WO1997045512A1 - Detergent compositions - Google Patents
Detergent compositions Download PDFInfo
- Publication number
- WO1997045512A1 WO1997045512A1 PCT/US1997/008235 US9708235W WO9745512A1 WO 1997045512 A1 WO1997045512 A1 WO 1997045512A1 US 9708235 W US9708235 W US 9708235W WO 9745512 A1 WO9745512 A1 WO 9745512A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- alkyl
- detergent composition
- group
- absent
- acid
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/228—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with phosphorus- or sulfur-containing groups
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3757—(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/378—(Co)polymerised monomers containing sulfur, e.g. sulfonate
Definitions
- the present invention relates to detergent compositions containing a cationic ester surfactant and a grease dispersing agent, which are suitable for use in laundry and dish washing methods.
- Grease dispersing agents can be employed in detergents to achieve prevention of (re)deposition of greasy stains/soils.
- examples of grease dispersing agents are polymers with hydrophobic side chains and hydrophilic monomer units in the backbone.
- EP-B-21,491 discloses detergent compositions containing a nonionic/cationic surfactant mixture and a builder mixture comprising aluminosilicate and polycarboxylate builder.
- the cationic surfactant may be a cationic ester. Improved particulate and greasy /oily soil removal is described.
- US-A-4,228,042 discloses biodegradable cationic surfactants, including cationic ester surfactants for use in detergent compositions to provide greasy /oily soil removal. The combination of these cationic surfactants with nonionic surfactants in compositions designed for particulate soil removal is also described.
- US-A-4,260,529 discloses laundry detergent compositions having a pH of no greater than 11 containing cationic ester surfactant and nonionic surfactant at defined weight ratios.
- WO 91/08281 discloses dispersing polymers for dispersion of detergent droplets, with a hydrophilic backbone and hydrophobic side chains.
- the cationic ester surfactant is can reduce deposition of 'lime soaps' on the fabric. The reduction of deposition will facilitate the absorbance of the grease dispersing agent onto the greasy soils or stains. Thereby, an improvement of their dispersing performance is achieved.
- the cationic ester surfactant can act to facilitate solubilisation of greasy soil/ stain components. This will aid the grease dispersing agent's dispersal of the soil/ stain components. Thus, an overall improved cleaning of the detergent is achieved.
- the detergent composition of the present invention comprises
- the grease dispersing agent is present at a level of from 0.1 % to 15% by weight of the detergent composition.
- the cationic ester surfactant is selected from those having the formula:
- Ri is a C5-C31 linear or branched alkyl, alkenyl or alkaryl chain or M " . N+(R6R7R8)(CH2)s;
- X anc * Y. independently, are selected from the group consisting of COO, OCO, O, CO, OCOO, CONH, NHCO, OCONH and NHCOO wherein at least one of X or Y is a COO, OCO, OCOO, OCONH or NHCOO group;
- R2, R3, R4, R6, R7, and Rs are independently selected from the group consisting of alkyl, alkenyl, hydroxyalkyl, hydroxy-alkenyl and alkaryl groups having from 1 to 4 carbon atoms; and
- R5 is independently H or a C1-C3 alkyl group; wherein the values of m, n, s and t independently lie in the range of from 0 to 8, the value of b lies in the range from 0 to 20, and the values of
- An essential element of the detergent compositions of the invention is a cationic ester surfactant.
- the cationic ester surfactant is preferably present at a level from 0.1 % to 20.0%, more preferably from 0.5% to 10%, most preferably from 1.0% to 5.0% by weight of the detergent composition.
- the cationic ester surfactant of the present invention is a, preferably water dispersible, compound having surfactant properties comprising at least one ester (i.e. -COO-) linkage and at least one cationically charged group.
- Suitable cationic ester surfactants including choline ester surfactants, have for example been disclosed in US Patents No.s 4228042, 4239660 and 4260529.
- ester linkage and cationically charged group are separated from each other in the surfactant molecule by a spacer group consisting of a chain comprising at least three atoms (i.e. of three atoms chain length), preferably from three to eight atoms, more preferably from three to five atoms, most preferably three atoms.
- the atoms forming the spacer group chain are selected from the group consisting of carbon, nitrogen and oxygen atoms and any mixtures thereof, with the proviso that any nitrogen or oxygen atom in said chain connects only with carbon atoms in the chain.
- spacer groups having, for example, -O-O- (i.e.
- spacer groups having, for example -CH2-O- CH2- and -CH2-NH-CH2- linkages are included.
- the spacer group chain comprises only carbon atoms, most preferably the chain is a hydrocarbyl chain.
- Preferred cationic ester surfactants are those having the formula:
- Ri is a C5-C31 linear or branched alkyl, alkenyl or alkaryl chain or M".
- N + (R£R7R8)(CH2)s; X and Y, independently, are selected from the group consisting of COO, OCO, O, CO, OCOO, CONH, NHCO, OCONH and NHCOO wherein at least one of X or Y is a COO, OCO, OCOO, OCONH or NHCOO group;
- R2, R3, R4, Re, R7, and Rs are independently selected from the group consisting of alkyl, alkenyl, hydroxyalkyl and hydroxy-alkenyl groups having from 1 to 4 carbon atoms and alkaryl groups; and
- R5 is independently H or a C1-C3 alkyl group; wherein the values of m, n, s and t independently lie in the range of from 0 to 8, the value of b lies in the range from 0 to 20, and the values of a,
- M is selected from the group consisting of halide, methyl sulfate, sulfate, and nitrate, more preferably methyl sulfate, chloride, bromide or iodide.
- the cationic ester surfactant is selected from those having the formula:
- Ri is a C5-C31 linear or branched alkyl, alkenyl or alkaryl chain
- X is selected from the group consisting of COO, OCO, OCOO, OCONH and NHCOO
- R2, R3, and R4 are independently selected from the group consisting of alkyl and hydroxyalkyl groups having from 1 to 4 carbon atoms
- R5 is independently H or a C1-C3 alkyl group; wherein the value of n lies in the range of from 0 to 8, the value of b lies in the range from 0 to 20, the value of a is either 0 or 1 , and the value of m is from 3 to 8.
- R2, R3 and R4 are independently selected from a C1-C4 alkyl group and a C1-C4 hydroxyalkyl group.
- at least one, preferably only one, of R2, R3 and R4 is a hydroxyalkyl group.
- the hydroxyalkyl preferably has from 1 to 4 carbon atoms, more preferably 2 or 3 carbon atoms, most preferably 2 carbon atoms.
- at least one of R2, R3 and R4 is a C2-C3 alkyl group, more preferably two C2-C3 alkyl groups are present.
- Suitable cationic ester surfactants have the structural formulas below, wherein d may be from 0 to 20.
- the cationic ester surfactant is hydrolysable under the conditions of a laundry wash method.
- the particularly preferred choline esters may be prepared by the direct esterification of a fatty acid of the desired chain length with dimethylaminoethanol, in the presence of an acid catalyst.
- the reaction product is then quaternized with a methyl halide, preferably in the presence of a solvent such as ethanol, water, propylene glycol or preferably a fatty alcohol ethoxylate such as C IQ-CIS fatty alcohol ethoxylate having a degree of ethoxylation of from 3 to 50 ethoxy groups per mole forming the desired cationic material.
- a solvent such as ethanol, water, propylene glycol or preferably a fatty alcohol ethoxylate such as C IQ-CIS fatty alcohol ethoxylate having a degree of ethoxylation of from 3 to 50 ethoxy groups per mole forming the desired cationic material.
- They may also be prepared by the direct esterification of a long chain fatty acid of the desired chain length together with 2-haloethanol
- An essential element of the present invention is a grease dispersing agent.
- grease dispersing agent is meant herein a component capable of dispersing or suspending greasy stain/ soil components into the (wash) solution.
- the grease dispersing agents in accord with the present invention are typically polymers, which have a hydrophilic backbone and at least one hydrophobic side chain.
- the hydrophobic side chain acts functionally to provide affinity of the grease dispersing agent for greasy soil/stain components.
- the hydrophilic backbone acts functionally to provide affinity of the grease dispersing agent for aqueous environments.
- the hydrophilic backbone of the polymer is predominantly linear (the main chain of the backbone constitutes at least 50 % , preferably more than 75% , most preferred more than 90% by weight of the backbone), suitable monomer constituents of the hydrophilic backbone are for example unsaturated Ci-C ⁇ acids, ethers, alcohols, aldehydes, ketones or esters, sugar units, alkoxy units, maleic anhydride and saturated polyalcohols such as glycerol.
- suitable monomer units are acrylic acid, methacrylic acid, maleic acid, vinyl acetic acid, glucosides, ethylene oxide and glycerol.
- the hydrophilic backbone made from the backbone constituents in the absence of hydrophobic side-groups is relatively water-soluble at ambient temperatures and a pH of between 6.5 and 14.0.
- the solubility is more than 1 g/l, more preferably more than 5 g/l, most preferably more than 10 g/l.
- the hydrophobic sidegroups are composed of alkoxy groups for example butylene oxide and/or propylene oxide and/or alkyl or alkenyl chains having from 5 to 24 carbon atoms.
- the hydrophobic groups may be connected to the hydrophilic backbone via relatively hydrophilic bonds for example a poly ethoxy linkage.
- Preferred grease dispersing agents are the polymers of the formula:
- Q2 is a molecular entity of formula (la):
- R 1 represents -COO-0-, -0-, -0-CO-, XH2-, CO-NH-, or is absent:
- R2 represents from 1 to 50 independently selected alkyleneoxy groups preferably ethylene oxide or propylene oxide groups, or is absent, provided that when R-* is absent and R4 represents hydrogen or contains no more than 4 carbon atoms, then R2 must contain an alkyleneoxy group preferably more than 5 alkyleneoxy groups with at least 3 carbon atoms;
- R3 represents a phenylene linkage, or is absent
- R4 represents hydrogen or a C ⁇ _24 alkyl or C2-24 alkenyl group, with the provisos that
- R5 represents hydrogen or a group of formula -COOA 4 ;
- R6 represents hydrogen or C 1.4 alkyl
- Ql is a multifunctional monomer, allowing the branching of the polymer, wherein the monomers of the polymer may be connected to Q* in any direction, in any order, therewith possibly resulting in a branched polymer.
- Ql is trimethyl propane triacrylate (TMPTA), methylene bisacrylamide or divinyl glycol.
- z and v are 1 ; n is at least 1 ; x is at least l; (x + y + p -f q + r) : z is from 4 : 1 to 1,000 : 1, preferably from 6 : 1 to 250 : 1; in which the monomer units may be in random order; and preferably p and q are zero and/or r is zero; most preferably p, q, y and r are zero.
- R? and R represents -CH3 or is a hydrogen
- R9 and R*0 represent substituent groups such as amino, amine, amide, sulphonate, sulphate, phosphonate, phosphate, hydroxy, carboxyl and oxide groups, preferably they are selected from -S ⁇ 3Na, -CO-O-C2H4- OS ⁇ 3Na, -CO-0-NH-C(CH3)2-S03Na, -CO-NH2, -O-CO-CH3, -OH;
- the monomers of the polymer may be variable in direction and position along the polymer backbone and along the side chain(s).
- polymeric grease dispersing agents for use in compositions of the invention which are of relatively high pH (say 10 or more) are substantially free of hydrolysable groups such as carbonyl groups for increased polymer stability at high pH values.
- Particularly preferred polymeric grease dispersing agents for use in high pH compositions of the invention comprise hydrophilic backbones constituted by acid groups such as acrylic acid and at least one hydrophobic side chain which is constituted of from 5 to 75 relatively water-insoluble alkoxy groups such as propoxy units optionally linked to the hydrophilic backbone via a poly- alkoxy linkage constituted of from 1-10 relatively water soluble alkoxy groups such as ethoxy units.
- Especially preferred grease dispersing agents of this type are the polymers of the formula :-
- - R2 represents -CO-0-, -0-, -O-CO-, CH2-, -CO-NH-, or is absent;
- - Rl represents -C3H6-N + -(CH3)3(C1"), -C2H4-OS ⁇ 3-(Na+), -S0 3 -(Na + ), -C 2 H 4 N + (CH 3 ) 3 CI " , -C 2 H 4 N+ (C 2 H 6 )3 CI".
- R a is CH2, C2H4, C3H6 or is absent;
- R° represents form 1 to 50 independently selected alkylene oxide groups, preferably ethylene oxide groups or is absent;
- R c represents -OH or -H; and wherein if R2, Ra and R D are absent, then R c is not -H.
- - Rl represents -CH2O- or -0-;
- - R2 represents -CH2COO"Na + , -C3H6 ⁇ N + (CH3)3Cl" or -C3H3N + (CH 3 ) 3 C1-
- R3 and R 4 represents -OH, CH2OH, -0(C3H6 ⁇ )p-H, -CH2-0(C 3 H6 ⁇ )p-H or -OCH2COO"Na+ or -0-C3H6 ⁇ N + (CH3)3Cl- or -0- C 3 H 6 N + (CH3)3Cl-
- - R5 represents -OH, ONH-CO-CH3 or -0(C3H6 ⁇ )p-H
- - R6 represents -OH, -CH2OH, -CH2-OCH3, -0(C3H6 ⁇ )p-H or -CH2-0-(C 3 H 6 0)p-H
- - p is from 1 - 10.
- grease dispersing agents for use in compositions have a molecular weight of between 500 and 100,000, more preferred from 1 ,000 to 20,000, especially preferred from 1,500 to 10,000 most preferred from 2,800 to 6,000.
- Grease dispersing agents for use in compositions of the invention may for example be prepared by using conventional aqueous polymerisation procedures, suitable methods are for example described in GB 89 24477, GB 89 24478 and GB 89 24479.
- the grease dispersing agent will be used at from 0.1 % to 15 % , more preferably from 0.5% to 8.0% , especially preferred from 1.0% to 5.0% by weight of the detergent composition.
- the detergent compositions of the invention may also contain additional detergent components.
- additional detergent components and levels of inco ⁇ oration thereof will depend on the physical form of the composition, and the precise nature of the washing operation for which it is to be used.
- compositions of the invention preferably contain one or more additional detergent components selected from additional surfactants, bleaches, builders, additional enzymes, suds suppressors, lime soap dispersants, and corrosion inhibitors.
- additional surfactant selected from additional surfactants, bleaches, builders, additional enzymes, suds suppressors, lime soap dispersants, and corrosion inhibitors.
- the detergent compositions of the invention preferably contain an additional surfactant selected from anionic, nonionic, non-ester cationic, ampholytic, amphoteric and zwitterionic surfactants and mixtures thereof.
- ampholytic, amphoteric and zwitteronic surfactants are generally used in combination with one or more anionic and/or nonionic surfactants.
- the detergent compositions in accord with the present invention preferably comprise an additional anionic surfactant.
- anionic surfactants useful for detersive pu ⁇ oses can be comprised in the detergent composition. These can include salts (including, for example, sodium, potassium, ammonium, and substituted ammonium salts such as mono-, di- and triethanolamine salts) of the anionic sulfate, sulfonate, carboxylate and sarcosinate surfactants.
- Anionic sulfate surfactants are preferred.
- anionic surfactants include the isethionates such as the acyl isethionates, N-acyl taurates, fatty acid amides of methyl tauride, alkyl succinates and sulfosuccinates, monoesters of sulfosuccinate (especially saturated and unsaturated C ⁇ -Cig monoesters) diesters of sulfosuccinate (especially sat urated and unsaturated Cg-C ⁇ diesters), N-acyl sarcosinates.
- Resin acids and hydrogenated resin acids are also suitable, such as rosin, hydrogenated rosin, and resin acids and hydrogenated resin acids present in or derived from tallow oil.
- Anionic sulfate surfactant include the isethionates such as the acyl isethionates, N-acyl taurates, fatty acid amides of methyl tauride, alkyl succinates and sulfosuccinates
- Anionic sulfate surfactants suitable for use herein include the linear and branched primary and secondary alkyl sulfates, alkyl ethoxysulfates, fatty oleoyl glycerol sulfates, alkyl phenol ethylene oxide ether sulfates, the C5-C17 acyl-N-(C ⁇ -C4 alkyl) and -N-(C ⁇ -C2 hydroxyalkyl) glucamine sulfates, and sulfates of alkylpolysaccharides such as the sulfates of alkylpolyglucoside (the nonionic nonsulfated compounds being described herein).
- Alkyl sulfate surfactants are preferably selected from the linear and branched primary C10-C18 alkyl sulfates, more preferably the C11-C15 branched chain alkyl sulfates and the C12-C14 linear chain alkyl sulfates.
- Alkyl ethoxysulfate surfactants are preferably selected from the group consisting of the Cio-Cig alkyl sulfates which have been ethoxylated with from 0.5 to 20 moles of ethylene oxide per molecule. More preferably, the alkyl ethoxysulfate surfactant is a Cn-Cis, most preferably C11-C15 alkyl sulfate which has been ethoxylated with from 0.5 to 7, preferably from 1 to 5, moles of ethylene oxide per molecule.
- a particularly preferred aspect of the invention employs mixtures of the preferred alkyl sulfate and alkyl ethoxysulfate surfactants. Such mixtures have been disclosed in PCT Patent Application No. WO 93/18124.
- Anionic sulfonate surfactant Anionic sulfonate surfactant
- Anionic sulfonate surfactants suitable for use herein include the salts of C5-C20 linear alkylbenzene sulfonates, alkyl ester sulfonates, C6-C22 primary or secondary alkane sulfonates, C6-C24 olefin sulfonates, sulfonated polycarboxylic acids, alkyl glycerol sulfonates, fatty acyl glycerol sulfonates, fatty oleyl glycerol sulfonates, and any mixtures thereof.
- Anionic carboxylate surfactant Suitable anionic carboxylate surfactants include the alkyl ethoxy carboxylates, the alkyl polyethoxy polycarboxylate surfactants and the soaps ('alkyl carboxyls'), especially certain secondary soaps as described herein.
- Suitable alkyl ethoxy carboxylates include those with the formula RO(CH2CH2 ⁇ ) x CH2COO-M + wherein R is a C ⁇ to C18 alkyl group, x ranges from O to 10, and the ethoxylate distribution is such that, on a weight basis, the amount of material where x is 0 is less than 20 % and M is a cation.
- Suitable alkyl polyethoxy polycarboxylate surfactants include those having the formula RO-(CHR ⁇ -CHR2-0)-R3 wherein R is a C ⁇ to Cjg alkyl group, x is from 1 to 25, Ri and R2 are selected from the group consisting of hydrogen, methyl acid radical, succinic acid radical, hydroxysuccinic acid radical, and mixtures thereof, and R3 is selected from the group consisting of hydrogen, substituted or unsubstituted hydrocarbon having between 1 and 8 carbon atoms, and mixtures thereof.
- Suitable soap surfactants include the secondary soap surfactants which contain a carboxyl unit connected to a secondary carbon.
- Preferred secondary soap surfactants for use herein are water-soluble members selected from the group consisting of the water-soluble salts of 2-methyl- 1-undecanoic acid, 2-ethyl-l-decanoic acid, 2-propyl-l-nonanoic acid, 2- butyl-1-octanoic acid and 2-pentyl-l-heptanoic acid. Certain soaps may also be included as suds suppressors.
- alkali metal sarcosinates of formula R-CON (R*) CH2 COOM, wherein R is a C5-C17 linear or branched alkyl or alkenyl group, Rl is a C1-C4 alkyl group and M is an alkali metal ion.
- R is a C5-C17 linear or branched alkyl or alkenyl group
- Rl is a C1-C4 alkyl group
- M is an alkali metal ion.
- alkoxylated nonionic surfactants are suitable herein.
- the ethoxylated and propoxylated nonionic surfactants are preferred.
- Preferred alkoxylated surfactants can be selected from the classes of the nonionic condensates of alkyl phenols, nonionic ethoxylated alcohols, nonionic ethoxy lated/propoxylated fatty alcohols, nonionic ethoxylate/propoxylate condensates with propylene glycol, and the nonionic ethoxylate condensation products with propylene oxide/ethylene diamine adducts.
- the condensation products of aliphatic alcohols with from 1 to 25 moles of alkylene oxide, particularly ethylene oxide and/or propylene oxide, are suitable for use herein.
- the alkyl chain of the aliphatic alcohol can either be straight or branched, primary or secondary, and generally contains from 6 to 22 carbon atoms.
- Particularly preferred are the condensation products of alcohols having an alkyl group containing from 8 to 20 carbon atoms with from 2 to 10 moles of ethylene oxide per mole of alcohol.
- Nonionic polvhvdroxy fatty acid amide surfactant Nonionic polvhvdroxy fatty acid amide surfactant
- Polyhydroxy fatty acid amides suitable for use herein are those having the structural formula R2C0NRlZ wherein : RI is H, C 1-C4 hydrocarbyl, 2- hydroxy ethyl, 2-hydroxy propyl, ethoxy, propoxy, or a mixture thereof, preferable C1-C4 alkyl, more preferably Ci or C2 alkyl, most preferably Ci alkyl (i.e., methyl); and R2 is a C5-C31 hydrocarbyl, preferably straight-chain C5-C19 alkyl or alkenyl, more preferably straight-chain C9-C17 alkyl or alkenyl, most preferably straight-chain C11-C17 alkyl or alkenyl, or mixture thereof; and Z is a polyhydroxy hydrocarbyl having a linear hydrocarbyl chain with at least 3 hydroxyls directly connected to the chain, or an alkoxylated derivative (preferably ethoxylated or propoxylated) thereof. Z preferably will be
- Nonionic fatty acid amide surfactant Nonionic fatty acid amide surfactant
- Suitable fatty acid amide surfactants include those having the formula: R6C0N(R7)2 wherein R6 is an alkyl group containing from 7 to 21 , preferably from 9 to 17 carbon atoms and each R7 is selected from the group consisting of hydrogen, C1-C4 alkyl, C1-C4 hydroxyalkyl, and - (C2H4 ⁇ ) x H, where x is in the range of from 1 to 3.
- Suitable alkylpolysaccharides for use herein are disclosed in U.S. Patent 4,565,647, Llenado, issued January 21, 1986, having a hydrophobic group containing from 6 to 30 carbon atoms and a polysaccharide, e.g., a polyglycoside, hydrophilic group containing from 1.3 to 10 saccharide units.
- Preferred alkylpolyglycosides have the formula
- R2 is selected from the group consisting of alkyl, alkylphenyl, hydroxyalkyl, hydroxyalkylphenyl, and mixtures thereof in which the alkyl groups contain from 10 to 18 carbon atoms; n is 2 or 3; t is from 0 to 10, and x is from 1.3 to 8.
- the glycosyl is preferably derived from glucose.
- Suitable amphoteric surfactants for use herein include the amine oxide surfactants and the alkyl amphocarboxylic acids.
- Suitable amine oxides include those compounds having the formula R3(OR 4 ) X N0(R5)2 wherein R3 is selected from an alkyl, hydroxyalkyl, acylamidopropoyl and alkyl phenyl group, or mixtures thereof, containing from 8 to 26 carbon atoms; R 4 is an alkylene or hydroxy alkylene group containing from 2 to 3 carbon atoms, or mixtures thereof; x is from 0 to 5, preferably from 0 to 3; and each R ⁇ is an alkyl or hydroxyalkyl group containing from 1 to 3, or a polyethylene oxide group containing from 1 to 3 ethylene oxide groups.
- Preferred are C10-C 18 alkyl dimethylamine oxide, and CiO-18 acylamido alkyl dimethylamine oxide.
- a suitable example of an alkyl aphodicarboxylic acid is Miranol(TM) C2M Cone, manufactured by Miranol, Inc., Dayton, NJ.
- Zwitterionic surfactants can also be inco ⁇ orated into the detergent compositions hereof. These surfactants can be broadly described as derivatives of secondary and tertiary amines, derivatives of heterocyclic secondary and tertiary amines, or derivatives of quaternary ammonium, quaternary phosphonium or tertiary sulfonium compounds. Betaine and sultaine surfactants are exemplary zwitterionic surfactants for use herein.
- Suitable betaines are those compounds having the formula R(R')2N+R2cOO- wherein R is a C6-C18 hydrocarbyl group, each R 1 is typically C1-C3 alkyl, and R2 is a C1-C5 hydrocarbyl group.
- Preferred betaines are C 12- 18 dimethyl-ammonio hexanoate and the CiO-18 acylamidopropane (or ethane) dimethyl (or diethyl) betaines.
- Complex betaine surfactants are also suitable for use herein.
- Suitable cationic surfactants include the quaternary ammonium surfactants selected from mono C ⁇ -C M,, preferably C-6-C10 N-alkyl or alkenyl ammonium surfactants wherein the remaining N positions are substituted by methyl, hydroxyethyl or hydroxypropyl groups.
- alkalinity system is present to achieve optimal cationic ester surfactant performance.
- the alkalinity system comprises components capable of providing alkalinity species in solution.
- alkalinity species it is meant herein: carbonate, bicarbonate, hydroxide, the various silicate anions, percarbonate, perborates, pe ⁇ hosphates, persulfate and persilicate.
- alkalinity species can be formed for example, when alkaline salts selected from alkali metal or alkaline earth carbonate, bicarbonate, hydroxide or silicate, including crystalline layered silicate, salts and percarbonate, perborates, pe ⁇ hosphates, persulfate and persilicate salts and any mixtures thereof are dissolved in water.
- alkaline salts selected from alkali metal or alkaline earth carbonate, bicarbonate, hydroxide or silicate, including crystalline layered silicate, salts and percarbonate, perborates, pe ⁇ hosphates, persulfate and persilicate salts and any mixtures thereof are dissolved in water.
- Examples of carbonates are the alkaline earth and alkali metal carbonates, including sodium carbonate and sesqui-carbonate and any mixtures thereof with ultra-fine calcium carbonate such as are disclosed in German Patent Application No. 2,321,001 published on November 15, 1973.
- Suitable silicates include the water soluble sodium silicates with an Si ⁇ 2: Na2 ⁇ ratio of from 1.0 to 2.8, with ratios of from 1.6 to 2.0 being preferred, and 2.0 ratio being most preferred.
- the silicates may be in the form of either the anhydrous salt or a hydrated salt.
- Sodium silicate with an Si ⁇ 2: Na2 ⁇ ratio of 2.0 is the most preferred silicate.
- Preferred crystalline layered silicates for use herein have the general formula
- M is sodium or hydrogen
- x is a number from 1.9 to 4 and y is a number from 0 to 20.
- Crystalline layered sodium silicates of this type are disclosed in EP-A-0164514 and methods for their preparation are disclosed in DE-A-3417649 and DE-A-3742043.
- x in the general formula above preferably has a value of 2, 3 or 4 and is preferably 2.
- the most preferred material is ⁇ -Na2Si2 ⁇ 5, available from Hoechst AG as NaSKS-6.
- the detergent compositions of the present invention preferably contain a water-soluble builder compound, typically present at a level of from 1 % to 80% by weight, preferably from 10% to 70% by weight, most preferably from 20% to 60% by weight of the composition.
- Suitable water-soluble builder compounds include the water soluble monomeric polycarboxylates, or their acid forms, homo or copolymeric polycarboxylic acids or their salts in which the polycarboxylic acid comprises at least two carboxylic radicals separated from each other by not more that two carbon atoms, borates, phosphates, and mixtures of any of the foregoing.
- the carboxylate or polycarboxylate builder can be momomeric or oligomeric in type although monomeric polycarboxylates are generally preferred for reasons of cost and performance.
- Suitable carboxylates containing one carboxy group include the water soluble salts of lactic acid, glycolic acid and ether derivatives thereof.
- Polycarboxylates containing two carboxy groups include the water-soluble salts of succinic acid, malonic acid, (ethylenedioxy) diacetic acid, maleic acid, diglycolic acid, tartaric acid, tartronic acid and fumaric acid, as well as the ether carboxylates and the sulfinyl carboxylates.
- Polycarboxylates containing three carboxy groups include, in particular, water-soluble citrates, aconitrates and citraconates as well as succinate derivatives such as the carboxymethyloxysuccinates described in British Patent No. 1,379,241, lactoxysuccinates described in British Patent No. 1,389,732, and aminosuccinates described in Netherlands Application 7205873, and the oxypolycarboxylate materials such as 2-oxa-l,l,3-propane tricarboxylates described in British Patent No. 1,387,447.
- Polycarboxylates containing four carboxy groups include oxydisuccinates disclosed in British Patent No. 1,261,829, 1,1,2,2-ethane tetracarboxylates, 1,1, 3, 3 -propane tetracarboxylates and 1,1,2,3-propane tetracarboxylates.
- Polycarboxylates containing sulfo substituents include the sulfosuccinate derivatives disclosed in British Patent Nos. 1,398,421 and 1,398,422 and in U.S. Patent No. 3,936,448, and the sulfonated pyrolysed citrates described in British Patent No. 1,439,000.
- Preferred polycarboxylates are hydroxycarboxylates containing up to three carboxy groups per molecule, more particularly citrates.
- the parent acids of the monomeric or oligomeric polycarboxylate chelating agents or mixtures thereof with their salts e.g. citric acid or citrate/citric acid mixtures are also contemplated as useful builder components.
- Suitable examples of water-soluble phosphate builders are the alkali metal tripolyphosphates, sodium, potassium and ammonium pyrophosphate, sodium and potassium and ammonium pyrophosphate, sodium and potassium orthophosphate, sodium polymeta/phosphate in which the degree of polymerization ranges from about 6 to 21 , and salts of phytic acid.
- Partially soluble or insoluble builder compound Partially soluble or insoluble builder compound
- the detergent compositions of the present invention may contain a partially soluble or insoluble builder compound, typically present at a level of from 1 % to 80% by weight, preferably from 10% to 70% by weight, most preferably from 20% to 60% weight of the composition.
- Examples of largely water insoluble builders include the sodium aluminosilicates.
- Suitable aluminosilicate zeolites have the unit cell formula Na z [(Al ⁇ 2)z(Si ⁇ 2)y] • XH2O wherein z and y are at least 6; the molar ratio of z to y is from 1.0 to 0.5 and x is at least 5, preferably from 7.5 to 276, more preferably from 10 to 264.
- the aluminosilicate material are in hydrated form and are preferably crystalline, containing from 10% to 28% , more preferably from 18% to 22% water in bound form.
- the aluminosilicate zeolites can be naturally occurring materials, but are preferably synthetically derived. Synthetic crystalline aluminosilicate ion exchange materials are available under the designations Zeolite A, Zeolite B, Zeolite P, Zeolite X, Zeolite HS and mixtures thereof. Zeolite A has the formula
- Zeolite X has the formula Na 86 [(Al ⁇ 2)86(Si ⁇ 2)i06]. 276 H 2 0.
- a preferred feature of detergent compositions of the invention is an organic peroxyacid bleaching system.
- the bleaching system contains a hydrogen peroxide source and an organic peroxyacid bleach precursor compound.
- the production of the organic peroxyacid occurs by an in situ reaction of the precursor with a source of hydrogen peroxide.
- Preferred sources of hydrogen peroxide include inorganic perhydrate bleaches.
- a preformed organic peroxyacid is inco ⁇ orated directly into the composition.
- Compositions containing mixtures of a hydrogen peroxide source and organic peroxyacid precursor in combination with a preformed organic peroxyacid are also envisaged.
- Inorganic perhydrate salts are a preferred source of hydrogen peroxide. These salts are normally inco ⁇ orated in the form of the alkali metal, preferably sodium salt at a level of from 1 % to 40% by weight, more preferably from 2% to 30% by weight and most preferably from 5% to 25% by weight of the compositions.
- inorganic perhydrate salts include perborate, percarbonate, pe ⁇ hosphate, persulfate and persilicate salts.
- the inorganic perhydrate salts are normally the alkali metal salts.
- the inorganic perhydrate salt may be included as the crystalline solid without additional protection.
- the preferred executions of such granular compositions utilize a coated form of the material which provides better storage stability for the perhydrate salt in the granular product.
- Suitable coatings comprise inorganic salts such as alkali metal silicate, carbonate or borate salts or mixtures thereof, or organic materials such as waxes, oils, or fatty soaps.
- Sodium perborate is a preferred perhydrate salt and can be in the form of the monohydrate of nominal formula NaB ⁇ 2H2 ⁇ 2 or the tetrahydrate NaB ⁇ 2H2 ⁇ 2-3H2 ⁇ .
- Alkali metal percarbonates particularly sodium percarbonate are preferred perhydrates herein.
- Sodium percarbonate is an addition compound having a formula corresponding to 2Na2C ⁇ 3.3H2 ⁇ 2, and is available commercially as a crystalline solid.
- Potassium peroxymonopersulfate is another inorganic perhydrate salt of use in the detergent compositions herein.
- Peroxyacid bleach precursors are compounds which react with hydrogen peroxide in a perhydrolysis reaction to produce a peroxyacid.
- peroxyacid bleach precursors may be represented as
- L is a leaving group and X is essentially any functionality, such that on perhydroloysis the structure of the peroxyacid produced is
- Peroxyacid bleach precursor compounds are preferably inco ⁇ orated at a level of from 0.5% to 20% by weight, more preferably from 1 % to 15% by weight, most preferably from 1.5% to 10% by weight of the detergent compositions.
- Suitable peroxyacid bleach precursor compounds typically contain one or more N- or O-acyl groups, which precursors can be selected from a wide range of classes.
- Suitable classes include anhydrides, esters, imides, lactams and acylated derivatives of imidazoles and oximes. Examples of useful materials within these classes are disclosed in GB-A-1586789.
- Suitable esters are disclosed in GB-A-836988, 864798, 1147871, 2143231 and EP-A-0170386.
- L group The leaving group, hereinafter L group, must be sufficiently reactive for the perhydrolysis reaction to occur within the optimum time frame (e.g., a wash cycle). However, if L is too reactive, this activator will be difficult to stabilize for use in a bleaching composition.
- Preferred L groups are selected from the group consisting of:
- R is an alkyl, aryl, or alkaryl group containing from 1 to 14 carbon atoms
- R is an alkyl chain containing from 1 to 8 carbon atoms
- R is H or R
- Y is H or a solubilizing group.
- Any of R , R and R may be substituted by essentially any functional group including, for example alkyl, hydroxy, alkoxy, halogen, amine, nitrosyl, amide and ammonium or alkyl ammmonium groups
- the preferred solubilizing groups are -SO ⁇ ' M -t- , -C ⁇ 2 ⁇ M + , -SO ⁇ ' M -f- ,
- R is an alkyl chain containing from 1 to 4 carbon atoms
- M is a cation which provides solubility to the bleach activator
- X is an anion which provides solubility to the bleach activator.
- M is an alkali metal, ammonium or substituted ammonium cation, with sodium and potassium being most preferred
- X is a halide, hydroxide, methylsulfate or acetate anion.
- Alkyl percarboxylic acid bleach precursors form percarboxylic acids on perhydrolysis.
- Preferred precursors of this type provide peracetic acid on perhydrolysis.
- Preferred alkyl percarboxylic precursor compounds of the imide type include the N-,N,NlN* tetra acetylated alkylene diamines wherein the alkylene group contains from 1 to 6 carbon atoms, particularly those compounds in which the alkylene group contains 1, 2 and 6 carbon atoms. Tetraacetyl ethylene diamine (TAED) is particularly preferred.
- TAED Tetraacetyl ethylene diamine
- alkyl percarboxylic acid precursors include sodium 3,5,5- tri-methyl hexanoyloxybenzene sulfonate (iso-NOBS), sodium nonanoyloxybenzene sulfonate (NOBS), sodium acetoxybenzene sulfonate (ABS) and pentaacetyl glucose.
- Amide substituted alkyl peroxyacid precursor compounds are suitable herein, including those of the following general formulae:
- Rl is an alkyl group with from 1 to 14 carbon atoms
- R2 is an alkylene group containing from 1 to 14 carbon atoms
- R ⁇ is H or an alkyl group containing 1 to 10 carbon atoms and L can be essentially any leaving group.
- Amide substituted bleach activator compounds of this type are described in EP-A-0170386.
- Perbenzoic acid precursor compounds provide perbenzoic acid on perhydrolysis.
- Suitable O-acylated perbenzoic acid precursor compounds include the substituted and unsubstituted benzoyl oxybenzene sulfonates, and the benzoylation products of sorbitol, glucose, and all saccharides with benzoylating agents, and those of the imide type including N-benzoyl succinimide, tetrabenzoyl ethylene diamine and the N-benzoyl substituted ureas.
- Suitable imidazole type perbenzoic acid precursors include N- benzoyl imidazole and N-benzoyl benzimidazole.
- Other useful N-acyl group-containing perbenzoic acid precursors include N-benzoyl pyrrolidone, dibenzoyl taurine and benzoyl pyroglutamic acid.
- Cationic peroxyacid precursor compounds produce cationic peroxyacids on perhydrolysis.
- cationic peroxyacid precursors are formed by substituting the peroxyacid part of a suitable peroxyacid precursor compound with a positively charged functional group, such as an ammonium or alkyl ammmonium group, preferably an ethyl or methyl ammonium group.
- Cationic peroxyacid precursors are typically present in the solid detergent compositions as a salt with a suitable anion, such as a halide ion.
- the peroxyacid precursor compound to be so cationically substituted may be a perbenzoic acid, or substituted derivative thereof, precursor compound as described hereinbefore.
- the peroxyacid precursor compound may be an alkyl percarboxylic acid precursor compound or an amide substituted alkyl peroxyacid precursor as described hereinafter
- Cationic peroxyacid precursors are described in U.S. Patents 4,904,406; 4,751,015; 4,988,451; 4,397,757; 5,269,962; 5,127,852; 5,093,022; 5,106,528; U.K. 1,382,594; EP 475,512, 458,396 and 284,292; and in JP 87-318,332.
- Suitable cationic peroxyacid precursors include any of the ammonium or alkyl ammonium substituted alkyl or benzoyl oxybenzene sulfonates, N- acylated caprolactams, and monobenzoyltetraacetyl glucose benzoyl peroxides.
- Preferred cationic peroxyacid precursors of the N-acylated caprolactam class include the trialkyl ammonium methylene benzoyl caprolactams and the trialkyl ammonium methylene alkyl caprolactams.
- precursor compounds of the benzoxazin-type as disclosed for example in EP-A-332,294 and EP-A-482,807, particularly those having the formula:
- R j is H, alkyl, alkaryl, aryl, or arylalkyl.
- the organic peroxyacid bleaching system may contain, in addition to, or as an alternative to, an organic peroxyacid bleach precursor compound, a preformed organic peroxyacid , typically at a level of from 1 % to 15% by weight, more preferably from 1 % to 10% by weight of the composition.
- a preferred class of organic peroxyacid compounds are the amide substituted compounds of the following general formulae:
- R 1 is an alkyl, aryl or alkaryl group with from 1 to 14 carbon atoms
- R2 is an alkylene, arylene, and alkarylene group containing from 1 to 14 carbon atoms
- R5 is H or an alkyl, aryl, or alkaryl group containing 1 to 10 carbon atoms.
- Amide substituted organic peroxyacid compounds of this type are described in EP-A-0170386.
- organic peroxyacids include diacyl and tetraacylperoxides, especially diperoxydodecanedioc acid, diperoxytetradecanedioc acid and diperoxyhexadecanedioc acid.
- diacyl and tetraacylperoxides especially diperoxydodecanedioc acid, diperoxytetradecanedioc acid and diperoxyhexadecanedioc acid.
- Mono- and diperazelaic acid, mono- and diperbrassylic acid and N-phthaloylaminoperoxicaproic acid are also suitable herein.
- compositions optionally contain a transition metal containing bleach catalyst.
- a transition metal containing bleach catalyst is a catalyst system comprising a heavy metal cation of defined bleach catalytic activity, such as copper, iron or manganese cations, an auxiliary metal cation having little or no bleach catalytic activity, such as zinc or aluminum cations, and a sequestrant having defined stability constants for the catalytic and auxiliary metal cations, particularly ethylenediaminetetraacetic acid, ethylenediaminetetra(methylenephosphonic acid) and water-soluble salts thereof.
- ethylenediaminetetraacetic acid ethylenediaminetetra(methylenephosphonic acid) and water-soluble salts thereof.
- bleach catalysts include the manganese-based complexes
- bleach catalysts see U.S. Pat. 4,246,612 and U.S. Pat. 5,227,084. See also U.S. Pat. 5,194,416 which teaches mononuclear manganese (IV) complexes such as Mn(l,4,7-trimethyl- l,4,7-triazacyclononane)(OCH3)3_(PF6).
- Still another type of bleach catalyst, as disclosed in U.S. Pat. 5,114,606, is a water-soluble complex of manganese (III), and/or (IV) with a ligand which is a non-carboxylate polyhydroxy compound having at least three consecutive C-OH groups.
- binuclear Mn complexed with tetra-N-dentate and bi-N-dentate ligands including N4MnHI(u-0)2MnIVN4)+and [Bipy2Mn ⁇ i(u-0)2Mn I Vbipy2]-(C104)3.
- bleach catalysts are described, for example, in European patent application No. 408,131 (cobalt complex catalysts), European patent applications, publication nos. 384,503, and 306,089 (metallo- po ⁇ hyrin catalysts), U.S. 4,728,455 (manganese/multidentate ligand catalyst), U.S. 4,711,748 and European patent application, publication no. 224,952, (absorbed manganese on aluminosilicate catalyst), U.S. 4,601,845 (aluminosilicate support with manganese and zinc or magnesium salt), U.S. 4,626,373 (manganese/ligand catalyst), U.S. 4,119,557 (ferric complex catalyst), German Pat.
- the detergent compositions of the invention preferably contain as an optional component a heavy metal ion sequestrant.
- heavy metal ion sequestrant it is meant herein components which act to sequester (chelate) heavy metal ions. These components may also have calcium and magnesium chelation capacity, but preferentially they show selectivity to binding heavy metal ions such as iron, manganese and copper.
- Heavy metal ion sequestrants are generally present at a level of from 0.005% to 20%, preferably from 0.1 % to 10%, more preferably from 0.25% to 7.5% and most preferably from 0.5% to 5% by weight of the compositions.
- Suitable heavy metal ion sequestrants for use herein include organic phosphonates, such as the amino alkylene poly (alkylene phosphonates), alkali metal ethane 1 -hydroxy disphosphonates and nitrilo trimethylene phosphonates.
- Preferred among the above species are diethylene triamine penta (methylene phosphonate), ethylene diamine tri (methylene phosphonate) hexamethylene diamine tetra (methylene phosphonate) and hydroxy- ethylene 1, 1 diphosphonate.
- Suitable heavy metal ion sequestrant for use herein include nitrilotriacetic acid and polyaminocarboxylic acids such as ethylenediaminotetracetic acid, ethylenetriamine pentacetic acid, ethylenediamine disuccinic acid, ethylenediamine diglutaric acid, 2- hydroxypropylenediamine disuccinic acid or any salts thereof.
- Suitable heavy metal ion sequestrants for use herein are iminodiacetic acid derivatives such as 2-hydroxyethyl diacetic acid or glyceryl imino diacetic acid, described in EP-A-317,542 and EP-A- 399,133.
- iminodiacetic acid-N-2-hydroxypropyl sulfonic acid and aspartic acid N-carboxymethyl N-2-hydroxypropyl-3-sulfonic acid sequestrants described in EP-A-516,102 are also suitable herein.
- EP-A-509,382 The ⁇ - alanine-N,N' -diacetic acid, aspartic acid-N,N'-diacetic acid, aspartic acid- N-monoacetic acid and iminodisuccinic acid sequestrants described in EP- A-509,382 are also suitable.
- EP-A-476,257 describes suitable amino based sequestrants.
- EP-A-510,331 describes suitable sequestrants derived from collagen, keratin or casein.
- EP-A-528,859 describes a suitable alkyl iminodiacetic acid sequestrant. Dipicolinic acid and 2-phosphonobutane-l,2,4-tricarboxylic acid are alos suitable.
- Glycinamide-N,N' -disuccinic acid Glycinamide-N,N' -disuccinic acid (GADS), ethylenediamine-N- N'-diglutaric acid (EDDG) and 2-hydroxypropylenediamine-N-N'- disuccinic acid (HPDDS) are also suitable.
- Another preferred ingredient useful in the detergent compositions is one or more additional enzymes.
- Preferred additional enzymatic materials include the commercially available lipases, cutinases, amylases, neutral and alkaline proteases, cellulases, endolases, esterases, pectinases, lactases and peroxidases conventionally inco ⁇ orated into detergent compositions. Suitable enzymes are discussed in US Patents 3,519,570 and 3,533,139.
- protease enzymes include those sold under the tradenames Alcalase, Savinase, Primase, Durazym, and Esperase by Novo Industries A/S (Denmark), those sold under the tradename Maxatase, Maxacal and Maxapem by Gist-Brocades, those sold by Genencor International, and those sold under the tradename Opticlean and Optimase by Solvay Enzymes.
- Protease enzyme may be inco ⁇ orated into the compositions in accordance with the invention at a level of from 0.0001 % to 4% active enzyme by weight of the composition.
- Preferred amylases include, for example, ⁇ -amylases obtained from a special strain of B licheniformis, described in more detail in GB- 1,269,839 (Novo).
- Preferred commercially available amylases include for example, those sold under the tradename Rapidase by Gist-Brocades, and those sold under the tradename Termamyl and BAN by Novo Industries A/S.
- Amylase enzyme may be inco ⁇ orated into the composition in accordance with the invention at a level of from 0.0001 % to 2% active enzyme by weight of the composition.
- Lipolytic enzyme may be present at levels of active lipolytic enzyme of from 0.0001 % to 2% by weight, preferably 0.001 % to 1 % by weight, most preferably from 0.001 % to 0.5% by weight of the compositions.
- the lipase may be fungal or bacterial in origin being obtained, for example, from a lipase producing strain of Humicola sp., Thermomyces sp. or Pseudomonas sp. including Pseudomonas pseudoalcaligenes or Pseudomas fluorescens. Lipase from chemically or genetically modified mutants of these strains are also useful herein.
- a preferred lipase is derived from Pseudomonas pseudoalcaligenes. which is described in Granted European Patent, EP-B-0218272.
- Another preferred lipase herein is obtained by cloning the gene from Humicola lanuginosa and expressing the gene in Aspergillus orvza. as host, as described in European Patent Application, EP-A-0258 068, which is commercially available from Novo Industri A/S, Bagsvaerd, Denmark, under the trade name Lipolase. This lipase is also described in U.S. Patent 4,810,414, Huge-Jensen et al, issued March 7, 1989.
- Non-grease-dispersing organic polymeric compounds are suitable additional components of the detergent compositions in accord with the invention, and are preferably present as components of any particulate components where they may act such as to bind the particulate component together.
- non-grease-dispersing organic polymeric compound essentially any polymeric organic compound which is not a grease dispersing agent in accord with the present invention and which is commonly used as dispersants, and anti-redeposition and non-greasy soil suspension agents in detergent compositions, including any of the high molecular weight organic polymeric compounds described as clay flocculating agents herein.
- Non-grease-dispersing organic polymeric compound is typically inco ⁇ orated in the detergent compositions of the invention at a level of from 0.1 % to 30% , preferably from 0.5 % to 15 % , most preferably from 1 % to 10% by weight of the compositions.
- suitable organic polymeric compounds for use herein are polyamino compounds, including those derived from aspartic acid such as those disclosed in EP-A-305282, EP-A-305283 and EP-A-351629.
- Te ⁇ olymers containing monomer units selected from maleic acid, acrylic acid, polyaspartic acid and vinyl alcohol, particularly those having an average molecular weight of from 5,000 to 10,000, are also suitable herein.
- organic polymeric compounds are the polyethylene glycols, particularly those of molecular weight 1000-10000, more particularly 2000 to 8000 and most preferably about 4000.
- the detergent compositions of the invention when formulated for use in machine washing compositions, preferably comprise a suds suppressing system present at a level of from 0.01 % to 15 %, preferably from 0.05 % to 10%, most preferably from 0.1 % to 5% by weight of the composition.
- Suitable suds suppressing systems for use herein may comprise essentially any known antifoam compound, including, for example silicone antifoam compounds and 2-alkyl alcanol antifoam compounds.
- antifoam compound any compound or mixtures of compounds which act such as to depress the foaming or sudsing produced by a solution of a detergent composition, particularly in the presence of agitation of that solution.
- Particularly preferred antifoam compounds for use herein are silicone antifoam compounds defined herein as any antifoam compound including a silicone component. Such silicone antifoam compounds also typically contain a silica component.
- silicone antifoam compounds as used herein, and in general throughout the industry, encompasses a variety of relatively high molecular weight polymers containing siloxane units and hydrocarbyl group of various types.
- Preferred silicone antifoam compounds are the siloxanes, particularly the polydimethylsiloxanes having trimethylsilyl end blocking units.
- Suitable antifoam compounds include the monocarboxylic fatty acids and soluble salts thereof. These materials are described in US Patent 2,954,347, issued September 27, 1960 to Wayne St. John.
- the monocarboxylic fatty acids, and salts thereof, for use as suds suppressor typically have hydrocarbyl chains of 10 to 24 carbon atoms, preferably 12 to 18 carbon atoms.
- Suitable salts include the alkali metal salts such as sodium, potassium, and lithium salts, and ammonium and alkanolammonium salts.
- Suitable antifoam compounds include, for example, high molecular weight fatty esters (e.g. fatty acid triglycerides), fatty acid esters of monovalent alcohols, aliphatic Cjg-C40 ketones (e.g. stearone) N-alkylated amino triazines such as tri- to hexa-alkylmelamines or di- to tetra alkyldiamine chlortriazines formed as products of cyanuric chloride with two or three moles of a primary or secondary amine containing 1 to 24 carbon atoms, propylene oxide, bis stearic acid amide and monostearyl di- alkali metal (e.g. sodium, potassium, lithium) phosphates and phosphate esters.
- high molecular weight fatty esters e.g. fatty acid triglycerides
- fatty acid esters of monovalent alcohols e.g. fatty acid esters of monovalent alcohols
- a preferred suds suppressing system comprises
- antifoam compound preferably silicone antifoam compound, most preferably a silicone antifoam compound comprising in combination
- silica at a level of from 1 % to 50%, preferably 5% to 25% by weight of the silicone/silica antifoam compound; wherein said silica/silicone antifoam compound is inco ⁇ orated at a level of from 5 % to 50% , preferably 10% to 40% by weight;
- a dispersant compound most preferably comprising a silicone glycol rake copolymer with a polyoxyalkylene content of 72-78 % and an ethylene oxide to propylene oxide ratio of from 1 :0.9 to 1 : 1.1, at a level of from 0.5 % to 10% , preferably 1 % to 10% by weight;
- a particularly preferred silicone glycol rake copolymer of this type is DC0544, commercially available from DOW Corning under the tradename DC0544;
- an inert carrier fluid compound most preferably comprising a Ci ⁇ - Cig ethoxylated alcohol with a degree of ethoxylation of from 5 to 50, preferably 8 to 15, at a level of from 5 % to 80% , preferably 10% to 70%, by weight;
- a highly preferred particulate suds suppressing system is described in EP- A-0210731 and comprises a silicone antifoam compound and an organic carrier material having a melting point in the range 50 °C to 85 °C, wherein the organic carrier material comprises a monoester of glycerol and a fatty acid having a carbon chain containing from 12 to 20 carbon atoms.
- EP-A-0210721 discloses other preferred particulate suds suppressing systems wherein the organic carrier material is a fatty acid or alcohol having a carbon chain containing from 12 to 20 carbon atoms, or a mixture thereof, with a melting point of from 45 °C to 80°C.
- the detergent compositions may contain a clay softening system comprising a clay mineral compound and optionally a clay flocculating agent.
- the clay mineral compound is preferably a smectite clay compound.
- Smectite clays are disclosed in the US Patents No.s 3,862,058, 3,948,790, 3,954,632 and 4,062,647.
- European Patents No.s EP-A- 299,575 and EP-A-313, 146 in the name of the Procter and Gamble Company describe suitable organic polymeric clay flocculating agents.
- the detergent compositions herein may additionally comprise from 0.01 % to 10 %, preferably from 0.05% to 0.5% by weight of polymeric dye transfer inhibiting agents.
- the polymeric dye transfer inhibiting agents are preferably selected from copolymers of N-vinylpyrrolidone and N-vinylimidazole, polyvinylpyrrolidonepolymers or combinations thereof.
- Suitable herein are copolymers of N-vinylimidazole and N- vinylpyrrolidone having an average molecular weight range of from 5,000 to 50,000.
- the preferred copolymers have a molar ratio of N- vinylimidazole to N-vinylpyrrolidone from 1 to 0.2.
- the detergent compositions herein may also utilize poly vinylpyrrolidone ("PVP") having an average molecular weight of from 2,500 to 400,000.
- PVP poly vinylpyrrolidone
- Suitable polyvinylpyrrolidones are commercially vailable from ISP Co ⁇ oration, New York, NY and Montreal, Canada under the product names PVP K-15 (viscosity molecular weight of 10,000), PVP K-30 (average molecular weight of 40,000), PVP K-60 (average molecular weight of 160,000), and PVP K-90 (average molecular weight of 360,000).
- PVP K-15 is also available from ISP Co ⁇ oration.
- Other suitable polyvinylpyrrolidones which are commercially available from BASF Cooperation include Sokalan HP 165 and Sokalan HP 12.
- the detergent compositions herein may also utilize polyvinyloxazohdones as polymeric dye transfer inhibiting agents.
- Said polyvinyloxazohdones have an average molecular weight of from 2,500 to 400,000.
- the detergent compositions herein may also utilize polyvinylimidazole as polymeric dye transfer inhibiting agent.
- Said polyvinylimidazoles preferably have an average molecular weight of from 2,500 to 400,000.
- the detergent compositions herein also optionally contain from about 0.005 % to 5 % by weight of certain types of hydrophilic optical brighteners.
- Hydrophilic optical brighteners useful herein include those having the structural formula:
- Ri is selected from anilino, N-2-bis-hydroxyethyl and NH-2- hydroxyethyl
- R2 is selected from N-2-bis-hydroxy ethyl, N-2- hydroxyethyl-N-methylamino, mo ⁇ hilino, chloro and amino
- M is a salt-forming cation such as sodium or potassium.
- the brightener is 4,4' ,-bis[(4-anilino-6-(N- 2-bis-hydroxyethyl)-s-triazine-2-yl)amino]-2,2'-stilbenedisulfonic acid and disodium salt.
- This particular brightener species is commercially marketed under the tradename Tinopal-UNPA-GX by Ciba-Geigy Co ⁇ oration. Tinopal-UNPA-GX is the preferred hydrophilic optical brightener useful in the detergent compositions herein.
- the brightener is 4,4'- bis[(4-aniIino-6-(N-2-hydroxyethyl-N-methylamino)-s-triazine-2- yl)amino]2,2'-stilbenedisulfonic acid disodium salt.
- This particular brightener species is commercially marketed under the tradename Tinopal 5BM-GX by Ciba-Geigy Co ⁇ oration.
- the brightener is 4,4'-bis[(4-anilino-6-mo ⁇ hiIino- s-triazine-2-yl)amino]2,2'-stilbenedisulfonic acid, sodium salt.
- This particular brightener species is commercially marketed under the tradename Tinopal AMS-GX by Ciba Geigy Co ⁇ oration.
- Cationic fabric softening agents can also be inco ⁇ orated into compositions in accordance with the present invention.
- Suitable cationic fabric softening agents include the water insoluble tertiary amines or dilong chain amide materials as disclosed in GB-A-1 514 276 and EP-B-0 011 340.
- Cationic fabric softening agents are typically inco ⁇ orated at total levels of from 0.5% to 15% by weight, normally from 1 % to 5% by weight.
- compositions of the invention include perfumes, colours and filler salts, with sodium sulfate being a preferred filler salt. pH of the compositions
- compositions preferably have a pH measured as a 1 % solution in distilled water of at least 8.5, preferably from 9.0 to 12.5, most preferably from 9.5 to 11.0.
- compositions in accordance with the invention can take a variety of physical forms including granular, tablet, bar and liquid forms.
- the compositions are particularly the so-called concentrated granular detergent compositions adapted to be added to a washing machine by means of a dispensing device placed in the machine drum with the soiled fabric load.
- granular detergent compositions in accordance with the present invention can be made via a variety of methods including dry mixing, spray drying, agglomeration and granulation.
- the mean particle size of the components of granular compositions in accordance with the invention should preferably be such that no more that 5 % of particles are greater than 1.7mm in diameter and not more than 5 % of particles are less than 0.15mm in diameter.
- mean particle size as defined herein is calculated by sieving a sample of the composition into a number of fractions (typically 5 fractions) on a series of Tyler sieves. The weight fractions thereby obtained are plotted against the aperture size of the sieves. The mean particle size is taken to be the aperture size through which 50% by weight of the sample would pass.
- the bulk density of granular detergent compositions in accordance with the present invention typically have a bulk density of at least 600 g/litre, more preferably from 650 g/litre to 1200 g/litre.
- Bulk density is measured by means of a simple funnel and cup device consisting of a conical funnel moulded rigidly on a base and provided with a flap valve at its lower extremity to allow the contents of the funnel to be emptied into an axially aligned cylindrical cup disposed below the funnel.
- the funnel is 130 mm high and has internal diameters of 130 mm and 40 mm at its respective upper and lower extremities. It is mounted so that the lower extremity is 140 mm above the upper surface of the base.
- the cup has an overall height of 90 mm, an internal height of 87 mm and an internal diameter of 84 mm. Its nominal volume is 500 ml.
- the funnel is filled with powder by hand pouring, the flap valve is opened and powder allowed to overfill the cup.
- the filled cup is removed from the frame and excess powder removed from the cup by passing a straight edged implement eg; a knife, across its upper edge.
- the filled cup is then weighed and the value obtained for the weight of powder doubled to provide a bulk density in g/litre. Replicate measurements are made as required.
- the cationic ester surfactant herein preferably with additional surfactants, is preferably present in granular compositions in the form of surfactant agglomerate particles, which may take the form of ftakes, prills, marumes, noodles, ribbons, but preferably take the form of granules.
- the most preferred way to process the particles is by agglomerating powders (e.g. aluminosilicate, carbonate) with high active surfactant pastes and to control the particle size of the resultant agglomerates within specified limits.
- Such a process involves mixing an effective amount of powder with a high active surfactant paste in one or more agglomerators such as a pan agglomerator, a Z-blade mixer or more preferably an in-line mixer such as those manufactured by Schugi (Holland) BV, 29 Chroomstraat 8211 AS, Lelystad, Netherlands, and Gebruder Lodige Maschinenbau GmbH, D-4790 Paderborn 1 , Elsenerstrasse 7-9, Postfach 2050, Germany. Most preferably a high shear mixer is used, such as a Lodige CB (Trade Name).
- a high active surfactant paste in one or more agglomerators such as a pan agglomerator, a Z-blade mixer or more preferably an in-line mixer such as those manufactured by Schugi (Holland) BV, 29 Chroomstraat 8211 AS, Lelystad, Netherlands, and Gebruder Lodige Maschinenbau GmbH, D-4790 Paderborn 1 , Elsener
- a high active surfactant paste comprising from 50% by weight to 95% by weight, preferably 70% by weight to 85% by weight of surfactant is typically used.
- the paste may be pumped into the agglomerator at a temperature high enough to maintain a pumpable viscosity, but low enough to avoid degradation of the anionic surfactants used.
- An operating temperature of the paste of 50°C to 80°C is typical.
- Machine laundry methods herein typically comprise treating soiled laundry with an aqueous wash solution in a washing machine having dissolved or dispensed therein an effective amount of a machine laundry detergent composition in accord with the invention.
- an effective amount of the detergent composition it is meant from 40g to 300g of product dissolved or dispersed in a wash solution of volume from 5 to 65 litres, as are typical product dosages and wash solution volumes commonly employed in conventional machine laundry methods.
- a dispensing device is employed in the washing method.
- the dispensing device is charged with the detergent product, and is used to introduce the product directly into the drum of the washing machine before the commencement of the wash cycle. Its volume capacity should be such as to be able to contain sufficient detergent product as would normally be used in the washing method.
- the dispensing device containing the detergent product is placed inside the drum.
- water is introduced into the drum and the drum periodically rotates.
- the design of the dispensing device should be such that it permits containment of the dry detergent product but then allows release of this product during the wash cycle in response to its agitation as the drum rotates and also as a result of its contact with the wash water.
- the device may possess a number of openings through which the product may pass.
- the device may be made of a material which is permeable to liquid but impermeable to the solid product, which will allow release of dissolved product.
- the detergent product will be rapidly released at the start of the wash cycle thereby providing transient localised high concentrations of product in the drum of the washing machine at this stage of the wash cycle.
- Preferred dispensing devices are reusable and are designed in such a way that container integrity is maintained in both the dry state and during the wash cycle.
- Especially preferred dispensing devices for use with the composition of the invention have been described in the following patents; GB-B-2, 157, 717, GB-B-2, 157, 718, EP-A-0201376, EP-A-0288345 and EP-A-0288346.
- An article by J. Bland published in Manufacturing Chemist, November 1989, pages 41-46 also describes especially preferred dispensing devices for use with granular laundry products which are of a type commonly know as the "granulette”.
- Another preferred dispensing device for use with the compositions of this invention is disclosed in PCT Patent Application No. W094/11562.
- Especially preferred dispensing devices are disclosed in European Patent Application Publication Nos. 0343069 & 0343070.
- the latter Application discloses a device comprising a flexible sheath in the form of a bag extending from a support ring defining an orifice, the orifice being adapted to admit to the bag sufficient product for one washing cycle in a washing process. A portion of the washing medium flows through the orifice into the bag, dissolves the product, and the solution then passes outwardly through the orifice into the washing medium.
- the support ring is provided with a masking arrangemnt to prevent egress of wetted, undissolved, product, this arrangement typically comprising radially extending walls extending from a central boss in a spoked wheel configuration, or a similar structure in which the walls have a helical form.
- the dispensing device may be a flexible container, such as a bag or pouch.
- the bag may be of fibrous construction coated with a water impermeable protective material so as to retain the contents, such as is disclosed in European published Patent Application No. 0018678.
- it may be formed of a water-insoluble synthetic polymeric material provided with an edge seal or closure designed to rupture in aqueous media as disclosed in European published Patent Application Nos. 0011500, 0011501 , 0011502, and 0011968.
- a convenient form of water frangible closure comprises a water soluble adhesive disposed along and sealing one edge of a pouch formed of a water impermeable polymeric film such as polyethylene or polypropylene.
- Ci4_i5 predominantly linear primary alcohol condensed with an average of 7 moles of ethylene oxide
- Nai2(A102Si ⁇ 2)i2- 27H20 having a primary particle size in the range from 0.1 to 10 micrometers
- Citric acid Anhydrous citric acid Carbonate Anhydrous sodium carbonate with a particle size between 200 ⁇ m and 900 ⁇ m
- Bicarbonate Anhydrous sodium bicarbonate with a particle size distribution between 400 ⁇ m and 1200 ⁇ m
- MA/AA Copolymer of 1 :4 maleic/acrylic acid average molecular weight about 70,000.
- Brightener 1 Disodium 4,4'-bis(2-sulphostyryl)biphenyl
- Brightener 2 Disodium 4,4'-bis(4-anilino-6-mo ⁇ holino-l .3.5- triazin-2-yl)amino) stilbene-2:2'-disulfonate.
- Silicone antifoam Polydimethylsiloxane foam controller with siloxane-oxyalkylene copolymer as dispersing agent with a ratio of said foam controller to said dispersing agent of 10: 1 to 100:1.
- % by weight of the composition all levels are quoted as % by weight of the composition:
- laundry detergent compositions A to F were prepared in accord with the invention:
- J is a phosphorus-containing detergent composition
- K is a zeolite-containing detergent composition
- L is a compact detergent composition
- liquid detergent formulations according to the present invention were prepared:
Abstract
Description
Claims
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/194,476 US5981460A (en) | 1996-05-31 | 1997-05-15 | Detergent compositions comprising a cationic ester surfactant and a grease dispensing agent |
BR9709505A BR9709505A (en) | 1996-05-31 | 1997-05-15 | Detergent compositions |
EP97924730A EP0906383A4 (en) | 1996-05-31 | 1997-05-15 | Detergent compositions |
CA002256892A CA2256892A1 (en) | 1996-05-31 | 1997-05-15 | Detergent compositions |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB9611324.6 | 1996-05-31 | ||
GB9611324A GB2313602A (en) | 1996-05-31 | 1996-05-31 | Detergent compositions |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1997045512A1 true WO1997045512A1 (en) | 1997-12-04 |
Family
ID=10794539
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1997/008235 WO1997045512A1 (en) | 1996-05-31 | 1997-05-15 | Detergent compositions |
Country Status (6)
Country | Link |
---|---|
EP (1) | EP0906383A4 (en) |
AR (1) | AR014858A1 (en) |
BR (1) | BR9709505A (en) |
CA (1) | CA2256892A1 (en) |
GB (1) | GB2313602A (en) |
WO (1) | WO1997045512A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001094518A1 (en) * | 2000-06-09 | 2001-12-13 | Basf Aktiengesellschaft | Polymers used as controllable dispersing agents |
US6498136B2 (en) * | 1999-03-23 | 2002-12-24 | National Starch And Chemical Investment Holding Corporation | Polymer having a hydrophilic backbone and hydrophobic moieties as soil suspending agent in powder detergents |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE50109370D1 (en) * | 2001-12-24 | 2006-05-18 | Cognis Ip Man Gmbh | Cationic preparations for the cleaning of hard surfaces |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4220562A (en) * | 1977-06-29 | 1980-09-02 | The Procter & Gamble Company | Laundry additive product |
US4240920A (en) * | 1978-02-28 | 1980-12-23 | The Procter & Gamble Company | Detergent bleach composition and process |
US4290903A (en) * | 1978-06-26 | 1981-09-22 | The Procter & Gamble Company | Packaged free flowing bleach activator product |
US4992194A (en) * | 1989-06-12 | 1991-02-12 | Lever Brothers Company, Division Of Conopco Inc. | Stably suspended organic peroxy bleach in a structured aqueous liquid |
US5147576A (en) * | 1988-06-13 | 1992-09-15 | Lever Brothers Company, Division Of Conopco, Inc. | Liquid detergent composition in the form of lamellar droplets containing a deflocculating polymer |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4260529A (en) * | 1978-06-26 | 1981-04-07 | The Procter & Gamble Company | Detergent composition consisting essentially of biodegradable nonionic surfactant and cationic surfactant containing ester or amide |
US4239660A (en) * | 1978-12-13 | 1980-12-16 | The Procter & Gamble Company | Detergent composition comprising a hydrolyzable cationic surfactant and specific alkalinity source |
JPS598392B2 (en) * | 1979-06-29 | 1984-02-24 | 花王株式会社 | cleaning composition |
AU535124B2 (en) * | 1979-07-23 | 1984-03-01 | Johnson & Johnson Baby Products Company | Surfactant compositions containing phosphoric acid triesters |
DE3135014A1 (en) * | 1981-09-04 | 1983-03-24 | Hoechst Ag, 6000 Frankfurt | SOFT SOFTENER |
DE3402437A1 (en) * | 1984-01-25 | 1985-07-25 | Rewo Chemische Werke Gmbh, 6497 Steinau | POWDERED SOFT SOFT DETERGENT, METHOD FOR THE PRODUCTION THEREOF AND DETERGENT CONTAINING THIS |
DE3588115T3 (en) * | 1984-05-16 | 2003-03-27 | Stepan Europ Voreppe | Concentrated plasticizer compositions based on quaternary ammonium-containing cationic surface-active compounds |
CA1299962C (en) * | 1985-10-31 | 1992-05-05 | Eugene Joseph Pancheri | Liquid detergent composition |
WO1996021715A1 (en) * | 1995-01-12 | 1996-07-18 | The Procter & Gamble Company | Stabilized liquid fabric softener compositions |
-
1996
- 1996-05-31 GB GB9611324A patent/GB2313602A/en not_active Withdrawn
-
1997
- 1997-05-15 WO PCT/US1997/008235 patent/WO1997045512A1/en not_active Application Discontinuation
- 1997-05-15 CA CA002256892A patent/CA2256892A1/en not_active Abandoned
- 1997-05-15 BR BR9709505A patent/BR9709505A/en not_active Application Discontinuation
- 1997-05-15 EP EP97924730A patent/EP0906383A4/en not_active Withdrawn
- 1997-05-30 AR ARP970102358 patent/AR014858A1/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4220562A (en) * | 1977-06-29 | 1980-09-02 | The Procter & Gamble Company | Laundry additive product |
US4240920A (en) * | 1978-02-28 | 1980-12-23 | The Procter & Gamble Company | Detergent bleach composition and process |
US4290903A (en) * | 1978-06-26 | 1981-09-22 | The Procter & Gamble Company | Packaged free flowing bleach activator product |
US5147576A (en) * | 1988-06-13 | 1992-09-15 | Lever Brothers Company, Division Of Conopco, Inc. | Liquid detergent composition in the form of lamellar droplets containing a deflocculating polymer |
US4992194A (en) * | 1989-06-12 | 1991-02-12 | Lever Brothers Company, Division Of Conopco Inc. | Stably suspended organic peroxy bleach in a structured aqueous liquid |
Non-Patent Citations (1)
Title |
---|
See also references of EP0906383A4 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6498136B2 (en) * | 1999-03-23 | 2002-12-24 | National Starch And Chemical Investment Holding Corporation | Polymer having a hydrophilic backbone and hydrophobic moieties as soil suspending agent in powder detergents |
WO2001094518A1 (en) * | 2000-06-09 | 2001-12-13 | Basf Aktiengesellschaft | Polymers used as controllable dispersing agents |
US6878683B2 (en) | 2000-06-09 | 2005-04-12 | Basf Aktiengesellschaft | Polymers used as controllable dispersing agents |
Also Published As
Publication number | Publication date |
---|---|
EP0906383A1 (en) | 1999-04-07 |
GB2313602A (en) | 1997-12-03 |
EP0906383A4 (en) | 1999-11-24 |
CA2256892A1 (en) | 1997-12-04 |
AR014858A1 (en) | 2001-04-11 |
BR9709505A (en) | 1999-08-10 |
GB9611324D0 (en) | 1996-08-07 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
EP0843715A1 (en) | Detergent compositions | |
WO1997003161A9 (en) | Laundry washing method | |
WO1997043366A1 (en) | Detergent composition | |
WO1999019429A1 (en) | A detergent composition | |
EP0842247A1 (en) | Detergent compositions | |
WO1997031889A1 (en) | Cationic detergent compounds | |
EP0915950A1 (en) | A detergent composition comprising an acid source with a specific particle size | |
WO1998004662A9 (en) | A detergent composition comprising an acid source with a specific particle size | |
WO1997043367A1 (en) | Detergent composition | |
EP0915960A1 (en) | A process and composition for detergents | |
WO1997003158A1 (en) | Detergent compositions | |
EP0915956A1 (en) | A detergent composition | |
EP0845024A1 (en) | Detergent compositions | |
EP0906384A1 (en) | Detergent compositions | |
WO1997032955A1 (en) | Cationic detergent compounds | |
EP0906383A1 (en) | Detergent compositions | |
WO1998017760A1 (en) | A detergent composition | |
WO1998000491A1 (en) | Detergent composition | |
EP0856044A1 (en) | Detergent compositions comprising cation ester surfactant and enzyme | |
WO1997003155A2 (en) | Detergent compositions | |
WO1998000501A1 (en) | Detergent composition comprising dianionic cleaning agent and an enzyme | |
WO1997003163A1 (en) | Detergent compositions | |
WO1997045513A1 (en) | Detergent composition | |
GB2303142A (en) | Detergent compositions | |
WO1997003159A1 (en) | Detergent compositions |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): BR CA MX US |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE |
|
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
WWE | Wipo information: entry into national phase |
Ref document number: 1997924730 Country of ref document: EP |
|
ENP | Entry into the national phase |
Ref document number: 2256892 Country of ref document: CA Kind code of ref document: A Ref document number: 2256892 Country of ref document: CA |
|
WWE | Wipo information: entry into national phase |
Ref document number: PA/a/1998/010101 Country of ref document: MX Ref document number: 09194476 Country of ref document: US |
|
WWP | Wipo information: published in national office |
Ref document number: 1997924730 Country of ref document: EP |
|
WWW | Wipo information: withdrawn in national office |
Ref document number: 1997924730 Country of ref document: EP |