WO1996011249A1 - Cleaning composition - Google Patents

Cleaning composition Download PDF

Info

Publication number
WO1996011249A1
WO1996011249A1 PCT/US1995/012930 US9512930W WO9611249A1 WO 1996011249 A1 WO1996011249 A1 WO 1996011249A1 US 9512930 W US9512930 W US 9512930W WO 9611249 A1 WO9611249 A1 WO 9611249A1
Authority
WO
WIPO (PCT)
Prior art keywords
foam
composition according
composition
stain
repellent
Prior art date
Application number
PCT/US1995/012930
Other languages
French (fr)
Inventor
Colin W. Brown
Gerald L. Hart
David F. Holmes
Original Assignee
S.C. Johnson & Son, Inc.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by S.C. Johnson & Son, Inc. filed Critical S.C. Johnson & Son, Inc.
Priority to US08/809,428 priority Critical patent/US5955414A/en
Priority to AU38285/95A priority patent/AU3828595A/en
Priority to CA002201923A priority patent/CA2201923C/en
Publication of WO1996011249A1 publication Critical patent/WO1996011249A1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0094High foaming compositions
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/004Surface-active compounds containing F
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/75Amino oxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66Non-ionic compounds
    • C11D1/83Mixtures of non-ionic with anionic compounds
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0043For use with aerosol devices
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005Other compounding ingredients characterised by their effect
    • C11D3/0031Carpet, upholstery, fur or leather cleansers
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3746Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3757(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions
    • C11D3/3765(Co)polymerised carboxylic acids, -anhydrides, -esters in solid and liquid compositions in liquid compositions

Definitions

  • the present invention relates to aqueous aerosol foam cleaning compositions, particularly for use on carpets and upholstery.
  • the invention is summarized as an aerosol foam-cleaning aqueous composition containing hydrocarbon propellant, foam-stabilizing polymer, surfactant, foam booster and a fluorinated stain-repellent, in which composition the proportions of the said components provide a foam of anti-flammability stability and sufficient residual amount of stain-repellent.
  • Figs. 1-4 are graphs of flammability and oil repellency data from the tests described, below, in the Modes of Carrying out the Invention.
  • Aerosol foam compositions for shampooing floor-coverings such as carpets or soft furnishings such as upholstery commonly comprise blends of surfactants and foam- stabilizer polymers, together with various other ingredients such as solvents, corrosion inhibitors and fragrances.
  • the polymer stabilizes the foam produced and assists in the cleaning.
  • a volatile hydrocarbon liquid propellant commonly is used to create a foam, the most commonly used propellant being butane.
  • a typical foam cleaning aerosol composition might comprise an aqueous dispersion of acrylic/styrene copolymer; sodium lauryl sulfate; ammonia; preservative and perfume, all in water; and a propane/butane blend as propellant.
  • Such a composition would possess the following advantages: (a) excellent pick-up;
  • the foam resulting from these aerosols has a stability dependent on the combination of the properties of the components, such as the amount of surfactant and the nature of the polymer and the other foaming agents. This stability will also affect the rate of release of butane or other hydrocarbon from the foam structure. Since the hydrocarbons, particularly butane, are very inflammable, this rate of release can influence the flammability properties of the foam structure and particularly the risk of ignition if the foam is applied close to an ignition source. However, the permissible amounts and the relative ratios of the components can usually vary widely and still provide otherwise operable compositions.
  • stain repellents materials treating the substrate material by forming a coating.
  • stain-repellents include fluoro stain repellents, particularly oil repellent components that provide a stain-repellent finish to the material being treated with a foam cleaner, the finish remaining after cleaning is completed.
  • Particular stain repellents are fluorocompounds such as fluoropolymers.
  • Applicant's attempts to combine these fluorocompounds with aerosol foam cleaning compositions have resulted in foams that are unstable and that release hydrocarbon at an excessive rate, giving rise to flammability problems.
  • non- volatile fluorocompound stain repellent compounds can be combined with the other components of a foam cleaning composition to provide a product that retains appropriate foam stability to provide a composition sufficiently non-flammable for use with improved safety even where there are potential ignition sources, such as open fires, cigarettes, and the like.
  • These non-volatile fluorocompounds are added not as part of the propellant but as a part of the non- propellant portion of the cleaning composition. Fluorocompounds have been added to cleaning foams in the past, but those fluorocompounds were volatile compounds added as part of the propellant.
  • an aerosol foam-cleaning aqueous composition containing hydrocarbon propellant, foam-stabilizer polymer, surfactant, foam booster and a fluorinated stain repellent in which the proportions of the said components provide a foam of anti-flammability stability and that leaves behind on the surface being cleaned an effective amount of stain repellent left as residual on the surface.
  • Anti-flammability stability is defined here to mean that the rate of collapse of the foam does not release the hydrocarbon propellant at a rate that creates a flammability problem having regard to the standards established in the industry and described in detail in this patent.
  • An "effective amount" of an ingredient is defined to be an amount sufficient to achieve the specified result or effect.
  • An amount of stain repellent left as residual on a surface is deemed effective if it reduces the tendency of the surface to receive and retain visually apparent stains.
  • the invention comprises an aerosol foam cleaning or shampoo formulation particularly for carpets or other soft furnishings, preferably comprising specified amounts of the particular components set out above.
  • the particular composition relies on the presence of a volatile hydrocarbon liquid propellant, preferably butane, to create a foam on actuation. It is essential that the foam generated be sufficiently stable, and foam stability depends upon, inter alia, the amount and nature of surfactant utilized, the amount and nature of polymer utilized, the presence or absence of other foaming aids, and the amount of fluorocompounds present.
  • the fluoro stain repellent compounds are added to such compositions to provide a post-cleaning, stain repellent finish and particularly an oil-repellent finish on the carpet, and can be fluoropolymer compounds or fluorosurfactant compounds.
  • fluorocompounds in the foam has a marked influence on the surface tension thereof and therefore can greatly decrease the stability of the foam, which in turn leads to a marked increase in ignition potential. This is because, if the foam decreases in stability, then the level and rate of release therefrom of the volatile hydrocarbon propellant will increase. Since volatile hydrocarbon propellants are flammable, then their release above certain levels cannot be permitted in compositions of the type described herein without the production of unacceptable flammability.
  • the amount of flammable volatile hydrocarbon propellant is carefully selected to be high enough that sufficient foam is generated but not so high that a flammable mixture is created.
  • the composition must include sufficient fluorocompounds that an adequate level of post-cleaning stain repellency exists on the carpet after cleaning, while the composition remains sufficiently non-flammable.
  • the precise amount of each component may have to be adjusted in a particular composition to achieve maximum cleaning activity and stability of foam.
  • a number of materials can be utilized as the foam-stabilizer polymeric component of the foam cleaning compositions of the present invention, including the styrene maleic anhydride and related resins as disclosed in U.S. Pat. No. 3,835,071.
  • resins as disclosed in U.S. Pat. Nos. 3,723,358 and 3,723,357 also can be used.
  • acrylate copolymers and terpolymers such as methyl methacrylate-methacrylic acid copolymers and styrene- methyl methacrylate-methacrylic acid terpolymers.
  • acrylic polymers are primary cleaning agents in these compositions and provide the function of soil entrapment when dry as well as some anti-resoil benefits.
  • a preferred acrylic polymer for use in the invention is a copolymer of styrene and acrylic acids.
  • a particular such acrylic polymer available commercially is JONCRYL 8660, which is provided as an aqueous emulsion of styrene and acrylic acid.
  • This styrene acrylic acid copolymer is available as an aqueous dispersion containing from 20-30 weight percent resin, with the balance being water.
  • the JONCRYL 8660 aqueous dispersion is an off-white, semi-translucent liquid. Since this acrylic polymer is commercially available as an aqueous emulsion, an appropriate adjustment has to be made in formulating the composition of the subject invention to allow for the presence of water. Thus, to provide a composition containing approximately 2 weight percent acrylic copolymer, JONCRYL 8660 dispersion would be added in an amount of 25 weight percent of composition.
  • JONCRYL 8660 is available from S. C. Johnson & Son, Inc., of Racine, Wisconsin, and is also distributed by Specialty Chemicals Mijdrecht b.v., P.O. Box 259, 3640 AG Mijdrecht, The Netherlands.
  • the surface active agents that are particularly useful in the present invention are anionic and nonionic synthetic organic detergents. These detergents can be used alone or in combination with other anionic or nonionic detergents.
  • anionic organic detergents are alkyl glyceryl ether sulfonates, alkyl sulfonates, alkyl mono-glyceride sulfates or sulfonates, alkyl polyethoxy ether sulfonates, alkyl aryl sulfonates, acyl sarcosinates, acyl esters of isethionates, alkyl esters of sulfosuccinic acid, and alkyl phenol polyethoxy sulfonates.
  • the alkyl and the acyl groups respectively contain 10 to 20 carbon atoms. They are used in the form of water-soluble salts, such as, by way of example only, sodium, potassium and ammonium salts.
  • the anionic organic detergents include sodium lauryl sulfate, sodium dodecyl sulfonate and sodium N- lauroyl sarcosinate.
  • nonionic organic detergents include polyethylene oxide condensates of alkyl phenols wherein the alkyl group contains from 6 to 12 carbon atoms and the ethylene oxide is present in a molar ratio of ethylene oxide to alkyl phenol in the range of 10 : 1 to 25 : 1 ; condensation products of ethylene oxide with the product resulting from the reaction of propylene oxide and ethylene diamine wherein the molecular weight of the condensation products ranges from 5,000 to 11,000; the condensation product of from about 5 to 30 moles of ethylene oxide with one mole of a branched or straight-chain aliphatic alcohol containing from 8 to 18 carbon atoms; and trialkyl amine oxides and trialkyl phosphine oxides wherein one alkyl group ranges from 10 to 18 carbon atoms and two alkyl groups range from one to three carbon atoms.
  • the preferred surfactants utilized in the present invention are anionic surfactants.
  • a particular desirable surfactant blend is a mixture of sodium lauryl sulfate and di- sodium cocoamido sulfosuccinate. This particular surfactant blend is available from Rewo Chemicals Limited, Flimby Works, Maryport, Cumbria, CA15 8RP, England, under the trade name Rewopol TS 35.
  • Rewopol TS 35 is provided in a dispersion of 35% in water to form a liquid. Since Rewopol TS 35 is provided as an aqueous preparation, appropriate adjustment has to be made to the composition to allow for the presence of water in the commercially available material.
  • Suitable foam boosters can be any one of several commercially available amine oxides or mixtures thereof.
  • a preferred amine oxide is of the formula CH 3 (CH 2 ) ⁇ oCH 2 -N(CH 3 ) 2 -_ ⁇ 0.
  • other foam boosters can be employed.
  • AMMONYX LO is lauryl dimethyl amine oxide and appears as a light straw liquid and is available from the Onxy Chemical Company, which is a division of the Millmaster Onyx Corporation, Jersey City, New Jersey 07302, U.S.A..
  • BARLOX 12 is cocodimethylamine oxide available as a 30% aqueous solution from Lonza Inc., 22-10 Route 208, Fair Lawn, New Jersey 08410, U.S.A.
  • an appropriate adjustment would need to be made to take account of the fact that some of the materials available are provided as aqueous solutions.
  • the fluoro stain repellent useful in the subject invention can be one of the fluoro materials known in the art to have this function and that is capable of being dispersed in the compositions. Such materials are generally fluoro polymers, optionally with surfactant groups, and are available as aqueous dispersions.
  • the fluoro compounds useful in compositions made in accordance with the invention unlike the volatile and relatively low molecular weight stain repellent materials previously used as part of the propellant, are left on the substrate after the treatment. They are either fluorosurfactants or fluoropolymers or a mixture thereof. If the fluorocompound is a fluorosurfactant, then the amount of other surfactant required may be reducible by the amount of the fluorosurfactant present.
  • ZONYL 7950 available from Du Pont Chemicals, Wilmington, Delaware 19898, U.S.A.
  • ZONYL 7950 is a fluorinated surfactant provided in an aqueous/isopropyl alcohol solution, and the water involved must be taken into account when calculating the weight percentages of the ingredients of a composition made in accordance with the invention.
  • an organic solvent is optionally, but preferably, included within the compositions of the present invention.
  • solvents can be alcohols such as ethyl alcohol and isopropanol; glycol ether solvents such as propylene glycol monomethyl ether, tripropylene glycol butyl ether, dipropylene glycol n-butyl ether, dipropylene glycol dimethyl ether, ethylene glycol monoethyl ether, and ethylene glycol monoburyl ether; as well as propylene carbonate.
  • glycol ethers and especially preferred is a mixture of propylene glycol monomethyl ether and dipropylene glycol methyl ether.
  • the propellant used in the invention may be any volatile hydrocarbon liquid propellant of the type generally utilized in the art.
  • butane or a mixture of propane/butane is suitable.
  • the propellant is butane.
  • ingredients may be included as optional ingredients.
  • preservatives and antimicrobial agents such as substituted diphenyl ethers; optical brighteners such as distyrylbiphenyl derivatives or stilbene derivatives; dyes; fragrances and deodorants; stain-blocking agents such as aromatic sulfonic acid condensates or carboxylated polymer salts; anti-redeposition agents such as mixtures of a nonionic surfactants or sodium salts of modified polyacrylic acids or sodium salts of maleic anhydride/olefin copolymers; ultraviolet light absorbing compounds such as 2-hydroxy-4-methoxy benzophenone or 2-hydroxy- 4-methoxy benzophenone-5-sulfonic acid; detergent builders such as borax; chelating agents; anti-corrosion agents; and anti-static agents.
  • a pH adjuster may also be required, for example an alkali metal hydroxide and particularly potassium hydroxide
  • the balance of the composition of the subject invention is water, and preferably deionized water.
  • the aerosol composition of the invention can be prepared by any conventional method of combining foam forming materials and propellant, for example by
  • a carpet or upholstery aerosol composition was formed by combining the following foam structure components:
  • Figures 1-4 illustrate the effects on flammability and oil repellency observed by changing the concentrations of the various composition components in the manner indicated in the following tests.
  • Graph 1 shows the effect on flammability and oil repellency of incremental changes in the amount of the fluorocompound (fluorosurfactant) in the formula described below.
  • Variation of Surfactant Blend Level Graph 2 (Fig 2) displays data showing the effect of varying the amount of the surfactant blend used in the formula described below.
  • the acceptable range for inclusion of this material based on the parameters of flammability and oil repellency (using a standard inclusion of fluorosurfactant within the range of the data in Graph 1) is 2.4 - 4.5% by weight of 100% active surfactant.
  • the most effective range is 2.45 - 4.2%.
  • Graph 3 (Fig 3) displays data showing the effect of varying the amount of amine oxide.
  • amine oxide When added as a foam booster, amine oxide has a very adverse effect on oil repellency at higher concentrations of amine oxide, while having a very positive effect on flammability.
  • the range of acceptable overall effect within the standard formula is 0.25 - 0.55% by weight of 100% active material. The most effective range is 0.255- 0.45%.
  • the polymer included in the formula described below does not seem to have much of an effect on the oil repellency and only a limited effect on flammability, both of these parameters being mainly influenced by the surfactants and fluorocompounds in the system.
  • a preferred range is established of 2.0 - 3.5% by weight of 100% active polymer.
  • the most effective range is 2.0-3.125%.
  • Fluorocompound stain repellent Zonyl 7950 (25%) 0.50 o Balance Water and incidental components* * to 85%
  • Fluorinated surfactant (Zonyl 7950, 25%) 0.0 0.2 0.4 0.6 0.8 1.0 1.2
  • composition of the invention is immediately applicable to the industrial need for cleaning products of the sort disclosed having controlled flammability.
  • the practical practice of the invention is described, above.

Abstract

An aerosol foam cleaning composition for carpets and soft-furnishings is provided with a fluorine-containing stain repellent, the proportions of stain repellent, foam-stabilizer polymer, surfactant, and foam booster being balanced to provide a stable foam, i.e. one which does not release hydrocarbon propellant at such a rate as to create flammability problems, with adequate cleaning properties and an adequate residue of stain repellent.

Description

CLEANING COMPOSITION
Technical Field
The present invention relates to aqueous aerosol foam cleaning compositions, particularly for use on carpets and upholstery.
Disclosure of Invention
The invention is summarized as an aerosol foam-cleaning aqueous composition containing hydrocarbon propellant, foam-stabilizing polymer, surfactant, foam booster and a fluorinated stain-repellent, in which composition the proportions of the said components provide a foam of anti-flammability stability and sufficient residual amount of stain-repellent.
Brief Description of Drawings
Figs. 1-4 are graphs of flammability and oil repellency data from the tests described, below, in the Modes of Carrying out the Invention.
Modes of Carrying out the Invention
Aerosol foam compositions for shampooing floor-coverings such as carpets or soft furnishings such as upholstery commonly comprise blends of surfactants and foam- stabilizer polymers, together with various other ingredients such as solvents, corrosion inhibitors and fragrances. The polymer stabilizes the foam produced and assists in the cleaning. In an aerosol composition, a volatile hydrocarbon liquid propellant commonly is used to create a foam, the most commonly used propellant being butane. A typical foam cleaning aerosol composition might comprise an aqueous dispersion of acrylic/styrene copolymer; sodium lauryl sulfate; ammonia; preservative and perfume, all in water; and a propane/butane blend as propellant. Such a composition would possess the following advantages: (a) excellent pick-up;
(b) good anti-soiling;
(c) very high powder hardness;
(d) fast drying;
(e) good wetting; (f) excellent removability; and
(g) improved foam stability.
The foam resulting from these aerosols has a stability dependent on the combination of the properties of the components, such as the amount of surfactant and the nature of the polymer and the other foaming agents. This stability will also affect the rate of release of butane or other hydrocarbon from the foam structure. Since the hydrocarbons, particularly butane, are very inflammable, this rate of release can influence the flammability properties of the foam structure and particularly the risk of ignition if the foam is applied close to an ignition source. However, the permissible amounts and the relative ratios of the components can usually vary widely and still provide otherwise operable compositions.
In United States Patent No.4,013,595 there is described a foam composition of the above type in which flammability is adjusted by addition of lauryl alcohol to a composition containing lauryl sulfosuccinate. In such compositions, stain blocking agents have been suggested including, for example, sulfonic acid condensates. A stain blocking agent interacts with the substrate being cleaned to prevent staining materials subsequently interacting with the substrate.
Applicant has also been considering the use of stain repellents, materials treating the substrate material by forming a coating. Such stain-repellents include fluoro stain repellents, particularly oil repellent components that provide a stain-repellent finish to the material being treated with a foam cleaner, the finish remaining after cleaning is completed. Particular stain repellents are fluorocompounds such as fluoropolymers. However, Applicant's attempts to combine these fluorocompounds with aerosol foam cleaning compositions have resulted in foams that are unstable and that release hydrocarbon at an excessive rate, giving rise to flammability problems. It has now been found that non- volatile fluorocompound stain repellent compounds can be combined with the other components of a foam cleaning composition to provide a product that retains appropriate foam stability to provide a composition sufficiently non-flammable for use with improved safety even where there are potential ignition sources, such as open fires, cigarettes, and the like. These non-volatile fluorocompounds are added not as part of the propellant but as a part of the non- propellant portion of the cleaning composition. Fluorocompounds have been added to cleaning foams in the past, but those fluorocompounds were volatile compounds added as part of the propellant.
According to the invention there is provided an aerosol foam-cleaning aqueous composition containing hydrocarbon propellant, foam-stabilizer polymer, surfactant, foam booster and a fluorinated stain repellent in which the proportions of the said components provide a foam of anti-flammability stability and that leaves behind on the surface being cleaned an effective amount of stain repellent left as residual on the surface. "Anti-flammability stability" is defined here to mean that the rate of collapse of the foam does not release the hydrocarbon propellant at a rate that creates a flammability problem having regard to the standards established in the industry and described in detail in this patent. An "effective amount" of an ingredient is defined to be an amount sufficient to achieve the specified result or effect. An amount of stain repellent left as residual on a surface is deemed effective if it reduces the tendency of the surface to receive and retain visually apparent stains.
The precise proportions of polymer, surfactant, fluorinated stain repellent and active components such as foam boosters will be governed by the specific components selected. But, once a group of components has been selected, the adjustment of the proportions necessary to achieve the desired stability, cleaning characteristics, and post- application stain repellency will be readily determinable by reference to the proportions taught in this patent.
In one embodiment of the present invention there is provided an aerosol foam cleaning composition comprising an aqueous foam structure composition that is by weight:
(a) from 2.4 to 4.5 weight percent of at least one surfactant;
(b) from 2.00 to 3.5 weight percent of at least one foam-stabilizer polymer;
(c) from 0.1 to 0.2 weight percent of at least one fluoro stain- repellent compound;
(d) 0.25 to 0.5 weight percent of at least one foam booster; and
(e) the balance water.
From 2.5 to 3.5 weight percent of at least one volatile hydrocarbon propellant is provided in the total aerosol composition, with the balance being the foam structure composition just described. Although the propellant participates in the "foam structure," the term "foam structure composition" as used herein refers to the total of those components other than the volatile propellant that contribute to the foaming characteristics of the cleaning composition.
Thus the invention comprises an aerosol foam cleaning or shampoo formulation particularly for carpets or other soft furnishings, preferably comprising specified amounts of the particular components set out above. The particular composition relies on the presence of a volatile hydrocarbon liquid propellant, preferably butane, to create a foam on actuation. It is essential that the foam generated be sufficiently stable, and foam stability depends upon, inter alia, the amount and nature of surfactant utilized, the amount and nature of polymer utilized, the presence or absence of other foaming aids, and the amount of fluorocompounds present. As mentioned above, the fluoro stain repellent compounds are added to such compositions to provide a post-cleaning, stain repellent finish and particularly an oil-repellent finish on the carpet, and can be fluoropolymer compounds or fluorosurfactant compounds. However, it has been found that the presence of such fluorocompounds in the foam has a marked influence on the surface tension thereof and therefore can greatly decrease the stability of the foam, which in turn leads to a marked increase in ignition potential. This is because, if the foam decreases in stability, then the level and rate of release therefrom of the volatile hydrocarbon propellant will increase. Since volatile hydrocarbon propellants are flammable, then their release above certain levels cannot be permitted in compositions of the type described herein without the production of unacceptable flammability.
With the composition so described, there is sufficient surfactant, sufficient polymer and sufficient foam booster that the foam produced is sufficiently stable to be effective as a cleaning composition, while the amount of surfactant and polymer is not so high as to impair the post-cleaning performance of the fluorocompounds.
The amount of flammable volatile hydrocarbon propellant is carefully selected to be high enough that sufficient foam is generated but not so high that a flammable mixture is created.
The composition must include sufficient fluorocompounds that an adequate level of post-cleaning stain repellency exists on the carpet after cleaning, while the composition remains sufficiently non-flammable.
Having regard to the functions and effects of the various components, the precise amount of each component may have to be adjusted in a particular composition to achieve maximum cleaning activity and stability of foam. A number of materials can be utilized as the foam-stabilizer polymeric component of the foam cleaning compositions of the present invention, including the styrene maleic anhydride and related resins as disclosed in U.S. Pat. No. 3,835,071. In addition to these compositions, resins as disclosed in U.S. Pat. Nos. 3,723,358 and 3,723,357 also can be used. Preferred are the various acrylate copolymers and terpolymers, such as methyl methacrylate-methacrylic acid copolymers and styrene- methyl methacrylate-methacrylic acid terpolymers. Most preferred are the acrylic polymers. In addition to providing foam stability, these polymers are primary cleaning agents in these compositions and provide the function of soil entrapment when dry as well as some anti-resoil benefits. A preferred acrylic polymer for use in the invention is a copolymer of styrene and acrylic acids. A particular such acrylic polymer available commercially is JONCRYL 8660, which is provided as an aqueous emulsion of styrene and acrylic acid. This styrene acrylic acid copolymer is available as an aqueous dispersion containing from 20-30 weight percent resin, with the balance being water. The JONCRYL 8660 aqueous dispersion is an off-white, semi-translucent liquid. Since this acrylic polymer is commercially available as an aqueous emulsion, an appropriate adjustment has to be made in formulating the composition of the subject invention to allow for the presence of water. Thus, to provide a composition containing approximately 2 weight percent acrylic copolymer, JONCRYL 8660 dispersion would be added in an amount of 25 weight percent of composition. JONCRYL 8660 is available from S. C. Johnson & Son, Inc., of Racine, Wisconsin, and is also distributed by Specialty Chemicals Mijdrecht b.v., P.O. Box 259, 3640 AG Mijdrecht, The Netherlands.
As noted above with respect to JONCRYL 8660, in commercial practice, many components of the composition of the invention are obtained as aqueous or organic solvent dispersions. The proportions of the active components stated in this description are based on the practical amounts of commercial preparations used, and are calculated from the proportion purported to be present in the commercial material added. However, some allowance must be made for commercial variance in the materials supplied, together with the possible effects of relatively inert materials also present in such commercial dispersions.
The surface active agents that are particularly useful in the present invention are anionic and nonionic synthetic organic detergents. These detergents can be used alone or in combination with other anionic or nonionic detergents. Examples of anionic organic detergents are alkyl glyceryl ether sulfonates, alkyl sulfonates, alkyl mono-glyceride sulfates or sulfonates, alkyl polyethoxy ether sulfonates, alkyl aryl sulfonates, acyl sarcosinates, acyl esters of isethionates, alkyl esters of sulfosuccinic acid, and alkyl phenol polyethoxy sulfonates. In these compounds, the alkyl and the acyl groups respectively contain 10 to 20 carbon atoms. They are used in the form of water-soluble salts, such as, by way of example only, sodium, potassium and ammonium salts. Specific examples of the anionic organic detergents include sodium lauryl sulfate, sodium dodecyl sulfonate and sodium N- lauroyl sarcosinate.
Examples of nonionic organic detergents include polyethylene oxide condensates of alkyl phenols wherein the alkyl group contains from 6 to 12 carbon atoms and the ethylene oxide is present in a molar ratio of ethylene oxide to alkyl phenol in the range of 10 : 1 to 25 : 1 ; condensation products of ethylene oxide with the product resulting from the reaction of propylene oxide and ethylene diamine wherein the molecular weight of the condensation products ranges from 5,000 to 11,000; the condensation product of from about 5 to 30 moles of ethylene oxide with one mole of a branched or straight-chain aliphatic alcohol containing from 8 to 18 carbon atoms; and trialkyl amine oxides and trialkyl phosphine oxides wherein one alkyl group ranges from 10 to 18 carbon atoms and two alkyl groups range from one to three carbon atoms. The preferred surfactants utilized in the present invention are anionic surfactants. A particular desirable surfactant blend is a mixture of sodium lauryl sulfate and di- sodium cocoamido sulfosuccinate. This particular surfactant blend is available from Rewo Chemicals Limited, Flimby Works, Maryport, Cumbria, CA15 8RP, England, under the trade name Rewopol TS 35. Rewopol TS 35 is provided in a dispersion of 35% in water to form a liquid. Since Rewopol TS 35 is provided as an aqueous preparation, appropriate adjustment has to be made to the composition to allow for the presence of water in the commercially available material. Thus, even though the surfactant blend is present in the above mentioned range of 2.4 to 4.5, for this reason the commercial Rewopol TS 35 would in preferred practice form approximately 35% of the composition (giving about 3.4% of active material). Amine oxides are added to act as foam boosters and assist in stabilizing the foam. However, excessive amine oxide could adversely affect the fluoro stain repellent that can be used in the composition of the invention. Suitable foam boosters can be any one of several commercially available amine oxides or mixtures thereof. A preferred amine oxide is of the formula CH3(CH2)ιoCH2-N(CH3)2 -_► 0. However, other foam boosters can be employed. One such commercially available amine oxide is EMPIGEN OB available from Albright & Wilson. Another such is AMMONYX LO while another is BARLOX. AMMONYX LO is lauryl dimethyl amine oxide and appears as a light straw liquid and is available from the Onxy Chemical Company, which is a division of the Millmaster Onyx Corporation, Jersey City, New Jersey 07302, U.S.A.. BARLOX 12 is cocodimethylamine oxide available as a 30% aqueous solution from Lonza Inc., 22-10 Route 208, Fair Lawn, New Jersey 08410, U.S.A. When formulating the composition of the invention, an appropriate adjustment would need to be made to take account of the fact that some of the materials available are provided as aqueous solutions. The fluoro stain repellent useful in the subject invention can be one of the fluoro materials known in the art to have this function and that is capable of being dispersed in the compositions. Such materials are generally fluoro polymers, optionally with surfactant groups, and are available as aqueous dispersions. The fluoro compounds useful in compositions made in accordance with the invention, unlike the volatile and relatively low molecular weight stain repellent materials previously used as part of the propellant, are left on the substrate after the treatment. They are either fluorosurfactants or fluoropolymers or a mixture thereof. If the fluorocompound is a fluorosurfactant, then the amount of other surfactant required may be reducible by the amount of the fluorosurfactant present. One such suitable fluorosurfactant is ZONYL 7950 available from Du Pont Chemicals, Wilmington, Delaware 19898, U.S.A. ZONYL 7950 is a fluorinated surfactant provided in an aqueous/isopropyl alcohol solution, and the water involved must be taken into account when calculating the weight percentages of the ingredients of a composition made in accordance with the invention.
To improve cleaning of oily dirt, from 0 - 5 % and more preferably from about 2% to 5% by weight of an organic solvent is optionally, but preferably, included within the compositions of the present invention. Examples of such solvents can be alcohols such as ethyl alcohol and isopropanol; glycol ether solvents such as propylene glycol monomethyl ether, tripropylene glycol butyl ether, dipropylene glycol n-butyl ether, dipropylene glycol dimethyl ether, ethylene glycol monoethyl ether, and ethylene glycol monoburyl ether; as well as propylene carbonate. Preferred are glycol ethers and especially preferred is a mixture of propylene glycol monomethyl ether and dipropylene glycol methyl ether.
The propellant used in the invention may be any volatile hydrocarbon liquid propellant of the type generally utilized in the art. As examples only, butane or a mixture of propane/butane is suitable. Preferably the propellant is butane.
In addition to the above required ingredients, minor amounts, typically less than 5% of the total foam structure composition, of conventional additives may be included as optional ingredients. These include preservatives and antimicrobial agents such as substituted diphenyl ethers; optical brighteners such as distyrylbiphenyl derivatives or stilbene derivatives; dyes; fragrances and deodorants; stain-blocking agents such as aromatic sulfonic acid condensates or carboxylated polymer salts; anti-redeposition agents such as mixtures of a nonionic surfactants or sodium salts of modified polyacrylic acids or sodium salts of maleic anhydride/olefin copolymers; ultraviolet light absorbing compounds such as 2-hydroxy-4-methoxy benzophenone or 2-hydroxy- 4-methoxy benzophenone-5-sulfonic acid; detergent builders such as borax; chelating agents; anti-corrosion agents; and anti-static agents. A pH adjuster may also be required, for example an alkali metal hydroxide and particularly potassium hydroxide.
The balance of the composition of the subject invention is water, and preferably deionized water. The aerosol composition of the invention can be prepared by any conventional method of combining foam forming materials and propellant, for example by
(a) confining said propellant in a compartment of an aerosol canister at a pressure of 48 psig;
(b) confining the balance of the ingredients in a second compartment of said aerosol canister;
(c) allowing said propellant to escape from said first compartment to said second compartment. EXAMPLE
A carpet or upholstery aerosol composition was formed by combining the following foam structure components:
Material % w/w
Water 73.05
Acrylic styrene polymer Joncryl 8660 (25%)* 8.00 Glycol ether solvent*** 4.00
Surfactant Blend (35%) (Rewopol TS35)* 9.70
Amine Oxide (Empigen OB)* 1.00
Fluorocompound (Zonyl 7950)* 0.50
Incidental ingredients ** 3.75 Total Foam Structure Composition 100.00
This was packaged as outlined above to produce the aerosol composition:
Foam Structure Composition 97.00 Propellant Butane 48 PSIG 3.00
Total: 100.00%
* Supplied as an inert organic solvent aqueous solution or dispersion.
** Incidental components: detergent builders, corrosion inhibitors, fragrance, stain blocking agent. * * * Mixture of propylene glycol methyl ether and dipropylene glycol methyl ether. The composition demonstrated acceptable flammability, foam cleaning and post- cleaning oil repellency. TEST METHODOLOGY
Samples of foam cleaners were tested by the following methods:
1. Flammability
For the purpose of this evaluation, a modification of the watch glass test is used. Six watch glasses are prepared, each with an equivalent size ball of foam (actuated at time zero for all six glasses). The experiment is performed in a fume cupboard with no air flow activated. At thirty second intervals, a naked flame is introduced to one of the glasses and removed immediately. The foam is observed for partial flash, total flash, and sustained burn. The limit of acceptable flammability is the time when the foam flashes but does not sustain the burn (and the foam is observed to burn on the next reading). As an arbitrary figure, a time of 90 seconds was selected as the acceptable limit, below which the formula would be rejected.
2. Oil Repellency
The method used for this evaluation follows the procedure set out in the AATCC test method, AATCC 118 - 1978 Oil Repellency : Hydrocarbon Resistance Test. In practical terms, virgin short cut pile white nylon carpet is used (i.e carpet that has been removed from the mill prior to dyeing and finishing with any protective treatments). The aerosol foam to be tested is applied to sections of this carpet under normal usage conditions and shampooed well into the pile. The swatches are allowed to dry for 24 hours and then are vacuumed to remove any product residues. The various hydrocarbons listed in the test method then are applied to the treated sections of the carpet in the form of 3-5mm droplets. The drops are observed after 30 seconds to see if they are beading, wetting over the surface, or soaking into the pile. The score assigned to each formula represents the highest oil still beading on the carpet. If an oil is observed to flatten (wet) on the surface but not soak in, the score is assigned as half a 6/11249 PC17US95/12930
- 12 -
unit above the previous number. On this type of carpet an acceptable score would be 1.5, below which, the repellency would not be significant.
TESTS
In the attached drawings, Figures 1-4 illustrate the effects on flammability and oil repellency observed by changing the concentrations of the various composition components in the manner indicated in the following tests.
1. Variation of Fluoro Stain Repellent
Graph 1 (Fig. 1) shows the effect on flammability and oil repellency of incremental changes in the amount of the fluorocompound (fluorosurfactant) in the formula described below. Using the limitations of acceptability for the two parameters, it can be seen from the data that mere is a particular range of inclusion of fluorosurfactant within which both flammability and oil repellency are acceptable. This range is 0.1 - 0.2% by weight of 100% active fluorocompound. Above this level, the flammability becomes too great, while below this level the oil repellency tails off.
2. Variation of Surfactant Blend Level Graph 2 (Fig 2) displays data showing the effect of varying the amount of the surfactant blend used in the formula described below. The acceptable range for inclusion of this material, based on the parameters of flammability and oil repellency (using a standard inclusion of fluorosurfactant within the range of the data in Graph 1) is 2.4 - 4.5% by weight of 100% active surfactant. The most effective range is 2.45 - 4.2%.
3. Variation of Foam Booster (Amine Oxide) Level
Graph 3 (Fig 3) displays data showing the effect of varying the amount of amine oxide. When added as a foam booster, amine oxide has a very adverse effect on oil repellency at higher concentrations of amine oxide, while having a very positive effect on flammability. The range of acceptable overall effect within the standard formula is 0.25 - 0.55% by weight of 100% active material. The most effective range is 0.255- 0.45%.
4. Variation of Polymer Level
The polymer included in the formula described below does not seem to have much of an effect on the oil repellency and only a limited effect on flammability, both of these parameters being mainly influenced by the surfactants and fluorocompounds in the system. However, based on the data displayed in Graph 4 (Fig 4), a preferred range is established of 2.0 - 3.5% by weight of 100% active polymer. The most effective range is 2.0-3.125%.
Formulae of the Compositions Used in the Tests:
1. Change in Surfactant Type/Level
5 Base 1
Raw Material % bv .weight
Acrylic/Styrene emulsion Polymer 8.00 Glycol ether solvent 4.00
Fluorocompound stain repellent Zonyl 7950 (25%) 0.50 o Balance Water and incidental components* * to 85%
** Incidental components: detergent builders, corrosion inhibitors, fragrance, stain blocking agent etc. 3.75%.
% by weight 5 Raw Material A B C D E F G H I J
Base l 85 85 85 85 85 85 85 85 85 85
Deionised 0 water 10 8 6 4 2 0 5 4.5 3 2
Surfactant
Blend(35%) 4 6 8 10 12 14 10 10 10 10
5 Amine
Oxide (30%) 1 1 1 1 1 1 0 0.5 2 3 2. Change in Fluorinated Component
Base 2
Raw Material % by weight
Acrylic Polymer emulsion (25%) 8.00
Surfactant Blend (35%) 9.70
Glycol solvent 4.00
Amine Oxide (30%) 1.00
Balance water and incidental ingredients** Balance to 98.8% * * Incidental ingredients, see note to Base 1 about 3.75% by weight
% by weight
Raw Material A B C D E F G
Base 2 98.8 98.8 98.8 98.8 98.8 98.8 98.8
Deionised Water 1.2 1.0 0.8 0.6 0.4 0.2 0.0
Fluorinated surfactant (Zonyl 7950, 25%) 0.0 0.2 0.4 0.6 0.8 1.0 1.2
3. Change in Polvmer Level
Base 3
Raw Material % by weight Glycol solvent 4.00 Surfactant Blend (35%) 9.70 Amine Oxide (30%) 1.00 Fluorocompound Zonyl 7950 (25%) 0.50 Water and incidental ingredients** Balance
** See note to Base 1 about 3.75% by weight incidental ingredients
% bv weight
Raw Material A B C D E F
Base 3 85 85 85 85 85 85
Deio ised Water 11
Acrylic/styrene Polymer for Cleaner (25%) 10 12 14
For all of the formulae above, the following conditions hold.-
-pH adjusted to 8.5 using KOH (50%)
-Product filled by weight 97.00% Formula with 3.00% Butane 48 PSIG propellant. -Conventional invert-use valve (no dip tube) and foam actuator used. -Formulae produced using same batches of raw materials. Data Relating to Tables
% Inclusion Flammabilit Oil Repellencv (mins)
Graph 1 0.0 3.0 0.0
(Fluorosurfactant 0.2 2.5 0.5 25% Active) 0.4 2.0 1.5
0.6 2.0 1.5
0.8 1.5 1.75
1.0 1.0 1.75
1.2 0.0 2.0
Graph 2 4.0 0.5 2.0
(Surfactant Blend) 6.0 1.0 2.0 35% Active) 8.0 2.0 2.0
10.0 2.0 2.0
12.0 1.5 2.0
14.0 1.5 1.0
Graph 3 0.0 0.0 0.75 (Amine Oxide 0.5 0.0 1.0 30% Active) 1.0 2.0 2.0
2.0 2.0 0.75
3.0 2.0 1.0
Graph 4 4.0 1.0 2.0 (Polymer 6.0 1.0 2.0 25% Active) 8.0 1.5 2.0
10.0 1.5 2.0
12.0 2.0 2.0
14.0 1.0 2.0
Industrial Applicability
The composition of the invention is immediately applicable to the industrial need for cleaning products of the sort disclosed having controlled flammability. The practical practice of the invention is described, above.

Claims

CI-AΪMS;
1. An aqueous aerosol foam cleaning composition containing hydrocarbon propellant, foam-stabilizing polymer, surfactant, foam booster and a fluorinated stain repellent in which the proportions of the said components provide a foam of anti- flammability stability and sufficient residual amount of stain-repellent.
2. A composition according to Claim 1 comprising from 2.5 to 3.5 weight percent of at least one volatile hydrocarbon propellant, the balance of the composition being a foam structure composition comprising by weight of the foam structure composition:
(a) from 2.4 to 4.5 weight percent of at least one surfactant;
(b) from 2.00 to 3.5 weight percent of at least one foam-stabilizer polymer; (c) from 0.1 to 0.2 weight percent of at least one stain-repellent fluorocompound;
(d) from 0.25 to 0.5 weight percent of at least one foam booster; and
(e) the balance water.
3. A composition according to Claim 1 , wherein said propellant includes butane.
4. A composition according to Claim 1 , wherein the foam booster includes at least one amine oxide.
5. A composition according to Claim 4 wherein said amine oxide is
CH3(CH2)10 CH2 -N(CH3)2 ^ 0.
6. A composition according to Claim 1 , wherein said foam stabilizer polymer is an acrylic polymer.
7. A composition according to Claim 6 wherein said acrylic polymer is a copolymer of styrene and acrylic acid.
8. A composition according Claim 1 , wherein said fluorinated stain repellent compound is selected from the group consisting of a fluorosurfactant, a fluoropolymer, or a mixture thereof.
9. A composition according to Claim 2, which also contains an organic solvent in an amount not exceeding 5% by weight of the foam structure composition.
10. A composition according to Claim 9 wherein said solvent is a glycol ether.
11. A composition according to Claim 10 wherein said glycol ether is selected from the group consisting of propylene glycol methyl ether, dipropylene glycol methyl ether, or mixtures thereof .
12. A composition according to Claim 1 , further comprising a stain blocking agent.
13. A composition according to Claim 1 , which contains as incidental ingredients one or more of preservatives and antimicrobials, anti-corrosion agents, optical brighteners, fragrances and deodorants, anti-redeposition agents, ultra-violet absorbents, detergent builders, chelating agents, anti-static agents and pH adjusters.
PCT/US1995/012930 1994-10-05 1995-10-05 Cleaning composition WO1996011249A1 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US08/809,428 US5955414A (en) 1994-10-05 1995-10-05 Cleaning foam having fluorinated stain repellent and low flammability
AU38285/95A AU3828595A (en) 1994-10-05 1995-10-05 Cleaning composition
CA002201923A CA2201923C (en) 1994-10-05 1995-10-05 Cleaning composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB9420037.5 1994-10-05
GB9420037A GB9420037D0 (en) 1994-10-05 1994-10-05 (Carpet) foam cleaning composition

Publications (1)

Publication Number Publication Date
WO1996011249A1 true WO1996011249A1 (en) 1996-04-18

Family

ID=10762352

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1995/012930 WO1996011249A1 (en) 1994-10-05 1995-10-05 Cleaning composition

Country Status (4)

Country Link
AU (1) AU3828595A (en)
CA (1) CA2201923C (en)
GB (1) GB9420037D0 (en)
WO (1) WO1996011249A1 (en)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5728669A (en) * 1997-01-16 1998-03-17 Reckitt & Colman Inc. Shelf stable hydrogen peroxide containing carpet cleaning and treatment compositions
WO1999036499A1 (en) * 1998-01-19 1999-07-22 Unilever N.V. Hard surface cleaners
US5955413A (en) * 1997-10-24 1999-09-21 3M Innovative Properties Company Carpet cleaning and reapplication system based on methacrylic acid polymer, sequestrant, and anionic surfactant
US6028044A (en) * 1997-10-08 2000-02-22 Adrian J. Harris Method for cleaning hard and soft surfaces with multi-purpose cleaner/degreaser and carpet/fabric stain remover
WO2000049363A1 (en) * 1999-02-19 2000-08-24 Bureaux John G Foam formulations
WO2001068793A1 (en) * 2000-03-15 2001-09-20 Henkel Kommanditgesellschaft Auf Aktien Cleaning agent
US6415800B2 (en) 2000-01-14 2002-07-09 The Gillette Company Method of shaving and a dispensing apparatus therefor
EP1264875A1 (en) * 2001-06-08 2002-12-11 Givaudan SA Cleaning composition

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3723357A (en) * 1970-11-16 1973-03-27 Colgate Palmolive Co Liquid detergent compositions
US3723358A (en) * 1971-02-22 1973-03-27 Johnson & Son Inc S C Fabric treating shampoo compositions
US3835071A (en) * 1969-11-17 1974-09-10 Atlantic Richfield Co Rug shampoo compositions
US4013595A (en) * 1975-05-23 1977-03-22 S. C. Johnson & Son, Inc. Non-flammable rug cleaning composition
US4089804A (en) * 1976-12-30 1978-05-16 Ciba-Geigy Corporation Method of improving fluorinated surfactants
US5259848A (en) * 1990-06-11 1993-11-09 Interface, Inc. Method for removing stains from carpet and textiles
US5338475A (en) * 1991-08-16 1994-08-16 Sterling Drug, Inc. Carpet cleaning composition with bleach
US5439610A (en) * 1993-10-19 1995-08-08 Reckitt & Colman Inc. Carpet cleaner containing fluorinated surfactant and styrene maleic anhydride polymer

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3835071A (en) * 1969-11-17 1974-09-10 Atlantic Richfield Co Rug shampoo compositions
US3723357A (en) * 1970-11-16 1973-03-27 Colgate Palmolive Co Liquid detergent compositions
US3723358A (en) * 1971-02-22 1973-03-27 Johnson & Son Inc S C Fabric treating shampoo compositions
US4013595A (en) * 1975-05-23 1977-03-22 S. C. Johnson & Son, Inc. Non-flammable rug cleaning composition
US4089804A (en) * 1976-12-30 1978-05-16 Ciba-Geigy Corporation Method of improving fluorinated surfactants
US5259848A (en) * 1990-06-11 1993-11-09 Interface, Inc. Method for removing stains from carpet and textiles
US5338475A (en) * 1991-08-16 1994-08-16 Sterling Drug, Inc. Carpet cleaning composition with bleach
US5439610A (en) * 1993-10-19 1995-08-08 Reckitt & Colman Inc. Carpet cleaner containing fluorinated surfactant and styrene maleic anhydride polymer

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5728669A (en) * 1997-01-16 1998-03-17 Reckitt & Colman Inc. Shelf stable hydrogen peroxide containing carpet cleaning and treatment compositions
GB2321251A (en) * 1997-01-16 1998-07-22 Reckitt & Colman Inc Carpet cleaning and treatment compositions
GB2321251B (en) * 1997-01-16 2001-03-14 Reckitt & Colman Inc Carpet cleaning and treatment compositions
US6028044A (en) * 1997-10-08 2000-02-22 Adrian J. Harris Method for cleaning hard and soft surfaces with multi-purpose cleaner/degreaser and carpet/fabric stain remover
US5955413A (en) * 1997-10-24 1999-09-21 3M Innovative Properties Company Carpet cleaning and reapplication system based on methacrylic acid polymer, sequestrant, and anionic surfactant
WO1999036499A1 (en) * 1998-01-19 1999-07-22 Unilever N.V. Hard surface cleaners
WO2000049363A1 (en) * 1999-02-19 2000-08-24 Bureaux John G Foam formulations
US6553887B1 (en) 1999-02-19 2003-04-29 Her Majesty The Queen In Right Of Canada As Represented By The Solicitor General Acting Through The Commissioner Of The Royal Canadian Mounted Police Foam formulations
US6415800B2 (en) 2000-01-14 2002-07-09 The Gillette Company Method of shaving and a dispensing apparatus therefor
US6622943B2 (en) 2000-01-14 2003-09-23 The Gillette Company Method of shaving and a dispensing apparatus therefor
WO2001068793A1 (en) * 2000-03-15 2001-09-20 Henkel Kommanditgesellschaft Auf Aktien Cleaning agent
EP1264875A1 (en) * 2001-06-08 2002-12-11 Givaudan SA Cleaning composition

Also Published As

Publication number Publication date
GB9420037D0 (en) 1994-11-16
AU3828595A (en) 1996-05-02
CA2201923A1 (en) 1996-04-18
CA2201923C (en) 2001-06-19

Similar Documents

Publication Publication Date Title
US5955414A (en) Cleaning foam having fluorinated stain repellent and low flammability
US5338475A (en) Carpet cleaning composition with bleach
US5514302A (en) Fabric cleaning shampoo compositions
EP0766728B1 (en) Carpet cleaning and restoring composition
AU650341B2 (en) Removing stains from carpet
AU699687B2 (en) Aerosol cleaning compositions
US4606842A (en) Cleaning composition for glass and similar hard surfaces
US6043209A (en) Stable compositions for removing stains from fabrics and carpets and inhibiting the resoiling of same
EP0804536B1 (en) Glass cleaner compositions
US5712240A (en) Aqueous cleaning compositions providing water and oil repellency to fiber substrates
ES2201274T3 (en) CLEANING AND TREATMENT COMPOSITIONS OF STORAGE CARPETS STORAGE CONTAINING HYDROGEN PEROXIDE.
US6867174B2 (en) Non-foaming cleaning compositions and a method for their use
EP0616637B1 (en) Fabric cleaning shampoo compositions
EP0888433B1 (en) Glass cleaner compositions having good filming/streaking characteristics containing amine oxide polymers functionality
CA2201923C (en) Cleaning composition
US5439610A (en) Carpet cleaner containing fluorinated surfactant and styrene maleic anhydride polymer
EP0648834B1 (en) Carpet cleaner
CA1323819C (en) Carpet cleaning composition
JP2004505183A (en) Ironing auxiliary composition
WO2002083828A1 (en) Non-foaming cleaning compositions and a method for their use
WO1996034933A1 (en) Glass cleaner compositions having linear alkyl sulfate surfactants
JPH0925478A (en) Aqueous dispersion-type water-and-oil-repellent composition
NZ203306A (en) Aqueous glass-cleaning composition containing polyacrylic resin
US7229954B1 (en) Carpet cleaning composition with citrus
CA2248790C (en) Glass cleaner compositions having good filming/streaking characteristics containing amine oxide polymers functionality

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AU BG BR CA CZ EE FI HU JP LT LV MX NZ PL RO RU UA US

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): AT BE CH DE DK ES FR GB GR IE IT LU MC NL PT SE

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
ENP Entry into the national phase

Ref document number: 2201923

Country of ref document: CA

Ref country code: CA

Ref document number: 2201923

Kind code of ref document: A

Format of ref document f/p: F

WWE Wipo information: entry into national phase

Ref document number: 08809428

Country of ref document: US

122 Ep: pct application non-entry in european phase