WO1999023180A1 - Polyurethane adhesive/sealant remover - Google Patents
Polyurethane adhesive/sealant remover Download PDFInfo
- Publication number
- WO1999023180A1 WO1999023180A1 PCT/US1998/023146 US9823146W WO9923180A1 WO 1999023180 A1 WO1999023180 A1 WO 1999023180A1 US 9823146 W US9823146 W US 9823146W WO 9923180 A1 WO9923180 A1 WO 9923180A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- composition
- adhesive
- sealant
- polyurethane adhesive
- glycol ether
- Prior art date
Links
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G15/00—Apparatus for electrographic processes using a charge pattern
- G03G15/20—Apparatus for electrographic processes using a charge pattern for fixing, e.g. by using heat
- G03G15/2003—Apparatus for electrographic processes using a charge pattern for fixing, e.g. by using heat using heat
- G03G15/2014—Apparatus for electrographic processes using a charge pattern for fixing, e.g. by using heat using heat using contact heat
- G03G15/2053—Structural details of heat elements, e.g. structure of roller or belt, eddy current, induction heating
- G03G15/2057—Structural details of heat elements, e.g. structure of roller or belt, eddy current, induction heating relating to the chemical composition of the heat element and layers thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/3154—Of fluorinated addition polymer from unsaturated monomers
Definitions
- polyurethane adhesive/sealants can be used to accompany thru-hulls for raw water engine intake, air conditioner intakes, macerator in-take and out-take fittings, transducers and so on wherein placement of the material around the fitting during installation creates not only an impermeable seal, but the adhesive prevents the fitting from coming loose.
- Polyurethane adhesive/sealant has enormous adhesion abilities, yet it maintains the ability to remain flexible after it cures. Unique to the polyurethane material is its ability to remain workable for up to four hours, wherein it becomes tack-free in 48 hours and completely cures within seven days . Polyurethane adhesives/sealant further remains flexible after it cures.
- table tops in boats are typically joined by use of polyurethane adhesive. If incorrectly joined, one item may be destroyed in an attempt to separate the items. Even if separated, the remaining adhesive may be difficult to remove requiring scraping or grinding to remove the old adhesive before the new adhesive is employed. Thus, what is lacking is a convenient means of destroying the adhesive bond on cured polyurethane adhesive/sealant without affecting the items to which the adhesive is secured to.
- the instant invention is composition for use in removal of polyurethane adhesive.
- the composition is capable of destroying the adhesive bond of a polyurethane adhesive/sealant such as that adhesive bond produced in the well known 3M 5200.
- the composition consists of PMA glycol ether acetate (l-methoxy-2- acetoxypropane , 2-methoxy-l-acetoxypropane) ; Dipentene; and a nonylphenol polyethylene glycol ether.
- the composition is maintained as a liquid and liberally applied to a cured polyurethane adhesive.
- the acetate ether composition is capable of entering the structure of the adhesive wherein the composition propagates freely throughout the adhesive where it attacks the adhesive bond causing its immediate degradation. As the bond is destroyed, the adhesive/sealant can be easily removed from the item bonded too. For example, if two items are bonded together incorrectly by use of the 3M 5200 polyurethane adhesive/sealant, the adhesive bond can be destroyed upon the liberal application of the acetate ether composition.
- the composition is preferably applied in a liquid form, spray or brush, or as a paste wherein the composition is admixed with an inert material. After a contact time of approximately fifteen minutes, the composition will enter the adhesive causing immediate destruction.
- Still another objective of the instant invention is to disclose a polyurethane adhesive/sealant removal composition capable of effectively destroying the adhesive bond in most bonding applications in less than fifteen minutes.
- the instant invention is a composition for use in removing polyurethane adhesive/sealant such as that manufactured by 3M Corporation and sold under the trademark 5200.
- the adhesive/sealant cures to a tough, flexible, rubbery consistency.
- the polyurethane adhesive/sealant is the most recommended material for permanent bonding of materials because of its enormous adhesive strength.
- the sealant remains permanently flexible which allows some movement without cracking or losing adhesion.
- the composition of the instant invention has the primary constituents of l-methoxy-2-acetoxypropane, 2-methoxy-l- acetoxypropane; Dipentene; and nonylphenol polyethylene glycol ether.
- the 1-methoxy-2 -acetoxypropane forms approximately 98% of the acetate and 2 -methoxy-1-acetoxypropane forming the remaining 2% of the acetate, commercially known as PMA glycol ether acetate.
- PMA glycol ether acetate is sold under the trademark DOWANOL as manufactured by the Dow Chemical Company.
- the PMA glycol ether acetate is admixed with Dipentene and a nonpropanol polyethylene glycol.
- the nonpropanol polyethylene glycol being nonionic surfactant and sold under the trademark TERGITOL NP-9 as manufactured by the Union Carbide Chemical and Plastics Company.
- the glycol ether acetate C10-H12-03 forms 89% of the weight of the composition; Dipentene C10-H16 approximately 8% by weight; and nonpropanol polyethylene glycol ether C33-H60-016 the remaining 2% of the composition.
- the composition can be stored over a period of time if evaporation is prevented. As with any ether acetate, exposure to vapors is not deemed hazardous although may cause slight eye irritation if used in a closed area.
- the composition is applied to fully cured polyurethane adhesive wherein the composition is capable of entering the adhesive causing the degradation of adhesive bond wherein the 5200 can be easily removed. When the adhesive bond is broken, the sealant maintains some resiliency allowing the material to be peeled off.
- composition of the instant invention also operates on other types of adhesive/sealants such as polysulfides and silicone bases adhesive/sealants.
- Polyurethane adhesive/sealant is the primary embodiment as it is recognized as one of the most commonly used materials for permanent bonding because of its adhesive strength; 5200 being the most popular and well established brands. The mixtures stated above are approximate although the preferred mixture ratio at the time of patent submittal. It is to be understood that while we have described certain forms of our invention, it is not to be limited to a specific form or arrangement herein described. It will be apparent to those skilled in the art that various changes may be made without departing from the scope of the invention and the invention is not to be considered limited to what is described in the specification.
Abstract
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU12938/99A AU1293899A (en) | 1997-10-31 | 1998-10-29 | Polyurethane adhesive/sealant remover |
CA002308304A CA2308304C (en) | 1997-10-31 | 1998-10-29 | Polyurethane adhesive/sealant remover |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/962,108 US5935712A (en) | 1997-10-31 | 1997-10-31 | Fuser member with surface treated SnO2, CuO, or mixture filler |
US08/962,108 | 1997-10-31 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1999023180A1 true WO1999023180A1 (en) | 1999-05-14 |
Family
ID=25505431
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1998/021774 WO1999023535A1 (en) | 1997-10-31 | 1998-10-13 | FUSER MEMBER WITH SURFACE TREATED SnO2 FILLER |
PCT/US1998/023146 WO1999023180A1 (en) | 1997-10-31 | 1998-10-29 | Polyurethane adhesive/sealant remover |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1998/021774 WO1999023535A1 (en) | 1997-10-31 | 1998-10-13 | FUSER MEMBER WITH SURFACE TREATED SnO2 FILLER |
Country Status (7)
Country | Link |
---|---|
US (1) | US5935712A (en) |
EP (1) | EP1027631B1 (en) |
JP (1) | JP2001522067A (en) |
AU (1) | AU1293899A (en) |
CA (1) | CA2308304C (en) |
DE (1) | DE69815878T2 (en) |
WO (2) | WO1999023535A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1201735A1 (en) * | 2000-10-27 | 2002-05-02 | Huber Friedrich Aeronova GmbH & Co. | Aqueous lubricant-coolant for mechanical removal of polyurethane based polymers |
CN103525155A (en) * | 2013-09-27 | 2014-01-22 | 韦谷林 | Preparation method of environment-friendly type ink removing adhesive |
Families Citing this family (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6090491A (en) * | 1998-02-27 | 2000-07-18 | Eastman Kodak Company | Fuser member with styrl-treated Al2 O3 filler and functionalized release fluids |
US6218014B1 (en) * | 1998-12-30 | 2001-04-17 | Nexpress Solutions | Fluorocarbon fuser member with silicon carbide filler |
US20020132074A1 (en) * | 2001-01-30 | 2002-09-19 | Gervasi David J. | Chlorofluoro elastomer compositions for use in electrophotoraphic fusing applications |
US6582871B2 (en) | 2001-06-12 | 2003-06-24 | Heidelberger Druckmaschinen Ag | Toner fusing system and process for electrostatographic reproduction, fuser member for toner fusing system and process, and composition for fuser member surface layer |
US6617090B2 (en) | 2001-06-12 | 2003-09-09 | Heidelberger Druckmaschinen Ag | Toner fusing system and process for electrostatographic reproduction |
US6890657B2 (en) | 2001-06-12 | 2005-05-10 | Eastman Kodak Company | Surface contacting member for toner fusing system and process, composition for member surface layer, and process for preparing composition |
US6606476B2 (en) * | 2001-12-19 | 2003-08-12 | Xerox Corporation | Transfix component having haloelastomer and silicone hybrid material |
US6759118B2 (en) | 2002-02-19 | 2004-07-06 | Xerox Corporation | Electrophotographic system with member formed from boron nitride filler coupled to a silane |
EP1387224A3 (en) * | 2002-08-02 | 2011-11-16 | Eastman Kodak Company | Fuser member, apparatus and method for electrostatographic reproduction |
US8092359B1 (en) | 2002-11-13 | 2012-01-10 | Eastman Kodak Company | Fuser member and fuser member surface layer |
US7195853B1 (en) | 2002-11-13 | 2007-03-27 | Eastman Kodak Company | Process for electrostatographic reproduction |
US7056578B2 (en) * | 2002-11-13 | 2006-06-06 | Eastman Kodak Company | Layer comprising nonfibrillatable and autoadhesive plastic particles, and method of preparation |
US7744960B2 (en) * | 2005-05-23 | 2010-06-29 | Xerox Corporation | Process for coating fluoroelastomer fuser member using fluorinated surfactant |
US7651740B2 (en) * | 2005-05-23 | 2010-01-26 | Xerox Corporation | Process for coating fluoroelastomer fuser member using fluorinated surfactant and fluroinated polysiloxane additive blend |
US7485344B2 (en) * | 2005-05-23 | 2009-02-03 | Xerox Corporation | Process for coating fluoroelastomer fuser member layer using blend of two different fluorinated surfactants |
US7641942B2 (en) * | 2005-05-23 | 2010-01-05 | Xerox Corporation | Process for coating fluoroelastomer fuser member using fluorine-containing additive |
US7205513B2 (en) * | 2005-06-27 | 2007-04-17 | Xerox Corporation | Induction heated fuser and fixing members |
US20060292360A1 (en) * | 2005-06-28 | 2006-12-28 | Xerox Corporation | Fuser and fixing members and process for making the same |
US20080152896A1 (en) * | 2006-12-22 | 2008-06-26 | Carolyn Patricia Moorlag | Process to prepare carbon nanotube-reinforced fluoropolymer coatings |
US7732029B1 (en) | 2006-12-22 | 2010-06-08 | Xerox Corporation | Compositions of carbon nanotubes |
US8080318B2 (en) * | 2008-03-07 | 2011-12-20 | Xerox Corporation | Self-healing fuser and fixing members |
KR101495547B1 (en) | 2008-04-17 | 2015-02-25 | 롬엔드하스전자재료코리아유한회사 | Novel compounds for electronic material and organic electronic device using the same |
CN104471012B (en) | 2012-07-30 | 2017-03-29 | 道康宁公司 | The preparation and application of heat conduction condensation reaction curable polyorganosiloxane compositionss and said composition |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS52121045A (en) * | 1976-04-05 | 1977-10-12 | Toyota Motor Corp | Remover of urethane sealant |
US5232515A (en) * | 1991-09-19 | 1993-08-03 | Arco Chemical Technology, L.P. | Water-reducible coating removers containing n-methyl-2-pyrrolidone |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0018140B1 (en) * | 1979-04-04 | 1984-08-01 | Xerox Corporation | A member for, a method of, and a system for fusing toner images to a substrate |
JPS61228481A (en) * | 1985-04-03 | 1986-10-11 | Fuji Xerox Co Ltd | Fixing device for electrophotographic copying machine |
JPS6417080A (en) * | 1987-07-10 | 1989-01-20 | Ricoh Kk | Fixing roller |
US5017432A (en) * | 1988-03-10 | 1991-05-21 | Xerox Corporation | Fuser member |
US5336596A (en) * | 1991-12-23 | 1994-08-09 | Tropix, Inc. | Membrane for chemiluminescent blotting applications |
US5332641A (en) * | 1992-04-27 | 1994-07-26 | Xerox Corporation | Fuser member with an amino silane adhesive layer |
US5269740A (en) * | 1992-11-30 | 1993-12-14 | Eastman Kodak Company | Fuser roll for fixing toner to a substrate |
US5292606A (en) * | 1992-11-30 | 1994-03-08 | Eastman Kodak Company | Fuser roll for fixing toner to a substrate |
US5480724A (en) * | 1992-11-30 | 1996-01-02 | Eastman Kodak Company | Fuser roll for fixing toner to a substrate comprising tin oxide fillers |
US5292562A (en) * | 1992-11-30 | 1994-03-08 | Eastman Kodak Company | Fuser roll for fixing toner to a substrate |
US5401570A (en) * | 1993-08-02 | 1995-03-28 | Xerox Corporation | Coated fuser members |
US5464698A (en) * | 1994-06-29 | 1995-11-07 | Eastman Kodak Company | Fuser members overcoated with fluorocarbon elastomer containing tin oxide |
US5595823A (en) * | 1994-06-29 | 1997-01-21 | Eastman Kodak Company | Fuser members overcoated with fluorocarbon elastomer containing aluminum oxide |
JP3135024B2 (en) * | 1994-09-12 | 2001-02-13 | 富士ゼロックス株式会社 | Toner composition for electrostatic charge development and image forming method |
US5851673A (en) * | 1997-02-25 | 1998-12-22 | Eastman Kodak Company | Toner fuser member having a metal oxide filled fluoroelastomer outer layer with improved toner release |
-
1997
- 1997-10-31 US US08/962,108 patent/US5935712A/en not_active Expired - Lifetime
-
1998
- 1998-10-13 WO PCT/US1998/021774 patent/WO1999023535A1/en active IP Right Grant
- 1998-10-13 EP EP19980953549 patent/EP1027631B1/en not_active Expired - Lifetime
- 1998-10-13 JP JP2000519330A patent/JP2001522067A/en active Pending
- 1998-10-13 DE DE1998615878 patent/DE69815878T2/en not_active Expired - Lifetime
- 1998-10-29 CA CA002308304A patent/CA2308304C/en not_active Expired - Lifetime
- 1998-10-29 WO PCT/US1998/023146 patent/WO1999023180A1/en active Application Filing
- 1998-10-29 AU AU12938/99A patent/AU1293899A/en not_active Abandoned
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS52121045A (en) * | 1976-04-05 | 1977-10-12 | Toyota Motor Corp | Remover of urethane sealant |
US5232515A (en) * | 1991-09-19 | 1993-08-03 | Arco Chemical Technology, L.P. | Water-reducible coating removers containing n-methyl-2-pyrrolidone |
Non-Patent Citations (1)
Title |
---|
DATABASE WPI Week 7747, Derwent World Patents Index; AN 77-83623Y, XP002093990, "Compsn. for removing urethane sealants - comprises water and alcohol and opt. surfactant" * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1201735A1 (en) * | 2000-10-27 | 2002-05-02 | Huber Friedrich Aeronova GmbH & Co. | Aqueous lubricant-coolant for mechanical removal of polyurethane based polymers |
CN103525155A (en) * | 2013-09-27 | 2014-01-22 | 韦谷林 | Preparation method of environment-friendly type ink removing adhesive |
Also Published As
Publication number | Publication date |
---|---|
JP2001522067A (en) | 2001-11-13 |
CA2308304C (en) | 2008-01-08 |
EP1027631B1 (en) | 2003-06-25 |
WO1999023535A1 (en) | 1999-05-14 |
US5935712A (en) | 1999-08-10 |
DE69815878T2 (en) | 2003-12-18 |
CA2308304A1 (en) | 1999-05-14 |
EP1027631A1 (en) | 2000-08-16 |
DE69815878D1 (en) | 2003-07-31 |
AU1293899A (en) | 1999-05-24 |
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