WO1997001435A1 - Product and process for laminating documents - Google Patents

Product and process for laminating documents Download PDF

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Publication number
WO1997001435A1
WO1997001435A1 PCT/US1996/010856 US9610856W WO9701435A1 WO 1997001435 A1 WO1997001435 A1 WO 1997001435A1 US 9610856 W US9610856 W US 9610856W WO 9701435 A1 WO9701435 A1 WO 9701435A1
Authority
WO
WIPO (PCT)
Prior art keywords
sheet
εheet
underlying
overlying
pouch
Prior art date
Application number
PCT/US1996/010856
Other languages
French (fr)
Inventor
Carl B. Samuelson
Original Assignee
Samuelson Carl B
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Samuelson Carl B filed Critical Samuelson Carl B
Priority to AU63405/96A priority Critical patent/AU6340596A/en
Publication of WO1997001435A1 publication Critical patent/WO1997001435A1/en

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/06Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/10Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of paper or cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/32Layered products comprising a layer of synthetic resin comprising polyolefins
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/34Layered products comprising a layer of synthetic resin comprising polyamides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/36Layered products comprising a layer of synthetic resin comprising polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/14Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers
    • B32B37/26Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the properties of the layers with at least one layer which influences the bonding during the lamination process, e.g. release layers or pressure equalising layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B7/00Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
    • B32B7/04Interconnection of layers
    • B32B7/12Interconnection of layers using interposed adhesives or interposed materials with bonding properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/41Opaque
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/40Properties of the layers or laminate having particular optical properties
    • B32B2307/412Transparent
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2317/00Animal or vegetable based
    • B32B2317/12Paper, e.g. cardboard
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2323/00Polyalkenes
    • B32B2323/10Polypropylene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2367/00Polyesters, e.g. PET, i.e. polyethylene terephthalate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2377/00Polyamides

Definitions

  • This invention relates generally to products and processes for laminating flexible sheet material and, in particular, to a product and process for laminating such sheet material that is useful at low temperatures .
  • the present invention is concerned with lamination of sheet material such as paper or similar documents utilizing commonly available xerographic copiers, laser printers, plain paper facsimile machines, and the like, which utilize heat and pressure rollers in their operation.
  • lamination of documents is accomplished with specially designed laminating machines which are utilized only in large offices or job shops since they are too complicated and expensive for ordinary office use.
  • a special plastic pouch and leader system is utilized to obtain the rapid lamination of documents or other flat materials by utilizing the heat and pressure of the common office copier machines, facsimile machines, laser printers, or similar printing machines.
  • Such machines have at least one heated roller through which the paper sheet on which the copy image is formed is passed.
  • photographs, business cards, ordinary print materials, identification cards, and the like can be laminated utilizing common office copier machines. Since no additional machinery is involved, only the relatively inexpensive specially designed laminating pouch is required to obtain excellent laminated documents with the ordinary office copier types of machines.
  • This invention concerns a means and method for laminating flexible sheet material by feeding the item to be laminated after it has been placed in the "pocket/envelope" of the laminating package into the copy paper supply tray of the standard office copier, laser printer, or facsimile machine.
  • the toner of the machine is turned down to a minimum and a blank piece of paper is placed on the copying surface.
  • the copy machine is then activated and the pouch is fed by means of the leader which is either paper or a specially coated extension of the plastic sheet through the feed and ultimately through the heated rollers of the ordinary copy machine.
  • Crumrine et al. xerographic machinery is utilized for aerial reconnaissance. It shows the utilization of adhesive coated paper strip to protect and cover a further strip on which the paper image is formed.
  • a set of pressure rollers is used to set a transparent plastic web so that it adheres to the adhesive on a transfer strip and fixes the powder image thereon, forming a protective cover therefor.
  • U.S. 5,126,797 Forest et al. A tone image sheet is laminated using a transparent laminating sheet fed from a normal copy sheet supply of a copier printer or the like with the laminating contact with the toner image after the tone image has been formed on a receiving sheet. The resulting sandwich layer is fed through the fuser, laminating the image between the sheets.
  • the Cherian '326 patent describes bonding using pressure and heat applied through the use of a heated top platen.
  • a cover assembly for use with photographs comprising a flexible polyester sheet larger than the photograph with a central transparent viewing portion and outer frame portion, the cover assembly having a layer of adhesive on its rear surface along the frame portion to afford firm adhesion of the sheet to the edge portion of the photograph and to a surface to support the photograph and cover assembly along the surface but being removable from the ⁇ urface and photograph without damaging them.
  • a laminating pouch for laminating a flexible sheet material.
  • the pouch includes an overlying sheet formed of a film having an exposed side and an interior side, and a first surface area.
  • a low temperature heat seal adhesive is coated on the interior side of the overlying sheet.
  • the pouch also includes an underlying sheet formed of a film having an adjacent side positioned adjacent the low temperature heat seal adhesive and a distal side opposite the adjacent side.
  • the underlying sheet has a second surface area that is substantially the same as the first surface area of the overlying sheet.
  • An adhesion promoting coating is provided on the adjacent side of the underlying sheet for the purpose of promoting adhesion between the overlying sheet and the underlying sheet.
  • the laminating pouch is used for the purpose of laminating a flexible sheet material.
  • the flexible sheet material has a third surface area that is smaller than the first and second surface areas of the overlying and underlying sheets, respectively.
  • the overlying sheet can be permanently adhered to the underlying sheet with the flexible sheet material therebetween when the laminating pouch is subjected to temperatures between about 150 F and 300 F.
  • a release coating is used on the adjacent side of the underlying sheet for the purpose of permitting the underlying sheet to be separated from the adhered overlying sheet and flexible sheet material when the lamination is complete.
  • a process for laminating a flexible sheet material is also provided.
  • the invention accordingly comprises an article of manufacture possessing the feature ⁇ , propertie ⁇ , and the relation of elements which will be exemplified in the article hereinafter described, and the ⁇ everal steps and the relation of one or more of such ⁇ teps with re ⁇ pect to each of the other ⁇ thereof, which will be exemplified in the method hereinafter disclosed, and the scope of the invention will be indicated in the claims .
  • FIG. 1 is a side plan view of a laminating pouch constructed and arranged in accordance with the invention
  • FIG. 2 is a sectional view of the laminating pouch of FIG. 1;
  • FIG. 3 i a top plan view of a laminating pouch con ⁇ tructed and arranged in accordance with the invention illustrating placement of a flexible sheet material therein;
  • FIG. 4 is a top plan view of a laminating pouch constructed and arranged in accordance with the invention having a flexible ⁇ heet material therein; and, FIG. 5 is a top plan view of a fully laminated pouch constructed and arranged in accordance with the invention.
  • a laminating pouch constructed and arranged in accordance with the invention is indicated generally by reference numeral 2.
  • the laminating pouch 2 include ⁇ an overlying or top film ⁇ heet 14 and an underlying or bottom film ⁇ heet 4.
  • the film may be clear, opaque, matte, color tinted, ⁇ urface embossed or textured plastic.
  • Suitable films include, but are not limited to, polyester, polyethylene terephthalate, polyethylene naphthalate, nylon, polypropylene, vinyl, and the like. Suitable films are commercially available from 3M Corporation of Minneapolis, Minne ⁇ ota, and Preci ⁇ ion Coating ⁇ , Walled Lake, Michigan, and Arkwright Corp. of Fi ⁇ kville, Rhode I ⁇ land. In a preferred embodiment, a polye ⁇ ter film i ⁇ used.
  • the overlying sheet or layer 14 has a predetermined ⁇ urface area and a thickne ⁇ of between about 0.0005 and 0.010 inche ⁇ , preferably about 0.002 inch.
  • a laminating pouch 2 i ⁇ formed from the overlying ⁇ heet 14 it will be under ⁇ tood that the overlying ⁇ heet 14 will have an exposed side or top surface 16 adjacent the exterior of the pouch 2 and an interior side or bottom surface 18 adjacent the interior of the pouch 2.
  • the overlying sheet 14 can be coated on both the exposed side 16 and interior side 18.
  • the overlying film sheet 14 has a coating 42 of a low temperature heat seal adhesive on it ⁇ interior side 18.
  • the low temperature heat ⁇ eal adhe ⁇ ive be activated at temperature ⁇ between about 180 F and 300 F, preferably between about 180 F and 245 F, mo ⁇ t preferably about 180 F.
  • the precise adhesive that is used can be determined based on the type of equipment, such as a copier, printer, fac ⁇ imile machine, or the like in which it i ⁇ de ⁇ ired to use the particular laminating pouch 2.
  • ⁇ moother adhe ⁇ ive coating ⁇ 42 are required a ⁇ the ⁇ peed of the equipment increa ⁇ e ⁇ .
  • the laminating pouch 2 of the invention will only be useful in high speed copiers that make 100 to 150 copies per minute or more if the adhesive coating 42 is glas ⁇ smooth.
  • Suitable low temperature heat seal adhesives include, but are not limited to, ethylene vinyl acetate, acrylic, acrylic copolymer ⁇ , polye ⁇ ter, polye ⁇ ter copolymers, polyethylene- ethylene vinyl acetate, ethylene copolymers, low density polyethylene, high density polyethylene, and mixture ⁇ thereof.
  • Suitable adhesive ⁇ are available from Oliver Products Corp., Grand Rapids, Michigan and Baker Adhe ⁇ ives, Inc. of Newark, New Jersey.
  • the thickness of the adhesive layer is between about 0.0003 to 0.003 inches thick, preferably about 0.002 inch.
  • the adhesive layer 42 preferably includes an anti ⁇ static compound.
  • Anti-static compound ⁇ serve to minimize inclu ⁇ ion of dust particles before and during lamination.
  • Suitable anti-static compounds include, but are not limited to, quaternary ammonium salts.
  • the laminating pouch 2 also includes an underlying sheet or bottom film layer 4.
  • the underlying sheet 4 can be formed of any suitable heat stable, clear, matte, surface embo ⁇ sed, textured, or ⁇ mooth plastic film or sheet.
  • Suitable film ⁇ or ⁇ heets include, but are no limited to, polyester, polyethylene terephthalate, polyethylene naphthalate, polycarbonate, nylon, paper, board, polypropylene, vinyl, and the like.
  • Polye ⁇ ter tran ⁇ parent film ⁇ such as Mylar, available from E.I. Dupont, are particularly suitable.
  • the underlying sheet 4 has a predetermined surface area sub ⁇ tantially contiguou ⁇ with the predetermined ⁇ urface area of the overlying ⁇ heet 14 and a thickne ⁇ of between about 0.00092 to 0.010 inches, preferably about 0.004 inch.
  • the underlying ⁇ heet or film 4 may be heat ⁇ tabilized ⁇ o that it will not be deformed by heat from printing machine roller ⁇ , which generally operate at temperatures between about 180 Fahrenheit and 300 Fahrenheit.
  • the underlying ⁇ heet 4 When a laminating pouch 2 is formed from the underlying ⁇ heet 4, it will be under ⁇ tood that the underlying ⁇ heet 4 will have an adjacent ⁇ ide or top ⁇ urface 12 adjacent the low temperature heat seal adhesive layer 42 on the overlying ⁇ heet 14 of the pouch 2 and a di ⁇ tal ⁇ ide or bottom ⁇ urface 10 oppo ⁇ ite the adjacent side 12.
  • An adhesion promoting coating 32 is provided on the adjacent side 12 of the underlying sheet 4. As with the adhe ⁇ ive coating 42, the ⁇ moothne ⁇ of the adhe ⁇ ion promoting coating 32 mu ⁇ t increa ⁇ e a ⁇ the ⁇ peed of the equipment in which the laminating pouch 2 is to be u ⁇ ed increa ⁇ e ⁇ .
  • Suitable adhe ⁇ ion promoting coating ⁇ include, but are not limited to, ethylene acrylic acid, acrylic resin, polye ⁇ ter re ⁇ in, ultraviolet cured acrylate, ⁇ ilicone ⁇ ilicate, urethane, and mixture ⁇ thereof.
  • an ethylene acrylic acid coating is used.
  • the thickness of the adhesion promoting coating 32 is between about 0.00005 and 0.0010 inches.
  • the coating 32 on the adjacent side 12 of the underlying ⁇ heet 4 may be a relea ⁇ e coating.
  • a ⁇ ilicone relea ⁇ e coating may be provided.
  • the underlying layer 4 i ⁇ ⁇ eparated from the overlying layer 14 and flexible ⁇ heet material 26 after the lamination proces ⁇ is complete. The overlying layer 14 and the flexible sheet material 26 remain laminated together.
  • a friction enhancing coating 34 is provided on the distal ⁇ ide or bottom 10 of film sheet 4.
  • the friction enchancing coating 34 serves to increase the coefficient of friction of the underlying ⁇ heet 4 and provide traction for the laminating pouch 2 ⁇ o that it can be fed through roller ⁇ of a copier or printing machine or the like.
  • the friction enhancing coating 34 provides scratch resi ⁇ tance to the distal surface 10 of the underlying film 4.
  • Suitable friction enhancing coating ⁇ 34 include, but are not limited to, acrylic re ⁇ in, polye ⁇ ter re ⁇ in, ultraviolet cured acrylate, silicone ⁇ ilicate, urethane, and the like.
  • Such coating material ⁇ generally include incorporated ⁇ ilica, or clay fillers to enhance roughness and provide a disparate surface.
  • an acrylic or polyester resin coating i ⁇ used.
  • the friction enhancing coating ⁇ 34 can be formulated to provide a clear or matte ⁇ urface and to enhance the coefficient of friction of the underlying ⁇ heet 4.
  • the thickness of friction enhancing coating 34 is between about 0.00005 and 0.0004 inches.
  • Both the adhesion promoting coating 32 and the friction enhancing coating 34 may include an anti-static compounds.
  • anti-static compounds serve to minimize inclusion of dust particles before and during lamination.
  • Suitable anti-static compounds include, but are not limited to, quaternary ammonium salt ⁇ .
  • a front leader 6 is an extension of the underlying or lower film sheet 4 and is of the same thickness.
  • the leader 6 can either be an integral part of the bottom pla ⁇ tic ⁇ heet 4 ⁇ eparated by perforation 20, or alternatively, a ⁇ eparate paper leader or other heat ⁇ table material.
  • the leader 6 has a length of between about 1 and 5 inches, preferably about 3 inches.
  • the attaching means must be of a removable character so the leader 6 can be removed from the underlying sheet 4 when the lamination process is completed. Alternatively, the leader 6 can be cut from the underlying sheet 4. In a preferred embodiment, the right lead corner of leader 6 can be notched at 7 to indicate the lead end for convenience.
  • the overlying sheet or top film layer 14 with exposed ⁇ ide or top ⁇ urface 16 and interior ⁇ ide or bottom ⁇ urface 18 is joined to the underlying sheet or bottom film layer 4 along indicated edge 24. This is accomplished, for example, by ⁇ uch means a ⁇ heat sealing approximately 1/8 to 1/4 inch with adhe ⁇ ive 13 along the leading edge 24 of the top film layer 14.
  • a flexible sheet material or document 26 which has a surface area le ⁇ than the predetermined ⁇ urface area of the overlying sheet 14 and the underlying sheet , to be laminated is in ⁇ erted back side 28 up into the pouch 2 with the face 27 down, as shown in FIGS. 3 and 4.
  • the face 27 of the document or the part to be seen is adjacent the bottom film layer 4.
  • Document 26 leading edge 29 is snug to the heat sealed joint 24 between the bottom film layer 4 and the top film layer 14.
  • Document 26 preferably should be at least 1/8 to 1/4 inch smaller on each side than the pouch 2. The borders thus formed 44, 46, and 48 are necessary to ensure that the top film layer 14 properly adheres to the bottom film layer 4 along the edges 44, 46, and 48.
  • the finished laminated document 26 has an approximately 1/4 inch wide plastic film border or plastic frame resulting from the operation.
  • the setting on the toner level of the copier is adjusted to the lowest level and a copy bypass function is used if it is available.
  • a perfectly clean white sheet of paper is placed on the document glass and the entire glass covered. If the copier has a manual feed tray, the document pouch 2 is placed therein with the forward lead feeder fir ⁇ t with the notch 7 or indicia on the right, with the bottom film of the laminate ⁇ andwich on the lower ⁇ ide. In the event a copy machine print ⁇ on the underside of the page, reverse the sandwich, forward feed the leader on the bottom side of the sandwich top notch 7 on the left, pres ⁇ the copier operating button and the sandwich will feed through the copier.
  • the sandwich is placed in the main feed tray of the printer, forward feed leader fir ⁇ t, bottom ⁇ ide of the ⁇ andwich down, notch on top right, feed the blank page by entering a couple of carriage return ⁇ on the computer and ⁇ end the print command to the printer.
  • Some ⁇ oftware package ⁇ allow to print a blank page or form feed a single sheet using the bypass sy ⁇ tem.
  • the sandwich will feed through the printer.
  • the document pouch is placed in the plain paper feed tray with the forward feed leader first, bottom of the sandwich down, top notch right. Insert a clean white sheet of paper into automatic document feeder and pres ⁇ the copy key. The ⁇ andwich will now feed through the facsimile machine.
  • the pouch can be used with conventional laminating machine ⁇ .
  • lamination i ⁇ complete remove the forward and rear leader ⁇ 6 and 8 by tearing off at the perforation ⁇ 9 and 20 a ⁇ shown in FIG. 5.
  • the initially sealed pouch may be rerun through the copier, reversing end ⁇ to assure complete adhesion.
  • the bottom film layer has a heat activated adhe ⁇ ive on the top ⁇ ide.
  • the top heat activated adhe ⁇ ive coated layer 14 can be paper or paper board.
  • the bottom layer 4 could be paper or paper board in which ca ⁇ e the image ⁇ ide of document 26 would face top layer 14.
  • a ⁇ heet may be in ⁇ erted between the document and film layer ⁇ to serve as a shield for the document and may al ⁇ o be used to introduce specular effects, sparkling highlights and other ⁇ pecial effect ⁇ . Thus the document could later be removed from the lamination without destroying the document.
  • Bottom film layer has clear coating on the underside and 1/4 inch heat activated adhesive border around it ⁇ perimeter on its top side.
  • the top film layer remains the same with the heat activated adhe ⁇ ive over the entire underside.
  • Both top and bottom films can have 1/4 inch adhesive border around the perimeters.

Abstract

Documents are laminated in office copiers and printing machines wherein the toner is fixed with hot rollers. A specially designed pouche (2) is used comprising a bottom sheet (4) of a film such as polyester which is sealed along one traverse line (20) to an overlying sheet (14) of similar or different polyester or other plastic material having a heat sealable adhesive on its bottom surface (18). The underlying sheet extends beyond the top cover sheet to form leader strips (20) which are detachable from the main portion of the sheet along perforated tear strips. The front leader (6) optionally can have an indicia indicating a forward corner to orient the pouch within the copier machine in a proper direction and surface position. The pouch is dimensioned so that it is slightly larger than the document to be laminated.

Description

PRODUCT AND PROCESS FOR LAMINATING DOCUMENTS This is a continuation-in-part of U.S. Patent Application Serial No. 08/496,278, filed June 28, 1995.
Field of the Invention This invention relates generally to products and processes for laminating flexible sheet material and, in particular, to a product and process for laminating such sheet material that is useful at low temperatures .
Background of the Invention The present invention is concerned with lamination of sheet material such as paper or similar documents utilizing commonly available xerographic copiers, laser printers, plain paper facsimile machines, and the like, which utilize heat and pressure rollers in their operation. Conventionally, lamination of documents is accomplished with specially designed laminating machines which are utilized only in large offices or job shops since they are too complicated and expensive for ordinary office use.
In accordance with this invention, a special plastic pouch and leader system is utilized to obtain the rapid lamination of documents or other flat materials by utilizing the heat and pressure of the common office copier machines, facsimile machines, laser printers, or similar printing machines. Such machines have at least one heated roller through which the paper sheet on which the copy image is formed is passed.
In accordance with the present invention, photographs, business cards, ordinary print materials, identification cards, and the like can be laminated utilizing common office copier machines. Since no additional machinery is involved, only the relatively inexpensive specially designed laminating pouch is required to obtain excellent laminated documents with the ordinary office copier types of machines.
This invention concerns a means and method for laminating flexible sheet material by feeding the item to be laminated after it has been placed in the "pocket/envelope" of the laminating package into the copy paper supply tray of the standard office copier, laser printer, or facsimile machine. The toner of the machine is turned down to a minimum and a blank piece of paper is placed on the copying surface. The copy machine is then activated and the pouch is fed by means of the leader which is either paper or a specially coated extension of the plastic sheet through the feed and ultimately through the heated rollers of the ordinary copy machine. This results in the overlying sheet being adhesively secured to the underlying sheet around the required perimeter, the middle sheet to be laminated, and the heat sealing of the underlying sheet to the back face of the flexible sheet to be laminated, leaving the front or good side of the piece not adhered to the cover sheet, making for a clearer and more accurate view of the face of the item laminated. Experimentation shows that the preferred leader extension is important in order to assure initiation of the feed of the product into the copy machine although the laminating may optionally be utilized without a separate leader.
In U.S.3,091,160 Crumrine et al. xerographic machinery is utilized for aerial reconnaissance. It shows the utilization of adhesive coated paper strip to protect and cover a further strip on which the paper image is formed. A set of pressure rollers is used to set a transparent plastic web so that it adheres to the adhesive on a transfer strip and fixes the powder image thereon, forming a protective cover therefor.
U.S. 5,126,797 Forest et al. A tone image sheet is laminated using a transparent laminating sheet fed from a normal copy sheet supply of a copier printer or the like with the laminating contact with the toner image after the tone image has been formed on a receiving sheet. The resulting sandwich layer is fed through the fuser, laminating the image between the sheets.
The patent of Coleman et al. U.S. 5,327,201 and the two patents of Cherian U.S. 5,337,132 and U.S. 5,357,326 disclose the creation of simulated color photographic prints using xerography. For example, as described in the Coleman et al. patent, a transparent carrier having a xerographically formed mirror image fused thereto is bonded to a plastic substrate through the use of heat and pressure. The Cherian '132 patent discloses an apparatus for accomplishing that purpose.
The Cherian '326 patent describes bonding using pressure and heat applied through the use of a heated top platen.
In U.S. 5,364,671 Gustafson there is disclosed a cover assembly for use with photographs comprising a flexible polyester sheet larger than the photograph with a central transparent viewing portion and outer frame portion, the cover assembly having a layer of adhesive on its rear surface along the frame portion to afford firm adhesion of the sheet to the edge portion of the photograph and to a surface to support the photograph and cover assembly along the surface but being removable from the εurface and photograph without damaging them.
Summary of the Invention
In general, a laminating pouch for laminating a flexible sheet material is provided in accordance with the invention. The pouch includes an overlying sheet formed of a film having an exposed side and an interior side, and a first surface area. A low temperature heat seal adhesive is coated on the interior side of the overlying sheet. The pouch also includes an underlying sheet formed of a film having an adjacent side positioned adjacent the low temperature heat seal adhesive and a distal side opposite the adjacent side. The underlying sheet has a second surface area that is substantially the same as the first surface area of the overlying sheet. An adhesion promoting coating is provided on the adjacent side of the underlying sheet for the purpose of promoting adhesion between the overlying sheet and the underlying sheet.
The laminating pouch is used for the purpose of laminating a flexible sheet material. The flexible sheet material has a third surface area that is smaller than the first and second surface areas of the overlying and underlying sheets, respectively. When the flexible sheet material is positioned between the low temperature heat seal adhesive on the overlying sheet and the adhesion promoting coating on the underlying sheet, the overlying sheet can be permanently adhered to the underlying sheet with the flexible sheet material therebetween when the laminating pouch is subjected to temperatures between about 150 F and 300 F. In an alternate embodiment, a release coating is used on the adjacent side of the underlying sheet for the purpose of permitting the underlying sheet to be separated from the adhered overlying sheet and flexible sheet material when the lamination is complete. A process for laminating a flexible sheet material is also provided.
The invention accordingly comprises an article of manufacture possessing the featureε, propertieε, and the relation of elements which will be exemplified in the article hereinafter described, and the εeveral steps and the relation of one or more of such εteps with reεpect to each of the otherε thereof, which will be exemplified in the method hereinafter disclosed, and the scope of the invention will be indicated in the claims . Brief Description of the Drawings
For a fuller understanding of the invention, reference is had to the following description taken in connection with the accompanying drawings, in which:
FIG. 1 is a side plan view of a laminating pouch constructed and arranged in accordance with the invention;
FIG. 2 is a sectional view of the laminating pouch of FIG. 1;
FIG. 3 iε a top plan view of a laminating pouch conεtructed and arranged in accordance with the invention illustrating placement of a flexible sheet material therein;
FIG. 4 is a top plan view of a laminating pouch constructed and arranged in accordance with the invention having a flexible εheet material therein; and, FIG. 5 is a top plan view of a fully laminated pouch constructed and arranged in accordance with the invention. Detailed Description of the Preferred Embodiments
In the accompanying drawings, a laminating pouch constructed and arranged in accordance with the invention is indicated generally by reference numeral 2. The laminating pouch 2 includeε an overlying or top film εheet 14 and an underlying or bottom film εheet 4.
The overlying εheet 14 iε formed of a εuitable heat reεiεtant film. The film may be clear, opaque, matte, color tinted, εurface embossed or textured plastic. Suitable films include, but are not limited to, polyester, polyethylene terephthalate, polyethylene naphthalate, nylon, polypropylene, vinyl, and the like. Suitable films are commercially available from 3M Corporation of Minneapolis, Minneεota, and Preciεion Coatingε, Walled Lake, Michigan, and Arkwright Corp. of Fiεkville, Rhode Iεland. In a preferred embodiment, a polyeεter film iε used.
The overlying sheet or layer 14 has a predetermined εurface area and a thickneεε of between about 0.0005 and 0.010 incheε, preferably about 0.002 inch. When a laminating pouch 2 iε formed from the overlying εheet 14, it will be underεtood that the overlying εheet 14 will have an exposed side or top surface 16 adjacent the exterior of the pouch 2 and an interior side or bottom surface 18 adjacent the interior of the pouch 2.
The overlying sheet 14 can be coated on both the exposed side 16 and interior side 18. The overlying film sheet 14 has a coating 42 of a low temperature heat seal adhesive on itε interior side 18. In general, it is deεired that the low temperature heat εeal adheεive be activated at temperatureε between about 180 F and 300 F, preferably between about 180 F and 245 F, moεt preferably about 180 F. The precise adhesive that is used can be determined based on the type of equipment, such as a copier, printer, facεimile machine, or the like in which it iε deεired to use the particular laminating pouch 2.
The smoothneεε of the adheεive coating 42 iε a function of the equipment in which the laminating pouch 2 is to be uεed. In general, εmoother adheεive coatingε 42 are required aε the εpeed of the equipment increaεeε . The laminating pouch 2 of the invention will only be useful in high speed copiers that make 100 to 150 copies per minute or more if the adhesive coating 42 is glasε smooth.
Suitable low temperature heat seal adhesives include, but are not limited to, ethylene vinyl acetate, acrylic, acrylic copolymerε, polyeεter, polyeεter copolymers, polyethylene- ethylene vinyl acetate, ethylene copolymers, low density polyethylene, high density polyethylene, and mixtureε thereof. In a preferred embodiment, polyethylene-ethylene vinyl acetate iε used.
Suitable adhesiveε are available from Oliver Products Corp., Grand Rapids, Michigan and Baker Adheεives, Inc. of Newark, New Jersey. The thickness of the adhesive layer is between about 0.0003 to 0.003 inches thick, preferably about 0.002 inch.
The adhesive layer 42 preferably includes an anti¬ static compound. Anti-static compoundε serve to minimize incluεion of dust particles before and during lamination. Suitable anti-static compounds include, but are not limited to, quaternary ammonium salts.
The laminating pouch 2 also includes an underlying sheet or bottom film layer 4. The underlying sheet 4 can be formed of any suitable heat stable, clear, matte, surface emboεsed, textured, or εmooth plastic film or sheet. Suitable filmε or εheets include, but are no limited to, polyester, polyethylene terephthalate, polyethylene naphthalate, polycarbonate, nylon, paper, board, polypropylene, vinyl, and the like. Polyeεter tranεparent filmε such as Mylar, available from E.I. Dupont, are particularly suitable.
The underlying sheet 4 has a predetermined surface area subεtantially contiguouε with the predetermined εurface area of the overlying εheet 14 and a thickneεε of between about 0.00092 to 0.010 inches, preferably about 0.004 inch. Depending upon the specific film thickneεε that is used, the underlying εheet or film 4 may be heat εtabilized εo that it will not be deformed by heat from printing machine rollerε, which generally operate at temperatures between about 180 Fahrenheit and 300 Fahrenheit.
When a laminating pouch 2 is formed from the underlying εheet 4, it will be underεtood that the underlying εheet 4 will have an adjacent εide or top εurface 12 adjacent the low temperature heat seal adhesive layer 42 on the overlying εheet 14 of the pouch 2 and a diεtal εide or bottom εurface 10 oppoεite the adjacent side 12.
An adhesion promoting coating 32 is provided on the adjacent side 12 of the underlying sheet 4. As with the adheεive coating 42, the εmoothneεε of the adheεion promoting coating 32 muεt increaεe aε the εpeed of the equipment in which the laminating pouch 2 is to be uεed increaεeε.
Suitable adheεion promoting coatingε include, but are not limited to, ethylene acrylic acid, acrylic resin, polyeεter reεin, ultraviolet cured acrylate, εilicone εilicate, urethane, and mixtureε thereof. In a preferred embodiment, an ethylene acrylic acid coating is used. The thickness of the adhesion promoting coating 32 is between about 0.00005 and 0.0010 inches. Alternatively, the coating 32 on the adjacent side 12 of the underlying εheet 4 may be a releaεe coating. In particular, a εilicone releaεe coating may be provided. In this embodiment, the underlying layer 4 iε εeparated from the overlying layer 14 and flexible εheet material 26 after the lamination procesε is complete. The overlying layer 14 and the flexible sheet material 26 remain laminated together.
A friction enhancing coating 34 is provided on the distal εide or bottom 10 of film sheet 4. The friction enchancing coating 34 serves to increase the coefficient of friction of the underlying εheet 4 and provide traction for the laminating pouch 2 εo that it can be fed through rollerε of a copier or printing machine or the like. In addition, the friction enhancing coating 34 provides scratch resiεtance to the distal surface 10 of the underlying film 4.
Suitable friction enhancing coatingε 34 include, but are not limited to, acrylic reεin, polyeεter reεin, ultraviolet cured acrylate, silicone εilicate, urethane, and the like. Such coating materialε generally include incorporated εilica, or clay fillers to enhance roughness and provide a disparate surface. In a preferred embodiment, an acrylic or polyester resin coating iε used.
The friction enhancing coatingε 34 can be formulated to provide a clear or matte εurface and to enhance the coefficient of friction of the underlying εheet 4. The thickness of friction enhancing coating 34 is between about 0.00005 and 0.0004 inches.
Both the adhesion promoting coating 32 and the friction enhancing coating 34 may include an anti-static compounds. Again, anti-static compounds serve to minimize inclusion of dust particles before and during lamination. Suitable anti-static compounds include, but are not limited to, quaternary ammonium saltε.
A front leader 6 is an extension of the underlying or lower film sheet 4 and is of the same thickness. The leader 6 can either be an integral part of the bottom plaεtic εheet 4 εeparated by perforation 20, or alternatively, a εeparate paper leader or other heat εtable material. The leader haε a thickneεs of between about 0.003 and 0.008 inches and can be attached to the underlying sheet 4 by any suitable means such as heat sealing, gluing, or taping to a leading edge. The leader 6 has a length of between about 1 and 5 inches, preferably about 3 inches.
The attaching means must be of a removable character so the leader 6 can be removed from the underlying sheet 4 when the lamination process is completed. Alternatively, the leader 6 can be cut from the underlying sheet 4. In a preferred embodiment, the right lead corner of leader 6 can be notched at 7 to indicate the lead end for convenience.
A rear leader 8 as shown in the embodiment with perforation lines 9 iε alεo contemplated in accordance with the invention, but is not required on most machines. When used, the rear leader 8 is between about 1 and 3 inches in length.
The overlying sheet or top film layer 14 with exposed εide or top εurface 16 and interior εide or bottom εurface 18 is joined to the underlying sheet or bottom film layer 4 along indicated edge 24. This is accomplished, for example, by εuch means aε heat sealing approximately 1/8 to 1/4 inch with adheεive 13 along the leading edge 24 of the top film layer 14.
A flexible sheet material or document 26, which has a surface area leεε than the predetermined εurface area of the overlying sheet 14 and the underlying sheet , to be laminated is inεerted back side 28 up into the pouch 2 with the face 27 down, as shown in FIGS. 3 and 4. Thus, the face 27 of the document or the part to be seen is adjacent the bottom film layer 4. Document 26 leading edge 29 is snug to the heat sealed joint 24 between the bottom film layer 4 and the top film layer 14. Document 26 preferably should be at least 1/8 to 1/4 inch smaller on each side than the pouch 2. The borders thus formed 44, 46, and 48 are necessary to ensure that the top film layer 14 properly adheres to the bottom film layer 4 along the edges 44, 46, and 48. The finished laminated document 26 has an approximately 1/4 inch wide plastic film border or plastic frame resulting from the operation. In the above example using the pouch 2 in a copier, before feeding the document 26 in the plastic pouch 2 through a copier, the setting on the toner level of the copier is adjusted to the lowest level and a copy bypass function is used if it is available.
A perfectly clean white sheet of paper is placed on the document glass and the entire glass covered. If the copier has a manual feed tray, the document pouch 2 is placed therein with the forward lead feeder firεt with the notch 7 or indicia on the right, with the bottom film of the laminate εandwich on the lower εide. In the event a copy machine printε on the underside of the page, reverse the sandwich, forward feed the leader on the bottom side of the sandwich top notch 7 on the left, presε the copier operating button and the sandwich will feed through the copier.
For laser printers the sandwich is placed in the main feed tray of the printer, forward feed leader firεt, bottom εide of the εandwich down, notch on top right, feed the blank page by entering a couple of carriage returnε on the computer and εend the print command to the printer. Some εoftware packageε allow to print a blank page or form feed a single sheet using the bypass syεtem. The sandwich will feed through the printer. In thermal fax machines, the document pouch is placed in the plain paper feed tray with the forward feed leader first, bottom of the sandwich down, top notch right. Insert a clean white sheet of paper into automatic document feeder and presε the copy key. The εandwich will now feed through the facsimile machine.
Of course, the pouch can be used with conventional laminating machineε. When lamination iε complete remove the forward and rear leaderε 6 and 8 by tearing off at the perforationε 9 and 20 aε shown in FIG. 5.
If necesεary to completely εeal the document and assure complete adhesion the initially sealed pouch may be rerun through the copier, reversing endε to assure complete adhesion.
Since the adhesive iε on the back side of the document 26 this leaves the front side free of adhesive and resultε in a lamination with more depth in the appearance of the print. It is more attractive than conventional two-sided adheεive coated plaεtic pouch laminations.
The advantage of this process is that it iε quicker than conventional laminating machineε, uses less energy, no special laminating equipment is required, and process may be utilized with most office copiers, laεer printers and thermal fax machines. Resulting laminations are more flexible than ordinary laminationε with conventional poucheε.
Alternatively the bottom film layer has a heat activated adheεive on the top εide. Alεo, the top heat activated adheεive coated layer 14 can be paper or paper board. The bottom layer 4 could be paper or paper board in which caεe the image εide of document 26 would face top layer 14.
Alεo, a εheet may be inεerted between the document and film layerε to serve as a shield for the document and may alεo be used to introduce specular effects, sparkling highlights and other εpecial effectε. Thus the document could later be removed from the lamination without destroying the document.
Bottom film layer has clear coating on the underside and 1/4 inch heat activated adhesive border around itε perimeter on its top side. The top film layer remains the same with the heat activated adheεive over the entire underside. Both top and bottom films can have 1/4 inch adhesive border around the perimeters.
While the invention has been described by reference to an illustrative embodiment, it is not intended that the novel device be limited thereby, but that modifications thereof are intended to be included as falling within the broad spirit and scope of the foregoing diεcloεure, the following claimε and the appended drawingε.

Claims

WHAT IS CLAIMED IS:
1. A laminating pouch for laminating a flexible sheet material compriεing: an overlying sheet formed of a film having an exposed side and an interior side, said overlying εheet further having a firεt εurface area; a low temperature heat εeal adheεive coated on the interior side of the overlying sheet; an underlying εheet formed of a film having an adjacent εide positioned adjacent the low temperature heat seal adhesive and a distal side opposite the adjacent side, said underlying εheet further having a εecond εurface area εubstantially the same as the first surface area of the overlying sheet; an adhesion promoting coating on the adjacent side of the underlying sheet for the purpoεe of promoting adhesion between the overlying sheet and the underlying sheet; whereby when a flexible εheet material having a third εurface area εmaller than the firεt and second surface areaε iε poεitioned between the low temperature heat seal adhesive on the overlying sheet and the adhesion promoting coating on the underlying sheet, the overlying εheet can be permanently adhered to the underlying εheet with the flexible εheet material therebetween when the laminating pouch iε εubjected to temperatureε between about 150 F and 300 F.
2. The laminating pouch of claim 1 wherein the overlying εheet is a film selected from the group consiεting of polyethylene terephthalate, polyethylene naphthalate, nylon, polypropylene, and vinyl.
3. The laminating pouch of claim 1 wherein the overlying sheet is between about 0.0005 and 0.10 inches thick.
4. The laminating pouch of claim 1 wherein the overlying sheet is clear.
5. The laminating pouch of claim 1 wherein the overlying sheet is opaque.
6. The laminating pouch of claim 1 wherein the low temperature heat seal adheεive coating iε glaεs smooth.
7. The laminating pouch of claim 1 wherein the low temperature heat seal adhesive iε εelected from the group conεiεting of ethylene vinyl acetate, acrylic, acrylic copolymer, polyester, polyester copolymer, polyethylene-ethylene vinyl acetate, ethylene copolymer, low denεity polyethylene, high denεity polyethylene, and mixtures thereof.
8. The laminating pouch of claim 7 wherein the low temperature heat seal adheεive iε polyethylene-ethylene vinyl acetate copolymer.
9. The laminating pouch of claim 7 wherein the low temperature heat εeal adheεive includeε an anti-εtatic compound.
10. The laminating pouch of claim 7 wherein the low temperature heat εeal is used as an activated dry adheεive coating and iε coated at a thickneεε of between about 0.0003 and 0.003 incheε.
11. The laminating pouch of claim 1 wherein the underlying εheet is a selected from the group consiεting of polyethylene terephthalate, polyethylene naphthalate, nylon, paper, board, polypropylene, and vinyl.
12. The laminating pouch of claim 1 wherein the underlying εheet iε between about 0.00092 and 0.010 incheε thick.
13. The laminating pouch of claim 1 wherein the underlying εheet iε clear.
14. The laminating pouch of claim 1 wherein the adhesion promoting coating is glaεε smooth.
15. The laminating pouch of claim 1 wherein the adheεion promoting coating iε εelected from the group conεiεting of ethylene acrylic acid, acrylic reεin, polyester resin, ultraviolet cured acrylate, silicone εilicate, urethane, and mixtureε thereof.
16. The laminating pouch of claim 1 wherein the adheεion promoting coating haε a thickneεs of between about 0.00005 and 0.0020 inches.
17. The laminating pouch of claim 1 wherein the pouch further includes a friction enhancing coating on the distal εide of the underlying εheet.
18. The laminating pouch of claim 17 wherein the friction enhancing coating iε selected from the group consiεting of acrylic reεin, polyeεter reεin, ultraviolet cured acrylate, εilicone εilicate, urethane, and mixtureε thereof.
19. The laminating pouch of claim 18 wherein the friction enhancing coating further includeε a roughneεε enhancer εelected from the group conεisting of εilica, clay, and mixtureε thereof.
20. The laminating pouch of claim 17 wherein the friction enhancing coating has a thickness between about 0.00005 and 0.0004 inches.
21. The laminating pouch of claim 1 wherein the pouch further includes a leader secured to the underlying εheet.
22. A laminating pouch for laminating a flexible sheet material comprising: an overlying sheet formed of a film having an exposed side and an interior εide, said overlying sheet further having a first εurface area; a low temperature heat εeal adheεive coated on the interior εide of the overlying εheet; an underlying εheet formed of a film having an adjacent εide poεitioned adjacent the low temperature heat seal adheεive and a distal side opposite the adjacent side, said underlying sheet further having a second surface area subεtantially the εame aε the first surface area of the overlying sheet; a release coating on the adjacent side of the underlying sheet for the purpose of permitting the underlying sheet to be separated; whereby when a flexible εheet material having a third εurface area εmaller than the firεt and εecond surface areas is positioned between the low temperature heat εeal adhesive on the overlying sheet and the release coating on the underlying sheet, the overlying sheet can be permanently adhered to the the flexible sheet material when the laminating pouch is subjected to temperatures between about 150 F and 300 F and the underlying εheet can then be εeparated from the adhered overlying εheet and flexible sheet material.
23. The laminating pouch of claim 22 wherein the release coating iε εilicone.
24. A process for laminating a flexible sheet material comprising: providing a laminating pouch having an overlying sheet formed of a film having an exposed εide and an interior εide, said overlying sheet further having a first surface area; a low temperature heat seal adhesive coated on the interior side of the overlying sheet; an underlying sheet formed of a film having an adjacent side poεitioned adjacent the low temperature heat seal adheεive and a distal side opposite the adjacent εide, said underlying sheet further having a εecond surface area substantially the same as the firεt surface area of the overlying sheet; an adhesion promoting coating on the adjacent side of the underlying εheet for the purpose of promoting adhesion between the overlying sheet and the underlying εheet; poεitioning a flexible εheet material having a third εurface area εmaller than the firεt and second surface areaε between the low temperature heat seal adhesive on the overlying sheet and the adjacent side coating on the underlying sheet; and, subjecting the laminating pouch to a temperature between about 150 F and 300 F so that the overlying εheet iε permanently adhered to the underlying εheet with the flexible εheet material therebetween.
PCT/US1996/010856 1995-06-28 1996-06-27 Product and process for laminating documents WO1997001435A1 (en)

Priority Applications (1)

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US49627895A 1995-06-28 1995-06-28
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Cited By (3)

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Publication number Priority date Publication date Assignee Title
US6544629B1 (en) 2001-05-24 2003-04-08 Bryan A. Netsch Food grade laminate
US6794004B1 (en) 2001-03-13 2004-09-21 Bryan A. Netsch Food package insert and decoder game
US6811646B1 (en) 2001-03-13 2004-11-02 Bryan A. Netsch Food package insert and decoder game

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US4158587A (en) * 1977-09-26 1979-06-19 General Binding Corporation Method of producing laminated sheets using laminated pouch support
US4185405A (en) * 1977-04-05 1980-01-29 General Binding Corporation Prefabricated laminating packet with tab
US5058926A (en) * 1990-03-26 1991-10-22 Transilwrap Company, Inc. Lamination product for manufacture of identification card

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Publication number Priority date Publication date Assignee Title
US3918188A (en) * 1974-03-14 1975-11-11 Transilwrap Co Inc Laminating pouch and integrated carrier
US4185405A (en) * 1977-04-05 1980-01-29 General Binding Corporation Prefabricated laminating packet with tab
US4158587A (en) * 1977-09-26 1979-06-19 General Binding Corporation Method of producing laminated sheets using laminated pouch support
US5058926A (en) * 1990-03-26 1991-10-22 Transilwrap Company, Inc. Lamination product for manufacture of identification card

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Publication number Priority date Publication date Assignee Title
US6794004B1 (en) 2001-03-13 2004-09-21 Bryan A. Netsch Food package insert and decoder game
US6811646B1 (en) 2001-03-13 2004-11-02 Bryan A. Netsch Food package insert and decoder game
US6544629B1 (en) 2001-05-24 2003-04-08 Bryan A. Netsch Food grade laminate

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