemistry electrochemical plating method
JP4303484B2 (en) * 2003-01-21 2009-07-29 大日本スクリーン製造株式会社 Plating equipment
US20040200725A1 (en) * 2003-04-09 2004-10-14 Applied Materials Inc. Application of antifoaming agent to reduce defects in a semiconductor electrochemical plating process
US7473339B2 (en) * 2003-04-18 2009-01-06 Applied Materials, Inc. Slim cell platform plumbing
US7727366B2 (en) * 2003-10-22 2010-06-01 Nexx Systems, Inc. Balancing pressure to improve a fluid seal
JP4642771B2 (en) 2003-10-22 2011-03-02 ネックス システムズ インコーポレイテッド Method and apparatus for fluid processing a workpiece
US7648622B2 (en) * 2004-02-27 2010-01-19 Novellus Systems, Inc. System and method for electrochemical mechanical polishing
US20050283993A1 (en) * 2004-06-18 2005-12-29 Qunwei Wu Method and apparatus for fluid processing and drying a workpiece
KR100651919B1 (en) * 2005-09-29 2006-12-01 엘지전자 주식회사 Mobile telecommunication device having function for adjusting recording rate and method thereby
EP1839695A1 (en) * 2006-03-31 2007-10-03 Debiotech S.A. Medical liquid injection device
US8500985B2 (en) * 2006-07-21 2013-08-06 Novellus Systems, Inc. Photoresist-free metal deposition
US20080237048A1 (en) * 2007-03-30 2008-10-02 Ismail Emesh Method and apparatus for selective electrofilling of through-wafer vias
US20090065365A1 (en) * 2007-09-11 2009-03-12 Asm Nutool, Inc. Method and apparatus for copper electroplating
US8741765B2 (en) * 2011-03-31 2014-06-03 Globalfoundries Inc. Controlled electroplated solder bumps
KR102233334B1 (en) * 2014-04-28 2021-03-29 삼성전자주식회사 Tin plating solution, Tin plating equipment and method for fabricating semiconductor device using the tin plating solution
EP3318083A1 (en) * 2015-06-30 2018-05-09 Telefonaktiebolaget LM Ericsson (publ) Dynamic mobile network architecture
CN109950155A (en) * 2017-12-21 2019-06-28 海太半导体(无锡)有限公司 A kind of backside of wafer tin plating technique and device

Family Cites Families (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3716462A (en) 1970-10-05 1973-02-13 D Jensen Copper plating on zinc and its alloys
US3930963A (en) 1971-07-29 1976-01-06 Photocircuits Division Of Kollmorgen Corporation Method for the production of radiant energy imaged printed circuit boards
DE2244434C3 (en) 1972-09-06 1982-02-25 Schering Ag, 1000 Berlin Und 4619 Bergkamen Aqueous bath for the galvanic deposition of gold and gold alloys
US4137867A (en) 1977-09-12 1979-02-06 Seiichiro Aigo Apparatus for bump-plating semiconductor wafers
US4341629A (en) 1978-08-28 1982-07-27 Sand And Sea Industries, Inc. Means for desalination of water through reverse osmosis
US4220506A (en) * 1978-12-11 1980-09-02 Bell Telephone Laboratories, Incorporated Process for plating solder
US4246088A (en) 1979-01-24 1981-01-20 Metal Box Limited Method and apparatus for electrolytic treatment of containers
SU921124A1 (en) 1979-06-19 1982-04-15 Институт Физико-Химических Основ Переработки Минерального Сырья Со Ан Ссср Method of metallization of printed circuit board apertures
US4422915A (en) 1979-09-04 1983-12-27 Battelle Memorial Institute Preparation of colored polymeric film-like coating
US4259166A (en) 1980-03-31 1981-03-31 Rca Corporation Shield for plating substrate
US4304641A (en) 1980-11-24 1981-12-08 International Business Machines Corporation Rotary electroplating cell with controlled current distribution
US4466864A (en) 1983-12-16 1984-08-21 At&T Technologies, Inc. Methods of and apparatus for electroplating preselected surface regions of electrical articles
US4565609A (en) 1983-12-22 1986-01-21 Learonal, Inc. Bath and process for plating tin, lead and tin-lead alloys
US4565610A (en) 1983-12-22 1986-01-21 Learonal, Inc. Bath and process for plating lead and lead/tin alloys
US4701244A (en) * 1983-12-22 1987-10-20 Learonal, Inc. Bath and process for electroplating tin, lead and tin/alloys
US4617097A (en) 1983-12-22 1986-10-14 Learonal, Inc. Process and electrolyte for electroplating tin, lead or tin-lead alloys
DE3500005A1 (en) 1985-01-02 1986-07-10 ESB Elektrostatische Sprüh- und Beschichtungsanlagen G.F. Vöhringer GmbH, 7758 Meersburg COATING CABIN FOR COATING THE SURFACE OF WORKPIECES WITH COATING POWDER
US4685414A (en) 1985-04-03 1987-08-11 Dirico Mark A Coating printed sheets
US4576685A (en) 1985-04-23 1986-03-18 Schering Ag Process and apparatus for plating onto articles
US4959278A (en) 1988-06-16 1990-09-25 Nippon Mining Co., Ltd. Tin whisker-free tin or tin alloy plated article and coating technique thereof
US4849059A (en) 1988-09-13 1989-07-18 Macdermid, Incorporated Aqueous electroplating bath and method for electroplating tin and/or lead and a defoaming agent therefor
GB8911566D0 (en) * 1989-05-19 1989-07-05 Sun Ind Coatings Plating system
CA2035970C (en) 1990-02-09 1999-06-01 Eiji Hirai Process for surface treating titanium-containing metallic material
US5135636A (en) 1990-10-12 1992-08-04 Microelectronics And Computer Technology Corporation Electroplating method
US5271953A (en) 1991-02-25 1993-12-21 Delco Electronics Corporation System for performing work on workpieces
US5194137A (en) * 1991-08-05 1993-03-16 Motorola Inc. Solder plate reflow method for forming solder-bumped terminals
US5209817A (en) 1991-08-22 1993-05-11 International Business Machines Corporation Selective plating method for forming integral via and wiring layers
US5399564A (en) 1991-09-03 1995-03-21 Dowelanco N-(4-pyridyl or 4-quinolinyl) arylacetamide and 4-(aralkoxy or aralkylamino) pyridine pesticides
JP2734269B2 (en) * 1991-12-26 1998-03-30 日本電気株式会社 Semiconductor manufacturing equipment
JP2888001B2 (en) 1992-01-09 1999-05-10 日本電気株式会社 Metal plating equipment
US5698087A (en) 1992-03-11 1997-12-16 Mcgean-Rohco, Inc. Plating bath and method for electroplating tin and/or lead
JP3200468B2 (en) * 1992-05-21 2001-08-20 日本エレクトロプレイテイング・エンジニヤース株式会社 Wafer plating equipment
US5227041A (en) * 1992-06-12 1993-07-13 Digital Equipment Corporation Dry contact electroplating apparatus
JPH0625899A (en) 1992-07-10 1994-02-01 Nec Corp Electroplating device
US5372848A (en) 1992-12-24 1994-12-13 International Business Machines Corporation Process for creating organic polymeric substrate with copper
US5296128A (en) 1993-02-01 1994-03-22 Technic Inc. Gallic acid as a combination antioxidant, grain refiner, selective precipitant, and selective coordination ligand, in plating formulations
JP3308333B2 (en) 1993-03-30 2002-07-29 三菱電機株式会社 Electroplating apparatus and electrolytic plating method
US5282953A (en) 1993-06-28 1994-02-01 Technic Incorporated Polyoxyalklene compounds terminated with ketone groups for use as surfactants in alkanesulfonic acid based solder plating baths
JP3377849B2 (en) * 1994-02-02 2003-02-17 日本エレクトロプレイテイング・エンジニヤース株式会社 Wafer plating equipment
US5391285A (en) * 1994-02-25 1995-02-21 Motorola, Inc. Adjustable plating cell for uniform bump plating of semiconductor wafers
DE9404771U1 (en) 1994-03-21 1994-06-30 Thyssen Aufzuege Gmbh Locking device
US5651873A (en) 1994-06-30 1997-07-29 Mitsubishi Materials Corporation Electroplating solution for forming Pb-Sn alloy bump electrodes on semiconductor wafer surface
US5472592A (en) 1994-07-19 1995-12-05 American Plating Systems Electrolytic plating apparatus and method
US5625233A (en) 1995-01-13 1997-04-29 Ibm Corporation Thin film multi-layer oxygen diffusion barrier consisting of refractory metal, refractory metal aluminide, and aluminum oxide
US5549808A (en) 1995-05-12 1996-08-27 International Business Machines Corporation Method for forming capped copper electrical interconnects
US5670034A (en) 1995-07-11 1997-09-23 American Plating Systems Reciprocating anode electrolytic plating apparatus and method
US5807469A (en) * 1995-09-27 1998-09-15 Intel Corporation Flexible continuous cathode contact circuit for electrolytic plating of C4, tab microbumps, and ultra large scale interconnects
US5597460A (en) 1995-11-13 1997-01-28 Reynolds Tech Fabricators, Inc. Plating cell having laminar flow sparger
US5620581A (en) 1995-11-29 1997-04-15 Aiwa Research And Development, Inc. Apparatus for electroplating metal films including a cathode ring, insulator ring and thief ring
US5747098A (en) 1996-09-24 1998-05-05 Macdermid, Incorporated Process for the manufacture of printed circuit boards
US5904827A (en) 1996-10-15 1999-05-18 Reynolds Tech Fabricators, Inc. Plating cell with rotary wiper and megasonic transducer
US5776327A (en) 1996-10-16 1998-07-07 Mitsubishi Semiconuctor Americe, Inc. Method and apparatus using an anode basket for electroplating a workpiece
US5788829A (en) 1996-10-16 1998-08-04 Mitsubishi Semiconductor America, Inc. Method and apparatus for controlling plating thickness of a workpiece
US5843296A (en) 1996-12-26 1998-12-01 Digital Matrix Method for electroforming an optical disk stamper
US6001235A (en) 1997-06-23 1999-12-14 International Business Machines Corporation Rotary plater with radially distributed plating solution
US6017437A (en) * 1997-08-22 2000-01-25 Cutek Research, Inc. Process chamber and method for depositing and/or removing material on a substrate
US6159354A (en) 1997-11-13 2000-12-12 Novellus Systems, Inc. Electric potential shaping method for electroplating
US6156167A (en) 1997-11-13 2000-12-05 Novellus Systems, Inc. Clamshell apparatus for electrochemically treating semiconductor wafers
US5932077A (en) 1998-02-09 1999-08-03 Reynolds Tech Fabricators, Inc. Plating cell with horizontal product load mechanism
US6080291A (en) 1998-07-10 2000-06-27 Semitool, Inc. Apparatus for electrochemically processing a workpiece including an electrical contact assembly having a seal member
JP4766579B2 (en) 1998-11-30 2011-09-07 アプライド マテリアルズ インコーポレイテッド Electrochemical deposition equipment

Also Published As

Publication number Publication date
US20020000378A1 (en) 2002-01-03
US6669834B2 (en) 2003-12-30
WO2000040779A1 (en) 2000-07-13
TW483950B (en) 2002-04-21
US6334937B1 (en) 2002-01-01

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