WO1996038620A1 - Flat elastomeric nonwoven laminates - Google Patents
Flat elastomeric nonwoven laminates Download PDFInfo
- Publication number
- WO1996038620A1 WO1996038620A1 PCT/US1996/007938 US9607938W WO9638620A1 WO 1996038620 A1 WO1996038620 A1 WO 1996038620A1 US 9607938 W US9607938 W US 9607938W WO 9638620 A1 WO9638620 A1 WO 9638620A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- laminate
- web
- elastomeric
- nonwoven
- recovery
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
- B32B7/14—Interconnection of layers using interposed adhesives or interposed materials with bonding properties applied in spaced arrangements, e.g. in stripes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/40—Layered products comprising a layer of synthetic resin comprising polyurethanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/022—Non-woven fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/024—Woven fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/02—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
- B32B5/026—Knitted fabric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B5/00—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
- B32B5/22—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
- B32B5/24—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
- B32B5/26—Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/42—Alternating layers, e.g. ABAB(C), AABBAABB(C)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0276—Polyester fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/02—Synthetic macromolecular fibres
- B32B2262/0292—Polyurethane fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
- B32B2262/10—Inorganic fibres
- B32B2262/106—Carbon fibres, e.g. graphite fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/51—Elastic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/724—Permeability to gases, adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/726—Permeability to liquids, absorption
- B32B2307/7265—Non-permeable
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/2481—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including layer of mechanically interengaged strands, strand-portions or strand-like strips
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/2481—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] including layer of mechanically interengaged strands, strand-portions or strand-like strips
- Y10T428/24818—Knitted, with particular or differential bond sites or intersections
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/24—Structurally defined web or sheet [e.g., overall dimension, etc.]
- Y10T428/24802—Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T428/24826—Spot bonds connect components
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/10—Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
- Y10T442/102—Woven scrim
- Y10T442/133—Inorganic fiber-containing scrim
- Y10T442/14—Including an additional scrim layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/10—Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
- Y10T442/102—Woven scrim
- Y10T442/133—Inorganic fiber-containing scrim
- Y10T442/141—Including a woven fabric which is not a scrim
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/10—Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
- Y10T442/102—Woven scrim
- Y10T442/133—Inorganic fiber-containing scrim
- Y10T442/143—Including a nonwoven fabric which is not a scrim
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3472—Woven fabric including an additional woven fabric layer
- Y10T442/3602—Three or more distinct layers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3707—Woven fabric including a nonwoven fabric layer other than paper
- Y10T442/378—Coated, impregnated, or autogenously bonded
- Y10T442/3829—Four or more layers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/40—Knit fabric [i.e., knit strand or strip material]
- Y10T442/488—Including an additional knit fabric layer
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/40—Knit fabric [i.e., knit strand or strip material]
- Y10T442/494—Including a nonwoven fabric layer other than paper
Definitions
- the present invention is concerned with a laminate material having stretch and recovery, a method of making such laminate material and articles made therefrom. More particularly, the present invention is directed to a laminate material of (1) a first web of, for example, a knit, woven, or scrim material, i.e., a textile material, together with (2) a second web of a nonwoven elastomeric material and (3) a third web of, for example, a knit, woven, or scrim material, i.e., a textile material, to provide a laminate with stretch and recovery; a method of making such laminate, and articles made therefrom.
- a laminate material of (1) a first web of, for example, a knit, woven, or scrim material, i.e., a textile material, together with (2) a second web of a nonwoven elastomeric material and (3) a third web of, for example, a knit, woven, or scrim material, i.e., a textile material, to provide a laminate with stretch and recovery;
- a textile material having stretch and good recovery characteristics yet which provides a flat surface, and has other desirable properties such as breathability, opacity, puncture resistance, etc. Accordingly, it is an object of the present invention to provide a textile material, having a knit, woven or scrim web and having stretch and recovery characteristics in all directions, limited, of course, by the inherent stretch limits of the starting textile material, which textile material is flat, and a method of making such textile material. It is a further object of the present invention to provide a textile material having a knit or woven web, and having stretch and recovery characteristics, but without the need to include elastomeric yarn in the knit or woven structure, and without the need for elastomeric films.
- the present invention is constituted by a laminate of (1) a first web of a knit, woven or scrim material, (2) a second web of nonwoven elastomeric material, and (3) a third web of a knit, woven or scrim material, discontinuously adhesively bonded together.
- the webs when the nonwoven elastomeric web is in an unstretched state, are flat (that is, the first web is non-gathered or non-puckered).
- the laminate material has stretchability and recovery, breathability and barrier properties.
- the laminate material is free of an elastomeric film and the nonwoven elastomeric web provides recovery to the laminate.
- the nonwoven elastomeric web is preferably a web of meltblown elastomeric fibers.
- Figure 1 schematically illustrates a first embodiment of forming a three-web 5 laminate according to the present invention.
- nonwoven fabric or web means a web having a structure
- Nonwoven fabrics or webs have been formed from many processes such as for example, meltblowing processes, spunbonding processes, and bonded carded web processes.
- the basis weight of nonwoven fabrics is usually expressed in ounces of material per square yard (osy) or grams per square meter (gsm) and the fiber diameters
- microfibers means small diameter fibers having an average diameter not greater than about 75 microns, for example, having an average diameter of from about 0.5 microns to about 50 microns, or more particularly, microfibers
- 20 may have an average diameter of from about 2 microns to about 40 microns.
- Another frequently used expression of fiber diameter is denier, which is defined as grams per 9000 meters of a fiber.
- spunbonded fibers refers to small diameter fibers which are formed by extruding molten thermoplastic material as filaments from a plurality of fine, usually circular capillaries of a spinnerette with the diameter of the extruded filaments then being rapidly reduced as by, for example, in U.S. Patent no. 4,340,563 to
- Spunbond fibers are generally not tacky when they are deposited onto a collecting surface. Spunbond fibers are generally continuous and have diameters larger than 7 microns, more particularly, between about 10 and 20 microns.
- meltblown fibers means fibers formed by extruding a molten thermoplastic material through a plurality of fine, usually circular, die capillaries as molten threads or filaments into converging high velocity gas (e.g. air) streams which attenuate the filaments of molten thermoplastic material to reduce their diameter, which may be to microfiber diameter. Thereafter, the meltblown fibers are carried by the high velocity gas stream and are deposited on a collecting surface to form a web of randomly disbursed meltblown fibers.
- high velocity gas e.g. air
- polymer generally includes but is not limited to, homopolymers, copolymers, such as for example, block, graft, random and alternating copolymers, terpolymers, etc. and blends and modifications thereof. Furthermore, unless otherwise specifically limited, the term “polymer” shall include all possible geometrical configuration of the material. These configurations include, but are not limited to isotactic, syndiotactic and random symmetries.
- machine direction means the length of a fabric in the direction in which it is produced.
- cross machine direction means the width of fabric, i.e. a direction generally perpendicular to the MD.
- switchbonded means, for example, the stitching of a material in accordance with U.S. Patent 4,891 ,957 to Strack et al. or U.S. Patent 4,631,933 to Carey, Jr., both incorporated by reference herein.
- ultrasonic bonding means a process performed, for example, by passing the fabric between a sonic horn and anvil roll as illustrated in U.S. Patent 4,374,888 to Bomslaeger incorporated by reference herein.
- thermal point bonding involves passing a fabric or web of fibers to be bonded between a heated calender roll and an anvil roll.
- the calender roll is usually, though not always, patterned in some way so that the entire fabric is not bonded across its entire surface.
- various patterns for calender rolls have been developed for functional as well as aesthetic reasons.
- One example of a pattern has points and is the Hansen Pennings or "H&P" pattern with about a 30% bond area with about 200 bonds/square inch as taught in U.S. Patent 3,855,046 to Hansen and Pennings.
- the H&P pattern has square point or pin bonding areas wherein each pin has a side dimension of 0.038 inches (0.965 mm), a spacing of 0.070 inches (1.778 mm) between pins, and a depth of bonding of 0.023 inches (0.584 mm).
- the resulting pattern has a bonded area of about 29.5%.
- Another typical point bonding pattern is the 5 expanded Hansen and Pennings or "EHP" bond pattern which produces a 15% bond area with a square pin having a side dimension of 0.037 inches (0.94 mm), a pin spacing of 0.097 inches (2.464 mm) and a depth of 0.039 inches (0.991 mm).
- Another typical point bonding pattern designated “714" has square pin bonding areas wherein each pin has a side dimension of 0.023 inches, a spacing of 0.062 inches (1.575 mm) between 0 pins, and a depth of bonding of 0.033 inches (0.838 mm). The resulting pattern has a bonded area of about 15%.
- Other common patterns include a diamond pattern with repeating and slightly offset diamonds and a wire weave pattern looking as the name suggests, e.g. like a window screen.
- the percent bonding area varies from around 10% to around 30% of the area of the fabric laminate web.
- the spot bonding holds the laminate layers together as well as imparts integrity to each individual layer by bonding filaments and/or fibers within each layer, unless prebonded.
- carrier fabric means a fabric which is relatively impermeable to the transmission of liquids, i.e., a fabric which has blood strikethrough O rate of 1.0 or less according to ASTM test method 22.
- multi-use means a material which may be laundered after use and reused at least 25 times without loss of structural integrity and without undue deterioration of its original properties.
- the term "garment” means any type of non-medically oriented 5 apparel which may be worn. This includes industrial work wear and coveralls, undergarments, pants, shirts, jackets, gloves, socks, and the like.
- infection control product means medically oriented items such as surgical gowns and drapes, face masks, head coverings like bouffant caps, surgical caps and hoods, footwear like shoe coverings, boot covers and slippers, wound dressings, bandages, sterilization wraps, wipers, garments like lab coats, coveralls, aprons and jackets, patient bedding, stretcher and bassinet sheets, and the like.
- personal care product means diapers, training pants, absorbent underpants, adult incontinence products, and feminine hygiene products.
- Hydrohead A measure of the liquid barrier properties of a fabric is the hydrohead test. The hydrohead test determines the height of water (in centimeters) which the fabric will support before a predetermined amount of liquid passes through. A fabric with a higher hydrohead reading indicates it has a greater barrier to liquid penetration than a fabric with a lower hydrohead. The hydrohead test is performed according to Federal Test Standard No. 191A, Method 5514. Frazier Porosity: A measure of the breathability of a fabric is the Frazier Porosity which is performed according to Federal Test Standard No. 91 A, Method 5450. Frazier Porosity measures the air flow rate through a fabric in cubic feet of air per square foot of fabric per minute or CSM.
- the blood strikethrough or resistance to blood penetration of a fabric is a measure of the amount of blood which penetrates the fabric at a particular pressure.
- the blood strikethrough is performed by weighing a blotter placed next to the fabric before and after the test which consists of applying 1 pound per square inch gauge (psig) pressure to the side of the fabric away from the blotter, which side has blood thereon. The pressure is ramped up over approximately 10 seconds and removed when it reaches 1 psig. The difference in the weight of the blotter before and after the test in grams represents the amount of blood which has penetrated the fabric.
- psig pound per square inch gauge
- Bacterial Filtration Efficiency The Bacterial Filtration Efficiency (BFE) is a measure of the ability of a fabric to stop the passage of bacteria through it. A higher BFE is generally more desired, especially in medical applications. BFE is measured in percent according to military specification MIL-M-36954C, 4.4.1.1.1 and 4.4.1.2.
- the melt flow rate is a measure of the viscosity of a polymer.
- the MFR is expressed as the weight of material which flows from a capillary of known dimensions under a specified load or shear rate for a measured period of time and is measured in grams/10 minutes at 220°C according to, for example, ASTM test 1238, condition E.
- the Gelbo Lint test determines the relative number of particles released from a fabric when it is subjected to a continuous flexing and twisting movement. It is performed in accordance with INDA test method 160.1-92. A sample is placed in a flexing chamber. As the sample is flexed, air is withdrawn from the chamber at 1 cubic foot per minute for counting in a laser particle counter. The particle counter counts the particles by size from 0.3 to 10 microns using six channels to size the particles. The results can be reported as the total particles counted over 10 consecutive 30 second periods, the maximum concentration achieved in one of the ten counting periods or as an average of the ten counting periods.
- Dry Spore test evaluates the aerosol filtration efficiency of woven and nonwoven fabrics. An aerosol is drawn through a sample of material at a rate of 1 cfm and the results calculated after one minute. The aerosol is a mixture of Bacillus subtilis spores and talc.
- Water Resistance Impact test This test measures a fabric's resistance to the penetration of water under dynamic conditions and is performed according to AATCC standard test 42. A specified volume of water is allowed to spray down against the taut surface of a sample mounted at a 45° angle. The sample is backed by a blotter which is weighed before and after the test. Values are recorded as the number of grams of water penetrated through the fabric. Low numbers indicate good resistance to water penetration.
- Flammability This test is designed to measure the flame resistance of materials when they are in prolonged contact (20 seconds) with the source of ignition and is performed according to NFPA-702. The test also measures the rate of burning. A standardized flame is impinged for twenty seconds (or until ignition) on the lower edge of a specified sized sample mounted at a 45° angle. Results are recorded in seconds for the flame to spread 5 inches.
- Alcohol This test provides a rough index of the resistance of non-woven fabrics to penetration by alcohol and is particularly applicable when comparing various finishes on a given fabric.
- the effectiveness of alcohol-repellent finishes or treatments is determined by placing drops of specified percentages of isopropanol solutions on the surface of the sample and evaluating them after 5 minutes. Grading is by comparison with standard test rating photographs in accordance with INDA test method 80.9-74, revision '82.
- the present invention contemplates a laminate material including two textile webs, e.g., nonelastic textile webs such as webs of knit material, or woven material, or scrim, having stretch and recovery characteristics, achieved by laminating the textile webs to a nonwoven elastomeric web, preferably, a web of elastomeric meltblown fibers.
- the laminated structure is flat, i.e., non-gathered by bonding the textile webs and nonwoven elastomeric web while the nonwoven elastomeric web is in a non-stretched state or so little stretched that, upon relaxation of the stretch, the textile material does not gather.
- the webs are flat after lamination, we mean that the knit web, woven web or scrim web, as part of the lamination, is not gathered when the nonwoven elastomeric web is unstretched, after the bonding has been performed.
- the gathering of a web attached to a nonwoven elastomeric web is described in U.S. Patent No. 4,720,415, the contents of which is incorporated herein by reference in their entirety.
- the present product differs substantially from that in U.S. Patent No. 4,720,415.
- the laminate material can be stretched as much as the knit, woven or scrim web can be stretched, with the nonwoven elastomeric web providing power recovery retraction force upon relaxation of the stretching of the laminate.
- the laminate according to the present invention includes at least three webs, that is, three webs or more than three webs can be included. If three webs are used, the nonwoven elastomeric web can be an inner web of a sandwich of three webs, with the two outer webs, for example, being knit or woven or scrim webs. In this instance, the elastomeric web would be buried.
- the nonwoven elastomeric web can be, for example, a spunbond web or a web of meltblown fibers. Desirably, the nonwoven elastomeric web is made of meltblown elastomeric fibers.
- meltblown elastomeric fibers such as a copolyetheresters; copolymers of ethylene and at least one vinyl monomer (e.g., ethylene vinyl acetate); A-B-A' block copolymers, wherein A and A' may be the same or different end blocks and each is a thermoplastic polymer end block or segment which contains a styrenic moiety such as polystyrene or polystyrene homologs, and B is an elastomeric polymer midblock or segment, segmented block copolymers, of two alternating segments, having the formula A-B; and a urethane polymer (e.g., polyurethane or a urethane copolymer), can be used in the present
- polyester polyamide block copolymer having the general formula:
- PA represents a polyamide polymer segment
- PE represents a polyether polymer segment.
- the polyether block amide copolymer has a melting point of from about 150°C to about 170°C, as measured in accordance with ASTM D-789; a melt index of from about 6 grams per 10 minutes to about 25 grams per 10 minutes, as measured in accordance with ASTM D-1238, condition Q (235 C/1Kg load); a modulus of elasticity in flexure of from about 20 Mpa to about 200 Mpa, as measured in accordance with ASTM D-790; a tensile strength at break of from about 29 Mpa to about 33 Mpa as measured in accordance with ASTM D- 638 and an ultimate elongation at break of from about 500 percent to about 700 percent as measured by ASTM D-638.
- a particular embodiment of the polyether block amide copolymer has a melting point of about 152°C as measured in accordance with ASTM D- 789; a melt index of about 7 grams per 10 minutes, as measured in accordance with ASTM D-1238, condition Q (235 C/1 Kg load); a modulus of elasticity in flexure of about 29.50 Mpa, as measured in accordance with ASTM D-790; a tensile strength at break of about 29 Mpa, a measured in accordance with ASTM D-639; and an elongation at break of about 650 percent as measured in accordance with ASTM D-638.
- Such materials are available in various grades under the trade designation PEBAX® from Atochem Inc.
- Polymers composed of an elastomeric A-B-A-B tetrablock copolymer may also be used in the practice of this invention. Such polymers are discussed in U.S. Patent 5,332,613 to Taylor et al. In such polymers, A is a thermoplastic polymer block and B is an isoprene monomer unit hydrogenated to substantially a poly(ethylene-propylene) monomer unit.
- An example of such a tetrablock copolymer is a styrene-poly(ethylene- propylene)-styrene-poly(ethylene-propylene) or SEPSEP elastomeric block copolymer available from the Shell Chemical Company of Houston, Texas under the trade designation KRATON® G-1657. KRATON® block copolymers are available in several different formulations, a number of which are identified in U.S. Patents 4,663,220 and 5,304,599, hereby incorporated by reference.
- exemplary elastomeric materials which may be used include polyurethane elastomeric materials such as, for example, those available under the trademark ESTANE® from B. F. Goodrich & Co. or MORTHANE® from Morton Thiokol Corp., and polyester elastomeric materials such as, for example, those known as ARNITEL®, formerly available from Akzo Plastics of Arnhem, Holland and now available from DSM of Sittard, Holland, or those known as HYTREL® which are available from E.I. duPont de Nemours of Wilmington, Delaware. These specific elastomeric materials are only illustrative, and not limiting.
- the nonwoven elastomeric web useful in the present invention, may be an unbonded or bonded material. Specifically, bonding of the nonwoven elastomeric material can enhance abrasion resistance. Such bonding can be achieved thermally, ultrasonically or by stitchbonding, for example, the nonwoven elastomeric web can be thermally point bonded.
- Stretch recovery of the nonwoven elastomeric web is important in connection with the present invention, since the degree of recovery of the nonwoven elastomeric web will control the degree of recovery in the laminate. It is desirable that the nonwoven elastomeric web have omni-directional stretch and recovery, so as to deliver power recovery to whatever cloth is used.
- a nonwoven elastomeric web having omni-directional stretch and recovery if the knit web of the laminate stretches in the machine direction (MD) then the laminate will have power recovery in the MD. If the knit web stretches in all directions, then the laminate will have power recovery in all directions.
- a unique aspect of woven materials is that they stretch mostly in the bias, e.g., 45° off the machine direction (MD) or cross direction (CD). Using a nonwoven elastomeric web having omni-directional stretch and recovery, recovery is also provided in the bias direction.
- MD machine direction
- CD cross direction
- the nonwoven elastomeric material is preferably a meltblown material.
- the fibers in the nonwoven elastomeric web illustratively range from 0.5 to 100 microns in diameter.
- Barrier properties in the finished laminate e.g., increased opacity and/or insulation and/or dirt protection and/or liquid repellency, are enhanced by the use of finer fibers, in the 0.5-20 micron range.
- the nonwoven elastomeric web may be a nonwoven elastomeric composite web.
- such composite web can be made of a mixture of two or more different fibers or a mixture of fibers and particulates.
- Such mixtures may be formed by adding fibers and/or particulates to the gas stream in which elastomeric meltblown fibers are carried so that an intimate entangled commingling of the elastomeric meltblown fibers and other materials occurs prior to collection of the meltblown fibers upon a collection device to form a coherent web of randomly dispersed meltblown fibers and other materials, such as disclosed in U.S. Patent Nos. 4,100,324 and 4,803,117, the contents of each of which are incorporated herein by reference in their entirety.
- nonwoven elastomeric composite webs include, for example, wood pulp fibers, staple length fibers from natural and synthetic sources, e.g., cotton, wool, asbestos, rayon, polyester, polyamide and the like, non-elastic meltblown fibers, and particulates such as, for example, activated carbon particulates or hydrocolloid (hydrogel) particulates commonly referred to as superabsorbents.
- wood pulp fibers staple length fibers from natural and synthetic sources, e.g., cotton, wool, asbestos, rayon, polyester, polyamide and the like
- non-elastic meltblown fibers e.g., activated carbon particulates or hydrocolloid (hydrogel) particulates commonly referred to as superabsorbents.
- Other types of nonwoven elastomeric composite webs may be used.
- a hydraulically entangled nonwoven elastomeric composite web may be used such as disclosed in U.S. Patent No. 4,879,170 to Radwanski, et al.,
- the basis weight of the nonwoven elastomeric web may illustratively range from 0.20 to 6.0 osy (6.8 to 204 gsm).
- the basis weight is selected to provide desired laminate properties, including recovery and barrier properties.
- the more preferred basis weight for the nonwoven elastomeric web is from 0.3-3.0 osy (10.2 to 102 gsm).
- the nonwoven elastomeric web must be bonded to a knit web, or a woven web or scrim web, e.g., a nonelastic textile web, according to the present invention.
- the basis weight of the nonwoven nonelastomeric web may illustratively range from 0.20 to 6.0 osy.
- These knit webs, woven webs and scrim webs are known in the art; conventional webs, e.g. textile webs, such as a nonelastic textile web, can be used for the present invention.
- One particularly well suited type of material is, for example, nylon tricot fabric.
- Another fabric useful in the practice of this invention and having greater heat resistance than nylqn is polyester knit fabric.
- polyester knit fabric incorporating about 4 percent of carbon fibers for static reduction functions well in the practice of this invention.
- Continuous fiber material are preferred because they tend to produce less lint than other materials.
- These knit webs, woven webs and scrim webs can be formed as done conventionally. Knitted fabrics generally have good stretch but relatively poor recovery. Since there is not much retraction force in the recovery, these knitted fabrics tend to lose their shape.
- a laminate according to the present invention utilizing a nonwoven elastomeric web as discussed above, imparts recovery to the knit.
- the laminate material has unique z- direction impact and puncture resistance.
- the durability of the knit fabric is enhanced because the yarns are locked onto the elastomeric surface, e.g. elastomeric meltblown surface, and are not subject to the same level of yarn-to-yarn abrasion and stresses that the free knit structure would experience.
- knits backed or laminated with the nonwoven elastomeric web e.g., an elastomeric meltblown web, become snag and run resistant because the yarns are immobilized on the elastomeric meltblown surface.
- the use of the nonwoven elastomeric web provides power recovery to prevent bagging and sagging and provides puncture resistance, particle filtration and liquid penetration resistance.
- a woven or scrim web can be used. While woven and scrim webs have more dimensional stability than knits, especially in the machine and cross directions, power recovery is added to these materials to the extent that they stretch. Of particular interest is the bias stretch of, e.g., woven webs.
- the laminate of the present invention, using a nonwoven elastomeric web together with the woven web, provides a stretch recovery in the bias.
- the woven or laid scrim yarns are stabilized in their original structure, reducing yarn against yam wearing, when the woven or scrim webs are laminated with the nonwoven elastomeric web according to the present invention. Stabilization of laid scrim webs is particularly useful, since the nonwoven scrims have poor dimensional stability to begin with.
- the z-directional puncture and impact resistance of the woven and scrim laminate is improved in the structure of the present invention, as compared with using a woven or scrim web by itself.
- the nonwoven elastomeric web can be laminated to the web of knit, woven or scrim material using an adhesive.
- the nonwoven elastomeric web be unstretched during lamination; or, alternatively, that any stretching of the nonwoven elastomeric web during bonding be sufficiently little such that when the nonwoven elastomeric web is relaxed to its unstretched state after bonding, there is no gathering or puckering of the, e.g., knit web.
- An adhesive may be pre-applied to the nonwoven elastomeric web and/or to the textile material; such adhesive may be heat activated to achieve lamination. Moreover, aqueous adhesives, or solvent-based additives, known in the art, may be used. An adhesive web can be interposed between textile material and the nonwoven elastomeric web, to provide the bonding.
- the adhesive should be a crosslinking one and preferably a self-crosslinking and durable adhesive. Examples of such adhesives are described in U.S.
- Patent Application 07/995,468 (the '468 application), incorporated herein by reference, to Faass and assigned to the same assignee as this application, and may be in the form of a randomly scattered network of hot-melt adhesive filaments and/or fibers.
- the adhesive material may be a coating of any suitable conventional commercially available hot-melt adhesive such as, for example, hot melt adhesives which may be based on blends of polyolefins, adhesive resins, triblocks and waxes.
- the adhesive may typically be used in an amount between about 3 and 20 gsm or more particularly about 5 gsm. 5
- a good coating for the practice of this invention is that of U.S. Patent 5,149,741, hereby incorporated by reference, to Alper et al.
- This coating is an adhesive which comprises about 15 to 40 parts of a styrene-isoprene-styrene block copolymer wherein the styrene content of the copolymer is 25 to 50 weight percent, about 40 to 70 parts of a compatible tackifying 10 resin such as, for example, pentaerythritol esters, about 5 to 30 parts of a napthenic/paraffinic oil and 0.1 to 2 parts, by weight, of a phosphite antioxidant, hindered phenolic antioxidant and a stabilizer, where the adhesive has a melt viscosity of not greater than 6000cP at 325°F.
- Bondstar® RS- 0178 is a thermoplastic urethane adhesive which can be dispensed from conventional hotmelt equipment at temperatures up to about 400°F (204°C).
- the bonding temperature can range from ambient temperature to 20500°F (482°C)., the optimum temperature range being dependent on the webs and adhesive used. Using liquid adhesives could allow ambient bonding temperatures. Elevated bonding temperatures are needed to fuse the webs together using a thermoplastic adhesive web, with actual temperatures being dependent on the adhesive used and the melting temperatures of the involved webs.
- 25 Fig. 1 shows an embodiment of forming a three-web laminate according to the present invention, using an adhesive to provide the bonding for the lamination.
- reference characters 14-16 represent three webs to be laminated. Both of webs 14 and 16 are a textile web, while web 15 is the nonwoven elastomeric web.
- Reference character 17 represents an adhesive applicator, known in the art, which 0 deposits an adhesive on both the top and bottom surfaces of the middle web 15. After the adhesive has been applied, web 15 is combined with webs 14 and 16 and passed between the bonding rolls 18 and 19, where bonding occurs.
- the adhesive used can be any suitable adhesive (liquid or thermoplastic), and can include aqueous or solvent based adhesives, as well as fusible coatings. The adhesive must be applied in a pattern, i.e. discontinuously.
- any number of webs can be laminated, to form a laminate material according to the present invention, and either the textile web or the nonwoven elastomeric web, or both, can be exposed in the laminate product.
- the laminates of this invention may also have topical treatments applied to them for more specialized functions.
- topical treatments and their methods of application are known in the art and include, for example, alcohol repellency treatments, anti-static treatments and the like, applied by spraying, dipping, etc.
- Fluorocarbon chemicals to enhance chemical repellency which may be, for example, any of those taught in U.S. patent 5,178,931 , incorporated by reference herein, may be added to the fabric.
- One example of such a topical treatment is the application of Zelec® antistat (available from E.I. duPont, Wilmington, Delaware).
- One preferred repellency treatment is produced by Synfin Industries of North Wales, PA as a proprietary treatment chemical.
- the laminate may also have conductive carbon fibers incorporated therein up to about 10 weight percent, as a static reducing measure to meet the requirements of static decay under Federal test 101C method 4046.
- Fabrics for infection control applications for example as a surgical gown, must have good liquid barrier properties in order to protect medical personnel from contact with the bodily fluids of the patient yet must be breathable in order for the wearer's perspiration to pass through the fabric so as to remain comfortable.
- the fabric must also be strong enough to perform the desired function in the appropriate environment yet be soft, stretchable and drapeable for the wearer's comfort and to avoid restricting the wearer's range of motion.
- nonwovens for example as garments
- the finished product it is also important in many applications of nonwovens, for example as garments, for the finished product to be as lightweight as possible yet still perform its desired function.
- a lighter garment performing the same function as a heavier garment would be more comfortable for the wearer and probably less expensive to manufacture since less raw material would be necessary for its production.
- a lighter weight, soft fabric having high liquid barrier properties, high vapor transmission and good strength would be of great utility in a diverse range of applications.
- Yet another useful property of the fabric of this invention is that it may be reused a number of times before being disposed of. Such reusability helps reduce disposal costs and environmental problems when the fabric is used as a surgical gown, for example, since materials contaminated with bodily fluids require specialized disposal procedures. By reducing the volume of material which must be disposed of relative to single use materials, surgical garments made from the fabric of this invention can contribute to a reduction in national health care expenditures.
- the apparel When the laminate material according to the present invention is used as a garment, the apparel has thermal insulation and a dirt barrier to protect the wearer, while having breathability for comfort. Moreover, wearing apparel made of the laminate material of the present invention has opacity not otherwise achievable in lightweight knits.
- Described below is a laminate according to the practice of this invention as well as two commercially available materials currently used for surgical gowns. Also set forth in Table 1 for each of these examples are various properties of the materials as measured according to the tests described above.
- Example 1 The ComPel® fabric used was part of a reusable or multi-use surgical gown and is made from tightly woven 100 percent polyester yarn. ComPel® fabric does not stretch and recover. The material tested had one layer and is available from the Standard Textile Company, Inc. of Cincinnati, Ohio, 45222. The ComPel® fabric tested had a coating of a repellent known as SYLGARD® from Dow-Corning. The manufacturer of ComPel® fabric claims it may be laundered and reused 100 times. The test results are on unlaundered material.
- Example 2 This material is a spunbond/meltblown/spunbond or SMS laminate available from the Kimberly-Clark Corporation of Neenah, WI as a disposable surgical gown material under the trade designation Evolution® III. Evolution® III gown SMS fabric does not stretch and recover.
- the spunbond layers each have a basis weight of 0.545 osy (18.5 gsm) and the meltblown layer has a basis weight of 0.5 osy (17 gsm).
- the spunbond layers were made from polypropylene manufactured by the Exxon Chemical Company of Houston, Tx under the trade designation PD 9355. These layers included minor amounts of pigments.
- the meltblown layer was also made from polypropylene from Exxon. This material was designated PD 3495G. This layer also included a minor amount of pigment.
- the fabric was thermally point bonded. The fabric was topically treated with a repellent chemical mixture including Dupont's 7700 repellent, Zelec® antistat, and hexanol.
- Example 3 This material is a laminate made according to the invention. It was comprised of a 1.5 osy (51 gsm) elastic meltblown web adhesively laminated to a continuous filament S850 nylon tricot knit with 18 loops per inch on both sides.
- the meltblown web is available under the trade designation Demique® fabric from the Kimberly-Clark Corporation and was comprised of elastomeric fibers made from DSM's Arnitel® EM400 polymer.
- the adhesive used was Bondstar® RS-10178 urethane adhesive applied at an amount of about 5 gsm to each side of the elastic web using dot gravure printing.
- the laminate was treated with a repellent treatment from Synfin Industries of North Wales, PA. This material has been laundered 50 times without delamination and hence is a multi-use or reusable material. The test results are on unlaundered materials.
- the laminate material of the present invention provides improved properties as compared with commercially available materials.
- the laminate of this invention has a low blood strikethrough rate coupled with good hydrohead and very high breathability (Frazier Porosity). Particle filtration is also very good and lint generation an order of magnitude better than competitive fabrics at the smaller particle size, due at least in part, the inventors believe, to the fact that the fibers of the textile webs of this invention are preferably continuous fibers. This combination of properties makes this laminate an excellent candidate for protective yet breathable service requirements.
- the present laminate textile materials have power recovery in all directions, although the degree of stretch is limited by the inherent stretch of the starting textile (knit or woven or scrim).
- the nonwoven elastomeric web component particularly when such component is a web of meltblown elastomeric fibers, tightens the textile structure providing barrier properties and closing holes between the yarns of the, e.g., woven or knit web. These barrier properties include puncture resistance, insulation, filtration, opacity and liquid repellency.
- the elastomeric component may be buried in the textile structure (e.g., sandwiched between two webs of textile material such as knit material), whereby any undesirable feel of the elastomeric component may be avoided by a simple processing technique.
- the textile structure e.g., sandwiched between two webs of textile material such as knit material
- any undesirable feel of the elastomeric component may be avoided by a simple processing technique.
- an expensive core wrapping procedure is performed to overcome the poor coverage and tactile aesthetics of such yarn; such core wrapping procedure is unnecessary in the present invention.
- the present invention can provide a textile material having stretch and recovery characteristics, as well as other properties as discussed above, in a relatively simple and inexpensive procedure.
- Such procedure according to the invention is clearly preferable to the present technique for forming textile fabrics, incorporated spandex or rubber yarns into the knitted or woven structure; such spandex or rubber yarns are very difficult to process on knitting and weaving equipment due to their stretchiness and relatively high coefficient of friction, and relatively high costs of equipment set-up.
- the laminate material of the present invention including the nonwoven elastomeric web and the textile webs, achieves the advantages of a textile web, while also achieving improved properties due to the nonwoven elastomeric web.
- the laminate according to the present invention has improved breathability, as compared to textile laminates including an elastic film.
- the laminates according to the present invention can be produced in lower basis weights than wovens or knits that contain elastic yams, due to the denier of elastic yarns. Furthermore, the laminates according to the present invention can be produced at a lower cost than wovens or knits that contain elastic yarns, due to the processing difficulties of elastic yarns.
- the laminate processing according to the present invention provides techniques for adding elasticity to available textiles, efficiently and at a relatively low cost.
Abstract
Description
Claims
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AU59500/96A AU5950096A (en) | 1995-06-01 | 1996-05-29 | Flat elastomeric nonwoven laminates |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US08/456,842 US5681645A (en) | 1990-03-30 | 1995-06-01 | Flat elastomeric nonwoven laminates |
US08/456,842 | 1995-06-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO1996038620A1 true WO1996038620A1 (en) | 1996-12-05 |
Family
ID=23814353
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/US1996/007938 WO1996038620A1 (en) | 1995-06-01 | 1996-05-29 | Flat elastomeric nonwoven laminates |
Country Status (4)
Country | Link |
---|---|
US (1) | US5681645A (en) |
AU (1) | AU5950096A (en) |
CA (1) | CA2220179A1 (en) |
WO (1) | WO1996038620A1 (en) |
Cited By (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998038363A1 (en) * | 1997-02-28 | 1998-09-03 | Smith & Nephew Plc | Bandages |
WO1998037779A1 (en) * | 1997-02-27 | 1998-09-03 | Kimberly-Clark Worldwide, Inc. | Face masks including a spunbonded/meltblown/spunbonded laminate |
WO1999057355A1 (en) * | 1998-05-01 | 1999-11-11 | The Dow Chemical Company | Method of making a breathable, barrier meltblown nonwoven |
WO2000044556A1 (en) * | 1999-01-29 | 2000-08-03 | Ato Findley, Inc. | High strenght through-bonding technique for elastomeric laminates |
EP1066957A1 (en) * | 1999-07-05 | 2001-01-10 | Uni-Charm Corporation | Process for making elastically stretchable composite sheet |
EP1066961A1 (en) * | 1999-07-05 | 2001-01-10 | Uni-Charm Corporation | Process for making elastically stretchable composite sheet |
EP1069223A1 (en) * | 1999-07-12 | 2001-01-17 | Uni-Charm Corporation | Elastically stretchable composite sheet |
EP1138472A1 (en) * | 2000-03-30 | 2001-10-04 | Uni-Charm Corporation | Elastically stretchable composite sheet and process for making the same |
SG85236A1 (en) * | 2000-03-31 | 2001-12-19 | Uni Charm Corp | Composite sheet and process for making the same |
SG85235A1 (en) * | 2000-03-31 | 2001-12-19 | Uni Charm Corp | Process for making elastically stretchable composite sheet |
EP1184162A2 (en) * | 2000-09-01 | 2002-03-06 | Uni-Charm Corporation | Hydrophilic elastically stretchable composite sheet |
EP1184163A2 (en) * | 2000-09-01 | 2002-03-06 | Uni-Charm Corporation | Elastically stretchable composite sheet and process for making the same |
WO2002058492A2 (en) * | 2000-11-17 | 2002-08-01 | Kimberly-Clark Worldwide, Inc. | Extensible and retractable face mask |
US6436216B1 (en) | 1999-01-29 | 2002-08-20 | Ato Findley, Inc. | Pre-packaging relaxation for laminated elastic webs |
US7311102B2 (en) | 2001-11-02 | 2007-12-25 | The Secretary Of State For Defence | Protective apparel |
DE102012016107A1 (en) * | 2012-08-15 | 2014-02-20 | Otto Bock Healthcare Gmbh | Composite material and method for its production |
US9616258B2 (en) | 2010-03-03 | 2017-04-11 | 3M Innovative Properties Company | Dispensable face mask and method of making the same |
Families Citing this family (50)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6383431B1 (en) * | 1997-04-04 | 2002-05-07 | The Procter & Gamble Company | Method of modifying a nonwoven fibrous web for use as component of a disposable absorbent article |
ES2187194T3 (en) | 1998-09-08 | 2003-05-16 | Brookwood Companies Inc | WATERPROOF LAMINATE WATERPROOF AND MANUFACTURING PROCEDURE OF LAMINATED SAID. |
DE69905059T2 (en) * | 1998-10-02 | 2003-11-20 | 3M Innovative Properties Co | ELASTIC COMPOSITES |
TW469226B (en) * | 1998-10-02 | 2001-12-21 | Du Pont | Uniform stretchable fabric with flat surface appearance |
US6706649B2 (en) * | 1999-02-01 | 2004-03-16 | Nordenia Technologies Gmbh | Web with two outer layers and an adhesive middle layer as well as process to produce said web |
US6387471B1 (en) * | 1999-03-31 | 2002-05-14 | Kimberly-Clark Worldwide, Inc. | Creep resistant composite elastic material with improved aesthetics, dimensional stability and inherent latency and method of producing same |
US6547915B2 (en) * | 1999-04-15 | 2003-04-15 | Kimberly-Clark Worldwide, Inc. | Creep resistant composite elastic material with improved aesthetics, dimensional stability and inherent latency and method of producing same |
US6357440B1 (en) * | 1999-06-16 | 2002-03-19 | Mallinckrodt Inc. | Pliable respiratory mask |
US6465073B1 (en) | 1999-06-30 | 2002-10-15 | Kimberly-Clark Worldwide, Inc. | Variable stretch material and process to make it |
US6682514B1 (en) | 1999-06-30 | 2004-01-27 | Kimberly-Clark Worldwide Inc. | Efficient zoned elastic laminate |
JP3723711B2 (en) * | 2000-01-20 | 2005-12-07 | ユニ・チャーム株式会社 | Stretchable composite sheet and method for producing the same |
AU2001257281A1 (en) * | 2000-04-25 | 2001-11-07 | E.I. Du Pont De Nemours And Company | Stretchable flashing materials and processes for making |
US8182457B2 (en) * | 2000-05-15 | 2012-05-22 | Kimberly-Clark Worldwide, Inc. | Garment having an apparent elastic band |
US6717028B1 (en) * | 2000-08-30 | 2004-04-06 | Kimberly-Clark Worldwide, Inc. | Bond pattern |
US7157614B1 (en) * | 2000-12-21 | 2007-01-02 | Fountainhead, Llc | Treatment devices providing targeted antimicrobial action |
US6491776B2 (en) * | 2001-04-23 | 2002-12-10 | Bostik Findley, Inc. | Dual adhesive application for laminating elastic webs |
US6602006B2 (en) * | 2001-06-29 | 2003-08-05 | Hewlett-Packard Development Company, L.P. | Techniques for printing onto a transparent receptor media using an inkjet printer |
JP3790496B2 (en) * | 2002-05-20 | 2006-06-28 | 株式会社クラレ | Composite nonwoven fabric for protective clothing and method for producing the same |
US6928657B2 (en) | 2002-10-25 | 2005-08-16 | Kimberly-Clark Worldwide, Inc. | Face mask having hook and loop type fastener |
US20040102123A1 (en) * | 2002-11-21 | 2004-05-27 | Bowen Uyles Woodrow | High strength uniformity nonwoven laminate and process therefor |
US7032751B2 (en) * | 2002-12-19 | 2006-04-25 | Kimberly-Clark Worldwide, Inc. | Dispensing assembly for single piece face mask |
US6934969B2 (en) * | 2002-12-27 | 2005-08-30 | Kimberly-Clark Worldwide, Inc. | Anti-wicking protective workwear and methods of making and using same |
US6957884B2 (en) | 2002-12-27 | 2005-10-25 | Kinberly-Clark Worldwide, Inc. | High-speed inkjet printing for vibrant and crockfast graphics on web materials or end-products |
US7155746B2 (en) | 2002-12-27 | 2007-01-02 | Kimberly-Clark Worldwide, Inc. | Anti-wicking protective workwear and methods of making and using same |
US7943813B2 (en) | 2002-12-30 | 2011-05-17 | Kimberly-Clark Worldwide, Inc. | Absorbent products with enhanced rewet, intake, and stain masking performance |
CN100340393C (en) * | 2003-03-21 | 2007-10-03 | 纳幕尔杜邦公司 | Multi-layer adhesive-bonded nonwoven sheet and process therefor |
US7998188B2 (en) | 2003-04-28 | 2011-08-16 | Kips Bay Medical, Inc. | Compliant blood vessel graft |
US20050131520A1 (en) | 2003-04-28 | 2005-06-16 | Zilla Peter P. | Compliant blood vessel graft |
US20040235380A1 (en) * | 2003-05-21 | 2004-11-25 | Rene Kapik | Cross-directionally stretched barrier fabrics and methods of making same |
DE60311240T2 (en) * | 2003-07-03 | 2007-07-05 | Fresenius Hemocare Italia S.R.L., Cavezzo | Filter for removing substances from blood products |
US8273066B2 (en) | 2003-07-18 | 2012-09-25 | Kimberly-Clark Worldwide, Inc. | Absorbent article with high quality ink jet image produced at line speed |
US8091550B2 (en) | 2003-12-22 | 2012-01-10 | Kimberly-Clark Worldwide, Inc. | Face mask having baffle layer for improved fluid resistance |
WO2006007154A2 (en) * | 2004-06-22 | 2006-01-19 | Dow Global Technologies Inc. | Elastomeric monoalkenyl arene-conjugated diene block copolymers |
WO2006031625A2 (en) * | 2004-09-10 | 2006-03-23 | Invista Technologies S.A.R.L. | Extensible fibers, method for their production and use |
EP1650021A1 (en) * | 2004-10-25 | 2006-04-26 | Lankhorst Indutech B.V. | Method for preparing a composite product of a polyolefenic article and a cloth |
WO2006060292A2 (en) * | 2004-11-30 | 2006-06-08 | Pgi Polymer, Inc. | Disposable nonwoven undergarments with support panels |
FR2879079B1 (en) * | 2004-12-09 | 2007-05-11 | Lainiere De Picardie Bc Soc Pa | TEXTILE COMPLEX COMPRISING AN ASSOCIATED SUBSTRATE COATED ON BOTH SIDES |
US8622059B2 (en) | 2004-12-21 | 2014-01-07 | Kimberly-Clark Worldwide, Inc. | Face mask with absorbent element |
US7725948B2 (en) * | 2004-12-22 | 2010-06-01 | Kimberly-Clark Woldwide, Inc. | Face mask with offset folding for improved fluid resistance |
US20060130841A1 (en) * | 2004-12-22 | 2006-06-22 | Kimberly-Clark Worldwide, Inc | Face mask with horizontal and vertical folds |
US7290545B2 (en) * | 2004-12-23 | 2007-11-06 | Kimberly-Clark Worldwide, Inc. | Face mask with anti-fog folding |
US20060137810A1 (en) * | 2004-12-28 | 2006-06-29 | Beck Scott A | Method of making an elastic laminate using direct contact thermal rolls for controlling web contraction |
DE602006020704D1 (en) * | 2005-03-16 | 2011-04-28 | Stuart Press | HYDROPHOBIC INSULATING MATERIAL |
US7845351B2 (en) * | 2005-08-31 | 2010-12-07 | Kimberly-Clark Worldwide Inc. | Germicidal face mask |
JP5179384B2 (en) | 2006-02-21 | 2013-04-10 | ファイバーウェブ・シンプソンヴィル,インコーポレイテッド | Extensible absorbent composite |
FR2903626B1 (en) * | 2006-07-12 | 2008-10-10 | Eads Space Transp Sas Soc Par | ASSEMBLY OF PREIMPREGNES FOR THE PRODUCTION OF STRUCTURES, FOR EXAMPLE A DEPLOYMENT BY INFLATION |
US7968479B2 (en) * | 2008-06-30 | 2011-06-28 | Kimberly-Clark Worldwide, Inc. | Elastic multilayer composite including pattern unbonded elastic materials, articles containing same, and methods of making same |
US8535776B2 (en) * | 2010-11-16 | 2013-09-17 | Velcro Industries B.V. | Breathable and elastic fabric lamination |
TWI597172B (en) * | 2013-10-04 | 2017-09-01 | 隆芳興業股份有限公司 | Reusable modeling breathable fabric assembly |
US11077325B2 (en) * | 2016-04-01 | 2021-08-03 | Dupont Safety & Construction, Inc. | Flame and particulate resistant knit article |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1993015247A1 (en) * | 1992-01-24 | 1993-08-05 | Fiberweb North America, Inc. | Process stable nonwoven fabric |
WO1993025746A1 (en) * | 1992-06-10 | 1993-12-23 | Fiberweb North America, Inc. | Composite nonwoven fabric and method of making same |
EP0581524A1 (en) * | 1992-07-29 | 1994-02-02 | William D. Walters | Gas impermeable, elastically deformable laminate and inflatable articles formed therefrom |
WO1995003443A1 (en) * | 1992-01-24 | 1995-02-02 | Fiberweb North America, Inc. | Composite elastic nonwoven fabric |
Family Cites Families (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4663220A (en) * | 1985-07-30 | 1987-05-05 | Kimberly-Clark Corporation | Polyolefin-containing extrudable compositions and methods for their formation into elastomeric products including microfibers |
US4720415A (en) * | 1985-07-30 | 1988-01-19 | Kimberly-Clark Corporation | Composite elastomeric material and process for making the same |
US4699621A (en) * | 1985-09-06 | 1987-10-13 | Kimberly-Clark Corporation | Form-fitting self-adjusting disposable garment with anchored waist and leg elastics |
US4701170A (en) * | 1985-09-06 | 1987-10-20 | Kimberly-Clark Corporation | Form-fitting self-adjusting disposable garment with fixed position fasteners |
US4756709A (en) * | 1985-09-06 | 1988-07-12 | Kimberly-Clark Corporation | Form-fitting self-adjusting disposable garment with a 3-section stretchable outer cover |
US4803117A (en) * | 1986-03-24 | 1989-02-07 | Kimberly-Clark Corporation | Coformed ethylene-vinyl copolymer elastomeric fibrous webs |
US4724184A (en) * | 1986-10-15 | 1988-02-09 | Kimberly-Clark Corporation | Elastomeric polyether block amide nonwoven web |
US4741949A (en) * | 1986-10-15 | 1988-05-03 | Kimberly-Clark Corporation | Elastic polyetherester nonwoven web |
US4707398A (en) * | 1986-10-15 | 1987-11-17 | Kimberly-Clark Corporation | Elastic polyetherester nonwoven web |
US4801482A (en) * | 1986-10-15 | 1989-01-31 | Kimberly-Clark Corporation | Elastic nonwoven pad |
US4929492A (en) * | 1987-07-24 | 1990-05-29 | Minnesota Mining And Manufacturing Company | Stretchable insulating fabric |
US4879170A (en) * | 1988-03-18 | 1989-11-07 | Kimberly-Clark Corporation | Nonwoven fibrous hydraulically entangled elastic coform material and method of formation thereof |
US5418044A (en) * | 1988-05-07 | 1995-05-23 | Akzo N.V. | Irreversibly stretchable laminate comprising layers of woven or knitted fabrics and water-vapor permeable films |
US4908263A (en) * | 1988-05-13 | 1990-03-13 | Minnesota Mining And Manufacturing Company | Nonwoven thermal insulating stretch fabric |
US5226992A (en) * | 1988-09-23 | 1993-07-13 | Kimberly-Clark Corporation | Process for forming a composite elastic necked-bonded material |
US5268212A (en) * | 1989-10-17 | 1993-12-07 | Malden Mills Industries, Inc. | Windproof and water resistant composite fabric with barrier layer |
US5093422A (en) * | 1990-04-23 | 1992-03-03 | Shell Oil Company | Low stress relaxation extrudable elastomeric composition |
CA2027850C (en) * | 1990-10-17 | 2000-06-27 | Pierre P. Meunier | Stretchable protective fabric and protective apparel made therefrom |
US5354604A (en) * | 1991-07-17 | 1994-10-11 | Medical Materials Corporation | Thermoplastic thermoformable composite material and method of forming such material |
US5385775A (en) * | 1991-12-09 | 1995-01-31 | Kimberly-Clark Corporation | Composite elastic material including an anisotropic elastic fibrous web and process to make the same |
US5393599A (en) * | 1992-01-24 | 1995-02-28 | Fiberweb North America, Inc. | Composite nonwoven fabrics |
US5405682A (en) * | 1992-08-26 | 1995-04-11 | Kimberly Clark Corporation | Nonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and elastomeric thermoplastic material |
US5332613A (en) * | 1993-06-09 | 1994-07-26 | Kimberly-Clark Corporation | High performance elastomeric nonwoven fibrous webs |
-
1995
- 1995-06-01 US US08/456,842 patent/US5681645A/en not_active Expired - Fee Related
-
1996
- 1996-05-29 AU AU59500/96A patent/AU5950096A/en not_active Abandoned
- 1996-05-29 CA CA002220179A patent/CA2220179A1/en not_active Abandoned
- 1996-05-29 WO PCT/US1996/007938 patent/WO1996038620A1/en active Application Filing
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1993015247A1 (en) * | 1992-01-24 | 1993-08-05 | Fiberweb North America, Inc. | Process stable nonwoven fabric |
WO1995003443A1 (en) * | 1992-01-24 | 1995-02-02 | Fiberweb North America, Inc. | Composite elastic nonwoven fabric |
WO1993025746A1 (en) * | 1992-06-10 | 1993-12-23 | Fiberweb North America, Inc. | Composite nonwoven fabric and method of making same |
EP0581524A1 (en) * | 1992-07-29 | 1994-02-02 | William D. Walters | Gas impermeable, elastically deformable laminate and inflatable articles formed therefrom |
Cited By (36)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1998037779A1 (en) * | 1997-02-27 | 1998-09-03 | Kimberly-Clark Worldwide, Inc. | Face masks including a spunbonded/meltblown/spunbonded laminate |
US5883026A (en) * | 1997-02-27 | 1999-03-16 | Kimberly-Clark Worldwide, Inc. | Face masks including a spunbonded/meltblown/spunbonded laminate |
KR100550512B1 (en) * | 1997-02-27 | 2006-02-13 | 킴벌리-클라크 월드와이드, 인크. | Face Masks Including a Spunbonded/Meltblown/Spunbonded Laminate |
WO1998038363A1 (en) * | 1997-02-28 | 1998-09-03 | Smith & Nephew Plc | Bandages |
AU729101B2 (en) * | 1997-02-28 | 2001-01-25 | Smith & Nephew Plc | Bandages |
US6176952B1 (en) | 1998-05-01 | 2001-01-23 | The Dow Chemical Company | Method of making a breathable, meltblown nonwoven |
WO1999057355A1 (en) * | 1998-05-01 | 1999-11-11 | The Dow Chemical Company | Method of making a breathable, barrier meltblown nonwoven |
WO2000044556A1 (en) * | 1999-01-29 | 2000-08-03 | Ato Findley, Inc. | High strenght through-bonding technique for elastomeric laminates |
US6436216B1 (en) | 1999-01-29 | 2002-08-20 | Ato Findley, Inc. | Pre-packaging relaxation for laminated elastic webs |
US6475932B1 (en) | 1999-01-29 | 2002-11-05 | Ato Findley, Inc. | High strength through-bonding technique for elastomeric laminates |
EP1066961A1 (en) * | 1999-07-05 | 2001-01-10 | Uni-Charm Corporation | Process for making elastically stretchable composite sheet |
EP1066957A1 (en) * | 1999-07-05 | 2001-01-10 | Uni-Charm Corporation | Process for making elastically stretchable composite sheet |
US6531014B1 (en) | 1999-07-05 | 2003-03-11 | Uni-Charm Corporation | Process for making elastically stretchable composite sheet |
US6372067B1 (en) | 1999-07-05 | 2002-04-16 | Uni-Charm Corporation | Process for making elastically stretchable composite sheet |
EP1069223A1 (en) * | 1999-07-12 | 2001-01-17 | Uni-Charm Corporation | Elastically stretchable composite sheet |
KR100707152B1 (en) * | 1999-07-12 | 2007-04-16 | 유니챰 가부시키가이샤 | Elastically stretchable composite sheet |
US6730390B1 (en) | 1999-07-12 | 2004-05-04 | Uni-Charm Corporation | Elastically stretchable composite sheet |
US6720063B2 (en) | 2000-01-09 | 2004-04-13 | Uni-Charm Corporation | Elastically stretchable composite sheet and process for making the same |
US6649546B2 (en) | 2000-03-30 | 2003-11-18 | Uni-Charm Corporation | Elastically stretchable composite sheet and process for making the same |
EP1138472A1 (en) * | 2000-03-30 | 2001-10-04 | Uni-Charm Corporation | Elastically stretchable composite sheet and process for making the same |
US6821372B2 (en) | 2000-03-30 | 2004-11-23 | Uni-Charm Corporation | Elastically stretchable composite sheet and process for making the same |
SG85236A1 (en) * | 2000-03-31 | 2001-12-19 | Uni Charm Corp | Composite sheet and process for making the same |
SG85235A1 (en) * | 2000-03-31 | 2001-12-19 | Uni Charm Corp | Process for making elastically stretchable composite sheet |
US6686028B2 (en) | 2000-09-01 | 2004-02-03 | Uni-Charm Corporation | Hydrophilic elastically stretchable composite sheet |
EP1184163A2 (en) * | 2000-09-01 | 2002-03-06 | Uni-Charm Corporation | Elastically stretchable composite sheet and process for making the same |
SG89418A1 (en) * | 2000-09-01 | 2002-06-18 | Uni Charm Corp | Hydrophilic elastically stretchable composite sheet |
EP1184162A2 (en) * | 2000-09-01 | 2002-03-06 | Uni-Charm Corporation | Hydrophilic elastically stretchable composite sheet |
EP1184162A3 (en) * | 2000-09-01 | 2002-05-08 | Uni-Charm Corporation | Hydrophilic elastically stretchable composite sheet |
EP1184163A3 (en) * | 2000-09-01 | 2002-06-05 | Uni-Charm Corporation | Elastically stretchable composite sheet and process for making the same |
KR100732125B1 (en) * | 2000-09-01 | 2007-06-27 | 유니챰 가부시키가이샤 | Elastically stretchable composite sheet and producing method thereof |
US6644314B1 (en) | 2000-11-17 | 2003-11-11 | Kimberly-Clark Worldwide, Inc. | Extensible and retractable face mask |
WO2002058492A3 (en) * | 2000-11-17 | 2003-02-13 | Kimberly Clark Co | Extensible and retractable face mask |
WO2002058492A2 (en) * | 2000-11-17 | 2002-08-01 | Kimberly-Clark Worldwide, Inc. | Extensible and retractable face mask |
US7311102B2 (en) | 2001-11-02 | 2007-12-25 | The Secretary Of State For Defence | Protective apparel |
US9616258B2 (en) | 2010-03-03 | 2017-04-11 | 3M Innovative Properties Company | Dispensable face mask and method of making the same |
DE102012016107A1 (en) * | 2012-08-15 | 2014-02-20 | Otto Bock Healthcare Gmbh | Composite material and method for its production |
Also Published As
Publication number | Publication date |
---|---|
MX9709297A (en) | 1998-08-30 |
US5681645A (en) | 1997-10-28 |
CA2220179A1 (en) | 1996-12-05 |
AU5950096A (en) | 1996-12-18 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US5681645A (en) | Flat elastomeric nonwoven laminates | |
CA2130882C (en) | Nonwoven fabric laminate with enhanced barrier properties | |
AU683020B2 (en) | Stretchable meltblown fabric with barrier properties | |
CA2122702C (en) | Protective barrier apparel fabric | |
EP1017346B1 (en) | Personal care articles with abrasion resistant meltblown layer | |
US5688157A (en) | Nonwoven fabric laminate with enhanced barrier properties | |
US6028240A (en) | Disposable diaper that stretchably conforms to a wearer | |
EP0812371B1 (en) | Nonwoven fabric from polymers containing particular types of copolymers and having an aesthetically pleasing hand | |
EP0782504B1 (en) | Microporous film/nonwoven composites | |
CA2147523C (en) | Slit elastic fibrous nonwoven laminates | |
CA2157757C (en) | Composite elastic nonwoven fabric | |
US6387471B1 (en) | Creep resistant composite elastic material with improved aesthetics, dimensional stability and inherent latency and method of producing same | |
KR20070058482A (en) | Breathable elastic composite | |
CA2217123A1 (en) | Nonwoven-film laminates | |
EP0452727B2 (en) | Laminate material having stretch and recovery process for forming and use of same | |
US9139939B2 (en) | Treated laminates | |
CA2069840C (en) | Disposable protective garment adapted to stretchably conform to a wearer | |
MXPA97009297A (en) | Non-woven laminates elastomeric pla | |
Gosavi et al. | Nonwoven laminates containing cotton for medical applications | |
CA2130529A1 (en) | Elastic scrimmed insulating batting | |
MXPA97006442A (en) | Non-woven fabric of polymers containing typesparticulars of copolymers and having an actually placent touching |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: PA/a/1997/009297 Country of ref document: MX |
|
AK | Designated states |
Kind code of ref document: A1 Designated state(s): AL AM AT AU AZ BB BG BR BY CA CH CN CZ DE DK EE ES FI GB GE HU IS JP KE KG KP KR KZ LK LR LS LT LU LV MD MG MK MN MW MX NO NZ PL PT RO RU SD SE SG SI SK TJ TM TR TT UA UG UZ VN AM AZ BY KG KZ MD RU TJ TM |
|
AL | Designated countries for regional patents |
Kind code of ref document: A1 Designated state(s): KE LS MW SD SZ UG AT BE CH DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN ML |
|
DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
ENP | Entry into the national phase |
Ref document number: 2220179 Country of ref document: CA Ref country code: CA Ref document number: 2220179 Kind code of ref document: A Format of ref document f/p: F |
|
REG | Reference to national code |
Ref country code: DE Ref legal event code: 8642 |
|
122 | Ep: pct application non-entry in european phase |