WO1999038916A1 - Fluorescent polymeric pigments - Google Patents
Fluorescent polymeric pigments Download PDFInfo
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- WO1999038916A1 WO1999038916A1 PCT/US1999/001686 US9901686W WO9938916A1 WO 1999038916 A1 WO1999038916 A1 WO 1999038916A1 US 9901686 W US9901686 W US 9901686W WO 9938916 A1 WO9938916 A1 WO 9938916A1
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/006—Preparation of organic pigments
- C09B67/0061—Preparation of organic pigments by grinding a dyed resin
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B69/00—Dyes not provided for by a single group of this subclass
- C09B69/10—Polymeric dyes; Reaction products of dyes with monomers or with macromolecular compounds
Definitions
- Objects which exhibit intensely fluorescent color in daylight, or when exposed to a beam of light at night are particularly useful as not only as markers, signs, and other informative and safety oriented devices, but as decorative features.
- fluorescent colored objects and objects coated with materials such as fluorescent paint, may lose their fluorescent coloration fading. This effect is caused by exposure to the elements, particularly sunlight.
- lightfastness of the fluorescent color may determine the useful life of the object.
- a fluorescent pigment should exhibit good color, heat stability, and friability.
- the fluorescent pigment should also be capable of being mixed with either the material of the object that is to be colored, or be mixed in paint or ink.
- the fluorescent dyes themselves are not generally capable of mixing with the material of the object, they are typically combined with resins or other polymeric products to provide a pigment.
- the polymer component of the pigment typically acts as a carrier or solvent for the dye; the polymer and the dye associate in a " solid state solution” .
- the conventional fluorescent dye carriers have varied compositions which are selected depending upon the dye and the use of the pigment. The use of certain polyamide polymers and polyamide-polyester copolymers as carriers for fluorescent dye have been described previously; however the polymers are first formed and then the fluorescent dye is added, to form a solid state solution of dye and polymer. While such light fast pigments are useful, upon exposure to ultra-violet light, the lightfastness of the pigments is limited.
- t would be desirable to have a fluorescent pigment having good color, heat stability, friability, which is suitable for coloring a variety of materials, that demonstrates improved lightfastness .
- the present invention provides thermoplastic, preferably non-water soluble, fluorescent pigments having improved lightfastness which are suitable for coloring a variety of materials including plastics, particularly polyolefins, as well as paints, inks and textiles .
- the pigments of the present invention referred to herein as the " light fast pigments" demonstrate good color, migration resistance, heat stability, water insolubility, friability and resistance to plateout .
- the light fast pigments of the present invention have several embodiments, the polyamide embodiment, polyamide ester embodiment and the polyester embodiment.
- the pigments of the present invention comprises a polymer which comprises polymerized units of fluorescent dye and polymerized monomers such as for example dicarboxylicacids, polycarboxylicacids, dia ines, polyamines, alkanolamines, carboxyalcohols, carboxyamines and difunctional alcohols, and/or polyhydric alcohols.
- the polyamide pigment embodiment and polyamide-ester pigment embodiment are polymers which comprise polyamide linkages .
- the polyester pigment embodiment are polymers that comprise polyester linkages, but substantially lacks polyamide linkages.
- the light fast pigments of the present invention contain a fluorescent dye reacted into, and covalently bound to the polymer backbone; this distinguishes the light fast pigment from conventional pigments which typically exist as a solid state solution of fluorescent dye and polymer carrier.
- the fluorescent dye which is physically incorporated into the backbone of polymer chain, is the BXDA fluorescent dye or an analog thereof .
- the fluorescent dye is the BXDA fluorescent dye or its analogs thereof, or certain conventional dyes. While the light fast pigment of the present invention -3-
- the invention also relates to a method of making such light fast pigment
- the light fast pigment of the present invention comprise polymers that comprise polymerized units of fluorescent dye, the fluorescent dye is incorporated into the backbone of the polymer chain by covalent bonding Since the fluorescent dye is actually incorporated into the backbone, it is technically a monomer, however for clarity, as used herein, the term “ monomer” means a monomer, other than the fluorescent dye, which polymerizes to form the polymeric pigment As used herein, the term “ monomer” includes units such as dimers, trimers, and other oligomers
- the polyamide and polyamide-ester pigment embodiment comprise polymers that comprise amide linkages, an amide linkage is formed from the condensation reaction between a carboxylic acid group on one monomer molecule and an amme group on an adjacent monomer molecule
- the monomers used to form the amide linkages may contain, on a single monomer molecule, both a carboxylic acid group and an amme group, or the monomers may contain an amme group on one monomer molecule and a carboxylic acid group on another monomer molecule
- Ester linkages are formed by the condensation reaction between a carboxylic acid group on one monomer molecule and an alcohol group on an adjacent monomer molecule Where the pigment contains both ester and amide linkages it is referred to herein as a " polyamide-ester pigment " Where the pigment contains ester linkages but no amide linkages then it is referred to herein as a
- polyester pigment Where the pigment contains amide linkages but no ester linkages than it is referred to herein as a " polyamide pigment"
- Monomers used as a source of amme groups to form the amide linkages include diammes , polyfunctional amines, carboxy-amines, and alkanolammes
- the monomers used to form the polymeric pigment of the present invention each contain at least two functional groups.
- the functional groups may be the same or different.
- all light fast pigments of the present invention contain a first monomer having at least one carboxylic acid group and where such first monomer lacks an alcohol or amine group, then such polymer pigment contains a second monomer containing at least one amine group or at least one alcohol group.
- Monomers used as a source of carboxy groups used to create the amide linkages and the ester linkages include dicarboxylic acids, polyfunctional carboxylic acids, carboxy-alcohols, carboxyamines.
- Monomers used as a source of alcohol groups used to create the ester linkages include alkanolamines, carboxy-alcohols, difunctional alcohols, and polyfunctional alcohols.
- the monomers used to form the polymeric pigment of the present invention each contain at least two functional groups .
- the functional groups are amine groups, alcohol groups and carboxylic acid groups.
- at least one type of monomer contains an amine group and at least one monomer contains a carboxyl group; the monomers can have both the amino group and the carboxyl group on a single monomer.
- at least one type of monomer contains an amine group and at least one monomer contains a carboxylic acid group and at least one monomer contains an alcohol group.
- the alcohol group, the carboxyl group and the amine group can be present on the same monomer or on different monomers.
- the polyester pigment embodiment contains polymerized monomer in which at least one type of monomer had a carboxyl group and at least one monomer had an alcohol group; the alcohol group and the carboxyl group can be present on the same monomer, or different monomers.
- the diamine monomers are the preferred monomer for the source of amine groups .
- the diamine monomers have the general formula : H,N - R - NH, wherein R is a straight or branched chain alkylene group of from 2 to 20 carbon atoms, or a cycloalkylene group of from 5 to 6 carbon atoms or a cyclo alkylene group with straight or branched alkyl amino groups additionally having up to three ring substitutions which may be the same or different, such substitution groups selected from the group consisting of C 1 -C 5 alkyl groups.
- diamine monomers include ethylenediamine, 1-amino- 3 -aminomethyl-3 , 5 , 5-trimethyl cyclohexane, (also referred to herein as isophoronediamine) , hexamethylenediamine, l, 12-dodecanediamine, 2-methylpentamethylenediamine, 2-ethyltetramethylenediamine, 1, 2-diaminocyclohexane, 1, 3-diaminocyclohexane, cis 1 , 4-diaminocyclohexane, and trans 1, 4-diaminocyclohexane.
- the isophoronediamine and 2-methylpentamethylenediamine are preferred. Mixtures of diamine monomers may be used.
- the Polyamine Monomers may be used.
- the polyamine monomers typically have the same general structure as the diamine monomers, but contain at least one additional amine group. Mixtures of polyamines may be used.
- the Carboxy-Amine Monomers may be used.
- the carboxyamine monomers contain at least one amine group and at least one carboxylic acid group.
- Carboxy-amine monomers include p-aminobenzoic acid, and lactones, such as caprolactone . Mixtures of carboxy amine monomers may be used.
- alkanolamine monomers have the general formula :
- alkanolamine monomers include ethanolamine, butanolamine, n-propanolamine, and isopropanolamine. Monoethanolamine and monoisopropanolamine are preferred. Mixtures of alkanolamine monomers may be used.
- the polyfunctional alkanolamine monomers have the same general structure as the alkanolamine monomers, but contain at least one additional functional group such as an amine group or alcohol group or carboxylic acid group . Mixtures of alkanolamine monomers may be used .
- the dicarboxylic acid monomers are the preferred monomer for the source of carboxy groups.
- the dicarboxylic acid monomer is a dicarboxylic acid or its ester or anhydride derivative of the general formula :
- R' is: a straight or branched chain alkylene group of from 3 to 20 carbon atoms; a cycloalkylene group of from 5 to 8 carbon atoms, or a cycloalkylene group with straight chain or branched alkyl carboxy groups optionally having up to three ring substitutions, which may be the same or different, such substitution groups selected from the group consisting of C ⁇ alkyl groups; a mono-cyclic or bicyclic arylene group of from 6 to 10 carbon atoms optionally having up to six ring substitutions which may be the same or different, selected from the group consisting of C 1 -C 5 alkyl groups; or a Ci-C j dialkyl ester or an anhydride of the diacid formed by said monocyclic or bicyclic arylene group.
- dicarboxylic acid monomers or ester or anhydride derivatives include phthalic acid/phthalic anhydride, isophthalic acid, terephthalic acid, 2 , 6-naphthalene dicarboxylic acid, succinic acid/succinic anhydride, glutaric acid, adipic acid, azelaic acid, sebacic acid, decanedioic acid, dodecanedioic acid, mixtures of succinic, glutaric and adipic acids, cyclohexane dicarboxylic acid, dimethylisophthalate, dimethylphthalate, dimethylterephthalate, dimethyl 2 , 6-naphthalene dicarboxylate, dimethyladipate, dimethylglutarate, and dimethylsuccinate . Phthalic acid, isophthalic acid and terephthalic acid are preferred. Mixtures of dicarboxylic acid monomers may be used.
- the polyfunctional carboxylic acid monomers have the same general structure as the dicarboxylic acid monomers, but contain at least one additional carboxylic acid group. Mixtures of polyfunctional carboxylic acid monomers may be used. - 7 -
- the difunctional alcohol monomers have the general formula:
- R" ' is : a straight or branched chain alkylene group having 2 to 20 carbon atoms; a cycloalkylene group having 5 to 8 carbon atoms or a cycloalkylene group with straight chain or branched alkyl alcohol groups and optionally having up to three ring substitutions, which may be the same or different, said ring substitution groups containing alkyl groups having 1 to 5 carbon atoms .
- Representative difunctional alcohol monomers include: cyclohexandimethanol , ethylene glycol , propylene glycol . Mixtures of difunctional alcohol monomers may be used. The difunctional alcohol monomer is present from 0% to about 49%, preferably from about 0.1% to about 49%, more preferably from 5% to 40%, of the pigment weight.
- the polyfunctional alcohol monomers have the same general structure as the difunctional alcohol monomers, but contain at least one additional alcohol group. Mixtures of polyfunctional alcohol monomers may be used.
- Illustrative polyhydric alcohol monomers include trimethylolpropane, pentaerythritol available from Celanese, and dipentaerythritol .
- the carboxy-alcohol monomers contain at least one carboxy group and at least one alcohol.
- the carboxy-alcohol monomers include p-hydroxybenzoic acid, 2-chloro-4-hydroxybenzoic acid and salicyslic acid.
- the ratio of carboxylic acid groups to amine groups is preferably 0.75:1 to 1.5:1, more preferably 0.95:1 to 1:1 for polyamide polymers.
- the ratio of carboxylic acid groups to amine and alcohol groups is preferably 0.75:1 to 1.5:1, more preferably
- the fluorescent dyes which are incorporated into the backbone of the polymer chain include both certain conventional fluorescent organic dyes, and benzoxanthene dyes as well as 1H,3H-Z- benzopyrano [6 , 5, 4-mna] xanthene-1, 3-dione, designated herein as " BXDA" which was not previously known to be a fluorescent dye.
- BXDA also known as 3 , 4-benzoxanthenedicarboxylic anhydride, is a non-water soluble fluorescent dye having the following forms • . ,
- x is oxygen or sulfur
- R 1 is: hydrogen; a halogen, preferably chlorine or bromine; an alkyl group having 1 to 6 , preferably 4, carbon atoms, an alkoxy group having 1 to 6 , preferably 4 , carbon atoms ; or a carboalkoxy group having 1 to 6 , preferably 4, carbon atoms;
- R 2 is: hydrogen; an alkyl group having l to 6 , preferably 4 , carbon atoms ; or an alkoxy group having 1 to 6 , preferably 4, carbon atoms.
- BXDA dye which typically produces a fluorescent yellow color
- X is oxygen
- Rj is hydrogen
- R 2 is hydrogen
- the dye is of the anhydride form; this molecule, 1- H, 3-H-Z-benzopyrano [6 , 5, 4-mna] xanthene-1, 3-dione, was not previously known to be a fluorescent dye.
- the conventional fluorescent dyes which are incorporated into the backbone of the polymer chain are those dyes which posses at least one reactive group capable of reacting with the monomers so as to be incorporated into the backbone of the polymer chain.
- Such dyes include, for example, conventional benzoxanthenes , benzothioxanthene , benzoxanthene dicarboxylic anhydride, and benzothioxanthene dicarboxylic anhydride.
- the fluorescent dye comprises from about 0.05 to about 15%, preferably about 0.5 to about 10% of the total weight of the pigment .
- the pigment of the present invention in which fluorescent dye has been incorporated into the backbone of the polymer chain, may be combined with conventional dye that is not incorporated into the backbone, to provide the pigment with a different, modified color.
- a light stabilizer be combined with the pigment.
- the light stabilizer may be added to the pigment or it may be added to the material to be colored, before or after the pigment is added.
- Suitable light stabilizers are conventional, and include, for example, benzotriazols; hindered amines; benzophenones; and metal organic complexes, and mixtures thereof.
- a preferred hindered amine light stabilizer is commercially available as " Tinuvin 770" from Ciba-Geigy.
- Light stabilizers may also be purchased already added to plastic; suitable products of this type are polypropylenes available as " Stamylin” , from DSM Company, and “ Kelbron, " which contain a - 10 -
- Light stabilizer is added to pigment from 0 to 5%, preferably from about 0.1% to about 5%, more preferably about 0.1% to about 2% of pigment weight.
- the fluorescent pigments of the present invention may be altered by including modifiers which react with the monomers during the formation of the polymer.
- modifiers are included to increase the molecular weight by chain extension, alter the softening or melting point, provide enhanced compatibility for particular plastics to be colored, or otherwise complement or enhance the suitability of the pigment for a particular application.
- Preferred modifiers include monofunctional acids, monofunctional amines, monofunctional alcohols, epoxies, metal oxides, metal carbonates and metal acetates.
- Illustrative monofunctional acids include for example, benzoic acid, p-tertbutylbenzoic acid, stearic acid, lauric acid, pelargonic acid, palmitic acid, and cyclohexanecarboxylic acid.
- Illustrative monofunctional amines include, for example, n-nonylamine, isononylamine, stearylamine, cyclohexylamine and benzylamine.
- Illustrative monofunctional alcohols include for example, stearyl alcohol, cetyl alcohol, n-nonyl alcohol, benzyl alcohol, monofunctional aliphatic alcohols having a weight-average molecular weight in the range of from 400 to 700, such as an alcohol having 30-50 carbon atoms and an average molecular weight of 425, available as Unilin 425 from Petrolite, tridecyl alcohol, n-decyl alcohol, cyclohexanol , 2-ethylhexanol and cyclododecanol .
- Illustrative epoxies include bisphenol A epoxies and aliphatic epoxies.
- the amount of modifier used should not adversely affect the basic novel properties of the fluorescent compositions.
- the amount of the reactive modifier, when employed, will range from about 1% to about 20% based on the total weight of the pigment.
- additives such as opacifiers, antioxidants and processing acids are optionally added to the fluorescent pigments.
- Phosphorous acid is optionally added as an antioxidant or - 11-
- Defoamers such as silicone type foam stabilizer, available as Nalco 2300, from Nalco Chemical Co. or Hodag PV 48-R, from Hodag Company, are optionally used.
- the additives may be added prior to, during, or after the condensation reaction is completed.
- the BXDA fluorescent dye is prepared according to the method described in United States Patent Number 3,741,971, to Fuchs O. et . al . issued June 26, 1973.
- the structure of the BXDA dye used in the present invention is shown as structures 5 and 6, column 2, lines 50-60 as an intermediate compound formed in the synthesis of another dye, as disclosed in United States Patent Number 3,741,971.
- the synthesis disclosed in United States Patent Number 3,741,971, is terminated at the anyhdride form.
- Preparation of the Polymer Polymers are prepared by charging the monomers and fluorescent dyes into a vessel equipped with a means of heating, mechanical stirring, and a condenser to remove the water of reaction. Alternatively, the monomers are charged and the dye added later, however the polymerization reaction must not be completed, so as to permit incorporation of the dye into the backbone of the polymer chain. Both methods produce a pigment containing the dye incorporated into the backbone of the polymer chain.
- the polymer formulations preferably contain 0.5-1.2 equivalents, more preferably 0.75 - 1.1 equivalents of amine per equivalent of carboxylic acid for the polyamide embodiment and the polyamide-ester embodiment.
- the polymer formulations preferably contain from about 0.05% to about 20%, more preferably from about 0.5 to about 10% BXDA.
- the amine or alcohol equivalents are equal to or greater than the equivalents of dye being utilized.
- the light fast pigments are substantially linear and have a weight-average molecular weight in the range of from about 500 to -12-
- reaction terminators are optional.
- the molecular weight may be controlled by regulation of the reaction time and temperature.
- the reactive group on the fluorescent dye reacts with the functional groups on the monomers .
- the carboxylic acid group of the dye molecule including the BXDA dye molecule reacts with the amino groups present on monomers. If monomers containing alcohol group are present, the carboxylic groups on the BXDA dye molecules react with alcohol groups on the monomers. As a result, the dye molecule is incorporated into the backbone of the polymer chain as it is formed.
- the light fast pigments of the present invention are prepared by condensation polymerization reactions illustrated by the following examples.
- the cooled resin is typically ground to the desirable particle size.
- the resin has been found to be friable and easily ground to the typical particle size as small as 0.5 microns, although it is typically ground to a size of from about 2 to about 10 microns . Grinding is done in a conventional manner.
- the light fast pigments are typically mixed in either plastic, or paint, as desired.
- injection grade or extrusion grade polyethylene or polypropylene were used such as: Kelburon, a modified propylene elastomer polymer from DSM Holland; Statoil 211038, a modified propylene elastomer polymer from State Oil Company, Sweden; Stamylin, a modified propylene polymer; or polypropylene 4240, from Eastman Kodak Company.
- the plastic containing the pigment was then injected molded, typically in a Newbury injection molder at 450°C to provide a molded plastic article.
- a reaction vessel equipped as described above was charged with 52.9 parts of 2-methylpentamethylenediamine, 109.4 parts 5 cyclohexanedimethanol, 189 parts of isophthalic acid, 5.25 parts of the alcohol modifier, Unilin, and 7.0 parts of the BXDA dye, to provide a dye concentration of 2% pigment weight.
- the mixture was raised to a temperature of 220°C and maintained at that temperature for 120 minutes.
- the resin was cooled to room temperature, ground 10 and added to Statoil 211038, to provide a final concentration of 4% total plastic weight.
- Example 2 Example 2
- a pigment was prepared as in example 5 except that 14.0 parts of the dye was added, to provide a dye concentration of 4% total 15 pigment weight. The pigment was then added to Statoil 211038, to provide a final pigment concentration of 4% total plastic weight.
- Example 3
- a pigment was prepared as in example 7 , and then added to Kelburon, to provide a final pigment concentration of 4% total 20 plastic weight.
- a pigment was prepared by charging 78.9 parts cyclohexanedimethanol, 74.7 parts monoisopropanolamine, 0.6 parts of the silicone foam defoamer, Nalco 2300, 247.85 parts isophthalic
- Example 5 25 acid, 3.5 part phosphorous acid and 7.0 parts BXDA dye, into a reactor, heating the mixture to 210°C for 3 hours, then dumping. The pigment was then added to paint formulation.
- Example 5 25 acid, 3.5 part phosphorous acid and 7.0 parts BXDA dye, into a reactor, heating the mixture to 210°C for 3 hours, then dumping. The pigment was then added to paint formulation.
- Example 5 25 acid, 3.5 part phosphorous acid and 7.0 parts BXDA dye, into a reactor, heating the mixture to 210°C for 3 hours, then dumping. The pigment was then added to paint formulation.
- Example 5 25 acid, 3.5 part phosphorous acid and 7.0 parts BXDA dye
- a reaction vessel equipped as described above was charged with 121 g. of 2-methylpentamethylenediamine, 250 g. cyclohexanedimethanol, 432 g. of isophthalic acid, 12 g of the alcohol modifier, Unilin 425 and 16 g. of the BXDA dye, to provide a dye concentration of 2% total pigment weight.
- the mixture was raised to a temperature of 220°C and maintained at that temperature for 120 minutes.
- the resin was cooled to room temperature and ground, and added to polypropylene 4240.
- Example 12 A pigment was prepared as in Example 12, except that the 4 % pigment, and 1 % Tinuvin 770, light stabilizer, was added to polypropylene 4240.
- Example 8 A pigment was prepared as in Example 12 except that the 4 % pigment, and 0.5 % Tinuvin 770, light stabilizer, was added to polypropylene 4240.
- Example 9 A pigment was prepared as in Example 12 except that the 4 % pigment, and 0.5 % Tinuvin 770, light stabilizer, was added to polypropylene 4240.
- a pigment was prepared as in Example 12 , except that the pigment was added to Kelburon to provide a final concentration of 4% total plastic weight.
- a pigment was prepared as in Example 12, except that 4 % pigment was added to Stamylin 83MF 10.
- Example 11 A pigment was prepared as in Example 12, except that 4 % pigment was added to Stamylin 83MF 10.
- a pigment was prepared as in Example 12 , except that 4 % pigment was added to Stamylin 83MF 90.
- a pigment was prepared as in Example 12, except that 4 % pigment was added to Stamylin 83MF 94.
- a pigment was prepared as in Example 12, except that 4 % pigment was added to Stamylin 83MF 97.
- Example 15 A pigment was prepared by charging the reactor with 1.04 parts zinc oxide, 0.06 parts silicone foam stabilizer, Nalco 2300, 24.79 parts water, 99.98 parts isophrone diamine, 25.97 parts cyclohexylamine, 22.78 parts pentaerythritol, 75.55 parts stearic acid, 153.46 parts isophthalic acid, 7.0 parts BXDA, and 0.41 phosphorous acid. The mixture was heated to 260°C in about 1.5 hours, cooled to 230°C for in about 1.5 hours and then dumped.
- Example 16 A pigment was prepared by charging the reactor with 1.04 parts zinc oxide, 0.06 parts silicone foam stabilizer, Nalco 2300, 24.79 parts water, 99.98 parts isophrone diamine, 25.97 parts cyclohexylamine, 22.78 parts pentaerythritol, 75.55 parts stearic acid, 153.46 parts isophthalic acid, 7.0 parts BXDA, and 0.41 phosphorous acid
- a pigment was prepared by charging 81.1 parts cyclohexane, dimethanol, 75.9 parts mono-isoproponolamine, 251.7 parts isophthalic acid, 0.06 parts Nalco 2300 defoamer, 3.5 parts phosphoric acid and 7.4 parts BXDA into a reactor. The mixture was heated for about 2 hours at 220°C, and then dumped.
- Example 17
- Example 18 A pigment was prepared as in Example 26 except 3.5 parts Tinuvin 770 was also added to the charge.
- a pigment was prepared by charging 162.2 parts cyclohexanedimethanol, 151.8 parts monoisopropanolamine, 503.4 parts isophthalic acid, 0.12 parts Nalco 2200, 7.0 parts 70% phosphoric acid, and 14.5 parts BXDA dye to the reactor. The mixture was heated for 2 hours at 220°C. The mixture was then cooled for 10 minutes then dumped.
- a pigment was prepared by charging a reactor with 244.88 g. cyclohexanedimethanol (90%), 13.63 g. trimethylolpropane, 55.87 g. isophthalic acid, 172.63 g. terephthalic acid, 10 g. Unilin 425, 4 g. Fascat 4101 and 4 g. of silicone foam stabilizer Nalco 2300. The mixture was then heated to 240°C for one hour and 8 g. of the BXDA -16-
- Example 19A A pigment was made as in the previous example except that 8 g. of BXDA was added when the other reagents were charged in the reactor.
- a pigment was prepared by charging the reactor with 177.48 g. cyclohexanedimethanol (90%), 47.40 g. trimethylolpropane, 301.08 g. dimethylterephthalate, 2.8 Fascat 4102, 0.8 g. defoamer Nalco 2341. The mixture was then heated to about 240°C for four hours. Then 8 g. BXDA was added. Next, the mixture was cooled and ground.
- a pigment was prepared as in the previous example except that the 8 g . of BXDA were charged in the reactor along with the other reagents .
- a reaction vessel equipped as above was charged with 91.1 parts isophrone diamine, 88.8 parts cyclohexane dimethanol, 8.0 parts BXDA, 1.5 parts of a 70% solution of phosphorous acid in water and 114 parts of isophthalic acid.
- the batch was heated to 230°C, then 120 parts of polyethylene terephthalate was added in three equal aliquats.
- the batch was heated to 250°C over about one hour and then an additional 64 parts of isophthalic acid was added.
- the batch was maintained at 230°C for 120 minutes, then the product was dumped and cooled to room temperature.
- the solid mass was reduced in particle size by mechanical grinding.
- a pigment containing a conventional coumarin dye was made by mixing a coumarin with an ester-amide polymer carrier to provide a - 17 -
- a pigment containing a conventional fluorescent dye, Golden Yellow a 2H, 13H-3 -phenylpyrazolol-1 , 5-B (thioxantheno) -2 , 1, 10-D, E, F (isoquinoline) -2 , 13-dione was added to the polyamide carrier to provide a solid state solution of dye and polymer; the dye was not incorporated into the backbone of the polymer.
- the pigment was then added to polypropylene, which contains proprietary light stabilizer. Comparative Example C
- a pigment containing the BXDA dye was mixed with paraformaldehyde and toluene sulphonamide to provide a solid state solution of a sulphonamide melamine resin and dye.
- the paraformaldehyde and the toluene sulphonamide do not have groups that react with the novel BXDA dye, thus the dye is not incorporated into the backbone of the polymer chain.
- the pigment was then added to paint formulation. Comparative Example D
- a pigment was prepared as in Example C except a conventional coumarin dye was added rather than the BXDA dye to provide a solid state solution of coumarin dye and sulphonamide melamine resin. Since neither the paraformaldehyde, toluene sulphonamide, nor the coumarin have groups that react with each other, the coumarin dye is not incorporated into the backbone of the polymer chain. The pigment was then added to paint formulation for evaluation.
- a pigment was prepared as in Example A, and added to propylene which contained the light stabilizer Tinuvin 770. - 18 -
- the pigment of the above Examples 1, 2, 3, 6, and 7-15 were dry blended with pelletized plastic using mineral oil as wetting agent and shaken, then molded.
- the molded samples were evaluated for lightfastness, were physically masked over about half of the surface of the plastic article to prevent exposure to light.
- the article was then placed either: outdoors at a 45° angle Cleveland South; or in a fadometer at 0.35 w/m 2 , 50% relative humidity and 65°C black panel temperature; for a duration as noted in Table I.
- the plastic samples were removed and were evaluated by visual inspection. The results are presented in Table I.
- N - pigment contains polymerized units of dye -20-
- SMF - sulphonamide melamine formaldehyde res N - pigment contains polymerized units of dye
- the pigments of Examples 1, 2 and 3 were subjected to fluorescent spectrophotometry using an F-4500 fluorescence spectrophotometer manufactured by Hitachi Instruments, Inc
- the Hitachi Instrument uses a 150 watt xenon lamp and a R3788 photomultiplier detector at 1 0 nm resolution, w th an excitation bandpass at 1, 2 5, 5 and 10 nm and an emission bandpass at 1, 2 5, 5, 10 and 20 nm
- the results are presented in Table III -21-
- the light fast pigment having the BXDA dye incorporated in the backbone of the polymer chain display improved lightfastness as compared to the conventional pigments of the comparative examples.
- the conventional pigments which contain dyes such as coumarin or BTDXA are not incorporated into the backbone of the polymer chain.
- the addition of light stabilizer to the pigment of the present invention further improves the lightfastness.
- the exposed Examples 1, 2, and 3 which contain the pigment having the BXDA dye incorporated in to the backbone of the polymer chain, demonstrate a improved lightfastness when compared to Comparative Example B.
- the exposed portions of Comparative Example B faded relative to the unexposed Comparative Example B, as determined by peak height.
- the pigment of Examples 16, 17 and 18 which contain the BXDA dye were ground using a laboratory impact grinder and combined with conventional ingredients used to make fluorescent inks to provide a fluorescent ink having 10% pigment.
- the ink was drawn down onto cotton cloth, dried and placed in the xenon arc fadometer at 0.35 w/m 2 , 50% relative humidity and 65°C black panel temperature.
- a conventional ink containing 5% conventional pigment also was applied to cotton cloth and tested in the same manner. By 50 hours the conventional ink had disappeared, but the ink containing the light fast pigments of Examples 16, 17 and 18 were still vivid. By 160 hours the inks containing the light fast pigments of Examples 16, 17 and 18 were still vivid. At 320 hours, the ink containing the pigment of Example 18 was still excellent.
Abstract
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Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BR9908535-6A BR9908535A (en) | 1998-01-28 | 1999-01-27 | Fluorescent polymeric pigments |
CA002318972A CA2318972A1 (en) | 1998-01-28 | 1999-01-27 | Fluorescent polymeric pigments |
EP99904307A EP1051441A4 (en) | 1998-01-28 | 1999-01-27 | Fluorescent polymeric pigments |
JP2000529380A JP2002501963A (en) | 1998-01-28 | 1999-01-27 | Fluorescent polymer pigment |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/014,747 | 1998-01-28 | ||
US09/014,747 US6103006A (en) | 1998-01-28 | 1998-01-28 | Fluorescent polymeric pigments |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1999038916A1 true WO1999038916A1 (en) | 1999-08-05 |
Family
ID=21767460
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1999/001686 WO1999038916A1 (en) | 1998-01-28 | 1999-01-27 | Fluorescent polymeric pigments |
Country Status (6)
Country | Link |
---|---|
US (1) | US6103006A (en) |
EP (1) | EP1051441A4 (en) |
JP (1) | JP2002501963A (en) |
BR (1) | BR9908535A (en) |
CA (1) | CA2318972A1 (en) |
WO (1) | WO1999038916A1 (en) |
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FR2811663A1 (en) | 2000-07-13 | 2002-01-18 | Commenplus | Surface finishing luminescent material for ground, wall or glazed surfaces, contains a heat curable resin and a luminescent pigment |
US6582730B2 (en) | 2001-03-30 | 2003-06-24 | Council Of Scientific & Industrial Research | Natural fluorescent dye obtained from a marine invertebrate, compositions containing the said dye and their uses |
US6689391B2 (en) | 2001-03-30 | 2004-02-10 | Council Of Scientific & Industrial Research | Natural non-polar fluorescent dye from a non-bioluminescent marine invertebrate, compositions containing the said dye and its uses |
US6916492B2 (en) | 2001-03-30 | 2005-07-12 | Council Of Scientific & Industrial Research | Natural nontoxic multicolor fluorescent protein dye from a marine invertebrate, compositions containing the said dye and its uses |
US6956122B2 (en) | 2001-09-05 | 2005-10-18 | Council Of Scientific & Industrial Research | Multiple fluorescent natural dye compound from a marine organism |
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US20060063855A1 (en) * | 2003-03-20 | 2006-03-23 | Mca Technologies Gmbh | Process for the preparation of fluorescet and non-fluorescent pigments |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3741971A (en) * | 1967-11-02 | 1973-06-26 | Hoechst Ag | Water insoluble benzoxanthene dicarboxylic acid imide dyestuffs and process for preparing them |
US3915884A (en) * | 1972-05-17 | 1975-10-28 | Day Glo Color Corp | Modified amides for pigments and method for producing the same |
US5236621A (en) * | 1989-09-19 | 1993-08-17 | Day-Glo Color Corp. | Fluorescent pigments |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1142504A (en) * | 1964-12-29 | 1969-02-12 | Dainichiseika Color Chem | Fluorescent and coloured polymers |
CH523308A (en) * | 1967-11-02 | 1972-05-31 | Hoechst Ag | Process for the preparation of water-insoluble benzoxanthene-dicarboximide dyes |
DE2017765C3 (en) * | 1970-04-14 | 1979-08-16 | Hoechst Ag, 6000 Frankfurt | Daytime luminescent pigments, their use and process for their production |
DE2613493A1 (en) * | 1976-03-30 | 1977-10-06 | Hoechst Ag | DYED POLYESTERS, THE PROCESS FOR THEIR MANUFACTURING AND THEIR USE FOR THE COLORING OF PLASTICS |
US4746751A (en) * | 1987-05-07 | 1988-05-24 | Baxter Travenol Laboratories, Inc. | Silicone reactive/fluorescent silane dye compositions |
DE3921498A1 (en) * | 1988-09-28 | 1990-03-29 | Bayer Ag | POLYMER-TIED DYES, METHOD FOR THE PRODUCTION AND USE THEREOF |
US5155149A (en) * | 1991-10-10 | 1992-10-13 | Boc Health Care, Inc. | Silicone polyurethane copolymers containing oxygen sensitive phosphorescent dye compounds |
US5292855A (en) * | 1993-02-18 | 1994-03-08 | Eastman Kodak Company | Water-dissipatable polyesters and amides containing near infrared fluorescent compounds copolymerized therein |
DE19530449A1 (en) * | 1995-08-18 | 1997-02-20 | Bayer Ag | Polymer fluorescent markers |
-
1998
- 1998-01-28 US US09/014,747 patent/US6103006A/en not_active Expired - Lifetime
-
1999
- 1999-01-27 WO PCT/US1999/001686 patent/WO1999038916A1/en not_active Application Discontinuation
- 1999-01-27 CA CA002318972A patent/CA2318972A1/en not_active Abandoned
- 1999-01-27 JP JP2000529380A patent/JP2002501963A/en not_active Withdrawn
- 1999-01-27 EP EP99904307A patent/EP1051441A4/en not_active Withdrawn
- 1999-01-27 BR BR9908535-6A patent/BR9908535A/en not_active Application Discontinuation
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3741971A (en) * | 1967-11-02 | 1973-06-26 | Hoechst Ag | Water insoluble benzoxanthene dicarboxylic acid imide dyestuffs and process for preparing them |
US3915884A (en) * | 1972-05-17 | 1975-10-28 | Day Glo Color Corp | Modified amides for pigments and method for producing the same |
US5236621A (en) * | 1989-09-19 | 1993-08-17 | Day-Glo Color Corp. | Fluorescent pigments |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2811663A1 (en) | 2000-07-13 | 2002-01-18 | Commenplus | Surface finishing luminescent material for ground, wall or glazed surfaces, contains a heat curable resin and a luminescent pigment |
US6582730B2 (en) | 2001-03-30 | 2003-06-24 | Council Of Scientific & Industrial Research | Natural fluorescent dye obtained from a marine invertebrate, compositions containing the said dye and their uses |
US6689391B2 (en) | 2001-03-30 | 2004-02-10 | Council Of Scientific & Industrial Research | Natural non-polar fluorescent dye from a non-bioluminescent marine invertebrate, compositions containing the said dye and its uses |
US6916492B2 (en) | 2001-03-30 | 2005-07-12 | Council Of Scientific & Industrial Research | Natural nontoxic multicolor fluorescent protein dye from a marine invertebrate, compositions containing the said dye and its uses |
US6956122B2 (en) | 2001-09-05 | 2005-10-18 | Council Of Scientific & Industrial Research | Multiple fluorescent natural dye compound from a marine organism |
US7012093B2 (en) | 2001-09-05 | 2006-03-14 | Council Of Scientific & Industrial Research | Multiple fluorescent natural dye compound from a marine organism and method of use thereof |
WO2011036075A1 (en) * | 2009-09-24 | 2011-03-31 | Basf Se | Migration-free coloured copolycondensates for colouring polymers |
CN102510882A (en) * | 2009-09-24 | 2012-06-20 | 巴斯夫欧洲公司 | Migration-free coloured copolycondensates for colouring polymers |
US8697792B2 (en) | 2009-09-24 | 2014-04-15 | Basf Se | Migration-free coloured copolycondensates for colouring polymers |
CN102510882B (en) * | 2009-09-24 | 2015-04-15 | 巴斯夫欧洲公司 | Migration-free coloured copolycondensates for colouring polymers |
WO2013166227A1 (en) * | 2012-05-02 | 2013-11-07 | Eastman Kodak Company | Use of fluorescing toners for imaging |
US9052624B2 (en) | 2012-05-02 | 2015-06-09 | Eastman Kodak Company | Use of fluorescing toners for imaging |
US11279826B2 (en) | 2018-06-27 | 2022-03-22 | Mitsubishi Gas Chemical Company, Inc. | Resin composition and molded article |
US20220396701A1 (en) * | 2021-06-11 | 2022-12-15 | Day-Glo Color Corp. | Hybrid pigments and methods of making same |
Also Published As
Publication number | Publication date |
---|---|
BR9908535A (en) | 2001-10-16 |
EP1051441A4 (en) | 2002-08-07 |
US6103006A (en) | 2000-08-15 |
EP1051441A1 (en) | 2000-11-15 |
CA2318972A1 (en) | 1999-08-05 |
JP2002501963A (en) | 2002-01-22 |
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