WO1999056914A1 - Abrasive articles having abrasive layer bond system derived from solid, dry-coated binder presursor particles having a fusible, radiation curable component - Google Patents
Abrasive articles having abrasive layer bond system derived from solid, dry-coated binder presursor particles having a fusible, radiation curable component Download PDFInfo
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- WO1999056914A1 WO1999056914A1 PCT/US1999/006962 US9906962W WO9956914A1 WO 1999056914 A1 WO1999056914 A1 WO 1999056914A1 US 9906962 W US9906962 W US 9906962W WO 9956914 A1 WO9956914 A1 WO 9956914A1
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- abrasive
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D11/00—Constructional features of flexible abrasive materials; Special features in the manufacture of such materials
- B24D11/001—Manufacture of flexible abrasive materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D11/00—Constructional features of flexible abrasive materials; Special features in the manufacture of such materials
- B24D11/001—Manufacture of flexible abrasive materials
- B24D11/005—Making abrasive webs
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/02—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
- B24D3/20—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially organic
- B24D3/28—Resins or natural or synthetic macromolecular compounds
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/34—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties
- B24D3/342—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties incorporated in the bonding agent
- B24D3/344—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties incorporated in the bonding agent the bonding agent being organic
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
- Y10T428/24372—Particulate matter
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24355—Continuous and nonuniform or irregular surface on layer or component [e.g., roofing, etc.]
- Y10T428/24372—Particulate matter
- Y10T428/24413—Metal or metal compound
Definitions
- ABRASIVE ARTICLES HAVING ABRASIVE LAYER BOND SYSTEM DERIVED FROM SOLID, DRY-COATED BINDER PRECURSOR PARTICLES
- This invention is in the field of abrasive articles. More specifically, this invention relates to abrasive articles in which a powder of fusible particles is dry coated, liquefied, and then cured to form at least a portion of the bond system of the abrasive article.
- Coated abrasive articles generally comprise a backing to which a multiplicity of abrasive particles are bonded by a suitable bond system.
- a common type of bond system includes a make coat, a size coat, and optionally a supersize coat.
- the make coat includes a tough, resilient polymer binder that adheres the abrasive particles to the backing.
- the size coat also including a tough resilient polymer binder that may be the same or different from the make coat binder, is applied over the make coat to reinforce the particles.
- the supersize coat including one or more antiloading ingredients or perhaps grinding aids, may then be applied over the size coat if desired.
- the ingredients that are used to form the make coat are dispersed or dissolved, as the case may be, in a sufficient amount of a solvent, which may be aqueous or nonaqueous, to provide the make coat formulation with a coatable viscosity.
- the fluid formulation is then coated onto the backing, after which the abrasive particles are applied to the make coat formulation.
- the make coat formulation is then dried to remove the solvent and at least partially cured.
- the ingredients that are used to form the size coat are also dispersed in a solvent, and the resultant fluid formulation is then applied over the make coat and abrasive particles, dried and cured.
- a similar technique is then used to apply the supersize coat over the size coat.
- Typical make and size coat formulations may include 10 to 50 weight percent of solvent.
- Supersize coating formulations require even more solvent in order to form useful coatings having the desired coating weight and viscosity.
- Solvents can be expensive to purchase and/or to handle properly. Solvents also must be removed from the coatings, involving substantial drying costs in terms of capital equipment, energy costs, and cycle time. There are also further costs and environmental concerns associated with solvent recovery or disposal. Solvent-based coating formulations also typically require coating methods involving contact with underlying layers at the time of coating. Such contact can disrupt the orientation of the coated abrasive particles, adversely affecting abrading performance.
- a coating is formed by dry coating a powder of extremely fine, curable binder particles onto a suitable backing, melting the coated powder so that the particles fuse together to form a uniform melt layer, and then curing the melt layer to form a solid, thermoset, binder matrix.
- PCT patent publication WO 97/25185 describes forming a binder for abrasive particles from dry powders.
- the dry powders comprise thermally curable phenolic resins that are dry coated onto a suitable backing. After coating, the particles are melted. Abrasive particles are then applied to the melted formulation. The melted formulation is then thermally cured to form a solid, make coat binder matrix.
- a size coat may be applied in the same way.
- the make and size coats are formed without any solvent, and the size coat powder may be deposited without contacting, and hence disrupting, the underlying abrasive particles.
- the powders described in this document incorporate resins that are thermally cured.
- the use of such resins poses substantial challenges during manufacture.
- Thermally cured resins generally tend to be highly viscous at reasonable processing temperatures, and thus are difficult to get to flow well. This makes it somewhat challenging to cause the binder particles to melt and fuse together in a uniform manner.
- the thermally curable resins also typically require relatively high temperatures to achieve curing. This limits the kinds of materials that can be incorporated into an abrasive article. In particular, many kinds of otherwise desirable backing materials could be damaged or degraded upon exposure to the temperatures required for curing. It is also difficult to control the start and rate of
- the powder is in the form of a multiplicity of binder precursor particles comprising a radiation curable component.
- the powder comprises at least one metal salt of a fatty acid and optionally an organic component that may be a thermoplastic macromolecule, a radiation curable component, and/or a thermally curable macromolecule.
- the powder exists as a solid under the desired dry coating conditions, but is easily melted at relatively low temperatures and then solidified also at reasonably low processing temperatures.
- the principles of the present invention can be applied to form make coats, size coats, and/or supersize coats, as desired.
- the present invention offers several advantages. Firstly, because melting and curing occur at relatively low temperatures, abrasive articles prepared in accordance with the present invention can be used with a wider range of other components, for example, backing materials, that otherwise would be damaged at higher temperatures. The ability to use lower processing temperatures also means that the present invention has lower energy demands, making the invention more efficient and economical in terms of energy costs. Additionally, the powder coatings can be applied at 100% solids with no solvent whatsoever.
- Powder coating is a noncontact coating method. Unlike many solvent coating techniques, for example, roll coating or the like, powder coating methods are noncontact and, therefore, avoid the kind of coating contact that might otherwise disrupt coated abrasive particles. This advantage is most noticeable when applying size and supersize coats over underlying make coat and abrasive particles. Powder coating methods are versatile and can be applied to a broad range of materials.
- dry powder particles comprising a radiation curable component and/or a metal salt of a fatty acid is particularly advantageous in that excellent control is
- the binder particles of the present invention comprising a radiation curable component can be formed using low molecular weight, radiation curable materials that have relatively low viscosity when melted, providing much better flow and fusing characteristics than thermally curable, resinous counterparts.
- the present invention relates to an abrasive article comprising a plurality of abrasive particles incorporated into a bond system, wherein at least a portion of the bond system comprises a cured binder matrix derived from ingredients comprising a plurality of solid, binder precursor particles, said binder precursor particles comprising a radiation curable component that is fluidly flowable at a temperature in the range from about 35 °C to about 180 °C.
- the present invention relates to a method of forming an abrasive article, comprising the steps of (a) incorporating a plurality of abrasive particles into a bond system; and (b) deriving at least a portion of the bond system from a plurality of solid, binder precursor particles, said binder precursor particles comprising a radiation curable component that is fluidly flowable at a temperature in the range from about 35 °C to about 180 °C.
- the present invention provides a powder, comprising a radiation curable component that is a solid at temperatures below about 35 °C and is fluidly flowable at a temperature in the range from about 35 °C to about 180 °C.
- the present invention also provides a fusible powder, comprising 100 parts by weight of a metal salt of a fatty acid and 0 to 35 parts by weight of a fusible organic component.
- the present invention also relates to a method of forming a supersize coating on an underlying abrasive layer of an abrasive article.
- a fusible powder is dry coated onto the abrasive layer, wherein the fusible powder comprises at least one metal salt of a fatty acid.
- the fusible powder is liquefied to form a supersize melt layer.
- the supersize melt layer is solidified, whereby the supersize coating is formed.
- cured binder matrix refers to a matrix comprising a crosslinked, polymer network in which chemical linkages exist between polymer chains.
- a preferred cured binder matrix is generally insoluble in solvents in which the corresponding, crosslinkable binder precursor(s) is readily soluble.
- binder precursor refers to monomeric, oligomeric, and/or polymeric materials having pendant functionality allowing the precursors to be crosslinked to form the corresponding cured binder matrix.
- the cured binder matrix of the present invention may be in the form of an interpenetrating polymer network (LPN) in which the binder matrix includes separately crosslinked, but entangled networks of polymer chains.
- LPN interpenetrating polymer network
- the cured binder matrix may be in the form of a semi-IPN comprising uncrosslinked components, for example, thermoplastic oligomers or polymers that generally do not participate in crosslinking reactions, but nonetheless are entangled in the network of crosslinked polymer chains.
- macromolecule shall refer to an oligomer, a polymer, and combinations thereof.
- Fig. 1 is a sectional side view of a coated abrasive article according to one embodiment of the present invention.
- Fig. 2 schematically shows a reaction scheme for making one kind of radiation curable monomer suitable in the practice of the present invention.
- Fig. 3 is a preferred embodiment of radiation curable monomer prepared using the reaction scheme of Fig. 2.
- Fig. 4 schematically shows a reaction scheme for making another class of radiation curable monomer suitable in the practice of the present invention.
- Fig. 5 is a preferred embodiment of radiation curable monomer prepared using the reaction scheme of Fig. 4.
- Fig. 6 is a preferred embodiment of another radiation curable monomer of the present invention.
- Fig. 7 schematically shows a reaction scheme for making the class of radiation curable monomers including the monomer of Fig. 6.
- - 5 - Fig. 8 A is a preferred embodiment of another radiation curable monomer of the present invention.
- Fig. 8B is a cyanate ester novolak oligomer suitable in the practice of the present invention.
- Fig. 9 shows a general formula for a metal salt of a fatty acid suitable in the practice of the present invention.
- Fig. 10 shows the formula for one embodiment of a radiation curable novolak type phenolic oligomer suitable in the practice of the present invention.
- Fig. 11 shows a formula for one type of a radiation curable epoxy oligomer suitable in the practice of the present invention.
- Fig. 12 is a schematic representation of an apparatus for making a coated abrasive of the present invention having make, size and supersize coatings.
- the radiation curable, fusible binder precursor particles of the present invention may be incorporated into a wide range of different kinds of abrasive articles with beneficial results.
- the radiation curable, fusible binder precursor particles will be described with respect to the particular flexible, coated abrasive article 10 illustrated in Fig. 1.
- the embodiments of the present invention described in connection with Fig. 1 are not intended to be exhaustive or to limit the invention to the precise forms disclosed in the following detailed description. Rather the embodiments are chosen and described so that others skilled in the art may appreciate and understand the principles and practices of the present invention.
- Abrasive article 10 generally includes backing 12 and abrasive layer 14 bonded to backing 12.
- Backing 12 may be any suitable backing and typically may be comprised of paper, vulcanized rubber, a polymeric film (primed or unprimed), a woven or nonwoven fibrous material, composites of these, and the like.
- Backings made from paper typically may have a basis weight in the range from 25 g/m ⁇ to 300 g/m ⁇ or more.
- Backings made from paper or fibrous materials optionally may be treated with a presize, backsize, and or saturant coating in accordance with conventional practices.
- Specific materials suitable for use as backing 12 are well known in the art and have been described, for example, in U.S. Patent Nos. 5,436,063; 4,991,362; and 2,958,593.
- Abrasive coating 14 includes a plurality of abrasive particles 16 functionally distributed in bond system 18 generally comprising make coat 20, size coat 22, and optional supersize coat 24.
- Abrasive particles 16 may comprise any suitable abrasive material or combination of materials having abrading capabilities.
- Abrasive particles 16 preferably comprise at least one material having a Mohs hardness of at least about 8, more preferably at least about 9.
- abrasive particles 16 may include a surface coating to enhance the performance of the particles in accordance with conventional practices.
- the surface coating can be formed from a material, such as a silane coupling agent, that increases adhesion between abrasive particles 16 and the binders used in make coat 20, size coat 22, and/or supersize coat 24.
- Abrasive particles 16 can be present in any suitable size(s) and shape(s).
- preferred abrasive particles 16 typically have an average size in the range from about 0.1 micrometers to 2500 micrometers, more preferably from about 1 micrometer to 1300 micrometers.
- Abrasive particles 16 may also have any shape suitable for carrying out abrading operations. Examples of such shapes include rods, triangles, pyramids, cones, solid spheres, hollow spheres, combinations of these, and the like.
- Abrasive particles 16 may be present in substantially nonagglomerated form or, alternatively, may be in the form of abrasive agglomerates in which individual particles are adhered together. Examples of abrasive agglomerates are described in U.S. Patent No. 4,652,275 and U.S. Patent No. 4,799,939.
- Make coat 20 helps adhere abrasive particles 16 to backing 12.
- Size coat 22 is applied over make coat 20 and abrasive particles 16 in order to reinforce particles 16.
- Optional supersize coat 24 may be included over size coat 22 in order to prevent or reduce the accumulation of swarf (the material abraded from a workpiece) among abrasive particles 16 during abrading operations.
- supersize coat 24 may also be included over size coat 22 in order to incorporate grinding aids into abrasive article 10. Supersize coatings are further described in European Patent Publication No. 486, 308.
- At least portions of one or more of make coat 20, size coat 22, and/or supersize coat 24 constituting bond system 18 comprise a cured binder matrix derived from the binder precursor particles of the present invention.
- the binder precursor particles of the present invention generally include a radiation curable component that may be formed from any one or more radiation curable, fusible materials that can be dry coated in particulate form, then liquefied to convert the precursor material into a fluid, melt layer, and then cured by exposure to a suitable source of curing energy to convert the fluid melt layer into a thermoset, solid, cured binder matrix component of bond system 18.
- a radiation curable component that may be formed from any one or more radiation curable, fusible materials that can be dry coated in particulate form, then liquefied to convert the precursor material into a fluid, melt layer, and then cured by exposure to a suitable source of curing energy to convert the fluid melt layer into a thermoset, solid, cured binder matrix component of bond system 18.
- radiation curable refers to functionality directly or indirectly pendant from a monomer, oligomer, or polymer backbone (as the case may be) that participate in crosslinking reactions upon exposure to a suitable source of curing energy.
- Such functionality generally includes not only groups that crosslink via a cationic mechanism upon radiation exposure but also groups that crosslink via a free radical mechanism.
- Representative examples of radiation crosslinkable groups suitable in the practice of the present invention include epoxy groups, (meth)acrylate groups, olefmic carbon-carbon double bonds, allyloxy groups, alpha-methyl styrene groups, (meth)acrylamide groups, cyanate ester groups, vinyl ethers groups, combinations of these, and the like.
- the energy source used for achieving crosslinking of the radiation curable functionality may be actinic (for example, radiation having a wavelength in the ultraviolet or visible region of the spectrum), accelerated particles (for example, electron beam radiation), thermal (for example, heat or infrared radiation), or the like.
- the energy is actinic radiation or accelerated particles, because such energy provides excellent control over the initiation and rate of crosslinking.
- actinic radiation and accelerated particles can be used for curing at relatively low temperatures. This avoids degrading components of abrasive article 10 that might be sensitive to the relatively high temperatures that might be required to initiate crosslinking of the radiation curable groups when using thermal curing techniques.
- Suitable sources of actinic radiation include a mercury lamp, a xenon lamp, a carbon arc lamp, a tungsten filament lamp, sunlight, and the like. Ultraviolet radiation, especially from a medium pressure mercury arc lamp, is most preferred.
- the amount of curing energy to be used for curing depends upon a number of factors, such as the amount and the type of reactants involved, the energy source, web speed, the distance from the energy source, and the thickness of the bond layer to be cured. Generally, the rate of curing tends to increase with increased energy intensity. The rate of curing also may tend to increase with increasing amounts of photocatalyst and/or photoinitiator being present in the composition.
- actinic radiation typically involves a total energy exposure from about 0.1 to about 10 J/cm ⁇
- electron beam radiation typically involves a total energy exposure in the range from less than 1 Megarad to 100 Megarads or more, preferably 1 to 10 Mrads. Exposure times may be from less than about 1 second up to 10 minutes or more. Radiation exposure may occur in air or in an inert atmosphere such as nitrogen.
- the particle size of the binder precursor particles of the present invention is not particularly limited so long as the particles can be adequately fused and then cured to form desired portions of bond system 18 with the desired level of uniformity and performance. If the particles are too big, it is more difficult to control the uniformity of coating thickness. Larger particles are also not as free flowing as smaller particles. Therefore, particles with a smaller average particle size such that the particles are in the form of a free flowing powder are preferred. However, extremely small particles may pose a safety hazard. Additionally, control over coating thickness also may become more difficult when using extremely small particles. Accordingly, as general guidelines, preferred binder precursor particles generally have an average particle size of less than about 500 micrometers, preferably less than about 125 micrometers, and more preferably 10 to 90 micrometers. In the practice of the present invention, the average particle size of the particles may be determined by laser diffraction using an instrument commercially available under the trade designation "HORLBA LA-910" from Horiba Ltd.
- the radiation curable component of the fusible binder precursor particles comprises one or more radiation curable monomers, oligomers, and/or polymers that, at least in combination, exist as a solid at about room temperature, for example, 20 °C to about 25 °C, to facilitate dry coating
- oligomer refers to a compound that is a combination of 2 to 20 monomer units.
- polymer refers to a compound that is a combination of 21 or more monomer units.
- the radiation curable component may exist as a solid only at relatively cool temperatures below ambient conditions. However, such embodiments would involve carrying out dry coating at correspondingly cool temperatures to ensure that the radiation curable component was solid during dry coating. Similarly, in other alternative embodiments of the invention, the radiation curable component may exist as a solid up to higher temperatures above about 180 °C. However, such embodiments would involve carrying out melting and curing at correspondingly higher temperatures as well, which could damage other, temperature sensitive components of abrasive article 10.
- any radiation curable monomer, oligomer, and/or polymer, or combinations thereof, that is solid under the desired dry coating conditions and that may be melted under the desired melt processing conditions may be incorporated into the radiation curable component. Accordingly, the present invention is not intended to be limited to specific kinds of radiation curable monomers, oligomers, and polymers so long as these processing conditions are satisfied.
- particularly preferred radiation curable components that have excellent flow characteristics when liquefied generally comprise at least one polyfunctional, radiation curable monomer and at least one polyfunctional, radiation curable macromolecule (that is, an oligomer or polymer, preferably an oligomer), wherein at least one of the monomer and/or the macromolecule has a solid to nonsolid phase transition at a sufficiently high temperature such that the combination of the monomer and macromolecule is a solid below about 35 °C, but is liquefied at a temperature in the range from about 35 °C to about 180 °C, preferably
- radiation curable components comprising one or more monomers and one or more oligomers are preferred over embodiments including polymers.
- Blends of oligomers and monomers tend to have lower viscosity and better flow characteristics at lower temperatures, thus easing melting and fusing of the particles during processing.
- representative embodiments of radiation curable components suitable in the practice of the present invention include the following components:
- a solid blend including 10 to 90 parts by weight of a solid, radiation curable, polyfunctional monomer and 10 to 90 parts by weight of a solid, radiation curable, polyfunctional macromolecule
- a solid blend including 10 to 80 parts by weight of a liquid, radiation curable, polyfunctional monomer and 10 to 80 parts by weight of a solid, radiation curable, polyfunctional macromolecule
- a solid blend comprising 0.1 to 10 parts by weight of a liquid, radiation curable, polyfunctional monomer and 100 parts by weight of a metal salt of a fatty acid (make coat and/or size coat)
- a solid blend comprising 0 to 30 parts by weight of a solid, radiation curable, polyfunctional macromolecule and 100 parts by weight of a metal salt of a fatty acid (supersize coat)
- the solid to nonsolid phase transition is typically the melting point of the monomer.
- the solid to nonsolid phase transition is typically the glass transition temperature of the macromolecule. In the practice of the present invention, glass transition temperature,
- Tg is determined using differential scanning calorimetry (DSC) techniques.
- polyfunctional with respect to the monomer or macromolecule means that the material comprises, on average, more than 1 radiation curable group, preferably two or more radiation curable groups, per molecule. Polyfunctional monomers, oligomers, and polymers cure quickly into a crosslinked network due to the multiple radiation curable groups available on each molecule. Further, polyfunctional materials are preferred in this invention to encourage and promote polymeric network formation in order to provide bond system 18 with toughness and resilience.
- Preferred monomers, oligomers, and polymers of the present invention are aromatic and/or heterocyclic.
- Aromatic and/or heterocyclic materials generally tend to be thermally stable when melt processed and also tend to have melting point and/or Tg characteristics in the preferred temperature ranges noted above.
- at least one of the monomer and the macromolecule, preferably the macromolecule further comprises OH, that is, hydroxyl, functionality. While not wishing to be bound by theory, it is believed that the OH functionality helps promote adhesion between abrasive particles 16 and the corresponding portion of bond system 18.
- the macromolecule includes, on average, 0.1 to 1 OH groups per monomeric unit incorporated into the macromolecule.
- Fig. 2 schematically shows reaction scheme 30 by which hydroxyl functional (meth)acrylate reactant 32 reacts with dicarboxylic acid reactant 34 to form radiation curable, poly(meth)acrylate functional polyester monomer 36.
- the moiety W of reactant 34 desirably comprises an aromatic moiety for the reasons described above.
- the moiety Z is any suitable divalent linking group. Any kinds of hydroxyl functional (meth)acrylate reactant 32 and such aromatic
- - 12 - dicarboxylic acid reactant 34 may be reacted together so long as the resultant radiation curable component is a solid under the desired dry coating conditions and has a melting point in the desired processing range.
- hydroxyl functional (meth)acrylate reactant 32 include hydroxyethyl acrylate, hydroxyethyl methacrylate, hydroxybutyl acrylate, hydroxybutyl methacrylate, combinations of these, and the like.
- aromatic dicarboxylic acid reactant 34 include terephthalic acid, isophthalic acid, phthalic acid, combinations of these, and the like. Although reactant 34 is shown as a dicarboxylic acid, an acid dihalide, diester, or the like could be used instead.
- the moiety X in monomer 36 is a divalent linking group typically identical to Z.
- R is hydrogen or a lower alkyl group of 1 to 4 carbon atoms, preferably -H or -CH3.
- Fig. 3 shows a particularly preferred embodiment of a radiation curable monomer 38 prepared in accordance with the reaction scheme of Fig. 2.
- Radiation curable monomer 38 has a melting point of 97 °C.
- the radiation curable monomers 36 and 38 of Figs. 2 and 3, and methods of making such monomers are further described in U.S. Patent No. 5,523,152.
- FIG. 4 Another representative class of monomers in the form of radiation curable vinyl ether monomer 40 suitable in the practice of the present invention is shown as the product in Fig. 4 of a reaction between diisocyanate reactant 42 and hydroxyl functional vinyl ether reactant 44.
- the moiety W' desirably includes an aromatic moiety in the backbone for the reasons described above, and Z' is a suitable divalent linking group.
- R is as defined above in Fig 2. Any kinds of hydroxyl functional vinyl ether reactant 44 and diisocyante reactant 42 may be reacted together so long as the resultant radiation curable component is a solid under the desired dry coating conditions and has a melting point in the desired processing range.
- diisocyanate reactant 42 include diphenylmethane-4, 4- diisocyanate, toluene diisocyanate, combinations of these, and the like.
- Fig. 5 shows a particularly preferred embodiment of a radiation curable vinyl ether monomer 50 prepared in accordance with the reaction scheme of Fig. 4. Radiation curable vinyl ether monomer 50 has a melting point of 60 - 65 °C.
- Fig. 6 shows another example of a suitable radiation curable, aromatic monomer 60 commonly referred to in the art as tris (2 -hydroxyethyl) isocyanurate triacrylate, or "TATHEIC" for short.
- This monomer has a melting point in the range from 35 °C to 40 °C.
- the TATHEIC monomer is generally formed by reaction scheme 70 of Fig. 7 in which hydroxyl functional isocyanurate 72 is reacted with carboxylic acid 74 to form acrylated isocyanurate 76.
- the X" moiety may be any suitable divalent linking group such as -CH 2 CH 2 - or the like.
- the acrylate form is shown in Fig. 6, but monomer 60 could be a methacrylate or the like as well.
- Fig. 8 A shows another example of a radiation curable, aromatic monomer in the form of an aromatic cyanate ester 80. This monomer has a melting point of 78 °C to
- Preferred radiation curable oligomers of the present invention generally have a number average molecular weight in the range from about 400 to 5000, preferably about 800 to about 2500 and either are solid at ambient conditions, or if not solid under ambient conditions, nonetheless form solid blends in combination with other ingredients of the radiation curable component.
- radiation curable oligomers of the present invention generally have a number average molecular weight in the range from about 400 to 5000, preferably about 800 to about 2500 and either are solid at ambient conditions, or if not solid under ambient conditions, nonetheless form solid blends in combination with other ingredients of the radiation curable component.
- preferred oligomers of the present invention also preferably include pendant hydroxyl functionality and are aromatic.
- One preferred class of radiation curable, hydroxyl functional, aromatic oligomers found to be suitable in the practice of the present invention includes the class of radiation curable, novolak-type phenolic oligomers.
- a representative radiation curable, aromatic novolak-type phenolic oligomer 90 having pendant cyanate ester functionality is shown in Fig. 8B, wherein n has a value in the range from about 3 to about 20, preferably 3 to 10.
- Another representative, radiation curable oligomer 100 having pendant acrylamide functionality and hydroxyl functionality (a combination of functionality that is particularly beneficial when incorporated into a make coat formulation) is shown in Fig. 10, wherein n has an average value in the range from about 3 to 20, preferably 3 to 10.
- n has an average value of about 3 to 5.
- the resultant oligomer for which the average value of n is about 3 to 5 tends to have a taffy-like consistency under ambient conditions.
- such oligomer readily forms solid particles when combined with other solid, radiation curable monomers, oligomers, and polymers to facilitate dry coating, but flows easily when heated after dry coating, facilitating formation of uniform, fused binder matrices.
- the class of radiation curable, novolak- type phenolic oligomers, including the particular oligomer 100 shown in Fig. 10 has been described generally in U.S. Patent Nos. 4,903,440 and 5,236,472.
- Another preferred class of radiation curable, hydroxyl functional, aromatic oligomers found to be suitable in the practice of the present invention includes the class of epoxy oligomers obtained, for example, by chain extending bisphenol A up to a suitable molecular weight and then functionalizing the resultant oligomer with radiation curable functionality.
- Fig. 11 illustrates such an epoxy oligomer 110 which has been reacted with an acrylic acid to provide radiation curable functionality.
- n of Fig. 11 has a value such that oligomer 110 has a number average molecular weight in the range from about 800 to 5000, preferably about 1000 to 1200.
- Such materials typically are viscous liquids under ambient conditions but nonetheless form solid powders when blended with other solid materials such as solid monomers, solid macromolecules, and/or calcium and/or zinc stearate. Accordingly, such materials also can be easily dry coated in solid form under ambient conditions, but then
- oligomers according to Fig. 11 demonstrate excellent flow characteristics upon heating to facilitate formation of binder matrices having desired performance characteristics. Indeed, any oligomer that has this dual liquid/solid behavior under ambient conditions would be particularly advantageous with respect to achieving such processing advantages.
- Acrylate oligomers according to Fig. 11 are available under the trade designations "RSX29522" and “EBECRYL 3720", respectively, from UCB Chemicals Corp., Smyrna, GA.
- oligomers suitable in the practice of the present invention are not limited solely to the preferred novolak-type phenolic oligomers or epoxy oligomers described above.
- other radiation curable oligomers that are solid at room temperature, or that form solids at room temperature in blends with other ingredients, include polyether oligomers such as polyethylene glycol 200 diacrylate having the trade designation "SR259” and polyethylene glycol 400 diacrylate having the trade designation "SR344,” both being commercially available from Sartomer Co., Exton, PA; and acrylated epoxies available under the trade designations "CMD 3500,” “CMD 3600,” and “CMD 3700,” from Radcure Specialties.
- radiation curable polymers also can be beneficially incorporated into the radiation curable component, although polymers tend to be more viscous and do not flow as easily upon heating as compared to monomers and oligomers.
- Representative radiation curable polymers of the present invention comprise vinyl ether functionality, cyanate ester functionality, (meth)acrylate functionality,
- (meth)acrylamide functionality cyanate ester functionality, epoxy functionality, combinations thereof, and the like.
- Representative examples of polymers that may be functionalized with one or more of these radiation curable groups include polyamides, phenolic resins, epoxy resins, polyurethanes, vinyl copolymers, polycarbonates, polyesters, polyethers, polysulfones, polyimides, combinations of these, and the like.
- the radiation curable polymer may be an epoxy functional resin having at least one oxirane ring polymerizable by a ring opening reaction.
- These materials generally have, on the average, at least two epoxy groups per molecule (preferably more than two epoxy groups per molecule).
- the polymeric epoxides include linear polymers having terminal epoxy groups (for example, a diglycidyl ether of a polyoxyalkylene glycol), polymers having skeletal oxirane units (for example, polybutadiene polyepoxide), and polymers having pendent epoxy groups
- the number average molecular weight of the epoxy functional resin most typically may vary from about 1000 to about 5000 or more.
- Another useful class of epoxy functional macromolecules includes those which contain cyclohexene oxide groups derived from monomers such as the epoxycyclohexanecarboxylates, typified by 3,4-epoxycyclohexylmethyl-3,4- epoxycyclohexane carboxylate, 3,4-epoxy-2-methylcyclohexylmethyl-3,4-epoxy-2- methylcyclohexane carboxylate, and bis(3,4-epoxy-6-methylcyclohexylmethyl) adipate.
- cyclohexene oxide groups derived from monomers such as the epoxycyclohexanecarboxylates, typified by 3,4-epoxycyclohexylmethyl-3,4- epoxycyclohexane carboxylate, 3,4-epoxy-2-methylcyclohexylmethyl-3,4-epoxy-2- methylcyclohexane carboxylate, and bis(3,4-epoxy-6-methylcyclohex
- epoxy functional macromolecules which are particularly useful in the practice of this invention include resins incorporating glycidyl ether monomers of the formula:
- R' is alkyl or aryl and n is an integer of 1 to 6.
- examples are the glycidyl ethers of polyhydric phenols obtained by reacting a polyhydric phenol with an excess of chlorohydrin such as epichlorohydrin, for example, the diglycidyl ether of 2,2-bis-2,3- epoxypropoxyphenol propane. Further examples of epoxides of this type are described in U.S. Patent No. 3,018,262. There are also several commercially available epoxy macromolecules that can be used in this invention.
- epoxides which are readily available include octadecylene oxide, epichlorohydrin, styrene oxide, vinyl cyclohexene oxide, glycidol, glycidyl-methacrylate, diglycidyl ether of Bisphenol A (for example, those available under the trade designations "EPON 828,” “EPON 1004,” and “EPON 1001F” from Shell Chemical Co., and "DER-332” and “DER-334,” from Dow Chemical Co.), diglycidyl ether of Bisphenol F (for example, “ARALDITE GY281" from Ciba-Geigy), vinylcyclohexene dioxide (for example, having the trade designation "ERL 4206” from Union Carbide Corp.), 3,4-epoxycyclohexyl-methyl-3,4-epoxycyclohexene carboxylate (for example, having the trade designation "ERL-4221” from Union Carbide Corp.), 2- (3
- the binder precursor particles of the present invention may also include a thermoplastic resin in order to adjust the properties of the particles and/or the resultant cured binder matrix.
- thermoplastic resins can be incorporated into the particles in order to adjust flow properties of the particles upon being melted, to allow the melt layer to display pressure sensitive adhesive properties so that abrasive particles more aggressively adhere to the melt layer prior to curing (desirable for a make coat), to adjust the flexibility characteristics of the resultant cured binder matrix, combinations of these objectives, and the like.
- thermoplastic polymers useful in the present invention include polyester, polyurethane, polyamide, combinations of these, and the like.
- the binder precursor particles may include up to 30 parts by weight of a thermoplastic component per 100 parts by weight of the radiation curable component.
- the fusible powder may also include a binder comprising one or more monomers and/or macromolecules that may be thermoplastic, thermally curable, and/or radiation curable as described above in connection with the binder precursor particles.
- the fusible powder comprises 70 to 95 parts by weight of at least one metal salt of a fatty acid and 0 to 30 parts by weight of the binder.
- the metal salts of a fatty acid ester suitable for use in the fusible powder generally may be represented by formula 90 shown in Fig. 9 wherein R' is a saturated or unsaturated moiety, preferably an alkyl group having at least 10, preferably 12 to 30, carbon atoms, M is a metal cation having a valence of n, wherein n typically is 1 to 3.
- Specific examples of compounds according to formula 90 of Fig. 9 include lithium stearate, zinc stearate, calcium stearate, magnesium stearate combinations of these, and the like.
- the metal salt of a fatty acid preferably is calcium stearate, zinc stearate, or a combination thereof wherein the weight ratio of calcium stearate to zinc stearate is in the range from 1:1 to 9: 1.
- the use of a powder comprising a combination of calcium and zinc stearates also provides an excellent way to control the melting characteristics of the powder. For example, if it is desired to increase the melting temperature of the powder, the amount of calcium stearate being used can be increased relative to the amount of zinc stearate.
- the amount of zinc stearate being used can be increased relative to the amount of calcium stearate.
- Calcium stearate is unique in that this material never truly melts.
- a powder having an average particle size of less than about 125 micrometers calcium stearate can be used by itself, or in combination with other materials, to provide powders that readily flow when heated at moderately low processing temperatures.
- metal salts of fatty acids for example, the metal stearates
- the metal stearates may be blended with liquid monomers, oligomers, and/or polymers to
- the fusible powder of the present invention may include one or more fatty acids.
- a fatty acid makes it easier to melt process the fusible powder at reasonably low processing temperatures, for example, 35 °C to 180 °C.
- a preferred embodiment of a fusible powder of the present invention might include calcium stearate (a metal salt of a fatty acid) as a major component.
- a fusible powder including just calcium stearate by itself tends to be difficult to melt process, because calcium stearate never truly melts.
- the resultant blend can be readily melt processed at convenient temperatures.
- preferred embodiments of the present invention include a sufficient amount of a fatty acid so that the fusible powder can be melt processed at the desired temperature, for example a temperature in the range from 35 °C to 180 °C.
- Preferred fusible powders of the present invention incorporate up to 30, preferably about 10, parts by weight of one or more fatty acids per 70 to 100, preferably about 90, parts by weight of the metal salt of a fatty acid.
- a preferred fatty acid is the corresponding acid form of the metal salt of a fatty acid being used.
- stearic acid is a preferred fatty acid when the metal salt of a fatty acid is a stearate, for example, zinc stearate or calcium stearate.
- the binder precursor particles and/or fusible powder of the present invention may also include one or more grinding aids.
- grinding aids include waxes, organic halide compounds, halide salts, metals, and alloys of metals.
- Organic halide compounds typically break down during abrading and release a halogen acid or a gaseous halide compound.
- organic halides include chlorinated waxes, such as tetrachloronapthalene, pentachloronapthalene, and polyvinyl chloride. Chlorinated waxes can also be considered to be waxes.
- halide salts include sodium chloride (NaCl), potassium chloride (KCl), potassium fluoroborate
- the grinding aids include sulfur and organic sulfur compounds, graphite, and metallic sulfides. Combinations of grinding aids can be used.
- the preferred grinding aid for stainless steel is potassium fluoroborate.
- the preferred grinding aid for mild steel is cryolite.
- the ratio of the fusible organic component to grinding aid ranges from 0 to 95, preferably ranges from about 10 to about 85, more preferably about 15 to about 60, parts by weight of a fusible organic component to about 5 to 100, preferably about 15 to about 85, more preferably about 40 to about 85, parts by weight grinding aid.
- the binder precursor particles and/or fusible powder of the present invention additionally may comprise one or more optional additives, such as, plasticizers, other antiloading agents (that is, materials useful for reducing or preventing swarf accumulation), grinding aids, surface modification agents, fillers, flow agents, curing agents, hydroxyl containing additives, tackifiers, grinding aids, expanding agents, fibers, antistatic agents, lubricants, pigments, dyes, UN stabilizers, fungicides, bacteriocides, and the like.
- additives such as, plasticizers, other antiloading agents (that is, materials useful for reducing or preventing swarf accumulation), grinding aids, surface modification agents, fillers, flow agents, curing agents, hydroxyl containing additives, tackifiers, grinding aids, expanding agents, fibers, antistatic agents, lubricants, pigments, dyes, UN stabilizers, fungicides, bacteriocides, and the like.
- additives such as, plasticizers
- binder precursor particles and/or fusible powder for a particular application will depend, to a large extent, upon the portion of bond system 18 into which the particles will be incorporated. Different compositions may be more desirable depending upon whether the binder precursor particles are to be incorporated into make coat 20, size coat 22, and/or supersize coat 24. Further, not all binder precursor particles to be incorporated into bond system 18 need be the same. Binder precursor particles of one composition, for instance, may be incorporated into make coat 20 and size coat 22, while binder precursor particles of a second composition are incorporated into supersize coat 24.
- a preferred binder precursor particle composition (Make/Size Composition I) comprises 100 parts by weight of a radiation curable binder component, about 1 to 5 parts by weight of a flow control agent, and about 0.5 to 5 parts by weight of a photoinitiator or photocatalyst.
- the preferred radiation curable binder component comprises a (i) solid, radiation curable monomer and (ii) a solid radiation curable oligomer and/or polymer, wherein the weight ratio of the monomer to the
- oligomer/polymer is in the range from 1 :10 to 10:1, preferably 1 :4 to 4:1, more preferably about 1 :1.
- Preferred examples of the solid monomer include the monomer of Fig. 3, the cyanate ester of Fig. 8, and the TATHEIC monomer of Fig. 6.
- Preferred examples of the solid oligomer/polymer include the epoxy functional resin commercially available under the trade designation "EPON 100 IF" from Shell
- Preferred flow control agents include waxes and acrylic copolymers commercially available under the trade designation Modarez MFP-V from Synthron, Inc., metal stearates such as zinc stearate and/or calcium stearate, combinations of these, and the like. These ingredients may be melt blended together, cooled, and then ground into a free flowing powder of the desired average particle size.
- a composition (Make/Size Composition II) identical to Make/Size Composition I is used, except that a liquid oligomer and/or polymer is substituted for the solid oligomer/polymer.
- the liquid oligomer or polymer is highly viscous. "Highly viscous" means that the material is a liquid at 25 °C and has a weight average molecular weight of at least about 5000, preferably at least about 8000, more preferably at least about 10,000.
- Preferred examples of highly viscous oligomers and polymers include the oligomer of Fig. 10 in which n is about 5, as well as the acrylate functional resin of Fig. 11.
- a preferred binder precursor particle composition comprises 75 to 95 parts by weight of a solid metal salt of a fatty acid, about 5 to 25 parts by weight of a liquid, radiation curable monomer, oligomer and/or polymer, and about 1 to 5 parts by weight of a photoinitiator or photocatalyst.
- the ingredients can be melt blended, cooled, and then ground to form a free flowing, solid powder.
- Preferred metal salts of a fatty acid include zinc stearate, calcium stearate, and combinations of these.
- Preferred liquid materials include acrylate functional epoxy oligomers available under the trade designations "EBECRYL 3720 and 302", acrylate functional polyester available under the trade designation "EBECRYL 450", acrylate
- a preferred binder precursor particle composition (Supersize Composition II) is identical to Supersize Composition I except that one or more solid radiation curable monomers, oligomers, and/or polymers is substituted for the liquid radiation curable materials.
- Preferred examples of the solid radiation curable material include the monomer of Fig. 3, the cyanate ester of Fig. 8, and the TATHEIC monomer of Fig. 6.
- Preferred examples of the solid oligomer/polymer include the epoxy functional resin commercially available under the trade designation "EPON 100 IF" and the acrylate functional oligomer available under the trade designation "RSX 29522".
- a preferred binder precursor particle composition comprises 70 to 95 parts by weight of a metal salt of a fatty acid as described above, 5 to 30 parts by weight of a thermoplastic resin, and optionally 5 to 30 parts by weight of a solid or liquid radiation curable component as described above.
- thermoplastic resins include polyamides, polyesters, ethylene vinyl acetate copolymers, combinations of these, and the like.
- a particularly preferred resin is available from Union Camp Chemical Product Division under the trade designation
- a preferred binder precursor particle composition (Supersize Composition IV) comprises 70 to 95 parts by weight of the metal salt of a fatty acid as described above and 5 to 20 parts by weight of a thermosetting resin other than a radiation curable resin.
- thermosetting resin examples include phenol-formaldehyde resins (that is, novolak type phenolic resins and powdered resole resins) such as the resin available under the trade designation "VARCUM 29517” from the Durez Division of the Occidental Chemical Corp. (“Oxychem”), and urea- formaldehyde resins such as the resin available under the trade designation "AEROLITE UP4145” from Dynochem UK,
- the binder precursor particles and/or fusible powder of the present invention are easily made by a process in which all of the ingredients to be incorporated into the particles or powder, as the case may be, are first blended together to form a homogeneous, solid admixture. Blending can be accomplished by dry blending the ingredients together in powder form, but more preferably is accomplished by melt processing in which at least the radiation curable ingredients of the particles are liquefied during blending. Typically, melt processing occurs at a temperature above the glass transition temperatures and/or melting points of at least some of the radiation curable ingredients, while nonetheless occurring at a sufficiently low temperature to avoid premature crosslinking of the binder components. The melt processing temperature is also below temperatures that might degrade any temperature sensitive ingredients of the particles.
- melt processing and blending is not critical, and any convenient technique can be used.
- processing the ingredients through an extruder to form a solid, blended extrudate is suitable, so long as extruder temperature is carefully monitored to avoid premature crosslinking of, and degradation to, the ingredients.
- the resultant solid can then be milled, for example, ground, into particles of the desired particle size.
- the type of milling technique is not critical and representative examples include cryogenic grinding, hammer milling (either cold or at room temperature), using a mortar and pestle, using a coffee grinder, ball milling, and the like. Hammer milling at room temperature is presently preferred.
- the dry particles can then be used, without use of any solvent whatsoever, to form the binder matrix component of make coat 20, size coat 22, and/or supersize coat 24, as desired.
- the particles may be applied to an underlying surface of abrasive article 10 using any convenient dry coating technique such as drop coating, electrostatic spraying, electrostatic fluidized bed coating, hot melt spraying, and the like.
- the particles are liquefied, preferably by heating, in a manner such that the particles fusibly flow together to form a uniform, fluid melt layer.
- the melt layer can then be exposed to a suitable source of energy in order to cure the melt layer so that a thermoset, solid, binder matrix is formed.
- abrasive particles 16 to be incorporated may be
- the binder precursor particles can be dry coated and liquefied first, after which abrasive particles 16 are coated into the melt layer prior to curing.
- the binder precursor particles can be dry coated and liquefied first, after which abrasive particles 16 are coated into the melt layer prior to curing.
- Fig. 12 is a schematic representation of an apparatus 200 suitable for forming abrasive article 10.
- Fig. 12 shows forming each of make coat 20, size coat 22, and supersize coat 24 of abrasive article 10 from binder precursor particles of the present invention.
- the present invention is not limited to the illustrated application in which the entirety of bond system 18 is formed from the binder precursor particles, but rather is applicable to circumstances in which any one or more portions of bond system 18 is derived from such binder precursor particles.
- Fig. 12 shows backing 202 being transported from supply roll 204 to take-up roll 206.
- backing 202 may be transported at a speed in the range from 0.1 m/min to as much as 100 m/min or more.
- backing 202 is supported upon suitable number of guide rollers 208 as backing 202 passes through coating stations 210, 212, and 214.
- Make coat 20, size coat 22, and supersize coat 24 are applied at stations 210, 212, and 214, respectively.
- binder precursor particles 216 corresponding to the binder matrix of make coat 20 are drop coated onto backing 202 from dry coating apparatus 220.
- Backing 202 then passes through oven 224 in which particles 216 are heated to form a liquefied make coat melt layer.
- Abrasive particles 16 are then electrostatically coated into the make coat melt layer from mineral coater 226.
- the coated backing then passes ultraviolet light source 228, where the make coat melt layer is exposed to ultraviolet radiation to crosslink and cure the make coat.
- the crosslinked make coat now firmly bonds abrasive particles 16 to backing 202.
- the coated backing 202 passes through station 212 to form size coat 22.
- Binder precursor particles 230 corresponding to the binder matrix of size coat 22 are drop coated onto make coat 20 from dry coating apparatus 232.
- the coated backing 202 then passes through oven 234 in which particles 230 are heated to form a liquefied size coat melt layer.
- the coated backing then passes ultraviolet light source 238, where the size coat melt layer is exposed to ultraviolet radiation to crosslink and cure the size coat.
- the crosslinked size coat now helps reinforce the attachment of abrasive particles 16 to backing 202.
- the coated backing 202 passes through station 214 to form supersize coat 24.
- the coated backing 202 then passes through oven 244 in which particles 240 are heated to form a liquefied supersize coat melt layer.
- the coated backing 202 then passes ultraviolet light source 248, where the supersize coat melt layer is exposed to ultraviolet radiation to crosslink and cure the supersize coat.
- the crosslinked supersize coat now helps provide abrasive article 10 with desired performance characteristics, for example, anti-loading capabilities if supersize coat 24 incorporates an antiloading agent.
- the finished abrasive article 10 is then stored on take-up roll 206, after which abrasive article may be cut into a plurality of sheets, discs or the like, depending upon the desired application.
- abrasive article 10 may be transported directly to a cutting apparatus to form sheets or discs, after which the sheets or discs may be stored, packaged for distribution, used, or the like.
- EP1 Bisphenol A epoxy resin commercially available from Shell Chemical, Houston, TX under the trade designation "EPON 828"
- LiSt Lithium stearate commercially available from Witco Chemical
- AMOX Di-t-amyloxalate (acts as an accelerator) as described in U.S.
- ACL Aluminum chloride commercially available from Aldrich
- a make coat precursor was prepared from DS1227 (20.7 parts), EPl (30.5 parts), EP2 (33.7 parts), CHDM (2.9 parts), COM (0.6 part), KBl ( 1.0 part) and AMOX (0.6 parts).
- the batch was prepared by melting DS1227 and EP2 together at 140°C, mixing, then adding EPl and CHDM. Then, TMPTA (4.5 parts) was added with mixing at 100°C.
- To this sample was added COM, AMOX, and KBl followed by mixing at 100 °C.
- the make coat precursor was applied at 125 °C by means of a knife coater to the paper backing at a weight of about 20 g/m ⁇ .
- the sample was then irradiated (3 passes at 18.3 m min) with one 400 W/cm "D" bulb immediately before PI 80 AO abrasive particles were electrostatically projected into the make coat precursor at a weight of about 85 g/m ⁇ .
- the intermediate product was thermally cured for 15 minutes at a temperature of 100 °C.
- a size coat precursor was roll coated over the abrasive grains at a weight of about 50 g/m2.
- the size coat precursor included a 100% solids blend of EPl (40 parts), ERL 4221 (30 parts), TMPTA (30 parts), KBl (1 part), and COM (1 part).
- the sample was then irradiated (3 passes at 18.3 m/min) with one 400 W/cm "D” bulb followed by a thermal cure for 10 minutes at 100 °C.
- Abrasive article B was prepared by the same methodology as described above using the formulations shown in Table 1.
- Abrasive articles used a backing that was a 95 g/m paper backing C90233 EX commercially available from Kimberly-Clark, Neenah, WI.
- a make coat precursor was prepared from DS1227 (20.7 parts), EPl (30.5 parts), EP2 (33.7 parts),
- the sample was then irradiated (3 passes at 18.3 m/min) with one 400 W/cm "D" bulb immediately before PI 80 AO abrasive particles were electrostatically projected into the make coat precursor at a weight of about 85 g/m ⁇ .
- the intermediate product was thermally cured for 15 minutes at a temperature of 100 °C.
- a size coat precursor was roll coated over the abrasive grains at a weight of about 50 g/m2.
- the size coat precursor included a 100% solids blend of EPl (40 parts), ERL 4221 (30 parts), TMPTA (30 parts), KBl (1 part), and COM (1 part).
- the samples were then irradiated (3 passes at 18.3 m/min) with one 400 W/cm "D" bulb followed by a thermal cure for 10 minutes at 100 °C.
- the sample was supersized at a weight of about 35 g/m ⁇ with a calcium stearate solution (50% solids aqueous calcium stearate/acrylic binder solution) available from Witco Chemical Corporation, Memphis, TN.
- Comparative Article L was prepared by the same methodology as described above for Abrasive Article A using the formulations shown in Table 1.
- Comparative Articles A, C, G, I, O, AA, CC are commercially available from Minnesota Mining and Manufacturing Company, St. Paul, MN under trade designation "216U PI 80 Fre-Cut Production Paper A Weight".
- binder precursor particles according to the present invention were prepared from the formulations in Table 2. To make each sample, the ingredients were either (1) melt blended together, solidified, and ground into a powder or (2) dry blend mixed and ground into powders. The samples were ground into fine powders by mortar and pestle or hammer mill, unless otherwise indicated. A few examples are given below to illustrate the methodology. _ Preparation of binder precursor particles comprising a combination of ZnSt2/CaSt2/EBl/IRGl (45/45/10/1
- a 0.5 L.jar was charged with 45 g of ZnSt2, 45 g of CaSt2 and 10 g of EB1.
- the materials were melted at 120-160 °C, mixed, and 1 g of IRG1 was added. The material was cooled, and the resultant solid was ground into a fine powder.
- binder precursor particles comprising a combination of ZnSt2/UFl (80/20)
- a 0.5 L. jar was charged with 80 g of ZnSt2 and 20 g of UF1. The solids were dry blended in a grinder.
- ZnSt2/CaSt2/EP2/IMID 50/50/14/1
- a 0.5 L.jar was charged with 50 g of ZnSt2, 50 g of CaSt2 and 14 g of EP2, The materials were melted at 120-140 °C, mixed, and 1 g of IMID was added. The material was cooled, and the resultant solid was ground into a fine powder.
- Binder precursor particle samples 1-38H were dry coated onto Abrasive Articles A and/or B (see Table 3), melted, and then solidified to form supersize coats according to the following procedures. The details of the resultant abrasive articles are disclosed in Table 3.
- the binder precursors samples 2-15,16, 22-36, and 38A-38B were respectively coated onto Abrasive Article A or B.
- the binder precursor particles were powder coated at about 7.0 to 23g/m2 onto the abrasive articles by drop coating with a mesh sifter, spray coating with a fluidized or electrostatic fluidized spray gun, or coating with an electrostatic fluidized bed coater.
- the binder precursor particles were then melted by placing the abrasive article in an oven at a temperature of from about 120° to about 165 °C for about 5-15 minutes.
- the resultant melt layer was then cured bypassing the abrasive article through a UN lamp (1 pass at 7.6 m min. with 157w/cm bulb).
- Adhesive sheeting was attached to the backside of the abrasive article and 10.2 cm or 15.2 cm discs were died out of the abrasive articles. The discs were used for Schiefer or Offhand DA testing, described below.
- Adhesive sheeting was attached to the backside of the abrasive article and 10.2 cm or 15.2 cm discs were died out of the abrasive articles. The discs were used for Schiefer or Offhand DA testing, describe below.
- Supersize coat samples formed from binder precursor particles 38B-G were prepared identically to samples 2-14,16 22-36, and 38 A except that the amount of time that the samples were placed in the oven was extended to 30-90 minutes to thermally cure the resultant melt layer.
- Adhesive sheeting was attached to the backside of the abrasive articles and 10.2 cm or 15.2 cm discs were died out of the abrasive articles. The discs were used for Schiefer tests, described below.
- Supersize coat samples formed from binder precursor particles 17-21 were prepared identically to samples 2-14,16 22-36, and 38A except that, prior to powder coating, a composition comprising 50 g of radiation curable monomer
- Abrasive Article A and allowed to air dry. About 8 g/m ⁇ were then applied to the corresponding abrasive article by electrostatic fluidizing spray gun. The abrasive article was then placed in an oven at a temperature in the range of from about 120 °C to about
- melt layer was cured by passing the abrasive article through a UN lamp (1 pass at 7.6 m/min. with a 157 w/cm bulb).
- Adhesive sheeting was attached to the backside of the abrasive article and 10.2 cm or
- Each 10.2 cm diameter disc of the abrasive articles of each Sample 1-38H and Comparative Samples A-O and AA-JJ(See Tables 4-7) was secured to a foam back-up pad by means of a pressure sensitive adhesive.
- Each coated abrasive disc and back-up pad assembly was installed on a Schiefer testing machine, and the coated abrasive disc was used to abrade a cellulose acetate butyrate polymer of predetermined weight. The load was 4.5 kg. The test was considered complete after 500 revolution cycles of the coated abrasive disc. The cellulose acetate butyrate polymer was then weighed, and the amount of cellulose acetate butyrate polymer removed was recorded.
- a paint panel that is, a steel substrate with an e-coat, primer, base coat, and clear coat typically used in automotive paints, was abraded in each case with coated abrasives made in accordance with the invention and with coated abrasives as comparative examples.
- coated abrasive had a diameter of 15.2 cm and was attached to a random orbital sander (available under the trade designation "DAQ", from
- the abrading pressure was about 0.2 kg/cm ⁇ , while the sander operated at about 60 PSI(@TOOL (413 kPa).
- the painted panels were purchased from ACT Company of Hillsdale, MI. The cut in grams was computed in each case by weighing the primer-coated substrate before abrading and after abrading for a predetermined time, for example, 1 or 3 minutes.
- Example 37 10.15 87 88
- Example 38A 11.75 100 101
- a make coat precursor was prepared from DS1227 (20.7 parts), EPl (30.5 parts), EP2 (33.7 parts), CHDM (2.9 parts), COM (0.6 part), KBl ( 1.0 part) and AMOX (0.6 parts).
- the batch was prepared by melting DS1227 and EP2 together at 140 °C, mixing, and then adding EPl and CHDM and mixing. Then, TMPTA (4.5 parts) was added with mixing at 100 °C. To this sample was added COM, AMOX, and KBl followed by mixing at 100 °C.
- the make coat precursor was applied at 125 °C by means of a knife coater to the paper backing at a weight of about 20 g/m ⁇ .
- the sample was then irradiated (3 passes at 18.3 m min) with one 400 W/cm "D" bulb immediately before PI 80 AO abrasive particles were electrostatically projected into the make coat precursor at a weight of about 85 g/m ⁇ .
- the intermediate product was thermally cured for 15 minutes at a temperature of 100 °C.
- An abrasive article used a 5 mil thick polyester backing that can be obtained commercially from Minnesota Mining and Manufacturing Company, St. Paul, MN.
- a make coat precursor comprising an aqueous solution ofUF2, a 75% solid aqueous resole phenolic resin with a formaldehyde/phenol ratio of approximately 1.1-3.0/1 and a pH of 9, ACL and PTSOH (85/15/2/1) was roll coated onto the backing at an approximate weight of 40 g/m ⁇ .
- a blend of PI 80 and A1O/CUB abrasive particles 50-90/10-50 was electrostatically projected into the make coat precursor at a weight of about 155 g/m ⁇ .
- the make resin was cured in an oven at 100 °C for 60 minutes.
- a make coat precursor was prepared from DS1227 (20.7 parts), EPl (30.5 parts), EP2 (33.7 parts), CHDM (2.9 parts), COM (0.6 part), KBl ( 1.0 part) and AMOX (0.6 parts).
- the batch was prepared by melting DS1227 and EP2 together at 140 °C, mixing, and then adding EPl and CHDM. Then, TMPTA (4.5 parts) was added with mixing at 100 °C. To this sample was added COM, AMOX, and KBl followed by mixing at 100 °C.
- Make coat precursors were applied at 125 °C by means of a knife coater to the paper backing at a weight of about 20 g/m ⁇ .
- the sample was then irradiated (3 passes at 18.3 m/min) with one 400 W/cm "D" bulb immediately before PI 80 AO abrasive particles were electrostatically projected into the make coat precursor at a weight of about 85 g/m ⁇ .
- the intermediate product was thermally cured for 15 minutes at a temperature of 100 °C.
- a size coat precursor was roll coated over the abrasive grains at a weight of about 50 g/m2.
- the size coat precursor included a 100% solids blend of EPl (40 parts), ERL 4221 (30 parts), TMPTA (30 parts), KBl (1 part), and COM (1 part). The samples were then irradiated (3 passes at 18.3 m/min) with one 400 W/cm "D" bulb followed by a thermal cure for 10 minutes at 100 °C.
- An abrasive article used a 5 mil thick polyester backing with a backing that can be obtained commercially from Minnesota Mining and Manufacturing Company, Paul, M ⁇ .
- a make coat precursor comprising an aqueous solution ofUF2, a 75% solid aqueous resole phenolic resin with a with a formaldehyde/phenol ratio of approximately l.l-3.)/l and pH of 9, ACL, and PTSOH (85/15/2/1) was roll coated onto the backing at an approximate weight of 40g/m2.
- a blend of PI 80 and A1O/CUB abrasive particles 50-90/10-50 was electrostatically projected into the make coat precursor at a weight of about 155g/m2.
- a size coat precursor comprising a 75% solids aqueous solution of resole phenolic resin with a formaldehyde/phenol ratio of approximately 1.1-3.0/1, pH of 9 and feldspar (70/35) was coated onto the make coat at an approximate weight of
- the size resin was cured by placing the sample in an oven at 100-110 °C for 1-2 hours.
- EP2 (33.7 parts), resin ACL/PTSO parts), EP2 (33.7 resin/ACL/PTSO
- AMOX (0.6 parts). 1.0 part) and AMOX (0.6 parts).
- the product was found to have a T m of about 97 °C, by DSC. Thin layer chromatography showed the product to be pure, as evidenced by a single spot (elution solvent of 10% methanol/90% chloroform, using F254 silica gel coated glass plates).
- the resinous product was transferred to a glass jar, with gentle heating of the flask walls to aid in its flow. NMR analysis of this resin showed some traces of triethylamine hydrochloride still present, and approximately 10 weight percent of THF. The main product showed approximately 0.2 mol of acrylate ester per ring of phenol.
- the novolak had a calculated formaldehyde to phenol ratio of about 0.8 3_, Acrylamidomethyl novolak (AMN) AMN was prepared as described in US Patent Nos. 4,903,440 and 5,236,472.
- binder precursor particles comprising a combination of AMN/PDAP/CAB-O-SIL/IRGl (50/50/0.2/2)
- a 0.5 L. jar was charged with 100 g of AMN (a viscous liquid), 100 g of PDAP and 0.4 g of CAB-O-SIL. The sample was heated to 110-115 °C for 30 minutes and mixed. Next, 4 g of IRGl was added to the molten mixture, mixed and cooled to room temperature. The resulting solid was ground into a fine powder with a grinder. 2. Preparation of binder precursor particles comprising of a combination of
- a 0.25 L. jar was charged with 25 g of a viscous liquid ,PAN, and 25g of PDAP.
- the sample was heated to 110-115 °C for 30 minutes and mixed.
- lg. of IRGl and 0.1 g of MOD was added to the molten mixture, mixed and cooled to room temperature.
- the resulting solid was ground into a fine powder with a grinder. The addition of liquid nitrogen to the cooling solid aided in grinding.
- binder precursor particles comprising a combination of AMN/PDAP /CRY/IRGl (50/50/100/2)
- a 0.5 L jar was charged with 50 g of AMN (a viscous liquid), 50 g of PDAP, and 100 g of CRY The sample was heated to 110-115 °C for 30 minutes and mixed. Next, 2 g of IRGl was added to the molten mixture, mixed and cooled to room temperature. The resulting solid was ground into a fine powder.
- AMN a viscous liquid
- PDAP a viscous liquid
- CRY 100 g
- IRGl was added to the molten mixture, mixed and cooled to room temperature. The resulting solid was ground into a fine powder.
- binder precursor particles comprising a combination of EP1/EP2/SD 7280/COM (20/60/20/1)
- a 0.5 L jar was charged with 20 g of EPl, 60 g of EP2, and 20 g of SD 7280. The sample was heated to 120 °C for 60 minutes and mixed. Next, 1 g of COM was added to the molten mixture, mixed and cooled to room temperature. The resulting solid was ground into a fine powder.
- EP1/EP2/SD 7280/CRY/COM (20/60/20/100/2)
- a 0.5 L jar was charged with 20 g of EPl (a viscous liquid), 60 g of EP2, 20 g of SD 7280 and 100 g of CRY.
- the sample was heated to 120 °C for 60 minutes and mixed.
- 2 g of COM was added to the molten mixture, mixed and cooled to room temperature. The resulting solid was ground into a fine powder with a grinder.
- binder precursor particles comprising a combination of PT60/COM (100/1)
- a 0.5 L jar was charged with lOOg of PT-60 and heated to 90 °C. lg of COM was added, and the resultant solid was cooled to room temperature. The solid was ground into a fine powder with a grinder.
- binder precursor particles comprising a combination PT60/CRY/IRG1 (50/50/1)
- a 0.5 L jar was charged with 50 g of 100/1 PT60/COM solid. Next 50 g of CRY was added. The two solids were mixed and ground into a fine powder with a grinder.
- binder precursor particles comprising a combination EP2/PDAP/IRG1/COM (70/30/1/1)
- a 0.5 L. jar was charged with 70 g of (EP2), as solid, 30 g of (PDAP), 4g of CaSt2, and 2g of ZnSt2.
- the sample was heated to 110-115 °C for 30 minutes and mixed.
- 1 g of IRGl and 1 g of COM was added to the molten mixture, mixed and cooled to room temperature.
- the resulting solid was ground into a fine powder with a grinder.
- Binder precursor particles sample 39-50 were coated onto one or more of
- the binder precursor particle samples 39-46 and 48 were coated onto Abrasive Article D, while binder precursor particle sample 45 and 47 were coated onto Abrasive Article C.
- the binder precursor particles were powder coated onto the abrasive articles at 30 to 160 g/m ⁇ by drop coating with a mesh sifter.
- the binder precursor particles were then melted by placing the abrasive article in an oven at a temperature in the range from about 120 °C to about 165 °C for 5-15 minutes.
- the size coat was then cured by passing the abrasive through a UV lamp (1 pass at 7.6 m/min.
- Samples 46 and 47 were placed in an oven for 10 minutes at 100 °C Adhesive sheeting was attached to the abrasive articles and 10.2 cm discs were died out of the abrasive articles.
- the binder precursor particle samples 49 and 50 were coated onto Abrasive Article C. Specifically, the binder precursor particles were powder coated onto the abrasive articles by drop coating with a mesh sifter. The abrasive samples were placed in an oven at a temperature in the range from about 105 °C to about 140 °C for about 2 hours. Adhesive sheeting was attached to the abrasive articles and 10.2 cm discs were died out of the abrasive articles.
- a make coat precursor was prepared from DS1227 (20.7 parts), EPl (30.5 parts), EP2 (33.7 parts), CHDM (2.9 parts), COM (0.6 part), KBl ( 1.0 part) and AMOX (0.6 parts).
- the batch was prepared by melting DS1227 and EP2 together at 140 °C, mixing, and then adding EPl and CHDM followed by further mixing. Then, TMPTA (4.5 parts) was added with mixing at 100 °C. To this sample was added COM, AMOX, and KBl followed by mixing at
- the make coat precursor was applied at 125 °C by means of a knife coater to the paper backing at a weight of about 30g/m2.
- the sample was then irradiated (3 passes at 18.3 m/min) with one 400 W/cm "D" bulb immediately before PI 80 AO abrasive particles were electrostatically projected into the make coat precursor at a weight of about 85g/m2.
- the intermediate product was thermally cured for 15 minutes at a temperature of 100 °C.
- a size coat precursor was roll coated over the abrasive grains at a wet weight of about 50 g/m ⁇ .
- the size coat precursor included a 100% solids blend of EPl (40 parts), ERL 4221 (30 parts), TMPTA (30 parts), KBl (1 part), and COM (1 part).
- the sample was then irradiated (3 passes at 18.3 m/min) with one 400 W/cm "D" bulb followed by a thermal cure for 10 minutes at 100 °C.
- PDAP/ ⁇ RGI (loo/i) A 0.5 L. jar was charged with 100 g of PDAP. The sample was heated to 110-
- binder precursor particles comprising a combination of AMN/PDAP/ ⁇ RGI (70/30/n
- a 0.5 L. jar was charged with 70 g of AMN (a viscous liquid) and 30 g of
- a 8oz. jar was charged with 25 g of , a viscous liquid PAN and 25g of PDAP.
- the sample was heated to 110-115 °C for 30 minutes and mixed. Next, lg. of
- IRGACURE 651 was added to the molten mixture, mixed and cooled to room temperature. The resulting solid was ground into a fine powder with a grinder.
- a 0.5 L. jar was charged with 70 g EP2 , a solid, and 30 g of PDAP. The sample was heated to 110-115 °C for 30 minutes and mixed. Next, 1 g of IRGl and 1 g of COM was added to the molten mixture, mixed and cooled to room temperature.
- the resulting solid was ground into a fine powder with a grinder
- Binder precursor particle samples 51 -54 were drop coated onto paper backing EX C90233 which is commercially available from Kimberly-Clark, Neenah, WI. The specific make weights can be found in Table 15. Next, the binder precursor particles were melted onto the backing in an oven at 100-140 °C, and PI 80 AO mineral was drop coated onto the make coat at a weight of 115 g/m ⁇ . The sample was then irradiated (3 passes at 18.3 m min) with one 400 W/cm "D" bulb.
- a size coat precursor was roll coated over the abrasive grains at a wet weight of about 100 g/m ⁇ .
- the size coat precursor included a 100% solids blend of EPl (40 parts), ERL 4221 (30 parts), TMPTA (30 parts), KBl (1 part), and COM (1 part).
- the sample was then irradiated (3 passes at 18.3 m/min) with one 400 W/cm "D" bulb followed by a thermal cure for 10 minutes at 100 °C.
- the coated abrasive article for each example was converted into a 10.2 cm diameter disc and secured to a foam back-up pad by means of a pressure sensitive adhesive.
- the coated abrasive disc and back-up pad assembly were installed on a Schiefer testing machine, and the coated abrasive disc was used to abrade a cellulose acetate butyrate polymer.
- the load was 4.5 kg.
- the endpoint of the test was 500 revolutions or cycles of the coated abrasive disc.
- the amount of cellulose acetate butyrate polymer removed is recorded.
- radiation curable binder precursor particles show utility as make coats, especially when the oligomeric material has hydroxyl functionality, for example, AMN and EP2.
- Abrasive articles used a backing that was a 1080 g/m ⁇ fiber disk (17.8 cm diameter disc) commercially available from Kimberly-Clark, Neenah, WI. For each, a
- make coat precursor was prepared from a 75% solids aqueous solution of a phenolic resole (formaldehyde/phenolic ratio of 1.1-3.0/1, pH of about 9), CaCO2 and FEO
- the make coat precursor was applied to the backing with a paint brush.
- grade 50 AZ mineral was electrostatically projected into the make coat precursor at a weight of about 685 g/m ⁇ .
- the intermediate product was thermally cured for 45 minutes at a temperature of 90 °C.
- a size coat precursor was applied with a paint brush at a weight of 405 g/m ⁇ .
- the size coat precursor was prepared from a 75% solids aqueous solution of a phenolic resole (formaldehyde/phenolic ratio of 1.1-3.0/1, pH of about 9), CRY, and FEO (50/60/2)
- Abrasive articles used a backing that was a 1080 g/m ⁇ fiber disk (17.8 cm diameter disc) commercially available from Kimberly-Clark, Neenah, WI.
- a make coat precursor was prepared from a 75% solids aqueous solution of a phenolic resole
- the make coat precursor was applied to the backing with a paint brush.
- grade 50 AZ mineral was electrostatically projected into the make coat precursor at a weight of about 685 g/m ⁇ .
- the intermediate product was thermally cured for 45 minutes at a temperature of 90 °C .
- a size coat precursor was applied with a paint brush at a weight of 405 g/m ⁇ .
- the size coat precursor was prepared from a 75% solids aqueous solution of a phenolic resole (formaldehyde/phenolic ratio of 1.1-3.0/1, pH of about 9), CRY, and FEO
- PDAP/KBF4/ZnSt2/IRGl (30/60/10/1) A 0.5 L. jar was charged with 30 g of PDAP, 60 g of KBF4, and lOg of ZnSt2.
- the sample was heated to 110-115 °C for 30 minutes and mixed. Next, lg. of IRGl was added to the molten mixture, mixed and cooled to room temperature. The resulting solid was ground into a fine powder with a grinder.
- Binder precursor particle sample 55 were drop coated with a mesh sifter onto
- Abrasive Article E The specific supersize weights can be found in Table 18. Next, the binder precursor particles were melted onto the abrasive article in an oven at 100- 140 °C, The samples were then irradiated (1 pass at 18.3 m/min) with one 400 W/cm "D" bulb.
- radiation curable binder precursor particles show utility as grinding aid supersize coats.
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE69921803T DE69921803T2 (en) | 1998-05-01 | 1999-03-30 | ABRASIVES WITH GRINDING WHEEL CARRYING BASE ON THE BASIS OF A COATING POWDER WITH A MELTING, RADIATION-HARDENABLE COMPONENT |
EP99915130A EP1077791B1 (en) | 1998-05-01 | 1999-03-30 | Abrasive articles having abrasive layer bond system derived from solid, dry-coated binder presursor particles having a fusible, radiation curable component |
AU33722/99A AU3372299A (en) | 1998-05-01 | 1999-03-30 | Abrasive articles having abrasive layer bond system derived from solid, dry-coated binder presursor particles having fusible, radiation curable component |
JP2000546916A JP4303421B2 (en) | 1998-05-01 | 1999-03-30 | Abrasive article having an abrasive layer bonding system derived from binder precursor particles having a dry-coated solid fusible radiation curable component |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/071,263 US6228133B1 (en) | 1998-05-01 | 1998-05-01 | Abrasive articles having abrasive layer bond system derived from solid, dry-coated binder precursor particles having a fusible, radiation curable component |
US09/071,263 | 1998-05-01 |
Publications (1)
Publication Number | Publication Date |
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WO1999056914A1 true WO1999056914A1 (en) | 1999-11-11 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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PCT/US1999/006962 WO1999056914A1 (en) | 1998-05-01 | 1999-03-30 | Abrasive articles having abrasive layer bond system derived from solid, dry-coated binder presursor particles having a fusible, radiation curable component |
Country Status (6)
Country | Link |
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US (3) | US6228133B1 (en) |
EP (2) | EP1493535B1 (en) |
JP (1) | JP4303421B2 (en) |
AU (1) | AU3372299A (en) |
DE (2) | DE69943189D1 (en) |
WO (1) | WO1999056914A1 (en) |
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Also Published As
Publication number | Publication date |
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JP2002513685A (en) | 2002-05-14 |
EP1493535A1 (en) | 2005-01-05 |
US6753359B2 (en) | 2004-06-22 |
US20010011108A1 (en) | 2001-08-02 |
DE69921803D1 (en) | 2004-12-16 |
EP1493535B1 (en) | 2011-02-09 |
DE69921803T2 (en) | 2005-12-15 |
JP4303421B2 (en) | 2009-07-29 |
EP1077791A1 (en) | 2001-02-28 |
AU3372299A (en) | 1999-11-23 |
US20020123548A1 (en) | 2002-09-05 |
US6228133B1 (en) | 2001-05-08 |
EP1077791B1 (en) | 2004-11-10 |
US6441058B2 (en) | 2002-08-27 |
DE69943189D1 (en) | 2011-03-24 |
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