WO1997048832A3 - Process for making thermally stable metal coated polymeric monofilament or yarn - Google Patents

Process for making thermally stable metal coated polymeric monofilament or yarn Download PDF

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Publication number
WO1997048832A3
WO1997048832A3 PCT/US1997/009116 US9709116W WO9748832A3 WO 1997048832 A3 WO1997048832 A3 WO 1997048832A3 US 9709116 W US9709116 W US 9709116W WO 9748832 A3 WO9748832 A3 WO 9748832A3
Authority
WO
WIPO (PCT)
Prior art keywords
yarn
thermally stable
metal coated
stable metal
coated polymeric
Prior art date
Application number
PCT/US1997/009116
Other languages
French (fr)
Other versions
WO1997048832A2 (en
Inventor
John D Cawston
Merwin F Hoover
Thomas F Burke
Thomas H Stearns
Original Assignee
Du Pont
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/655,733 external-priority patent/US6045680A/en
Priority claimed from US08/656,914 external-priority patent/US5935706A/en
Application filed by Du Pont filed Critical Du Pont
Priority to CA002255646A priority Critical patent/CA2255646C/en
Priority to JP50299398A priority patent/JP4060363B2/en
Priority to EP97944281A priority patent/EP0902854B1/en
Priority to DE69709094T priority patent/DE69709094T2/en
Publication of WO1997048832A2 publication Critical patent/WO1997048832A2/en
Publication of WO1997048832A3 publication Critical patent/WO1997048832A3/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1635—Composition of the substrate
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1635—Composition of the substrate
    • C23C18/1639—Substrates other than metallic, e.g. inorganic or organic or non-conductive
    • C23C18/1641—Organic substrates, e.g. resin, plastic
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1646—Characteristics of the product obtained
    • C23C18/165—Multilayered product
    • C23C18/1653—Two or more layers with at least one layer obtained by electroless plating and one layer obtained by electroplating
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18—Pretreatment of the material to be coated
    • C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
    • C23C18/22—Roughening, e.g. by etching
    • C23C18/24—Roughening, e.g. by etching using acid aqueous solutions
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601—Process or apparatus
    • C23C18/1633—Process of electroless plating
    • C23C18/1655—Process features
    • C23C18/1658—Process features with two steps starting with metal deposition followed by addition of reducing agent
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/18—Pretreatment of the material to be coated
    • C23C18/20—Pretreatment of the material to be coated of organic surfaces, e.g. resins
    • C23C18/28—Sensitising or activating
    • C23C18/30—Activating or accelerating or sensitising with palladium or other noble metal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Textile Engineering (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Chemically Coating (AREA)

Abstract

Monofilaments of a yarn to be coated with electroless nickel are pretreated with an acid and a surfactant to render the monofilament surfaces water wettable and not substantially mechanically degraded. The pretreated yarns is passed through an electroless nickel coating bath under little or no tension so that the electroless nickel can coat all of the monofilament surfaces substantially uniformly. The nickel coated yarn then can be coated with electrolytic metal such as copper in an electrolytic metal plating step, as desired.
PCT/US1997/009116 1996-05-30 1997-05-30 Process for making thermally stable metal coated polymeric monofilament or yarn WO1997048832A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CA002255646A CA2255646C (en) 1996-05-30 1997-05-30 Process for making thermally stable metal coated polymeric monofilament or yarn
JP50299398A JP4060363B2 (en) 1996-05-30 1997-05-30 Production of polymer monofilaments or yarns coated with heat stable metals
EP97944281A EP0902854B1 (en) 1996-05-30 1997-05-30 Process for making thermally stable metal coated polymeric monofilament
DE69709094T DE69709094T2 (en) 1996-05-30 1997-05-30 PROCESS FOR PRODUCING A THERMALLY STABLE, METAL-COATED POLYMER MONOFILAMENT

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US08/655,733 1996-05-30
US08/656,914 1996-05-30
US08/655,733 US6045680A (en) 1996-05-30 1996-05-30 Process for making thermally stable metal coated polymeric monofilament or yarn
US08/656,914 US5935706A (en) 1996-05-30 1996-05-30 Thermally stable metal coated polymeric monofilament or yarn

Publications (2)

Publication Number Publication Date
WO1997048832A2 WO1997048832A2 (en) 1997-12-24
WO1997048832A3 true WO1997048832A3 (en) 1998-02-26

Family

ID=27097017

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1997/009116 WO1997048832A2 (en) 1996-05-30 1997-05-30 Process for making thermally stable metal coated polymeric monofilament or yarn

Country Status (6)

Country Link
EP (1) EP0902854B1 (en)
JP (1) JP4060363B2 (en)
CA (1) CA2255646C (en)
DE (1) DE69709094T2 (en)
ES (1) ES2165628T3 (en)
WO (1) WO1997048832A2 (en)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1435407A1 (en) 2003-01-02 2004-07-07 Teijin Twaron B.V. Aramid filament yarn provided with a conductive finish
WO2006081622A1 (en) * 2005-02-03 2006-08-10 Australian Wool Innovation Limited Fibre coating composition
GB0505822D0 (en) * 2005-03-22 2005-04-27 Conductive Inkjet Tech Ltd Treatment of flexible web material
JP5327494B2 (en) * 2005-11-16 2013-10-30 日立化成株式会社 Method for producing catalyst concentrate for electroless plating and method for applying plating catalyst using the same
GB0614706D0 (en) * 2006-07-25 2006-09-06 Gore W L & Ass Uk Fabric
JP2013533387A (en) * 2010-07-23 2013-08-22 シスコム アドバンスド マテリアルズ Conductive metal coated fiber, continuous method for its preparation, and its use
US9324472B2 (en) 2010-12-29 2016-04-26 Syscom Advanced Materials, Inc. Metal and metallized fiber hybrid wire
JP6220113B2 (en) * 2011-02-17 2017-10-25 矢崎総業株式会社 Manufacturing method of shield sleeve
JP6006931B2 (en) * 2011-11-24 2016-10-12 矢崎総業株式会社 Plated fiber and manufacturing method thereof
JP2014120327A (en) * 2012-12-17 2014-06-30 Yazaki Corp Conductor for electric wire
CN114687205A (en) * 2022-04-19 2022-07-01 中国科学院苏州纳米技术与纳米仿生研究所 Multi-metal compounding method of high polymer fiber material and multi-metal composite fiber

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3234031A (en) * 1961-02-04 1966-02-08 Bayer Ag Reduction nickel plating with boron reducing agents and organic divalent sulfur stabilizers
US3515649A (en) * 1967-05-02 1970-06-02 Ivan C Hepfer Pre-plating conditioning process
GB1243481A (en) * 1969-01-22 1971-08-18 Hoechst Ag Metallisation of plastics
EP0201806A2 (en) * 1985-05-06 1986-11-20 International Business Machines Corporation Process for preparing a substrate for subsequent electroless deposition of a metal
US4634805A (en) * 1985-05-02 1987-01-06 Material Concepts, Inc. Conductive cable or fabric
US4673469A (en) * 1984-06-08 1987-06-16 Mcgean-Rohco, Inc. Method of plating plastics
US5302415A (en) * 1992-12-08 1994-04-12 E. I. Du Pont De Nemours And Company Electroless plated aramid surfaces and a process for making such surfaces

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3234031A (en) * 1961-02-04 1966-02-08 Bayer Ag Reduction nickel plating with boron reducing agents and organic divalent sulfur stabilizers
US3515649A (en) * 1967-05-02 1970-06-02 Ivan C Hepfer Pre-plating conditioning process
GB1243481A (en) * 1969-01-22 1971-08-18 Hoechst Ag Metallisation of plastics
US4673469A (en) * 1984-06-08 1987-06-16 Mcgean-Rohco, Inc. Method of plating plastics
US4634805A (en) * 1985-05-02 1987-01-06 Material Concepts, Inc. Conductive cable or fabric
EP0201806A2 (en) * 1985-05-06 1986-11-20 International Business Machines Corporation Process for preparing a substrate for subsequent electroless deposition of a metal
US5302415A (en) * 1992-12-08 1994-04-12 E. I. Du Pont De Nemours And Company Electroless plated aramid surfaces and a process for making such surfaces

Also Published As

Publication number Publication date
EP0902854B1 (en) 2001-12-12
JP2000512690A (en) 2000-09-26
CA2255646C (en) 2008-04-08
DE69709094D1 (en) 2002-01-24
DE69709094T2 (en) 2002-07-18
WO1997048832A2 (en) 1997-12-24
JP4060363B2 (en) 2008-03-12
EP0902854A2 (en) 1999-03-24
CA2255646A1 (en) 1997-12-24
ES2165628T3 (en) 2002-03-16

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