WO1997019582A3 - A polymeric composition in pellet form - Google Patents

A polymeric composition in pellet form Download PDF

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Publication number
WO1997019582A3
WO1997019582A3 PCT/US1996/018507 US9618507W WO9719582A3 WO 1997019582 A3 WO1997019582 A3 WO 1997019582A3 US 9618507 W US9618507 W US 9618507W WO 9719582 A3 WO9719582 A3 WO 9719582A3
Authority
WO
WIPO (PCT)
Prior art keywords
weight
composition
hot melt
pellet
tacky
Prior art date
Application number
PCT/US1996/018507
Other languages
French (fr)
Other versions
WO1997019582A2 (en
Inventor
Eugene Simmons
Kevin Sweeney
Jeffrey Lindquist
Christopher Olson
Freddie Cartes
James Farmer
Original Assignee
Fuller H B Licensing Financ
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fuller H B Licensing Financ filed Critical Fuller H B Licensing Financ
Priority to BR9611968A priority Critical patent/BR9611968A/en
Priority to DE69635829T priority patent/DE69635829D1/en
Priority to AU10546/97A priority patent/AU719936B2/en
Priority to EP96941387A priority patent/EP0861285B1/en
Priority to CA002239983A priority patent/CA2239983C/en
Priority to JP52053997A priority patent/JP3792724B2/en
Publication of WO1997019582A2 publication Critical patent/WO1997019582A2/en
Publication of WO1997019582A3 publication Critical patent/WO1997019582A3/en

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J153/02Vinyl aromatic monomers and conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/12Powdering or granulating
    • C08J3/124Treatment for improving the free-flowing characteristics
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C08L53/025Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J123/00Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
    • C09J123/02Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers not modified by chemical after-treatment
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J151/00Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J153/00Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
    • C09J153/02Vinyl aromatic monomers and conjugated dienes
    • C09J153/025Vinyl aromatic monomers and conjugated dienes modified
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/24Graft or block copolymers according to groups C08L51/00, C08L53/00 or C08L55/02; Derivatives thereof

Abstract

A polymeric composition in pellet form comprising a tacky hot melt composition, comprising a) from about 5 % by weight to about 90 % by weight of a thermoplastic polymer, b) from about 10 % by weight to about 65 % by weight of a tackifying resin, c) up to about 50 % by weight of a plasticizer, d) up to about 2 % by weight of an antioxidant, and a pelletizing aid, wherein the tacky hot melt composition is a pressure sensitive adhesive having a storage modulus, G', at about 25 °C, of less than about 5 x 106 dynes/cm2, and each pellet has a substantially tack-free surface. This invention further discloses a polymeric composition in pellet from suitable for molding articles. The composition comprises a tacky hot melt composition comprising at least one high molecular weight triblock copolymer of the general configuration A-B-A and a plasticizer and a pelletizing aid. The pelletizing aid substantially surroudns the tacky composition such that the molded articles are substantially free from surface tack. A method of forming the pellets is also disclosed.
PCT/US1996/018507 1995-11-16 1996-11-18 A polymeric composition in pellet form WO1997019582A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
BR9611968A BR9611968A (en) 1995-11-16 1996-11-18 Polymeric composition in granular form
DE69635829T DE69635829D1 (en) 1995-11-16 1996-11-18 PELLET-FORM POLYMER COMPOSITION
AU10546/97A AU719936B2 (en) 1995-11-16 1996-11-18 A polymeric composition in pellet form
EP96941387A EP0861285B1 (en) 1995-11-16 1996-11-18 A polymeric composition in pellet form
CA002239983A CA2239983C (en) 1995-11-16 1996-11-18 A polymeric composition in pellet form
JP52053997A JP3792724B2 (en) 1995-11-16 1996-11-18 Pellet polymer composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US55900695A 1995-11-16 1995-11-16
US08/559,006 1995-11-16

Publications (2)

Publication Number Publication Date
WO1997019582A2 WO1997019582A2 (en) 1997-06-05
WO1997019582A3 true WO1997019582A3 (en) 1997-07-03

Family

ID=24231901

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1996/018507 WO1997019582A2 (en) 1995-11-16 1996-11-18 A polymeric composition in pellet form

Country Status (9)

Country Link
US (2) US5869555A (en)
EP (1) EP0861285B1 (en)
JP (1) JP3792724B2 (en)
CN (1) CN1193068C (en)
AU (1) AU719936B2 (en)
BR (1) BR9611968A (en)
CA (1) CA2239983C (en)
DE (1) DE69635829D1 (en)
WO (1) WO1997019582A2 (en)

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US5942569A (en) 1999-08-24
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EP0861285A2 (en) 1998-09-02
EP0861285B1 (en) 2006-02-15
BR9611968A (en) 1999-07-13
CN1193068C (en) 2005-03-16
WO1997019582A2 (en) 1997-06-05
DE69635829D1 (en) 2006-04-20
CA2239983C (en) 2002-07-30
CN1314433A (en) 2001-09-26
JP3792724B2 (en) 2006-07-05
US5869555A (en) 1999-02-09

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