WO1998008893A1

WO1998008893A1 - Carpet backing precoats, laminate coats, and foam coats prepared from polyurethane formulations including fly ash

Info

Publication number: WO1998008893A1
Application number: PCT/US1997/014740
Authority: WO
Inventors: Randall C. Jenkines
Original assignee: The Dow Chemical Company
Priority date: 1996-08-28
Filing date: 1997-08-21
Publication date: 1998-03-05
Also published as: DE69718176T2; US6555199B1; US6096401A; DE69718176D1; AU719798B2; EP0922067A1; KR20000035834A; JP2000517361A; BR9711246A; CA2262782A1; CA2262782C; EP0922067B1; NZ333977A; AU4081697A; TW449605B

Abstract

The present invention is a polyurethane carpet backing prepared from a polyurethane-forming composition wherein fly ash is included as a filler material. High loadings of fly ash can be obtained without detriment to the process for preparing a polyurethane carpet backing, or adverse effect to the physical properties of the carpet baking.

Description

CARPET BACKING PRECOATS, LAMINATE COATS, AND FOAM COATS PREPARED FROM POLYURETHANE FORMULATIONS INCLUDING FLY ASH

The present invention relates to polyurethane-backed articles. The present invention particularly relates to polyurethane-backed articles and to a process and composition used in making same.

Articles having attached polyurethane foam layers are well known. For example, carpets and other substrates having attached polyurethane foam layers as backing are described in U.S. Patent Nos.: 3,755,212; 3,821,130; 3,862.879; 4,022,941 ;

4,171,395; 4,278,482; 4,286,003; 4,296,159; 4,405,393; 4,483,894; 4,512,831 ;

4,515,646; 4,595,436; 4,611,044; 4,657,790; 4,696,849; 4,853,054; 4,853,280 and,

5,104,693. Typically a filler material is used to prepare a polyurethane formulation for carpet backing. The filler can replace some of the polymer required to prepare a polyurethane backed article, while maintaining bulk in the article. This can lower the cost of production of the article, since materials used as fillers are typically less expensive than the polymer material that is being replaced.

In selecting a filler for a particular application, the effect that the filler can have on the process — and on the physical properties of the article — should be considered. For example, in a process for preparing polyurethane backed carpets, a filler that is too alkaline can cause premature gellation. Conversely, a filler that is too acidic can cause an unacceptable delay in the onset of gellation. Increasing the amount of conventional fillers used in preparing carpet backing, such as calcium carbonate (CaCO₃) and aluminum trihydrate (ATH), can result in an undesirable viscosity increase in a polyurethane formulation. While cost reduction can be an incentive for introducing as much filler as possible into a polyurethane formulation, it can be unacceptable to reduce the cost of production at the expense of the quality of the article produced. The amount of filler incorporated into a polyurethane formulation can be limited by the adverse effects that the filler can have on the properties of a polyurethane, such as flexibility, resiliency, and adhesion, for example.

Fly ash has been used as a filler material in systems such as cement and concrete products, roadbases/subbases, and structural fills. See, for example, U.S. Department of Transportation / Federal Highway Administration Report No. FHWA- SA-94-081 (August 1995). The Electric Power Research Institute (EPRI), in EPR1 Report CS-4765 (September 1986) (hereinafter CS-4765), reported that fly ash recovered from a direct acid leaching process was added as a filler to polymerized nylon and polypropylene.

It would be desirable to increase the loading of filler into a polyurethane formulation without detriment to the process of preparing a polyurethane carpet backing, or to the final physical properties of the final product. It would also be desirable to use fly ash as a filler material in a reactive polymeric system without significant effect on a polymer forming reaction.

In one aspect, the present invention is a polyurethane-forming composition, useful for preparing a polyurethane precoat, polyurethane laminate coat, or polyurethane foam coat comprising a polyol; a chain extender; a polyisocyanate; a catalyst; a surfactant; a filler wetting agent; and a filler, wherein the filler includes fly ash; and optionally including a surfactant and a blowing agent. In another aspect, the present invention is a backed carpet having a polyurethane backing that includes at least one coat of polyurethane that is prepared from a polyurethane-forming composition comprising a polyol; a chain extender; a polyisocyanate; a catalyst; a filler wetting agent; a filler, wherein the filler includes fly ash; and optionally including a surfactant and a blowing agent.

In still another aspect, the present invention is a process for preparing a carpet having a polyurethane backing comprising the steps: (1) applying at least one layer of a polyurethane-forming composition to a carpet substrate, wherein the polyurethane- forming composition includes fly ash; and (2) curing the polyurethane-forming composition to form a tack-free polyurethane backing. Applicant has developed a process for preparing a polyurethane composition which incorporates fly ash as a filler material. The process of the present invention can result in an improved process, including increased flow of a polyurethane composition into the backstitch of a carpet. and increased pot life of a polyurethane composition. The use of fly ash as filler reduces pilling and fuzzing of the carpet face, improves flexibility of the carpet during installation, and also reduces puddle gellation during application of a polyurethane- forming composition. In addition, fly ash can be included at a higher loading than conventional fillers, without detriment to established process parameters or to the physical properties of a polyurethane carpet backing.

The polyurethane-forming composition of the present invention comprises a polyol as described herein, a chain extender, a polyisocyanate, a catalyst as described herein, a surfactant, a filler wetting agent, and a filler that includes fly ash. The composition of the present invention contains reactive components such as active hydrogen containing compounds and compounds having isocyanate functionality. Active hydrogen containing compounds are compounds having active hydrogen functionality, wherein at least one hydrogen atom is bonded to an electronegative atom such as sulfur, nitrogen, or oxygen. Active hydrogen containing compounds described herein can contain any combination of hydroxyl , amino, and mercaptyl functionality — in addition to other active hydrogen groups — and can be reacted with isocyanate groups under conditions suitable for preparing a polyurethane carpet backing. The average functionality of an active hydrogen containing compound refers to the average number of active hydrogen groups per compound.

A polyol is an example of an active hydrogen containing compound, in the present invention. As used herein, the term "polyol" can refer to a single polyol or to a mixture of two or more polyols. A polyol of the present invention can have an average equivalent weight of from 500 to 5000, preferably from 750 to 2500, and more preferably from 750 to 2000. The average equivalent weight of a compound can be determined by dividing the average molecular weight of the compound by the functionality of the compound. In the present invention, at least about 30 percent, preferably about 50 percent, and more preferably about 60 percent of the hydroxyl functionality of a polyol is primary hydroxyl functionality. While a wide range of materials can be used, polyether polyols are preferred based on their performance and wide availability. Polymers of propylene oxide which are at least partially end-capped with ethylene oxide are particularly preferred.

Polyols of the present invention are prepared by known methods by reacting an alkylene oxide with a suitable polyhydric initiator compound. The alkylene oxide preferably has 2 - 8 carbon atoms. For example suitable alkylene oxides can be ethylene oxide, propylene oxide, 1,2-butylene oxide, 2,3-butylene oxide, styrene oxide, epichlorohydrin, 3-methyl- 1,2-butylene oxide, like compounds and mixtures thereof, with propylene oxide being the preferred oxide. The initiator compound can be a polyhydric compound such as water, ethylene glycol, propylene glycol, 1 ,2-butane diol, 1,3-butane diol, glycerine, trimethylol propane, p,p'-isopropylidine diphenol, aniline, ammonia, ethylene diamine, aminoethylethanolamine, like compounds and mixtures thereof.

When a single polyol is used in the present invention, the polyol can have an average functionality of from 1.4 to 3.0. Preferably the average functionality of the polyol is from 1.6 to 2.8. A mixture of polyols can be used which includes at least a second polyol in addition to the first polyol. The second polyol can be described in the same manner as the first polyol except that the second polyol can have a functionality of at least about 2.05. Preferably, the second polyol has a functionality of from 2.4 to 3.0, more preferably the functionality is from 2. 5 to 2.95. When a polyol mixture is used, the average functionality of the polyol mixture can be from 1.97 to 2.5, preferably from 1.98 to 2.4 and more preferably from a 1.99 to 2.3.

The present invention optionally includes a chain extender. A chain extender is typically a low equivalent weight active hydrogen containing compound having about 2 active hydrogen groups per molecule. The active hydrogen groups can be hydroxyl, mercaptyl, or amino groups. If the active hydrogen groups are amino groups then the amine is preferably a sterically hindered amine. A sterically hindered amine is an amine that is substituted with bulky groups that tend to inhibit the reactivity of the amine, for example alkyl groups having 2 or more carbons. An amine chain extender can also be blocked, encapsulated, or otherwise rendered less reactive. Preferred chain extenders include glycols and glycol ethers such as: ethylene glycol; 1,4-butane diol; 1 ,6-hexamethylene glycol; dipropylene glycol; tripropylene glycol; diethylene glycol; triethylene glycol; cyclohexanedimethanol; the diverse bisphenols; like compounds and mixtures thereof. Suitable amine chain extenders include: methylene bis(o- chloroaniline); NaCl-blocked methylene dianiline; diethyltoluenediamine; like compounds, and mixtures thereof.

In preparing a polyurethane backing of the present invention, small amounts of chain extender are advantageously used. Generally, from 5 to 50 parts, preferably from 5 to 30 parts of the chain extender per 100 parts of polyol, by weight, are used. More preferably from 5 to 20 parts of chain extender per 100 parts of polyol are used in the practice of the present invention.

The polyurethane-forming composition of the present invention also includes a polyisocyanate. The average functionality of a polyisocyanate is the average number of isocyanate groups per molecule. The polyisocyanate used herein has an average functionality of from 1.9 to 3.0. The polyisocyanate preferably has an average functionality of 1.95 to 2.5, and more preferably from 1.95 to 2.4. Most preferably, the polyisocyanate has an average functionality of from 2.0 to 2.4.

The polyisocyanate can be aliphatic or aromatic. Aromatic polyisocyanates suitable for use herein include: phenyl diisocyanate; 2,4-toluene diisocyanate; 2,6- toluene diisocyanate; ditoluene diisocyanate; naphthalene 1 ,4-diisocyanate; 2,4'- or a combination of 4,4'-diphenylmethane diisocyanate (MDI); polymethylene polyphenylenepolyisocyanates (polymeric MDI); like compounds, and mixtures thereof. Suitable aliphatic polyisocyanates include: the hydrogenated derivatives of suitable aromatic polyisocyanates such as 1 ,6-hexamethylene diisocyanate; isophorone diisocyanate; 1.4-cyclohexyl diisocyanate; like compounds and mixtures thereof.

Prepolymers prepared by reacting a polyol or chain extender with a polyisocyanate are suitable, as well. The polyisocyanate can be used in an amount suitable to prepare a polyurethane-forming composition with an isocyanate index of from 85 to 130. The isocyanate index can be calculated by multiplying the ratio of isocyanate equivalents to active hydrogen equivalents by 100. The preferred isocyanate index is a variable that depends on the amount of water in the textile. Preferably the isocyanate index is in the range of from 85 to 115 for a laminate coat, and preferably from 85 to 110 for a foam coat.

A catalyst is used in the practice of the present invention. Suitable catalysts include tertiary amines, and organometallic compounds, like compounds and mixtures thereof. For example, suitable catalysts include di-n-butyl tin bis(mercaptoacetic acid isooctyl ester), dimethyltin dilaurate, dibutyltin dilaurate, dibutyltin sulfide, stannous octoate, lead octoate, ferric acetylacetonate, bismuth carboxylates, triethylenediamine, N-methyl morpholine, like compounds and mixtures thereof. An amount of catalyst is advantageously employed such that a relatively rapid cure to a tack-free state is obtained. If an organometallic catalyst is employed, such a cure can be obtained using from 0.01 to 0.5 parts per 100 parts of the polyurethane-forming composition, by weight. If a tertiary amine catalyst is employed, the catalyst preferably provides a suitable cure using from 0.01 to 3 parts of tertiary amine catalyst per 100 parts of the polyurethane-forming composition, by weight. Both an amine type catalyst and an organometallic catalyst can be employed in combination.

The present invention includes a filler material. The filler material includes fly ash. The filler can be exclusively fly ash, or it can optionally include conventional fillers such as milled glass, calcium carbonate, ATH, talc, bentonite, antimony trioxide, kaolin, or other known fillers. Preferably, fly ash makes up at least 50 percent by total weight of the filler used in the present invention. More preferably, fly ash makes up at least 75 percent of the filler, and even more preferably at least 90 percent of the filler used in the present invention. Most preferably fly ash makes up substantially all of the filler material, that is at least 99 percent of the filler is fly ash.

Fly ash is a residue that results from the combustion of pulverized coal, and can include various proportions of oxides of silicon (Si), aluminum (Al), iron (Fe), calcium (Ca), and magnesium (Mg). The major portion of fly ash is composed of oxides of aluminum and silicon. Fly ash can be classified as either Class C or Class F type fly ash. Class C fly ash is obtained from subbituminous and lignite coals. Class F fly ash is obtained from bituminous and anthracite coals. The fly ash of the present invention is Class F fly ash. The fly ash used in the present invention can be treated according to known processes to remove impurities or undesirable components. For example, fly ash can be treated by water washing. Alternatively, fly ash can be treated by direct acid leaching (DAL) as described in CS-4765. As another alternative, fly ash suitable for use with the present invention can be purchased commercially.

Fly ash can be included in a formulation of the present invention at a higher loading than can be obtained using conventional fillers. Fly ash can be loaded at greater than 400 parts of fly ash per 100 parts of active hydrogen compounds. Conventional fillers loaded at greater than 400 parts per 100 parts can cause problems in a process for preparing a polyurethane carpet backing. For example, conventional fillers can cause an unacceptable viscosity increase in a polyurethane-forming formulation when included at a concentration of greater than 400 parts. For the purposes of the present invention, filler can be loaded into a precoat or laminate coat at a concentration of from 100 to 1000 parts of filler per 100 parts of active hydrogen containing compounds. Preferably the filler is loaded at a concentration of from 300 to 900 parts per 100 parts. More preferably the filler is loaded at a concentration of from 300 to 700 parts per 100 parts of active hydrogen containing compounds. In a foam coat, filler can be loaded at a concentration of from 100 to 400 parts of filler per 100 parts of active hydrogen containing compounds. Preferably, filler is loaded at from 150 to 400 parts, more preferably from 200 to 400 parts.

The present invention also includes a filler wetting agent. A filler wetting agent generally performs the function of compatiblizing the filler and the polyurethane- forming composition. Useful filler wetting agents can include ethoxylated phosphate esters in an organic carrier. Examples of suitable filler wetting agents include Maphos™ 56, Pegafax™ 410, and Code 5027 (available from Fibro Chem, Inc.).

A filler wetting agent can be included in a polyurethane-forming composition of the present invention at a concentration of at least about 0.5 parts per 100 parts of filler, by weight. Preferably the filler wetting agent is included at a concentration of from 0.5 to 1.5 parts per 100 parts of filler, more preferably from 0.75 to 1.25 parts per 100 parts of filler.

The present invention can include other optional components. For example, a polyurethane-forming composition of the present invention can include a surfactant, a blowing agent, a flame retardant, pigments, antistatic agents, reinforcing fibers, antioxidants, preservatives, water scavengers, acid scavengers. Suitable blowing agents include gases such as air, carbon dioxide, nitrogen, argon, and helium. Also suitable are liquids such as water, volatile halogenated alkanes such as the various chlorfluoromethanes and chlor fluoroethanes, and azo-blowing agents such as azobis(formamide). Preferred in the practice of this invention is the use of a gas as a blowing agent. Particularly preferable is the use of air as a blowing agent. A surfactant can be desirable in the present invention. A surfactant can be particularly useful in preparing a polyurethane foam coat, or a polyurethane laminate coat using a composition of the present invention. Suitable surfactants include block copolymers of ethylene oxide and silicone surfactants. For example, suitable block copolymers of ethylene oxide include copolymers having at least 60 weight percent of the polymer being derived from oxyethylene units, 15 to 40 weight percent of the polymer being derived from polydimethylsiloxane units, and the polymer having a molecular weight of less than 30,000, as described in U.S. Pat. No. 4,483,894. A surfactant can be included in a formulation of the present invention in an amount ranging from 0.01 to 2 parts per 100 parts by weight of polyol.

Backed carpets can include a precoat and a laminate coat applied to the back of a caφet substrate. In addition, a backed caφet can optionally include an attached foam cushion that is applied to the caφet substrate. Generally, caφets having attached cushions are prepared by tufting or weaving yarn into a primary backing, applying an adhesive precoat to the primary backing to bind the tufted material into the backing, and then applying a polyurethane foam cushion. Use of any of the polyurethane coats can be optional in the practice of the present invention. For example, application of a separate polyurethane precoat can be eliminated by application of a sufficient amount of a laminate coat, such that the laminate coat soaks into the caφet weave and performs the function of both a precoat and a laminate coat. Similarly, a polyurethane foam coat can be applied in an amount sufficient to eliminate separate application of a polyurethane precoat or a combination of laminate coat.

Use of a precoat layer is preferred because use of a precoat allows greater flexibility in the processing conditions used in preparing a polyurethane backed caφet. For example, use of a precoat allows use of higher functionality in a polyurethane laminate coat composition. Higher functionality tends to have a detrimental effect on the physical properties of a caφet. A precoat layer can prevent a subsequent laminate coat or foam coat from penetrating the caφet weave, thereby enabling use of a laminate or foam coat having higher functionality without detriment to caφet properties.

In preparing polyurethane-backed caφets according to this invention, the individual components of the polyurethane-forming composition are mixed and applied as a layer of preferably uniform thickness onto one surface of the caφet substrate. It is often preferable to pre-mix all components except the polyisocyanate (and optional blowing agent, when a gas is used) to form a formulated "B-side". This simplifies the metering and mixing at the time the polyurethane-forming composition is prepared. In preparing a frothed polyurethane backing, it is preferred to mix all components and then blend a gas into the mixture, using equipment such as an Oakes or Firestone foamer.

The polyurethane-forming composition is then applied to one surface of a caφet substrate before it cures to a tack-free state. Typically the polyurethane-forming composition is applied to the surface attached to a primary backing. The composition may be applied to the caφet substrate before any substantial curing occurs, using equipment such as a doctor knife, air knife, or extruder to apply and gauge the layer. Alternatively, the composition may be formed into a layer on a moving belt or other suitable apparatus and partially cured, then married to the caφet substrate using equipment such as a double belt (also known as double band) laminator or a moving belt with an applied foam cushion. The amount of polyurethane-forming composition used can vary widely, from 5 to 500 ounces per square yard, depending on the characteristics of the textile. After the layer is applied and gauged, the layer is cured using heat from any suitable heat source such as an infrared oven, a convection oven, or heating plates. A temperature of from 100°C to about 170°C, and a time of from 1 minute to 60 minutes are suitable for curing the polyurethane. The polyurethane-forming composition of the present invention can be used to coat a variety of substrates. For example the composition of the present invention can be used to coat textiles such as: broadloom caφet; carpet tile; automotive caφet; fabrics for automotive trim; paneling and trunk liners; synthetic playing surfaces; tennis ball covers; drapery fabrics; wall-covering fabric; woven and non-woven scrim.

EXAMPLES

The following examples and comparative example were meant to be illustrative of the present invention. These examples and comparative example were not intended to limit the scope of the claims of the present invention and they should not be inteφreted in that manner.

EXAMPLE 1 - PRECOAT A 2000 molecular weight polyether diol (A) was prepared by reacting dipropylene glycol with propylene oxide to a molecular weight of about 1760, followed by reaction with ethylene oxide to a molecular weight of about 2000. 85 grams of component A was mixed with 15 grams of dipropylene glycol, 400 grams of fly ash (AlSil™, JTM grade O1TR), and 4 grams of Code 5027 filler wetting agent. A 23 weight percent isocyanate prepolymer (B) was prepared by reacting a dipropylene/tripropylene glycol mixture (45/55 weight percent) with an equal weight of diphenyl methane 4,4'- diisocyanate. A 27.5 weight percent isocyanate prepolymer (B') mixture was prepared by adding a 2.3 functional polyisocyanate to component B. 59.5 grams of component B' and 0.15 grams of dibutyltin sulfide was added to component A and the components thoroughly mixed. The resulting precoat blend was applied to a commercial grade loop nylon caφet having a woven polypropylene primary backing (Sea Island) with a blade over roll applicator (that is doctored) at a rate of 30 ounces per square yard (opsy). The caφet was cured for eight (8) minutes in an oven maintained at 120°C. A mechanical froth as described in U.S. Pat. No. 5,104.693 was doctored onto the precoated caφet. A non-woven polyester scrim, as described in U.S. Pat. No. 4,853,280 (Style NO. 21 17 from Hoechst Fiber), was placed onto the surface of the uncured froth. The resulting composite was cured for an additional eight (8) minutes at 120°C. The caφet backing was tested for Edge Curl, Edge Ravel, and Tuft Bind as described below. The results of the testing were recorded in Table 1.

Tuft Bind

Tuft Bind was determined according to ASTM D-1335.

Edge Curl Submerge three 2" x 6" pieces of caφet in room temperature water for 30 seconds. Wring the excess water from the caφet. Place the samples on a flat surface with the backing side down. Weight down the samples at the first 2" of the end opposite the end to be measured. Set a timer for 30 minutes and leave the samples undisturbed for the duration of the timer setting. After 30 minutes measure the distance from the flat surface to the backing side of the outer edges of each piece.

Edge Ravel

The Edge Ravel test was conducted using an Instron. Die cut three 2" x 6" caφet samples (1 each from left, right and center of caφet, cut left and right samples no closer than 1" from the edge of the caφet). Condition the samples for at least 24 hours at 23°C + 3°C, 50percent humidity, +_5percent. Prepare the samples by pulling out two complete tuft rows. This can be accomplished using needle nose pliers. Trim any excess primary backing, foam, or scrim away from the third tuft row with scissors. Start pulling the next tuft row approximately 1.5 to 2 inches of total yarn length along the prepared length. Mount the tension load cell (set at either 100 or 10 lbs.) and allow the cell to warm up for 10 minutes. Install the pneumatic jaws on the Instron. Check the crosshead levers to insure that they were in their proper positions. The right lever should be pushed to the rear and the left lever should be pulled toward the front of the machine. Operate the Instron according to the manufacturer's instructions, setting the maximum extension at a setting of 8 and the speed at a setting of 10. Place the test specimen in the lower jaw of the Instron with the prepared edge facing upwards. Secure the partially unraveled tuft row in the upper jaw. Start the test by pressing the UP button on the control panel. Record the results.

EXAMPLE 2 - COMPARATIVE PRECOAT EXAMPLE

The procedure of Example 1 was followed, except 215 parts of ATH was used instead of fly ash, and 1.5 parts of Code 5027 filler wetting agent was used instead of 4 parts. The caφet was tested for edge curl, edge ravel, and tuft bind. The results were recorded in Table 1.

EXAMPLE 3 - LAMINATE COAT PREPARED WITH SCRIM The precoat blend of Example 1 was used with the following exceptions: 65.0 parts of component B' per 100 parts of polyol were included; a blowing agent (water, 0.5 parts per 100 parts of polyol) was included; and, a surfactant (Niax™ L-5614, 0.75 parts per 100 parts of polyol) was included. The formulation was mechanically frothed to a density of 1200 g/ml, and the froth was applied to Sea Island at a rate of 49 opsy. A non-woven polyester scrim, as described in U.S. Pat. No. 4,853,280 (Style NO. 2117 from Hoechst Fiber), was placed onto the surface of the uncured froth. The caφet composite was cured in an oven for 3.5 minutes at 120°C. The scrim was flattened onto the laminate with a smooth roller (regauged) according to a procedure described in U.S. Patent No. 4,278,482. The caφet sample was cured for an additional 4.0 minutes at 120°C. The laminate was tested for tuft bind, edge ravel and edge curl. The results were reported in Table 1.

EXAMPLE 4 - LAMINATE PREPARED WITH A SCRIM

A laminate coat was applied to the same caφet substrate according to the procedure of Example 3. The laminate blend was prepared as in Example 3 except diethylene glycol chain extender was used instead of dipropylene glycol. The results were recorded in Table 1. TABLE 1

EXAMPLE NO 1 ₂Λ 3 4

Caψet Style Sea Island Sea Island Sea Island Sea Island

Tuft Bind (lbs) 1 1 5/10 9 13.3/10 7 1 1 14

Edge Ravel (lbs) 2 0/3 7 2.1/2 1 0 8 1 8

Edge curl (cm) 0/0 0/0 0 01 0 02

'Not an example of the present invention.

EXAMPLE 5 - FOAM COAT

A foam coat was prepared using 90 parts of a polyol (Voranol® 9741), 10 parts of diethylene glycol chain extender per 100 parts of polyol, 220 parts of fly ash filler (AlSil. JTM grade O1TR) per 100 parts of polyol, Code 5027 filler wetting agent (0.5 part per 100 parts of filler). Isonate® 7045 isocyanate (41.5 parts per 100 parts of polyol) dibutyltin sulfide catalyst (0.15 parts per 100 parts of polyol), and Niax L-5614 surfactant (0.75 parts per 100 parts of polyol).

EXAMPLE 6 - VISCOSITY OF COMPOUNDS CONTAINING FLY ASH FILLER The compound viscosity data were obtained using the following procedure. A stock polyol blend was prepared with 85 parts per hundred parts of Voranol® 9120 polyol, 15 parts per hundred parts of dipropylene glycol chain extender, and 1 part per hundred parts of water. A filler wetting agent and a filler were added to the polyol in varying amounts (see Table 2). The components were mixed to 120°F, then cooled to 72°F. The viscosity of the mixtures were determined using a # 7 spindle rotating at 10 φm on a Brookfield viscometer model RVTDV-II. The results were recorded in Table 2.

TABLE 2

Filler ATH (H36U)" CaCO, (D70)¹ AlSιl (OlTR)

Loading 200 300 200 300 200 300 400 400 400

Temperature 72 72 72 72 72 72 72 82 92

(°F)

Viscosity 7200 19600 7600 30800 3600 10400 22400 14000 1 1600 (cps)

"Not an example of the present invention.

Claims

What is claimed is:

1. A polyurethane-forming composition useful for preparing a polyurethane precoat, polyurethane laminate coat, or polyurethane foam coat comprising: (a) a polyol;

(b) a chain extender

(c) a polyisocyanate;

(d) a catalyst;

(e) a filler wetting agent; (f) a filler, wherein the filler includes fly ash.

2. The polyurethane-forming composition of Claim 1 wherein the composition additionally includes:

(1) a surfactant; and (2) a blowing agent.

3. The polyurethane-forming composition of Claim 1 wherein the polyol has an average functionality of from 1.4 to 3.0.

4. The polyurethane composition of Claim 1 wherein the polyol has an average functionality of from 1.6 to 2.8.

5. The polyurethane composition of Claim 1 wherein a polyol mixture is included.

6. The polyurethane composition of Claim 5 wherein the polyol mixture has an average functionality of from 1.97 to 2.5.

7. The polyurethane composition of Claim 5 wherein the polyol mixture has an average functionality of from 1.98 to 2.4.

8. The polyurethane composition of Claim 5 wherein the polyol mixture has an average functionality of from 1.99 to 2.3.

9. The polyurethane composition of Claim 1 wherein the filler includes at least 50 percent fly ash, by weight of total filler.

10. The polyurethane composition of Claim 1 wherein the filler includes at least 75 percent fly ash, by weight of total filler.

1 1. The polyurethane composition of Claim 1 wherein the filler includes at least 90 percent fly ash, by weight of total filler.

12. The polyurethane composition of Claim 1 wherein substantially all of the filler is fly ash.

13. A backed caφet having a polyurethane backing that includes at least one coat of polyurethane that is prepared from a polyurethane-forming composition comprising:

(a) a polyol;

(b) a chain extender

(c) a polyisocyanate; (d) a catalyst;

(e) a filler wetting agent;

(f) a filler, wherein the filler includes fly ash

14. The backed caφet of Claim 13 wherein the polyurethane-forming composition additionally includes:

(1) a surfactant; and

(2) a blowing agent.

15. The backed caφet of Claim 13 wherein the caφet backing includes:

(a) a polyurethane precoat; and

(b) a polyurethane laminate coat.

16. The backed caφet of Claim 15 wherein the precoat and laminate coat each includes fly ash.

17. The backed caφet of Claim 15 wherein the caφet backing additionally includes a polyurethane foam coat.

18. The backed caφet of Claim 17 wherein the precoat. laminate coat and foam coat each includes fly ash.

19. The backed caφet of Claim 13 wherein the caφet backing includes a polyurethane precoat and a polyurethane foam coat.

20. The backed caφet of Claim 19 wherein the foam coat includes fly ash.

21. The backed caφet of Claim 19 wherein the precoat and the foam coat each includes fly ash.

22. A process for preparing a caφet having a polyurethane backing comprising the steps:

(1) applying at least one layer of a polyurethane-forming composition to a caφet substrate, wherein the polyurethane-forming composition includes fly ash; and

(2) curing the polyurethane-forming composition to form a tack-free polyurethane backing.